ion exchange resins - · pdf file© 2007 rohm and haas company ier1 ion exchange resins...

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© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS z Boiler feed water z Drinking water: removal of contaminants z Radioactive waste cleaning z Ultra-pure water for semiconductors z Waste treatment: recovery of metals z Food and beverage processing z Pharmaceuticals

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Page 1: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER1

ION EXCHANGE RESINS

Boiler feed waterDrinking water: removal of contaminantsRadioactive waste cleaningUltra-pure water for semiconductorsWaste treatment: recovery of metalsFood and beverage processingPharmaceuticals

Page 2: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER2

Resins

Uniform particle sizeAmberjet™

Standard particle sizeAmberlite™

Various polymersStyrenicAcrylicPhenolic

Different matricesGel typeMacroporous

Amberjet 4400

Amberlite IRA67

Page 3: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER3

Applications

Water treatment

Special applications

Industrial water treatmentBoiler feed water Nuclear powerCondensateRadioactive wasteUltra-pure waterDrinking waterHousehold softeningWaste water

CatalystsSeparationsPurificationsNutritionPharmacyBiotechnologies

Page 4: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER4

Industrial water treatment

Softening

Demineralisation

Mixed bed polishing

ADI standard plant

Page 5: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER5

Demineralisation

Boiler feed water withAmberjet resins

Quality0.1 to 1 µS/cmbefore polishing0.055 to 0.1 µS/cmafter polishing

Page 6: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER6

Amberpack™

Reverse flow regenerationtechnology

Compact systemEasy regenerationVery little waste98 % water recovery99.95 % salt rejectionHundreds of plants in service

Page 7: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER7

Advanced Amberpack™

With fractal distributionADI 60: 60 m3/h demineralisationADN for nitrate removalCompact and modular

ADI 60

Page 8: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER8

Polishing

After RO

After primary demin

After flash evaporation

Condensate polishing

Mixed bed technologyAmberjet resins

Amberpack Sandwich™No mixing, no backwash

Freeboard Collector

Feedwater

Treated water

Resin 1

Resin 2

Amberpack Sandwich

Page 9: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER9

Demineralisation

Mixed bed for electro-erosion machinesSpecial resin for this application onlyReady for useAmberlite MB9L

Page 10: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER10

Power

Boiler make-up water

Condensate polishing

Primary circuit

Secondary circuit

Radioactive waste treatment

Fuel storage pond

Nuclear and fossil-fuelled stations (EdF etc.)

Page 11: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER11

Condensate polishing

Unique resin combination:Amberjet 1500 + Ambersep 900

StableClean High ammonia capacityExcellent separability

Page 12: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER12

Household softening

Large and small producers of softeners use

Amberlite SR1LNaImac™ HP1110Na

Approved by French Health Authorityand many other authorities

In Europe, all dishwashers are equipped with a small softener using a resin like

Amberlite IR120FF Na

Page 13: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER13

Drinking water

• Point of useA growing market withImac HP333

Hardness removal cartridgesImac HP555

Selective nitrate removal

Page 14: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER14

Drinking water

• MunicipalAmberlite PWA5

Nitrate removalAmberlite PWA10

Boron removalAmberlite PWA2

Perchlorate removal

Advanced Amberpack™ADN in the UK

Page 15: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER15

Desalination

Boron removal after ROAmberlite PWA10Totally selective resinRemoves B only0.1 mg/L residual B99% + water recovery

Boron removal in Kziot

Page 16: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER16

Ultra-pure water

Amberjet UP and Amberlite UPdeveloped specifically for the semiconductor industry

Minor impurities in the water used for the production of wafers can create short-circuits and make the product unusable

Amberjet UP6040used in the final mixed bed polisher

It brings the last impurities down to ng/L (ppt) levels.

Page 17: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER17

Waste water solutions

Soil reclamationHeavy metals removal (Hg, Cd)

Ambersep GT74Amberlite IRC748

Removal of phenolAmberlite XAD4

Ammonium nitrate recoveryFertilizer plants

Page 18: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER18

Catalysis using ion exchange resins

Amberlyst 31, 131 & 121main catalysts used for Bisphenol A, one of the components of polycarbonate and epoxy resins.

Amberlyst 15Dry & 36DryFor the production of alkylphenols used in detergent formulations

Amberlyst 35catalyst used in the synthesis of octane improvers (petrol additives) such as MTBE, ETBE, TAME & iso-octane

Page 19: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER19

Chemical separations

Uranium miningAmberjet™ 4400 & Ambersep™ 920U

Soil reclamationHeavy metals removal (Hg, Cd)

Ambersep GT74Amberlite IRC748

Removal of phenolAmberlite XAD4

Ammonium nitrate recoveryFertilizer plants

PurificationsPhenolGlycolFormaldehyde

Page 20: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER20

Chemical separations (2)

Boron removalFrom magnesium brine

Amberlite IRA743

Calcium removal from brineChlor-alkali industry

Amberlite IRC747

Biodiesel purificationRemoval of potassium and sodium

Amberlite BD10Dry

Page 21: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER21

Metals

Many applicationsRinse water from plating bathsRecovery of metal catalystsChromic acid recyclingPickling baths recyclingRemoval of iron from chromic acidMetal catalyst recovery in plastics productionRecovery of gold from plating solutionsRecovery of silver

Page 22: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER22

Sugar & sweeteners

Calcium removal from beet juiceAmberlite FPC14 Na

De-ashing of liquid sugarAmberlite FPC22 H and FPA53

Colour removal from cane juiceAmberlite FPA98 Cl and FPA90 Cl

Purification of sweetenersGlucose, fructose, maltosePolyols

Chromatographic separationsAmberlite CR1310 & CR1320

High fructose syrup

Page 23: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER23

Beverages

Orange juice debitteringAmberlite FPX66

Water for breweriesDe-alkalisation, partial deionisation

Amberlite PWC13

Water for soft drinksRemoval of colour and natural organics

Amberlite PWA9

Page 24: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER24

Pharmaceutical applications

Resins as active ingredientsDuolite AP143 = cholestyramine

Blood cholesterol control

Amberlite IRP69 = sodium polystyrene sulphonate

Reduces blood potassium level

Resins as drug excipientsART (advanced release technologies)

A series of technologies and products– Tablet disintegrants– Taste-masking– Slow release

Amberlite IRP64Taste maskingControlled release of drugsNicotine loaded chewing gums

Page 25: ION EXCHANGE RESINS -  · PDF file© 2007 Rohm and Haas Company IER1 ION EXCHANGE RESINS zBoiler feed water zDrinking water: removal of contaminants zRadioactive

© 2007 Rohm and Haas Company IER25

Biotechnologies

Amberlite CobalamionPurification of Vitamin B 12 from fermentation broths

Amberlite XAD1600Non-ionic adsorbentSeparation of two or more similar species Production & purification of antibiotics

Amberzyme™ OxiraneEnzyme immobilisation

Amberchrom™ CG & XTAdsorptionReversed phase liquid chromatography Purification of proteins and peptides