hexane

7
Hexane 1 Hexane Hexane Identifiers CAS number 110-54-3 [1]  PubChem 8058 [2] ChemSpider 7767 [3]  UNII 2DDG612ED8 [4]  EC number 203-777-6 [5] UN number 1208 DrugBank DB02764 [6] KEGG C11271 [7]  MeSH n-hexane [8] ChEBI CHEBI:29021 [9]  ChEMBL CHEMBL15939 [10]  RTECS number MN9275000 Beilstein Reference 1730733 Gmelin Reference 1985 Jmol-3D images Image 1 [11] Properties Molecular formula C 6 H 14 Molar mass 86.18 g mol 1 Appearance Colorless liquid Odor Petrolic

Upload: techzones

Post on 16-Oct-2015

14 views

Category:

Documents


0 download

DESCRIPTION

Hexane

TRANSCRIPT

  • 5/26/2018 Hexane

    1/7

    Hexane 1

    Hexane

    Hexane

    Identifiers

    CAS number110-54-3

    [1]

    PubChem8058

    [2]

    ChemSpider7767

    [3]

    UNII2DDG612ED8

    [4]

    EC number203-777-6

    [5]

    UN number 1208

    DrugBankDB02764

    [6]

    KEGGC11271

    [7]

    MeSHn-hexane

    [8]

    ChEBICHEBI:29021

    [9]

    ChEMBLCHEMBL15939

    [10]

    RTECS number MN9275000

    Beilstein Reference 1730733

    Gmelin Reference 1985

    Jmol-3D imagesImage 1

    [11]

    Properties

    Molecular formula C6H

    14

    Molar mass86.18 g mol

    1

    Appearance Colorless liquid

    Odor Petrolic

    http://en.wikipedia.org/w/index.php?title=Odorhttp://en.wikipedia.org/w/index.php?title=Molar_masshttp://en.wikipedia.org/w/index.php?title=Molecular_formulahttp://chemapps.stolaf.edu/jmol/jmol.php?model=CCCCCChttp://en.wikipedia.org/w/index.php?title=Jmolhttp://en.wikipedia.org/w/index.php?title=Gmelin_databasehttp://en.wikipedia.org/w/index.php?title=Beilstein_databasehttp://en.wikipedia.org/w/index.php?title=RTECShttp://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttps://www.ebi.ac.uk/chembldb/index.php/compound/inspect/CHEMBL15939http://en.wikipedia.org/w/index.php?title=ChEMBLhttp://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttps://www.ebi.ac.uk/chebi/searchId.do?chebiId=29021http://en.wikipedia.org/w/index.php?title=ChEBIhttp://www.nlm.nih.gov/cgi/mesh/2014/MB_cgi?mode=&term=n-hexanehttp://en.wikipedia.org/w/index.php?title=Medical_Subject_Headingshttp://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttp://www.kegg.jp/entry/C11271http://en.wikipedia.org/w/index.php?title=KEGGhttp://www.drugbank.ca/drugs/DB02764http://en.wikipedia.org/w/index.php?title=DrugBankhttp://en.wikipedia.org/w/index.php?title=UN_numberhttp://esis.jrc.ec.europa.eu/lib/einecs_IS_reponse.php?genre=ECNO&entree=203-777-6http://en.wikipedia.org/w/index.php?title=EC_number_%28chemistry%29http://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttp://fdasis.nlm.nih.gov/srs/srsdirect.jsp?regno=2DDG612ED8http://en.wikipedia.org/w/index.php?title=Unique_Ingredient_Identifierhttp://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttp://www.chemspider.com/Chemical-Structure.7767.htmlhttp://en.wikipedia.org/w/index.php?title=ChemSpiderhttp://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=8058http://en.wikipedia.org/w/index.php?title=PubChemhttp://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttp://www.commonchemistry.org/ChemicalDetail.aspx?ref=110-54-3http://en.wikipedia.org/w/index.php?title=CAS_registry_numberhttp://en.wikipedia.org/w/index.php?title=File:Hexane-3D-vdW.pnghttp://en.wikipedia.org/w/index.php?title=File:Hexane-from-xtal-1999-at-an-angle-3D-balls.pnghttp://en.wikipedia.org/w/index.php?title=File:Hexane-2D-B.pnghttp://en.wikipedia.org/w/index.php?title=File:Hexane-2D-Skeletal.svg
  • 5/26/2018 Hexane

    2/7

    Hexane 2

    Density0.6548 g mL

    1

    Melting point 96 to 94 C; 141 to 137 F; 177 to 179 K

    Boiling point 68.5 to 69.1 C; 155.2 to 156.3 F; 341.6 to 342.2 K

    Solubility in water9.5 mg L

    1

    log P 3.764

    Vapor pressure 17.60 kPa (at 20.0 C)

    kH 7.6 nmol Pa

    1kg

    1

    max

    200 nm

    Refractive index (nD

    ) 1.375

    Viscosity 294 Pa s

    Thermochemistry

    Specific

    heat capacity C265.2 J K

    1mol

    1

    Std molar

    entropy So

    298

    296.06 J K1

    mol1

    Std enthalpy of

    formation fH

    o

    298

    199.4198.0 kJ mol1

    Std enthalpy of

    combustion cH

    o

    298

    41804140 kJ mol1

    Hazards

    MSDS External MSDS

    GHS pictograms

    GHS signal word DANGER

    GHS hazard statements H225, H304, H315, H336, H373, H411

    GHS precautionary statements P210, P261, P273, P281, P301+310, P331

    EU Index 601-037-00-0

    EU classification

    F Xn N

    R-phrases R11, R38, R48/20, R51/53, R62, R65, R67

    S-phrases (S2), S16, S29, S33, S36/37

    NFPA 704

    Flash point 26.0 C (14.8 F; 247.2 K)

    Explosive limits 1.27.7%

    U.S. Permissible

    exposure limit (PEL)

    500 ppm (1800 mg m-3

    as an 8 h TWA)

    LD50 25 g kg

    1(oral, rat)

    http://en.wikipedia.org/w/index.php?title=Median_lethal_dosehttp://en.wikipedia.org/w/index.php?title=Permissible_exposure_limithttp://en.wikipedia.org/w/index.php?title=Permissible_exposure_limithttp://en.wikipedia.org/w/index.php?title=Explosive_limithttp://en.wikipedia.org/w/index.php?title=Flash_pointhttp://en.wikipedia.org/w/index.php?title=NFPA_704http://en.wikipedia.org/w/index.php?title=S36/37:_Wear_suitable_protective_clothing_and_gloveshttp://en.wikipedia.org/w/index.php?title=S33:_Take_precautionary_measures_against_static_dischargeshttp://en.wikipedia.org/w/index.php?title=S29:_Do_not_empty_into_drainshttp://en.wikipedia.org/w/index.php?title=S16:_Keep_away_from_sources_of_ignition_-_No_smokinghttp://en.wikipedia.org/w/index.php?title=%28S2%29:_Keep_out_of_the_reach_of_childrenhttp://en.wikipedia.org/w/index.php?title=List_of_S-phraseshttp://en.wikipedia.org/w/index.php?title=R67:_Vapours_may_cause_drowsiness_and_dizzinesshttp://en.wikipedia.org/w/index.php?title=R65:_Harmful:_may_cause_lung_damage_if_swallowedhttp://en.wikipedia.org/w/index.php?title=R62:_Possible_risk_of_impaired_fertilityhttp://en.wikipedia.org/w/index.php?title=R51/53:_Toxic_to_aquatic_organisms%2C_may_cause_long-term_adverse_effects_in_the_aquatic_environmenthttp://en.wikipedia.org/w/index.php?title=R48/20:_Harmful:_danger_of_serious_damage_to_health_by_prolonged_exposure_through_inhalationhttp://en.wikipedia.org/w/index.php?title=R38:_Irritating_to_skinhttp://en.wikipedia.org/w/index.php?title=R11:_Highly_flammablehttp://en.wikipedia.org/w/index.php?title=List_of_R-phraseshttp://en.wikipedia.org/w/index.php?title=File:Hazard_N.svghttp://en.wikipedia.org/w/index.php?title=File:Hazard_X.svghttp://en.wikipedia.org/w/index.php?title=File:Hazard_F.svghttp://en.wikipedia.org/w/index.php?title=Dangerous_Substances_Directive_%2867/548/EEC%29http://en.wikipedia.org/w/index.php?title=GHS_precautionary_statementshttp://en.wikipedia.org/w/index.php?title=GHS_hazard_statementhttp://en.wikipedia.org/w/index.php?title=Globally_Harmonized_System_of_Classification_and_Labelling_of_Chemicalshttp://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-pollu.svghttp://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-silhouete.svghttp://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-exclam.svghttp://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-flamme.svghttp://en.wikipedia.org/w/index.php?title=GHS_hazard_pictogramshttp://en.wikipedia.org/w/index.php?title=Hexane_%28data_page%29%23Material_Safety_Data_Sheethttp://en.wikipedia.org/w/index.php?title=Material_safety_data_sheethttp://en.wikipedia.org/w/index.php?title=Standard_enthalpy_change_of_combustionhttp://en.wikipedia.org/w/index.php?title=Standard_enthalpy_change_of_combustionhttp://en.wikipedia.org/w/index.php?title=Standard_enthalpy_change_of_formationhttp://en.wikipedia.org/w/index.php?title=Standard_enthalpy_change_of_formationhttp://en.wikipedia.org/w/index.php?title=Standard_molar_entropyhttp://en.wikipedia.org/w/index.php?title=Standard_molar_entropyhttp://en.wikipedia.org/w/index.php?title=Specific_heat_capacityhttp://en.wikipedia.org/w/index.php?title=Specific_heat_capacityhttp://en.wikipedia.org/w/index.php?title=Viscosityhttp://en.wikipedia.org/w/index.php?title=Refractive_indexhttp://en.wikipedia.org/w/index.php?title=Lambda-maxhttp://en.wikipedia.org/w/index.php?title=Henry%27s_lawhttp://en.wikipedia.org/w/index.php?title=Vapor_pressurehttp://en.wikipedia.org/w/index.php?title=Partition_coefficienthttp://en.wikipedia.org/w/index.php?title=Waterhttp://en.wikipedia.org/w/index.php?title=Solubilityhttp://en.wikipedia.org/w/index.php?title=Boiling_pointhttp://en.wikipedia.org/w/index.php?title=Melting_pointhttp://en.wikipedia.org/w/index.php?title=Density
  • 5/26/2018 Hexane

    3/7

    Hexane 3

    Related compounds

    Related alkanes Pentane

    Heptane

    Supplementary data page

    Structure and

    properties

    n, r, etc.

    Thermodynamic

    data

    Phase behaviour

    Solid, liquid, gas

    Spectral data UV, IR, NMR, MS

    Except where noted otherwise, data are given for materials in their standard state (at 25 C (77 F), 100 kPa)

    (verify)[12]

    (what is: / ?)

    Infobox references

    Hexane/hksen/ is an alkane of six carbon atoms, with the chemical formula C6H

    14.

    The term may refer to any of the five structural isomers with that formula, or to a mixture of them. In IUPAC

    nomenclature, however, hexane is the unbranched isomer (n-hexane); the other four structures are named as

    methylated derivatives of pentane and butane. IUPAC also uses the term as the root of many compounds with a

    linear six-carbon backbone, such as 2-methylhexane (C7H

    16), which is also called "isoheptane".

    Hexanes are significant constituents of gasoline. They are all colorless liquids at room temperature, odorless when

    pure, with boiling points between 50 and 70 C. They are widely used as cheap, relatively safe, largely unreactive,

    and easily evaporated non-polar solvents.

    Isomers

    Common name IUPAC name Text formula Skeletal formula

    normal hexane

    n-hexane

    hexane CH3(CH

    2)4CH

    3

    isohexane 2-methylpentane (CH3)2CH(CH

    2)2CH

    3

    3-methylpentane CH3CH

    2CH(CH

    3)CH

    2CH

    3

    2,3-dimethylbutane CH3CH(CH

    3)CH(CH

    3)CH

    3

    neohexane 2,2-dimethylbutane CH3C(CH

    3)2CH

    2CH

    3

    http://en.wikipedia.org/w/index.php?title=File:2%2C2-dimetilbut%C4%81ns.svghttp://en.wikipedia.org/w/index.php?title=2%2C2-Dimethylbutanehttp://en.wikipedia.org/w/index.php?title=File:2%2C3-dimetilbut%C4%81ns.svghttp://en.wikipedia.org/w/index.php?title=2%2C3-Dimethylbutanehttp://en.wikipedia.org/w/index.php?title=File:3-metilpent%C4%81ns.svghttp://en.wikipedia.org/w/index.php?title=3-Methylpentanehttp://en.wikipedia.org/w/index.php?title=File:2-metilpent%C4%81ns.svghttp://en.wikipedia.org/w/index.php?title=2-Methylpentanehttp://en.wikipedia.org/w/index.php?title=File:Hexane-2D-Skeletal.svghttp://en.wikipedia.org/w/index.php?title=Solventhttp://en.wikipedia.org/w/index.php?title=Chemical_polarityhttp://en.wikipedia.org/w/index.php?title=Gasolinehttp://en.wikipedia.org/w/index.php?title=2-Methylhexanehttp://en.wikipedia.org/w/index.php?title=Butanehttp://en.wikipedia.org/w/index.php?title=Pentanehttp://en.wikipedia.org/w/index.php?title=Methyl_grouphttp://en.wikipedia.org/w/index.php?title=International_Union_of_Pure_and_Applied_Chemistryhttp://en.wikipedia.org/w/index.php?title=Structural_isomerhttp://en.wikipedia.org/w/index.php?title=Chemical_formulahttp://en.wikipedia.org/w/index.php?title=Carbonhttp://en.wikipedia.org/w/index.php?title=Alkanehttp://en.wikipedia.org/w/index.php?title=Help:IPA_for_Englishhttp://en.wikipedia.org/w/index.php?title=Help:IPA_for_English%23Keyhttp://en.wikipedia.org/w/index.php?title=Help:IPA_for_Englishhttp://en.wikipedia.org/wiki/Chemical_infobox#Referenceshttp://en.wikipedia.org/w/index.php?title=File:X_mark.svghttp://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttp://en.wikipedia.org/wiki/WikiProject_Chemicals/Chembox_validationhttp://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=443856572&page2=Hexanehttp://en.wikipedia.org/w/index.php?title=File:Yes_check.svghttp://en.wikipedia.org/w/index.php?title=Standard_statehttp://en.wikipedia.org/w/index.php?title=Mass_spectrometryhttp://en.wikipedia.org/w/index.php?title=NMR_spectroscopyhttp://en.wikipedia.org/w/index.php?title=Infrared_spectroscopyhttp://en.wikipedia.org/w/index.php?title=UV/VIS_spectroscopyhttp://en.wikipedia.org/w/index.php?title=Hexane_%28data_page%29%23Spectral_datahttp://en.wikipedia.org/w/index.php?title=Hexane_%28data_page%29%23Thermodynamic_propertieshttp://en.wikipedia.org/w/index.php?title=Hexane_%28data_page%29%23Thermodynamic_propertieshttp://en.wikipedia.org/w/index.php?title=Dielectric_constanthttp://en.wikipedia.org/w/index.php?title=Refractive_indexhttp://en.wikipedia.org/w/index.php?title=Hexane_%28data_page%29%23Structure_and_propertieshttp://en.wikipedia.org/w/index.php?title=Hexane_%28data_page%29%23Structure_and_propertieshttp://en.wikipedia.org/w/index.php?title=Hexane_%28data_page%29http://en.wikipedia.org/w/index.php?title=Heptanehttp://en.wikipedia.org/w/index.php?title=Pentane
  • 5/26/2018 Hexane

    4/7

    Hexane 4

    Uses

    In industry, hexanes are used in the formulation of glues for shoes, leather products, and roofing. They are also used

    to extract cooking oils (such as canola oil) from seeds, for cleansing and degreasing a variety of items, and in textile

    manufacturing.

    A typical laboratory use of hexanes is to extract oil and grease contaminants from water and soil for analysis.[13]

    Since hexane cannot be easily deprotonated, it is used in the laboratory for reactions that involve very strong bases,

    such as the preparation of organolithiums. For example, butyllithiums are typically supplied as a hexane solution.

    In many applications (especially pharmaceutical), the use of n-hexane is being phased out due to its long term

    toxicity. It is often replaced by n-heptane, which will not form the toxic metabolite hexane-2,5-dione.

    Production

    Hexanes are chiefly obtained by the refining of crude oil. The exact composition of the fraction depends largely on

    the source of the oil (crude or reformed) and the constraints of the refining. The industrial product (usually around

    50% by weight of the straight-chain isomer) is the fraction boiling at 6570 C.

    Physical properties

    All alkanes are colourless. The boiling points of the various hexanes are somewhat similar and, as for other alkanes,

    are generally lower for the more branched forms. The melting points are quite different and the trend is not

    apparent.[14]

    Isomer M.P. (C) B.P. (C)

    n-hexane 95.3 68.7

    3-methylpentane 118.0 63.3

    2-methylpentane (isohexane) 153.7 60.3

    2,3-dimethylbutane 128.6 58.0

    2,2-dimethylbutane (neohexane) 99.8 49.7

    Normal hexane (n-hexane) has considerable vapor pressure at room temperature:[15]

    Temperature (C) Vapor pressure (mmHg)

    40 3.36

    30 7.12

    20 14.01

    10 25.91

    0 45.37

    10 75.74

    20 121.26

    25 151.28

    30 187.11

    40 279.42

    50 405.31

    60 572.76

    http://en.wikipedia.org/w/index.php?title=Boiling_pointhttp://en.wikipedia.org/w/index.php?title=Melting_pointhttp://en.wikipedia.org/w/index.php?title=Petroleumhttp://en.wikipedia.org/w/index.php?title=Oil_refineryhttp://en.wikipedia.org/w/index.php?title=Hexane-2%2C5-dionehttp://en.wikipedia.org/w/index.php?title=N-heptanehttp://en.wikipedia.org/w/index.php?title=Organolithium_reagenthttp://en.wikipedia.org/w/index.php?title=Deprotonationhttp://en.wikipedia.org/w/index.php?title=Grease_%28lubricant%29http://en.wikipedia.org/w/index.php?title=Petroleumhttp://en.wikipedia.org/w/index.php?title=Degreasinghttp://en.wikipedia.org/w/index.php?title=Canola_oilhttp://en.wikipedia.org/w/index.php?title=Cooking_oilhttp://en.wikipedia.org/w/index.php?title=Adhesive
  • 5/26/2018 Hexane

    5/7

    Hexane 5

    Safety

    Acute exposure to n-hexane usually occurs by inhalation, but it may be absorbed orally and transdermally. Minor

    exposures may occur when persons fill their automobile fuel tanks with gasoline. Recent research suggests that

    certain fungi may be able to produce n-hexane.

    The acute toxicity of n-hexane is rather low. However, it has been reported to be the most highly toxic member of

    the alkanes. When n-hexane is ingested, it causes nausea, vertigo, bronchial irritation, intestinal irritation and CNS

    effects. It has been reported that ~ 50 g of n-hexane may be fatal to humans. Furthermore, n-hexane is

    biotransformed to 2-hexanol and further to 2,5-hexanediol by cytochrome P450 mixed function oxidases by omega

    oxidation. 2,5-Hexanediol may be further oxidized to 2,5-hexanedione, which is neurotoxic and produces a

    polyneuropathy.

    n-Hexane is also used as a solvent in the extraction of oil from seeds (soybean, cottonseed, flaxseed, safflower seed,

    and others). It is sometimes used as a denaturant for alcohol, and as a cleaning agent in the textile, furniture, and

    leather industries. It is slowly being replaced with other less toxic solvents.

    The National Institute for Occupational Safety and Health recommended exposure limit is 50 ppm (180 mg m3

    ),

    expressed as an 8 h time-weighted average (TWA). A peer reviewed study found that inhalation of n-Hexane at 5000ppm for 10 minutes produces marked vertigo; 2500-1000 ppm for 12 hours produces drowsiness, fatigue, loss of

    appetite, paresthesia in distal extremities; 2500-500 ppm produces muscle weakness, cold pulsation in extremities,

    blurred vision, headache and anorexia.

    Occupational hexane poisoning has occurred with Japanese sandal workers, Italian shoe workers, Taiwan press

    proofing workers, and others. Analysis of Taiwanese workers has shown occupational exposure to substances

    including n-Hexane. Recently, Chinese workers manufacturing iPhones have suffered hexane poisoning.[16]

    References

    [1] http://www.commonchemistry.org/ChemicalDetail.aspx?ref=110-54-3

    [2] http://pubchem. ncbi.nlm.nih.gov/summary/summary.cgi?cid=8058

    [3] http://www.chemspider.com/Chemical-Structure.7767. html

    [4] http://fdasis.nlm.nih.gov/srs/srsdirect.jsp?regno=2DDG612ED8

    [5] http://esis.jrc.ec.europa.eu/lib/einecs_IS_reponse.php?genre=ECNO&entree=203-777-6

    [6] http://www.drugbank.ca/drugs/DB02764

    [7] http://www.kegg.jp/entry/C11271

    [8] http://www.nlm.nih.gov/cgi/mesh/2014/MB_cgi?mode=&term=n-hexane

    [9] https://www.ebi.ac.uk/chebi/searchId.do?chebiId=29021

    [10] https://www.ebi.ac.uk/chembldb/index.php/compound/inspect/CHEMBL15939

    [11] http://chemapps.stolaf.edu/jmol/jmol.php?model=CCCCCC

    [12] http://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=443856572& page2=Hexane

    [13] Use of ozone depleting substances in laboratories (http://www.norden.org/pub/ebook/2003-516. pdf). TemaNord 2003:516.

    [14] William D. McCain (1990), The properties of petroleum fluids(http://books.google.com/books?id=1TJQ64JN2ZUC&

    printsec=frontcover). PennWell. ISBN 0-87814-335-1

    [15] vapor pressure (http://www.xydatasource.com/xy-showdatasetpage.php?datasetcode=84114&dsid=63Hexane)

    [16] Workers poisoned while making iPhones (http://www.abc.net.au/news/stories/2010/10/26/3048024. htm) ABC News, 25 October

    2010

    http://www.abc.net.au/news/stories/2010/10/26/3048024.htmhttp://www.xydatasource.com/xy-showdatasetpage.php?datasetcode=84114&dsid=63Hexanehttp://books.google.com/books?id=1TJQ64JN2ZUC&printsec=frontcoverhttp://books.google.com/books?id=1TJQ64JN2ZUC&printsec=frontcoverhttp://www.norden.org/pub/ebook/2003-516.pdfhttp://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=443856572&page2=Hexanehttp://chemapps.stolaf.edu/jmol/jmol.php?model=CCCCCChttps://www.ebi.ac.uk/chembldb/index.php/compound/inspect/CHEMBL15939https://www.ebi.ac.uk/chebi/searchId.do?chebiId=29021http://www.nlm.nih.gov/cgi/mesh/2014/MB_cgi?mode=&term=n-hexanehttp://www.kegg.jp/entry/C11271http://www.drugbank.ca/drugs/DB02764http://esis.jrc.ec.europa.eu/lib/einecs_IS_reponse.php?genre=ECNO&entree=203-777-6http://fdasis.nlm.nih.gov/srs/srsdirect.jsp?regno=2DDG612ED8http://www.chemspider.com/Chemical-Structure.7767.htmlhttp://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=8058http://www.commonchemistry.org/ChemicalDetail.aspx?ref=110-54-3http://en.wikipedia.org/w/index.php?title=IPhonehttp://en.wikipedia.org/w/index.php?title=Time-weighted_averagehttp://en.wikipedia.org/w/index.php?title=Recommended_exposure_limithttp://en.wikipedia.org/w/index.php?title=National_Institute_for_Occupational_Safety_and_Healthhttp://en.wikipedia.org/w/index.php?title=Polyneuropathyhttp://en.wikipedia.org/w/index.php?title=Neurotoxicityhttp://en.wikipedia.org/w/index.php?title=2%2C5-hexanedionehttp://en.wikipedia.org/w/index.php?title=Omega_oxidationhttp://en.wikipedia.org/w/index.php?title=Omega_oxidationhttp://en.wikipedia.org/w/index.php?title=Cytochrome_P450http://en.wikipedia.org/w/index.php?title=2%2C5-hexanediolhttp://en.wikipedia.org/w/index.php?title=2-hexanolhttp://en.wikipedia.org/w/index.php?title=Gasoline
  • 5/26/2018 Hexane

    6/7

    Hexane 6

    External links

    International Chemical Safety Card 1262 (http://www.inchem.org/documents/icsc/icsc/eics1262.htm)

    (2-methylpentane)

    Material Safety Data Sheet for Hexane (http://physchem.ox.ac.uk/MSDS/HE/hexane.html)

    National Pollutant Inventory n-hexane fact sheet (http://www.npi.gov.au/database/substance-info/profiles/

    47.html)

    NIOSH Pocket Guide to Chemical Hazards (http://www.cdc.gov/niosh/npg/npgd0323.html) (hexane

    isomers)

    Phytochemica l database entry (http://www.ars-grin.gov/cgi-bin/duke/chemical.pl?HEXANE)

    Center for Disease Control and Prevention (http://www.cdc.gov/mmwr/preview/mmwrhtml/mm5045a3.

    htm)

    Warning from National Safety Council "COMMON CHEMICAL AFFECTS AUTO MECHANICS" (http://

    www.nsc.org/EHC/jrn/tips/tip167.htm)

    Australian National Pollutant Inventory (NPI) (http://www.npi. gov.au/database/substance-info/profiles/47.

    html) page

    "EPA does not consider n-hexane classifiable as a human carcinogen." (http://www.epa.gov/ttn/atw/vegoil/

    fr12ap01.pdf) Federal Register / Vol. 66, No. 71 / Thursday, 12 April 2001 / Rules and Regulations

    http://www.epa.gov/ttn/atw/vegoil/fr12ap01.pdfhttp://www.epa.gov/ttn/atw/vegoil/fr12ap01.pdfhttp://www.npi.gov.au/database/substance-info/profiles/47.htmlhttp://www.npi.gov.au/database/substance-info/profiles/47.htmlhttp://www.nsc.org/EHC/jrn/tips/tip167.htmhttp://www.nsc.org/EHC/jrn/tips/tip167.htmhttp://www.cdc.gov/mmwr/preview/mmwrhtml/mm5045a3.htmhttp://www.cdc.gov/mmwr/preview/mmwrhtml/mm5045a3.htmhttp://www.ars-grin.gov/cgi-bin/duke/chemical.pl?HEXANEhttp://www.cdc.gov/niosh/npg/npgd0323.htmlhttp://www.npi.gov.au/database/substance-info/profiles/47.htmlhttp://www.npi.gov.au/database/substance-info/profiles/47.htmlhttp://physchem.ox.ac.uk/MSDS/HE/hexane.htmlhttp://www.inchem.org/documents/icsc/icsc/eics1262.htm
  • 5/26/2018 Hexane

    7/7

    Article Sources and Contributors 7

    Article Sources and ContributorsHexane Source: http://en.wikipedia.org/w/index.php?oldid=604626255 Contributors: 1exec1, 2mengrong, Animum, Antimatter15, Apple2, Arkwatem, Aronzak, Aussie Alchemist, Badagnani,

    Beetstra, Belovedfreak, Benjah-bmm27, Bgwhite, Bitoffish, Blurpeace, Bobblewik, Bobo192, Br77rino, BrightStarSky, Brookie, Butofcourse22, Cburnett, Ceyockey, Cfailde, Chem-awb,

    Chempedia, Chinasaur, Choess, Christian75, DGtal, Da Joe, DePiep, Deflective, Denelson83, Dhaluza, Die Antwoorde, Drthomasj, Dyna900, Edgar181, El Cazangero, Enchanter, Firsfron, Gene

    Nygaard, Giftlite, Gzkn, Hernandog, Idahoev, Ikbentbeu, Ilikechicken1234, Jaknouse, Jarble, Jiang, Jim1138, JimVC3, Jni, Joelholdsworth, JohnSRoberts99, Jorge Stolfi, Josh Cherry, Joshua,

    Jrockley, Jynto, Karlhahn, Keilana, Kerinlau, Kevinbsmith, Kierano, Kjkolb, LarryMorseDCOhio, Levent, Luka Krstulovi, Magicwombat, Magioladitis, Malafaya, Malick78, Materialscientist,

    Mintleaf, Mofluk, Munita Prasad, Mushin, Navdar, Nintendowii2006, Niteowlneils, Nixietech, OccultZone, Olivierd, Osarbu, PGWG, PeterJeremy, Physchim62, Plasmic Physics,

    Ponydepression, PopUpPirate, Pseudomonas, Ptdecker, Pll, Qball369, Raptomania, Reify-tech, Rifleman 82, Rjwilmsi, Ronhjones, Rostz, Sburke, Scarian, Schneelocke, Sciurin, Securiger,Shaddack, Shimmin, Skuphal, Smenge32, Spiffy sperry, Stepa, Stevenmitchell, Storm Rider, Super-Magician, Tarquin, Taweetham, The PIPE, Tim Starling, TimeLord mbw, Tomaxer, Uncle G,

    Unitknow, VPliousnine, Vchorozopoulos, Vicdahl, Vsmith, Widr, William915, WolfmanSF, Worksafe, ~K, , , 172 anonymous edits

    Image Sources, Licenses and ContributorsFile:Hexane-2D-Skeletal.svg Source: http://en.wikipedia.org/w/index.php?title=File:Hexane-2D-Skeletal.svgLicense: Public Domain Contributors: Joel Holdsworth (Joelholdsworth)

    File:Hexane-2D-B.png Source: http://en.wikipedia.org/w/index.php?title=File:Hexane-2D-B.pngLicense: Public Domain Contributors: Ben Mills

    File:Hexane-from-xtal-1999-at-an-angle-3D-balls.png Source: http://en.wikipedia.org/w/index.php?title=File:Hexane-from-xtal-1999-at-an-angle-3D-balls.pngLicense: Public Domain

    Contributors: Ben Mills

    File:Hexane-3D-vdW.png Source: http://en.wikipedia.org/w/index.php?title=File:Hexane-3D-vdW.pngLicense: Public Domain Contributors: Ben Mills

    File:Yes check.svg Source: http://en.wikipedia.org/w/index.php?title=File:Yes_check.svgLicense: Public Domain Contributors: Anomie

    Image:GHS-pictogram-flamme.svg Source: http://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-flamme.svgLicense: Public Domain Contributors: Torsten Henning

    Image:GHS-pictogram-exclam.svg Source: http://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-exclam.svgLicense: Public Domain Contributors: Torsten Henning

    Image:GHS-pictogram-silhouete.svg Source: http://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-silhouete.svgLicense: Public Domain Contributors: Torsten Henning

    Image:GHS-pictogram-pollu.svg Source: http://en.wikipedia.org/w/index.php?title=File:GHS-pictogram-pollu.svgLicense: Public Domain Contributors: Torsten Henning

    Image:Hazard_F.svg Source: http://en.wikipedia.org/w/index.php?title=File:Hazard_F.svgLicense: Public Domain Contributors: Phrood

    Image:Hazard_X.svg Source: http://en.wikipedia.org/w/index.php?title=File:Hazard_X.svgLicense: Public Domain Contributors: BLueFiSH.as, Herbythyme, Leyo, MarianSigler, Matthias

    M., Phrood, Sarang, Sertion, W!B:, 8 anonymous edits

    Image:Hazard_N.svg Source: http://en.wikipedia.org/w/index.php?title=File:Hazard_N.svgLicense: Public Domain Contributors: See historic

    File:X mark.svg Source: http://en.wikipedia.org/w/index.php?title=File:X_mark.svgLicense: Public Domain Contributors: User:Gmaxwell

    File:2-metilpentns.svg Source: http://en.wikipedia.org/w/index.php?title=File:2-metilpentns.svgLicense: Creative Commons Attribution-ShareAlike 3.0 Unported Contributors: Dbc334,

    Dirk Hnniger, Hystrix, Yyy

    File:3-metilpentns.svg Source: http://en.wikipedia.org/w/index.php?title=File:3-metilpentns.svgLicense: Creative Commons Attribution-ShareAlike 3.0 Unported Contributors: Dbc334,

    Dirk Hnniger, Hystrix, Leyo, Yyy

    File:2,3-dimetilbutns.svg Source: http://en.wikipedia.org/w/index.php?title=File:2,3-dimetilbutns.svgLicense: Creative Commons Attribution-ShareAlike 3.0 Unported Contributors:

    Dbc334, Dirk Hnniger, Hystrix, Leyo, Yyy

    File:2,2-dimetilbutns.svg Source: http://en.wikipedia.org/w/index.php?title=File:2,2-dimetilbutns.svgLicense: Creative Commons Attribution-ShareAlike 3.0 Unported Contributors:

    Dbc334, Dirk Hnniger, Hystrix, Leyo, Yyy

    License

    Creative Commons Attribution-Share Alike 3.0//creativecommons.org/licenses/by-sa/3.0/