hydrogels and biodegradable polymers for bioapplications acs symposium series no. 627 edited by r....

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Polymer International 43 (1997) 197È198 Book Reviews thermoplastics : polycarbonates, polyacetals, poly- Engineering esters, cellulose esters Edited by L. Bottenbruch. Hanser, Munich, 1996. pp. xxi ] 497, price, DM298.00. ISBN 3-446-17473-7 A brief introductory chapter provides a synoptic overview of the four classes of polymer which collectively form the subject of this book, and locates them within the broader context of all the engineering thermoplastics which are available. The remainder is then divided into four sections, uniformly arranged, one devoted to each of the polymer types which the book addresses. This is a logical approach, since engineering thermoplastics, as a group, are distinguished by exhibiting speciÐc properties or superior property proÐles, rather than by similarities in chemical structure or morphology. It also makes the book easy to use and contributes to a clear and attractive layout, which is further enhanced by the inclusion of numerous photographs illustrating product applications. Greatest space is a†orded to the section on polycarbonates (176 pages), followed by polyesters (107), polyacetals (96) and cellulose esters (58). The distribution of the 1365 references cited is similar. A well structured and comprehensive treat- ment is provided for each polymer class, including details of preparation, modiÐcation, properties, processing and applica- tions. A shortcoming is the inadequate coverage of health and environmental aspects. With this single qualiÐcation, I would recommend this book to those interested in its subject area. D. M. Purbrick of polymers : fundamental and technological applica- Irradiation tions ACS symposium series no. 620 Edited by R. L. Clough and S. W. Shalaby. American Chemical Society, Washington DC, 1996. pp. xiii ] 433, price US$109.95. ISBN 0-8412-3377-2 Contributions to an ACS symposium held in August 1994 are reported here. About two-thirds of the papers were presented then, covering a wide range of radiation-related technologies. Apart from these papers, a further group of contributions from experts is included to improve the comprehensiveness and to emphasize the important role of radiation in elec- tronics and sterilization. The Ðrst group of papers reviews present understanding of radiation e†ects in polymers, charge transport and photo- ionization, and changes in the properties of irradiated poly- mers such as ultra-high molecular weight polyethylene and polybut-1-ene, and heterochain polymers such as poly- hydroxybutyrate. Computational and analytical methods of modelling radiation events are discussed, in relation to network formation, chain scission and end-group determi- nation. The second group of contributions includes discussion of radiation processing and sterilization in the food, biomedical and pharmaceutical industries : this includes a novel radioche- mical sterilization process for medical devices. Further chap- ters cover use of radiation in solid-state and thin-Ðlm polymerization, preparation of crosslinked useful gels, devel- opment of interpenetrating polymeric networks, Ðbre- reinforced composites, and improved synthetic rubbers. Later sections are concerned with speciÐc radiation e†ects, optical e†ects of radiated polymers, ageing properties, formation of photosensitive polymers, use of radiated polymers in X-ray lithography, and use of silylated reagents in microlithography. This volume, if not recommended reading, is certainly recommended browsing for those concerned with e†ects and use of radiation on polymers. A. C. Finch and biodegradable polymers for bioapplications Hydrogels symposium series no. 627 ACS Edited by R. M. Ottenbrite, S. J. Huang and K. Park. American Chemical Society, Washington DC, 1996. pp. x ] 268, price US$99.95. ISBN 0-8412-3400-0 This publication reports an ACS symposium held in Washing- ton in August 1994. It relates studies on the biodegradation and applications of hydrogels, including reversible and stimulus-sensitive types, and also some in vivo applications. Hydrogels can be formed by adding substantial amounts of water to a small amount of a speciality crosslinked polymer. After swelling, such hydrogels can be collapsed by pH change, temperature change, electric Ðelds, ionic changes, salt addi- tion, salt type, solvent addition, applied stress, light or pres- sure. Such phenomena are reviewed in the Ðrst paper, of a total of 20, which is a review contribution (with some 70 references), giving a useful introduction to the basics of hydro- gel technology. Five further papers are devoted to aspects of hydrogels in biosystems. Biodegradation is now an important technology in such applications as the degradation of synthetic materials in 197 Polymer International 0959-8103/97/$17.50 1997 SCI. Printed in Great Britain (

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Page 1: Hydrogels and biodegradable polymers for bioapplications ACS symposium series no. 627 Edited by R. M. Ottenbrite, S. J. Huang and K. Park. American Chemical Society, Washington DC,

Polymer International 43 (1997) 197È198

Book Reviews

thermoplastics : polycarbonates, polyacetals, poly-Engineeringesters, cellulose estersEdited by L. Bottenbruch.Hanser, Munich, 1996.pp. xxi ] 497, price, DM298.00.ISBN 3-446-17473-7

A brief introductory chapter provides a synoptic overview ofthe four classes of polymer which collectively form the subjectof this book, and locates them within the broader context ofall the engineering thermoplastics which are available. Theremainder is then divided into four sections, uniformlyarranged, one devoted to each of the polymer types which thebook addresses. This is a logical approach, since engineeringthermoplastics, as a group, are distinguished by exhibitingspeciÐc properties or superior property proÐles, rather than bysimilarities in chemical structure or morphology. It alsomakes the book easy to use and contributes to a clear andattractive layout, which is further enhanced by the inclusion ofnumerous photographs illustrating product applications.

Greatest space is a†orded to the section on polycarbonates(176 pages), followed by polyesters (107), polyacetals (96) andcellulose esters (58). The distribution of the 1365 referencescited is similar. A well structured and comprehensive treat-ment is provided for each polymer class, including details ofpreparation, modiÐcation, properties, processing and applica-tions. A shortcoming is the inadequate coverage of health andenvironmental aspects. With this single qualiÐcation, I wouldrecommend this book to those interested in its subject area.

D.M. Purbrick

of polymers : fundamental and technological applica-IrradiationtionsACS symposium series no. 620Edited by R. L. Clough and S. W. Shalaby.American Chemical Society, Washington DC, 1996.pp. xiii ] 433, price US$109.95.ISBN 0-8412-3377-2

Contributions to an ACS symposium held in August 1994 arereported here. About two-thirds of the papers were presentedthen, covering a wide range of radiation-related technologies.Apart from these papers, a further group of contributionsfrom experts is included to improve the comprehensivenessand to emphasize the important role of radiation in elec-tronics and sterilization.

The Ðrst group of papers reviews present understandingof radiation e†ects in polymers, charge transport and photo-ionization, and changes in the properties of irradiated poly-mers such as ultra-high molecular weight polyethylene andpolybut-1-ene, and heterochain polymers such as poly-hydroxybutyrate. Computational and analytical methods ofmodelling radiation events are discussed, in relation tonetwork formation, chain scission and end-group determi-nation.

The second group of contributions includes discussion ofradiation processing and sterilization in the food, biomedicaland pharmaceutical industries : this includes a novel radioche-mical sterilization process for medical devices. Further chap-ters cover use of radiation in solid-state and thin-Ðlmpolymerization, preparation of crosslinked useful gels, devel-opment of interpenetrating polymeric networks, Ðbre-reinforced composites, and improved synthetic rubbers. Latersections are concerned with speciÐc radiation e†ects, opticale†ects of radiated polymers, ageing properties, formation ofphotosensitive polymers, use of radiated polymers in X-raylithography, and use of silylated reagents in microlithography.

This volume, if not recommended reading, is certainlyrecommended browsing for those concerned with e†ects anduse of radiation on polymers.

A.C. Finch

and biodegradable polymers for bioapplicationsHydrogelssymposium series no. 627ACS

Edited by R. M. Ottenbrite, S. J. Huang and K. Park.American Chemical Society, Washington DC, 1996.pp. x ] 268, price US$99.95.ISBN 0-8412-3400-0

This publication reports an ACS symposium held in Washing-ton in August 1994. It relates studies on the biodegradationand applications of hydrogels, including reversible andstimulus-sensitive types, and also some in vivo applications.Hydrogels can be formed by adding substantial amounts ofwater to a small amount of a speciality crosslinked polymer.After swelling, such hydrogels can be collapsed by pH change,temperature change, electric Ðelds, ionic changes, salt addi-tion, salt type, solvent addition, applied stress, light or pres-sure. Such phenomena are reviewed in the Ðrst paper, of atotal of 20, which is a review contribution (with some 70references), giving a useful introduction to the basics of hydro-gel technology. Five further papers are devoted to aspects ofhydrogels in biosystems.

Biodegradation is now an important technology in suchapplications as the degradation of synthetic materials in

197Polymer International 0959-8103/97/$17.50 1997 SCI. Printed in Great Britain(