historical availability of metals before 1800’s, only 10 were in use: cu, sn, fe, pb, au, ag, zn,...
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Historical Availability of Metals
Before 1800’s, only 10 were in use:Cu, Sn, Fe, Pb, Au, Ag, Zn, Hg,
Bi, PtThey were either found uncombined
OrExtracted by heating with Carbon
More metals in use today than 200 years ago. Why?
Abundance; need for metals with new properties; ease of extraction
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Extracting Metals from Ores
Mineral: a pure crystalline compound found in the Earth’s crust (aluminium oxide)
Ores: a compound or mixture from which it is economic (or profitable) to extract desired substances (ie. Metals)
Eg. Bauxite (aluminium oxide) is an ore but aluminium silicates is not (not economic)
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Extracting Metals from Ores
5 tonnes bauxite mined produces one tonne Aluminium
Bauxite is crushed to obtain alumina mineral (Al2O3 – aluminium oxide)
Bauxite ore, a source of Al, is the most abundant element found in the earth's crust
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Uses of Aluminium
• kitchen utensils • cans & foil• aircraft & rockets • Window & door frames• 60% less conductive than Copper
but used for high voltage transmission lines
• Properties: light weight (low density); good tensile strength, high resistance to corrosion
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Digging for BauxiteDigging up the bauxite
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The size of the scoop
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Bauxite Reserves:
1985 - 21 billion tons1990 - 21.8 billion tons1993 - 23 billion tons2006 - 25 billion tons
Rate of use in 2006: 177 million tons per year
How long will reserves last? 141 years
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Extracting Metals from Ores
Strong electric current pass through the molten alumina (mobile ions of Al3+ and O2-) separating it into Aluminium metal & Oxygen gas
To keep it molten and to perform electrolysis, electricity is a major cost
Most smelters have their own electrical power plant
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Energy Consumption
Electricity consumption by the aluminium industry in the USA alone is equal to the consumption of all of New York City
Alcoa Aluminum smelter in Texas requires 36 million pounds of coal to fuel operations per day
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Australia is the world’s leading producer of bauxite. In 2010, it produced 71.5 million
tons
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Aluminium Industry
16,700 Employees
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50 Years of Industry in Australia
5 Bauxite mines
7 Alumina refineries
6 Aluminium smelters
12 Extrusion mills (19 presses)
2 Rolled product plants
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$5,055,402,000 in 2011
It a significant contributor the econonmy:
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Factors Affecting PriceAbundance & location of ores
Cost of extracting the metal from the ore
Cost of transportation (eg. to smelter)
World-wide demand
Metal Price/tonne
Al $ 2 150
Cu $ 3 250
Au $ 17 000 000
Zn $ 1 360
Pb $ 1 070
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Recyclingit can be recycled indefinitely – 2/3 of the
aluminum ever produced since 1886 is still in use
This does not change the fact that between 1990 and 2000, 7.1 million tons of aluminum cans (only cans!) were wasted – enough to reproduce the world’s commercial air fleet 25 times
At an average scrap value of $.58/lb, this represents $8.236 billion in lost revenue – just in cans!
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Energy Expenditure
Metal from natural ores (MJ)
from recycled material (MJ)
Aluminium 200 7
Copper 70 4
Mild steel 40 8
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Recycling Steps1. collect used Al products from homes, etc.
2. transport to central processing plant
3. separate the cans
4. Re-smelt the metal into ingots and transport them to product manufacturers
Australians currently recycle more than 2 billion aluminium cans each year. But 900 million aluminium cans are thrown away every year ($15 million dollars in the landfill)
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Benefits of Recycling
Less energy: requires 5% of the energy needed
No waste: 1 tonne recycled Al = 1 tonne new Al
Less rubish
Conserve Natural Resources: ores are non-renewable
Australians consumed more than 3 billion aluminium cans in 2002. Of these, 47% were soft drink cans and 53% where alcoholic beverage cans.