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INTERNATIONAL HUMIC SUBSTANCES SOCIETY

PROCEEDINGS

XII INTERNATIONAL MEETING OF IHSS

HUMIC SUBSTANCES ANDSOIL AND WATER ENVIRONMENT

EDITORSLadislau Martin-Neto

Debora Marcondes Bastos Pereira MiloriWilson Tadeu Lopes da Silva

July 25-30, 2004

Colina Verde HotelSao Pedro, Sao Paulo

Brazil

Contents

L- ORGANIC MATTER AND CLIMATE CHANGE

THE HISTORY OF (SOIL) CARBON SEQUESTRATION AND CARBONSEQUESTRATION IN THE HISTORY 3

Christian Feller, Vincent Eschenbrenner, Martial Bernoux

SOIL CARBON STOCKS IN THE BRAZILIAN AMAZON 4Carlos Clemente Cerri, Martial Bernoux, Carlos Eduardo Pellegrino Cerri, Marisa de CSssia Piccolo, Brigitte Josefine Feigl

CARBON SEQUESTRATION IN SOIL ORGANIC MATTER? 7Gerd Gleixner, Christiane Kramer, Andrej Thiete, Janet Rethemeyer, Axel Steinhoff, Pieter Groothes

DO CHANGES IN MICROCLIMATE AND LITTER INPUT AFFECT THE HUMUS COMPOSITION IN SOILSOF A HIGH-ELEVATION FOREST ECOSYSTEM? 8

Sandra Spielvogel, Jorg Prietzel, Ingrid Kdgel-Knabner

OIL SUBSTITUTES UTILISING HUMIC PRECURSORS:THE DEVELOPMENT OF A CARBOHYDRATE ECONOMY 11

Daniel John Hayes

EVALUATION OF CARBON SEQUESTRATION IN BRAZILIAN AREA OFSUGAR-CANE UNDER DIFFERENT TILLAGE SYSTEMS 14

Aline Segnini, Marcelo Luiz SimOes, Wilson Tadeu Lopes da Silva, D6bora Marcondes Bastos Pereira Milori, Helder VinicusAvanco Galeti, Antonio Luiz Cendeira, Denizart Bolonhezi, Ladislau Martin-Neto

MODELING SOIL CARBON DYNAMICS UNDER CHRONOSEQUENCES OFFOREST TO PASTURE IN THE BRAZILIAN AMAZON 17

Carlos Eduardo Pellegrino Cerri, Martial Bernoux, Carlos Clemente Cerri, Keith Paustian, Kevin Coleman, Marisa de Ca'ssiaPiccolo, Brigitte Josefine Feigl, Eleanor Milne

EFFECTS OF BIOSOLID APPLICATIONS ON GREENHOUSE GASEMISSION RATES FROM SOILS UNDER EUCALYPTUS GRANDIS 20

Christiane Medina Teixeira, Brigitte Josefine Feigl, Ma'rcia Toffani Simao Soares, Jose Leonardo de Moraes Goncalves,Marcos Siqueira Neto, Marisa de Cassia Piccolo, Carios Clemente Cerri

NITROUS OXIDE EMISSIONS AS AFFECTED BY TILLAGE AND CROPPINGSYSTEMS IN SOUTHERN BRAZIL 24

Gmello Bayer, Falberni de Souza Costa, Juliana Gomes, Marisa C. Piccolo, Joao Mielniczuk

METHANE EMISSION FROM A SOUTHERN BRAZILIAN RICE PADDY FIELDUNDER CONVENTIONAL AND NO-TILLAGE SYSTEMS 27

Falberni de Souza Costa, Magda Aparecida de Lima, Cim&io Bayer, Rosa Toyoko Shiraishi Frighetto,Humberto Bohnen, Vera Regina Mussoi Macedo, Elio Marcolin

QUANTITY AND QUALITY OF NOM IN 5 ACID SITES IN MID- AND SOUTHERN CHINA 30Guo Jingheng, Rolf D. Vogt

CARBON SEQUESTRATION IN SEMIARID PAMPEAN SOILS:ENVIRONMENTAL AND MANAGEMENT PRACTICES EFFECTS 34

Juan A. Galantini, Ramdn A. Rosell

NITROUS OXIDE EMISSIONS AS AFFECTED BY NO-TILLCROPPING SYSTEMS IN A SUBTROPICAL BRAZILIAN ACRISOL 37

Juliana Gomes, Falberni de S. Costa, Cimilio Bayer, JoSo Mielniczuk, Marisa C. Piccolo, Brigitte J. Feigl, Carios C. Cerri

EFFECT OF INOCULATED WHEAT STRAW ON HUMIFCATIONPROCESSES OF ERODED SOIL 40

Ognyan Kostov, Ekaterina Filcheva, Ngan Teng Ye

II - ORGANIC MATTER AND AQUATIC SYSTEM

HUMIC MATTER IN WATER TREATMENT - LEARNING FROM NATURE 45Fritz Hartmann Frimtnel, Gudrun Abbt-Braun, Margil Mueller, Thomas Brinkmann, Ulrich Lankes, Florenda Saravia

XI

Humic Substances and Soil and Water Environment

DEGRADATION OF LIGNIN MODELS BY SINGLET OXYGEN 48Ann McNally, Kristopher McNeill

HUMIC ACID ADSORPTION ON OXIDES: A MEANINGFUL COMPARISON OF DATA 52Etelka TombAcz, Erzs6bel 1116s, Andrea Majzik

LONG-TERM FIELD EXPOSURE OF PLANT TISSUE SUBMERGED IN AN EXTREMELYACIDIC MINING LAKE SEDIMENT: CHANGES IN CHEMICAL COMPOSITION ANDLIGNIN SIGNATURE 55

AbadChabbi, Cornelia Rumpel

PHOTOCHEMICAL AND MICROBIAL OXIDATION OF DISSOLVED ORGANIC MATTER:ROLE IN CARBON CYCLING IN ESTUARIES AND LAKES 57

Kenneth Mopper, Aron Stubbins, John Helms, David Kieber, Emily White

PHOTODEGRADATION OF DISSOLVED ORGANIC CARBON IN HUMIC COASTALLAGOONS (RJ, BRAZIL) 61

Albert L. Suhett, Fabiana MacCord, Andre M. Amado, Vinicius F. Farjalla, Francisco de A. Esteves

PHOSPHORUS COMPOSITION OF BENTHIC FLOC AND SOIL ALONGNUTRIENT GRADIENTS IN A SUBTROPICAL WETLAND 64

Benjamin L. Turner, Jana Newman, Susan Newman, K. flames/7 Reddy

CHARACTERIZATION OF DISSOLVED ORGANIC MATTER FROM LEACHATESOF AQUATIC MACROPHYTES AND DETRITUS OF THE SURROUNDINGVEGETATION OF A COASTAL LAGOON .: 66

Claudio C. Marinho, Vinicius F. Farjalla, Albert LSuhett, Bias M. de Faria, Francisco de A. Esteves

COMPARISON OF BENTONITE - HUMIC AND KAOLINITE - HUMIC SUSPENSIONS 69DragoljubD. Bilanovic, Timothy Kroeger, Steven A. Spigarelli

THE INFLUENCE OF PLANT COLONIZATION ON THE VERTICAL PROFILE OF FLUORESCENTORGANIC MATTER IN PORE WATERS FROM SALT MARSH SEDIMENTS _ 72

Eduarda Bastos Henriques dos Santos, Sofia Reis, Vanda Serra, Martinha Rodrigues, Armando Costa Duarte

INTERACTIONS OF CHLORINE AND CHLORINE DIOXIDE WITH TROPICAL AQUATICFULVIC ACIDS OBSERVED BY FLUORESCENCE SPECTROSCOPY 75

Eduarda Regina Carvalho, D6bora Marcondes Bastos Pereira Milori, Julio C. Rocha, Ladislau Martin-Neto

ADSORPTIVE FRACTIONATION OF HUMIC ACIDS BY MAGNETITE 77Erzsebet Illes, Etelka Tomb&cz

DETERMINATION OF LABILE METAL FRACTIONS IN AQUATIC HS BY MEANS OF ATANGENTIAL-FLOW ULTRAFILTRATION AND COPPER IONS AS COMPLEXANT AGENT 80

Gustavo Rocha de Castro, Julio Cesar Rocha, Wander Gustavo Botero, Ademir dos Santos, Andr4 Henrique Rosa, Pedro deMagalhaes Padilha, Peter Burba

HUMIFICATION OF VASCULAR AQUATIC PLANTS 82Irineu BianchiniJr, Marcela B. Cunha-Santino, Alexandre L. Bitar, Adalberto P. P. Toledo

DIVERSIFICATION OF PROPERTIES OF BOTTOM SEDIMENTS IN THESYSTEM OF WDZYDZE LAKES (NORTHERN POLAND) 85

Joanna Cieslewicz, SlawomirS. Gonet, Wlodzimierz Marszelewski, Patrycja Galganska

CONDITIONAL AND STOICHIOMETRIC STABILITY CONSTANTS OF CU(II) BYLAKE WATER FULVIC ACIDS '. 88

Joaquim C.G. Esteves da Silva, Pedro M.S.M. Rodrigues

OCCURRENCE OF THE RARE EARTH ELEMENTS IN COAL DERIVED HUMIC SUBSTANCES 91Karsten Franke, Doris R6!3ler, Bernd Wagner, Martin Melles, Hermann Kupsch

EVALUATION OF HUMIC AND FULVIC ACID CONTENTS IN PEAT SOILSFROM DIFFERENT BOGS AND FENS 93

Malgorzata Malawska, Boguslaw Wilkomirski

ANNUAL VARIATION OF MINERALIZATION RATES OF HUMIC SUBSTANCESIN A TROPICAL OXBOW LAKE (SAO PAULO, BRAZIL) 95

Marcela Bianchessi da Cunha-Santino, Irineu Bianchini Junior

XII

Contents

PH DEPENDENCE OF CH3HG+ AND HG2+ BONDING IN NATURAL ORGANIC MATTER 97Paul R Bloom, Abdul R. Khwaja, Patrick Brezonik, Chung-Ming Lin

FLUORESCENCE STUDY OF THE HS-PYRENE INTERACTIONS PH DEPENDENCE 100Thalita G. Rauen, Maria Marta de S. Sierra

FLUORESCENCE PROPERTIES OF COPPER (II) COMPLEXES WITH HUMIC ANDFULVIC ACIDS FROM PIG SLURRY AND AMENDED AND NON-AMENDED SOILS 103

Valeria D'Orazio, C6sar Plaza, Nicola Senesi, Alfredo Polo

HUMIFICATION DEGREE OF THE MEADOW-ALLUVIAL SOILS FROMDELTA OF AMU DARYA RIVER 106

Wilkomirski B., Malawska M., Abdrahmanov T, Tursunov L.

Ill - ECOLOGICAL FUNCTIONSOF HUMIC SUBSTANCESCHANGES IN PROPERTIES AND FUNCTIONS OF DOM

DURING LONG-TERM INCUBATION OF SOIL SAMPLES 111Bernd Marschner, DirkJddemann

THE CURRENCIES OF SOIL CARBON „ 1140. W. Hopkins, £. 6. Gregorich

THE EXPLOITATION OF SOIL ORGANIC MATTER RESERVES AS AN ENERGYSOURCE BY THE SOIL MICROBIAL BIOMASS 116

Maria De Nobili, M. Contin, N. .Mahieu, E. W. Randall, P. C. Brookes

POTENTIAL BIOLOGICAL EFFECTS OF ISOLATED HUMIC MATERIALS 119Jussi V.K. Kukkonen, Eija Schultz, Sari Pehkonen, Olli-Pekka Penttinen

ENDOCRINE DISRUPTING EFFECTS OF HUMIC SUBSTANCES IN AMPHIBS:INDICATIONS OF THE MOLECULAR MODES OF ACTION 123

Ilka Lutz, Zhang Jie,, Robert Opitz, WernerKloas,, Xu Ying, Christian E. W. Steinberg,

DISSOLVED ORGANIC MATTER IN SOIL 128Bozena Debska, SlawomirS. Gonet

BIOREMEDIATION OF HYDROCARBON POLLUTED SOIL THROUGHECOLOGICAL AND CHEMICAL TREATMENTS _ 131

CeccantiB., Garcia C, Masciandaro G., MacciC, Carmignani A., DoniS., BandiniS.

HUMUS STATE OF ACID SOIL POLLUTED WITH HEAVY METALS, AMENDED WITHORGANO-M1NERALMELIORANTS 132

Ekaterina Filcheva, Maya Benkova. Toshko Raychev

MEMBRANE DEPOLARIZATION AND ELEVATION OF ROS-DEFENSIVEMECHANISMS DUE TO THE IMPACT OF DISSOLVED NATURAL ORGANICMATTER (NOM) IN THE CHAROPHYTE NITELLOPSIS OBTUSA 135

Christian E. W. Steinberg, Levonas Manusadzianas, Reda Grigutyte,Rolandas Karitonas, Sigita Jurkoniene, Stephan Pflugmacher

DISSOLVED NATURAL ORGANIC MATTER (NOM) IMPACTS PHOTOSYNTHETICOXYGEN PRODUCTION AND ELECTRON TRANSPORT IN COONTAILCERATOPHYLLUM DEMERSUM 138

C. E. W. Steinberg, C. Pietsch, W. Rieger, S. Pflugmacher

HUMIC SUBSTANCES (NOM) MODIFY SWIMMING BEHAVIOR OF DAPHNIA MAGNA 142Daniela Baganz, Christian £ W. Steinberg, Stephan Pflugmacher

EFFECTS OF SOIL HUMIC ACID ON ALLELOPATHIC POTENTIAL OF ROOT EXUDATESFROM TOMATO PLANTS 145

Hisabetfa Loffredo, Stefania Laera, Nicola Senesi

HUMIC SUBSTANCES IN DEGRADED ECOSYSTEMS OF THE SNIEZNIK MASSIF,EAST SUDETY MTS., SOUTH WEST POLAND -148

Elzbieta Jaimoz, Andrzej Kocowicz, Lukasz Stawarz, Wojciech Zajac

XIII

Humic Substances and Soil and Water Environment

ECOLOGICAL FUNCTIONS OF WATER-SOLUBLE ORGANIC SUBSTANCES OF THEEAST EUROPEAN RUSSIAN TAIGA 151

£ Shamrikova

EFFECTS OF LOW TEMPERATURE ON SOIL ORGANIC MATTERCHARACTERISTICS AND CARBON TURNOVER 153

Fulvia Rosso, Michele Freppaz,, Luisella Cell, Martia Phillips, Veronika Stockli,Alberto Agnelli, Ermanno Zanini

TRANSFORMATION OF THE HUMIC COMPOUNDS IN DIFFERENTLY DEGRADED FORESTECOSYSTEMS IN THE KARKONOSZE MOUNTAINS, POLAND 155

Jerzy Drozd, Elzbieta Jamroz

THE EFFECTS OF HUMIC SUBSTANCES ON COPPER ACUTE TOXICITY TOCERIODAPHNIA SILVESTRII (DAPHNIIDAE) 158

Maria Alice Penna Firme dos Santos, Maria da Graca Gama MelSo, Ana Teresa Lombardi

HUMIC ACIDS OF ANTHROPOGENICALLY TRANSFORMED SOILS OFANCIENT SETTLEMENT 161

Olga lakimenko, Sergey Trofimov

MODELLING THE EFFECT OF DISSOLVED ORGANICMATTER ON COPPER ACTIVITY IN SOIL SOLUTIONS 165

Sagar Thakali, Alexander Ponizovsky, Herbert E. Allen, Dominic M. Di Tom

THE INFLUENCE OF HUMIC ACIDS ON THE PRIMARY PRODUCTION AND METABOLISM CHLORELLAVULGARIS 168

S.N. Chukov, M.S. Golubkov

REDOX STABILITY OF URANIUM(VI) IN PRESENCEOF SYNTHETIC AND NATURAL HUMIC ACIDS 172

Susanne Sachs, Gerhard Geipet, GertBernhard

ISOLATION AND CHARACTERIZATION OF HUMIC ACIDS IN SOIL COLLECTED AT JUNIPER BUTTERANGE, IDAHO 175

T. J. Cary, A. J. Palazzo, T. L. Bashore, N. Senesi, G. Brunetti, C. E. Clapp, J. J. Clapp,M. H. B. Hayes, K. Schmidt-Rohr, J. D. Mao

PHYSICO-CHEMICAL CHARACTERIZATION OF HUMICACIDS ISOLATED FROM A DEEP PEDOLOGICAL PROFILE 178

Teodoro M. Miano, Valeria D'Orazio, Donato Mondelli, Raffaele Lopez

CHANGES IN SOIL ORGANIC MATTER WITH FOREST DECLINE AT TANZAWAMOUNTAINS, KANTO DISTRICT, JAPAN 181

Teruo Higashi, Kenji Ohse, Kengo Morimoto, Haruo Tanaka, Kenji Tamura

INTERACTION OF NATURAL ORGANIC MATTER AND CALCIUM ON TOXICITY OFSUBSTANCES USED FOR THE TREATMENT OF EXTERNAL PARASITES IN FISH 184

Thomas Meinelt, B. Kent Bumison, Michael Pietrock, Angelika Stuber,Christian E. W. Steinberg

ENHANCED DETOXIFYING ABILITY OF HYDROQUINONES-ENRICHED HUMIC DERIVATIVESWITH RESPECT TO COPPER 189

Vladimir A. Kholodov, Anton N. Kovalenko, Natalia A. Kulikova,Galina F. Lebedeva, Irina V. Perminova

IV - ORGANIC AGRICULTURE AND PLANT GROWTH EFFECTS

THE ROLE OF HUMIC SUBSTANCES AND DOM IN METAL BINDING AND PLANT GROWTH 195Yona Chen, Maria De Nobili

CHEMICAL AND BIOLOGICAL ASPECTS OF EFFLUENT IRRIGATION ONORGANIC SOIL COMPONENTS 198

Elisabeth Jueschke, Bemd Marschner, Jorge Tarchitzky, Yona Chen

PHYSIOLOGICAL EFFECTS OF HUMIC LIKE SUBSTANCES ON MAIZE 200Sons Eyheraguibel, Jerome Silvestre, Phillipe Morard

XIV

Contents

BIOTESTING OF HUMIC PREPARATIONS FROM PRODUCTS OF ANAEROBIC FERMENTATIONOF ORGANIC RAW MATERIAL 203

Sharipa Jorobekova, Kamila Kydralieva

HUMIC STIMULATION OF TOMATO GROWTH IN SOIL AND HYDROPONICS 205Steven A. Spigarelli, Russell D. Essner, Sandra Mateega

EFFECT OF FULVIC ACIDS ON PLANT GROWTH, ROOT MORFOLOGY AND MACRONUTRIENTUPTAKE BY OAT PLANTS 207

Caria Machado da Rosa, Rosa Maria Vargas Castilhos, Ledemar Carios Vahl,Paula Fernanda Pinto da Costa

LOW MOLECULAR WEIGHT AND HUMIC ACIDS INCREASE PHOSPHORUS UPTAKE AND CORNGROWTH IN OXISOLS 211

Felipe Vaz Andrade, Eduardo de Si Mendonga, Ivo Ribeiro Silva, Renato Faria Mateus

RELATIONSHIP BETWEEN PHYSICOCHEMICAL PROPERTIES OF HUMIC ACIDS OFSOILS FfcOM SOUTHERN CHILE AND BIOLOGICAL ACTIVITY 215

Josefina Canales, Maria de la Luz Mora, Maria J. Aguirre, Minerva Gonzilez-lbarra,Beatriz King-Diaz, Bias Lotlna-Hennsen

VARIATION IN SOIL PHYSICAL-CHEMISTRY PARAMETERS AND BLACKBERRY (RUBUS SPP.)PRODUCTION AS AFFECTED BY COMPOSTED SUGAR MILL BY-PRODUCT ADDITION 217

J. Venegas G., CajusteJ. L, Trinidad S. A., GaviR. F., S&nchezG. P.

HUMIC SUBSTANCES FROM THE PRODUCTS OF ANAEROBICFERMENTATION OF ORGANIC SUBSTRATES 220

Kamila Kydralieva, Sharipa Jorobekova, Elnura Khudaybergenova, Vladimir Muratov

EVALUATION OF HUMIC ACIDS BIOACTIVITY BY A ROOT H+ EXTRUSION ASSAY 223Luciano Pasqualoto Canellas, Claudio Retamal, Daniel Basilio Zandonadi,

Arnoldo Rocha Facanha

COMPOSITIONS OF HUMIC-TYPE SUBSTANCES FROM ASCOPHYLLUMNODOSUM AND THE INFLUENCES ON GRASS GROWTH OF SEAWEEDEXTRACTS AND OTHER ORGANIC AMENDMENTS 226

R. J. Mclnemey, M. H. B. Hayes, C. E. Clapp, P. Cross, P. Pereira

SOIL AND PLANT RESPONSE TO ORGANICAMENDMENTS TO THREE STRAWBERRY CULTIVARS 230

ShankarGanapathi Shanmugam, Philip R. Warman

INFLUENCE OF HUMIC ACID IN THE ACTIVITY OF H+-ATPASES IN TRANSFORMED ROOTS OFCLOVER COLONIZED OR NOT FOR ARBUSCULAR MY CORRHIZAL FUNGI 233

Wallace Luis de Lima, Fabiola S. Rodrigues, Thiago P. Raposo, Gisele C.M.B. Tavares, Andr6a A. Lima, Orivaldo J. Saggin-Junior, Ricardo L.L. Berbara, Sonia R. de Souza

HIGH RESOLUTION MASS SPECTROMETRIC ANALYSIS OF DOM FROM A FIRE-IMPACTEDWATERSHED: EVIDENCE FOR EXPORT OF TERRESTRIAL BLACKCARBON TO AQUATIC ECOSYSTEMS 236

William Hockaday, Amanda Grannas, Sunghwan Kim, Patrick Hatcher

V - STRUCTURAL ASPECTS AND CHARACTERIZATION OFHUMIC SUBSTANCES

INTERCOMPARISONS OF SOME NEW APPROACHES FOR INVESTIGATING THE MOLECULARWEIGHT DISTRIBUTION OF DISSOLVED ORGANIC MATTER 241

Patrick G. Hatcher, Sunghwan Kim,, Yuko Sugiyama

PYROGENIC HUMIC SUBSTANCES - HOW RELIABLE IS THEIR ANALYSIS WITH NMRSPECTROSCOPY? 244

Heike Knicker, Kerstin Abelmann, Francisco J. GonzAiez-Vila, Gonzalo Almendros, Ingrid Kogel-Knabner

TRANSFORMATIONS OF PLANTS TO HUMIC SUBSTANCES 247Corinna Maria Byrne, C. Edward Clapp, Michael H. B. Hayes

XV

Humic Substances and Soil and Water Environment

USE OF TRITIUM LABELED PREPARATIONS FOR DIRECT MEASUREMENTS OFHUMIC SUBSTANCE HYDROPHOBICITY AND THEIR INTERFACIALADSORPTION IN TOLUENE - WATER SYSTEM 251

G. A. Badun, V. Yu. Pozdnyakova, M. G. Chemysheva, Z. A. Tyasto, I. V. Perminova

A NEW RAPID BATCH PROCEDURE FOR THE DETERMINATION OF HUMIC AND FULVIC ACIDSAND ITS RELEVANCE FOR GEOCHEMICAL MODELLING OF HEAVY METAL LEACHING 254

Andr6 van Zomeren, Esther van der Weij Joris J. Dijkstra and Rob N.J. Comans

ULTRAHIGH RESOLUTION MASS SPECTROMETRY OF AQUATIC HUMIC SUBSTANCES:RECURRINGMOLECULAR THEMES AND POLYMERIC CHARACTER 257

William T. Cooper, Alexandra Stenson, Lori Milligan, Jeffery Chanton, Thorsten Dittmar, Timothy Filley

COMPARISON OF HUMIC SUBSTANCES FROM AEROSOLS WITHTHOSE FROM OTHER ORIGINS 261

Regina M. B. O. Duarte, Eduarda B. H. Santos, CasimiroA. Pio, Armando C. Duarte

ON THE CHEMICAL NATURE OF HUMIC SUBSTANCES: A DYNAMICEQUILIBRIUM OF INDIVIDUAL MACROMOLECULES, SMALL MOLECULES ANDSUPRAMOLECULES GOVERNED BY THE ENVIRONMENTAL CONDITIONS 266

Jose M' Garcfa-Mina,, Maria Fuentes, Roberto Baigorri, Gustavo Gonzalez-Gaitano

INTEGRATION OF THE POLYPHENOL AND MAILLARD REACTIONS INTO A UNIFIED ABIOTICPATHWAY FOR HUMIFICATION IN NATURE: THE ROLE OF D-MNO2 269

A. Jokic, M.C. Wang, C. Liu, A. I. Frenkel, P.M. Huang

CHARACTERIZATION OF HUMIC-LIKE SUBSTANCES ISOLATED OFATMOSPHERIC AEROSOL FROM SAO PAULO CITY, BRAZIL 271

Andr6 Henrique Rosa, Maria Lucia Pereira Antunes.Luciana Camargo de Oliveira, Paulo Artaxo

CONFORMATIONAL AND MOLECULAR STRUCTURE OF HUMIC SUBSTANCES BASED ON MASSSPECTROMETRIC METHODS 274

A. Piccolo, P. Conte, R. Spaccini, G. Fiorentino

ATMOSPHERIC PRESSURE CHEMICAL IONIZATION (APCI) AND ELECTROSPRAYIONIZATION (ESI) MASS SPECTROMETRY OF SIZE-FRACTIONS OF A SOIL HUMIC ACID 277

Alessandro Piccolo, Michael Spiteller

A THERMOGRAVIMETRIC STUDY OF SALT MARSH SEDIMENTARY HUMIC ACIDS 281Ana Mendonca, Eduarda B. H. Santos, Armando C. Duarte

EMPLOYMENT OF TWO DIFFERENT MODELS TO FIT POTENTIOMETRIC DATA OF HUMICSUBSTANCES 284

Andreia Neves Femandes, Cristiano Giacomelli, Denise de Oliveira Vaz, Marcelo Giovanela, Maria Maria de Souza Sierra,Bruno Szpoganicz

CHARACTERIZATION OF HUMIC ACIDS ISOLATED BY VARIOUSEXTRACTANTS FROM AZRAQ OASIS, JORDAN 287

Bassam El-Eswed, Fawwaz Khalili, JalalZahra

EPR, NMR AND DRIFT SPECTROSCOPY DATA, ANALYZED BY CHEMOMETRIC METHODS, FORCONSIDERATIONS OF CHEMICAL STRUCTURES OF HUMIC SUBSTANCES FROM SOILS INDIFFERENT MANAGEMENT SYSTEMS 291

BetSnia Fraga Pereira, Antonio Salvio Mangrich, Michael H. B. Hayes, lara Messerschmidt, Fabio Andrade Silva, JulietaAdriana Ferreira

IRON (III)-PROMOTED OXIDAT1VE COUPLING: MODEL REACTIONS FORCARBON STABILISATION IN SOILS 294

C. Bos-VanderZalm.. P. J. Wallis, K. J. Booth, A. F. Patti,, J. L. Scott

EPR AND DRIFT CHARACTERIZATION OF HUMIC FRACTIONS FROM SAWDUST-PAPERMILL SLUDGE COMPOST 297

IMPACT OF LAND USE AND MANAGEMENT SYSTEM ON THE DISTRIBUTION AND QUALITY OFORGANIC MATTER IN PHYSICAL FRACTIONS OF A FERRASOL FROM SOUTHERN BRAZIL 299

Clodoalda Aldno A. dos Santos, Deborah P. Dick,, Heike Knicker,Ommo Bayer, Egon Klamt, Ingrid Kdgel-Knabner

XVI

Contents

REFERENCE SUWANNEE RIVER FULVIC ACID INTERACTIONS WITH COPPER (II) IONS 303Denise de Oliveira Vaz, Andreia Neves Fernandes, Maria Maria de Souza Sierra, Bruno Szpoganicz

SEPARATION OF PHENOLICS COMPOUNDS FROM LIGNIN DEGRADATION BYCAPILLARYELECTROPHORESIS 306

Diana L. D. Lima, Armando C. Duarte, Valdemar I. Esieves

THERMAL DEGRADATION KINETICS PARAMETERS OF HUMIC ACIDS WHEN FREE ANDANCHORED ONTO SILICA GEL SURFACE 309

Elaine A. Faria, Barbara S. Miranda, Paolla C. Martins, Alexandre G. S. Prado

INFLUENCE OF DIFFERENT TILLAGE PRACTICES AND WEED CONTROLSYSTEMS ON SOIL HUMIC AND FULVIC ACIDS 311

Emanuela Magherita, Gennaro Brunetti, Vito La Ghezza, Donato De Giorgio, Nicola Senesi

SPECTROSCOPIC STUDIES OF SOIL HUMIC ACIDS FROM TILLAGE SYSTEMSEXPERIMENTS - MULTIVARIATE DATA ANALYZES 314

Etelvino Henrique Novotny, Ladislau Martin-Neto

STUDY OF AMAZON ANTHROPOGENIC HUMIC ACID BY ATOMIC FORCE MICROSCOPY (AFM) 318Fibio de Lima Leite,, Tony Jarbas Ferreira da Cunha,, Ladislau Martin /Veto,, Beata Madari, Gabriel A. Santos, Luiz Henrique

Capparelli Mattoso,, Paulo S. de P. Herrmann

FLUORESCENCE CHARACTERISTICS OF BLACK SOIL HUMIC ACIDS FROM BRAZIL 321Gldria Maria Mauricio, Raul Almeida Nunes, Vinicius de Melo Benites

CHANGES IN THE CHARACTER OF ORGANIC MATTER DERIVED FROM WASTEWATERDURING SAND FILTRATION 324

Gudrun Abbt-Braun, Thomas Brinkmann, Sebastian Hesse, Fritz H. Frimmel

ISOLATION, FRACTIONATION, AND CHARACTERIZATION OF HUMIC SUBSTANCESFROM A MAIZE-AMENDED SOIL 327

Guixue Song and Michael M.B.Hayes

ANALYSIS OF CONCENTRATION EFFECT ON LASER-INDUCED FLUORESCENCE OF HUMICACIDS IN SOLID SAMPLES 332

Helder Vinicius Avanco Galeti,, D6bora Marcondes Bastos Pereira Milori,Tony Jarbas F. Cunha,, Ladislau Martin-Neto, BeAta Madari,Vinicius de M. Benites, Gabriel de Araujo Santos

CLOSE ASSOCIATIONS BETWEEN O-ALKYL C AND IRON OXIDES IN CLAY FRACTIONS 335Ingo SchOning, Heike Knicker, Ingrid Kogel-Knabner

TRANSFORMATIONS OF ORGANIC MATTER IN SOILS COMING FROM VARIOUS SOURCES 338Jolanta Kwiatkowska, Piotr Sklodowski, Alina Maciejewska

MONITORING THE HUMIFICATION PROGRESS DURING COMPOSTING OF "ALPERUJO",A SOLID BY-PRODUCT FROM THE OLIVE OIL INDUSTRY 341

Juan Cegarra, Jos6 Gonzilvez, Jos4 Antonio Alburquerque, German Tortosa, Diego Garcia

ASSESSMENT BY FLUORESCENCE SPECTROSCOPY OF THE LONG-TERM EFFECTS OFMUNICIPAL WASTE COMPOST AMENDMENT ON SOIL HUMIC ACIDS 345

Juan C. Garcia-Gil, Nicola Senesi, CAsar Plaza, Genaro Brunetti, Alfredo Polo

NMR EVIDENCE FOR DIFFERENCES IN HUMIC FRACTIONS 348Julieta A. Ferreira,, Jingdong Mao, Michael H. B. Hayes, Ana Belen Pedrosa, Betania F. Pereira,, Giuxue Song, Klaus Schmidt-

Rohr

CHEMICAL STRUCTURES OF HUMIC ACID FROM COMPOST DURING THE MUSHROOMAGARICUS BRASILIENSIS GROWTH 352

K&tia Cylene Lombardi, Antonio Salvio Mangrich, Tatiane do Valle, Jeniffer Vanelle dos Santos

THE EFFECT OF TOTAL ORGANIC CARBON (TOC) CONCENTRATION ON THE PHYSIO-CHEMICALPROPERTIES OF DISSOLVED NATURAL ORGANIC MATTER (DNOM) 355

Magnus Christiansen, Tone C. Gadmar, Egil T. Gjessing. RolfD. Vogt

FLUORESCENCE SPECTROSCOPY COMPARISON OF SOIL HUMIC ACIDS AND MODEL HUMICACID-TYPE POLYMERS 358

Marcilene Ferrari Barriquello,, OGbora Marcondes Bastos Pereira Milori, Eduardo Almeida Neves, Ladislau Martin-Neto

XVII

Humic Substances and Soil and Water Environment

STRUCTURAL CHARACTERIZATION OF BROWNWATER SEC FRACTIONS BY 13C MAS NMRSPECTROSCOPY 361

Margit Barbara Mueller, Ulrich Lankes, Gudrun Abbt-Braun, Fritz Hartmann Frimmel

STRUCTURAL ASPECTS OF AQUATIC HUMIC SUBSTANCES IN A PATAGONIC RIVER 365Maria del Carmen Scapini, Victor Conzonno, Vilma Balzaretti, Alicia Fernandez Cirelli

SPECTROSCOPIC CHARACTERIZATION OF SOIL ORGANIC MATTER FRACTIONS FROMRHIZOSPHERE AND BULK SOILS CULTIVATED FOR TOMATO AND ARTICHOKE 368

Maria Grasso, Valeria D'Orazio, Nicola Senesi

SPECTROSCOPIC AND THERMAL INVESTIGATION ON HYDROPHOBIC AND HYDROPHILICFRACTIONS OF DISSOLVED ORGANIC MATTER ISOLATED FROM VARIOUS SUBSTRATES 372

Maria Rosaria Provenzano, Giovanni Gigliotti, Antonella Cilenti, Flora Erriquens, Nicola Senesi

NEW INSIGHTS INTO THE MACROMOLECULAR AND SUPRAMOLECULAR NATURE OF HUMICSUBSTANCES: AN ULTRAFILTRATION-HPSEC STUDY 374

Maria Fuentes, Roberto Baigorri, Gustavo Gonzalez-Gaitano, Jose M' Garcfa-Mina,

NEW APPROACH TO EQUILIBRIUM SORPTION ON SOLID HUMIC ACIDS 377Martina KlucAkovA

CONTROL OF COAGULATION PROPERTY OF HUMIC ACID BY THE MODIFICATION WITHBIO-RELATED COMPOUND 380

Motoki Terashima, Shunitz Tanaka, Masami Fukushima

TRITIUM-LABELED HUMIC PREPARATIONS AS A PERSPECTIVE TOOL FORMEMBRANOTROPIC STUDIES 383

Natalia A. Kulikova, GennadiiA. Badun, Irina V. Perminova, Violetta Yu. Pozdnyakova, Elena Yu. Belyaeva, Alexei V.Kudryavtsev

CHARACTERIZATION OF HUMIC SUBSTANCES IN VARIOUS SOILS AND WATERS BY"C NMR SPECTROSCOPY 386

Nobuhide Fujitake, Khan Nazmul Ahsan, Yukiko Yanagi, Daichi Asakawa, Takeshi Suzuki, Hiroki Kodama, Seiya Nagao,Masayuki Tani

DIFFERENCES AND SIMILARITIES OF SOIL HUMIC ACIDS FRACTIONATED BYCOUPLING SEC-PAGE 389

Oleg Trubetskoj, Olga Trubetskaya, Claire Richard, Cesareo Saiz-Jimenez

COMBINATION OF ELECTROFOCUSING WITH TANDEM SEC-PAGE FOR ANALYSIS OF HUMIC-LIKEACID SUBSTANCES DURING COMPOST MATURATION 392

Olga Trubetskaya, Oleg Trubetskoj, Luciano Covani, Marco Grigatti, Claudio Ciavatta

QUAD-QUANTITATIVE CHARACTERIZATION OFPEAT, LEONARDITE AND LIGNITE HUMIC ACIDS 394

Omella Francioso, Daniela Montecchio, Paola Gioacchini, Claudio Ciavatta

CHARCOAL DERIVED HUMIC ACIDS: SYNTHESIS AND CHARACTERIZATION 396Patrick Marques Trompowsky, Vinicius de Melo Benites,

Alexandre Santos Pimenta, Rondinele de Oliveira Mouta

COMPARISON OF HUMIC SUBSTANCES FROM AEROSOLS WITHTHOSE FROM OTHER ORIGINS 399

Regina M. B. O. Duarte, Eduarda B. H. Santos, Casimiro A. Pio, Armando C. Duarte

THE IMPORTANCE OF METAL BRIDGES IN THE FINAL MOLECULAR CONFIGURATIONAND CONFORMATION OF HUMIC SUBSTANCES IN SOLUTION 404

Roberto Baigorri, Marta Fuentes, Gustavo GonzAlez-Gaitano, Jose M' Garcia-Mina,

FLUORESCENCE SPECTROSCOPY APPLIED TO HUMIC ACIDSEXTRACTED FROM PEAT AND VERMICOMPOST 407

RossineAmorim Messias, Debora Marcondes, Bastos Pereira Milori, Maria Olimpia de Oliveira Rezende

FUNCTIONAL GROUP DYNAMICS OF SOIL ORGANIC MATTER DECOMPOSITION INFOREST AND GRASS ECOSYSTEMS DESCRIBED BY NMR, DIFFERENTIALUV-VIS AND FT-tR SPECTROSCOPY 409

Ryan Fimmen, Daniel D.RichterJr., Dharni Vasudevan

XVIII

Contents

STUDY ON THE THERMODYNAMICS STABILITY OF SOIL HUMIC AND FULVIC ACIDS 413Sen Dou, Yves Tardy, Jinjing Zhang, Lifeng Ping, Shuiqiang YU, Lili Wang

THE 13C-NMR STUDY OF THE MOLECULAR STRUCTUREOF HUMIC ACIDS FROM SOILS OF RUSSIAN PLAIN 416

S. N. Chukov, E. D. Lodygin, V. A. Beznosikov

SOME CHARACTERISTICS OF THE HUMIC ACIDS OF THE AMAZONIAN DARK EARTH SOILS 419Tony Jarbas F. Cunha,, BeAta Madari, Vinicius de M. Benites, Gabriel de A. Santos, Luciano P. Canellas, Ladislau Martin Neto

USING CAPILLARY ELECTROPHORESIS TO ANALYSE PHENOLICCOMPOUNDS DERIVED FROM HUMIC SUBSTANCES DEGRADATION 422

Valdemarl. Esteves, Diana L D. Lima, Armando C. Duarte

CHANGES IN STRUCTURAL PROPERTIES OF HUMIC SUBSTANCES TRANSFORMED BYENZYMATIC REACTIONS 425

Yukiko Yanagi, Keiichi Kitayama, Takeshi Suzuki, Nobuhide Fujitake

AGGREGATION BEHAVIOR OF DISSOLVED ORGANIC MATTER EXTRACTED FROM THESPENT MUSHROOM SUBSTRATE (SMS) 428

Yuko Sugiyama, Patrick G. Hatcher

VI - SOIL AMENDMENT AND REMEDIATION: THE ROLE OF HUMIC SUBSTANCES

HUMIC ACIDS IN COMPOSTED MATERIALS AND IN COMPOST-AMENDED SOILS 433Nicola Senesi

ORGANIC MATTER DYNAMICS DURING IN-VESSEL COMPOSTING OFPAH-CONTAMINATED SOLID WASTE 437

Blanca Antizar-Ladislao, Joe Lopez-Real, Angus James Beck

PAH SEQUESTERED IN SOIL ORGANIC MATTER, BIOAVAILABILITY TO MICROBIAL ENZYMES 440Jeffrey W. Turner, Paula Mazzer, Patrick G. Hatcher

BIOREMEDIATION OF HYDROCARBON POLLUTED SOIL THROUGHECOLOGICAL AND CHEMICAL TREATMENTS 442

Ceccanti Brunello, Garcia Carlos, Masciandaro Grazia, Macci Cristina, Carmignani Alessia, Doni Serena, Bandini Silvio

ALUMINUM ORGANIC COMPLEXES AS AFFECTED BY PLANT RESIDUES 445ClAudio Celestino de Oliveira, Marcos Antonio Pavan, Mario Miyazawa

HUMIFICATION PROCESSES IN SOIL OF FRESH ORGANIC MATERIALS AND COMPOST 448Francesco Alianiello, Alessandra Ciampa, Anna Benedetti

EFFECTS OF SOIL CESIUM CONTAMINANTS ON RAPE (BRASSICA CAMPESTRIS) ROOTEXUDATES OF LOW MOLECULAR WEIGHT ORGANIC ACIDS IN RHIZOSPHERE SOILS 451

Po Neng Chiang, Ming Kuang Wang, Jeng Jong Wang and Chih-Yu Chiu

ORGANIC MATTER COMPOSITION IN TROPICAL SOILS IN THE MONTAINOUS REGIONS OFNORTHERN LAOS AS INFLUENCED BY SLASH AND BURN AGRICULTURE AND EROSION 454

Cornelia Rumpel, Marie Alexis, Abad Chabbi, Vincent Chaplot, Andr6 Mariotti

VII -APPLICATIONS OF HUMIC PRODUCTS: COMMERCIAL, COMPOSTING,AGRICULTURE, ENVIRONMENTAL AND POLLUTION CONTROL,

MEDICINAL, SENSORS, OTHERS

PROSPECTIVE APPLICATION OF ORGANOGENIC MATERIALS AS SORBENTS OF HEAVYMETALS FOR ENVIRONMENTAL POLLUTION CONTROL 459

Irena Twardowska, Joanna Kyziol

INVESTIGATIONS ON THE UV-B PROTECTIVE EFFECT OF HUMIC ACIDS ANDHUMIC ACID LIKE POLYMERS 462

Renate Klocking, Simone KOhn, Hans-Peter Klocking

XIX

Humic Substances and Soil and Water Environment

INTERACTION OF HUMIC SUBSTANCES WITH METAL IONS: STUDY OF THE SELECTIVITYOF HUMIC SUBSTANCES AND POSSIBLE TERAPEUTIC APPLICATIONS 465

Ademir dos Santos, Wander Gustavo Botero, Antonio Francisco Godinho, Julio Cesar Rocha

HUMIC ACIDS AS ANTI-INFLAMMATORY AGENTS 469A. Duncan Cromarty, Constance E. J. van Rensburg

SYNTHESIS AND CHARACTERIZATION OF HUMIC DERIVATIVES ENRICHED WITHHYDROQUINOIC AND CATECHOLIC MOIETIES 472

A. Kovalenko, M. Youdov, I. Perminova, V. Petrosyan

HUMIC SUBSTANCES APPLIED TO THE DETOXIFICATION OF THE SOLID WASTEFROM INGA BRAZILIAN ZINC COMPANY 474

Alexander I. Shulgin, Raul A. Nunes, Eduardo A. Brocchi, Maria Clara K. Faller

PIG SLURRY: NITROGEN AND PHOSPHORUS LOSS AND CONCENTRATION OFMETALS IN THE SOIL AND THEIR RELATION WITH THE ENVIRONMENT QUALITY 477

Carios Alberto Ceretta, Claudir Jos6 Basso, Eduardo Girotto, Isabel Cristina Lopes Moreira, Eder Trentin, Elizandra Pocojeski,Jorge Luis Manias

EVOLUTION OF HUMIC ACID PROPERTIES DURING CO-COMPOSTING OF OLIVE OIL MILLWASTEWATER SLUDGE MIXED WITH TREE CUTTINGS 480

C6sar Plaza, Nicola Senesi, Gennaro Brunetti, Donato Mondelli

ADSORPTION OF ADENINE OR ADENOSINE ON A CALCIUM-LOADED SOLID HUMIC ACID 483Elham A. Ghabbour, Jennifer Blakeman, Kaveri Datta, Kene Piasta, Geoffrey Davies

ADSORPTION OF NUCLEIC ACID CONSTITUENTS ADENINE AND ADENOSINE ON ANIRON (III)-LOADED SOIL-DERIVED HUMIC ACID 487

Elham A. Ghabbour, Kathleen Collins, Jong-Sum T. Park, Meredith Price, Geoffrey Davies

A MAGNESIUM-LOADED HUMIC ACID AS AN ADSORBENT OF THE NUCLEIC ACIDCONSTITUENTS URACIL AND URIDINE 491

Elham A. Ghabbour, Lauretta Kennedy, Christine Nguyen, Ahmed Shareb,

HUMIC ACID-BOUND MAGNESIUM CATALYZES ADENOSINE HYDROLYSIS 494Elham A. Ghabbour, Stephen McNutt, and Geoffrey Davies

CHEMICAL AND PHYSICAL CHARACTERIZATION OF PEAT FROM JACONE, SAQUAREMA,RIO DE JANEIRO (RJ) STATE, BRAZIL, FOR USE AS A SOIL AMENDMENT 497

Ernest Ramiarina

EFFECT OF ORGANIC AMENDMENTS ON BIOCHEMICAL PARAMETERS OFSUBSTRATES AND PLANT GROWTH 500

Giuseppe Piccone, Eligio Malusa, Michele Negre, Sofia Cavaciuti, Daniela Vindrola

COAGULATION FACTORS AS TARGETS OF NATURALLY OCCURRING HUMIC ACIDS ANDSYNTHETIC HUMIC ACID LIKE POLYMERS 504

Hans-Peter Klocking, NicolleMahr, Renate Klocking, Kari Heinz Heise, Wilhelm Herdering

DESIGN OF HUMIC MATERIALS OF A DESIRED REMEDIAL ACTION 506Irina Perminova, Anton Kovalenko, Vladimir Kholodov, Matvey Youdov, Denis Zhilin

EVALUATION OF SUNFLOWER GROWTH AND LEAVES PROTEIN EXPRESSION ATDIFFERENT CONDITIONS 509

Jerusa S/mone Garcia, Marco Aur&io Zezzi Arruda

THE EFFECT OF THE UREA ADDITIVE TO THE COMPOSTED MUNICIPAL WASTES ON THESELECTED HUMIFICATION PARAMETERS 513

Jerzy Drozd, Michal Licznar

THE INFLUENCE OF HUMIC ACIDS ON THE TREATMENT OF PAH CONTAMINATEDSEDIMENTS BY THE ELECTROCHEMICAL GEOOXIDATION TECHNOLOGY ASMONITORED BY PYROLYSIS GC-MS 516

J. Kenneth Wittle, Falk Doering, Lawrence M. Zanko

COOPER, ZINC AND MANGANESE IN SOILS UNDER APPLICATION OF PIG SLURRY INMICROCATCHMENTS IN SANTA CATARINA „ 519

Jorge Luis Mattias, Isabel Cristina Lopes Moreira, Carlos Alberto Ceretta, Elizandra Pocojeski, Eder Trentin, Eduardo Girotto,OedimarLorenzi

XX

Contents

COMPARISON WITH PYROLYSIS-GELMS OF ORGANIC MATTER IN COMPOSTED AND FRESHWASTES AS A TOOL TO EVALUATE COMPOST COMPOSITION AND STABILITY 522

Marie-France Dignac, Ce'dric Francou, Maelenn Poitrenaud, Sylvie Derenne, Sabine Houot

IDENTIFYING CRITERIA TO SELECT A SUITABLE BIOWASTE COMPOST TO USE AS A LANDFILLCOVER MATERIAL TO ENHANCE METHANE OXIDATION 525

Mark Chapman, Joe Lopez-Real, Liz Baggs, Angus J. Beck

EFFECTS OF COMMERCIAL HUMATE ON TOMATO GROWTH 527Michel Kaemmerer, Boris Eyheraguibel

ORGANIC-MINERAL COMPLEX FOR SOIL REMEDIATION 530Miloslav Pekao, Martina KlueAkovA, Gabriela BaraneikovA,

MikulAS Madaras, Jarmila MakovnikovA

EFFICIENCY OF HUMIC ACIDS AND FULVIC OF LEONARDITE (NATURVITAL PLUS)APPLIED IN THE CULTURE OF THE GRAPE 533

Paulo Augusto da Costa Pinto, Airton Soares de Carvalho, Joaquim Pereira Ne'i

HUMIC SUBSTANCES APPLIED TO THE PURIFICATION OF THE WASTEWATERFROM INGA BRAZILIAN ZINC COMPANY 535

Raul A. Nunes, Alexander I. Shulgin, Eduardo A. Brocchi, Maria Clara K. Faller

PRODUCTION OF HUMIC AND FULVIC ACIDS FROM DIFFERENT ORGANIC RAW MATERIALS 538Ricardo Munoz da Silva, Silvia dos Santos Garcia, Luiz Rodeval Alexandre, Vanessa Fabre de Mello, Andri Jablonski

EFFECTS OF OXIDATION IN BRAZILIAN COAL FOR HUMIC ACID PRODUCTION 541Silvia dos Santos Garcia, Ricardo Mundz da Silva, Daniela B. Mom, Andr6 Jablonski

LACCASE STABILIZATION IN THE PRESENCE OF COAL HUMIC ACIDS 545Valentina N. Davidchik, Natalia A. Kulikova, Olga V. Koroleva

THERMOGRAVIMETRIC AND ELEMENTAL ANALYSIS OF ANTARCTIC SOIL HUMIC ACIDS 547Vinicius de Melo Benites, Roberto Ferreira Machado Michel, Luis Eduardo Dias, Carios Ernesto G. Reynaud Schaefer, Eduardo

de SA Mendonca

HUMIFICATION DEGREE OF FERMENTATED URBAN RESIDUES DETERMINED BY CHEMICALAND SPECTROSCOPIC METHODS 550

Wilson Tadeu Lopes da Silva, Renata Natsumi Haneda, Antonio Pereira de Novaes, Marcelo Luiz Simdes,, Lucimar LopesFialho, Decora Marcondes Pereira Milori, Ladislau Martin-Neto, Joao Batista de Campos, Nagib AnderAos Neto, MArioNajm Filho, Luiz Carios Pereira de Almeida, Daniel Silveira

VIII - XENOBIOTICS AND HUMIC SUBSTANCES INTERACTIONS

EXPERIMENTAL CONCEPTS TO UNDERSTAND SOIL FUNCTIONS - BINDING ANDREMOBILISATION OF PESTICIDES 557

Peter Burauel, Frauke Schnitzler, Anne Bems

PHOTOCHEMICAL PROPERTIES OF HUMIC-LIKE MATERIALS EXTRACTED FROM COMPOSTS 559Olga Trubetskaya, Oleg Trubetskoj, Ghislain Guyot, Jean-Pierre Aguer, Claire Richard, Luciano Cavani, Marco Grigatti, Claudio

Ciavatta

STUDIES ON THE SORPTION OF PCBS TO DNOM FROM DIFFERENT SURFACE WATERS 562Christine Steiro, Georg Becher,, Alfred Christy, Egil T. Gjessing

HUMIC SUBSTANCES: THERE'S MORE TO LIFE THAN SOLUBILITY 566Philip R. Warman,, Michael D. Munroe

A POTENTIOMETRIC AND 113CD NMR STUDY OF CADMIUM COMPLEXATION BY NATURALORGANIC MATTER AT TWO DIFFERENT MAGNETIC FIELD STRENGTHS 569

E. Michael Perdue, Norbert Hertkom, Antonius Kettrup

ADSORPTION AND THERMOCHEMICAL DATA OF DIVALENT CATIONS ONTO SILICA GELSURFACE MODIFIED WITH HUMIC ACID AT SOLID/LIQUID INTERFACE 573

Alexandre G. S. Prado, BArbara S. Miranda, Luiz F. Zara

INTERACTION BETWEEN DISSOLVED ORGANIC MATTER AND TRIASULFURON: A CHEMICALAND SPECTROSCOPIC STUDY 576

Daniel Said-Pullicino, Giovanni Gigliotti, Maria Rosaria Provenzano, Antonella Cilenti

XXI

Humic Substances and Soil and Water Environment

SPECTROSCOPIC STUDY OF THE INTERACTION BETWEEN AHUMIC ACID AND AN OXAZINE DYE 579

Graciela P. Zanini, MarceloJ. Avena, Sarah Fiol, Florencio Arce, Ramdn R. Rosell

OXIDATIVE COUPLING OF HUMAN AND VETERINARY PHARMACEUTICALS WITHMONOMERIC HUMIC PRECURSORS 582

Heidi M. Balk, Joel A. Pedersen,

A METHODOLOGICAL APPROACH FOR STUDYING THE CHEMICAL INTERACTIONS BETWEENPHOSPHORUS AND HUMIC SUBSTANCES 585

maki Guardado, Oscar Urrutia, Jose Ms Garcia-Mina,

OXIDATION OF ATRAZINE BY HYDROGEN PEROXIDE IN THE PRESENCE OFFERRIHYDRITE AND HUMIC ACID 588

Juliana Cristina Barreiro, Hans Christian Bruun Hansen, Ladislau Martin-Neto, Milton Duffles Capelato

ENVIRONMENTAL CATALYSIS BY HUMIC SUBSTANCES 591Man's Klavins

DETOXIFICATION OF PENTACHLOROPHENOL BY THE COVALENTBINDING WITH HUMIC ACID 593

Masami Fukushima, Akira Sawada, Kenji Tatsumi

EFFECT OF INTERACTION OF PROSULFOCARB WITH SOIL ORGANO-MINERALSURFACES ON ITS PLANT BIOACTIVITY 596

M. Negre, C. Boursier, C. Mozzetti, M. Gennari

TRIPLET STATES OF HUMIC ACIDS STUDIED BY LASER FLASH PHOTOLYSIS WITHDIFFERENT EXCITATION WAVELENGTHS 599

Natalia Sultimova, Peter Levin, Olga Chaikovskaya, Irina Sokolova

LINURON ADSORPTION BY SOILS AMENDED WITH ORGANIC WASTES 602Sonay Sozudogru Ok, Funda Cimen

IX - ORGANIC MATTER AND PROPERTIES OF TROPICAL SOILS

ORGANIC MATTER AND PROPERTIES OF TROPICAL SOILS 607Eduardo de SA Mendonca, Ivo Ribeiro da Silva

HUMIFICATION DEGREE OF ORGANIC MATTER IN WHOLE SOIL DETERMINED BYLASER-INDUCED FLUORESCENCE 609

Dibora Marcondes Bastos Pereira Milori, Helder Vmfcius Avanco Galeti, Ladislau Martin-Neto, Cim&io Bayer, Julio Salton,Martha Gonzal6s-P6rez,

SOIL ORGANIC MATTER AS AFFECTED BY LIMING IN THE ESTABLISHMENT OF ANO-TILLAGE SYSTEM 612

Eduardo FAvero Caires, Luis Reynaldo Ferracciu Alleoni, MichelAlexandro Cambri, Gabriel Barth, Fernando Jos6 Garbuio

DOES ANAEROBIC DECOMPOSITION OF CROP RESIDUES ALTER SOIL ORGANIC MATTERQUALITY AND NUTRIENT CYCLING? 615

Daniel C. Oik

CARBON AND NITROGEN STOCKS OF A ARENOSOL UNDER IRRIGATED FRUIT ORCHARDSIN NORTHEASTERN BRAZIL 618

Pedro L. O. A. Machado, Alberto C. de Campos Bernard!, Silvio Roberto de Lucena Tavares, Lindebergue A. Crisdstomo,David Vilas Boas de Campos,

COMPARISON OF LEVELS OF ALTERATIONS BETWEEN SECOND-GROWTH FORESTECOSSYSTEM AND AGROECOSYSTEM IN FUNCTION OF HUMIFICATION DEGREE 621

Alessandra Simone Santos de Oliveira, Hadley Dantas Freitas Solano, Fabiola Pereira de Azevedo, Carios Augusto Cordeiro

SOIL ORGANIC MATTER AND GEOMORPHIC SURFACE STABILITY RELATIONSHIPIN AN OXISOL TOPOSEQUENCE (SE BRAZIL) 623

Alexandre Christofaro Silva, Pablo Vidal Torrado, Ladislau Martin /Veto, Felipe Macias Vasquez. Martha GonzAlez P6rez

XXII

Contents

ORGANIC CARBON AND ELECTRIC CHARGES OF SOME HUMID TROPICAL SOILS 627Camila Beig JordSo, Luis Reynaldo Ferraccitl Alleoni

DESORPTION OF ZINC IN THE INTERACTIONS AMONG SOME MINERALS AND A RED LATOSOILWITH SEVERAL ORGANIC ACIDS 629

CAssia Fernanda Domingues Bassan, Adem6rcio Antonio Paccola, Pedro de MagalhSes Padilha

AFFINITY COEFFICIENTS FOR COPPER IN SOME BRAZILIAN SOILS 632Cintia M. Lopes, Rafael S. Rodrigues, Cindy S. Moreira, Luis R. F. Alleoni

ORGANIC CARBON AND ADSORPTION OF CD, CU, Nl AND ZN IN HUMID TROPIC SOILS 635Cindy Silva Moreira, Luis Reynaldo Ferracciu Alleoni, Jos6 Carlos Casagrande

DISSOLUTION AND RECRISTALIZATION OF METALS OF A "LATOSSOLO VERMELHO"PROVOKED BY THE SUCROSE ADDITION 638

Claudia Cristina Teixeira Nicolau Mendonca, Ademdrcio Antonio Paccola

REFRACTORY ORGANIC MATTER IN CONSTRUCTED SOILS AND COAL SAMPLESAND RECONSTRUCTED SOILS FROM A COAL MINING AREA IN SOUTHERN BRAZIL 643

Clodoaldo Alcino A. dos Santos, DDeborah P. Dick,, Heike Knicker, Cim&io Bayer, Egon Klamt, Ingrid Kogel-Knabner, LeticiaA. Gomes, Aline Dressier

DECOMPOSITION OF SOIL CARBON DERIVED FROM FOREST IN AN ULTISOL UNDER SUGARCANE OR BRACHIARIA SP. IN THE ATLANTIC FOREST REGION OF BRAZIL 647

David Vilas Boas de Campos, Pedro Luiz Oliveira de Almeida Machado, Sergio Pereira Braz, Gabriel de Araujo Santos,Eduardo Lima, Bruno Jose' Rodrigues Alves, Segundo Urquiaga, Robert Boddey

HUMIC ACIDS ISOLATED FROM TWO BIOSOLID-AMENDED BRAZILIAN OXISOLS 650Edna I. Bertoncini, Valeria D'Orazio, Nicola Senesi, M. E Mattiazzo

TOTAL ORGANIC CARBON IN A SUBTROPICAL ACRISOL AS INFLUENCED BY TILLAGESYSTEMS AND SPRINKLER IRRIGATION 654

Fabiano Daniel De Bona, Cime'lio Bayer, Homero Bergamaschi, Joao Mielniczuk, Jeferson Diekow

NO-TILL CROPPING SYSTEMS AND NITROGEN FERTILIZATION TO INCREASE SOIL ORGANICCARBON CONTENT IN A SUBTROPICAL ACRISOL 657

Frederico Costa Beber Vieira, Cime'lio Bayer, JoSo Mielniczuk, Josile'ia AcordiZanatta

STABILITY AGAINST PYROLYTIC CLEAVAGE AND THE OCCURRENCE OF EXTREMELYRECALCITRANT HUMIC MATTER IN SOUTHERN AFRICAN SOILS 660

Gonzalo Almendros, Francisco J. Gonzalez- Vila, Luigi P. D'Acqui. Giuseppe G. Ristori, M. Cristina Zancada, M. Teresa Pardo

PROPOSAL FOR BRAZILIAN TAXONOMY OF HISTOSOLSBASED ON HUMIC SUBSTANCE CONTENT 664

Gustavo Souza Valladares, Marcos Gervasio Pereira, Lucia Helena Cunha dos Anjos, Vinicius de Melo Benites, AdiersonGilvani Ebeling

SUCCESSIVE APPLICATIONS OF POTASSIC FERTILIZER IN AN OXISOL AND DISTRIBUTIONOF ORGANIC MATTER AND POTASSIUM 667

Heloisa Rangel Carraro, Gilmar Ribeiro Nachtigall, Michel Alexandro Cambri, Luis Reynaldo Ferracciu Alleoni

ORGANIC MATTER COMPOSITION OF A SUBTROPICAL ACRISOL AS INFLUENCED BY NO-TILLCROPPING SYSTEMS AND N-FERTILISER, ASSESSED BY CP/MAS 13C NMRSPECTROSCOPY 670

Jeferson Diekow, JoAo Mielniczuk, Heike Knicker, Cim&io Bayer, Deborah Pinheiro Dick, Ingrid Kdgel-Knabner

NO-TILLAGE AND LEGUMINOUS-BASED CROPPING SYSTEMSARE EFFICIENT STRATEGIES TOINCREASE CARBON CONTENT IN A SUBTROPICAL SOIL 674

Josile'ia Acordi Zanatta, Cime'lio Bayer, Jeferson Diekow, JoSo Mielniczuk

SOIL TILLAGE SYSTEM EFFECTS IN THE FORMATION OFHYDROPHOBIC SITES IN HUMIC ACIDS 677

Marcelo L. Simoes,, Juliets Adriana Ferreira, Aline Segnini,, Wilson Tadeu Lopes da Silva, Cime'lio Bayer, Dibora MarcondesBastos Pereira Milori, Ladislau Martin Neto

CONTRIBUTION OF SOIL ORGANIC MATTER TO THE CATION EXCHANGE CAPACITY OFSOILS FROM SAO PAULO STATE, BRAZIL 681

Marcio Roberto Soares,, Lufs Reynaldo Ferracciu Alleoni, JosA Carios Casagrande,

XXIII

Humic Substances and Soil and Water Environment

NICKEL IN THE HUMIC SUBSTANCES OF A SOIL AFTER APPLICATION OF SEWAGE SLUDGECONTAMINATED WITH INCREASING RATES OF THE METAL AND CULTIVATION WITHSORGHUM 684

Marcos Donizeti Revoredo, Wanderiey JosA de Melo

ORGANIC MATTER EVALUATION OF A BRAZILIAN OXISOL BY SPECTROSCOPIC TECHNIQUES 686Martha GonzAlez-P6rez,, Debora M. B. P. Milori, Luiz A. Coinage Ladislau Martin-Neto

DISSOLVED ORGANIC CARBON AND ALUMINUM SPECIATION IN AN OXISOLUNDER NO-TILLAGE 689

Michel Alexandro Cambri, Luis Reynaldo Ferracciu Alleoni, Eduardo FAvero Caires

THE ROLE OF CHARCOAL ON NUTRIENTS BIOAVAILABILITY OF AN AMAZONIAN DARKEARTH SOIL AND SURROUNDING SOIL 691

Newton Paulo Souza FalcSo, Michaell da Silva Santos, Josephus Eduardus P., K. Antony Van Roy, Nicholas Comerford,Johannes Lehmann

THE ACTIVE ORGANIC MATTER IN MEDITERRANEAN FOREST SOILS 695Pere Rovira, V. Ramdn Vallejo

NICKEL IN THE HUMIC SUBSTANCES OF A SOIL TREATED WITHSEWAGE SLUDGE FOR SIX YEARS 698

Priscila De-Stefani Aguiar, Wanderiey Jose' de Melo, Valeria Peruca de Melo, Gabriel Maurfcio Peruca de Melo

ORGANIC CARBON AND MAXIMUM ADSORPTION OF CU IN SOME HUMID TROPICAL SOILS 701Rafael R. Silva, Cintia M. Lopes, Cindy S. Moreira, Luis R. F. Alleoni

REDUCTION OF MERCURY(II) BY TROPICAL SOIL HUMIC SUBSTANCES FROMCARVOEIRO REGION (BATHERED BY BLACK WATER) - RIO NEGRO-AM/BRASIL 703

Ricardo Lima Serudo, Julio Cesar Rocha, Heliandro Cordovil da Silva, William Ce'sar Pateriini, Andre1 Henrique Rosa

COPPER AND ZINC IN THE ORGANIC FRACTION OF VINEYARD SOILS AS AFUNCTION OF PH VARIATION 707

Roberta CorrSa Nogueirol, Gilmar Ribeiro Nachtigall, Michel Alexandro Cambri, Luis Reynaldo Ferracciu Alleoni

X - WATER TREATMENT AND NATURAL ORGANIC MATTER

ADSORPTION OF NATURAL ORGANIC MATTER BY A TUNABLE POLYMER COLLOID 713MarkM. Clark, XiangLi, Won-Young Ahn, NealSternisha, GurjitSandhu, RobertL. Riley

CHANGES IN QUALITY AND QUANTITY OF NOM -POSSIBLE CAUSES AND CONSEQUENCES 717RolfD. Vogt, Egil Gjessing, Georg Becher,

SPECTROSCOPIC EVALUATION OF DISINFECTION BY-PRODUCT FORMATION POTENTIAL 720Martha J. M. Wells, Mohamed Y. Z. About Eish, Ravi K. Doddi, Glenn T. Cunningham

CHARACTERIZATION OF THE POLARITY OF NATURAL ORGANIC MATTERUSING SOLID PHASE EXTRACTION 722

Fernando L. Rosario-Ortiz, Hakam Najib Al-Samarrai, Kathleen Kozawa, Fredrick W. Gerringer, Christopher J. Gabelich, I. H.(Mel) Suffet

FOURIER TRANSFORM INFRARED PHOTOACOUSTIC SPECTROSCOPIC ANALYSIS OFNATURAL ORGANIC MATTER FOULANTS ON ULTRAFILTRATION ANDREVERSE OSMOSIS MEMBRANES .". 725

Samuel D. Sibley, Fredrick W. Gerringer, Christopher J. Gabelich, I.H. (Mel) Suffet, Joel A. Pedersen,

REDUCTION OF CR (VI) IN CONTAMINATED EFLUENTS BY HUMIC ACIDSFROM DIFFERENT SOURCES 729

Bruno ResendeDebien, Fernando Barboza Egreja Filho, Janaina Goncalves Boucas

AGRICULTURAL USE OF STABILIZATION POND EFFLUENT: A CASE STUDY IN THE CITY OFLINS (SP, BRAZIL) 732

C6lia R. Montes, Adriel F. Fonseca, Adolpho J. Melfi, Thomas Gloaguen, Fernando C, Mendonca, Roque P. Pivelli, UweHerpin, Alex P. R. Santos, M. Cristina Forti, Yves Lucas, Stephanie Mounter, Adilson Carvalho, Vagner V. Almeida,Carios G. Cardinal'!, Thiago Steffen, Rubens C. Monteiro

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REMOVAL OF HUMIC SUBSTANCES IN WATER TREATMENT WITH PREOXIDATION ANDDOUBLE FILTRATION 735

Giovana KAtie Wiecheteck, Sandro Xavier de Campos, Cristina Filomena Pereira Rosa Paschoalato, Luiz Di Bernardo, EnyMaria Vieira

SPECTROSCOPICAL ANALYSIS OF HUMIC ACIDS INFLUENCE OVER THE PHOTOLYSIS OFAQUEOUS PESTICIDE RESIDUES 738

Jos6 Roberto Garbin, D6bora Marcondes Bastos Pereira Milori, Marcelo Luis SimOes, Wilson Tadeu Lopes da Silva, LadislauMartin-Neto

IS THE THEORY TO FORM TRIHALOMETHANE BY CHLORINATION OF AQUATIC HUMICSUBSTANCES TRUTH? 741

Koyo Yonebayashi, Hiroki Kodama, Yuko Kawamura, Hidekazu Yamada

CHARACTERIZATION OF THE WATER EXTRACTABLE ORGANIC MATERIALIN A DEEP SOIL PROFILE 744

Maddalena Corvasce, Adam Zsolnay, Valeria D'Orazio, Teodoro M. Miano

INTERACTION BETWEEN HUMIC ACIDS FROM PEAT AND SOLUBLE CUTTING OILS DETERMINEDBY FLUORESCENCE SPECTROSCOPY 748

Ozelito Possiddnio de Amarante Junior, Ricardo dos Santos Coelho,Sandro Xavier Campos, Natilene Mesquita Brito, Eny Maria Vieira

DECONSTRUCTING TIO2-NOM ISOTHERM 751Serif Allan Suphandag, Miray Bekbdlet

PHOTOCATALYTIC TREATMENT OF HUMIC SUBSTANCES BY MEANS OF TITANIA MODIFIEDWITH 2-AMINOTHIAZOLE 754

Valtair Marcos Cristante, Gustavo Rocha de Castro, Adriana Barbosa Araujo, Jorge Diniz de Oliveira, Pedro de MagalhAesPadilha, Ariovaldo de Oliveira Florentino, Julio Cesar Rocha

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