icp test report certification packet/media/electronics... · ltttelfuse phtls., tnc. lima tech...
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1
ICP Test Report Certification Packet
Company name : Littelfuse, Inc.
Product Series: Nano (Silver or Gold plated)
Product #: 456xxx Series
Issue Date: January 17, 2013
It is hereby certified by Littelfuse, Inc. that there is neither RoHS (EU Directive 2002/95/EC, and its
recast 2011/ 65/EU)-restricted substance nor such use, for materials to be used for unit parts, for
packing/packaging materials, and for additives and the like in the manufacturing processes.
In addition, it is hereby reported to you that the parts and sub-materials, the materials to be used
for unit parts, the packing/packaging materials, and the additives and the like in the manufacturing
processes, are all composed of the following components.
Issued by:
<Global EHS Engineer>
(1) Parts, sub-materials and unit parts
This document covers the Nano RoHS-Compliant series products manufactured by
Littelfuse, Inc.
< Raw Materials Used
Please see Table 1
(2) The ICP data on all measurable substances
Please see appropriate pages as identifed in Table 1
Remarks:
Pb (lead) contained in the high temperature melting solder > 85% and is categorized as
exempt under section 7a of the RoHS Annex.
Form 585-047 Rev. A 2/21/06
2
Table 1: List of Raw Materials covered by this report
Total Parts Raw Material Part Number Raw Material Description Page(s) 1 909-422 Body 3-10
2 910-259 (same as 910-238) Cap – Silver plated 11-18
3 910-554 (same as 910-275) Cap – Gold plated 19-24
4 087266 Anaerobic Adhesive 25-34
5 11-0010 (687xxx) Element-Pure Ag1000 35-40
6 079xxx Element 41-45
7 692323 Solder 46-51
8 425809 Ink 52-60
Test Report Number : TWNC00285767
Authorized By: On Behalf Of Intertek Testing Services Taiwan Limited
K. Y. Liang Director
*THJ0285767* Page 1 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Applicant: Littelfuse Philippines Inc. Date : Nov 19, 2012 LIMA Technology Center, Lipa City,
Malvar, Batangas
Sample Description:
One (1) group of submitted samples said to be : Part Description : Body Part Number : 909-422 Date Sample Received : Nov 12, 2012 Date Test Started : Nov 13, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Number : TWNC00285767
Test Conducted
*THJ0285767* Page 2 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅰ) Test Result Summary : Result (ppm)
Test Item White Plastic
Heavy Metal
Cadmium (Cd) content ND Lead (Pb) content ND Mercury (Hg) content ND Chromium VI (Cr6+) content ND
Polybrominated Biphenyls (PBBs) Monobrominated Biphenyls (MonoBB) ND Dibrominated Biphenyls (DiBB) ND Tribrominated Biphenyls (TriBB) ND Tetrabrominated Biphenyls (TetraBB) ND Pentabrominated Biphenyls (PentaBB) ND Hexabrominated Biphenyls (HexaBB) ND Heptabrominated Biphenyls (HeptaBB) ND Octabrominated Biphenyls (OctaBB) ND Nonabrominated Biphenyls (NonaBB) ND Decabrominated Biphenyl (DecaBB) ND
Polybrominated Diphenyl Ethers (PBDEs) Monobrominated Diphenyl Ethers (MonoBDE) ND Dibrominated Diphenyl Ethers (DiBDE) ND Tribrominated Diphenyl Ethers (TriBDE) ND Tetrabrominated Diphenyl Ethers (TetraBDE) ND Pentabrominated Diphenyl Ethers (PentaBDE) ND Hexabrominated Diphenyl Ethers (HexaBDE) ND Heptabrominated Diphenyl Ethers (HeptaBDE) ND Octabrominated Diphenyl Ethers (OctaBDE) ND Nonabrominated Diphenyl Ethers (NonaBDE) ND Decabrominated Diphenyl Ether (DecaBDE) ND
Number : TWNC00285767
Test Conducted
*THJ0285767* Page 3 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅰ) Test Result Summary : Result (ppm)
Test Item White Plastic
Halogen Content Fluorine (F) ND Chlorine (Cl) ND Bromine (Br) ND Iodine (I) ND
Remarks: ppm = Parts per million based on weight of tested sample = mg/kg ND = Not detected
Responsibility of Chemist :Irene Chiou / Kevin Liu / Cathy Chen
Date Sample Received : Nov 12, 2012 Test Period : Nov 13, 2012 To Nov 15, 2012
(Ⅱ) RoHS Limits:
Restricted Substances Limits
Cadmium (Cd) Content 0.01% (100ppm) Lead (Pb) Content 0.1% (1000ppm) Mercury (Hg) Content 0.1% (1000ppm) Chromium VI (Cr6+) Content 0.1% (1000ppm) Polybrominated Biphenyls (PBBs) 0.1% (1000ppm) Polybrominated Diphenyl Ehters (PBDEs) 0.1% (1000ppm)
The above limits were quoted from Annex II of 2011/65/EU for homogeneous material.
Number : TWNC00285767
Test Conducted
*THJ0285767* Page 4 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅲ) Test Method: Test Item Test Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex C, by alkaline digestion and determined by UV-Vis spectrophotometer.
1 ppm
Polybrominated Biphenyls (PBBs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary.
5 ppm
Polybrominated Diphenyl Ethers (PBDEs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary.
5 ppm
Halogen Content With reference to EN 14582:2007 by calorimetric bomb with oxygen and determined by Ion Chromatograph.
50 ppm
Remark: Reporting limit = Quantitation limit of analyte in sample
Number : TWNC00285767
Test Conducted
*THJ0285767* Page 5 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI)/PBBS/PBDES Contents Reference Standard: IEC 62321 edition 1.0:2008
Weigh sample and add organic solvent
By Soxhlet extraction or Solvent extraction
Concentrate the extract and make upwith organic solvent
PBBs/PBDEs
Analyzed by GC-MSD
Sample preparation
Take sample and immerse into Aqua Regia, start to strip plating layer
Stop the stripping procedure upon color change completely
Take the Aqua solution as plating component and stripped body as substrate component
For non-metal part For metal part
Make up with deionized water and add diphenyl-carbazide solution
Cr6+
Analyzed by UV-VIS
By spot test
Get 50cm2 sample
By boiling water extraction
Negative *2
Substrate Plating
Weigh sample and add alkaline solution
Definite temp. extraction
Cool and filter the extract
Cr6+
For different material, digest the sample with appropriate acid*1
Make up with deionized water
Cd/Pb/Hg
Analyzed by ICP-OES
Confirm the tested samples are totally dissolved
Number : TWNC00285767
Test Conducted
*THJ0285767* Page 6 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Remarks: *1: List of Appropriate Acid:
Material Acid Added for Digestion Polymers HNO3,HCl,HF,H2O2,H3BO3 Metals HNO3,HCl,HF Electronics HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as detected.
Number : TWNC00285767
Test Conducted
*THJ0285767* Page 7 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Test for Halogen Content Reference Standard:EN 14582
End of Report
This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct.
Add absorbent in a combustion flask & place weighed sample in equipment
Fill oxygen into calorimetric bomb
Ignite then leave the bomb at room temperature
Transfer the absorbent into a volumetric flask
Make up with deionized water
Sampling/grinding or cutting
Analyzed by ion chromatography
Number : TWNC00285767
Test Conducted
*THJ0285767* Page 8 of 8
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Photo
scsTest Report No.: LB12-01094C March 5, 2012 Page 1 of 4
LTTTELFUSE PHtLS., tNC.Lima Tech Center, SEZ,Lipa, Malvar, Batangas
The following sample(s) was/veere submitted and identified bylon behalt ol the client as:
Product Name
SGS Samplg Number
Recelved Date
Test Perlorming Date
T6sl Perlormed
Test Requested
Test llethod
Ted n6sult(5)
C,oncluslon
Cap 910-259 / Base
LB12-01094.004
FebrJary 21 ,2012
F€bruary 21,20121o March 5,2012
SGS Philippines subcontracted the testing ot sampte(s) setecl€d byapplicant with following results
Selected test(s) as requested by client.
Please reler to next page(s).
Please refer 1o next page(s).
Based on the perfomed tests on submitted sample(s), the results ofLead, Cadmium, Hexavalent chromium and l\,,lercury complywithlhe RoHS Dnective 2002/95/EC and iis subsequeni amendments.
This reportwillbe kepl on file for six months from the date ol issue.
Signed for and on behalt olSGS PHILIPPINES, INC.
I'EDEN L. PENEYHALaboralory Operalions Manager
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SGSTest Report No.: LB12'01094C March 5.2012 Page 2 ol4
Sample Number : LB11-01094.004Physlcal Das€ription : Base material of silver colored metalItem / Batch Numb€r : fl/A
RoHS Dlreclive 2002/95/EC
Tesl ltem(s) unit Itothod iIDL n6sult
Cadmium (Cd) mg/Kg IEC 62321: 2008 applicationof modified digestion by
surlace etching andperfomed by ICP-AES.
2 ND
Lead (Pb) MEKg 2 ' | 19
Mercury (Hg) mg/Kg 2 ND
Hexavalent Chromium C(Vl)
with reference to lEc 62321:2008 and perfomed byBoiling water extraction
Method.#
Negative
Nole :1 mg/kg = ppm ; 0.1wt% = lOOOppm2. ND = Not Detected
3. MDL = lllethod Det€ction Limit
4. " = Oualitative analysis (No Unit)
5. # = a. Posilive means the presence ol CrVl on the tested areasb. Negative means the. absence of CrVl on the tested areas
The detecGd concentration in boiling-water'extraction solulion is equalor grealer than 0 02 mg/kgwith 50 cm2lesled a€as.
6. Analyses were subcontracted to SGS Taiwan, Ltd
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sGsTest Report No.: LB12-01094C March 5,2012 Page 3 of 4
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ATALYSIS FLOWCHARTOF HEAVY METALS
Pb,cd,Hg
Negalive
Addinq 1,5-diph€nylcalbazide lor
Adding 1.5-
the prssence o, Cl6+.
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SGSTest Report
Sample Photo (As Becaived):
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No.: LB12-010S4C March 5, 2012
LB12-01094.004
. . .End ol Report.. .
Page 4 of 4
,
SGTest Heport
LITTELFUSE PHII..S., INC.Lima Tech Center, SEz,Lipa, Malvar, Batangas
The following sample(s) was/we
No.:1812-01094A March 5, 2012 Page 1 ot 4
Product Name
SGS Sample Numbel
Recelved Date
Test Performing Date
T€st Perfurmed
Te€t Requested
Test Method
Tqrt R.eult(s)
conclugion
re submitled and identilied bylon behalf of the client as:
Cap 910'259 / Plaling
L812,01094.002
Fehtuary 21 , 2012
February 21 , 2012 to lllarch 5, 2012
SGS Philippines subconlracted lhe tesling ol sample(s) selected byapplicant wilh following results
Selecled teg(s)as requested by client.
Please reler to next Page(s)
Please refer 10 next page(s).
Based on the perlormed tests on submitted sample(s)' the results ofLead, Cadmium, Hexavalent chromium and l\rercury complywlththe RoHS Dkective 2oo2l95/Eo and its subsequent amendments
This repod will be kept on file lor six months from the dale of issue'
Signed lor and on behalf olSGS PHILIPPINES, INC.
i,EDEN L. PENEYRALaboratory Operations Manager
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sGsTest Report No.:1812-01094A Llarch 5, 2012
Sample NumberPhygical DescriplionItom / Balch Numbor
: LB11-01094.002: Plating layer ot siMer colored metal
PaOe 2 ol 4
RoHS Dlrectlve 2002/95/EC
Test ltem(s) Unlt Method MDL Rg€ult
Cadmium (tu) mgKg IEC 62321: 2006 applicationol modified digestion by
surface etching andperformed by ICP-AES.
ND
Lead (Pb) m9Kg 2 1 8
Mercury (Hg) mg/kg 2 N O
Hexavalent Chromium C(Vl)
wilh reference to lEc 62321:2008 and performed byBoiling water extraction
Method.#Negalive
Nole :1 .
2.
6.
3.4.5.
mdks=ppm ; 0.1M%= 1000ppmND = Not DetectedMDL = Method Detection Limit" = Qualitative analysis (No Unit)# = a. Positive means the presence ot CrVl on the tested areas
b. Negative moans the absence of CrVl on lhe tested areasThe detected concentration in boiling-waterexlraction solulion is equalor greaterthan 0.02 mg/kgwith 50 cm, tested arcas.Analys€s were subcontracled to SGS Taiwan, Ltd
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SGSTest Report No.: LB12-01094A March 5,2012 Page 3 of 4
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ANALYSIS FLOWCHART OF HEAVY METALS
Pb,cd,Hg
Posilive
Negative
Sample l,leasursmenl
Heating ro90-95'C
Totat Digestion
Adding 1,5-
the presence ol Cr6+.
rhl. d@umnr i. |lnlstul .ndi$ ;;;;ii.i;i;iift;;iii,:r-ii.r.al"r .i,.t *.pcr'r *. Erah'd t" 60 d'v" onrv
SGSTest Report
Samole Photo (As Receiv€dl:
. .1
No.: LB12-01094A March 5,2012
LB12-01094.002
. . .End of Report . . .
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ro.r Epod ELr only ro the spl6(!) I6red lnd 3uch e.mpL{s) .E Et h6d td 60 d.y3 onlv."
Test Report Number : TWNC00285774
Authorized By: On Behalf Of Intertek Testing Services Taiwan Limited
K. Y. Liang Director
*THJ0285774* Page 1 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Applicant: Littelfuse Philippines Inc. Date : Nov 19, 2012 LIMA Technology Center, Lipa City,
Malvar, Batangas
Sample Description: One (1) group of submitted samples said to be : Part Description : Cap Part Number : 910-275 Date Sample Received : Nov 12, 2012 Date Test Started : Nov 13, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Number : TWNC00285774
Test Conducted
*THJ0285774* Page 2 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅰ) Test Result Summary : Result (ppm)
Test Item (1) (2)
Heavy Metal
Cadmium (Cd) content ND ND
Lead (Pb) content ND ND Mercury (Hg) content ND ND
Chromium VI (Cr6+) content (mg/kg with 50cm2) Negative (< 0.02)
(#)
Negative (< 0.02)
(#)
Remarks: ppm = Parts per million based on weight of tested sample = mg/kg ND = Not detected < = Less than mg/kg with 50cm2 = milligram per kilogram with 50 square centimetre Negative = A negative test result indicated positive observation
was not found at the time of Test. # = Due to the insufficient sample area, reduced total sample
surface of 25 cm2 was used and the dilution factor was adjusted accordingly.
Tested Components (1) Coppery metal base material (2) Golden plating layer
Responsibility of Chemist :Irene Chiou / Kevin Liu
Date Sample Received : Nov 12, 2012 Test Period : Nov 13, 2012 to Nov 16, 2012
(Ⅱ) RoHS Limits:
Restricted Substances Limits
Cadmium (Cd) Content 0.01% (100ppm) Lead (Pb) Content 0.1% (1000ppm) Mercury (Hg) Content 0.1% (1000ppm) Chromium VI (Cr6+) Content 0.1% (1000ppm)
The above limits were quoted from Annex II of 2011/65/EU for homogeneous material.
Number : TWNC00285774
Test Conducted
*THJ0285774* Page 3 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅲ) Test Method:
Test Item Test Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex B, by boiling water extraction and determined by UV-Vis Spectrophotometer.
0.02 mg/kg with 50cm2
Remark: Reporting limit = Quantitation limit of analyte in sample
Number : TWNC00285774
Test Conducted
*THJ0285774* Page 4 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Test For Cd/Pb/Hg/Chromium (VI) Reference Standard:IEC 62321 edition 1.0:2008
For different material, digest the sample with appropriate acid*1
Make up with deionized water
Cd/Pb/Hg
Analyzed by ICP-OES
Confirm the tested samples are totally dissolved
Sample preparation
Take sample and immerse into Aqua Regia, start to strip plating layer
Stop the stripping procedure upon color change completely
Take the Aqua solution as plating component and stripped body as substrate component
Cr6+
Make up with deionized water and add diphenyl-carbazide solution
Analyzed by UV-VIS
By spot test
Get 50cm2 sample
By boiling water extraction
Negative *2
Substrate Plating
Number : TWNC00285774
Test Conducted
*THJ0285774* Page 5 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Remarks: *1: List Of Appropriate Acid:
Material Acid Added For Digestion
Polymers HNO3,HCl,HF,H2O2,H3BO3 Metals HNO3,HCl,HF Electronics HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as detected.
End of Report
This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct.
Number : TWNC00285774
Test Conducted
*THJ0285774* Page 6 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Photo
Test Report Number : TWNC00285781
Authorized By: On Behalf Of Intertek Testing Services Taiwan Limited
K. Y. Liang Director
*THJ0285781* Page 1 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Applicant: Littelfuse Philippines Inc. Date : Nov 19, 2012 LIMA Technology Center, Lipa City,
Malvar, Batangas
Sample Description:
One (1) group of submitted samples said to be : Part Description : Anaerobic Adhesive Part Number : 087266 Date Sample Received : Nov 12, 2012 Date Test Started : Nov 13, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 2 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅰ) Test Result Summary : Result (ppm)
Test Item Green Liquid
Heavy Metal
Cadmium (Cd) content ND Lead (Pb) content ND Mercury (Hg) content ND Chromium VI (Cr6+) content ND
Polybrominated Biphenyls (PBBs) Monobrominated Biphenyls (MonoBB) ND Dibrominated Biphenyls (DiBB) ND Tribrominated Biphenyls (TriBB) ND Tetrabrominated Biphenyls (TetraBB) ND Pentabrominated Biphenyls (PentaBB) ND Hexabrominated Biphenyls (HexaBB) ND Heptabrominated Biphenyls (HeptaBB) ND Octabrominated Biphenyls (OctaBB) ND Nonabrominated Biphenyls (NonaBB) ND Decabrominated Biphenyl (DecaBB) ND
Polybrominated Diphenyl Ethers (PBDEs) Monobrominated Diphenyl Ethers (MonoBDE) ND Dibrominated Diphenyl Ethers (DiBDE) ND Tribrominated Diphenyl Ethers (TriBDE) ND Tetrabrominated Diphenyl Ethers (TetraBDE) ND Pentabrominated Diphenyl Ethers (PentaBDE) ND Hexabrominated Diphenyl Ethers (HexaBDE) ND Heptabrominated Diphenyl Ethers (HeptaBDE) ND Octabrominated Diphenyl Ethers (OctaBDE) ND Nonabrominated Diphenyl Ethers (NonaBDE) ND Decabrominated Diphenyl Ether (DecaBDE) ND
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 3 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅰ) Test Result Summary : Result (ppm)
Test Item Green Liquid
Halogen Content Fluorine (F) ND Chlorine (Cl) ND Bromine (Br) ND Iodine (I) ND
Phthalates Di(2-ethylhexyl) Phthalate (DEHP) ND Dibutyl Phthalate (DBP) 77 Benzyl Butyl Phthalate (BBP) ND
Others Hexabromocyclododecane (HBCDD) ND
Remarks: ppm = Parts per million based on wet weight of tested sample =
mg/kg ND = Not detected
Responsibility of Chemist :Irene Chiou / Kevin Liu / Cathy Chen
Date Sample Received : Nov 12, 2012 Test Period : Nov 13, 2012 To Nov 15, 2012
(Ⅱ) RoHS Limits:
Restricted Substances Limits
Cadmium (Cd) Content 0.01% (100ppm) Lead (Pb) Content 0.1% (1000ppm) Mercury (Hg) Content 0.1% (1000ppm) Chromium VI (Cr6+) Content 0.1% (1000ppm) Polybrominated Biphenyls (PBBs) 0.1% (1000ppm) Polybrominated Diphenyl Ehters (PBDEs) 0.1% (1000ppm)
The above limits were quoted from Annex II of 2011/65/EU for homogeneous material.
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 4 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅲ) Test Method: Test Item Test Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex C, by alkaline digestion and determined by UV-Vis spectrophotometer.
1 ppm
Polybrominated Biphenyls (PBBs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary.
5 ppm
Polybrominated Diphenyl Ethers (PBDEs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary.
5 ppm
Halogen Content With reference to EN 14582:2007 by calorimetric bomb with oxygen and determined by Ion Chromatograph.
50 ppm
Phthalates With reference to EN 14372: 2004, bysolvent extraction and determined byGC-MS.
50 ppm
Hexabromocyclododecane(HBCDD)
With reference to USEPA 3540C, by solvent extraction and determined byGC-MS.
10 ppm
Remark: Reporting limit = Quantitation limit of analyte in sample
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 5 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI)/PBBS/PBDES Contents Reference Standard: IEC 62321 edition 1.0:2008
Weigh sample and add organic solvent
By Soxhlet extraction or Solvent extraction
Concentrate the extract and make upwith organic solvent
PBBs/PBDEs
Analyzed by GC-MSD
Sample preparation
Take sample and immerse into Aqua Regia, start to strip plating layer
Stop the stripping procedure upon color change completely
Take the Aqua solution as plating component and stripped body as substrate component
For non-metal part For metal part
Make up with deionized water and add diphenyl-carbazide solution
Cr6+
Analyzed by UV-VIS
By spot test
Get 50cm2 sample
By boiling water extraction
Negative *2
Substrate Plating
Weigh sample and add alkaline solution
Definite temp. extraction
Cool and filter the extract
Cr6+
For different material, digest the sample with appropriate acid*1
Make up with deionized water
Cd/Pb/Hg
Analyzed by ICP-OES
Confirm the tested samples are totally dissolved
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 6 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Remarks: *1: List of Appropriate Acid:
Material Acid Added for Digestion
Polymers HNO3,HCl,HF,H2O2,H3BO3 Metals HNO3,HCl,HF Electronics HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as detected.
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 7 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Test for Halogen Content Reference Standard:EN 14582
Add absorbent in a combustion flask & place weighed sample in equipment
Fill oxygen into calorimetric bomb
Ignite then leave the bomb at room temperature
Transfer the absorbent into a volumetric flask
Make up with deionized water
Sampling/grinding or cutting
Analyzed by ion chromatography
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 8 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart:
Test For Phthalates Contents Reference Method: EN 14372: 2004
Sampling/grinding or cutting
Weigh sample and add organic solvent
By solvent extraction
Concentrate the extract and make up with organic solvent
Analyzed by GC-MSD
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 9 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart:
Test For Hexabromocyclododecane (HBCDD) Reference Standard:USEPA 3540C
End of Report
This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct.
Sampling/grinding or cutting
Weigh sample and add organic solvent
By soxhlet extraction
Concentrate the extract and make up with organic solvent
Analyzed by GC-MSD
Number : TWNC00285781
Test Conducted
*THJ0285781* Page 10 of 10
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Photo
Intertek Consumer Goods GmbH · Würzburger Straße 152 · 90766 Fürth ·
Durch die DAkkS nach DIN EN ISO/IEC 17025 akkreditiertes Prüflaboratorium Die Akkreditierung gilt für die in der Urkunde aufgeführten Prüfverfahren.
Intertek Consumer Goods GmbH Tel.: +49 911 74075 0 Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: +49 911 74075 30 Amtsgericht Fürth, HRB 5756 Kay Grönhardt 90766 Fürth, Germany [email protected] USt-IdNr. DE169317871 Rainer Mast
Polyfil AG Gina Gregorio Oberallmendstrasse 20A 6300 Zug / Switzerland
Fürth, 2012-12-19 Test report No. FUHL1236923 Testing of a material sample according to the RoHS directive 2011/65/EC Sample description: Ag1000 wire; part no. 4500236620; batch 13891141 Arrival in lab: 2012-012-04; Period of XRF analysis incl. sample preparation and photo documentation: 2012-12-07 – 2012-12-10 Head of Inorganic Lab: Claudia List Copying this test report is permitted only in agreement with the contracted lab. The test results refer only to the tested item. This report consists of 6 page(s). The test methods signed with * are not listed in the attachment of the accreditation certificate.
Conclusion based on tested item Test order Status testing according to the RoHS directive 2011/65/EC conform° ° Please see overview of test results - Test results see next pages -
Page 2 of 6 page(s) of our test report No. FUHL1236923 dated 2012-12-19
Sample description: Ag1000 wire; part no. 4500236620; batch 13891141
Intertek Consumer Goods GmbH Tel.: +49 911 74075 0 Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: +49 911 74075 30 Amtsgericht Fürth, HRB 5756 Kay Grönhardt 90766 Fürth, Germany [email protected] Ust-IdNr. DE169317871 Rainer Mast
nM = non Metal M = Metal cM = composite Material List of component parts:
Sample No. Part No. Material Description
236923 1 M Ag1000 wire; part no. 4500236620; batch 13891141
Page 3 of 6 page(s) of our test report No. FUHL1236923 dated 2012-12-19
Sample description: Ag1000 wire; part no. 4500236620; batch 13891141
Intertek Consumer Goods GmbH Tel.: +49 911 74075 0 Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: +49 911 74075 30 Amtsgericht Fürth, HRB 5756 Kay Grönhardt 90766 Fürth, Germany [email protected] Ust-IdNr. DE169317871 Rainer Mast
Comment
LOD = Limit of Detection
BL = Below Limit OL = Over Limit X = Inconclusive, further test necessary σ = Standard deviation CS = Composite sample
Remark: Results were obtained by EDXRF for primary screening. Additional chemical testing using ICP (for Cd, Pb), AAS (for Hg), IC-UC/VIS (for CrVI) and GC/MS (for PBBs/PBDEs) are recommended, if the concentration exceeds the below warning value according to IEC 62321. Element Unit non - metal metal
Cd mg / kg BL ≤ (70-3σ) < X < (130+3σ) ≤ OL BL ≤ (70-3σ) < X < (130+3σ) ≤ OL Pb mg / kg BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL Hg mg / kg BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL Br mg / kg BL ≤ (300-3σ) < X -- Cr mg / kg BL ≤ (700-3σ) < X BL ≤ (700-3σ) < X
Element Unit composite material
Cd mg / kg LOD < X < (150+3σ) ≤ OL Pb mg / kg BL ≤ (500-3σ) < X < (1500+3σ) ≤ OL Hg mg / kg BL ≤ (500-3σ) < X < (1500+3σ) ≤ OL Br mg / kg BL ≤ (250-3σ) < X Cr mg / kg BL ≤ (500-3σ) < X
Page 4 of 6 page(s) of our test report No. FUHL1236923 dated 2012-12-19
Sample description: Ag1000 wire; part no. 4500236620; batch 13891141
Intertek Consumer Goods GmbH Tel.: +49 911 74075 0 Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: +49 911 74075 30 Amtsgericht Fürth, HRB 5756 Kay Grönhardt 90766 Fürth, Germany [email protected] Ust-IdNr. DE169317871 Rainer Mast
1. XRF screening Method: XRF according to IEC 62321:2008*
Sample No. Part No. Pb Hg Cd Crtotal Br Status 236923 1 BL BL BL BL -- conform
Comment: Elements RoHS-limit value Lead (Pb) 1000 mg/kg Mercury (Hg) 1000 mg/kg Cadmium (Cd) 100 mg/kg Chromium VI (Cr VI) 1000 mg/kg Polybrominated Biphenyle (PBBs) 1000 mg/kg Polybrominated Diphenyl ether (PBDEs) 1000 mg/kg
- Flow charts see next page(s) -
Page 5 of 6 page(s) Test procedure
Intertek Consumer Goods GmbH Tel.: +49 911 74075 0 Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: +49 911 74075 30 Amtsgericht Fürth, HRB 5756 Kay Grönhardt 90766 Fürth, Germany [email protected] Ust-IdNr. DE169317871 Rainer Mast
YES
YES
YES
YES
YES
NO
NO NO
NO
NO
samples
metallic materials,
polymer materials,
electronics (PCB / component)
mechanical
sample preparation
mechanical
sample preparation
screening by XRF ?
sample uniform ?
screening procedure
by XRF
chemical test procedure (verification)
various methods (please see verification test
procedure below)
meets limits ?
further testing ?
meets limits ?
pass
entity based conforming
sample
fail
entity based non conforming
sample
pass
entity based conforming
sample
fail
entity based non conforming
sample
non-destructive
sample preparation
Page 6 of 6 page(s) Verification test procedure
Intertek Consumer Goods GmbH Tel.: +49 911 74075 0 Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: +49 911 74075 30 Amtsgericht Fürth, HRB 5756 Kay Grönhardt 90766 Fürth, Germany [email protected] Ust-IdNr. DE169317871 Rainer Mast
Sample Preparation
Sample Measurement
Sample solvent extraction
Concentration/ Dilution of extraction
solution
Filtration
GC/MS
DATA
Acid digestion with microwave / hotplate
Filtration
Residue
Total digestion
Solution
ICP-OES/AAS
DATA
Non-metallic material
Alkaline extraction Adding extraction
solution
Alkaline extraction Heating to 90~95°C
for extraction
Filtration and pH adjustment
Adding 1,5-diphenylcarbazide
for color development
UV-VIS or IC-UV/VIS
DATA
Metallic material
Spot test
Boiling water extraction
Adding 1,5-diphenylcarbazide
for color development
A red color indicates the presence of Cr6+ If necessary, confirm
with UV-VIS or IC-UV/VIS
DATA
Pb/Cd/Hg PBBs/PBDEs Cr6+
Positive
Negative
Test Report Number : TWNC00293764
Authorized by: On Behalf of Intertek Testing Services Taiwan Limited
K. Y. Liang Director
*THJ0293764* Page 1 of 5
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司 11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Applicant: Littelfuse Philippines Inc. Date : Jan 14, 2013 LIMA Technology Center, Lipa City,
Malvar, Batangas
Sample Description:
One (1) group of submitted samples said to be : Part Description : Element (Silver Strip Sn Plated) Part Number : 079026 Date Sample Received : Jan 07, 2013 Date Test Started : Jan 08, 2013
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Number : TWNC00293764
Test Conducted
*THJ0293764* Page 2 of 5
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司 11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅰ) Test Result Summary: Result
Test Item Unit Test Method Silvery metal
RL
Heavy Metal
Cadmium (Cd) content ppm
With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES.
ND 2
Lead (Pb) content ppm
With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES.
34 2
Mercury (Hg) content ppm
With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES.
ND 2
Chromium VI (Cr6+) content mg/kg with 50 cm2
With reference to IEC 62321: 2008, by boiling water extraction and determined by UV-Vis Spectrophotometer.
Negative 0.02
Remarks: ppm = parts per million based on weight of tested sample = mg/kg
ND = Not detected
RL = Reporting Limit, Quantitation limit of analyte in sample mg/kg with 50cm2 = milligram per kilogram with 50 square centimeter
Negative = A negative test result indicated positive observation was not found at the time of Test. When the spot test showed a negative result, the boiling water extraction procedure shall be used to verify the result.
Responsibility of Chemist: Kevin Liu/ Irene Chiou Date Sample Received : Jan 07, 2013 Test Period : Jan 08, 2013 To Jan 11, 2013 (Ⅱ) RoHS Limits: Restricted Substances Limits
Cadmium (Cd) content 0.01% (100ppm) Lead (Pb) content 0.1% (1000ppm) Mercury (Hg) content 0.1% (1000ppm) Chromium VI (Cr6+) content 0.1% (1000ppm) The above limits were quoted from Annex II of 2011/65/EU for homogeneous material.
Number : TWNC00293764
Test Conducted
*THJ0293764* Page 3 of 5
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司 11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅲ) Measurement Flowchart: Test For Cd/Pb/Hg/Chromium (VI) Reference Standard:IEC 62321 edition 1.0:2008
Sampling/grinding or cutting
For different material, digest the sample with appropriate acid*1
Make up with deionized water
Cd/Pb/Hg
Analyzed by ICP-OES
Weigh sample and add alkaline solution
Definite temp. extraction
Make up with deionized water and add diphenyl-carbazide solution
Cool and filter the extract
Cr6+
Analyzed by UV-VIS
By spot test
Get 50cm2 sample
Boiling water extraction
Metal Polymers / Electronics
Negative*2 Confirm the tested samples are totally dissolved
Number : TWNC00293764
Test Conducted
*THJ0293764* Page 4 of 5
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司 11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO3,HCl,HF,H2O2,H3BO3 Metals HNO3,HCl,HF Electronics HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as
detected.
End of Report
This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct.
Number : TWNC00293764
Test Conducted
*THJ0293764* Page 5 of 5
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司 11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Photo
Test Report Number : TWNC00285770
Authorized By: On Behalf Of Intertek Testing Services Taiwan Limited
K. Y. Liang Director
*THJ0285770* Page 1 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Applicant: Littelfuse Philippines Inc. Date : Nov 19, 2012 LIMA Technology Center, Lipa City,
Malvar, Batangas
Sample Description:
One (1) group of submitted samples said to be : Part Description : Solder (Pb is ≥ 90%) Part Number : 692323 Date Sample Received : Nov 12, 2012 Date Test Started : Nov 13, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Number : TWNC00285770
Test Conducted
*THJ0285770* Page 2 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅰ) Test Result Summary : Result (ppm)
Test Item Silvery Metal
Heavy Metal
Cadmium (Cd) content ND
Lead (Pb) content 910679 Mercury (Hg) content ND Chromium VI (Cr6+) content (mg/kg with 50cm2) Negative (< 0.02)
Remarks: ppm = Parts per million based on weight of tested sample = mg/kg ND = Not detected < = Less than mg/kg with 50cm2 = milligram per kilogram with 50 square centimetre Negative = A negative test result indicated positive observation
was not found at the time of Test.
Responsibility of Chemist :Irene Chiou / Kevin Liu
Date Sample Received : Nov 12, 2012 Test Period : Nov 13, 2012 To Nov 15, 2012
(Ⅱ) RoHS Limits:
Restricted Substances Limits
Cadmium (Cd) Content 0.01% (100ppm) Lead (Pb) Content 0.1% (1000ppm) Mercury (Hg) Content 0.1% (1000ppm) Chromium VI (Cr6+) Content 0.1% (1000ppm)
The above limits were quoted from Annex II of 2011/65/EU for homogeneous material.
Number : TWNC00285770
Test Conducted
*THJ0285770* Page 3 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅲ) Test Method: Test Item Test Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex B, by boiling water extraction and determined by UV-Vis Spectrophotometer.
0.02 mg/kg with 50cm2
Remark: Reporting limit = Quantitation limit of analyte in sample
Number : TWNC00285770
Test Conducted
*THJ0285770* Page 4 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart: Test For Cd/Pb/Hg/Chromium (VI) Reference Standard:IEC 62321 edition 1.0:2008
Sampling/grinding or cutting
For different material, digest the sample with appropriate acid*1
Make up with deionized water
Cd/Pb/Hg
Analyzed by ICP-OES
Weigh sample and add alkaline solution
Definite temp. extraction
Make up with deionized water and add diphenyl-carbazide solution
Cool and filter the extract
Cr6+
Analyzed by UV-VIS
By spot test
Get 50cm2 sample
Boiling water extraction
Metal Polymers / Electronics
Negative*2 Confirm the tested samples are totally dissolved
Number : TWNC00285770
Test Conducted
*THJ0285770* Page 5 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
(Ⅳ) Measurement Flowchart:
Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO3,HCl,HF,H2O2,H3BO3 Metals HNO3,HCl,HF Electronics HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as
detected.
End of Report
This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct.
Number : TWNC00285770
Test Conducted
*THJ0285770* Page 6 of 6
Intertek Testing Services Taiwan Ltd. 8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2410
Photo
Test Report Number : TWNC00253636
Authorized By: On Behalf Of Intertek Testing Services Taiwan Limited
K. Y. Liang Director
This report shall not be reproduced except in full, without the written approval of the laboratory.
Page 1 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
Applicant: Littelfuse Philippines Inc. Date : Apr 24, 2012 LIMA Technology Center, Lipa City,
Malvar, Batangas
Sample Description: One (1) group of submitted samples said to be : Part Description : Black Ink Part Number : 425809 Date Sample Received : Apr 19, 2012 Date Test Started : Apr 19, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Number : TWNC00253636
Test Conducted
Page 2 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
(Ⅰ) Test Result Summary : Result (ppm)
Test Item Black Paste
Heavy Metal
Cadmium (Cd) content ND Lead (Pb) content ND Mercury (Hg) content ND Chromium VI (Cr6+) content ND
Polybrominated Biphenyls (PBBs) Monobrominated Biphenyls (MonoBB) ND Dibrominated Biphenyls (DiBB) ND Tribrominated Biphenyls (TriBB) ND Tetrabrominated Biphenyls (TetraBB) ND Pentabrominated Biphenyls (PentaBB) ND Hexabrominated Biphenyls (HexaBB) ND Heptabrominated Biphenyls (HeptaBB) ND Octabrominated Biphenyls (OctaBB) ND Nonabrominated Biphenyls (NonaBB) ND Decabrominated Biphenyl (DecaBB) ND
Polybrominated Diphenyl Ethers (PBDEs) Monobrominated Diphenyl Ethers (MonoBDE) ND Dibrominated Diphenyl Ethers (DiBDE) ND Tribrominated Diphenyl Ethers (TriBDE) ND Tetrabrominated Diphenyl Ethers (TetraBDE) ND Pentabrominated Diphenyl Ethers (PentaBDE) ND Hexabrominated Diphenyl Ethers (HexaBDE) ND Heptabrominated Diphenyl Ethers (HeptaBDE) ND Octabrominated Diphenyl Ethers (OctaBDE) ND Nonabrominated Diphenyl Ethers (NonaBDE) ND Decabrominated Diphenyl Ether (DecaBDE) ND
Number : TWNC00253636
Test Conducted
Page 3 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
(Ⅰ) Test Result Summary : Result (ppm)
Test Item Black Paste
Halogen Content Fluorine (F) ND Chlorine (Cl) 610 Bromine (Br) ND Iodine (I) ND
Phthalates Di(2-ethylhexyl) Phthalate (DEHP) ND Dibutyl Phthalate (DBP) ND Benzyl Butyl Phthalate (BBP) ND
Others Hexabromocyclododecane (HBCDD) ND
Remarks: ppm = Parts per million based on wet weight of tested sample =
mg/kg ND = Not detected
Responsibility of Chemist :Irene Chiou / Kevin Liu / Cathy Chen
Date Sample Received : Apr 19, 2012 Test Period : Apr 19, 2012 To Apr 24, 2012
(Ⅱ) RoHS Requirement:
Restricted Substances Limits
Cadmium (Cd) Content 0.01% (100ppm) Lead (Pb) Content 0.1% (1000ppm) Mercury (Hg) Content 0.1% (1000ppm) Chromium VI (Cr6+) Content 0.1% (1000ppm) Polybrominated Biphenyls (PBBs) 0.1% (1000ppm) Polybrominated Diphenyl Ehters (PBDEs) 0.1% (1000ppm)
The above limits were quoted from 2002/95/EC and amendment 2005/618/EC for homogeneous material.
Number : TWNC00253636
Test Conducted
Page 4 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
(Ⅲ) Test Method: Test Item Test Method Reporting Limit
Cadmium (Cd) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Lead (Pb) content
With reference to IEC 62321 edition 1.0:2008 in clause 8/9/10, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Mercury (Hg) content
With reference to IEC 62321 edition 1.0:2008 in clause 7, by microwave digestion until the tested samples are totally dissolved and determined by ICP-OES.
2 ppm
Chromium VI (Cr6+) content
With reference to IEC 62321 edition 1.0:2008 in annex C, by alkaline digestion and determined by UV-Vis spectrophotometer.
1 ppm
Polybrominated Biphenyls (PBBs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary.
5 ppm
Polybrominated Diphenyl Ethers (PBDEs)
With reference to IEC 62321 edition 1.0:2008 in annex A, by solvent extraction and determined by GC-MS and further HPLC-DAD confirmation when necessary.
5 ppm
Halogen Content With reference to EN 14582:2007 by calorimetric bomb with oxygen and determined by Ion Chromatograph.
50 ppm
Phthalates With reference to EN 14372: 2004, by solvent extraction and determined by GC-MS.
10 ppm
Hexabromocyclododecane(HBCDD)
With reference to USEPA 3540C, by solvent extraction and determined by GC-MSD.
10 ppm
Remark: Reporting limit = Quantitation limit of analyte in sample
Number : TWNC00253636
Test Conducted
Page 5 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
(Ⅳ) Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI)/PBBS/PBDES Contents Reference Standard: IEC 62321 edition 1.0:2008
Remarks: *1: List of Appropriate Acid:
Material Acid Added for Digestion Polymers HNO3,HCl,HF,H2O2,H3BO3 Metals HNO3,HCl,HF Electronics HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as detected.
Sample preparation
For different material, digest the sample with appropriate acid*1
Make up with deionized water
Cd/Pb/Hg
Analyzed by ICP-OES
Weigh sample and add alkaline solution
Definite temp. extraction
Make up with deionized water and add diphenyl-carbazide solution
Cool and filter the extract
Cr6+
Weigh sample and add organic solvent
By Soxhlet extraction or Solvent extraction
Concentrate the extract and make upwith organic solvent
PBBs/PBDEs
Analyzed by UV-VIS
Analyzed by GC-MSD
By spot test
Get 50cm2 sample
By boiling water extraction
Metal Polymers / electronics
Negative *2
Confirm the tested samples are totally dissolved
Take sample and immerse into Aqua Regia, start to strip plating layer
Stop the stripping procedure upon color change completely
Take the Aqua solution as plating component and stripped body as substrate component
For non-metal part For metal part
Number : TWNC00253636
Test Conducted
Page 6 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
(Ⅳ) Measurement Flowchart:
Test for Halogen Content Reference Standard:EN 14582
Add absorbent in a combustion flask & place weighed sample in equipment
Fill oxygen into calorimetric bomb
Ignite then leave the bomb at room temperature
Transfer the absorbent into a volumetric flask
Make up with deionized water
Sampling/grinding or cutting
Analyzed by ion chromatography
Number : TWNC00253636
Test Conducted
Page 7 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
(Ⅳ) Measurement Flowchart:
Test For Phthalates Contents Reference Method: EN 14372: 2004
Sampling/grinding or cutting
Weigh sample and add organic solvent
By solvent extraction
Concentrate the extract and make up with organic solvent
Analyzed by GC-MSD
Number : TWNC00253636
Test Conducted
Page 8 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
(Ⅳ) Measurement Flowchart: Test For Hexabromocyclododecane (HBCDD) Reference Standard:USEPA 3540C
End of Report
Sampling/grinding or cutting
Weigh sample and add organic solvent
By soxhlet extraction
Concentrate the extract and make up with organic solvent
Analyzed by GC-MSD
Number : TWNC00253636
Test Conducted
Page 9 of 9 Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C. 全國公證檢驗股份有限公司 114台北市內湖區瑞光路 423號 8樓
Tel: (+886-2) 6602-2888.2797-8885 Fax: (+886-2) 6602-2400.6602-2401
Photo