hbr , v(m+i), i = 4-8,10 agust/rannsoknir/crete/ppt-131202x

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), i = 4-8,10 ://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-13120 ://notendur.hi.is/~ agust/rannsoknir/Crete/PXP-13120 ://notendur.hi.is/~agust/rannsoknir/Crete/XLS-13120

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HBr , V(m+i), i = 4-8,10 https://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-131202.pptx https://notendur.hi.is/~ agust/rannsoknir/Crete/PXP-131203.pxp https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131203.xlsx. HBr , V(m+i)´s. H + + Br (1/2). H + + Br (3/2) Normalized. - PowerPoint PPT Presentation

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HBr,V(m+i), i = 4-8,10

https://notendur.hi.is/~agust/rannsoknir/Crete/PPT-131202.pptx

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxphttps://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131203.xlsx

8

6

4

2

0

3.02.52.01.51.00.50.0

H+ + Br(1/2)

H+ + Br(3/2)Normalized

HBr, V(m+i)´s

V(m+10)

V(m+8) V(m+7) V(m+6) V(m+5)V(m+4)

H+ <- HBr+(v´)

Agust,lab top,C:/…/PXP-131127a.pxp ; Gr0, Lay0

KER/eV

2.5

2.0

1.5

1.0

0.5

0.0

3.02.52.01.5

HBr; 3/2 <-3/2transitions

KER/eV

V(m+10)

V(m+8)

V(m+7)

V(m+6)

V(m+5)

V(m+4)

Agust,lab top,C:/…/PXP-131127a.pxp ; Gr0, Lay0 <= XLS-131127.xls („KER,I,II“)

3.0

2.5

2.0

1.5

1.0

0.5

0.0

3.02.52.01.51.00.50.0

V(m+6)

V(m+5)

V(m+4)

KER/eV Agust,heima & lab top,C:/…/PXP-131129.pxp ; Gr1, Lay1 <= XLS-131127.xls („KER,I,II“)

v+= 8 10 12 13

v+= 8 10 12 13

v+= 8 10 12 13

HBr; 3/2 <-3/2TransitionsKER spectra normalized to the H+ + Br(3/2)channel

8

6

4

2

0

3.02.52.01.51.00.50.0 KER/eV Agust heima&,lab top,C:/…/PXP-131129.pxp ; Gr2, Lay2 <= XLS-131127.xls („KER,I,II“)

V(m+10)

V(m+8)

V(m+7)

v+= 8 10 12 13 15

v+= 8 10 12 13

v+= 8 10 12 13

HBr; 3/2 <-3/2TransitionsKER spectra normalized to the H+ + Br(3/2)channel

2.5

2.0

1.5

1.0

0.5

0.0

3.02.52.01.5 KER/eV agust heima/…/PXP-131202.pxp ; Gr0, Lay0 <= XLS-131202.xls („KER,III,IV“)

HBr; 1/2 <-1/2transitions

?

3.0

2.5

2.0

1.5

1.0

0.5

0.0

3.02.52.01.51.00.50.0 KER/eV agust heima/…/PXP-131202.pxp ; Gr1 Lay1

HBr; 3/2 <-3/2 (bold sticks) &1/2 <-1/2 (thin sticks)

v+= 8 10 11 12 8 9 10

v+= 8 10 12 13

8 9 10

v+= 8 10 12 13

8 9 10 11

V(m+6)

V(m+5)

V(m+4)

8

6

4

2

0

3.02.52.01.51.00.50.0

v+= 8 10 12 13

8 9 10

v+= 8 10 12 13

8 9 10 11

v+= 8 10 12 13 15

9 10 11

HBr; 3/2 <-3/2 (bold sticks) &1/2 <-1/2 (thin sticks)

KER/eV agust heima/…/PXP-131202.pxp ; Gr1 Lay1

V(m+10)

V(m+8)

V(m+7)

3.0

2.5

2.0

1.5

1.0

0.5

0.0

3.02.52.01.51.00.50.0 KER/eV agust heima/…/PXP-131203.pxp ; Gr1 Lay1

HBr; 1/2 <-3/2 (bold sticks) &3/2 <-1/2 (thin sticks)

v+= 10 12 13

6 7 8 9

v+= 10 12 13

6 7 8 9

v+= 10 12 13 6 7 8 9

V(m+6)

V(m+5)

V(m+4)

8

6

4

2

0

3.02.52.01.51.00.50.0

HBr; 1/2 <-3/2 (bold sticks) &3/2 <-1/2 (thin sticks)

KER/eV agust heima/…/PXP-131203.pxp ; Gr2 Lay2

v+= 10 12 13 15

6 7 8 9

v+= 10 12 13

6 7 8

v+= 10 12 13

6 7 8

V(m+10)

V(m+8)

V(m+7)

1.0

0.8

0.6

0.4

0.2

0.0

2.52.01.51.00.50.0

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131208.pxp

HBr; 3/2 <-3/2 (bold sticks) &1/2 <-1/2 (thin sticks)

KER/eV

E(0),J´=1

v+= 8 10 11 12 13 9 10

The vibrational structure in the„H+ + Br/Br* via HBr+(v+) ionization channel“ isdue to a combination of H+ + Br(3/2) <- HBr+(v+)(3/2) (i.e. 3/2 <-3/2)andH+ + Br(1/2) <- HBr+(v+)(1/2) (i.e. 1/2 <-1/2)transitions

1.25x105

1.20

1.15

1.10

1.05

1.00

0.95

Ene

rgy

/cm

-1

1.31.21.11.00.9

Internuclear Distance / Å

v+(3/2)1615

1413

12

11

10

v+(1/2)1413

12

11

10

9

8

V(m+10)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

1.25x105

1.20

1.15

1.10

1.05

1.00

0.95

Ene

rgy

/cm

-1

1.31.21.11.00.9

Internuclear Distance / Å

v+(3/2)1615

1413

12

11

10

v+(1/2)1413

12

11

10

9

8

V(m+8)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

1.25x105

1.20

1.15

1.10

1.05

1.00

0.95

Ene

rgy

/cm

-1

1.31.21.11.00.9

Internuclear Distance / Å

v+(3/2)1615

1413

12

11

10

v+(1/2)1413

12

11

10

9

8

V(m+7)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

1.25x105

1.20

1.15

1.10

1.05

1.00

0.95

Ene

rgy

/cm

-1

1.31.21.11.00.9

Internuclear Distance / Å

v+(3/2)1615

1413

12

11

10

v+(1/2)1413

12

11

10

9

8

V(m+6)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

1.25x105

1.20

1.15

1.10

1.05

1.00

0.95

Ene

rgy

/cm

-1

1.31.21.11.00.9

Internuclear Distance / Å

v+(3/2)1615

1413

12

11

10

v+(1/2)1413

12

11

10

9

8

V(m+5)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

1.25x105

1.20

1.15

1.10

1.05

1.00

0.95

Ene

rgy

/cm

-1

1.31.21.11.00.9

Internuclear Distance / Å

v+(3/2)1615

1413

12

11

10

v+(1/2)1413

12

11

10

9

8

V(m+4)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

14

14

16

V+max(3/2) V+max(1/2)

spectra calc spectra calc

V(m+10) 16 16 ? 14

V(m+8) 14 14 ? 13

V(m+7) 14 14 ? 12

V(m+6) 13 13 ? 11

V(m+5) 12 12 ? 11

V(m+4) 12 12 ? 10

1.4x105

1.3

1.2

1.1

1.0

0.9

0.8

Ene

rgy

/cm

-1

54321

Internuclear Distance / Å

[4P,5s] Rydb.

H + Br**(5s)

H*(n=2)+Br

H+ + Br-

H+Br+ + e

H++Br+e

[B2S+] ..superexcited state

[(3)2P] ..superexcited state

HBr+*(A)

HBr+(X)

2hn to V(m+7)

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

V

F

H

HBr+*(X)

v+=14v+=12

E

8

6

4

2

0

3.02.52.01.51.00.50.0

H+ + Br(1/2)

H+ + Br(3/2)Normalized

HBr, V(m+i)´s

V(m+10) V(m+9) V(m+8) V(m+7) V(m+6) V(m+5)V(m+4)

H+ <- HBr+(v´)

KER/eV

https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131209a.pxp ; Gr0 Lay0