isomerization of mixed xylene – ethylbenzene feeds over ... · pdf filecumene phenol,...
TRANSCRIPT
![Page 1: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/1.jpg)
This material is not to be reproduced without the permission of Exxon Mobil Corporation.
Thomas F. Degnan, Jr., David H. Olson, and B. K. HuhExxonMobil Research and Engineering CompanyAmerican Institute of Chemical Engineers Annual MeetingSan Francisco, CAMonday, November 4, 2013
Isomerization of Mixed Xylene –Ethylbenzene Feeds over ZSM-5:Analysis of Kinetics and Diffusion of C10 Transalkylation ProductsIn Honor of Professor W. Nicholas Delgass 2012 R. H. Wilhelm Award Recipient
![Page 2: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/2.jpg)
2
Congratulations Nick!
Great friend, wonderful colleague, and inspirational teacher
• 2003 Purdue University Outstanding Undergraduate Teaching Award in memory of Charles B. Murphy.
• Dean A.A. Potter Teaching Award, Purdue, Schools of Engineering, 1990. • R.N. Shreve Teaching Award, Purdue School of Chemical Engineering, 1983,
1986, 1989,1991, 2000 and 2002. • Purdue Schools of Engineering Mentoring Excellence Award 2003. • New York Catalysis Society Excellence in Catalysis Award, 2006• Inaugural North American Catalysis Society (NACS) Award for Distinguished
Service in the Advancement of Catalysis, 2010• AIChE R. H. Wilhelm Award, 2012
![Page 3: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/3.jpg)
3
Manufacture of High Value Alkylaromatics
Alkylaromatic Major Uses WW Production, lbs/yr Ethylbenzene Styrene, Polystyrene 60 BillionCumene Phenol, Bisphenol-A, Polycarbonate 18 BillionPara-Xylene Terephthalic acid, Polyester 36 Billion
Reformer
Fractionation TransalkylationC9
+ , C6/C7
Isomerization
Disproportionation
Cumene Synthesis
EB Synthesis
Xylene
Toluene
Benzene
C2=
C3=
Ethylbenzene
Cumene
Para-Xylene
BenzeneCracker / Separations
2011
![Page 4: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/4.jpg)
4
Manufacture of High Value Alkylaromatics
Alkylaromatic Major Uses WW Production, lbs/yr Ethylbenzene Styrene, Polystyrene 60 BillionCumene Phenol, Bisphenol-A, Polycarbonate 18 BillionPara-Xylene Terephthalic acid, Polyester 36 Billion
Reformer
Fractionation TransalkylationC9
+ , C6/C7
Isomerization
Disproportionation
Cumene Synthesis
EB Synthesis
Xylene
Toluene
Benzene
C2=
C3=
Ethylbenzene
Cumene
Para-Xylene
BenzeneCracker / Separations
2011
![Page 5: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/5.jpg)
5
Para-Xylene Can be Produced Via Equilibrium or Selective Processes
+2
+2
Xylene Isomerization Toluene Disproportionation
XylenesAt
Equilibrium
SelectiveProcesses
EquilibriumProcesses
Transalkylation
Selective TolueneDisproportionation
22% Ortho- 54% Meta- 24% Para-
Para- >> 24%
Para- ~ 24%
Para- ~ 24%
All ProcessesRequire
Separation
+ 2
![Page 6: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/6.jpg)
6
ExxonMobil’s Xylene IsomerizationProcess Development HistoryContinuous Development and Improvement for 35+ Years
Lower pX Concentration in Isom feeds(e.g. from adsorption)
Higher pX Concentration in Isom feeds(e.g. from crystallizers)
MHAI1990
MHTI1981
MLPI1978
MVPI1975
AdvancedMobilHighActivityIsom.
MobilHighActivityIsom.
MobilHighTemperatureIsom.
MobilLowPressureIsom.
MobilVaporPhaseIsom.
![Page 7: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/7.jpg)
7
ExxonMobil MHAIXylene Isomerization Process
p-Xylene recovery
Unit
C9+ Aromatics
Make-up Hydrogen
Separator
Compressor Hydrogen Recycle
Gas
Benzene &Toluene
Isomerate
CW
Stabilizer
Reactor
Furnace
XyleneColumn
Para-xylene
C8AromaticHeart-cut
EBConversion
Xylene Isomerization
Catalysts
+
![Page 8: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/8.jpg)
8
ExxonMobil MHAIXylene Isomerization Process
p-Xylene recovery
Unit
C9+ Aromatics
Make-up Hydrogen
Separator
Compressor Hydrogen Recycle
Gas
Benzene &Toluene
Isomerate
CW
Stabilizer
Reactor
Furnace
XyleneColumn
Para-xylene
C8AromaticHeart-cut
EBConversion
Xylene Isomerization
Catalysts
+
![Page 9: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/9.jpg)
9
Transalkylation Reactions inthe Ethylbenzene – Xylene System
+
+
E , E
E , X+
X , E++
X , X+ +
Ref: D. H. Olson and W. O. Haag, ACS Symp.Ser. 248, pp. 275 – 307 (1984)
+
![Page 10: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/10.jpg)
10
Xylene – EB TransalkylationProduces C9 and C10 Aromatics
ZSM-5 Crystal
+ +
+
+ +
+
+ +
DEB
DMEB
kE,E
kX,E kE,X
kX,X
![Page 11: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/11.jpg)
11
Xylene – EB TransalkylationProduces C9 and C10 Aromatics
ZSM-5 Crystal
+ +
+
+ +
+
+ +
DEB
DMEB
kE,E
kX,E kE,X
kX,X
Changes in DEB/DMEBRatio are indicators ofIntracrystallinediffusivity
![Page 12: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/12.jpg)
12
Transalkylation Kinetic Parametersin EB – Xylene System
Relative Rate ConstantsReaction ZSM-4 Mordenite ZSM-5
E, E 10.4 20.8 125.0E, X 2.2 3.6 16.8X, E 1.3 1.5 3.6X, X 1.0 1.0 1.0
Ethyl vs. Methyl TransferkE,E / kX,E 8.0 13.9 34.7kE,X / kX,X 2.2 3.6 16.8
Ethylbenzene vs. XylenekE,E / kE,X 4.7 5.8 7.4kX,E / kX,X 1.3 1.5 3.6Memo: Conditions: 250 – 280oC, 2800 kPa, WHSV = 2 to 20 hr-1
Ref: D. H. Olson and W. O. Haag, ACS Symp.Ser. 248, pp. 275 – 307 (1984)
![Page 13: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/13.jpg)
13
Aromatic Kinetic Diameters areClose to Pore Diameters of ZSM-5
Straight Channel5.4 x 5.6 Å
Sinusoidal Channel5.1 x 5.5 Å
Kinetic Diameter of Aromatics Close to the Pore Size of ZSM-56.8 6.8 5.8 5.8 5.8 5.8
~ ~ ~ ~
Ortho-Xylene Meta-Xylene Para-Xylene Ethylbenzene
>
Toluene Benzene
![Page 14: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/14.jpg)
14
The Role of Shape Selective Zeolites in C8 – C10 Aromatic Reactions
Reactant Selectivity (Hydrodealkylation)
Product or Isomer Selectivity (Selective Toluene Disproportionation)
+ H 2 +
+2
Csicsery, J Catal 1971, 23, 124
5.8 Å6.8 Å 6.8 Å
Metal
Transition State Selectivity (C8 Aromatics Disproportionation)
+very low
yields+ +Bulky
![Page 15: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/15.jpg)
15
Study Objectives
• Examine the diffusional characteristics of C10 transalkylation products (DMEB and DEB) in ZSM-5 catalyzed Isomerization of Xylene: Ethylbenzene Feeds
• ZSM-5 catalyzed isomerization of a mixed Xylene: EB feed• Mixed Xylenes (86 wt%) : Ethylbenzene (14 wt%)• Temperatures: 350o – 390oC• WHSV = 2 to 150 hr-1
• H2 : Hydrocarbon molar ratios = 2 to 4• Pressure = 1480 kPa
![Page 16: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/16.jpg)
16
ZSM-5 Catalysts
Designation Relative Activity (C6 cracking)
D/r2 , sec-1
(p-Xylene uptake method)
SCLA 1.5 3.2 x 10-4
MCLA 1.0 4.7 x 10-5
LCLA 1.3 6.3 x 10-6
SCMA 13.3 3.4 x 10-4
MCMA 17.5 4.5 x 10-5
LCMA 6.7 5.7 x 10-6
SCHA 70.0 3.1 x 10-4
MCHA 58.3 3.3 x 10-5
LCHA 54.7 5.0 x 10-6
Memo: SC - Small Crystal; MC - Midsize Crystal; LC - Large Crystal; LA – Low Activity; MA – Moderate Activity; HA – High Activity
![Page 17: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/17.jpg)
17
Effect of ZSM-5 Acidity onDiethylbenzene (DEB) Yield
EB Conversion, mole pct.
DE
B Y
ield
, mol
e pc
t.
Temperature: 370oCWHSV = 2 to 150 hr-1
H2 : Hydrocarbon molar ratios = 2 to 4Pressure = 1480 kPa
Large Crystal
Low activityModerate activityHigh activity
![Page 18: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/18.jpg)
18
Small Crystal
Medium Crystal
Large Crystal
Effect of Crystal Size onDiethylbenzene (DEB) Yield
Temperature: 370oCWHSV = 2 to 150 hr-1
H2 : Hydrocarbon molar ratios = 2 to 4Pressure = 1480 kPa
EB Conversion, mole pct.
DE
B Y
ield
, mol
e pc
t.
![Page 19: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/19.jpg)
19
Small Crystal
Medium Crystal
Large Crystal
Effect of Crystal Size onDimethylethylbenzene (DMEB) Yield
Temperature: 370oCWHSV = 2 to 150 hr-1
H2 : Hydrocarbon molar ratios = 2 to 4Pressure = 1480 kPa
EB Conversion, mole pct.
DM
EB
Yie
ld, m
ole
pct.
![Page 20: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/20.jpg)
20
Small Crystal
Medium Crystal
Large Crystal
Effect of Crystal Size onDEB / DMEB Ratio
Temperature: 370oCWHSV = 2 to 150 hr-1
H2 : Hydrocarbon molar ratios = 2 to 4Pressure = 1480 kPa
EB Conversion, mole pct.
DE
B /
DM
EB
Rat
io, m
olar
![Page 21: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/21.jpg)
21
Summary: Effects of ZSM-5 Crystal Size
• DEB yield is a direct function of the zeolite acidity, or number of acid sites.
• DEB yield is a strong function of EB conversion and a mild function of crystal size.
• Conversely, DMEB yield is a strong function of crystal size, indicating that it is more strongly influenced by intracrystalline diffusivity and crystal size.
• DEB/DMEB Ratio increases with ZSM-5 crystal size and activity which is consistent with differences in the intracrystalline diffusivities of DEB and DMEB
![Page 22: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/22.jpg)
22
0.1
1
10
0 0.02 0.04 0.06 0.08
DEB and DMEB:First Order Kinetics
1/WHSV
kDEB = 60 hr-1
Small Crystal; Low Activity ZSM-5370oC1515 kPa
kDEB = k E E kDMEB= k X E
1/WHSV
DMEB
Production of Diethylbenzene andDimethylethylbenzene are both governed by First Order Kinetics
DEB
No diffusion limitation expected - withlow crystal activities and small crystal
0.01
0.1
1
0 0.02 0.04 0.06 0.08
kDMEB = 6 hr-1
Olson and Haag This (1984) Study
kDEB / kDMEB 7.4 10.0
Frac
tion
DM
EB
in P
rodu
ct, m
olar
Frac
tion
DM
EB
in P
rodu
ct, m
olar
Ref: D. H. Olson and W. O. Haag, ACS Symp.Ser. 248, pp. 275 – 307 (1984)
![Page 23: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/23.jpg)
23
Transalkylation Kinetic Parametersin EB – Xylene System
Relative Rate ConstantsReaction ZSM-4 Mordenite ZSM-5
E, E 10.4 20.8 125.0E, X 2.2 3.6 16.8X, E 1.3 1.5 3.6X, X 1.0 1.0 1.0
Ethyl vs. Methyl TransferkE,E / kX,E 8.0 13.9 34.7kE,X / kX,X 2.2 3.6 16.8
Ethylbenzene vs. XylenekE,E / kE,X 4.7 5.8 7.4kX,E / kX,X 1.3 1.5 3.6Memo: Conditions: 250 – 280oC, 2800 kPa, WHSV = 2 to 20 hr-1
Ref: D. H. Olson and W. O. Haag, ACS Symp.Ser. 248, pp. 275 – 307 (1984)
![Page 24: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/24.jpg)
24
Diffusional Considerations
kobs = k
= R(k/D)1/2
= f (
Then, from Haag et al.,
= tanh R(k/D)1/2
and kH ~ alpha (hexane cracking activity)
Ref: W. O. Haag, R. M. Lago, and P. B. Weisz, Trans. Faraday Soc. pp 317-330 (1981)
ZSM-5 Crystal as a flat plate
![Page 25: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/25.jpg)
25
Transalkylation of EB to DEB
Crystal R,m
Activity,kH
kDEB obs
hr-1
Selectiv.kDEB obs
kH
R(kDEB obs)1/2
X 105 kintrins
sec-1
R2 kintrins
cm2/sec
SCLA 0.025 1.5 60 34 1.7 1 2.8E-04 1.0E-13
SCMA 0.02 13.3 532 34 4.2 0.97 2.8E-04 5.9E-13
SCHA 0.08 70 1235 15 259 0.42 1.2E-04 5.0E-11
MCLA 0.12 1 38 34 7.1 0.95 2.6E-04 1.6E-12
MCMA 0.15 17.5 600 29 33.9 0.83 2.3E-04 4.4E-11
MCHA 0.15 58.3 706 10 368 0.31 8.6E-05 1.5E-10
LCLA 1.25 1.3 32.941 26 66.2 0.75 2.1E-04 2.3E-10
LCMA 1.4 6.7 158.82 20.1 162 0.57 1.6E-04 1.5E-09
LCHA 5.5 54.7 289.41 4.5 862 0.13 3.6E-05 1.8E-07
![Page 26: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/26.jpg)
26
Effectiveness Factor Plot
Flat Plate
Ref: W. O. Haag, R. M. Lago, and P. B. Weisz, Trans. Faraday Soc. Pp 317-330 (1981)
![Page 27: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/27.jpg)
27
R(k)1/2
, C
ryst
al E
ffect
iven
ess
Fact
or
Effectiveness Factor Plot : DEB Production over ZSM-5 via Transalkylation
0.1
1.0
1 10 100 1000
0.2
0.3
0.4
0.5
0.7
T = 350oC
![Page 28: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/28.jpg)
28
Transalkylation of EB and Xylene to DMEB
Crystal R,m
Activity,kH
kDMEB obs
hr-1
Selectiv.kDMEBobs
kH
R(kDMEBobs)1/2 kintrins R2 kintrins
cm2/sec
SCLA 0.025 1.5 6 4.0 0.06 1.00 1.7E-04 1.0E-15
SCMA 0.02 13.3 53.2 4.0 0.15 1.00 1.5E-03 5.9E-15
SCHA 0.08 70 72.2 1.3 5.20 0.32 4.5E-01 2.9E-11
MCLA 0.12 1 3.8 3.8 0.23 0.95 1.1E-04 1.6E-14
MCMA 0.15 17.5 60.0 3.4 1.16 0.86 1.9E-03 4.4E-13
MCHA 0.15 58.3 57.1 0.9 10.20 0.22 5.7E-01 1.3E-10
LCLA 1.25 1.3 3.3 2.5 2.27 0.63 1.4E-04 2.3E-12
LCMA 1.4 6.7 8.2 1.2 2.90 0.59 3.8E-03 7.5E-11
LCHA 5.5 54.7 8.9 0.16 29.59 0.04 1.6E-02 4.9E-09
![Page 29: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/29.jpg)
29
R(k)1/2
Effectiveness Factor Plot : DMEB Production over ZSM-5 via Transalkylation
T = 350oC
0.01
0.10
1.00
0.01 0.10 1.00 10.00 100.00
, C
ryst
al E
ffect
iven
ess
Fact
or
![Page 30: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/30.jpg)
30
Effectiveness Factor Plot : vs R(k)1/2
for DEB and DMEB
R(k)1/2
=
tanh
Dimethylethyl
benzene (DMEB)
Diethylbenzene (DEB)
0.01
0.10
1.00
0.01 0.10 1.00 10.00 100.00 1000.00
T = 350oC
![Page 31: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/31.jpg)
31
Determination of DiffusionCoefficient, D for DEB and DMEB
Since, = tanh and R(k/D)1/2
If we know and R and k,
then we can calculate D for Diethylbenzene (DEB) production at T = 350oC
For large values of = 1 then
For = 0.31; R2kintrins = 1.5x10-10 cm2/sec; kintrins = 8.6x10-5/sec,
DDEB = 1.5 x 10-11 cm2/sec
Similarly,
DDMEB = 1.0 x 10-11 cm2/sec
![Page 32: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/32.jpg)
32
Aromatics Diffusion in ZSM-5Comparison with Other Studies
1.0E-12
1.0E-11
1.0E-10
1.0E-09
1.0E-08
1.0E-07
1.0E-06
250 300 350 400 450 500 550 600 650
Temperature, oK
Diff
usio
n C
oeffi
cien
t, cm
2 /sec Para-Xylene
Ortho-XylenePara-Ethyltoluene2,Methyl NaphthaleneDimethylethylbenzene (this study)Diethylbenzene (this study)
Refs: S. F. Garcia and P. B. Weisz, J. Catal. 121, 294 (1990);S. F. Garcia and P. B. Weisz, J. Catal. 142, 692 (1993) and others
![Page 33: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/33.jpg)
33
Impact of Temperature on DEB and DMEB Diffusion Coefficients in ZSM-5
Diffusion Coefficient, cm2/sec350oC 370oC 390oC
DDEB 1.5 x 10-11 2.1 x 10-11 2.4 x 10-11
DDMEB 1.0 x 10-11 1.3 x 10-11 1.6 x 10-11
• Temperature has small effect on the Diffusion Coefficients of DEB and DMEB in ZSM-5
• Ea – activation energy of intracrystalline Diffusion Coefficients, for bothDEB and DMEB are less than 1.0 kcal/mole – consistent with other studiesby Weisz et al.
![Page 34: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/34.jpg)
34
Conclusions
• We have evaluated the kinetics and diffusion characteristics associated with the formation of C10 aromatics in the isomerization of mixed ethylbenzene and xylene feeds (EB:Xylene) over ZSM-5 catalysts of differing crystal sizes and activities (’s)
• The formation of diethylbenzene (DEB) and dimethylethylbenzene (DMEB) are controlled by intracrystalline diffusion rather than transition state (spatio-) selectivity in the ZSM-5 channels and channel intersections
• The intracrystalline diffusivity of DMEB is approximately 66% of that of DEB
• Intracrystalline diffusivities for both DEB and DMEB are vritually independent of temperature
• The classical Thiele Modulus – Effectiveness Factor analysis is applicable to diffusion of alkylated aromatics in ZSM-5
![Page 35: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/35.jpg)
35
Back-up
![Page 36: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/36.jpg)
36
Ethylbenzene (EB) Conversion is First Order in ZSM-5 Isomerization
0.60 0.05 0.1 0.15 0.2
0.7
0.8
0.9
1.0
1/ WHSV
Frac
tion
of E
thyl
benz
ene
(EB
) Rem
aini
ng
![Page 37: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/37.jpg)
37
Para-Xylene Can be Produced Via Equilibrium or Selective Processes
+2
+2
Xylene Isomerization Toluene Disproportionation
XylenesAt
Equilibrium
SelectiveProcesses
EquilibriumProcesses
Transalkylation
Selective TolueneDisproportionation
22% Ortho- 54% Meta- 24% Para-
Para- >> 24%
Para- ~ 24%
Para- ~ 24%
All ProcessesRequire
Separation
+ 2
![Page 38: Isomerization of Mixed Xylene – Ethylbenzene Feeds over ... · PDF fileCumene Phenol, Bisphenol-A, ... Xylene Isomerization Process p-Xylene recovery Unit C 9+ Aromatics Make-up](https://reader033.vdocuments.us/reader033/viewer/2022051203/5a9e86a27f8b9a0d158b725c/html5/thumbnails/38.jpg)
38
The Role of Shape Selective Zeolites in C8 Aromatic Reactions
Reactant Selectivity (Hydrodealkylation)
Product or Isomer Selectivity (Selective Toluene Disproportionation)
+ H 2 +
+2
Ref: S. Csicsery, J Catal 23, 124 (1971)
5.8 Å6.8 Å 6.8 Å
Metal
Transition State (or Spatio-) Selectivity (C8 – C10 Aromatics Disproportionation)
+very low
yields+ +Bulky