jill grenon, terry svalberg, ted porwoll, mark story bridger-teton nf analysis of lake, bulk, nadp,...

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Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Stor Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

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Page 1: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story

Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Page 2: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Available datasets for analysis

Four Lakes in the Bridger Wilderness (annual, seasonal, inlet, outlet, hypolimnion, and epilimnion),1984.

Two bulk deposition sites in the Bridger Wilderness (annual deposition-includes snow and rain),1985.

Five NADP sites (annual and seasonal concentrations and deposition), GC and PI since 1982.

Three IMPROVE sites (annual and seasonal), 1988.

Page 3: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data
Page 4: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Statistics

SAS Institute statistical software was used to run analyses following draft USFS Data Analysis Protocol (DAP) recommendations in coordination with Lori Porth, RMRS Statistician

Non-parametric tests because we are working with non-normal distributions that have errors, gross outliers, or missing data in the data set.

Our designated alpha level for trend detection was α = 0.1, we also reported α levels of 0.05, 0.01, 0.001. A significant p-value does not speak to the magnitude of a trend.

Page 5: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Raw data preparation and exploratory analysis

Mann –KendallSen slope estimator

Kruskal-WallisSeasonal Mann-Kendall

Sen slope estimator

p-valuesSlope estimates

INTERPRETATION

Page 6: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Statistical Tests Used

Mann-Kendall – calculated each elemental variable over the years to see if there were statistically significant increasing or decreasing trends.

Kruskal-Wallis -- to see if seasons in the data set were statistically different

Seasonal Mann-Kendall-run to look for trends while taking seasonality into account

Sens slope estimator- magnitude of slope.

Page 7: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Gypsum Creek and Pinedale NADP sites Seasonal Trends

Winter Spring Summer Fall

GC PI GC PI GC PI GC PI

NH4+ *** --- --- --- ** * **** ***

NO3- ** --- --- --- --- --- ** *

IN *** --- --- --- ** --- *** **

SO42-

--- *** --- ** --- *** --- *

* = p<0.1, **= p<0.05, ***=p<0.01, **** =p<0.001

Page 8: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Gypsum Creek NADP site winter nitrogen deposition

0

0.1

0.2

0.3

0.4

0.5

0.6

kg

/ha

/yr

NH4NO3IN

Page 9: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Gypsum Creek

00.20.40.60.8

11.2

kg/h

a/yr

NH4NO3IN

00.20.40.60.8

11.21.4

kg/h

a/yr

NO3NH4IN

Fall Nitrogen wetDeposition NADP

Pinedale

Page 10: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Trends in Annual Lake Concentrations (μeq/L)

Black Joe Deep Hobbs

Inlet Outlet Inlet Outlet Inlet Outlet

NH4+ --- * --- --- ** *

NO3- *** ** ** --- * ---

SO42- * --- --- --- --- ---

* = p<0.1, **= p<0.05, ***=p<0.01, **** =p<0.001

Page 11: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Trends in Seasonal Lake Conc. (μeq/L) (at inlets unless stated otherwise)

Black Joe Deep Hobbs

S1 S2 S3 S1 S2 S3 S1 S2 S3

NH4+ --- --- --- --- --- --- ** * ---

NO3- --- ** *** --- ** * --- ** ---

SO42- --- ** --- --- --- --- --- ** ---

OutletNO3

- --- ** --- --- --- --- --- --- ---

OutletSO4

2- * --- * --- --- --- --- --- ---

* = p<0.1, **= p<0.05, ***=p<0.01, **** =p<0.001

Page 12: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

0

10

20

30

40

50

ueq

/L

Black JoeDeepHobbs

10

20

30

40

50

ueq

/L

Season 1

Season 3

Annual sulfate conc. From the

hypolimnion

Seasonal sulfate concentrationsFrom Black Joe

Outlet

Page 13: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Black Joe and Hobbs Bulk Deposition

Variable Black Joe Hobbs

NH4+ ** ***

NO3- ** ***

Total N * ***

Precipitation ** **

SO42- --- ---

* = p<0.1, **= p<0.05, ***=p<0.01, **** =p<0.001

Page 14: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Annual Nitrogen Bulk Deposition

(Total)1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

kg/h

a Hobbs

Black Joe

40

60

80

100

120

140

160cm

Hobbs

Black Joe

Annual precipitation at Bulk Deposition

sites

Page 15: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Yell2 IMPROVE site on a clear day and on a hazy day

Spectrum Seriesdv=0 Bext=10 SVR=390

Spectrum Seriesdv=17 Bext=52 SVR=75

Page 16: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

SVR= Standard Visual Range – measured in km. The measured distance one should be able to see.

dv = deciview – official unit for regional haze. The increment corresponding to the minimum change in visibility detectable to the human eye.

Visibility

Page 17: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

SVR at IMPROVE sites

50

100

150

200

250

300

350

km

BRID1

MOZI1

YELL1&2

BRID1

MOZI1

YELL1&2

20% best SVR

20% worst SVR

Page 18: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Trends at BRID1 and YELL1&2 IMPROVE sites

BRID1 in nitrate—winter *

in sulfate—annual**, summer**, fall**

YELL1&2 in nitrate—annual*

in sulfate—spring*

in sulfate—fall*

(R1 IMPROVE sites had no in nitrate or sulfate)

* = p<0.1, **= p<0.05, ***=p<0.01, **** =p<0.001

Page 19: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Brief Summary

General decrease in sulfate (but increase in some of the lakes)

General increase in visibility (IMPROVE site was just installed at Boulder which is projected to be the deposition hotspot).

Increase in ammonium (agrees with the general increase occurring across the western US).

Increase in nitrate this trend was also found in the CO Front Range.

Page 20: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

Where do we go from here?

Analyze the Bulk deposition sites for seasonality.

Quantify the deposition for each of the data sets and compare total deposition for N and S between data sets.

How much of an increase or decrease is there? Compare N and S deposition in R4 to R1 and

R2. What are the repercussions for increase in N

and S? Critical loads?

Page 21: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

N deposition and Critical Loads

Total N deposition at the Hobbs and BJ bulk sample sites average 2.35 and 2.66 kg/ha-1year-1 respectively and range from 1.23 to 4.3 kg/ha-1year-1

Baron (2006) suggest CL for high alpine lakes in CO ~1.5 kg/ha-1year-1

Fenn et al. (2008) suggest CL for lichens communities in mixed conifer forests of CA to be around 3.1 kg/ha-1year-1

Page 22: Jill Grenon, Terry Svalberg, Ted Porwoll, Mark Story Bridger-Teton NF Analysis of Lake, Bulk, NADP, and IMPROVE N and S data

THANK YOU

Laurie Porth Scott Copeland Thomas Dzomba GYCC for funding

the analysis Various reviewers.