ions in aqueous solutions and colligative properties
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Ions in Aqueous Solutions and Colligative Properties. Chapter 14. Dissociation. The separation of ions that occurs when an ionic compound dissolves. Dissociation examples. You try. - PowerPoint PPT PresentationTRANSCRIPT
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Ions in Aqueous Solutions and Colligative Properties
Chapter 14
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Dissociation
• The separation of ions that occurs when an ionic compound dissolves.
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Dissociation examples
ClNaNaCl
ClCaCaCl 222
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You try
• Write the equation for the dissolution of NH4NO3 in water. If 1 mol of ammonium nitrate is dissolved, how many moles of each type of ion are produced?
• 1 mol of each type of ion
3434 NONHNONH
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Precipitation Reactions
• When two solutions are mixed, a double replacement reaction may occur.
• If one of the products is insoluble, it will form a precipitate.
• See table 14-1 on page 427
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Example
• Solutions of (NH4)2S and Cd(NO3)2 are mixed. Will a precipitate form?
2424 2)( SNHSNH
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23 2)( NOCdNOCd
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Example continued
CdSNONHNOCdSNH 342324 2)(
)()(2
)()()(
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2324
sCdSaqNONH
aqNOCdaqSNH
The cadmium sulfide is the precipitate.
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Net Ionic Equations
• Includes only those compounds and ions that undergo a chemical change in a reaction in an aqueous solution.
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Spectator Ions
• Ions that do not take part in a chemical reaction and are found in solution both before and after the reaction.
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Example
)(2)(2)(
)()(2)(2)(
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243
2
aqNHaqNOsCdS
aqSaqNHaqNOaqCd
)()()( 22 sCdSaqSaqCd
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You try
• A solution of sodium sulfide is combined with a solution of iron(II) nitrate. Does a precipitate form?
• Iron(II) sulfide is the precipitate.
)()(2
)()()(
3
232
sFeSaqNaNO
aqNOFeaqSNa
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You try continued
• Write the net ionic equation for the previous reaction.
)()(2)(2
)(2)()()(2
3
322
sFeSaqNOaqNa
aqNOaqFeaqSaqNa
)()()( 22 sFeSaqFeaqS
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Ionization
• The process that forms ions from solute molecules by the action of the solvent.
• The attraction between the solvent and the solute is strong enough to break the covalent bonds.
)()( aqClaqHHCl
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Hydronium
• H3O+
• Formed when an H+ ion is combined with a water molecule (hydrated).
• Happens instantly when H+ ions are in water.
• Highly exothermic• Formed by many molecular compounds that
ionize
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A more accurate picture
)()( aqClaqHHCl
)()()()( 32 aqClaqOHgHCllOH
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Strong electrolytes
• Any compound whose dilute aqueous solutions conduct electricity well.
• All or almost all dissolved compound is in the form of ions– Not all compound has to dissolve, but the part
that does must be ions
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Weak electrolytes
• Any compound whose dilute aqueous solutions conduct electricity poorly.
• A small amount of the dissolved compound is in the form of ions.
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Be careful!
• Strong electrolytes have a high degree of ionization or dissociation, regardless of their concentration.
• Weak electrolytes have a low degree of ionization or dissociation, regardless of their concentration.
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Colligative Properties
• Properties of solutions that depend on the concentration of solute particles, but not the identity of solute particles.
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Nonvolatile substance
• Has little tendency to become a gas under existing conditions.
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Vapor-pressure lowering
• The vapor pressure of a solvent containing a nonvolatile solute is lower than the vapor pressure of the pure solvent at the same temperature.
• The solute lowers the concentration of solvent molecules at the surface.
• Fewer molecules enter the vapor phase.
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Effects
• See figure 14-6 on page 436
• The solution remains liquid over a wider temperature range.
• The freezing point is lowered and the boiling point is raised.
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Molal freezing-point constant
• Kf
• The freezing point depression of the solvent in a 1-molal solution of a nonvolatile, nonelectrolyte solute.
• = -1.86 °C/m for water
• 2 molal decreases 3.72 °C
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Freezing-point depression
• The difference between the freezing points of the pure solvent and a solution of a nonelectrolyte in that solvent.
• It is directly proportional to the molal concentration of the solution.
mKt ff
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Example
• Determine the freezing point of a water solution of fructose, C6H12O6 made by dissolving 58.0 g of fructose in 185 g of water.
• -3.24 °C
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You try
• Determine the molal concentration of a solution of ethylene glycol, HOCH2CH2OH, if the solution’s freezing point is -6.40 °C.
• 3.44 m
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Molal boiling-point constant
• The boiling-point elevation of the solvent in a 1-molal solution of a nonvolatile, nonelectrolyte solute.
• Kb = 0.51 °C/m for water
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Boiling-point elevation
• The difference between the boiling points of the pure solvent and a nonelectrolyte solution of that solvent.
• Directly proportional to the molal concentration of the solution
mKt bb
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Example
• What is the boiling point of a solution of 25.0 g of 2-butoxyethanol, HOCH2CH2OC4H9, in 68.7 g of ether?
• 40.8 °C
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You try
• What mass of glycerol, CH2OHCHOHCH2OH, must be dissolved in 1.00 kg of water in order to have a boiling point of 104.5 °C?
• 810 g
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Semipermeable membrane
• Allows the movement of some particles while blocking the movement of others.
• Example: allows water molecules through, but not sucrose molecules
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Osmosis
• The movement of solvent through a semipermeable membrane from the side of lower solute concentration to the side of higher solute concentration.
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Osmotic pressure
• The external pressure that must be applied to stop osmosis.
• The greater the concentration of a solution, the greater the osmotic pressure.
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Electrolytes
• 1 mole of an electrolyte produces more than one mole of particles in solution.– The ions separate
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Example
• A water solution contains 42.9 g of calcium nitrate dissolved in 500. g of water. Calculate the freezing point of the solution.
• -2.92 °C
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You try
• What is the expected boiling point of a 1.70 m solution of sodium sulfate in water?
• 102.6 °C
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Actual values
• Our expected values are not always what is observed.
• See table 14-3 on page 445
• Differences are caused by attractive forces between ions in solution.