introduction of mcc’s durabio,（bpa） o o ch3 ch3 c o m bpa-pc isosorbide monomer durabiotm...

Introduction of MCC’s DURABIO, A Bio-based engineering Plastic.

Mitsubishi Chemical Corporation

What we are.

GROUP INFORMATION

2014.12.1

2014.12.1

4

100％

Qualicaps Co., Ltd..

Healthy Life Compass Corp.

LSI Medience Corporation

API Corporation

The KAITEKI Institute, Inc.

Mitsubishi Chemical Holdings Corporation* Consolidated net sales: ¥3,498.8 billion Employees：56,031 *** Oct. 2005~

Organization (At November,2014)

Performance Products

Health Care

Industrial Materials

*: Listed

Figures for consolidated net sales is for the year ended March 2014（FY2013).

**:Group total

Mitsubishi Chemical Holdings America, Inc.

Mitsubishi Chemical Holdings (Beijing) Co., Ltd.

Mitsubishi Chemical Holdings Europe GmbH

Mitsubishi Chemical Holdings Corporate Staff, Inc.

Nov. 2010~

Jan. 2011~

Nov. 2012~

Apr. 2013~

Mitsubishi Tanabe Pharma Corporation*

[ Line of businesses ]

Performance products

Industrial materials etc.


Pharmaceuticals etc.


Plastics products

Inorganic fiber materials

etc.

[ Line of businesses ] Chemicals & plastics

Fibers Carbon fiber

& composite materials Water treatment etc.

Consolidated net sales:

¥412.7 billion


¥606.2 billion


¥442.7 billion

Mitsubishi Chemical Corporation

Mitsubishi Plastics, Inc.

Oct. 2005~ Oct. 2007~ Apr. 2008~ Apr. 2010~

Mitsubishi Rayon Co., Ltd.

Apr. 2009~


¥2,159.7 billion

Life Science

Institute, Inc.

[ Line of businesses ] Health, Medical ICT drug discovery and

manufacturing suppor1t business

Advanced medication

100％

Apr. 2014~

MCHC R&D Synergy Center, Inc. Apr. 2014~


[ ¥110.5 billion]

100％ 56.3％ 100％ 100％ 50.6％**

Group companies Group companies Group companies Group companies

※Data for Life Science Institute, Inc. reflect

Change in segmentation


¥552.7 billion

Taiyo Nippon Sanso

Corporation*

Nov. 2014～

[ Line of businesses ] Industrial gases

and related. equipment and

Installations and others

***:68,986, including the employees of Taiyo Nippon Sanso

2014.12.1

5

Overview of Mitsubishi Chemical Holdings

Profile＊

Established

Head office**

President

Paid-in capital

Listings

Activities

Business domains

Consolidated net sales

Consolidated operating income

Group employees

Website

October 3, 2005

1-1, Marunouchi 1-Chome, Chiyoda-ku, Tokyo

Yoshimitsu Kobayashi

¥50.0 billion

Tokyo Stock Exchange

Management of the Group companies (development

of Group strategies, allocation of financial resources, etc.)

Performance products, health care, and industrial materials

¥3,498.8 billion

¥110.5 billion

56,031 (68,986,including the employees of Taiyo Nippon Sanso)

http://www.mitsubishichem-hd.co.jp/english/

Mitsubishi Chemical Holdings Corporation

Yoshimitsu Kobayashi, ph D

President &

Chief Executive Officer

*All figures are for the year ended March 2013（FY2012）.

The Mitsubishi Chemical Holdings Group is made up of about 760 companies: the holding company Mitsubishi Chemical Holdings, its about 500 consolidated subsidiaries including

Mitsubishi Chemical, Mitsubishi Tanabe Pharma, Mitsubishi Plastics, Mitsubishi Rayon,

and Life Science Institute,Taiyo Nippon Sanso and its about 80 equity-method affiliates.

Under our corporate brand “THE KAITEKI COMPANY,”

We promote corporate activities aiming to achieve KAITEKI.






2014.12.1

6

History

Oct.2005

Oct.2007 Apr.2008

Apr.2009 Mar.2010 Nov.2010 Jan.2011 Jun.2012 Nov.2012 Jan.2013 Mar.2013 Apr.2013

Apri.2014

Nov.2014

Mitsubishi Chemical Holdings jointly established by Mitsubishi Chemical and Mitsubishi Pharma by

means of a stock-for-stock exchange Mitsubishi Plastics becomes wholly owned subsidiary

Mitsubishi Tanabe Pharma formed from merger of Tanabe Seiyaku and Mitsubishi Pharma New Mitsubishi Plastics established to integrate functional product businesses The KAITEKI Institute established Mitsubishi Rayon becomes consolidated subsidiary Mitsubishi Chemical Holdings America, Inc. established Mitsubishi Chemical Holdings (Beijing) Co., Ltd. Established MCFA Inc. becomes wholly owned subsidiary Mitsubishi Chemical Holdings Europe GmbH established MHCS Corporation established Qualicaps Co., Inc. acquired and becomes consolidated subsidiary MCFA Inc. changes its name to Mitsubishi Chemical Holdings Corporate Staff Corporation

Healthy Life Compass Corporation established Life Science Institute, Inc. established to strengthen and expand healthcare-related businesses MCHC R&D Synergy Center, Inc. estabished to integrate and strengthen common basic

technology domains of research and development

TAIYO NIPPON SANSO acquired and becomes consolidated subsidiary

Our Proposal for Automotive Parts

DURABIO can be a solution

CURRENT DURABIO Conventional Material with Paint

DURABIO without Paint

Painting has problems like, ○Low Yield ratio of painting ○VOC problem from paint ○High cost of painting

DURABIO can offer ○Mold, just one process ○Higher quality than paint ○Low VOC, Lower cost

Paint-less Parts Samples

DURABIO

SUZUKI Hustler(2013/12～)

2013/6~

Exterior pats

SUZUKI

2014/12~

Hustler 2014/1~

MCC CONFIDENTIAL

OEM A OEM B

MAZDA MX-5 (2015/2~）

Without paint painted DURABIO

2014/10~

2014/8~

Exterior parts

Paint-less Parts Samples

2014/12/10 Mazda Develops Bio-based Engineering Plastic Featuring High-Quality Finish without Paint and Suitable for Exterior Vehicle Parts

News Release from MAZDA


CURRENT DURABIO PC plate between polarizer film

DURABIO plate between polarizer film

Plastics has problems like, ○Rainbow pattern on part ○Hard-coating needed ○Flat shape only

DURABIO can offer ○Clear appearance ○Mold, just one process ○3D shape available

Transparent Panel Samples

Optical and HC –less is the key words.


CURRENT DURABIO Common appearance interior, exterior part

Lighted parts, new concept

Just surface ○Just garnish, one function ○Many parts to illuminate ○High cost to illuminate

Surface, and illumination ○Garnish and Illumination ○Less parts to illuminate ○Lower cost to illuminate

Detail Information about DURABIO.

OHHO

CH3

CH3

O

O

OH

HO

O

O

O

O

C

O

m

Bisphenol-A （BPA）

OO

CH3

CH3

C

O m

BPA-PC

Isosorbide monomer

DURABIOTM

Phenol / Acetone

Oil

Sorbitol

Plant-derived Glucose

oxygen-containing Alicyclic

Polycarbonate Co-polymers

Aromatic Polycarbonate

Co-monomers

DURABIOTM is a transparent bio-based engineering plastic which shows high functionality and performance.

X

X n

Tra

nspare

nt

Poly

mers

Polyacrylates

Polycycloolefin

Engineering Plastics

Bio-based Polymers

PS/SAN

PMMA

PC

COP/COC

PLA

Polystylene

C

CH3

CH3

OO C

O n

Transparent

Mechanical/Thermal

Optical

Bio-based

O

O

O

O

C

O

m

X n

DURABIOTM

Positioning of DURABIOTM

Low Birefringence Excellent Transparency

Low Photoelastic coefficient Retardant Property

High Impact Resistance (Multi-axial Impact)

Heat Resistance

Bio-based Content Flame Retardance

Surface Hardness

Superior UV Resistance

PC

PMMA

DURABIOTM

DURABIOTM comparative

general properties


general properties




Heat Resistance


Surface Hardness


PC

PMMA

DURABIOTM

Puncture impact behavior

PC (1) D7340 (2) D5380

Puncture point energy

J 77 96 89

Puncture point Displacement

mm 14.2 18.7 22.0

brittle fracture rate % 0～20 0 0

Samples

Sample：100mm×100mm×2mmt Machine：high rate multi-axial Impact machine Test bar out inside diameter ：20mm Support frame inside diameter：40mm Test rate：4.4m/sec

PMMA

brittle fracture

ductile fracture

Impact Test for Noise Barrier


general properties




Heat Resistance


Surface Hardness


PC

PMMA

DURABIOTM

Surface Hardness (Pencil test)

0 5 10 15 20 25 30 35

Ductil

Punctur Impact

Brittle

Good

PC （2B)

DURABIOTM

（F)

PC/PMMA alloy

⊿Haze by Tabor Abrasion（50 cycle）

（）: Pencil Test

Surface Hardness (Tabor abrasion test)

Lexan-DMX （2H)

Compare to other transparent plastic

Transparent

application sample

Smart phone cover

Surface Hardness (Tabor abrasion test)

Compare to PC/ABS with paint

0

20

40

60

80

100

120

Original 25 50 75 100

Number of Revolutions

Glo

ss R

ete

ntion

Piano black color

application sample

Cell-phone body

Much better

than paint!


general properties




Heat Resistance


Surface Hardness


PC

PMMA

MCC CONFIDENTIAL

DURABIOTM

Yellowness Index

after UV Light Irradiation

0

10

20

30

40

50

Machine: 6-kW Metaling Weather Meter M6T Irradiance: 1.5 kW/m2, Condition: 63℃ x 50%RH

Yellow Index

Time Scale

PC

DURABIO shows excellent UV light resistance, that is non-yellowing, compared with PC.

DURABIOTM

MCC CONFIDENTIAL




Heat Resistance


Surface Hardness


PC

PMMA

DURABIOTM


general properties

Optical：Birefringence behavior




Heat Resistance


Surface Hardness


PC

PMMA

DURABIOTM


general properties

15mmt Plate Plastics/ Neat Resin After Flame Test （>1,000℃） 1minx1 & 30secx2

Incombustibility Test for Plastic Plate

DURABIO PC PC

DURABIO

PC

After Testing




Heat Resistance


Surface Hardness


PC

PMMA

DURABIOTM


general properties

HD

T (

0.45

MP

a) /℃

Bio-mass Ratio/%

50

100

50 100

150

25 75

Bio-mass ratio

DURABIOTM 4 preliminary grades

All Values are Guiding Values only. Data

for PC, PMMA, PS as unmodified standard polymers

DURABIOTM

PC PMMA

Property T.C. Unit D7340R D7340-

810R D5380R D5360R

Density g/cm³ 1.36 1.35 1.31 1.31 1.20 1.19

Light

transmission % 92 92 92 92 91 93

Refractive

index - 1.50 1.50 1.50 1.50 1.58 1.49

Flexural

modulus MPa 2700 2600 2200 2100 2300 3300

MFR 230℃

2.16kgf g/10min 11 11 6 14

Charpy impact strength

notch

u.n. kJ/ m2

7

N.B.

7

N.B.

10

N.B.

9

N.B.

76

N.B.

1

19

HDT 1.80MPa

0.45MPa ℃

102

114

100

110

82

92

81

91

129

143

87

－

Hardness Pencil

test - F F HB HB 3B 2H

Piano Black ONLY

DURABIOTM Potential market

To Create “the only one” market by DURABIOTM ’s unique characters

BIOMASS Keyword：Biomass

Optical character Keyword：Glass substitution

UV Resistance Keyword：no color change

Hardness Keyword：Paint-less

Impact Resistance character

Automobile interior parts, Mobile phone

Display

Exterior parts, construction

Polymer Alloy

LED lighting

Cosmetic containers E&E housings

FPD front panel

UV stability Biomass

Optical characteristics（Glass substitution）

DURABIOTM

applications

Optical film

Lighting sheet

Surface Hardness（Paint-less）

Interior parts for automobiles

Cell phone Sunglass

Film-laminated steel sheet

Noise barrier wall

Application Samples

MLIT* has set DURABIO noise barrier in Mie Pre. (Route477)

*Ministry of Land, infrastructure, transportation and tourism

Other Samples

300 t/Y Demonstration Plant for DurabioTM has started the operation in 2010．

5,000t/Y Commercial Plant has started in 2012 ( This plant easily capacity up to 16,000t/Y)

Production of DURABIOTM

Thank you for your attention

introduction of mcc’s durabio,（bpa） o o ch3 ch3 c o m bpa-pc isosorbide monomer durabiotm...

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