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MAY 2020 www.im-mining.com IM NORDIC TECHNOLOGY IPCC MINING CHEMICALS REPROCESSING & TAILINGS REDUCTION FLEET MANAGEMENT GRAVITY, MAGNETIC, DENSITY SEPARATION

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  • MAY 2020www.im-mining.com

    IM

    NORDIC TECHNOLOGY

    IPCC

    MINING CHEMICALS

    REPROCESSING & TAILINGS REDUCTION

    FLEET MANAGEMENT

    GRAVITY, MAGNETIC, DENSITY SEPARATION

    IM COVER MAY 20.qxp_proof 30/04/2020 11:20 Page 1

    http://www.rocktechnology.sandvik

  • Whether it is for dewatering, mineral/

    metal recovery, optimisation of mineral

    processing, or long-term protection of

    key equipment, the use of mining chemicals is

    vital to the success of today’s operations.

    As mining companies take on the challenge of

    processing even more complex ores, using the

    right chemicals – with the right dosages – will

    continue to be critical into the future.

    Yet, as manufacturers of reagents, frothers and

    processing aids are being asked to develop more

    effective products, they are also battling with

    requirements to lower the impact on the

    workforces that interact with these chemicals and

    the environment in which they work.

    Reduced exposure Bernard Oosterndorp, Technical Manager at

    South Africa-based reagent producer Axis House,

    has seen the company’s clients demand exactly

    this – products that reduce handling or mixing on

    site.

    “We have seen a gradual move away from

    xanthates to liquid sulphide collectors for this

    very reason,” he told IM.

    While xanthates have been used in sulphide

    flotation since 1924 and are the most widely used

    sulphide collector in the flotation space, they

    pose some major risks, according to fellow

    reagent producer Clariant.

    They present health risks to workers, come

    with disposal challenges for mining companies,

    may require additional infrastructure for

    handling, and are classified as a fire and

    explosion hazard by many regulators, according

    to the company.

    Business Queensland, an arm of the

    Queensland Government, classifies xanthates as

    liable to spontaneous combustion in the

    Australian Dangerous Goods (ADG) Code, adding

    that they pose a number of hazards due to their

    nature, the vast quantities used in industry and

    the climate conditions at most Queensland mines

    using them.

    For these reasons, it is hardly surprising there

    has been a gradual market move away from

    xanthates.

    In the lead flotation process, Eammon Guitard,

    Global Marketing Manager, Mineral Processing,

    at Solvay Mining Solutions, says the company

    has seen more and more polymetallic (Cu/Pb/Zn)

    mines requesting selective collectors to replace

    xanthates in the flotation process.

    “Today over 40% of the industry has switched

    to alternative products,” he said, adding that

    Solvay’s AEROPHINE® is one of the leading

    technologies in these applications.

    Going to trial Clariant says its own push to replace xanthates

    worldwide is driven by three major factors.

    One is the simplification of flotation circuits

    through avoiding the use of multiple collectors

    where possible.

    Two is the elimination of the need for

    operational mine employees to handle large

    amounts of xanthate powder or pellets.

    Three is the problems associated with

    discarding contaminated packaging.

    “The goal to replace xanthates that have been

    in use for nearly 100 years is an ongoing challenge

    for the Clariant Mining Solutions team,” it said.

    The company has been making significant

    progress with this “ongoing challenge” since it

    launched its HOSTAFLOT® line of xanthate

    replacement technologies, part of its EcoTain®

    range of products, in 2015.

    The company told IM: “Clariant’s goal is to

    help mining operations increase their production

    efficiencies, lower production costs and improve

    sustainability with their HOSTAFLOT line of

    xanthate replacements.”

    Clariant’s application development teams have

    been working with customers to create and test

    several chemistries from the HOSTAFLOT series

    to replace xanthates in their respective regions,

    moving the products towards commercial

    applications, it said.

    In a previously reported initial plant trial of

    HOSTAFLOT chemistry at a large copper/gold

    mine in Brazil, collector consumption was

    reduced by 40% and frother consumption by

    25%, according to Clariant. The company noted

    the mine continues to experience both lower

    collector consumption and frother consumption

    since the trial.

    At another large copper/gold mine in Brazil,

    Clariant said the HOSTAFLOT xanthate

    replacement technology was able to replace not

    only the xanthate but also the supplemental

    collector, resulting in an overall reduction in

    collector consumption of 33%. Frother

    consumption has also been reduced by 50% at

    this mine.

    “In both copper mines, metallurgical targets

    for copper recovery continue to be achieved, with

    operational acceptance in the plants,” Clariant

    said. “Additional mines in Brazil have shown

    interest in the HOSTAFLOT xanthate replacement

    chemistries, and laboratory qualification is

    ongoing in gold flotation plants.”

    In Chile, some of the largest copper mines

    have moved from xanthate to HOSTAFLOT

    xanthate replacement technology, according to

    Clariant.

    Plant results have indicated a 1% improvement

    in copper recovery over sodium isopropyl

    xanthate, with the HOSTAFLOT collector

    indicating a better response at a lower pH than

    xanthates, which results in less lime

    consumption and lower reagent costs for the

    operator, Clariant explained.

    “Currently there are gold flotation plants in

    Chile undergoing lab trial qualifications to

    evaluate whether the HOSTAFLOT xanthate

    replacement product can replace their xanthate

    collector,” the company added.

    In Australia, a plant trial is ongoing at a large

    copper/gold mine where the miner is evaluating

    one of the HOSTAFLOT xanthate replacement

    chemistries to replace sodium ethyl xanthate in

    its flotation process. There are also several

    laboratory trials ongoing with a large lead-zinc-

    silver-copper producer to replace sodium ethyl

    xanthate in its zinc flotation circuit.

    36 International Mining | MAY 2020

    Balancing the formula

    Dan Gleeson delves into a sector focused on providing more environmentally friendly chemicals that retain, if not increase, their effectiveness in the process plant

    MINING CHEMICALS

    Solvay says its AEROPHINE xanthate replacement chemical technology enables base metal miners to maximise their net smelter returns for concentrate through the effective extraction of precious metals that can be sold as by-products

    MINING CHEMICALS.qxp_proof 29/04/2020 09:44 Page 1

  • Additional laboratory trials are being conducted

    by Clariant’s mining development laboratory in

    Australia on copper and gold mine flotation plants

    to evaluate HOSTAFLOT xanthate replacements, in

    all cases to replace potassium amyl xanthate, the

    company said.

    In South Africa, it is platinum and palladium

    producers currently interested in HOSTAFLOT

    xanthate replacement products, according to

    Clariant.

    At one platinum producer, the HOSTAFLOT

    xanthate replacement showed the new product

    can operate at a lower dosage than xanthate and

    result in reduced chrome content in the

    concentrate – an undesirable metal in this case, as

    it increases the slag liquid temperature in the

    subsequent smelting process, Clariant noted.

    There are also indications from the plant trial that

    frother consumption can be reduced, which will

    lead to additional reagent savings for the operator.

    Further, there are lab trial qualifications for

    HOSTAFLOT xanthate replacements ongoing in the

    new Clariant mining development lab in

    Johannesburg, South Africa, with the aim of

    moving to plant trials later in 2020.

    It’s clear from the breadth of testing to replace

    the likes of sodium isopropyl xanthate, sodium

    ethyl xanthate, potassium amyl xanthate and

    other xanthate collectors that there is no one-size-

    fits-all flotation solution. It is also apparent some

    of these replacement chemistries positively

    impact more than just the effectiveness of the

    collectors, the environment and personnel.

    Phosphine-based flotation alternatives When it comes to the adoption of Solvay’s

    AEROPHINE 3418A xanthate replacement chemical

    technology, the company also sees three market

    forces leading to further market adoption.

    First, with base metal prices subdued, the likes

    of copper, zinc and lead miners are exploring ways

    to effectively extract precious metals that can be

    sold as by-products. AEROPHINE enables mine

    operators to maximise their net smelter returns for

    concentrate, the Solvay says.

    Separation efficiency is another key selling

    point, with AEROPHINE enabling increased

    selectivity against gangue and penalty elements,

    while lowering the ore treatment cost. This

    potentially increases revenue at the same time as

    reducing operating expenses, the company says.

    Lastly – and a point already picked up on –

    AEROPHINE technology helps mines limit operator

    exposure to harmful chemicals.

    AEROPHINE 3418A, Solvay says, is a unique,

    phosphine-based chemistry originally developed

    for the flotation of copper and activated zinc minerals.

    More recently, it has demonstrated selectivity

    towards complex, polymetallic and massive

    sulphide ores, the company said, adding that

    AEROPHINE is highly selective for lead/zinc and

    lead/silver minerals and exhibits strength yet

    selectivity against iron sulphides (pyrite,

    pyrrhotite, marcasite and arsenopyrite), non-

    activated sphalerite and penalty elements.

    The company has provided a few examples to

    back this up.

    In an application where ore from a chalcopyrite-

    sphalerite deposit was being milled at a rate of

    around 10,000 t/d – with the concentrator using a

    conventional flowsheet of copper flotation

    followed by copper sulphate activation and zinc

    flotation – Solvay carried out laboratory tests on

    the use of AEROPHINE.

    After these lab tests were deemed successful,

    the AEROPHINE 3418A promoter was introduced

    for a full-scale 10-day plant trial, replacing the

    standard sodium amyl xanthate and methyl

    isobutyl carbinol mill promoter and frother,

    respectively. This saw copper recovery increase by

    around 8% and reagent dosage decrease by 30%,

    according to Solvay.

    The AEROPHINE 3418A promoter also induced

    minor improvements in zinc grades and recoveries,

    according to the company, with zinc recovery in

    the copper concentrate and copper recovery in the

    zinc concentrate “essentially equal” for both

    collectors, it noted.

    Solvay said: “The improvement in copper

    metallurgy alone translates into a substantial

    monthly increase in the value of copper recovered

    at the mill.”

    MINING CHEMICALS

    MAY 2020 | International Mining 37

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    The GHT F is a Diemme®

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    MINING CHEMICALS.qxp_proof 29/04/2020 09:44 Page 2

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  • Another case study looking at a trial of

    AEROPHINE 3418A on a 4,000 t/d copper-zinc-

    silver mine that previously used potassium amyl

    xanthate provided evidence of the collector’s

    precious metals recovery credentials.

    The 10-month test pitted metallurgy obtained

    with the standard promoter against the

    performance of a mixture of AEROPHINE 3418A

    promoter and potassium amyl xanthate.

    Looking at the monthly silver tailings assays as

    a function of head grades for nine of 10 months, it

    was evident there was a trend to lower silver tails

    assays with the AEROPHINE 3418A/potassium

    amyl xanthate combination. The average

    metallurgy over the ten-month period also saw the

    use of AEROPHINE 3418A promoter increase silver

    recoveries by 6%, according to Solvay.

    “Small but significant improvements in copper

    metallurgy were also observed together with a

    small reduction of zinc reporting to the copper

    concentrate,” Solvay said.

    Revadep proves its worth Axis House’s Oosterndorp says its clients can

    benefit from increased metal recoveries while

    improving the working conditions of their staff and

    streamlining their processes with the

    implementation of its environmentally sensitive

    products.

    As Cherry Thomas, Sales Manager, Africa, says:

    “Environmental regulations are…becoming stricter

    and requests for alternative reagents to common,

    but hazardous, chemicals (xanthates, NaHS,

    cyanide, etc) are increasing.

    “Axis House takes this into consideration during

    the reagent development work for clients.”

    Its xanthate-alternative sulphide collectors are

    being used successfully at a several copper mines

    in Zambia, as well as platinum and gold mines in

    South Africa, according to Oostendorp.

    “The European and Middle East market has

    shown substantial growth in the last 18 months,

    an area where we are focusing our resources to

    maximise on the market potential,” he added. This

    has seen multiple trials conducted and completed

    at copper-lead-zinc mines in Europe and Turkey,

    where sulphide collectors were successfully

    trialled in full-scale applications.

    Thomas said: “This allows Axis House to apply

    the application knowledge and market products to

    operations processing similar ore types.

    Successful application of reagents also forms a

    new baseline from which further development can

    take place.”

    Sulphide collectors are not all the South Africa-

    based company is working on.

    The company’s Revadep depressants range,

    engineered to target specific gangue minerals in

    the flotation process, has found favour with

    platinum group metal producers in Africa.

    Thomas said the depressants have proven

    highly effective in the PGM flotation process by

    reducing floatable gangue like talc.

    The company is also targeting the Zambia

    copper flotation market with its Revadep Cu++

    depressant formula, according to Thomas. “Highly

    floatable carbon is also a problematic mineral in

    some operations in Zambia and the Axis House

    carbon depressant, Cu++, was successfully trialled

    at full scale,” she said.

    In the DRC, the company’s mobile precipitation

    plant, built specifically for cobalt miners to analyse

    the effects of dosage, process conditions and

    reagent type on different types of ores, is starting

    to be appreciated by miners too, Thomas said.

    And, the development of a reagent range to

    remove cadmium in phosphate production has

    allowed Axis House clients to cost-effectively

    sustain phosphate output without bolting on

    processing units like ion exchange columns, she

    added.

    At the R&D stage of its Revadep depressants,

    Axis House is addressing the use of one of the

    more controversial reagents used across the

    mining industry, according to Thomas.

    “At development level, the focus is to expand

    the Revadep range to include selective

    depressants of sulphide gangue (pyrite,

    pyrrhotite) to replace or reduce the use of

    hazardous reagents like cyanide,” Thomas said.

    Automating cyanide control Speaking of cyanide, Orica says its Cyanide

    process review and optimisation services have

    recently helped a customer in Peru achieve

    significant reductions in cyanide and hydrogen

    peroxide consumption, all while increasing gold

    recoveries.

    Reducing reagent consumption offers

    significant and sustainable cost benefits to

    operations but comes at the risk of lower

    recoveries and greater disruption to process

    chemistry due to ore variability, Orica says.

    This is where Orica’s process review and

    optimisation service, PRO Service, comes in.

    A collection of tools and services developed to

    support the gold industry in achieving best

    practice in gold leaching and recovery, the PRO

    Service package uses tailored solutions from Orica

    including the Process Health Check benchmarking

    service, LeachIT™ process simulation and

    Cyantific™ process analysers.

    Process Health Check enables customers to

    identify problem areas where improvements will

    lead to significant gains in metal recoveries and

    savings in reagent consumption. It uses a

    customer’s historical data to benchmark their gold

    solid and solution losses against similar sites

    around the world. It also analyses incoming

    variables, and how well they are controlled, to

    produce the desired outcome – maximum

    recoveries at minimum cost.

    The same historical data can then be used with

    LeachIT – an intelligent software package that

    allows metallurgists to see how their process will

    respond to changes without time-consuming and

    expensive experiments. “Aimed at enabling best

    practice leaching, LeachIT simulates changes to

    the process and presents the impact on tails

    grade,” the company said. “The software harnesses

    this information not only to calculate but also

    visualise gold recovery and cyanide consumption.”

    Cyantific uses a range of online process

    analysers to optimise cyanide addition,

    detoxification processes, and tailings discharge –

    lowering costs while maintaining or improving

    recovery, Orica says. Customers with a properly

    installed and maintained OCM5500 Leach Process

    analyser typically reduce cyanide dose to the

    leach by 5-20%, according to the company.

    Orica’s Customer Solutions Manager – Global

    Cyanide, Paul Martin, said: “We aim to take our

    customers’ operations data and combine it with

    our expansive global Cyanide process data

    gathered over time, and then interpret that data

    into insights, delivered visually so that our

    customers can make more rapid and confident

    decisions.”

    At the open-pit gold mine in Peru, Orica was

    able to demonstrate how its PRO Service enables

    consumption savings and increased gold recovery.

    MINING CHEMICALS

    38 International Mining | MAY 2020

    Orica’s PRO Service methodology

    MINING CHEMICALS.qxp_proof 29/04/2020 09:44 Page 3

  • In recent years, the mine had experienced

    challenging mineralogy due to the depletion of

    oxidised mineral reserves and the onset of

    complex minerals.

    The Process Health Check methodology was

    used to analyse the site’s historical data. Among

    the relevant variables that were closely scrutinised

    were cyanide measurement and its dosage. It was

    determined there were inconsistencies in the free

    cyanide measurements due to copper variations

    and sulphide levels in the ore. This variability

    initially generated an overestimation of free cyanide.

    It was determined that investing in an enhanced

    method and frequency of free cyanide

    measurement would significantly improve cyanide

    control and result in a more efficient leaching

    system.

    Orica proceeded to implement Cyantific and its

    OCM5500 Leach Process analyser. The latter

    helped increase the accuracy and frequency of

    free cyanide measurement, together with the

    implementation of a control loop that was

    integrated with the Distributed Control System of

    the plant and actuators, Orica said. This automatic

    dosage system was developed with the flexibility

    to adjust the free cyanide set points that were

    optimised for each ore type.

    The automated control system managed to

    significantly reduce free cyanide variability,

    compared with the manual dosage, eliminating

    the periods of excessive and insufficient dosage.

    This resulted in a much more consistent free

    cyanide level, enabling a reduction in the

    consumption of reagents necessary for cyanide

    destruction, which is a critical requirement for

    tailings disposal, Orica said.

    Once the free cyanide set point requirements

    for each ore type was defined, there was a need to

    have greater accuracy in the free cyanide

    measurement to implement a new process control

    methodology, Orica explained.

    “An increased testing frequency was required to

    configure the process for different operating

    scenarios, which led to the integration of the OCM

    5500 analyser with the control room and the

    establishment of a methodology to continuously

    control the leaching process,” the company said.

    Throughout the project, a baseline was

    established for each relevant variable, including

    free cyanide concentrations before and after the

    project.

    The improved cyanide dosage control

    successfully reduced the variability of free cyanide

    in the process, according to Orica.

    By adopting the automated cyanide dosage

    system, the customer achieved a 40% reduction in

    cyanide consumption and a more than 70% drop

    in hydrogen peroxide consumption. It was

    validated that gold recovery increased by an

    average of 2.5% from the baseline.

    Orica said: “These significant gains can be

    further improved by using Orica’s LeachIT to

    determine the optimum cyanide levels for various

    blends of ores with different levels of copper and

    sulphide minerals.

    “Consistent levels of cyanide, as well as better

    accuracy of the results, produces a more accurate

    simulation of the leaching system and optimum

    leaching conditions resulting in further gains to

    customers.”

    Collector development Arkema-ArrMaz, recognising a need to simplify the

    flotation process and improve grades and

    recoveries across the Turkey feldspar industry,

    established a Joint Collector Development

    program (JCDP) in partnership with a leading

    feldspar producer in the country five years ago.

    The JCDP took a similar approach to that of

    sulphide and other industrial mineral applications,

    where advanced specialty blend collectors

    formulated to specific ore mineralogy have

    replaced single chemical component “commodity

    collectors” to efficiently and cost-effectively

    provide the selectivity required, according to

    Abdul Gorken, Senior Metallurgist, Arkema-

    ArrMaz, and Todd Parker, Global Mining Marketing

    Manager, Arkema-ArrMaz.

    Gorken and Parker explained: “Arkema-

    ArrMaz’s JCDP develops and evaluates potential

    collector chemistries formulated for a specific ore

    mineralogy with statistical mixture designs that

    consider mixture stability, component

    compatibility, cost and application benefits.

    “Since its inception, this JCDP has successfully

    completed six stages of development and

    evaluation, including multiple rounds of custom-

    blend collector formulation at Arkema-ArrMaz’s

    lab in Mulberry, Florida, as well as confirmatory

    tests and plant evaluations onsite in Turkey.

    “The results of each stage are used to drive

    improvements for the next in an iterative process.”

    The Turkey feldspar sector was chosen as the

    country’s deposits typically contain problematic

    gangue minerals such as heavy

    impurities (mostly rutile, titanate and

    spinel), significant amounts of mica

    (mostly biotite and lesser amounts of

    muscovite), and varying amounts of

    troublesome clays (including kaolin,

    illit and more), according to Gorken

    and Parker.

    “Most of the heavy magnetic iron

    impurities can be removed by dry and

    wet, high- and low-intensity magnetic

    separators,” they said. “However, the

    remaining heavy impurities consisting

    mainly of rutile, non-magnetic iron

    and mica require special reverse

    flotation techniques for removal before acceptable

    feldspar concentrate grade can be achieved.”

    In the early 1990s, some major local feldspar

    producers introduced a reverse flotation technique

    whereby heavy impurities were floated away with

    fatty acids first, after which mica was floated away

    with amines in acidic media.

    Later, with the development of more efficient

    fatty acid collectors, the same or better separation

    was achieved in a neutral flotation circuit using

    more environmentally friendly processes, Gorken

    and Parker explained.

    Then prina oil, a residue from local olive oil

    production, became the standard fatty acid

    replacement. In the mid-2000s, with the

    development of more selective fatty acid types

    and amines, further grade and recovery

    improvements were realised.

    “Today, however, with the rapid growth of

    Turkish feldspar production and the gradual

    decline of higher-grade deposits, better flotation

    concentration methods are needed,” Gorken and

    Parker said. “Feldspar producers and suppliers

    alike are seeking flotation improvements in

    selectivity, processing cost and simplicity with

    specially formulated fatty acids and amines.”

    When floating feldspar, de-sliming followed by

    two stages of flotation with two different

    collectors are usually required to produce

    acceptable product quality, according to Gorken

    and Parker. The typical feldspar beneficiation

    process involves:

    n Grinding, classification, screening, cycloning;

    n Magnetic separation; and

    n Froth flotation:

    n Direct flotation of feldspar – practiced on

    feldspar ores with high quartz content; or

    n Reverse flotation of feldspar – practiced

    on feldspar ores with small amounts of

    quartz.

    Anionic collectors (typically fatty acids and their

    soaps) make up 80% of industrial mineral

    collectors and are considered analogous to

    xanthates in sulphide flotation, according to

    Gorken and Parker. “These collectors are used in

    direct flotation of minerals with positive surface

    MAY 2020 | International Mining 39

    MINING CHEMICALS

    Arrkema-ArrMaz’s CustoFloat custom blend collectors yielded substantial performance improvements and a much simpler single-stage process in feldspar operations in Turkey

    MINING CHEMICALS.qxp_proof 29/04/2020 09:44 Page 4

  • 40 International Mining | MAY 2020

    charges such as calcite, phosphate and fluorspar;

    and in reverse flotation of heavy impurity minerals

    from feldspar and other similar industrial

    minerals.”

    “Commodity” fatty acids are currently the most

    widely used collector type in reverse feldspar

    flotation due to the absence of better alternatives,

    according to Gorken and Parker, but they come

    with poor selectivity, high dosage requirements

    and associated operational difficulties, such as

    equipment smearing and the need for collector

    removal from concentrates for specific

    applications, Gorken and Parker said.

    Due to these issues, modifiers have been

    introduced to enable continued use of fatty acid

    collectors, further complicating the flotation

    process and increasing costs, Gorken and Parker

    said. “Therefore, it is imperative that new, more

    efficient alternatives to century-old fatty acids be

    developed.”

    This led to the development of the JCDP, which

    has seen the typical two-stage reverse feldspar

    flotation process simplified to a single-stage

    process in Turkey – an industry first, according to

    Gorken and Parker.

    “Arkema-ArrMaz’s CustoFloat® custom blend

    collectors specifically formulated to the producer’s

    unique ore mineralogy yielded substantial

    performance improvements,” they said. “Collector

    dose was reduced by 30-50%, and significant

    increases in recovery and grade were observed.

    Both collectors improved overall operational

    efficiency and cost-performance considerably,

    while streamlining reagent dosing and handling.”

    The custom blend collectors developed under

    this JCDP provided enhanced capacity utilisation;

    improved flotation efficiency; better feldspar

    recovery and concentrate grade; simpler and

    easier application compared with current industry

    standards; improved flotation selectivity; better

    material handling; and regulatory

    compliance/cost avoidance, according to Gorken

    and Parker.

    The JCDP also showed collaboration between

    mineral processing operations and reagent

    formulators to develop tailor-made collectors

    yields better results compared with commodity

    collectors, Gorken and Parker remarked.

    Dewatering concentrate Dewatering and water reuse/recycling are

    influencing not only OEM and mineral processing

    equipment design; they are also impacting the

    development of chemicals.

    According to Clariant, mining operations have

    been demanding increasingly challenging

    operational targets for the dewatering process,

    requiring lower humidity for concentrates.

    The Clariant Mining Solutions’ applications

    technologies team in Brazil has developed, in

    conjunction with one of its iron ore customers, a

    novel dewatering agent that, it says, specifically

    targets sinter feed piles and iron flotation

    concentrate.

    Laboratory drainage tests using the FLOTICOR

    dewatering agent on iron ore sinter feed reported

    a potential improvement in moisture reduction of

    10.2%, according to Clariant. In a subsequent field

    trial, a relative reduction of 10.5% moisture (1%

    absolute) was achieved (as is shown in the photos

    right).

    The amount of water that was dewatered on the

    sinter feed pile versus the control pile that did not

    have the dewatering agent is also emphasised in

    the photos.

    Clariant said the dewatering agent is under

    further field trial evaluation ahead of future, more

    formal test work.

    “Dewatering of iron ore flotation concentrate

    has been conducted by the Clariant Mining

    Solutions team in Brazil and preliminary

    indications are that moisture content can be

    reduced by 2% under laboratory lead filtration

    testing,” the company said.

    Additional confirmation testing for operational

    qualification is being carried out and will lead to

    industrial trials later in 2020, according to Clariant.

    Addressing crud and scale On top of improving mineral processing using

    novel chemicals, Solvay’s customers are looking to

    it to both extend the life of processing equipment

    and improve said equipment’s effectiveness.

    Its ACORGA® CR60 series reagents are

    processing aids designed to help solvent

    extraction operations reduce crud formation from

    turbidity in leach solutions (patent-pending). They

    have also been found to improve phase separation

    in solutions with high colloidal silica, according to

    Solvay.

    Its MAX HT® sodalite scale inhibitor,

    meanwhile, is a “best-in-class” product that

    eliminates sodalite scale from heat exchangers

    throughout the Bayer Process and contributes to

    the sustainability of the alumina industry,

    according to the company.

    A liquid reagent, ACORGA CR60 affects the

    formation of the solid-stabilised organic/aqueous

    emulsion and therefore significantly reduces – and

    in many cases stops – crud formation, Solvay

    explained.

    In a six-month (pilot and commercial) trial with

    Lisbon Valley Mining Company at its copper

    operation in Utah, USA, the following benefits

    were demonstrated at the solvent extraction

    operation, according to paper given by Solvay at

    the 2020 SME Annual Conference and Expo:

    n Minimum levels of crud were maintained at

    extraction stages, without the need for crud

    pumping and processing from the stages;

    n ACORGA CR60 eliminated plant “upsets” and

    the need for flow rates reduction against

    increased turbidity events (ore curing, raining

    events, pad challenges, etc);

    n As a result of the reduced crud levels, pregnant

    leach solution throughput increased 7%

    throughout summer and winter seasons; and

    n No impact on downstream processes such as

    electrowinning and leaching.

    Solvay says its MAX HT scale inhibition

    technology has benefited global alumina

    refineries for over a decade by improving

    operating efficiency, saving energy costs, reducing

    carbon footprints and lowering freshwater usage.

    It has only recently been introduced to China’s

    alumina industry, leading to some impressive

    results.

    Solvay explained: “China produces over half of

    global alumina output, and the industry has a

    rapidly growing need to improve efficiency and

    reduce its environmental impact, as competition

    intensifies and more stringent regulations are

    being enforced.”

    This has led the industry to adopt new

    technologies in order to compete on a global

    stage and reduce its environmental footprint.

    The introduction of MAX HT, Solvay says, has

    provided “outstanding scale inhibition

    performance in the liquor evaporation process” in

    China.

    With MAX HT, it’s estimated that some 0.03 t of

    steam for evaporation can be saved, on average,

    for every 1 t of alumina produced (fresh water is

    heated to produce steam for evaporation. Thus,

    with MAX HT, fresh water, as well as the energy

    and resultant CO2 associated with steam

    production, are reduced).

    So far, Solvay’s scale technology has been used

    at over 30 evaporation lines in Chinese alumina

    refineries, bringing significant economic benefits

    to refineries, while contributing to reducing their

    environmental impact, it said.

    MINING CHEMICALS

    A field trial in Brazil of Clariant Mining Solutions’ novel FLOTICOR dewatering agent led to a 10.5% moisture (1% absolute) reduction in iron ore sinter feed

    IM

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