ion formation an atom there are the same number of protons and electrons it is electrically neutral
TRANSCRIPT
ION FORMATIONION FORMATION
an atom there are the same an atom there are the same number of protons and electronsnumber of protons and electrons
it is electrically neutral.it is electrically neutral.
ION FORMATIONION FORMATION
An ion is an atom that has lost or An ion is an atom that has lost or gained electrons and now has an gained electrons and now has an electric chargeelectric charge
ION FORMATIONION FORMATION
The net charge of an ion that has The net charge of an ion that has lost or gained electrons is shown lost or gained electrons is shown as a superscript to the right of the as a superscript to the right of the atomic symbolatomic symbol
It is also called the oxidation It is also called the oxidation numbernumber
ION FORMATIONION FORMATION
Na = Na+1
Bi = Bi-3
Bismuth will gain 3 electrons and have a negative 3 charge
Sodium will lose its electron and become positively charged
Oxidation number
ION FORMATIONION FORMATION
The number of electrons that an The number of electrons that an atom will gain or lose depends on atom will gain or lose depends on its position on the periodic table its position on the periodic table (group number)(group number)
Na =
Ca+ionCa+ion
An atom that has lost electrons and An atom that has lost electrons and now has a net positively chargednow has a net positively charged
Na+1
Sodium will lose its electron and become positively charged
AnionAnion
An atom that has gained an An atom that has gained an electron and now has a net electron and now has a net negative chargenegative charge
Bi = Bi -3
Bismuth will gain 3 electrons and have a negative 3 charge
ION FORMATIONION FORMATION
Metals, elements to the left of the Metals, elements to the left of the staircase, will form cations (+ staircase, will form cations (+ charge)charge)
Nonmetals, elements to the right of Nonmetals, elements to the right of the staircase will form anions (- the staircase will form anions (- negative)negative)
ION FORMATION ION FORMATION group “B” elementsgroup “B” elements
The oxidation numbers of the “B” The oxidation numbers of the “B” group elements are variable. group elements are variable.
They do not follow a pattern like They do not follow a pattern like the Group “A” elements.the Group “A” elements.
ION FORMATION ION FORMATION group “B” elementsgroup “B” elements
Oxidation numbers will be given to Oxidation numbers will be given to you as a Roman Numeral in you as a Roman Numeral in parentheses following the name parentheses following the name of the element.of the element.
Practice1. Write the ion formed by these
element.a. iodine I-1 d. cobalt (II) Co+2
b. potassium K+1 e. gallium Ga+3
c. sulfur S-2 f. chromium (III) Cr+3
ION FORMATION ION FORMATION group “B” elementsgroup “B” elements
ION FORMATION ION FORMATION group “B” elementsgroup “B” elements
Writing Ions Writing Ions PracticePractice
IONION OxidationOxidationCationCation
NumberNumber or Anion or Anion
BromineBromine 11 AnionAnion
RubidiumRubidium 11 CationCation
BariumBarium 22 CationCation
SulfurSulfur 22 AnionAnion
Tin (IV)Tin (IV) 44 CationCation
IodineIodine 11 AnionAnion
ArgonArgon 00 NeitherNeither
AluminumAluminum 33 CationCation
MagnesiumMagnesium 22 CationCation
IONION OxidationOxidationCationCation
NumberNumber or Anion or Anion
StrontiumStrontium 22 AnionAnion
Lead (II)Lead (II) 22CationCation
Antimony (V)Antimony (V) 55CationCation
PhosphorusPhosphorus 33 AnionAnion
Copper (I)Copper (I) 11 CationCation
SeleniumSelenium 22 AnionAnion
BONDINGBONDING
Remember that a compound Remember that a compound consist of two or more elements consist of two or more elements chemically combined togetherchemically combined together
HH22O, NaCl, SbO, NaCl, Sb33(PO(PO44))55
BONDINGBONDING
The smallest unit of a compound is The smallest unit of a compound is a moleculea molecule
Only electrons move during bondingOnly electrons move during bonding
It is the movement of valence It is the movement of valence electrons that determines how electrons that determines how one atom will bond with anotherone atom will bond with another
BONDINGBONDING
Octet Rule- all atoms need 8 Octet Rule- all atoms need 8 valence electrons to be stablevalence electrons to be stable
BONDING, FOUR TYPESBONDING, FOUR TYPES
IONIC- Transfer of electronsIONIC- Transfer of electrons
COVALENT- sharing of electronsCOVALENT- sharing of electrons
POLAR COVALENT- uneven sharing of electronsPOLAR COVALENT- uneven sharing of electrons
METALLIC- bonds between cations and free METALLIC- bonds between cations and free electronselectrons
IONIC BONDSIONIC BONDS
Electrons are transferred from one Electrons are transferred from one atom to anotheratom to another
This creates a Cation (+) and anThis creates a Cation (+) and an
Anion (-)Anion (-)
Opposite charges attract Opposite charges attract
IONIC BONDINGIONIC BONDING
Cl
Cl
-1
Na
Na+1
Cl-1
Na+1
The Cation (Na) is attracted to the Anion (Cl)
IONIC BONDINGIONIC BONDING
Ionic Bonds are the strongest bondsIonic Bonds are the strongest bonds
Form between Metals and Non-Form between Metals and Non-MetalsMetals
BONDINGBONDINGThe stair case separates Metals (Left) from Non-Metals (Right)
IONIC BONDINGIONIC BONDINGLewis DotLewis Dot
Cl
Cl
-1
Na
Na+1
BONDINGBONDINGEnergy LevelsEnergy Levels
Na
Na
Cl
Cl
+1-1
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Ion- an atom that has lost or gained Ion- an atom that has lost or gained electronselectrons
Cation- Lost electrons positive Cation- Lost electrons positive chargecharge
Anion- Gained electrons negative Anion- Gained electrons negative chargecharge
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Oxidation number- indicates the Oxidation number- indicates the number of electrons lost or number of electrons lost or gained during bondinggained during bonding
To be stable- oxidation number To be stable- oxidation number must be zero (no charge)must be zero (no charge)
Binary Compound– formed between Binary Compound– formed between metal and non-metalmetal and non-metal
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
1.1. Write the ion of the Cation – MgWrite the ion of the Cation – Mg+2+2
2.2. Write the ion of the Anion – OWrite the ion of the Anion – O-2-2
3.3. Write the subscripts (bottom Write the subscripts (bottom numbers) to indicate how many numbers) to indicate how many ions of each element is needed ions of each element is needed to make the sum of the oxidation to make the sum of the oxidation numbers zero (do not write 1’s)numbers zero (do not write 1’s)
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Magnesium (Mg)Magnesium (Mg)
Group IIGroup II
Loses two Loses two electronselectrons
MgMg+2+2
Oxygen (O)Oxygen (O)
Group VIGroup VI
Gains two Gains two electronselectrons
OO-2-2
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
MgMg+2 +2 + O + O -2 -2 = net charge of 0 = net charge of 0
Formula = MgOFormula = MgO
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Magnesium (Mg)Magnesium (Mg)
Group IIGroup II
Loses two Loses two electronselectrons
MgMg+2+2
Bromine (Br)Bromine (Br)
Group IIVGroup IIV
Gains one Gains one electronselectrons
Br Br -1-1
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
MgMg+2 +2 + Br + Br -1 -1 = net charge of +1 = net charge of +1We need 2 Br We need 2 Br -1 -1 ions to even out the ions to even out the
chargecharge
MgMg+2 +2 + Br + Br22 -1 -1 = net charge of 0 = net charge of 0(Mg(Mg+2 +2 + Br + Br -1 -1 + Br + Br -1-1 = net charge of 0) = net charge of 0)
Formula = MgBrFormula = MgBr22
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Sodium (Na)Sodium (Na)
Group IGroup I
Loses one Loses one electronselectrons
NaNa+1+1
Oxygen (O)Oxygen (O)
Group VIGroup VI
Gains two Gains two electronselectrons
O O -2-2
Combine Sodium and Oxygen
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
NaNa+1 +1 + O + O -2 -2 = net charge of -1 = net charge of -1We need 2 Na We need 2 Na +1 +1 ions to even out the ions to even out the
chargecharge
NaNa22+2 +2 + O + O -2 -2 = net charge of 0 = net charge of 0(Na(Na+1 +1 + Na+ Na+1 +1 + O + O -2-2 = net charge of 0) = net charge of 0)
Formula = NaFormula = Na22OO
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Calcium (Ca)Calcium (Ca)
Group IIGroup II
Loses two Loses two electronselectrons
CaCa+2+2
Fluorine (F)Fluorine (F)
Group VIIGroup VII
Gains one Gains one electronselectrons
F F -1-1
Combine Calcium and Fluorine
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
CaCa+2 +2 + F + F -1 -1 = net charge of +1 = net charge of +1We need 2 F We need 2 F -1 -1 ions to even out the ions to even out the
chargecharge
CaCa+2 +2 + F + F22 -1 -1 = net charge of 0 = net charge of 0(Ca(Ca+2 +2 + F+ F-1 -1 + F + F -1-1 = net charge of 0) = net charge of 0)
Formula = CaFFormula = CaF22
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Iron (II) (Fe II)Iron (II) (Fe II)
Fe Fe (II)(II)
Loses two Loses two electronselectrons
FeFe+2+2
Sulfur (S)Sulfur (S)
Group VIGroup VI
Gains two Gains two electronselectrons
S S -2-2
Combine Iron (II) and Sulfur
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
FeFe+2 +2 + S + S -2 -2 = net charge of 0 = net charge of 0
Formula = FeSFormula = FeS
Writing Formulas for Writing Formulas for Ionic Compounds: Ionic Compounds: CrisscrossCrisscrossA SHORTCUT to figure out then A SHORTCUT to figure out then
number of each ion needed to number of each ion needed to form a neutral compoundform a neutral compound
Writing Formulas for Writing Formulas for Ionic Compounds: Ionic Compounds: CrisscrossCrisscross1.1. Write each Cation first followed Write each Cation first followed
by the Anionby the Anion2.2. Cross the oxidation numbers Cross the oxidation numbers
(superscript) to be the subscript (superscript) to be the subscript of the other of the other
3.3. Reduce the subscripts if they Reduce the subscripts if they aren’t alreadyaren’t already
Writing Formulas for Writing Formulas for Ionic Compounds: Ionic Compounds: CrisscrossCrisscrossMagnesium (Mg)Magnesium (Mg)
Group IIGroup II
Loses two Loses two electronselectrons
MgMg+2+2
Bromine (Br)Bromine (Br)
Group IIVGroup IIV
Gains one Gains one electronselectrons
Br Br -1-1
Writing Formulas for Writing Formulas for Ionic Compounds: Ionic Compounds: CrisscrossCrisscross
MgMg+2 +2 Br Br -1-1
MgMg 11 Br Br22
Formula = MgBrFormula = MgBr22
Writing Formulas for Writing Formulas for Ionic Compounds: Ionic Compounds: CrisscrossCrisscrossMagnesium (Mg)Magnesium (Mg)
Group IIGroup II
Loses two Loses two electronselectrons
MgMg+2+2
Oxygen (O)Oxygen (O)
Group VIGroup VI
Gains two Gains two electronselectrons
OO-2-2
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
MgMg+2 +2 + O + O -2-2
MgMg+2+2 + O + O-2-2
Formula = MgFormula = Mg22 O O22
(REDUCE) (REDUCE)
=MgO
Writing Formulas for Writing Formulas for Ionic Compounds: Ionic Compounds: CrisscrossCrisscross
Sodium (Na)Sodium (Na)
Group IGroup I
Loses one electronLoses one electron
NaNa+1+1
Oxygen (O)Oxygen (O)
Group VIGroup VI
Gains two Gains two electronselectrons
O O -2-2
Combine Sodium and Oxygen
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
NaNa+1 +1 + O + O -2 -2
NaNa22 + O + O11
Formula = NaFormula = Na22OO
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
Iron (II) (Fe II)Iron (II) (Fe II)
Fe Fe (II)(II)
Loses two Loses two electronselectrons
FeFe+2+2
Sulfur (S)Sulfur (S)
Group VIGroup VI
Gains two Gains two electronselectrons
S S -2-2
Combine Iron (II) and Sulfur
Writing Formulas for Writing Formulas for Ionic CompoundsIonic Compounds
FeFe+2 +2 + S + S -2-2
FeFe2 2 + S + S22
FeFe22SS2 2
REDUCE to REDUCE to FeSFeS
Naming Ionic Naming Ionic CompoundsCompounds
1.1. Write the name of the cation Write the name of the cation firstfirst
Naming Ionic Naming Ionic CompoundsCompounds
2. If the cation is a transition metal 2. If the cation is a transition metal add a Roman Numeral in add a Roman Numeral in parentheses to indicate parentheses to indicate oxidation number oxidation number
a)a) Use crisscross method in reverseUse crisscross method in reverse
FeS = FeFeS = Fe+1+1 S S-1 -1
Naming Ionic Naming Ionic CompoundsCompoundsb) Check negative ion to see if it b) Check negative ion to see if it
has correct oxidation number; has correct oxidation number; multiply the charges by the multiply the charges by the correct number till it doescorrect number till it does
FeS = FeFeS = Fe+1+1 SS-1-1 should be Sshould be S-2-2
2 x (Fe2 x (Fe+1+1 S S-1-1 ) = Fe ) = Fe+2+2 S S+2+2
Naming Ionic Naming Ionic CompoundsCompoundsc) Remember the Roman numeral c) Remember the Roman numeral
only goes in the name, not the only goes in the name, not the formula formula
(TRANSITON METAL ONLY)(TRANSITON METAL ONLY)
FeS = FeFeS = Fe+2+2 S S+2+2
Naming Ionic Naming Ionic CompoundsCompounds
3.3. Write the name of the anionWrite the name of the anion
Take the root word of the element Take the root word of the element name and end it with –idename and end it with –ide
FeS = Iron (II) sulfideFeS = Iron (II) sulfide
Naming Ionic Naming Ionic CompoundsCompounds
NaFNaF
1.1. SodiumSodium
2.2. Sodium is not a Sodium is not a transition metaltransition metal
3.3. FluorideFluoride
Sodium FluorideSodium Fluoride
MgOMgO
1.1. MagnesiumMagnesium
2.2. Magnesium is Magnesium is not a transition not a transition metalmetal
3.3. OxideOxide
Magnesium OxideMagnesium Oxide
Naming Ionic Naming Ionic CompoundsCompounds
CuClCuCl221.1. CopperCopper2.2. Copper is a transition metalCopper is a transition metal
a)a) CuCl CuCl2 2 = Cu= Cu+2 +2 ClCl-1-1
b)b) Cu Cu+2 +2 ClCl-1 -1 is correctis correctc) Copper (II)c) Copper (II)
3. Chloride3. Chloride
Copper (II) ChlorideCopper (II) Chloride
Naming Ionic Naming Ionic CompoundsCompounds
PbOPbO1.1. LeadLead2.2. Lead is a transition metalLead is a transition metal
a)a) PbO PbO = Pb= Pb+1 +1 OO-1-1
b)b) Pb Pb+1 +1 OO-1 -1 is not correctis not correct2(Pb2(Pb+1+1 OO-1-1) = Pb) = Pb+2+2 OO-2-2
c) Lead (II)c) Lead (II)
3. Oxide3. Oxide
Lead(II) OxideLead(II) Oxide
Naming Ionic Naming Ionic CompoundsCompounds
ZnSZnS ZincZinc Zinc is a transition metalZinc is a transition metal
a)a) ZnS ZnS = Zn= Zn+1 +1 SS-1-1
b)b) Zn Zn+1 +1 SS-1 -1 is not correctis not correct2(Zn2(Zn+1+1 SS-1-1) = Zn) = Zn+2+2 SS-2-2
c) Zinc (II)c) Zinc (II)
3. Sulfide3. Sulfide
Zinc (II) sulfideZinc (II) sulfide
Naming Ionic Naming Ionic CompoundsCompounds
KK33NN PotassiumPotassium Potassium is not a transition metalPotassium is not a transition metal
3. Nitride3. Nitride
Potassium NitridePotassium Nitride
Naming Ionic Naming Ionic CompoundsCompounds
BaOBaO BarriumBarrium Barrium is not a transition metalBarrium is not a transition metal
3. Oxide3. Oxide
Barrium OxideBarrium Oxide
Naming Ionic Naming Ionic CompoundsCompounds
CaOCaO CalciumCalcium Calcium is not a transition metalCalcium is not a transition metal
3. Oxide3. Oxide
Calcium OxideCalcium Oxide
Naming Ionic Naming Ionic CompoundsCompounds
AlFAlF33
AluminumAluminum Zinc is not a transition metalZinc is not a transition metal
3. Fluoride3. Fluoride
Aluminum FluorideAluminum Fluoride
Naming Ionic Naming Ionic CompoundsCompounds
CuICuI22 CopperCopper Copper is a transition metalCopper is a transition metal
a)a) CuS CuS2 2 = Cu= Cu+2 +2 II-1-1
b)b) Cu Cu+2 +2 I I-1 -1 is correctis correct
c) Copper (II)c) Copper (II)
3. Iodide3. Iodide
Copper (II) IodideCopper (II) Iodide
Naming Polyatomic Naming Polyatomic CompoundsCompoundsPolyatomic compounds have more Polyatomic compounds have more
than 2 different types of elements than 2 different types of elements in the formula Ex. Hin the formula Ex. H22SOSO44
NHNH44+1 +1 is the only Polyatomic ion that is is the only Polyatomic ion that is
a Cation a Cation
All others will come after the metal All others will come after the metal ionion
Name Formula
Ammonium NH41+
Acetate C2H3O21-
Chlorate ClO31-
Hydroxide OH1-
Nitrate NO31-
Carbonate CO32-
Sulfate SO42-
Sulfite SO32-
Phosphate PO43-
Nitrite NO21-
Chlorite ClO21-
Cyanide CN1-
Naming Polyatomic Naming Polyatomic CompoundsCompounds
Name a polyatomic compound just Name a polyatomic compound just like you would an ionic like you would an ionic compound but you do not compound but you do not change the ending of the change the ending of the Polyatomic ionPolyatomic ion
ZnSOZnSO4 4
From the ion chart SOFrom the ion chart SO4 4 is an polyatomic is an polyatomic ionion
1.1. ZincZinc2.2. Zinc is a transition metalZinc is a transition metal
a) Zn(SOa) Zn(SO44)) = Zn= Zn+1 +1 (SO(SO44) ) -1-1
b) Znb) Zn+1 +1 (SO(SO44)) -1 -1 is not correctis not correct
From the ion chart (SOFrom the ion chart (SO44)) -2-2
2(Zn2(Zn+1+1 SOSO44-1-1) = Zn) = Zn+2+2 SOSO44
-2-2
c) Zinc (II)c) Zinc (II)
3. Sulfate… From the chart3. Sulfate… From the chart
Zinc(II) sulfateZinc(II) sulfate
Naming Polyatomic Naming Polyatomic CompoundsCompounds
NaOHNaOH
From the ion chart OHFrom the ion chart OH is an is an polyatomic ionpolyatomic ion
1.1. SodiumSodium
2.2. Sodium is not a transition metalSodium is not a transition metal
3.3. 3. OH… Hydroxide… From the chart3. OH… Hydroxide… From the chart
Sodium HydroxideSodium Hydroxide
Naming Polyatomic Naming Polyatomic CompoundsCompounds
CaCOCaCO33
From the ion chart COFrom the ion chart CO3 3 is an is an polyatomic ionpolyatomic ion
1.1. CalciumCalcium
2.2. Calcium is not a transition metalCalcium is not a transition metal
3.3. 3. CO3. CO3 3 from the chart = Carbonatefrom the chart = Carbonate
Calcium CarbonateCalcium Carbonate
Naming Polyatomic Naming Polyatomic CompoundsCompounds
KCl0KCl022
From the ion chart ClOFrom the ion chart ClO2 2 is an is an polyatomic ionpolyatomic ion
1.1. PotassiumPotassium
2.2. Potassium is not a transition metalPotassium is not a transition metal
3.3. 3. ClO3. ClO2 2 from the chart = Chloratefrom the chart = Chlorate
Potassium ChloratePotassium Chlorate
Naming Polyatomic Naming Polyatomic CompoundsCompounds
Al(OH)Al(OH)33
From the ion chart OHFrom the ion chart OH is an is an polyatomic ionpolyatomic ion
1.1. AluminumAluminum
2.2. Aluminum is not a transition metalAluminum is not a transition metal
3.3. OHOH from the chart = Hydroxidefrom the chart = Hydroxide
Aluminum HydroxideAluminum Hydroxide
Naming Polyatomic Naming Polyatomic CompoundsCompounds
MgMg33(PO(PO44))22
From the ion chart POFrom the ion chart PO4 4 is an is an polyatomic ionpolyatomic ion
1.1. MagnesiumMagnesium
2.2. MAgnesium is not a transition metalMAgnesium is not a transition metal
3.3. 3. PO3. PO4 4 from the chart = Phosphatefrom the chart = Phosphate
Magnesium PhosphateMagnesium Phosphate
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic Ions Covalently-bonded groups of Covalently-bonded groups of
atoms that behave as a unit and atoms that behave as a unit and carry a chargecarry a charge
NONO33-1-1
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic Ions The Charge that is shown is for The Charge that is shown is for
the whole group not just the last the whole group not just the last atomatom
(NO(NO33))-1-1
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic Ions
Polyatomic ions have very specific Polyatomic ions have very specific names. (LIST ON YOUR NOTES)names. (LIST ON YOUR NOTES)
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic Ions1.1. To write the formula, use the criss To write the formula, use the criss
cross method for Polyatomic ions cross method for Polyatomic ions just like you did for regular ions. just like you did for regular ions.
2.2. Never change anything within the Never change anything within the polyatomic ionpolyatomic ion
3.3. Add subscripts outside Add subscripts outside parentheses parentheses
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic Ions
Magnesium PhosphateMagnesium Phosphate
Mg Mg +2+2 POPO4 4 -3-3
MgMg33(PO(PO44))22
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic IonsMagnesium CarbonateMagnesium Carbonate
Mg Mg +2+2 COCO33-2-2
MgMg22(CO(CO33))2 Reduce 2 Reduce
Mg(COMg(CO33))
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic Ions
Calcium HydroxideCalcium Hydroxide
Ca Ca +2+2 OHOH -1-1
Ca(OH)Ca(OH)22
Binary Compounds Binary Compounds with Polyatomic Ionswith Polyatomic Ions
Manganese(IV) SulfiteManganese(IV) Sulfite
Mn Mn +4+4 SOSO3 3 -2-2
MnMn22(SO(SO33))44
Covalent BondsCovalent Bonds
Electrons are shared between Electrons are shared between atoms but not transferredatoms but not transferred
Electrons are located in the Electrons are located in the outermost energy levels of both outermost energy levels of both atoms at the same timeatoms at the same time
Form between nonmetalsForm between nonmetals
Covalent BondsCovalent Bonds
NHNH33
Lewis Dot Lewis Dot
NN
H
HH
Covalent BondsCovalent Bonds
NHNH33
Energy Level Energy Level H
H
H
N
Covalent BondsCovalent BondsIonic vs. Covalent Properties
Covalent Bonds Ionic Bonds
type of elements
Nonmetals only Metals and Nonmetals
type of bonding share electrons transfer electrons
structure not rigid – solid, liquid or gas
crystalline
melting point low high
hardness soft hard very hard
conduct electricity?
no yes (when dissolved in water)
Covalent Bonds: Covalent Bonds: Diatomic AtomsDiatomic Atoms
There are 7 elements that can form There are 7 elements that can form covalent bonds between its atomscovalent bonds between its atoms
HydrogenHydrogen
Atoms Atoms Molecule Molecule H·H· ·H ·H H:H H:H
Covalent Bonds: Covalent Bonds: Diatomic AtomsDiatomic Atoms
NitrogenNitrogen
AtomsAtoms · ·· ·
: N · · N :: N · · N : · · · ·MoleculeMolecule Forms a triple bondForms a triple bond
: N : : : N :: N : : : N :
Covalent Bonds: Covalent Bonds: Diatomic AtomsDiatomic Atoms
·· ··O : : O ·· ··
·· ··: F : F :
·· ··
·· ··:Cl : Cl :
·· ··
·· ··
: Br : Br: ·· ··
·· ··: I : I :·· ··
OXYGEN(Double bond
between atoms)
FLOURINE CHLORINE BROMINE IODINE
Determine ionic or Determine ionic or covalent bondscovalent bondsNN22OO55
A liquid at toom A liquid at toom temptemp
PbNOPbNO33
Covalent Covalent (nonmetals)(nonmetals)
Covalent (liquid)Covalent (liquid)
Ionic (Metal with Ionic (Metal with nonmetal)nonmetal)
Determine ionic or Determine ionic or covalent bondscovalent bondsA salt that conducts A salt that conducts
electricity in electricity in solutionsolution
KFKF
AgClAgCl
Ionic (conducts Ionic (conducts electricity)electricity)
Ionic (metal with Ionic (metal with nonmetal)nonmetal)
Ionic (Metal with Ionic (Metal with nonmetal)nonmetal)
Determine ionic or Determine ionic or covalent bondscovalent bondsGasolineGasoline
PClPCl33
OO22
Covalent (liquid)Covalent (liquid)
Covalent (metal to Covalent (metal to metal)metal)
Covalent (share Covalent (share electrons)electrons)
Naming Covalent Naming Covalent CompoundsCompoundsOxidation numbers are not used in Oxidation numbers are not used in
determining the formula unitdetermining the formula unit
Two nonmetals can combine in more Two nonmetals can combine in more than 1 waythan 1 way
We use prefixes to name and We use prefixes to name and indicate the number of atoms of indicate the number of atoms of each type each type
Naming Covalent Naming Covalent CompoundsCompounds
Prefix Number
mono 1
di 2
tri 3
tetra 4
penta 5
hexa 6
hepta 7
octa 8
nona 9
deca 10
Naming Covalent Naming Covalent CompoundsCompounds
Write the name of the element that Write the name of the element that is farthest left first is farthest left first
Write the other element second Write the other element second and change the ending to –ideand change the ending to –ide
Add prefixes to the two elementsAdd prefixes to the two elementsDo not use mono on first elementDo not use mono on first element
Naming Covalent Naming Covalent CompoundsCompoundsCOCO22
Element to left first, then the second element with Element to left first, then the second element with an –ide endingan –ide ending
Carbon OxideCarbon OxideAdd prefixesAdd prefixes
Monocarbon DioxideMonocarbon Dioxide
Drop Mono from first elementDrop Mono from first element
Carbon dioxideCarbon dioxide
Naming Covalent Naming Covalent CompoundsCompoundsCFCF44
Element to left first, then the second element with an –ide Element to left first, then the second element with an –ide endingending
Carbon FlourideCarbon FlourideAdd prefixesAdd prefixes
Monocarbon Monocarbon TetraflourideTetraflouride
Drop Mono from first elementDrop Mono from first element
Carbon Carbon TetraflourideTetraflouride
Naming Covalent Naming Covalent CompoundsCompoundsSiClSiCl33Element to left first, then the second element Element to left first, then the second element
with an –ide endingwith an –ide ending
Silicone ChlorideSilicone ChlorideAdd prefixesAdd prefixes
Monosilicone Monosilicone trichloridetrichloride
Drop Mono from first elementDrop Mono from first element
Silicon TrichlorideSilicon Trichloride
Naming Covalent Naming Covalent CompoundsCompoundsCOCO22
Element to left first, then the second element with Element to left first, then the second element with an –ide endingan –ide ending
Carbon OxideCarbon OxideAdd prefixesAdd prefixes
Monocarbon DioxideMonocarbon Dioxide
Drop Mono from first elementDrop Mono from first element
Carbon dioxideCarbon dioxide
Naming Covalent Naming Covalent CompoundsCompoundsCOCO22
Element to left first, then the second element with Element to left first, then the second element with an –ide endingan –ide ending
Carbon OxideCarbon OxideAdd prefixesAdd prefixes
Monocarbon DioxideMonocarbon Dioxide
Drop Mono from first elementDrop Mono from first element
Carbon dioxideCarbon dioxide
Naming Covalent Naming Covalent CompoundsCompoundsHH22OOElement to left first, then the second element with an –Element to left first, then the second element with an –
ide endingide ending
Hydrogen OxideHydrogen OxideAdd prefixesAdd prefixes
Dihydrogen oxideDihydrogen oxide
Drop Mono from first elementDrop Mono from first element
Dihydrogen Dihydrogen oxideoxide
Naming Covalent Naming Covalent CompoundsCompounds
Common names to rememberCommon names to remember
HH22O = WaterO = Water
NHNH3 3 = Ammonia= Ammonia
CHCH4 4 = Methane= Methane
Writing Formulas for Writing Formulas for Binary Covalent Binary Covalent CompoundsCompoundsList the symbol of the first element List the symbol of the first element
in the name first and then second in the name first and then second element nextelement next
Use the subscripts to identify the Use the subscripts to identify the prefix in the name for that atomprefix in the name for that atom
Writing Formulas for Writing Formulas for Binary Covalent Binary Covalent CompoundsCompoundsCarbon TetrachlorideCarbon Tetrachloride
C ClC Cl
Tetra= 4Tetra= 4
CClCCl44
Writing Formulas for Writing Formulas for Binary Covalent Binary Covalent CompoundsCompoundsDinitrogen TrioxideDinitrogen Trioxide
NN OO
Di = 2Di = 2 Tri = 3Tri = 3
NN22OO33
Writing Formulas for Writing Formulas for Binary Covalent Binary Covalent CompoundsCompoundsIodine PentaflourideIodine Pentaflouride
I FI F
Penta = 5Penta = 5
IFIF55
Writing Formulas for Writing Formulas for Binary Covalent Binary Covalent CompoundsCompoundsHexaboron SilicideHexaboron Silicide
B SiB Si
Hexa = 6 Hexa = 6
BB66SiSi
Writing Formulas for Writing Formulas for Binary Covalent Binary Covalent CompoundsCompoundsDiantomny PentoxideDiantomny Pentoxide
Sb OSb O
Di = 2Di = 2 Penta = 5Penta = 5
SbSb22OO55
Writing Formulas for Writing Formulas for Binary Covalent Binary Covalent CompoundsCompoundsAmmoniaAmmonia
NHNH33
Polar Covalent BondsPolar Covalent Bonds
A type of covalent bond where electrons A type of covalent bond where electrons are shared unequally between atomsare shared unequally between atoms
Electrons spend more time with one atom Electrons spend more time with one atom than the otherthan the other
The stronger atom will be slightly The stronger atom will be slightly negative and the other will be slightly negative and the other will be slightly positivepositive
Polar covalent BondsPolar covalent Bonds
Water: the electrons hang around Water: the electrons hang around the oxygen atom more than the the oxygen atom more than the hydrogen atomhydrogen atom
Example of Polar Covalent Bond in Action
O
Polar Covalent BondPolar Covalent Bond
Water Water
Lewis Dot Lewis Dot
H H
Metallic BondsMetallic Bonds
Bonds between positive ions and Bonds between positive ions and free-roaming electronsfree-roaming electrons
These are flexible and are good These are flexible and are good conductors as solids (electrons conductors as solids (electrons are free to moveare free to move