inorganic and hydrocarbon data for evacuable chamber (ec ...955 1015 1030 1045 1100 1115 ll 30 1145...
TRANSCRIPT
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APPENDIX D
Inorganic and Hydrocarbon Data for Evacuable Chamber (EC) Runs 360 through 387
269
-
EC -360 ALKANES, 1979 FEB
46 6
DEG f 16.0, 0.5J
BEGIN IRRADIATION 1015; 0.25 [NCH P\REX FILTER; TRICHROIC NOX INJECTED PRIOR TO PURE AIR FILL USING EC VACUUM RACK LESS THAN l PPB N-BUTYL NITRATE CETECTEO BRADY 292; DASIBI 1212; TECO 148-1 ~ TECO 148/E USED
FILTER our
T:O AT 1015 PST
PAN HCHO
RH INT
CALI B/1 12
3 4
SPECTRAL DISTRIBUTION WAVELENGTHINM) REL. INTEhSITY
N --.J 0
TS REL HUt-1 SSPO,IER RADIOM
H20 NO
N02-CORR N-Clt
NEO-C5 HCHO
ACETONE
DEG K i
KW MW/C M2
PPM PPM PPM PPM PPM PPM PPM
AVERAGE AVEil.AGE AVERAGE AVERAGE AVERAGE INIT COND rnn CGND IN[T COND INIT COND INIT COND INIT COND
2ac.1 50.90 15 ,95 0. 160 5.700E C.357 0.122 2.154 2.1:01 o.c22 o.co1
03*
500. 430. 403. 380. 370. 360. 350. 340. 330. 320. 310. 300. 290.
2.021 2.044 1.806 l. 59 3 l.413 l. l 7l 1.000 0.829 o.536 0.288 0.100 0.012 o.o
* ASSIGNED INITIAL CCNDITION Kl=0.39 MIN-1 SAMPLING RATE a 2,173 L/HIN
48 GC SAMPLES TAKEN
-
EC -360 ALKANES, 46 DEG F (6.0, 0.5l l 9 79 FEB 6
CLOCK TIME
ELAPSED TIH!Nl
OZONE PPM
NO PPH
NO PP/J
N02-CORR PPM
N02-COR~ PPM
NOX-CORR PPM
NOX-CORR PPM
N-C4 PPM
NEO-G5 PPM
955 -2 o. 0.000 I 148- l) 0.363
1148 /E J C. 3 E3
ll 411- ll o. 12 0
{141:l/E) 0. l 26
tl4B-1J 0.4tl2
tl4fl/EI o.5oa 2.83 2.82
l 0 l 5 o. 0.000 0.357 0.3€2 0.122 0.123 0.479 o.504 2.15 2.81 l0J0 15. 0.000 C.348 C.3t8 0.12s 0.134 0.413 0.501 •***** ****** 1045 3 o. 0.000 0.330 0.3:2 0.137 0.142 0. 1,61 0.492 2,46 2.52 1100 4 5. 0.000 o.315 0.335 0. 14 7 0. 156 0.461 0.490 2.44 2.48 lll 5 6 o. 0.000 0.302 C.319 0.156 0.166 0.455 o.485 2.42 2.48 1130 7 5. 0.000 0.286 C.3C5 0.164 0.112 0. 4 1t 7 0.4 77 2.40 2.45 1145 90. 0.000 0.271 O. 2H 0.112 o. 185 0.442 o. 4 73 2.39 2.44 1200 105. 0.000 0.259 0.276 0,180 o. 191 0.43tl 0.466 2. 3 5 2.42 1215 12 o. 0.002 o. 24 7 0.261 0.18d 0.200 0.435 o.460 2.35 2.41 1230 13 s. 0.002 0.237 c. 2 53 o. 19 3 o. 206 0.429 0.457 2.32 2.J8 12 45 15 o. 0.001 0.225 0.2.:n 0.201 0.216 0.425 0. 1,52 2.31 2.37 1300 165. 0.001 0.216 0.226 0.203 0.220 o. 'tl9 0.445 2.20 2.36 1315 l 80. 0.001 C.208 C.215 0.208 0.221 0.415 0.440 2.26 2.34 1330 195. 0.001 0. 19 7 0.2C5 0.214 0.229 0. 1110 0.432 2.2s 2 • .32 1345 2l0. 0.010 0.186 o.1ss 0.220 0.234 o.4 □ 5 0. 1,20 2.24 2.32 1400 2 2 ::i. 0.010 0.178 C. l E4 0.223 0.239 0.400 0.422 2.23 2.31
N 1415 240. 0.012 0.171 0.116 0.225 0.242 0.395 0. 'o l 7 2.20 2.28 -...J I-' 1430
1445 2 5 5. 210.
O. 0 l 2 0.012
0.164 0. 15 9
C.170 C.160
0.224 0.226
0.2;,1 0.246;
o.3a7 0.384
0.410 0.403
2. 18 2.11
2.26 2.25
1500 2 85. 0.011 0.150 o.1s3 0.22', 0 • 246 0.3 78 0.398 2. 15 2.,u, 1515 3 oo. 0.020 0.143 C.147 0.231 0.2't9 0.3 73 o.395 2.14 2.23 1530 315. 0.020 0.138 0. l 'i 2 0.232 0.249 0.368 0.389 2.12 2.20 1545 330. 0.020 o. 133 o.136 0.228 0.246 0.36J 0.380 2.12 2.20 1600 345. 0.022 0.120 G.121.J 0.232 0.246 0.357 0.376 2.09 2.18 1615 360. 0.024 0.123 0.122 0.230 0.248 0.351 0.369 2.09 2. 18
-
EC -360 ALKANES, 46 DEG f (6.0, 0.5)1979 FEB 6
CLOCK THIE
ELAPSED TtHIN)
PAN PPH
HCHO PPM
ACETALD PPI'
PROPALD PPM
ACETONE PPM
HEK PPM
C3-N-2 PPM
C4-N-2 PPM
METHANE PPM
ETHANc PPM
EThENE PPM
ACET VLEN PP/ol
N --..J N
955 1015 1030 1045 1100 1115 1130 1145 1200 1215 1230 1245 l3JO 1315 1330 1345 1400 1415 1430 l't45 1500 1515 1530 1545 1600 1615
-20. o.
15. 30. 45. 60. 75. 90.
l O5. 12 o. 135. 15 o. 165. l BO. 195. 2l0. 22 5. 240. 2 5 5. 210. 2 85. 300. 315. 330. 345. 360.
****** o.o *"'**** ******D ****** ******D ****** 0.001
*****-* 0.002
****** 0.002
****** 0.003
****** 0.004
****** 0.004
"'***** o.oos
****** 0.005
****** 0.006
****** 0.006
****** 0.022
****** ****** ******
0.008 ****** ****** ******
0.010 ****** ****** ******
0.013 *****• ****** ******
C.015 *****'Ii ****** •*****0.020
****** ****** ******
0.022
•***** c.o ****** ****** ****** o.ooca ****** ****** ****** G.OG38 •***** ****** ****** 0.0065 *"**>l* ****** *.. **** C.OCiS ****** •***** ****** 0.0126 ***""'~* *"'**** ****** 0.0136
****** o.o ****** ****** ***l1I1!'*-** ***"*"' ****** **•*** ****"'*
>1
-
EC -360 ILKANE S, 46 OEG F ( 6. C, 0. 5 I
1979 FEB 6
CLOCK ELAPSED TS REL HUl-t SSPOkER RAOIOl-t HCHO VOL TIME T{HlNI DEG F % Kw M1UCM2 L
955 -20. 44.2 42.0 *"**** ****** ****** 1015 o. 41.5 46.0 15.87 0. 15
-
EC -360 ALhANES, 1979 FEB
46 6
DEG f (6.0, 0.5)
CLOCK TIME
ELAPSED T(MIN)
N02 PPI',
N02 PPM
NOX PPI'
NOX PPM
TOT N03 PPM
TOT N PPM
H20 PPM
HCTCT PPMC
N '-I .po
955 1015 1030 1045 1100 1115 ll 30 1145 1200 1215 1230 1245 1300 1315 l..>30 1345 l4Ll0 1415 1430 1445 1500 l:.il5 1530 1545 1600 lol5
-20. o.
15. 3 o. 45. 6 ::>. 75. 90.
l O 5. 120. 135. 15 o. 16 5. l il J. l 95. 2 lo. 2 2 5. 240. 25 5. 2 7 o. 2 as. 300. 31 ~-33 o. 345. 360.
0.120 0.122 0.126 0.139 0.150 0.160 0.169 0 .177 0.187 0.195 0.202 0.210 0.213 0.219 0.225 0.232 0.236 o. 238 0.238 0.241 0.2"4 0.247 0.248 0.245 0.249 0.248
0.126 0.123 0.136 0.144 0.15l
-
EC -361 ALKANES, 1979 FEB
126 DEG 7
F (6.0, 0.5)
BEGIN lRRAOlATION 1015; 0.25 INCH PVREX FILTER; TRICHROlC FILTER NOX INJECTED PRIOR TO PURE AIR FILL U5ING EC VACUUM RACK RH OF FILL 15% AT 85 DEG F FOR A PRECICTED 5% RH AT 125 DEG F LESS THAN lPPB N-BUTVL NITRATE DETECTED SMALL AMOUNT OF UNKNCWN AT RETENTICN TIME 2.2 HIN. DASIBI 1212; TECO 14-1 t; TECO 14/E USED BECKMAN 6800 ON MANUAL CPERATION; CO FACTOR: 1.6/5.0
OUT
T=O AT 1015 PST
PAN HCHO
REL INT
CAL I 8/i 12
3 4
1-v --.j
V1 TS
SSPOWl:R RADIOM REL HUM
HZ □ ND
NOZ-CORR N-Ci1
NEO-C5 co
HCHO C4-N-2 MEHIANE ETHANE ETHE NE
ACETVLEN
DEG K KW
HW/CM2 %
PPM pp M PPM PPH PPM PPM PPM pp M PPM pp M PPM PPM
AVERAGE AVERAGE AVERAGE AVERAGE AVERAGE !NIT COf\D !NIT COND INIT CDNO !NIT CONO !NIT COND !NIT CCND INIT CON □ INIT COND !NIT CONO !NIT CGND INIT CONO
325.l lt.26 0. 154 5.COO 6.CBOE C.392 0. 132 2.631 2. ElO 1. 120 C .C.23 O.COl l.318 0 0 C03 O.C03 O.CC4
* 03•
SPECTRAL DISTRIBUTION WAVELENGTH(NM) REL. lNTENSITV
500. 2,502 430. l.951 403. l ,lh)9 3JO. 1.589 370. l.404 360. 1.164 350. 1.000 340. 0.7tll 330. o.sz3 320. 0.276 3l0. 0.099 300. 0.048 290. o.o
* ASSIGNED INITIAL CCNDITION Kla.0,39 MIN-1
SAMPLING RATE~ 2.287 L/MIN
46 GC SAMPLES TAKEN
-
EC -361 ALKANES, 126 DEG F (6.0, 0.5J 1979 FEB 7
CLOCK TIME
915 930
1000 1015 1030 1045 llOO
ELAPSED T(MIN)
-60. -45. -1 5.
o. l 5. 30. 45.
OZONE PP!".
****** o.o o.o 0.000 0.002 0.002 0.010
NO PPM
( 148-U **"'***
0.386 0.390 C.392 0.330 0.260 C.203
NO PPI<
I HB/E) *•****
0. '1 l B C. '115 0.'112 C.343 C.278 0.214
NOZ-CORR PPM
'14B-U ******
0.13C 0.132 o. u2 0.18', 0.251 o.302
NOZ-CORR PPM
(148/E) ******
0.151 0.174 0.178 o. 249 0.314 0.377
NOX-CORR PPM
(14ij-l) ****** 0.518 0.522 0.523 0.518 o. 511 0.505
NOX-CORR PPM
il4B/E) ****** 0.570 o.5a8 0.588 o. 590 o.590 0.590
N-C4 PPM
****** o.o 2. 83 2.83 2.79 2.11 2.15
NEO-C5 PPM
****** o.o 2.81 2.dl 2.80 2.79 2.17
1115 1130 1145 1200 1215 1230
60. 75. 90.
105. 12 o. 13 5.
0.011 0.021 0.046 0.076 0.110 0.151
0.155 0.111 0.084 0.056 C.044 0.033
0.161 C.115 C.C79 0.051 C.037 C. C 2'1
0.340 o. 369 o. 398 0.418 0.420 0.421
o. 431 0.'172 0.504 0.529 0.536 0.543
0.494 0.466 0.479 0.472 0.463 0.453
o.589 o.587 0.585 o.5a1 o. 573 0.567
2. 72 2.69 2.66
****** ******
2.58
2. 74 2. 73 2. 71 2.09
****"'* 2.64
N .......
°'
12 45 1300 1315 1330 1345 1400
15 o. 16 5. l !iO. l 95. 21 o. 225.
0.191 0.242 0.293 0.342 0.398 0.462·
0.026 0.021 0.018 0.016 0.012 O.Oll
c.c l7 o.c12 C.OC9 C.OC5 O.OC4 o.oc2
0.424 o.418 0.415 0.404 0.393 0.391
0.548 0.549 0.547 o.535 0.524 0. 522,
0.446 0.436 0.431 0.4ld 0.403 0.400
o.565 o.5oO 0.554 o. 540 0.526 0.523
2.53 2.52 2.48 2.45 2.39 2.38
2.63 2.61 2.59 2.56 2.52 2.51
1415 1430
240. 2 55.
c.525 o.579
0.011 o.ooc;
o.oc1 c.c
0.387 o.380
0.515 0.508
0.396 0.3 8 7
0.516 0.507
2.34 2.31
2.50 2.47
1445 1500
270. 2 65.
0.61,2 o. 711
0.010 0.010
o.c o.o
o.373 o.362
o. ,,95 o.•,84
0.379 0.371)
0.493 0.482
2.29 2.27
2.45 2.44
1515 1530
300. 315.
0.767 0.826
o.ooc; 0.001
o.c c.c
0.351 o.340
o. ,.10 0 • .1160
0.351 0.345
0.467 0.458
2.24 2.21
2.41 2.40
1545 330. 0.1387 0.010 -0.0Cl 0.327 o. 1145 0.334 0.442 2.19 2.3a 1&00 345. 0.940 0.001 o.o 0.31'1 o.•,3o 0.319 0.428 2.1e 2.35 1615 360. 0.977 C.007 o.o 0.301 0.416 0.307 0.414 2.12 2.33
-
EC -36l ALKANES, 126 OEG F 16.0, 0.5) l9J9 FEB 1
CLOCK TIME
ELAPSED TCMIN!
co PPM
PAN PPM
HCHC PPI-'
ACETALD PPM
PROPALD PPM
ACETONE PPM
MEK PPM
ME-N PPM
C3-N-2 PPM
C4-N-2 PPM
HE THANE PPH
ETHANE PPM
ETHE NE PPM
N "--.I "--.I
915 930
1000 lul5 1030 1045 1100 1115 1130 11 '• 5 120 (} 1215 12 30 1245 l3JO 13L5 1330 1345 1400 1415 1430 1445 l :iOu 1515 t530 1545 1600 lb 15
-60. -4 5. - 15.
o. 15. 3 o. 45. 60. 7 5. 90.
105. 12 o. 135. 15 o. 1o 5. 18 o. l 95. 2l0. 22 5. 240. 25 5. l 7 0 • 205. 300. 315. 330. 345. 360.
****** ****** "'"'****
1. 12 ••**** ****** •***** ****** ***•** ****** ****** "'***** ****** I(,***********
1.s4 **•>II**•"' ***•+• ·••***
0.182 •***** ****•* ••****
C.230
0.0010 ****"'* ****** ••***• ****** ****** ***"'** 0.045l(,0.0000 ****>lio 0.0J7d *****"' 0.0091 ****** 0.0177 "'** **"' O.Ol.32 ****** 0.0134 ****** 0.0164 ****** 0 .. 0178
**"'*>I
-
• •••••
EC -361 ALKANE s I 126 DEG F (6.0, 0.5) 1979 FEB 7
CLOCK TIME
915 930
1000 1015 lu30 1045 1100 1115 1130 1145 lZuC 1215 1230 1245 1300
N 1315--.J 00 1330
13 1,5 1400 1415 1430 1445 1500 1515 1530 1545 l&OO H.15
ELAPSED Tl MIN)
-60. -45. -15.
o. l 5. 30. 4~. 6 o. 75. 90.
l O 5. 12 o. 135. 15 0. 165. 180. 195. 21 o. 22 5. 240. 255. 270. 2 85. 300. 315. 330. 345. 360.
ACETYLEN PPM
(PNI 0.0029 ****** *****• 0.0039 ****** ****** *"'**** ****** ****** ****** *****¥ ****** ****** ****** ****** 0.0032 ****** ****** ****** ****** *****>ll ****** **"'*** ****** ****** ****** ****** 0.0030
ACET¥LEN PPM
{OMS.I
****** 0.0028 **** ... * ****** ****** *"'**** *"'**** ****** ****** *>I'**** *"'**** ****** ****** ****** ****** ****** ****** ****** **¥*** ****** ****"'*
'°****• ****** ****** ****** **•"'** ***•**
PROPJNE PPM
****•* c.oc12 ****'°* ****** *'II!'
****** ****** ****>+* ****al* ****** *al**** *"**** *"**** *****"' ****al* ****** >I >I** lj '4 ****al* '°****Jjo*"'**"'"' *"**** .,.*****'°***al '°***•* ****** ****** ...****
1-C4 PPM
***"'** 0.0001 ****** ****** ****** ****•* ****** ****** ****** ****** ****** ****** *>1
-
EC -3td ALKANES, 126 OEG F L6. 0, 0.5) l':179 FEB 7
CLOCK ELAPSED TS SSPOhER l
-
EC -3t.. l ALKANES, 126 DEG F ( 6 .o, o.5> 1979 FEB 7
CLOCK TI ME
ELAPSED T(MIN)
N02 PPM
N02 PPM
NOJI PP/'
NOX PPM
TOT N03 PPM
TOT N PPM
I-ICTOT PPMC
915 -60. ****** ****** *"**** •***** ****** •***** 1. 375 930 -45. 0.131 0.151 o.519 0.57C 0.001 0.548 ******
1000 -15. 0.133 0.175 0.5.:3 o.5sc; 0.001 0.548 ****** 1015 1030
o. 15.
0.133 0.191
0.178 0.250
C.524 C.51
-
EC -362 SURRJGATE Y, 85 Di:G f 10.7, 0.1) 1979 FEB 13
BEG[N IRRADIATION 0945; 0.25 INCt PYREX FILTER; TR!CHRDIC FILTER OUT NOX INJECTED PRJOR TG PLRE AIR FJLL U~JI\G EC VACUUM RACK HIGH PN VALUES SUSPECTED CUE TO PREVICUS HIGH-CONCENTRATION CALIBRATION BRADY 292i DASIBI 1212; TECO 146-l C lECO l'18/E USED DECKMAN b800 CN MANUAL CPi:RATICNi CO FACTOR: 1.6/13.7
T-0 AT 945 PST
CALIB/1 PAN 12
HCHO 3 REL INT 4
SPECTRAL WAVELENGTh{NMl
TS D!:G K AV ER AGE 302.€ 500. N REL HUM t AVERAGE l S. 9 l 4 3 o. 00 SSPO',ii:rl KW AVERAGE ll .25 40 3. I-'
RADIDM MW/CM2 AVERAGE G, 154 3 U o. H20 pp M AVERAGE 4,28CE C3>1< 310, NO PPM lNlT COND 0.(82 360.
N 02-C QR
-
EC -36 2 SUR.ROG ATE V, 85 DEG F ( 0. 7, 0.11 1979 Fi:B 13
CLOCK ELAPSED OlONE NO NO N02-CORR N02-CORR NOX-CORR NOX-CORR TIME T(MINJ PPM PPM
( 148- l) PPI'
( 148/E) PPM
1148-ll PPM
{14B/E) PPM
(14B-lJ PPM
(148/El 840 945
-65. o.
****** 0.000
"*,;
-
... 0
,.. 0
- =:l
N ~•o••a••O••o a: ..... * ......... *·••·*·•··• ♦ ........... o. oo••o••o••a••o••O••o~•o••o z w ti\...,.-** "'¼ *O* 4 ·O * .. aJ. * N 4 * N ¼ ¼0..Jl:-0-0-¼* 04 ... (/\ * * j. ~ (',.J * 4 ....OO• ...* 0 -l>-,; O*l>O** -, * -,; -lf':>*¼O* 0 * -~ ~ 00** ••• • * ~ • * * • * * * . * * io¼O¼¼O* 0 )!, * 0 *' * O**O** 0 ... *
w z ,.._-0*******'****'******'*'*-ll-***"' ~~ NN***********************N :cc. • ·•******4**1>*'*****'****** • ... ~ --•*~********~*********••-w -ll-*******ll-*****•****•*•* ~ ·lt * * * * .. * .. * * * * * * * * * * *. * * ..
.. O' * *"'**N¼.-0¼¼--T¼ ¼O'**~*',,: ::!:; •o• *N**"'**O•**O**O* +o**o*:::;: C. *O* * o * * a * *' ·.:> * * o * * • * it-•·';:to*•**·**·* * • * ~ • ** 0 .. -itO¼-l,0**04*0*' "'a.;;* o *
w 2 ,.._-O**""**..,**N**~**~**~**-0*¼0Ol: 0-0l>*O¼l>O**O**O**O**O*¼O u • • * * • * ¼ • + + • * ... • i> * -. * * • ~ -d- • * * C OO**O**O* 1t '2' ("\J ,o,. 9 it _... it * ~ t"" 11" 1t ¼ fl\ :r: C. *0***0"'*""0*~*U¼lt'IO 0. :,;:: -0 --'~~-Or--~QN~lt'I-O=~-N~tt\r--=o-"'~-0
-
EC -362 SLJRROGATE V • 85 DEG F 10.1. o.u 1979 FEB 13
CLOCK ELAPSED I-C4 N-C4 T2-C 4:a CIS2-C4- 2ME-C4:a2 2,3-0Mtl N-C6 TOLUENE M-XVL TIME T(MlN) PPM PPM ppr,_ PPM PPM PPM PPM PPM PPM
840 -65. 0.0001 0.0510 c.occ2 0.0051 0.0040 0.0164 ****** O.l.l04 0. 0095 9lt5 o. 0.000 l 0.0481 c .occ2 0.0039 0.0035 0.0167 u.0142 0~005 o.u100
1000 1015
15. 30.
****** ******
****** ******
****** ******
****** ******
****** *>IIII**** ******
****** ******
****** ******
****** ******
****** ******
****** ******
****** ***''*"'
1115 90. 0.0001 C.e4ol c.c C.0006 o.o O.Jl36 0.0125 0.004 0.0050 1130 1145
l O:;. 12 o.
****** ***"'**
****** ******
*** * * * *~****
*'\!l
-
EC -362 SURRJG ATE Y1 85 DEG F ( C. 7, o.u l9H FEB 13
CLOCK ELAPSED TS REL HUM SSPU\o.ER RAOIOM HCHO VOL TIME TIMINl DEG F % Kl, MW/CM2 L
840 -65. ****** ****** •~**•* ****** ****** 945 o. 03,3 16.5 l 6 • 111 ****~'* 20.00
1000 15. 04.3 l 8. G ****** o. l 5 6 ****** 1015 3 o. 84.5 19,0 ****** 0,154 ****** 10 30 4 5. 85.0 19. 5 ****** 0. 15 11 *** "'** 1045 6 o. 85.7 19.5 l 6. l '1 0,156 20.00 1100 75. 86, 5 19. 5 ****** 0. 15 6 ****** 1115 1130
90, l O5.
87.2 87,4
19.5 19,0
****•* ***"'*
****** *****"
****"'* ******
114 5 12 0. 85,2 19.5 16. 10 0. 15 'i 20. 00 1200 l J 5. as.a 20.c **** *" 0. lS l ****"* 1215 1230
15 o. 16 5.
84.8 85.0
20,5 20.5
****** ****•*
0.151 0.151
*"''~""* *'~**,;,;*
1245 1 8 o. 85.G 20.5 lo. C 6 o. 151 2 o. 00
N
1300 1315
19 5. 2 l O.
84,8 84.5
2LO 20.5
**''*** **,, ,. *>l< 0. 11, 9 0.14',
*"**>il:<
l 4 1,5 1500 1515
30 o. 315, 3 30.
85.5 05,5 86.0
20.5 20,5 20. 5
l6.3cl ***,;,*****>(,'i'>I<
0,156 0.156 0,156
20.00 ****** ******
1530 345. 86, 0 20.5 ****+* 0,159 **>i
-
EC -362 SURROGATi:: V, 85 CEG F (0.7, 0.11 1979 FEB l3
CLOCK TIME
ELAPSED T(MINl
N02 PPM
f\i02 PPM
NOX ppr,
NCJX PPM
TOT N03 PPM
TOT N PPM
H20 PPM
HCTOT PPHC
N (X)
0\
840 945
1000 1015 hl30 1045 llOJ 1115 1130 1145 1200 1215 1230 1245 1300 1315 1330 134:i 1400 141~ 1430 l',45 1500 1515 1530 1545
-&5. o.
15, 30. 45. oG. 75. 90.
105. 120. 135. 150. 16 5. 16 o. 195. 2 lo. 2 2 :i. 240. 25 5. 2 70, 285. JOO, 315. 330. 345. 360.
****** 0.029 0,041 0,055 0.055 0.064 o. 06'.i 0.070 0,06'.i 0,075 0.012 0,072 O.C72 0.072 0.010 O,J69 0,063 c. 06C 0.066 0,064 O,Oo4 0,065 0.061 0.062 0.063
******
****** 0.03G 0.038 0,04'.i 0.05S 0.067 O,OH C,OH 0.001 C,083 0,084 0,083 0,084 0.084 0,084 0,084 0.08~ c.c0~ O.OdJ 0.082 O.OiH C.083 O.Od3 0.081 0.060
*****>I
*~**** c.111 C. lC'i C. 111 C.1C5 o.1c2 C.lCC C.CS7 O,CS5 C.CS5 c.oc;o C.CE'i O.C87 O.Ot:6 c.co C,CEl O. Ci'i D.CHJ O.Ci7 O.C75 O.C14 C,074 0, Cil o.o a a.en
*~****
>II
-
EC -363 ALKANES, 1979 FEB
85 14
DEG F (3.0 1 0.05)
BEGIN IRRADIATlCN 1030; 0.25 II\Ch PYREX FILTER; TRICHROIC NOX INJECTED PRIOR TO PURE AIR FILL USING EC VACUUM RACK BRADY 292; DASIBI 1212; TECO 148-l & lECO 148/E USED BECKMAN 6800 ON MANUAL OPERATION; CO fACTOR: 1.6/12.9
FILTER OUT
T2 0 AT 1030 PST
PAN HCHO
REL INT
CAL I BIi 12
3 4
SPECTRAL DISTRIBUTION WAVELENGTHINH) REL. INTENSITY
N co --.J
TS REL HUH SSPOWcR RAD 101'1
1-120 NO
N02-CORR N-C4
NEO-C5 co
HCHCJ ACETALD HE THANE ETHANE ETHENE
ACETYLEN
DEG K :I:
KW HW/CH2
PPM PPI-\ PPM PPM PPM pp H PPM PPM PPM PPM PPM PPM
AVERAGE AVERAGE AVERAGE AV ER AGE AVERAGE HdT CCI\O INIT CGND IN IT COND INIT COND lNIT CCNO INIT COI\D IN IT COND INIT COND IN IT COND INIT CCI\D IN IT COND
302.7 l ':i. 8 5 le .C'i 0. 153 5.l'iCE C.C38 0. C15 1,491 l.4S8 0.260 O.C06 o.cc2 l. 176 O.C03 0 .oo l c.cc2
03*
500. 430. 403. 380. i70. 360. 350. 340. 330, 320. 310. 300. 290.
2.546 2.168 1.9 71 l.'/54 1..575 1,313 1.000 0.89 3 0,608 0.319 0.111 0.019 o.o
* ASSIGNED INITIAL CONDITION Kl:.0.39 HIN-l SAMPLING RATE: 2.271 L/HlN
36 GC SAHPLES TAKEN
-
f.C -363 ALK~\JES, 85 DEG F (3.0, 0.05) 1979 FEB 14
:LJCK EL4PSF.D 0lONE NO NO N02-C0RR N02-CORR N0X-CORR N0X-C0RR N-C4 NEO-C5 TI ME
1015
T(MIN)
-15.
PPM
****'°'*
PPM ( 14B-l) ******
PPM ( 148/E) **'°'***
PPM 0411-11 *'°'****
PPM 1148/~) ******
PPM 1148-11 ***'°'**
PPM fl4B/F) ******
PPM
1.50
PPM
1. 51 1030 o. o.o 0.153 0.155 o. 060 0.054 0.213 0.208 1.49 1.50 1045 15. 0.002 0.1'12 0. l't2 0.068 0.066 0.209 0. 2()8 1.47 1.48 1100 30. 0.005 0.134 0. 127 0.011 0.000 0.211 o. 206 1.45 1.46 1115 1130
45, 60.
0.007 0.012
o.114 0.102
0. 1-12 0.100
0.090 0. 10 l
0.093 0.106
0.204 0.201.
o. 205 0.205
1.44 1.43
1,44 1.44
ll 45 75. 0.015 0.092 o.oao 0, 110 0.117 0.202 0.203 1.41 l. 43 1200 90. 0.011 0.079 0.073 0.110 0.128 o. 196 0.201 1.40 l. 42 1215 l 05. 0.022 0.074 0.063 0.121 0.138 0.194 0.200 1.39 1.41 1230 12 o. 0.029 0,058 o. 052 0.132 0.147 0.190 0.198 1.38 1.40 ll45 135. 0.034 0.049 0. 0 1,4 0.139 0.153 0.188 0.197 1,37 l. 40 lJOO 150. 0.044 0.059 o.038 0.126 0.158 0.185 0,195 1.35 1.38 1315 1330
16 5. 180.
Q.054 0.0o't
a. 039 0.034
o. 031 0.025
0.146 0.144
0.162 0.164
0.183 0.177
o. 19:?. 0.189
1.35 1.33
1,38 1.37
1345 195. 0.073 0.032 0.022 o.144 0.165 0.176 0. 187 1. 3 2 1.36
N 00 (X)
14J0 1405 1410
210. 215. 2 2 o.
0.083 o.oa8 0.093
0.025 0.031 0.024
0.018 o. 018 o. 017
0.146 0.145 0.145
0.169 0.168 0.lo6
0.111 o. 175 0.169
0.187 0.186 0.185
1.31....... ******
1.34 ***,0:,0: ♦
•t•t** 1415 1430 1445
2 2 5. 240. 2 55.
0.098 0.073
>lO
-
EC -363 ALKANES, 05 DEG F ( 3. 0, 0.05l 1979 FEB 14
CLOCK ELAPSED co PAN liChO ACETALD PROPALD ACETONE MEI!< ***"'** ****** 1100 3 0. ****"'* o.o "'***** ***"'** ****** ****** ****** ****** ****** ****** **"'*** ****¥* 1115 4 5. ****** ****"'* **"'* ** ****** ****** ****** ****** ****** ****** ****** ***''"'* *"'** "* 1130 1145 1200
6 0. 75. 90.
0.29 ***>lI
-
EC -363 ALKANES, 85 DEG f (3.0, 0 .. 05} 1979 FEB 14
CLOCK ELAPSED TS REL HUM SSPCnER RAOIOI-' HCHO VOL Tl ME TtMIN) DEG F % KIi MW/CM2 L
1015 1030
-15. o.
****** 85.7
****** 17. 5
,. "* **. *•****
****"'* 0.156
**"'*** 20.00
1045 15. 86.C 18.C ****** 0.156 ****** 1100 3 o. 83.5 19.5 ****** 0.154 ****** 1115 4 5. 83.0 20.5 +>I**** ****** ****** 1130 6 o. 84.5 20.5 l6.C4 0.154 20.00 1145 75. 84.8 20.5 ****** ****** ****** 1200 90. 86.0 20.0 ****'°* ****** ****** 1215 1230
105. 12 o.
85.5 86.0
20.0 20.0
****** 16. JO
**"'*** o. 15')
*****,;, 20.00
1245 135. 86.2 20.0 *''**** 0.154 ****** 1300 15 o. 87.C 20.0 ****** 0.154 ****** 1315 165. 86.2 20.0 *H'*** 0 .14') ****** 1330 180. 85.7 20.c 16 .13 0.149 20.00 1345 195. 85.7 20.0 ****** 0. 151 ****** 1400 210. 85.5 20.0 ****** 0.156 **'"***
N '-D 0
1405 1410 1415 1430 1445
215. 220. 22 5. 240. 255.
85. 7 85.2 86.0 81.3
******
20.0 20.0 20.0 20.c
••****
*~**** ****** •***** *"****.......
0.14') 0.151 0.151
****** *•***•
>II
-
EC -363 ALt
-
EC -365 SURROGATE Y, 1979 FEB 16
BEGIN IRRADIATION COMPUTER ON LINE
46 DEG F 10.7, O.lJ
1030; 0.25 INCH PYREX FILTER; TRICHROIC FILTER OUT AT 1057
NOX INJECTED PRIOR TO PURE AIR Fill USING EC VACUUM RACK RH OF Fill 15% AT B!.> OFF F FOR A PREDICTED 25:C RH AT 45 DEG f JASIBI 1212; TECO 14-1 & TECO 14/E BECKMA'l 6800 ON
T=O AT 1030 PST
PAN HCHO
REL INT
N TS DEG K \,() SSPOWER KW N RADICJM Ml-.'/CM2
REL HUM % H21J PPM NO PPM
N02-CORR PPM co PPM
ACETALD PPM P~OPALD PPM AC ETO'li; PPM M!:Tti/,NE PPM ETHAME PPM ET HENE PPM
AC= TYLF.N PPM PROP Iii IE PPM PROPE"IE PPM
CIS2-C4= PPM 21-\~-C4=2 PPM
2,3-DMo PPM N-C6 PP-M
T:JLUEIIJE PPM M-XYL PPM
ASSIGNED*
MANUAL OPERATION;
CALIB#-12
3 4
AVE~.AGE AVERACE AV F.P. AGE AVERAGE AVffl ACE !NIT INIT IN IT INIT HI IT INIT INIT I NIT HIIT IN IT INIT HJIT INTT HIIT !NIT IN IT HIil INIT
INITIAL
CONO COND CCND COND COND CCND CCND COND COND CCND COND CGND COND CCND CONO CCNO CONO COND
CONDITION
USED CO FACTOR: 1.bll0.4
281.1 lc.21 o.157 63.00 * 6.690E 03* Q.1)72 * 0.021 * 2.400 0.009 0.001 0,005 l. 39'i 0.02s 0,01) 0.016 0.011 0.003 0,004 0.004 0.016 0.013 O.OO'i 0.010
SPECTRAL DISTRidUTlON HAVELENGTHlNMl REL. INTENSITY
500. 2.278 430. 1.920 4J3. l. 724 3UO. 1.528 370. l.35 1t 3oO. 1.146 330. 1.000 340. o. 79!.i 330. 0.522 320. 0.295 310. o. 10 5 300. 0.014 290. o.o
K1~0. 38 i-tl N-1
SAMPLING RATE= 2.2ti6 l/MIN
44 GC SA~PLES TAKEN
-
EC -365 SU~ROGATE V, 46 DEG F 10.1, c.11 1979 FEB 16
CLOCK ELAPSED OlONE NO NO N02-CORR N02-CORR NOX-CORR NOX-CORR lit-IE T(MINI PPH PPM PP/J PPM PPM PPM PPM
945 1030 1045 1100
-45. o.
15. 30.
*•**** ****"'• ******
0.007
(148-1) ***•** *****+****,.,.
0.055
(148/El ••**** .. ••*******••
0.053
t 148-1) •***** ***"'*"' ****** 0.043
{148/E) ****** ****** ******
0.042
( 148-1) ****** ****** ******
0.098
Ll4B/EI ****** ••••••***•*• 0.095
1115 45. 0.012 0.04'i 0.045 o. 01,6 o. 04 7. 0.095 0.091 1130 6 o. 0.012 0.048 c.c~s 0.046 o.049 0.093 0.088 ll 45 75. 0.019 0.03
-
EC -365 SURROGATE Y, 4o DEG F ( 0. 7, 0.11 l 'J 79 FEB 16
CLLlCK rlME
ELAPSED T(MlN)
ca PPM
PAN PPM
t-Cl-0 PPM
AC ET ALO PPM
PROP ALO PPM
ACETO,\lc PPM
MEK PPM
METHANE PPM
ETHANE PPM
ETHE NE PPM
ACETYLEN PPM
PROPANE pp~
PROP ENI PPM
(PNI 945 -45. ****** **"'**• ****•* 0.0102 ****** 0.0043 0.0004 1.39 0.0251 0.0136 0.0167 0. 0119 0.0034
1030 1045 lluO
o. l 5. 3 o.
2. 110 ****** ******
o.o *****•
o.o
o.o............... 0.0093 ****** ****** 0.0010 ****** ****** 0.0047 ****** ****** 0.0004 ****** ****** 1.39 ****** ****** 0.0249 ****** ****** 0.0135 ****** "'***** 0.0163 **"'*** ****** U.Oll't ***"'** "'**"'** 0.1)033
****** ••••••
N ~
1115 1130 1145 1200 1215 1230 1245 1300 1315 1330 13 45 l4Ll0
45. 60. 75. 90.
105. 120. 1J5. l 5 O. 1,:,5. 18 o. 195. 210.
****** 2.40
**>IIlo**"'** 0.003
"'****"' 0.004
**"'**• 0.005
****** 0.005
****** 0.006
***"'** O.OC6........
•"* ..... >lit** •• c.c.......
>I ..... * ****+*
C. C....... ·~····
!!'***** ++>I1Ili>It
-
EC -365 SURROGATE Y, 46 CEG F {0.7, 0 .11 1979 FEB 16
CLOCK ELAPSED 1-C'i N-C4 T2-C'I= CIS2-C4; 2ME-C4;2 2,3-DMli N-C6 TOLUENE M-XYL TIME TIMIN) PPM PPM PPI' PPM PPM PPM PPH PPM PPM
945 -45. 0.0001 0.04'.ll C.OOC3 0.004C 0.0036 0.0158 0.0139 0.004 0.0095 1030 1045 1100 1115 1130 1145 1200
o. 15. 30. 45. 60. 75. 9 a.
o.o •***** •****• 0.0001 ****** *•***• 0.0000
•***** *****" ••***• 0.0455 *•***• ·••*•• 0.0440
C.OGC2 ••**""'....... c.ooc1••••••• "** ♦ >4o G.C
0.0038 ****** ****** 0.0016 ****** •****• o.oooa
0.0036 ****** ****** 0.0001 ****** ***•** o.o
0.0165 ****** *****• 0.0143 ****** ****** 0.013 1,
0.0134 ***"** ***"'*• 0.0130 •***** *** ** * 0.0118
0.1)04 ****** *****•
0.004 ****** *****» 0.004
0.0101 ****** ·••*** 0.0076 ****** ****** 0.0056
121 5 12 30 1245 1300 1315 lBO
l O5. 12 o. 135. 15 o. 165. 18 o.
****** *****"' 0.0001 ****•***,;,*** 0.0000
*****•+>l**** o.0427 *****•• •***. 0.0417
:,j •••• + .. ,,. ...... c.o ,. ,. .. ,.. ****•* c.o
"'***** ****** 0.0003 ****** *****>4o 0.0002
****•* ****** o.o ****** ****** o.o
****** ****** 0.0124 ****** ****** 0.0119
****** *****,;, 0.0112 ****** ****** 0 .o 10 7
***"'** *****,;, 0.003
****** ,;,***** 0.003
ii30
2 85. 300.
•***"'* ******
*+**"' .. •·***•
*****,;,*......
**"'*** *****•
**•**'!' ***'***
****** ******
•***** ******
****,;,*******
****** ******
1545 3l5. 0.0002 0.0380 o.c o. 0 o.o 0.0100 0.0093 0.003 o. 0020 1600 1615
330. 345.
*****,;,******
*****>I ****•*
>l>i*,;,•• ****"*
*,;,*** * ***•**
*****>!< ******
****** ******
***"'** ****>II
-
•••••• ••••••
•••••• • ••••• ••••••
••••••
••••••
•••••• ••••••
••••••
•••••• •••••• •••••• • ••••• • •••••
•••••• ••••••
••••••
••••••
EC -365 SURROGATE Y, 46 CEG F ,0.1, 0.11 1979 FEB 16
CLOCK TIME
945 1030 1045 111.10 1115 1130 1145 1200 1215 1230 1245 1300 1315 1330 1345 1400
N 1415'° (J\ 1430
1445 1500 1515 1530 1545 1600 1615 1630
ELAPSED HMIN)
-45. o.
15. 3 o. 45. 60. 75. 90.
105. 120. 135. 15 o. 16 5. 180. 195. 210. 225. 240. 2 5 5. 270. 285. 300. 315. 330. 345. 36.:l.
TS DEG F
****** ****** ******
46.7 46.2 46.4 46.4 46.4 46.4 46. 4 46.4 46.4 45.9 46.2 45. lo***¥* ******
16.42 ******
16. 20
****** **•***
15.89
****** ****** 15.89
···••t ******
16.42
*****• 16.46
IUCICM Mk/0'2
****** **** ••
c. B9 C.159 C.159 c.159 0.1 !:6 0.156 0.156
C.1%
.,.. ♦♦ >lo
C.154 0.156 C.151 0. l!:6 C.156
·••t•• 0.164
11CHO 1/0l l
****** 20.00
****** ****** ****** 20.oc
****** ****** ****** 20.00
>lo***** •***** ,c.***** 20.oc
****** >lo***** 20.00
****** ***••· ****** 20.00
****** *'***** 20.00
-
EC -365 SURROGATE Yt 46 CEG F (0.7, o. 11 1979 FEB 16
CLOCK ELAPSED N02 N02 NGJC NOX TOT N03 TOT N HCTOT TI ME T(MlN) PPM PPM pp~ PPM PPM PPM PPMC
945 1030 10 45
-45. o.
l 5.
****** ****** ******
•***** ****** ••****
***•** •l>I++ ♦♦ *... >I .. *
****ll
-
EC -366 SURROGATE Yt 1979 FEB 21
125 DEG F 10.7, O.l)
BEGIN IRRADIATION 0900; 0.25 INCH PYREX FILTER; TRICHROIC NOX INJECTED PRIOR TC PURE AIR FILL USING EC VACUUM RACK BECKMAN 6800 ON MANUAL OPERATION; CO FACTOR: 1.6/11.45 BRADY 292; DASIBI l212i TECO 148-1 6 lECO l~B/E USED
FILTER OUT
T•O AT 900 PST
PAN HCHO
REL I NT
CALI B# 12
3 4
SPECTRAL DISTRIBUTION WAVELENGTH(NMl REL. INTENSITY
N \0 00
TS SSPDwER RADIOH
H20 REL HUM
NO N02-CORR
co HCHO
PROPALD ACETONE ME THANE ETHANE ETHENE
ACETYLEN PROPANE PROPENE N-C4
c1s2-c4.. 2ME-C4=2
2,3-DMB N-Cb
TJLUENE M-XYL
DEG K KW
HW/C M2 PPM
:j; pp M PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM pp~ PPM PPM PPM PPM PPM PPM PPM
AVERAGE AVERAGE AVERAGE AVERAGE AVERA(E INIT COND !NIT CGt,0 INIT CCt,D INIT COI\D IN IT COND IN IT CGNO IN IT COt,O !NIT COND 1N IT CCND lNIT COND INIT CGND IN IT COl'iD INIT COND INIT CCt,D IN IT CCt,D INIT COl'W IN IT CCND I NIT CGND !NIT CCND
324.'i 16.58 a.154 5.150E s.coo o.C7e O.C32 0.;64 c.c10 a.cos O.CCb 1. 135 O.C25 o.c12 O.Cl7 o.c12 O.C03 o.cso 0.004 C.CC3 a.en C.Cl5 O.CC5 O.Gl2
03* *
5J0. 430. 403. 360. 370. 360. 350. 340. 330. 320. 310. 300. 290.
2.186 l.920 l. 738 l.557 l .377 1.148 1.000 0.1db o.s22 0.20a 0.090 O.OOb o.o
,;. ASSIGNED INITIAL CONDITION Kl=0.38 MIN-1
SAMPLING RATE• 2.281 L/HIN
37 GC SAMPLES TAKEN
-
EC -360 SURROGATE Y, 125 DEG F (0.7, 0.1) 1979 FEB 21
CLOCK ELAPSED OZONE NO NO NG2-COAR N02-CORR NOX-CORR NOX-CORR TI ME
758 900
T
-
.. 166 SUKROGATE y' 125 DEG f (0.7, 0.lJ 1979 FEB 21
EC.
CLOCK TIME
ELAPSED HMIN)
co PPM
PAN PPM
tiCHO PP/'
ACETALO PPM
PROPALO PPM
AC ET ONE PPM
MEK PPM
METHANE PPM
ETHANE PPM
ETHENE pp~
ACETYLEN PPM
PROPANE PPM
PROPENE PPM
w 0 0
758 900 '115 930 945
1')00 1015 1030 10 1,5 1100 111 5 1130 1145 1200 1215 12 .30 12 ,,5 1300 1315 1330 13 ,,5 l'tOO 1415 1430 1445 1500
-62. o.
15. JO. 45. 6 o. 75. 90.
105. 120. 13 5. l 50. 16 5. l!W. l 9 '.i. 210. 225. 240. 25 5. 210. 285. 300. J l 5. 330. 345. 360.
****"'* 0.36
****"'* ****** ****••
0.38 *****"' ****** ******
0.56 ****>IIIII< ***"'** ***"'** ****** ******
1.14
0.0268 O.C252 ***~"I
-
EC -366 SURROGATE Y, 125 DEG F ,a.1, C. 11 1979 FEB 21
CLOCK ELAPSED I-C'i N-C4 T2-C4= CIS2-C4: 2ME-C4z2 2 1 3-0MB N-C6 TOLUENE M-XYL TIME TIMINI PPM PPM PPM PPM PPM PPM PPM PPM PPM
7!18 -62. a.a a.052 c.ooc2 0.0041 o.oa32 0.0112 0.0151 o.oa5 0.0133 900 915 930
a. l 5. 30,
0.0000
···••+******
0.050 c.oac3....... .. ....... ••***• ••••••
0.0041 ****** ******
0.0031 ****** ******
0.0169 ****** ""*****
0.0148 **•*** ******
o.uus ****** ******
o.ouo ****** ******
945 l UOO
45. 6 a.
c.0000 ******
0.04g *****•
c.ooc1 ,j, •** ••
0.001c *****+
0.0003 ******
0.0146 ******
0 .o 128 ******
0.004 ******
0.0082 ******
1015 75. ****** ****** ****** ****** ****** *****"'· ****** ****** ***** ... 1030 1045 HOO 11 l 5 1130 1145 1200
90. 105. 12 o. 135. 15 tJ. 16 5. 18 o.
0.0002 ****•* *****• 0.0001 *****• ••**** 0.0000
0.044....... ******
0.040 ****** ******
0.037
o.o•••••• ****** a.a*,. ** *. *** **,.c.c
0.0002 **>1lo*,(,***'¥*o.oou2
O.Oll4 ****-'I
-
••••••
•••••• ••••••
••••••
EC -366 SURROGATE V, 125 DEG f (0.7, C.ll 1979 FEB 21
CLOCK TI ME
758 900 915 930 945
1000 1015 1030 1045 lluO 1115 1130 1145 1200 1215 1230
l,.) 1245 0 1300N
1315 1330 1345 1400 1415 1430 1445 1500
ELAPSED T(MIN)
-62. o.
15. 30. 45. 60. 75. 90.
105. 120. 135. 150. 16 5. 180. l 95. 210. 22 5. 240. 25 5. 270. 285. 300. 315. 330. 345. 360.
TS DEG f
*****+ 121.e
****** ****** ******
124.5 ****** **•*** ******
126.C **"'*** ****** *****•
125.3 ***"'** ****** ******
125.8 ****** ****** ******
126.3 ****** ****** ******
125.8
SSPOwER KW
****** 16 .31
****** ****** *****•
16.5'i ··••*•......... ******
16. 51 *****• ••**** *****•
16.59 *****• ****** **"'***
16.51..... ,. ****** ******
lb.BO ****** ***•** ***"'**
16.75
RAD1Ct'1 /JW/C/J2
+>I**+* C. Hl C.154 C.159 c. 159 C. l 59
****>I* +***•* ******
C.156 ****** .,.....
C.154 C.151 C. 156 C.151 C.151 C.149
******
*****• C.156
******
.......
HCHO VOL L
+***** 20.00
*•**** ****** ******
20.00 ****** ****** *****"'
20.00 ****** *>ll**** ******
20.00 ****** ****** ******
20.00
•***** ****** 20.00
****** ****** ******
20.00
-
EC -366 SURROGATE Y, 125 DEG F t0.7, C.ll 1979 FEB 21
CLOCK ELAPSED N02 N02 NO.ll NOX TOT N03 TOT N HC TOT TIME TlMIN) PPI" PPM p Pl" PPM PPM PPM PPMC
758 -62. ****** ****** *,. •••• ****** ****** ****** 1. 909 900 o. 0.032 0.035 C. l 10 o. 112 o.o o. 110 1.887 915 15. 0.035 0.052 C. 1C9 0.112 0.000 0.109 ****** 930 3 o. 0.063 o. 074 0. 1 C6 0.113 0.000 0, 106 ****** 945 45. 0 .o 73 0.089 G.1C3 0.113 0.001 0, L03 2.225
1000 60. o. 077 0.09'i C. C'i9 o. 114 0.001 0.099 ****** 10 L5 10 30
75. 90.
0.002 0.079
0.106 0.112
c.csa o.os2
0.113 o. 116
o. 001 0.001
o.o9a 0.092
•***** 2 • 134
1045 l O5. 0.07d G.115 C.GSO o. 11 7 0.002 0.090 •***** 1100 120. 0.076 o. 11 7 0.085 o. 118 0. 002 0.086 ****** 1115 135. 0.074 0. 11 'i C.Ocl 0.11 'i 0.003 0.082 1.994 1130 l 5 o. 0.010 0.121 C. CSO 0. 12 C 0. 003 o.oso ****** 114 5 16 5. 0.069 0.124 C.C70 0. 12 2 o. 003 0.078 ****** 1200 1 ao. 0.010 0.124 C.C16 0.121 o. 004 o. 011 l • 9 5 2 1215 195. 0.012 0.126 C.CEl 0.123 o. 004 o.ou1 ******
l,.) 1230 210. 0.071 0.126 c.cao 0. 12 3 0. 004 0.081 ****** 0 l,.)
1245 1300 1H5 1330
22 s. 240. 2S5. 210.
o.oH 0.015 0.083 0.086
C,128 0.128 0 .12
-
FILTER OUT
SPECTRAL \.IAI/ELENGTHINMl
500. 430. 403. 380. 370. 360. 350. 340. 330. 320. 310. 300. 290.
Klc0.36 MIN-1
DISTR18UTION REL. INTENSIU
2.230 l .913 1.122 1.512 1.348 l .137 1.000 0.778 0.527 0.272 0.093 0.007 o.o
w 0 -t--
EC -367 SU~RQGATE Y, 121 OE( f (0.45, 1919 FEB 22
BEGIN IRRADIATION 0900; 0.25 INCh RH OF FILL 15l FOR A PRECICTED 5;
C.l)
PYREX FILTER; TRICHRO[C RH AT 125 DEG f
NOX INJECTED PRIOR TC PURE AIR FILL USING EC VACUUM RACK BRADY 292; DASlBl 1212; TECO l4tl-l BECKMAN 6800 ON
T.aO AT
PAN HCHO
REL INT
TS SSPOWER RADIOM REL HUM
HZO NO
N02-CORR co
HCHO PrtOPALO ACETLl'.'lE ME THAI-IE ETHANE ETHENE
ACETYL EN PROPANE PR,;PENE N-C4
CIS2-C4= 2ME-C4=2
2,.J-OM8 N-Co
TOLUENE M-XYL
900 PST
DEG K KW
Mw/CM2 %
PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM
... ASSIGNED
MANUAL CPERATICN;
CALIB# 12
3 4
AVERAGE AVERAGE AVERAGE AVERAGE AVERAGE IN IT CGI\D INIT CCND !NIT CCND !NIT CONO INIT CCND !NIT CCI\O INIT CGND !NIT CGNO !NIT CCNO !NIT CCNO IN IT CONO INIT CONO IN IT CCNO !NIT CCND INIT CGNO IN lT CONO IN IT CCNO lN 1T CON □ IN IT ccr-.o
INITIAL CCNOITION
& lECO 148/E USED CO FACTOR; 1.6/12.5
3 22. 5 ll: .38 0.149 5.COO "' 6. 280E C3* C. CIi l o.c:rn C.461 a.cos C.C04 C.C06 l.C6l O.Cl8 O.CC7 0.01.2 O.CC9 o.coz O~C:H O.CC3 O.C03 o.c11 C.ClG 0.003 C.C07
SAMPLING RATE= 2.266 L/MIN
44 GC SAMPLES TAKEN
-
EC -367 SURR::JGATE V, 121 DEG F {0.45, O.ll 1979 FEB 22
NO NC N02-CORR NU2-CORR NOX-CORR NOX-CQRRCLOCK ELAPSED OZONE ppr,, PPM PPM PPM PPMTIME HMIN) PPM PPM (14U-ll (148/El (141.l-lJ 1140/E} (140-11 '148/E)
820 _,, o. •***** *****• ·•*+•* +***** ****** ****** ***C
-
EC -36 7 SURROGATE 1979 FEB
Y, 22
121 DEG F (0.'t5, C.ll
CLOCK TIME
ELAPSED T(MIN)
co PPM
PAN PPM
hCHO PPI'
ACETALD PPM
PROPALD PPM
ACETONE PPM
MEK PPM
METHANE PPM
ETHANE PPM
ETHENE PPM
ACETVLEN PPM
PROPANE PPH
PROPEN PPM
l,,)
0
"'
a20 a30 900 915 9.:JO 945
1000 lOl5 1J30 lv 1t5 llOJ 1115 1130 ll 't5 1200 1215 1230 ll45 1300 1315 1330 1345 1400 1415 1430 1445 1500
-40. -30.
tl. 15. 3 o. 45. 60. l';j. 90.
l 0 5. 12J. 135. 15 o. 16 5. 18 o. 19 5. 21 I), 22 5. 24v. 2 55. 27 o. 2 us. 3 oo. 315. 330. 345. 360.
****** ****•*
0. 't 6 ****** ****** ******
0.50 ****** ***~** ****"'*
0.65 ****** ****** ******
0.73 ****'** *,c,.**** ******
0.Btl ****** ****** ******
0.86 ****** ****** ******
1.02
****** ****** u.o
****** o.o
****** o.o
••***• 0.000
**'lII*** 0.0985 ****** ****** o. 086 4 *****• ****** 0.0732 ****** ****** o.osua ****** >II+**** o.usoz ****** "'***** o.J405
0.0031i ****** 0.1)035 ****** ****** 0.0012 *****4< ****** 0.0074 ****** ****** 0.0080 >lI
****** lilI1 *···· * ·••*** ···••* ****** o.Ol.181 o.uoos "'***9* ··••**•••••• ***•*• 0.0076 1).1)005 ··••* ... ••••••.......··••** 0. l)i; 1lt c.oocz··••>1
-
EC -36 7 SURROGATE V, 121 DEG F IO .45, C.l) 1979 FEB 22
CLOCK TIME
ELAPSED T(MlN)
l-C4 PPM
N-C4 PPM
T2-C 4 .. pp,-
CIS2-C4= PPM
2ME-C4~2 PPM
2,3-DMB PPM
N-C6 PPM
TOLUENE PPM
M-XYL PPM
820 830 900
-40. -30.
o.
0.0001 ****** 0.0001
0.016a *****• O.C339
c.occ2....... c.occ2
0.0026 ****** 0.0026
0.0026 ****** 0.0021
o.Oll3•••••• 0.0109
0.0101 ****** 0.0096
0.001 ****"*
O.Ou3
0.0010 ••**** 0.0010
915 930
15. 3 o.
****** ******
****** "****•
****•*......... ****** "'***** ****** ****** ******· ****** ****** ****** ••**** ****** ****** *****· 945
1000 1015
45. 6 o. 15.
0.0002 ****** ****••
0,0316 >1'+**'4"1
*****•
o.c·••+••....... 0.0001 ****•* ****** o.o "'***** ****** 0.0097 *****• ****** 0.0084 ****** *****>I< 0.003 ****H' ****** 0.0049 *•**** ****"'*
1030 1045 ll 00
90. l O 5. 12 o.
0.0001 ****** ******
0.0293 ****•• ******
c.o................. c.0002 ****** "'***** o.o ****** ******
O.OOd3 ****** ****•*
O.OOH ****** ******
0.002 ****** ******
0.0029 ****** "'*****
1115 1130 1145
135. 150. l 6 5.
0.0002 ****** *****•
0.0210 *****• ••***•
o.c ~ ... ,. .. * ........
o.o ****** ******
o.o ****** ******
0.0012 **"'*** ******
0.0066 *"'"'*** •·****
0.002 ****** ******
0.0011 "'***** ******
1200 1 8 o. 0.0001 0.0252 c.o c.o o.o 0.0061 O.Ou55 0.002 0.0010 w 0 -..J
1215 1230 1245 1300 1315 1330 134, 1400 1415
19 5. 21 o. 22 5. 240. 2 5 5. 2 10. 2 85. 300. 315.
•***** *"'**** o.oooi ****** ****** 0.0001 ****** ****** 0.0001
.. >1• •••****** .. ......•***** 0.0230 c.c.~ .....••**** •***** •••••• 0.020c o.c....... ........ .. .... ...•****>I C.0194 c.o
****** ****** o.o ****** ***"'** o. o •****• ****** c.o
****** ****** o.o *****· ****** o. 0 . **"'*** ****** o.o
****** ****** 0.0054
***>I
-
L
{
EC -367 SURROGATE Y, 121 OEG f (0.45, c.u 1979 FEB 22
CLOCK EL AP SEO TS SSPOWE~ PAD ICM HCHll VOL TIME Tl MIN) DEG f KW ~II/C1"2
820 -40. ****** ****** •••••• ******.......830 -30. ****** •••••• **"'**• 900 o. 119.2 16. 35 C.15S 20.00 915 15. 121.4 •••••• •*** ,,.... ****** 930 30. 121.9 •••••• •••••• *-!O C. H9 •••••• 1345 285. 12 5. 1 ****** c.1n ****** 1400 300. 126.0 16.50 0.151 ****** 1415 315. 126.0 ****•• •••••• 20.00....... .......1430 330. 125.3 ****** 1445 345. 126.0 0.154****** ****** 1500 360. 125. l 16.80 0.151 20.00
-
EC -367 SURROGATE Vi 121 DEG F L0.45, c. u 1979 FE8 22
CLOCK TIME
ELAPSED TlMINI
N02 PPM
N02 PPM
NC.)I PP/I
NOX PPM
TOT N03 PPM
TOT N PPM
HCTOT PPHC
820 830 900
-40. -30.
o.
****"'* ******
0.038
*"'**** *****• 0.038
•~**** •~****
a.• 119
****** ****** 0.11 7
*****Ii< ****** o.o
****** ****** 0.119
.I.• 508 ******
1.561 915 l 5. C.05C 0,052 c. 120 0.11 7 o.o 0. 117 ****** 930 30. Q.070 C.C67 0.127 0.118 o.o 0.127 **"'*** 945 4 5, 0.079 a.oat c.120 a. 11 a o.o 0.120 1,794
1000 6 0 • o.oH 0,091 C,1C8 o. 11 a o.o 0,108 *"'**"'* 1015 75. 0.079 0.101 0. 105 0.11a 0.000 0.105 ****** 1-)30 1045 1100
90. 105, 12 o.
o.oa1 0.083 o.oa2
C.106 0 .112 0.114
C. l C3 c.1co C. C'i8
0.119 0.121 0.122
0.000 0.001 0.001
0.103 0.101 0,099
1,739 ****** ******
ll 15 13 5. o. 079 o. 11 7 0.0
-
fC -368 SURROGATE Y, 1979 FEB 23
48 GEG F (0.45, u.lt
BEGIN IRRADIATION 0900; 0.25 11\Ch f~REX FILTER; TRICHROIC NOX INJECTED PRIOR TO PURE AIR FILL U!ING EC VACUUM RACK BRADY 292i DASIBI 1212; TECO 148-1 & TECO 146/E USED BECKMAN 6800 ON MANUAL OPERATION; CO fACTORa l.6/12.4
FILTER OUT
T•O AT 900 PST
PAN HCHO
REL INT
CALIB# 12
3 4
SPECTRAL DISTRIBUTION WAVELENGTH(NM) REL. INTENSITY
w I-' 0
TS REL HUM SSPOWER RADIOM
H20 NO
N02-CORR co
HCHO ACETALD PRO PALO ACETONE METHA;,,jE ETHANE ETHENE
ACETYLEN PROPANE PROPENE
N-C4 Cl S2-C4a 2ME-C4=2
2,3-0MB N-Co
TOLUENE M-XYL
DEG K i
KW MW/CM2
PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM
AVERAGE AVERAGE AVERAGE AVERAGE AVERAGE INIT CGI\D IN IT COND IN IT CGNO INIT COND I NIT CCI\D INIT CQI\O INIT CCND INIT CCNO !NIT CONO INIT CCND INIT.COI\O IN IT CONO INIT CCI\D IN 1T CGI\O INIT COND INIT CONC INIT CONO INIT CONO I NIT CONO INIT CONO
281.9 28.90 H .01 0 .153 1. l3CE C.C68 O.C~3 0.252 o.coa 0.152 O.C03 O.C06 1.c51 O.Cl6 O.COl: o.c12 o.cca o.cc2 C.C31 o.co2 o.coz 0.010 O.C09 O.C03 O.C07
03•
500. 430. 403. 380. 370. 360. 350. 340. 330. 320. 310. 300. 290.
2.229 1.904 1.724 l.560 1.376 1.113 1.000 0.812 o.551 0.295 0.108 0.010 o.o
• ASSIGNED INITIAL CONDITION Kl•0.38 MIN-1 SAMPLING RATE• 2.286 L/HIN
44 GC SAMPLES TAKEN
-
EC -368 SURROGATE V, 48 CEG F {0.45, O.l) 1979 FEB 23
CLOCK ELAPSED OZONE NO NO N02-CORR N02-CORR NOX-CORR NOX-CDRR Tl HE T( MlNl PPM PPM PP/I PPM PPM PPM PPM
a.w 830 900
-40. -30.
o. ••••••••••••
0.000
t 143-U..... ,.••••••
0.068
ll4BIEJ >tU+•+... ,...
C.Ct9
'148- 1)••••••****** 0.033
tl4B/EJ••••••****** 0.033
( l4B-U
••••••******
0.102
ll4B/EJ••••••••••••
0.102 915 15. 0.000 0.068 c.02 0.022 o. 028 0.110 0.100 930 30. 0.002 0.068 0.068 0.031 0.030 0.099 0.098 945 4 5. 0.005 0.068 o.ou o. 030 o. OB 0.099 0.097
1000 6 o. 0.001 0.068 C.C60 0.034 0.035 0.102 0.094 . 1015 7 5 • 0.001 0.061 O.C56 0.03
-
EC •·H,8 SU,tiWGATE v, 48 CEG f ( 0 .4 5, o.u 1979 FEB 23
CLOCK ELAPSED co PAN t-Cl-0 ACETALD PROPALO ACETONE MEK METHAf\E ETHANE ETHENE ACETYLEN PRCPANE Pr.OPEN£ TIME T(MIN) PPM PPM PP/' PPM PPM PPM PPH PPM PPM PPM PPM PPH PPM
H20 H 3U ',100 915 930 9 1,5
l0U0 1015 l0J0 1045 1100 1115 llJ0
l,Jll 45 !-'121.lO Nl215
12)0 1245 1300 1315 1330 13 1,5 1400 1415 1430 1445 1500
-4v. -30.
o. 15. 3J. 45. 6U. 15. 90.
lOj. 120. 135. 15 o. 16 5. 1 ti tl. 195. 21 o. 22 5. 240. 2~5. 270. 205. 300. 315. 330. 345. 3b0.
***"*· ******
0.25 ****** ·•'III* •••••• >1o+••·· o.o •••••• ****** ••**** ****** 0.146{; o.oao o.ccu ******
****** *****"' ****** 0.001 0.1314••••••
• ***'~. •••••• •••••• 0.00 l 0.010 ******
**"'**• C.1208•••••• 0.001 ....... ****"'* .,... ,. ..****** ***"'** 0.002 O.OG6 0.1 ~60
****** •••••• ****** 0.002 ..... ... . ...***"'
·••-"*. • • ""* •• 0.1150 0.003 o.ocu -******
**,>.•·· •••••• **"'*"'* 0.003 O. l 061••••••,. ..... ........****** 0.004 0.013 ******
*****• 0.078 l****** 0.004 •••••• ******
****"'* •••••• ****** 0.004 0.013 0.0912
****** 0.0030 0.0033 *****"' ****** 0.0039 ****** ****** 0.0035 ****** ****** 0.0044 ****** ****** O.U04U ****•* ****** 0.0047 ***"'** ****'"I' 0.0048 *****"' *"'**** 0.0042 ******....... 0.0046
•••••• 0.0069 0.0050
••••••**"'*** 0.0069 ****** ***"'*"' O.OOU't ***••· ****** O.OOU5 ****IIO* ****** O.UO'J4 ****** •••••• 0.0099 *·***** ****"'* 0.0109 *****· ****** 0.0096 ****** ****** ****"'*
•••••• 0.0002 0.0002•••••••••••• 0.0002 ••.ia****>1lo*****•••••• ****** "'***** o. 0152 *** .. ** "'***** ..........•*"'***•••••• O. Cl SL ****** ****** •••••• ••••••
0.0155•••••• ***"'** ****** •••••• ••>1
-
EC -368 SURROGATE Y, 48 CEG f I0.45, 0.11 L979 FEB 23
CLOCK TlHE
ELAPSED TlMlNl
I-C4 PP~
N-C4 PPM
12-c 4 .. ppj,1
CIS2-C4• PPM
2ME-C4~2 PPH
2,3-0HB PPM
N-C6 PPM
TOLUENE PPM
M-XYL PPM
820 ll30 900 915 930 945
1000 1015 1030 1045 1100 ll 15
-40 •. .,.30.
o. 15. 30. 45. 60. 1-;. 'JO.
105. 120. 135.
0.0001 ***"'** 0.0002 ****** **••·· 0.0001 ****'°'* •***"'· 0.0001 ****** •***•* c.0001
0.0311 **"'*"'* 0.0300 ****** •••••• 0.0299 ****** ****** 0.0209••••••........ 0.0284
c.ooc2 0.0025 •o ♦ •U •"'****c.ooc1 0.0023•••••• •***** ***"** "'***** o.c 0.0018•••••• ******.... ,.,. ****** o.o 0.0011..... ,. . ****** ****** ****"'* c.o 0.0006
o. 0023 ***"'** 0.0023 ****** ****** o.oooe ·••*'°'* *****"' 0.0004 ****** ****"'• 0.0002
o. 0103 ••**** 0.0091 ****** ****** 0.009a ****** ****** 0.0088 ****** **""*** 0.0086
****** ••••••0.0089 ****** ****** 0.0079 **>ii***........ 0.001a ****** ••*•** ******
••••••0.003 0.003
••••••******
0.003 ***"'** ···••*
0.003 •*•*** ****>Iil*>il*>il* ****"* 0.0047 *****"'....... 0.0038
w 1--' w
1130 lL 45 1200 1215 1230 1245 1300 1315 1330 1345 1400 1415 1430 1445 1500
150. 165. l 8 o. 195. 2LO. 225. 240. 2 5 5. 2 70. 2 tlj. 300. 315. :no. 345. 360.
****** ****** 0.0003 *****" *****• 0.0002 •***** ,.. ..... 0.0001 ****** "'***** 0.0001 *****• *****"' 0.0000
***••· ****>II• O.C273 •**** .. •****• 0.0263 "'***** •••••• 0.0253 *****• •****"' 0.024S••••••*****"' 0.0241
****•••••••• o.o••••••.. ,., ... o.c........ *•**·•· c.o...... • ***.,. o. o·••••••.. ,.. ... o.o
****** ****** 0.0002 ****** **"'*** 0.0002 ··••** *****• 0.0001 ****** •***** a.a •***** ****** a.a
*****• ****** o.o ****** •••••• o.o *'°'**** •***•* o.o ****** **"'*** o.o •***** *"'**** o.o
*****'"' 111••*** O.OOll3 ****'°'* *•**** 0.0011 *"'***• **"'*** o.ooH · ****** *****• 0.0068 ****** ******· 0.0066
****** ••**** 0.0076 •**•** ****** 0.0073 *****" **"'*** 0.0068 *"'**** ****** O.OOo't ****** ***>ii**0.0060
****** ··••*• 0.002
····•*........ 0.002.......
***•** u.002
****** ****** 0.001
****** ****""• 0.002
*****>II***""*>II 0.0031 ****** **"'*** 0.0025 ****** ****** 0.0022 ···*•* ****** 0.00!2 ***>ii•******* 0.0015
-
,··
EC -368 SURROGATE V, 48 CEG F 40.45, O.lJ 1979 FEB 23
CLOCK ELAPSED TS REL HUI" SSPCliiER RAD IOM HCHO VOL Tl ME TlMIN) DEG F :c Klii t!w/CM2 L
w I-' .i:--
820 830 900 915 930 945
1000 1015 1030 1045 1100 1115 1130 1145 121)0 1215 1230 1245 UuO 1315 1330 1345
-40. -30.
o. 15. 30. 45. 60. 75. 90.
105. 120. 13 5. 150. 165. 180. 195. 210. 225. 240. 255. 27 o. 285.
****** ••••••43.2 4 7. l 47.4 48.l 47.9 48.l 48.l 48.6 48.6 48.9 48.4 48.6 48.4 48.4 47.6 47.4 47.4 47.9 47.4 47.6
•••••••••••• 28.5 29.0 29. 0 29.C 29.5 29.0 29.C 29.0 29.0 28.5 28.5 28.5 28.5 29.0 29.C 29.0 29.0 29.0 29.C 29.0
•:e••·· ••****
16.14••••••••••••••••••
16.14••••••••••••••••••
16 • C6•••••• "'***** ••••••
16. 19••••••••••••
15.S8····•*••••••••••••.,.....
........ ••••••
0.150 0.151 0.156
****** 0.156
****** ****** ******
0.151 ****** ••••••****** 0.156
•••••••••••••••••• 0.15'1
•••••• 0.14!i 0.151
****** ******
20.00 ****** ,jl>jl,je···
****** 20.00
****** •••••• ******
20.00 ****** ****** ****** 20.00
****** ****** ****** 20.00
****** •••••• ******
1400 1415 1430 1445
300. 315. 330. 345.
4 7. 4 47.1 47.l 47.9
29.0 29.0 29.G 28.5
15. 74 ,.,..... ••••••.,.....
0.14c;
••••••••••••••••••
20.00 ***Ci*"'••••••*****>ll
1,00 360. 47.l 29.0 15.1«; 0.156 20.00
-
EC -368 SURROGATE Y, 48 CEG F (0.45, C.lJ 1979 FEB 23
CLOCK ELAPSED N02 N02 NO~ NOX TOT N03 TOT N H20 HCTOT TIME HMIN) PPH PPM PPI' PPH PPM PPM PPM PPMC
820 830 900
-40. -30.
o. ••••••****** 0.033
..... ,. ******
0.033
•~*••·....... 0. l C 2
******••••••0.102
****** ••••••o.o **•***••••••
0.102
••••••***•*·
2718.
1.832••••••
1.825 915 15. 0.022 C·. 02 8 c.110 0.10c o.o 0.09ll 3198. ****** 930 3 o. 0.031 0.030, 0. CS9 0.098 o.o 0.099 3227. ****** 945 45. 0. 031 0.033 C. Cli S 0.097 0.000 0.099 3316. l. 7 8 8
1000 6 o. 0.034 0.035 O.lC3 0.095 0.000 0.103 3343. *****"' 1015 75. 0.040 0.036 c.1c1 0.092 0.000 0.101 3316. *****• 1030 104 5 1100 1115
90. 1 us. 120. 135.
0.040 0.042 0.043 0.049
0.040 0.041 0.043 c. 045
0.050 c.csz c.oso o.cs3
0.095 0.00s 0.087 0.086
0.001 u.001 0.001 O. GOl
0.102 0.093 0.090 0.093
3316. 3376. 3376. 3348.
1. H5
•••••••••••• l. 719
1130 1145
15 o. 165.
0.046 0.046
0.046 0.0'18
c.oa8 C.Oc6
0.084 0.083
o. 001 0.001
o.oaa o.o 86
3288. 3318 •
******•••••• 1200 18 o. 0.040 0.049 O.GE5 0.082 0.002 o.ou5 32U8. 1.111
w ......
1215 1230
195. 21 o.
0.0'19 o. 043
0.04S 0.050
a.cu O. Gel
o.oao o. 07 8
0.002 0.002
0.005 0.002
33'16. 3257. ••**•******•
LI\ 1245 22 5. 0. 0 5 6, 0.052 C.CE7 0.07':i 0.002 0.08d 3227. lobll6 1300 240. 0.050 0.051 C. C Hi 0.075 0.003 0.079 3227. ****** 1315 2 55. C.050 0.052 c.e1a 0.074 o. 003 0.078 32 86. ****** 1330 27 o. 0.049 0.04S o.o,6 0.076 0.003 0.011 3227. 1.662 1345 2 85. 0.04'3 0.051 a.OH 0.012 0.004 0.075 3257. ****** 1400 3 oo. o.049 0.052 O.OH 0.010 0.004 0.075 3227. ****** 1415 315. 0.052 0.052 0.015 0.06~ 0.004 a.on 3l'ilU. 1.586 1430 330. O. 04S 0.051 C.013 0.067 0.004 a.on 3198. ****** 1445 345. 0.050 0.051 C.072 0.066 0.004 0.012 3229. "***** 1500 360. 0.049 0.050 O.O'lO 0.064 o. 004 a.on 3198. 1.616
"
-
( ',
EC -369 ALKANES, 45 OEG f 13.0, 0.21 1979 fE8 26
BEGIN IRRADIATION 0845; C.25 1r-;CH F~RE) fllTERi TRICHROIC FILTER OUT NOX INJECTED PRIOR TO PURE AIR fill USING EC VACUUH RACK. CO FACTOR; l ■ 6/5.4; 8~CKMAN 6.00 Cl\ HANUAL QPElATION . BRADY 292; DAS161 1212, TECO 148-1 & lECO 1•a/E USED
T=O AT 845 PST
CALIB# PAN 12
HCHO 3 REL INT 4
SPECTRAL DISTRIBUTION WAVELENGTH(NM) REL. INTENSITY
TS DEG K AVERAGE 28C ■ l 500. 2.326 w REL HUM i AV ERA GE 32.85 430. l.936 I-' SSPOWER KW AVEHAGE H .15 403. 1.110
°' RAD IOM MW/CM2 AVERAGE 0. 15 i 380. l.539 H20 PPM AVERAGE 4.320E 03* 370. 1.373 NO PPH IN IT CONO C.137 360. 1.157
N02-CORR PPM INIT CONO O.C55 350. 1.000i N-C4 PPM IN IT CCND 1.416 J40. 0.791 ' ! NEO-C5 PPM INIT CCNO l ■ :?'i 1 330. o.533
HCHO PPM INIT cor.o O.Cll 320. 0.285 ACETONE PPM IN IT CCNO o.co1 310. 0.102
MEK PPM INIT .COI\D 0.002 300. 0.001 METHANE PPM INIT CONO l.H9 290. o.o ETHANE PPM HUT CGND O.C03 ETHENE PPM 'INIT CGNC o.co2
ACETYLEN PPM INIT CCI\D a.CO2
ASSIGNED INITIAL CCNDITlOt\ Kl• O. 38 KIN-1• SAMPLING RATE• 2.290 L/MIN
50 GC SAMPLES TAKEN
-
EC -369 ALKANES, 45 DEG f (3.0e 0.2) 1979 FEB 26
CLOCK ELAPSED OZONE NO NO N02-CORR N02-CORR NOX-CORR NOX-CORR N-C4 NEO-C5 TIME TtMINI PPM PPM PPI' PPM PPM PPM PPM PPM PPM
815 825
-30. -20.
••••••......... Cllitl-1) *****• ******
llliB/E)....... ......... ( lliB- U ****** ****** tl4l:i/E I *•**** ****"'* I 148-U *•****.,...... t lli8/fl ****** ·····* l.3~ 1.43 l.33 1.40 845 o. 0.000 0.131 c. !;'i 0.055 O.O't9 0.19.:! o.un 1.42 l .J9 900 15. 0.002 0. l 3'i C.127 0.051 O.O't9 0.189 0.185 1.42 1.1io 9t5 930
3 o. 45.
0.002 0.002
0.12s 0.123
o. LH C. lB
0.057 o.064
0.054 0.061
0.186 o.1ac:.
0.185 0. 18'1
1.36 1.34
1.34 1.37
945 60. o. 007 0.111 0.117 0.073 0.004 0.189 0.181 1.37 1.36 1000 7 5. 0.001 0.111 o. 111 0.010 0.068 0.181 0.171! 1. 37 1.35 1015 90. 0.001 0.101 O. lC5 0.0H o. 0 74 0.181 0.179 1.36 1.34 1030 l O5. 0.001 0.102 C.CS9 0.076 0.011 0. 1 7tJ 0.175 1.31 1.31 1045 12 o. 0.010 0.096 0. C'i 5 0.001 0.079 0.176 0.174 1.34 1•.n 1100 1115 1130
13 5. 150. 165.
0.010 0.012 0.012
0.092 C.088 o.oa8
0.(89 C.Cc3 o.c19
0.083 o.oa6 0.091
0.083 0.087 0.090
o. l 76 o. l 74 0.179
o. !72 0.110 O.lb9
1.33 1.32 1.31
1.32 l. 31 1.31
w ...... ---J
1145 1200 1215
180. l 95. 2 lo.
0.015 0.011 c.020
0.082 0.076 0.073
0.(15 o. Ct'i a. Cc6
0. 09b 0.093 0.095
o. 091 0. 094 0.095
0.111 0 .168 0.161
0.166 0.164 o. 1.6 l
1.31 1.28 1.28
1.30 1.29 l • 28
12 30 225. o. 02 o·· 0.070 0.061 0.097 0. 097' O.l6b 0.158 1.2a 1.28 1245 240. 0.022 0.066 0.058 0.098 0.099 0.164 0.157 1.26 1.n 1300 255. 0.024 o. 063 O.C56 0.105 0.100 0.167 0.156 1.25 1.25 1315 1330
270. 2 85.
o.021i 0.029
0.059 0.058
0.052 O.C49
0.100 0.101
0.102 0.104
0.15a o.1sa
0.155 0.152
1.25 1.24
1.25 1.25
1345 300. 0.032 0.056 a.OH, O.C99 0.103 0.155 0.150 l. 2.3 1.24 1400 315. 0.032 0.051 0.043 0.102 o. 104 0.152 0.147 1.22 1.23 1415 330. 0.037 0.048 0.041 o. 103 0.105 0.151 0.145 1.21 1.22 1430 345. 0.031 0.049 C.C38 o.101i 0.104 0.153 0.141 1.21 1.23 1445 360. 0.039 0.045 0 .036 0.102 0.105 0.147 0.14~ 1.20 1.21
' !.
-
•••••• • ••••• • ••••• •••••• •••••• • ••••• • ••••• •••••• • ••••• • •••••
•••••• •••••• • •••••
•••••• • ••••• •••••• • •••••
• ••••• •••••• •••••• • ••••• • ••••• •••••• •••••• • ••••• • ••••• • ••••• ••••••• •••••• • •••••
EC -369 ALKANES, 45 DEG F (3.0, 0.21 1979 FEB 26
CLOCK ELAPSED co PAN ~CH( ACETONE MEI< C4-N-2 METHANE ETHAl'iE ETHE NE ACETVLEN TIME T(HIN) PPM PPM PPfl PPM PPM PPM PPM PPM PPM PP/1 ........815 -30. ****** •••••• •••••• •••••• ****** •••••• •*ioc••· ****** ···••* (PN) 825 -20.
845 o. •••••• o.o G.Cl7 0.0014 0.0019 o.o 1.22 0.0029 0.0022 0.0019 900 15. *"'**** •••••• •••••• •••••• ***"'"'* •ioc••·* ****** •••••• ****** ****** 915 30. ****** o.o •••••• O.OOH 0.0052 0.0005 •••••• •••••• •••••• •••••• 930 45. •••••• •••••• •••••• •••••• •••••• ****** •••••• ....... •••••• ••••••.......945 b O. 0.76 o.o 0.01c 0.0069 O.OOlll 0.0011
1000 75. •••••• •••••• •••••• •••••• +9•··· ****** •••••• •••••• •••••• •••••• o.o 0.0012 0.00101015 90. •••••• ....... 0.0100 •••••• •••••• •••••• •••••• 1030 105. .......•••••• •••••• •••••• +cc**** ****** ****** •••••• •••••• •••••• lu45 12 o. o. 71 0.000 c.oca o.ooss o.ouo u.0010 1100 135. .. .......•••••• •••••• •••••• ****** •***** ****** •••••• ***"'** ****** 1115 150. •••••• 0.000 ........ o.oos2 o. 0158 0.0021 ****** ****** ....... •••••• 1130 16 5. •••••• •••••• •••••• ****** ****** •••••• •••••• ....... •••••• .,,.... 1145 18 o. 0.11 0.000 C.017 0.0087 0.0187 O.UJ25 •••••• ****** •••••• •••••• 1200 195. •••••• •••••• •••••• •••••• ****** ****** ****** ****** •••••• •••••• w 1215 210~ •••••• 0.001 ....... O.Oll't 0.0212 0.0029 •••••• •••••• ****** ••••••..... .. ...... .......00 1230 225. •••••• •••••• •••••• •••••• •••••• •••••• •••••• **••··1245 240. 0.11 ' 0.001 c.c1c 0.012c 0.0241 0.002a •••••• ....... •••••• ••••••.......1300 255. •••••• •••••• •••••• ****** •••••• •••••• *****• •••••• •••••• 1315 270. ••**** 0.001 •••••• 0.0151 0.0258· 0.0032 ....... •••••• •••••• ....... 1330 2 85. 1345 300. 0.1c c.001 o.cn 0.0121 0.028.3 0.0038 ....... 1400 315. •••••• •••••• •••••• ****** ****** •••••• •••••• ****** ••••••
330. •••••• •••••• 0.0129 ···•··~ 0.0040 •••••• . ....... .......1415 0.001 0.0310 ........ 1430 345. •••••• •••••• •••••• ****** •••••• •••••••• •••••• ****** ••••••♦ ¥····1445 360. 0.1a 0.001 0.015 0.0150 0.0319 O.OOH 1.22 0.0022 o.oou, O.OOh
-
•••••• •••••• •••••• •••••• •••••• •••••• •••••• •••••• •••••• •••••• •••••• •••••• ••••••
••••••
•••••• • •••••
• ••••• ••••••
•••••• ••••••
• ••••• L
EC -369 ALKANES, 45 DEG F (3.0, Oo2l 1979 FEB
CLOCK ELAPSED THIE HMIN)
815 -30. 825 -20. 845 o. 900 15. 915 30. 930 45. 94 5 60.
1000 75. 1015 'Jo. 1030 105. 1045 12 o. 1100 135. 1115 150. 1130 165. 1145 180. 1200 195.w
I-' 12 l 5 21 o. \D 1230 22 s.
1245 240. 1300 25 5. 1315 2 70. 1330 2 85. 1345 300. 1400 315. 1415 330. 1430 345. 1445 360.
26
TS DEG F
41.C 44.5 45.2 45.·2 45.4 45.7 45.7 45.4 45.7 45.4 45.9 45.7 45.7 45.7 45.4 45.4 45.7 45.9 45.9 45.9 46.2. 46. 2. 46.2 46.2 45.4:l
REL HUM t
32.5 33.0 33. 5 33.5 33.C 33.0 33.C 33.0 33.0 33.0 33.0 33.
-
EC -369 ~LKANES, 45 DEG F (3.0, 0.2) 1979 FEB 26
CLOCK TIME
ELAPSED rt Ml NI
N02 PP/'.
N02 PPM
NO)( PPN
NOX PPM
TOT N03 PPM
TOT N PPM
. H20 PPM
HCTOT PPMC
815 825 045 900 915 930 945
1000 1015 1030 1045 1100
-30. -20.
o. 15. 30. 45. 60. 75. 90.
l 05. 120. 135.
••••••****** 0.055 0.051 0.057 0.064 0.074 0.011 0.010 0.078 0.083 0.085
•••••• ******
0.04c; O.C4S 0.055 0.062 0.065 0.00c; 0.076 0.07'i 0.0111 C.085
•••••••••••• o. l':i2 c.1so c. lf6 0.1n o.1s1 G.H2 C.1E2 c.ieo 0.1111 C.118
••••••••*"'**
0.187 0.186. 0.185 0.185 o.1a2 0.180 O. 18C 0.111 0.175 0.114
****** ****** o.o 0.000 0.001 0.001 o. 001 0.001 o. 002 0.002 0.0112 0.002
******· ******
0.192 0.190 0.187 o.ld8 0.191 o.1a3 0.183 0.180 0.179 0.178
••••••******
2853. 3294. 3436. 3436. 3416. 3447. 3447. 3410. 3447. 3416.
•••••••••••• 13.878••••••13.433 ****** 13.580•••••• 13.448•••••• 13.341••••••
1115 1130
150. 165.
0.088 o.094
o.oac; 0.092
O. ll6 O. l E2
0.112 0.111
O.OOl o. 002
0.176 o.1u2
3479. 3447.
13.166 ******
I.,.)
N 0
1145 1200 1215 1230 1245
180. 195. 210. 225. 240.
0.099 0.096 0.099 0.100 , u.102
0.094 0.097 C. C9'i 0.101 0.102
C. lE0 c.1 H C. 11 C c.110 0.167
0.16S 0.16 7 o.165 0.162 0.160
o. 003 0.003 o. 003 0.003 o. 003
0.180 0.112 0.111 0.110 0.168
3447. 3447. 3416. 3364. 3395.
13.074•••••• 12.935•••••• ll. 173
1300 2~5. 0.100 0.104 C.170 0.15'i 0.004 0.171 3426. ****** 1315 1330
210. 2 85.
0.104 0.106
0.106 0.100
C.162 C.163
0.159 0.157
0.004 0.004
0.163 0.101
3426. 3426.
12.652••••••
1345 1400 1415 1430 1445
300. 315. 330. 345•. 360.
0.104 0.107 0.10a 0.109 0.101
0.100 0.10c; 0.110 0.110 0.110
C.lc0 C.157 0.156 0.158 0.153
O. l5't 0.152 0.15c 0.147 o.147
0.005 0.005 0.005 0.006 0.006
0.16.) 0.158 o.1so 0.159 0.153
3457. 3457. 3457. 3457. 3'e26.
12.576 **lj
-
EC -370 ALKANE s. 19B FEB
124 DEG 27
F 13 .o, 0 .2)
BEGIN IRRADIATION 0900; 0.25 IhCr P~REX FILTER; TRlCHROIC flLTER NOX INJECTED PRIOR TO PURE AIR FILL U~ING EC VACUUM RACK LESS THAN l PPB Of N-BUT~L NITRATE OETECTEC LESS THAN l PPB Of HETH'wL NITRATE JiT T"6 RH OF FILL 15% AT 85 DEG F FOR A PRECICTED 5; RH AT 125 DEG F BRADY 292; OASIBl l212; TECO 148-1 & TECO 118/E USED BECKHAN 6800 ON HANUAL OPERATION; CO FACTOR: l ■ b/12.35
OUT
T•O AT 900 PST
PAN HCHO
REL INT
CALlB# 12
3 4
SPECTRAL DISTRIBUTION WAVELENGTHlNHJ REL. lNTENS l TY
l.,.) N ..... TS
SSPOWER RADIOM
H20 .REL HUH
NO N02-CORR
N-C4 NEO-CS
co HCHU
ACE TuNE MEK
. ME THANE ETHANE ETHENE
ACETYLcN TOLUENE
DEG K KW
HW/CM2 PPH ~
PP/J. PPH PPH PPM PPM PPM PPM pp M PPM PPM PPM PPM pp H
AVERAGE AVERAGE AVERAGE AVERAGE AV ER AGE lNIT CONO IN IT CCND lNlT CONO IN IT CONO INlT CONO !NIT COhO INIT crno INIT cor-.o lNIT ccr-.o INIT COI\O IN IT CCt\D IN IT CChD lNlT CONO
324.4 H .37 0.145 5.lSOE s.ccc 0 • 15 7 0 • C62 l.~50 1.55C O. l67 o.co2 0.006o.co1 1.101 O.C03 a.CO2 a.CO2 O.Cl4
03••
+
500 • 430. 403. 3BO. 370. 360. 350. 340. 330. .3ZO. 310. 300. 290.
2.111 l. ll82 1.6137 la52b 1.346 1.124 1.000 o.793 0.528 0.283 0.098 0.007 o.o
* ASSIGNED INITIAL CCNOITIOt\ Kl 11 0.38 HlN-l
SAMPLING RATE - 2.289 L/HIN
49 GC SAMPLES TAKEN
-
EC -370 ALKANES, 124 DEG F (3.0, 0.2) 1979 fEli 27
CLOCK TIME
tl32 900
ELAPSED TOIIN)
-28. o.
OZONE PPM
••••••0.000
NO PPM
( 148-U
••••••0.157
NO PPI'
(148/EJ
•••••• C.160
N02-CORR PPM
(148-lJ
****** 0.062
N02-CORR PPH
t148/EI
****** O.Ob3
NOX-CORR PPM
( 148-1)
****** 0.219
NOX-CORR PPM
(148/El
****** 0.222
N-C4 PPM
1.55 1.55
NEO-C5 PPM
1.56 1.55
915 930 945
15. 30. 45.
0.007 0.012 0.029
0.122 o.oa1 o. 067
0.1.a o.oe4 C.G56
0.095 0.133 0.143
0.102 0.139 O.l61i
o.21o 0.220 0.209
0.223 0.223 0.224
1. 52 1.49 1.49
1.53 1. 52 1.52
!000 1015 1030 1045
60. 75. 90.
105.
0.046 0.011 0.103 0.137
C.043 0.02,; 0.021
. o. 016
C.CD c.020 o.c12 O.OG6
0.111 0.173 0.176 0.110
0.190 0.200 0.20& 0.215
0.213 0.201 0.197 0.199
0.223 0.221 0.220 o. 221
1.47 1.46 1.45 1.42
1.51 1.50 l.49 1. 47
1100 1115 1130
120. 13 ;. 150.
0.173 0.213 0.249
0.013 0.012 0.010
C.CC4 c.cc1 o.o
0 .161 o. 177 0.100
0. 216 o. 217 0.21s
o .194 C.ld9 O.l8d
0.220 0.218 0.211
l. 41 1.39 1.36
1. 't6 1.45 1.u
1145 1200 1215
165. 180. l 95.
0.291 o. 337 0.376
0.010 C.OG8 C.006
-0.0Cl -o.cc2 -G.OC3
0.179 o.1a1 0.17
-
• • •
N. 0
0
u. (,!) w 0
-1' N,_ -N
- criOU,W ,.._ w Ii. MZ I t!: ....
-
••••••
•••••• •••••• •••••• •••••• •••••• •••••• •••••• • ••••• •••••• •••••• •••••• •••••• •••••• •••••• • •••••
•••••• ••••••
••••••
•••••• ••••••
••••••
••••••
EC •370 ALKANES, 124 DEG F u.o, 0.21 1979 FEB 27
CLOCK TIME
832 900 915 930 945
1000 1015 1030 1045 1100 1115 ll30 1145 1200 1215 1230w
N 1245 .i,- 1300
1315 1330 1345 1400 1415 1430 1445 1500
ELAPSED HMlN)
-28. o.
15. 30. 45. 60. 15. 90.
105. 120. 135. 150. 165. 180. 195. 21u. 225. 240. 2.55. 270. 285. 300. 315. 330. 345. 360.
TS DEG F
****** 120.1 121.6 120. 4 121.4 122.1 123~1 123.8 124.3 125.l 125.3 125.l 126.0 126.5 126. 0 124.6 12 5. l 124. 6 , 125.3 124.3 125.l 124.3 124.3 124.3 '125.1 124.8
SSPOWEI-Kl
-
EC -370 ALKANES, 124 DEG F C3.0, 0.2) 1979 fE8 27
CLOCK ELAPSED N02 N02 NOll NOX TOT N03 TOT N HCTOT TIME TiMIN) PPM PPM PP/# PPM PPH PPM PPMC
ti 32 900
-2 a. o. ****** 0.062 •••••• 0.063 •o••* C.219 *****• 0.222 ****** o.o •••••• 0.219 •***** L5.090
915 15. 0.095 0.102 0.,11 0.223 0.001 0.211 *****"' 930 3 o. 0.134 C. 14 C c.221 0.224 o. 001 0.222 ****** 945 45. 0.145 C.170 0.211 o. 22 5 o. 002 0.212 ******
1000 1015 1030
60. 75. 90.
o. U3 0.176 b.181
0.192 C.2C4 0.213
0.215 C.2(5 C. 2C2
0.225 0.224 o. 22 5
0.002 0.00] 0.005
0.216 0.205 0.202
**"'*** lj
-
EC -371 SURROGATE Y, 1979 fcB 26
48 CEG f (2.2, O.C5)
BEGIN IRRADIATION 0900i 0.25 INC~ PYREX FILTER; TRICHROIC NOX INJECTED PRlCR TO PURE AIR fill USING EC VACUUM RACK BECKMAN 6800 ON MANUAL OPERATION; CO FACTOR: 1.6/12.S BRADY 292i DASISI l2l2i TECO 148-1 t lECO 148/E USED
FILTER OUT
T=O AT 900 PST
PAN HCHO
REL INT
CALIBM 12
3 4
SPECTRAL OISTRIBUTION WAVELENGTHlNtO REL. lNTENS ITY
I.,.)
N
"'
TS DEG K REL HUM t SSPOwER KW RAOIOM MW/CM2
H20 PPM NO PPl-4
N02-CORR PPM co PPM
HCHD PPM ACE TAL D PPM ACETONE PPM METHANE PPf,I ETHANE PPM ETHENE PPM
ACETYLEN PPM PROPANE PPM PROPENE PPM N-C4 PPM
T2-C4= PPM CIS2-C4= PPM 2ME-C4-=2 PPM CYCL-C5"' PPM
2,3-DMB PPM TOLUENE PPM
H-XYL PP/4
AVERAGE AVERAGE AVERAGE AVE!
-
EC -371 SURROGATE Y, 48 CEG F 12.2, O.C5) 1979 FEB 28
ClOCK ELAPSED OZONE NO NO N02-CORR N02-CORR NOX-CORR NOX-CORR TIME TIM!Nl PPM PPM PPI' PPM PPM PPM PP1\1
812 900
-40. o. "'***** 0.000
1148-ll
*****•0.033 1148/El ,. ,. **,. 11)
C.C29
1148-ll *****"' 0.025
114B/EI ******
0.016
I 14d-l) ******
o.u~B
1148/E) ******
0.044 9L5 15. 0.010 0.025 c.c20 0.030 0.022 0.055 0.042 930 3 o. 0.022 0.016 o.cco 0.037 0.030 0.053 o. 039 945 45. 0.037 0.011 O.OC3 0. 03 7 o. 032 0.047 0.035
1000 60. 0.051 0.000 c.oco o. 03 5 O.G29 c. 043 0.029 1015 75. 0.066 c.001 -o.oc2 0.031 0. 027 0.038 0.025 1030 90. 0.013 0.005 -C.OC3 0.029 0.023 0.034 0.020 1045 105. 0. 08 l c.005 -C.CC3 0.025 0. 020 0.029 0.016 llOO 12 0. 0.088 0.004 -O.CC4 o. 022 o. Oltl 0.026 0.013 ll 15 13 5. 0.095 0.004 -C.CC5 0.019 0.015 0.024 0.010 ll30 15 o. 0.098 0.004 -O.CC5 0,017 0.014 0.021 0,008 1145 16 5. 0,098 0.003 -O,CC5 0,016 0.012 0.019 0.001 1200 l 80, 0.100 0.005 -C.005 0.014 0,0ll 0.020 0,006 1215 19 5. c.100 C.006 -C,CC6 0,014 0.010 0.020 0,004 1230 210. 0,098 0,004 -C,OC6 0.015 0.010 0.019 0,004
l.,.l ll45 225. C.095 c.ooti -C.CC6 0.016 0.010 0.020 o.ooti N -...J l3JO
1315 240. 2 !> 5.
0,095 0.093
0.004 0,004
-C,CC6 -O.CC6
0.016 0.01s
0.010 0.010 ·
0.019 0.019
0.004 0.004
1330 2 7 o. c. 090 0,005 -o. CC6 0.014 0.010 0. ul ':.1 0.003 1H5 2 85. 0.090 0.005 -C.CC6 0.014 o.ooa 0.019 0.002 1400 JOO. 0. OtlB o.ooe -C.CC6 O.Cll 0.010 0.019 O.C03 1415 315. 0.088 0.005 -C,CC6 0.014 0.010 0.020 o. 003. 1.430 330~ o.oa6 0.006 -C.CC6 0.015 0.010 0.020 0.004 1445 345. 0.086 c.001 -C.CC6 0.013 0.009 0.020 0.003 1~00 360. 0.083 0.000 -0.CC6 0.012 0.000 0.01s 0.002
-
EC -371 SURROGATE 1979 FEO
v, 28
48 CEG f (2.2, O.C51
CLOCK TIME
ELAPSED T(MINl
co PPM
PAN PPM
1-'C~G PPI'
ACETALD PPM
PROF-ALO PPM
ACETONE PPM
MEK PPM
METHANE PPM
ETHANE PPH
ETHENE PPH
ACETYLEN 1-'PM
PRGPANE PPt'
PRJPENE PPM
w N co
!l 12 900 915 930 9,,5
1000 10 l. 5 lOJO 10 1t5 11 QO 1115 l lJO 1145 1200 1215 1230 1245 1300 1315 lH0 1345 h00 !415 1430 1445 1500
-48. o.
l .-:, . 30. 45. 60. 75. 90.
105. 120. 13 s. l '.>0. l t, 5. 180. 1. 95. 21 o. 225. 240. 255. 270. 2 U5. 300. 3 l 5. 330. 345. 360.
****** 1. 38
****** ***"'** ******
1.33 ****** ***"'** ******
1.30 ****** ****** ******
l.. 4 8 *"'"'*** ***•** "'*****
1. le 5 ****** ****** ******
l.51e "'"'**** ,c..,•••• * ******
1.57
•••••• o. 0
***•** 0.002
****** 0.005
•••••• 0.010
***I+
0. C29....... *••• ,.,. ,.,.....
C.023
***~*· o. 079 4 •'?'**** "'****"' o. 0343 **"'*** ****** 0.0329 ****** *"'•*** 0.0320 ***••· **>I
-
EC -3 71 SURROGATE ". 40 CEG F I 2. 2, O.C5) 1-,179 fE8 28
CLOCK ELAPSED I-C4 N-C4 T2-C4= CIS2-C4~ 2ME-C4=2 CYCL-C5~ 2,3-01'!8 TOLUENE H-XYL TIME T!H[Nl PP/o! PPM PPI' PPM PPM PPM PPM PPM PPB
812 -48. ****** o. 149 2 C.CCC4 0.0122 0.0101 0.0443 0.0469 0.014 0.0244 900 o. ••**** 0.1516 O.OCC6 0.0098 0.0102 0 .0430 0.0490 ****** O.Oi50 915 930 945
1000 1015
15. 3 o. 4 5. 6 o. 75.
*****• ****** "'****+ ****** **"'***
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****•• ****** G.OCC2..... ,.• * *>l +,j,
****** ****** 0.0060 •*"'*** >lo*****
**"'*** ***,,lI< 0.0012 ****** ****"*
****** "'**,,II.* •• ,:, c.c
0.0024 ****** >l***"'* c.ooc8
o.o ****** "'***** o.o
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o. 0'1311 ****** ****** 0.0419
"'***** ****** **'I)** ****** 0.0122
w N \D
1215 12 30 1245 1300 1315 1330 1345 1400 1415 1430 1445 1500
195. 21 a. 22 5. 240. 2 5 5. 2 7 o. 2 !l 5. 300. 315. 330. 345. 360.
*>III**"' *"'**** "'***** ,."'***"' 0.0003
*****'° ****** 0.1322 ****** ***"'*• 0.1303 ****** •****"' 0.1281 ***"'** "'"'***• 0.1259
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****** ****** 0.0002 *'***"'* "'**9*+ c.o •****• "'*"'*** o.o •***** "'****• o.o
****** *>i1I< 0.0109 ****** ****** 0.0101 ****** ****"'* 0.0096
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-
•••••• L
EC -3 7 l SURROGATE Y, 48 CEG f ,2.2, 0.05) 1979 FEil
CLOCK ELAPSED TIME T(MIN)
812 -48. 900 o. 915 15. 930 30. 945 4 5.
1000 6 o. 1015 75. 1030 90. 1045 105, 1100 120. 1115 13 5. 1130 150. 1145 165. 1200 180, 1215 195.
I.,.) I.,.) 12 30 210. 0 1245 22 j,
1300 240. 1315 25 5. 1330 2 7 o. 1345 285. 1400 300. 1415 315. 1430 33 o. 1445 345. 1500 360.
28
TS OEG f
****** 39.6 45.7 46.9 47.1 4 7.4 47.9 47.9 48.l 48. l 47.9 47,4 47,l 46.4 46.4 4&.7 47.l 4 7, 1 ·. 47.l 47.9 47.9 48.4 48.1 48,1 47.1 47.4
REL HU., %
>t++•inl
-
EC -371 SURROGATE V, 48 CEG F (2.2, O.C5) 1979 FEB 28
CLOCK ELAPSED N02 N02 NGX NOX TOT N03 TOT N t-120 HCTOT TIME
812
T011N)
-48.
PPI'
*****'
PPM
******
PP/J
,.,...,.. PPM •***** PPM ****** PPM ****** PPM *** .. ** PPMC 3.401 900 o. 0.025 O. IH6 C.C58 0. 011 4 o.o 0.050 2864. 3.404 915 15. 0.031 0.023 C.C!:6 o. 043 0.001 o.o 56 36 56. ****** 930 30. 0.038 0.032 0. C54 0.040 0,002 0.054 3825. **-'l'**• 945 4 5. 0.040 0.036 C. C51 o. 03':i 0.004 0.051 3860. 3. l 11
1000 6 o. 0.040 C.OH C.C48 0.034 (J,005 0.04B 3ct95. *****"' 10 l 5 75. 0.039 0.035 C.C46 0.033 0.000 0.046 3966. *****+ 1030 1045
90. l O 5.
0.039 0.037
o. 033 0.032
C.C44 C. CH
0,030 0.026
0.010 0.012
0,044 0.042
3966. 4002.
3.096 ++*"'**
1100 12 o. 0.036 C.C32 (.C40 0.027 0.014 0.040 4002. "'***** 1115 1130
135. 15 o.
0.034 0.034
c. 030 G.030
0. C;9 O.C37
0.025 0.025
0.015 0.011
0.038 0.037
3966. 3895.
3 .04 8 ***+*+
1145 16 s. 0.034 0.029 O. C37 0.024 a.on 0.037 3860, ****** 1200 l 80. 0,032 C. 02 'i o.c:rn 0.023 0.018 0.038 3757. 2. 94 2 1215 195. 0.032 0.028 C.C38 0.022 0,018 0.038 3757 • ******
l,..) l,..)
f-'
1230 1245
21 o. 225.
0.033 0.034
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O.C37 c.c::a
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0.018 O.Cl8
0.037 0.038
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1300 24 o. 0.034 c. 02 S c. C38 o. 02 3 0.019 0.038 3005. ****** 131 5 255. 0.034 0. 02 1l
-
_,
EC -372 SuRRJGATE Y, 125 DEG F (2.2, 0.05) 1979 MAR l
BEGIN IRRADIATION 1000; 0.25 INCII PYREX FILTER; TRICHROIC FILTER OUT NOX l~JE:TED P~IOR ln PURE AIR FILL USING EC VACUUM RACK 1035 U~TIL 1050 OZONE DATA AFFECTED DUE TO SLIGHT NEGATIVE PRESSURE IN EC
EC OP=~EO TO BAG AT 1046 RH OF FILL 151 AT 85 O[G F FOH A PREDICTED 5% RH AT 125 DEG f BECKMAN 6800 ON MANUAL OPERATION; CO FACTOR: 1.6/14.95 BRADY 292i DASI8I 1212; TECO 148-1 & TECO 148/E USED
T=O AT 1000 PST
CALI BIi PAN 12
tiCHO 3 REL I NT 4
SPECTRAL DISTRIBUTION WAVELENGTHtNM) REL. INTF.NSlTY
l,.) l,.) TS K 500. U,JDEG AVER.AGE 324.8 2 ■ N
SSPOWER KW AVERAl,1:. 16.67 430. L.941 R4DIIJM MW/CM2 AVERAGE 0.150 403. 1. 731 REL HUM % AVERAGE 4.600 380. 1. 543* H20 PP.M AVERAGE 6.lOOE 03* 370. L. 377
N·J PPM IN IT COMO 0.040 360. 1.157 N02-CORR PPM [NIT COND 0 .o 23 350. 1.000
co PPM INIT COND 0.182 340. 0.790 HCHQ PPM !NIT COIW 0.006 330. o. 531
METHA"IE P?M I N!T CGNO 1.05() 320. 0.280• 310. 0.096ETtiANc PPM IN IT CONO 0.032 * 0.001ETHE Ni: PPM !NIT COND 0.012 300.* o.oACE:TYLEN PPM IN IT COND 0.050 290.* PRO Ph.NF. PPM rnn corm 0.037
P~OPENE PPM [NIT CONO 0.012 N-C4 PPM IN IT corm 0.170
T2-C4= PPi--1 ! I~ !T COMO 0 .'JO l ClS2-C4= PPM I NIT CONO 0.014 2MF.-C4: 2 PPM INIT CCND 0.012
2, 3-0i18 PPM IN IT CONO 0.057 N-C6 PPM IN IT C
-
EC -3 72 SU~ROGATE Y, 125 DEG F 12.~, o.o~l 1979 HAR l
CLOCK TIME
930 1000
ELAPSED TIHINl
-30. o.
OZONE PPH
****** o.o
NO PPM
( l4U-1J ******
0.04C
NC PP/J
{14cl/El*.. *•••
G.C34
N02-CORR PPM
(14B-l) *****•
0.02::i
N02-CORR PPM
114B/El *"'****
0.017
NOX-CORR PPM
t l4o-l l ******
0.06.:1
NOX-CORR PPH
(148/EI ******
0.051 1015 15. 0.044 C.OlG c.occ 0.048 O.G48 0.05d 0.048 1030 3 o. 0.115 0.005 -C.CC4 0.045 0.048 0.049 0.044 1045 45. 0.150 o.oos -C.CC5 0.042 o.049 0.04b 0.044 llOO 6 o. 0.205 0.005 -c.CC5 0.039 0.052 0. 01t4 o.047 1115 75. 0.232 O.OG4 -C.CC5 0.038 0.056 0.042 0.051 1130 90. 0.256 0.005 -C.CC5 0.037 o. 056 0.042 o.os2 1145 105. 0. 211 C.005 -O.OC3 u.037 o. 027 0.042 0.025 1200 l 2 o. 0.286 0.005 -G.OCJ 0.038 0.030 0.043 0.021 1215 135. 0.298 CoC06 -c.cc2 o. 03!l o. c:n O.O't3 o. 02 8 1230 15 o. 0.313 0.005 -c.cc2 0.042 0.032 0.046 0.030 12,. 5 1300
16 s. l tl o.
0.318 0.325
o.ooa o.oos
-O.OC3 -C.CC3
0.042 0.047
0.035 0.037
0.049 o.os1
0.032 0.035
Ul 5 19 5. o. 332 0.005 -0.002 0.050 o. 037 0.056 o. 034 l,J w w
1330 1345
no. 2 2 5.
0.337 0.342
0.005 0,005
-O.GG2 -c.cc2
0.052 0.052
0.039 0.040
o. 05 7 0.057
0.036 0.031
1400 240. 0.342 0.004 -G.GC3 0.053 0.0 1,0 0.057 0.038 1415 255. o. 34 1 C.004 -G.CC3 0.053 o.043 o.o5a 0.040 1430 21 o. 0.352 0.004 -c.oc2 0.054 0.043 0.058 0.041 144 5 1500
2 tl 5. 3 oo.
o. 35 2 0.354
0.005 0.005
-0.GC3 -o.cc2
0.053 0.053
0. 044 0.045
o.osa 0.050
0.041 0.043
1515 315. 0.354 0.004 -o.oc2 0.054 0.045 0.058 0.043 1530 1545
3:.10. 345.
o. 3!> 7 0.357
0.004 0.005
-O.CC2 -c.cc2
0.055 0.053
o.047 0.047
0.059 0.059
0.044 o. 045
1600 360. 0.359 0.005 -o.ccz 0.054 0.048 0.058 0.046
-
••••••
EC -372 SURROGATE Y, 125 DEG F ,2.2, C.G5) 1979 MAR 1
CLOCK ELAPSED co PAN HCHC ACETALO PROPALD ACETONE MEK C3-N-2 C4-N-2 METHANE ETHANE ETHE NE ACETHi:N TIME TOHN) PPM PPM PPI' PPM PPM PPM PPM PPM PPM PPM PPM PPM PPM
930 -30. ****** ****** •••••• 0.0252 0.0598 0.0057 0.0003 ****** ****** *"'**** O.O't97 u.0204 0.0597 1000 o. 0.18 o.o O.OC6 ****** ****** *****• ****** o.o o.o ****** ****** ****** *****• 1015 15. ****** •••••• ....... ****** ****** ****** ****** ****** ****** ****** ****** •••••• •••••• 1030 3 o. ****** 0.001 •••••• "'***** ****** ****** ****** 0.0001 o.u •••••• ****** •••••• **'II**** 0.0462 0.1016 0.0332 0.0028 ****** ****** 1.05 0.0782 0.0274 O.O't99 1100 60. 0.28 0.010 G.042 0.0001 0.0001****** ****** ****** ****** ****** ****** ****** ****** 1115 75. ****** *****• •••••• ****** ****** "'***** ****** ****** ****** ****•* ****** ·••**• •**••* 1130 90. 0.010 0.0464 0.2152 0.0436 0.0045 0.0003 0.0005 0.0732 0.0224 o.u468****** ****** *'I'•···U45 l O 5. ****** ****** ........ ***"*** ****** ****** *•**** ****** ****** ****•* ****** *•**** ****** 1200 120. 0.42 c.010 0.011 ****** ****** ****** ****** 0.0004 O.iJ005 ****** **"'*** •••••• ****•• 1215 135. 0.0432 0.2391 0.0504 0.0050 0.0744 0.0202 0.0465 1230 15 o. ****** O.OC9 ••**•* ****** *****>lo ****** >lo*•*** 0.0004 O.OOi.15 **"'*•* ***•** •••••• >jl,C,**** 1245 165. ...... ,a,
****** ****** ..... .,.. ****** ****** *"'**** ****** *****• ****** ****** ****** ****** ****** ****** ****"* **'**** "'***** ••Ill***
1300 18 o. o. 51 o.008 C.Ot:4 0.0440 o. 2511 0.059.'.t 0.0076 0.0004 a. ooos O.G703 0.0105 C.0439 1315 195. ****** "'***** *+alO+• "'"'**** ****** ****** ****** ****** ****** "'***** *****• •••••• ··•*•>I<
l,..) l,..) 1330 21 a. ****** 0.001 >1>1**** ****** **"'*** ****** ****** 0.0004 0.0001 •***** ••**** ··•11
-
EC -372 SURROGATE Y, 125 OEG F I 2. 2, 0. O 5 l 1979 MAR l
CLOCK T 11-IE
ELAPSED TIMlN)
PRCPANE PPM
PROPENE PPM
l-C 4 PPI'
N-C4 PPM
T2-C4= PPH
C1S2-C4 2 PPM
2ME-C4=2 PPM
2, 3-0~il PPM
t,;-C6 PPM
TOLUENE PPM
M-XYL PPM
w w VI
930 1000 1015 1030 1045 11 LiO 1115 ll30 ll'i5 1200 1215 12 30 1L45 1300 1315 1330 1345 1400 1415 1430
-30. o.
l 5. 3 o. 45. 6 O. 75. 90.
l O5. 12 o. 13 5. 15 o. 16 5. l fiO. 195. 21 o. 2 2 s. 240. 255. 210.
0.0381 0.0368 ****** ****** 0.0366 ****** ****** o. 0349 ***"'** ****** 0.0334 ****** ****** o.u319 ****"'* ·***** 0.0309 ****** ****** 0.0304
0.0123 0.0122 **,;,********+ o.C058 •****• ****** 0.0026 ****** ****** 0.0011 ****** *"**** 0.0001 **••· .. ·••**" c.0002 ****"'* ++itt *,. ** *•**** '°***** *•*• ♦ +•••••• ,. *** ** *~•···• ,. • * •• +'I*•** *•"******,. * * .... •**.,..,.. .. >IU+ ♦ >!c
• ,.,...• ** .. >I++ ••.,. .... ,.,.. .....
0.1144 o.169'.i >!,**** * *****>!,0.1614 ***** * '°**"'** c.1497 *"'lllI
-
••••••
••••••
•••••• •••••• ••••••
EC -3 7 2 SURROGATE Y, 125 DEG F t2.2, C.C5J 1979 MAR l
CLOCK TI ME
930 1000 1015 1030 1045 1100 1115 1130 !145 1200 1215 1230 1245 1300 1315
Lu 1330 Lu 1345O'I
1400 1415 1430 1445 1500 1515 1530 1545 1600
ELAPSED TLMINI
-30. o.
15. 30. 45. 60. 75. 90.
l O 5. 12 o. 13 5. 15 o. 165. 180. 19 5. 210. 22 5. 240. 2!:>5. 210. 28 5. 300. 315. 330. 345. 360.
TS DEG F
****** 119.4 124. l 124.6 124.ii 126.0 126.5 125.5 123.8 124.l 124.1 124.3 123.8 124.3 124.3 124.6 124.3 125.l 124.6 125. l 125.8 126.0 126.8 126.0 126.3 125.8
SSPOwEfi Kw
****** 16.40
•***** *"****
16. 51 ****** •*****..... ,. 16.80
•***** >lo>Ilo***** ****** ******
16.88 ******
*****" 16. 59
****** •****,.
16.88
IIAOICM 1'1,/C/'2
• ,. •• "* C.147 C.151 o.H7
• "** "* 0.151 0.1:4
""*** +. c.1:9 0.151
******....... ******
0.151 ••****
C.149 0.149 0. 149 C.149 C.149 C.147 C.147
....,.. C.151
HCHO VOL L
****** 20.00
•***** "'***** ****** 20.oc
****** ****** ******
20.00 *****,.****** *****"' 20.00
****** ****** ******
20.00 ****** ****** *****" 20.oc
*****• ••**** ****** 20.00
-
EC -372 SURROGATE V, 125 DEG F ,2.2, 0.051 197'J MAR l
CLOCK ELAPSED N02 N02 NOX NOX TOT N03 TOT N HCTOT TIME
930
TIMIN)
-30.
PP/J
***"'**
PPM
****"'*
PPfJ
.,..... PPM ****** PPM *****·* PPM ljojl,jr,j
-
EC -373 ALKANES, 1979 MAR
46 6
DEG f (3.G, 0.5)
BEGIN lRRAOIATICN 0900; 0.25 l"C~ P¥REX FILTER; TRICHROIC NOX INJECTED PRIOR TO PURE AIR FILL U~ING EC VACUUM RACK RH Of FILL 15% FOR A PRECICTED 25~ RH AT 45 DEG f BRADY 292,0ASIBI 1212,TECO 14B-l £ TECO 148/E USED BECKMAN 6800 ON MANUAL CPERATIQN; CC fACTOR:l.6/7.0S
fllTER OUT
T"'O AT 900 PST
PAN HCHO
REL INT
CALI BIi 12
3 4
SPECTRAL DISTRIBUTION WAVELENGTHlNMJ REL. INTENSITY
w w CX)
TS REL HUM SSPOWER RADIDM
H20 NO
N02-CORR N-C4
NEO-CS co
HCHO ACETONE
MEI{ MET HANE ETHANE ETHENE