(i) [zr(opri {osi(otbu) }] (a) 3 · (i) [zr(opri) 3{osi(o tbu) 3}] (a) electronic supplementary...

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(i) [Zr(OPr i ) 3 {OSi(O t Bu) 3 }] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2012

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Page 1: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(i) [Zr(OPri)3{OSi(OtBu)3}] (A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 2: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(ii) [Zr(OPri){O(CH2)2O}{OSi(OtBu)3}] (1A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 3: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(iii) [Zr(OPri){O(CH2)3O}{OSi(OtBu)3}] (2A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 4: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(iv) [Zr(OPri){O(CH2)2CH(CH3)O}{OSi(OtBu)3}] (3A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 5: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(v) [Zr(OPri)2{OSi(OtBu)3}2] (B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 6: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(vi) [Zr{O(CH2)2O}{OSi(OtBu)3}2] (1B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 7: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(vii) [Zr{O(CH2)3O}{OSi(OtBu)3}2] (2B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 8: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(viii) [Zr{O(CH2)2CH(CH3)O}{OSi(OtBu)3}2] (3B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 9: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(ix) [Zr(OPri)3{OSi(OtBu)3}] (A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 10: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(x) [Zr(OPri){O(CH2)2O}{OSi(OtBu)3}] (1A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 11: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(xi) [Zr(OPri){O(CH2)3O}{OSi(OtBu)3}] (2A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 12: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(xii) [Zr(OPri){O(CH2)2CH(CH3)O}{OSi(OtBu)3}] (3A)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 13: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(xiii) [Zr(OPri)2{OSi(OtBu)3}2] (B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 14: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(xiv) [Zr{O(CH2)2O}{OSi(OtBu)3}2] (1B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 15: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(xv) [Zr{O(CH2)3O}{OSi(OtBu)3}2] (2B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012

Page 16: (i) [Zr(OPri {OSi(OtBu) }] (A) 3 · (i) [Zr(OPri) 3{OSi(O tBu) 3}] (A) Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry

(xvi) [Zr{O(CH2)2CH(CH3)O}{OSi(OtBu)3}2] (3B)

Fig. (i)-(viii) 1H NMR spectra and (ix)-(xvi) 13C{1H} NMR spectra of complexes (A, B, 1A-3A and 1B-3B)

Electronic Supplementary Material (ESI) for Dalton TransactionsThis journal is © The Royal Society of Chemistry 2012