itt chng ch 12 properties of solutions
TRANSCRIPT
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
1/30
Physical Properties of Solutions
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
2/30
12.1
A solutionis a homogenous mixture of 2 or
more substances
The soluteis(are) the substance(s) present in thesmaller amount(s)
The solventis the substance present in the larger
amount
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
3/30
A saturated solutioncontains the maximum amount of a
solute that will dissole in a gien solent at a specific
temperature.
An unsaturated solutioncontains less solute than thesolent has the capacity to dissole at a specific
temperature.
A supersaturated solutioncontains more solute than ispresent in a saturated solution at a specific temperature.
Sodium acetate crystals rapidly form when a seed crystal is
added to a supersaturated solution of sodium acetate.
12.1
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
4/30
12.2
Three types of interactions in the solution process!" solent#solent interaction" solute#solute interaction" solent#soluteinteraction
$soln% $1& $2& $'
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
5/30
like dissolves like
Two substances with similar intermolecularforces are li*ely
to be soluble in each other.
" non#polar molecules are soluble in non#polar solents
++l,in +-$-
" polar molecules are soluble in polar solents
+2
$
/$ in $2
/
" ionic compounds are more soluble in polar solents
0a+l in $2/ or 0$'(l)
12.2
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
6/30
+oncentration nits
The concentrationof a solution is the amount of solute
present in a gien uantity of solent or solution.
Percent by Mass
3 by mass % x 1443
mass of solute
mass of solute & mass of solent
% x 1443mass of solute
mass of solution
12.'
Mole Fraction(X)
XA%moles of A
sum of moles of all components
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
7/30
+oncentration nits +ontinued
M %moles of solute
liters of solution
Molarity(M)
Molality(m)
m % moles of solutemass of solent (*g)
12.'
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
8/30
5hat is the molality of a .6- Methanol (+2$/$)
solution whose density is 4.728 g9m:;
m % moles of solutemass of solent (*g)
M % moles of solute
liters of solution
Assume 1 : of solution!
.6- moles ethanol % 284 g ethanol728 g of solution (1444 m: x 4.728 g9m:)
mass of solent % mass of solution < mass of solute
% 728 g < 284 g % -8 g % 4.-8 *g
m %moles of solute
mass of solent (*g)%
.6- moles +2$/$
4.-8 *g solent% 6.72 m
12.'
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
9/30
Temperature and Solubility
Solid solubility and temperature
solubility increases withincreasing temperature
solubility decreases with
increasing temperature
12.,
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
10/30
Fractional crystallizationis the separation of a mixture of
substances into pure components on the basis of their differing
solubilities.
Suppose you hae 74 g =0/'
contaminated with 14 g 0a+l.
>ractional crystalli?ation!
1. @issole sample in 144 m: ofwater at -44+
2. +ool solution to 44+
'. All 0a+l will stay in solution
(s % ',.2g9144g),. 86 g of PB =0/'will
precipitate (s % 12 g9144g).
74 g < 12 g % 86 g
12.,
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
11/30
Temperature and Solubility
/2gas solubility and temperature
solubility usuallydecreases with
increasing temperature
12.,
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
12/30
Pressure and Solubility of Cases
12.
The solubility of a gas in a liuid is proportional to the
pressure of the gas oer the solution (Henrys law).
c% kP
cis the concentration (M) of the dissoled gas
Pis the pressure of the gas oer the solution
kis a constant for each gas (mol9:"atm) that
depends only on temperature
low P
low c
high P
high c
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
13/30
Chemistry In Action:The =iller :a*e
Lake Nyos, West Africa
8!"8#
C$!Clo%d &eleased
"'(( Cas%alties
)ri**er+
" earth%ake
" landslide
" stron* Winds
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
14/30
+olligatie Properties of 0onelectrolyte Solutions
Colligative propertiesare properties that depend only on the
n%mberof solute particles in solution and not on the nat%reofthe solute particles.
-a.or/Press%re Lo0erin*
Raoults law
Df the solution contains only one solute!
X1% 1
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
15/30
PA%XA P A4
PE%XE P E4
PT% PA& PE
PT%XA P A4 +XE P E
4
Ddeal Solution
12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
16/30
PTis greater than
predicted by aoultsFs law
PTis less than
predicted by aoultsFs law
>orce
A#E
>orce
A#A
>orce
E#EG H
>orce
A#E
>orce
A#A
>orce
E#EI H
12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
17/30
Fractional 1istillation A..arat%s
12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
18/30
2oilin*/Point 3levation
Tb% Tb< T b4
TbI T b4
TbI 4
T bis the boiling point of
the pure solent
4
T bis the boiling point of
the solution
Tb% Kbm
mis the molality of the solution
Kbis the molal boiling#point
eleation constant (4+9m)
for a ien solent12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
19/30
Free4in*/Point 1e.ression
Tf% T f < Tf4
T fI Tf4
TfI 4
T f is the free?ing point of
the pure solent
4
T f is the free?ing point of
the solution
Tf% Kfm
mis the molality of the solution
Kfis the molal free?ing#point
depression constant (4+9m)
for a gien solent 12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
20/30 12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
21/30
5hat is the free?ing point of a solution containing ,86 g
of ethylene glycol (antifree?e) in '242 g of water; The
molar mass of ethylene glycol is -2.41 g.
Tf% Kfm
m % moles of solutemass of solent (*g)
% 2.,1 m%'.242 *g solent
,86 g x1 mol
-2.41 g
Kfwater % 1.6-4+9m
Tf% Kfm % 1.6-4+9mx 2.,1 m% ,.,6 4+
Tf% T f < Tf4
Tf% T f < Tf4 % 4.44 4+ < ,.,6 4+ % #,.,6 4+
12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
22/30
$smotic Press%re 56
12.-
Osmosisis the selectie passage of solent molecules through a porous
membrane from a dilute solution to a more concentrated one.
A semipermeable membraneallows the passage of solent molecules butbloc*s the passage of solute molecules.
Osmotic pressure ()is the pressure reuired to stop osmosis.
dilutemore
concentrated
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
23/30
$igh
P
:ow
P
$smotic Press%re 56
% MRT
M is the molarity of the solution
Ris the gas constant
Tis the temperature (in =) 12.-
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
24/30
A cell in an:
12.-
isotonic
solution
ypotonic
solution
ypertonic
solution
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
25/30
+olligatie Properties of 0onelectrolyte Solutions
Colligative propertiesare properties that depend only on the
n%mberof solute particles in solution and not on the nat%reof
the solute particles.
12.-
-a.or/Press%re Lo0erin* P1%X1 P 14
2oilin*/Point 3levation Tb% Kbm
Free4in*/Point 1e.ression Tf% Kfm
$smotic Press%re 56 % MRT
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
26/30
+olligatie Properties of Blectrolyte Solutions
12.8
4.1 m0a+l solution 4.1 m0a&ions H 4.1 m+l#ions
Colligative propertiesare properties that depend only on then%mberof solute particles in solution and not on the nat%reof
the solute particles.
4.1 m0a+l solution 4.2 mions in solution
vant Ho!! !actor (i)%actual number of particles in soln after dissociation
number of formula units initially dissoled in soln
nonelectrolytes
0a+l
+a+l2
ishould be
1
2
'
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
27/30
2oilin*/Point 3levation Tb% iKbm
Free4in*/Point 1e.ression Tf% i Kfm
$smotic Press%re 56 % iMRT
+olligatie Properties of Blectrolyte Solutions
12.8
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
28/30
A colloidis a dispersion of particles of one substance
throughout a dispersing medium of another substance.
+olloid ersus solution" collodial particles are much larger than solute molecules
" collodial suspension is not as homogeneous as a solution
12.6
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
29/30
The +leansing Action of Soap
12.6
-
7/29/2019 ITT Chng Ch 12 Properties of Solutions
30/30
Chemistry In Action:
@esalination