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Hazard Identification and Risk Assessment Prepared for John and Anna Arcidiacono BP Huntingwood 6 Honeman Close, Huntingwood, NSW Date: 13/07/2017 Project No: 11034 Revision: A

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Hazard Identification and Risk Assessment

Prepared for

John and Anna Arcidiacono

BP Huntingwood

6 Honeman Close, Huntingwood, NSW

Date: 13/07/2017

Project No: 11034 Revision: A

Cadway Project No 10909

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 1 of 39

Prepared by:

Authored by Approved by Approval Date

C. Karageorgos C. Rogers 14/07/17

History:

Rev Nature of Change/Issue Author Date

A Issued for DA C. Karageorgos 14/07/17

Disclaimer

This report is based on information provided by the Client in terms of the types of dangerous goods and the

quantities to be stored and handled on site. A facility management plan shall include the quantities of

dangerous goods stored and any relevant information contained in this report so that users are aware of these

requirements. This report assesses only the situations indicated and does not address all possible scenarios or

catastrophic events which may be possible but have a very low likelihood of occurring. Assumptions have

been made, as indicated and these need to be considered in management practices. The report outcomes

do not totally eliminate the risks, but rather present a risk management approach intended to mitigate risks to

as low as practicable to achieve compliance with the appropriate standards for the facility. If the activities or

dangerous goods or quantities change then this assessment shall be updated to ensure compliance is

maintained and safety is properly considered.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 2 of 39

Contents

1. Scope of this Report ....................................................................................................................................... 3

2. Description of Site ........................................................................................................................................... 4

3. Description of the Proposed Fuel Facilities ................................................................................................ 5

4. Findings and Recommendations ................................................................................................................ 7

5. Methodology ................................................................................................................................................. 11

6. Site Manifest .................................................................................................................................................. 12

7. Hazard Identification and Risk Assessment ............................................................................................. 14

8. SEPP 33 Preliminary screening .................................................................................................................... 31

9. Appendix A - Legislation ............................................................................................................................. 32

10. Appendix B - Proposed Site Plan ............................................................................................................... 33

11. Appendix C - Safety Data Sheets ............................................................................................................. 34

12. Appendix D - Enviropacific Services Fuel Experience ........................................................................... 35

13. Appendix E - Enviropacific Services Fuel Industry Clients ..................................................................... 36

14. Appendix G - Enviropacific Services Fuel Industry Projects .................................................................. 37

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 3 of 39

1. Scope of this Report

A Hazard Identification and Risk Assessment of the proposed BP Huntingwood Service station 6

Honeman Close, Huntingwood, NSW, 2148 was carried out by Enviropacific Services Pty Ltd on the

13/07/17 on behalf of John and Anna Arcidiacono. The purpose of this Hazard Identification and

Risk Assessment is to report on the compliance of the Hazardous Chemical storage, and the fuel

dispensing system at this facility as required by current National and relevant State Acts,

Regulations, Codes, and Australian Standards and Local Authority Approvals (refer to Appendix A).

The observations and comments in this Hazard Identifications and Risk Assessment Report are based

on information supplied to Enviropacific Services by the client and the proposed works to be

undertaken on site. This report has reviewed the proposed service station and does not assess the

hazards and risks outside of the service station boundary in relation to the adjoining development.

Enviropacific’s duty is to ensure that all information contained in this Hazard Identification and Risk

Assessment Report is accurate and current. Enviropacific Services recommendations are

applicable only to matters relevant to the National and State Acts, Regulations, Codes, Australian

Standards (refer to Appendix A), and Local Authority Approvals made available by the Client.

While this report identifies intentional criminal activities such as vandalism and theft, deliberate acts

of sabotage or terrorism are outside the scope of this document and should be addressed by a

specialist consultant if required. Work Health and Safety risk assessments should be carried out in

addition to this Hazard Identification and Risk Assessment Report.

Items not specifically mentioned in this Hazard Identification and Risk Assessment Report should not

be regarded as having been inspected by Enviropacific Services. Recommendations are not

exhaustive, and when applicable, all recommended works are subject to approval and full

compliance by the National and State Authorities.

Enviropacific Services Pty Ltd is a registered Building Design Company which has worked for and

within the Retail Petroleum Industry for more than 20 years (refer to Appendix D for Enviropacific

Services company profile). The recommendations contained within this document are based on

Enviropacific Services industry experience and on sound professional practice. Opinions and

advice given by Enviropacific Services in the following report represents Enviropacific Services best

judgement, but (to the permitted extent by law) Enviropacific Services accepts no liability for

claims or damages caused by its negligence (or that of its employees or agents) or otherwise. As

such, the reader is invited to obtain any supporting information he or she feels is necessary before

making any decisions.

The following report is confidential and not to be made available to other parties unless under the

consent of the Client.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 4 of 39

2. Description of Site

Address: BP Huntingwood Service station

6 Honeman Close,

Huntingwood

NSW, 2148

Site Area of proposed works: 15032 m2

Real Property Description: Lot 2 on DP229466

Local Authority: Blacktown Council

Owner: John and Anna Arcidiacono

Operator: John and Anna Arcidiacono

Figure 1 Aerial Photo of Site Locality

PROPOSED SITE

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 5 of 39

3. Description of the Proposed Fuel Facilities

The following is a description of the facilities based on the findings and recommendation contained

within this report which when implemented mitigate the identified risks to an acceptable level.

This is a new service station development consisting of a shop building, car canopy and

truck canopy.

The sales building has an area of 475m2.

The car canopy covers has an area 420m2.

The truck canopy covers has an area 380m2.

The car canopy will have 6 x 8 hose fuel dispensers.

The truck canopy will have 5 x 6 hose fuel dispensers.

The Underground Petroleum Storage System (UPSS) consists of 5 x 110kL double contained

skin fibreglass tanks complying with AS 1692-2006 and AS 1940-2004.

A gravity flow, containment and treatment device shall be installed to collect any potential

contamination or spills to prevent hydrocarbons from entering the council stormwater

system. This system shall have a minimum spill capacity of 9,500 litres in the event of a fuel

tanker compartment rupture as required by AS 1940-2004.

The UPSS remote fill points are contained within a spill safe fill box and located within the spill

containment area.

A stainless steel DEF remote fill point is contained within a spill safe fill box and located within

the spill containment area.

Filling of the underground fuel tanks will be conducted by a tanker that will enter in a

forward direction onto the hardstand area. The tanker discharge area will contain an

emergency stop, automatic tank gauging panel, fire hydrant with foam making facilities,

fire extinguishers, and associated compliant signage.

Vents for the UPSS and treatment system shall be located in a landscaping island and

protected by bollards or equivalent.

Vapour Recovery Stage 1 shall be installed on site.

Pipe work shall be installed on site to allow for the installation of Vapour Recovery Stage 2.

Sufficient bollards shall be installed to provide adequate vehicle impact protection to

vulnerable equipment.

Impervious concrete pavements will be installed on site.

1 x emergency stops shall be located under the truck canopy. 1 x emergency stop shall be

located at the shopfront directly accessible from the car canopy. 1 x emergency stop shall

be located on the console.

3 x 9kg ABE fire extinguishers in break glass cabinet shall be located on columns under the

car canopy. 5 x 9kg ABE fire extinguishers in break glass cabinet shall be located on

columns under the truck canopy.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 6 of 39

A fire hose reel will be provided at the forecourt and readily accessible.

A spill kit shall be located in the forecourt.

An air/water point will be located adjacent the car parking bay.

There will be landscaping around the street frontages of the site.

There will be 2 x LPG exchange gas bottle cage located at the front of the shop.

An ice freezer will be located on the plinth at the front of the shop.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 7 of 39

4. Findings and Recommendations

This report is to be referenced in its entirety by the project design team. Excerpts shaded in yellow

however are items to be specifically considered & included as part of the project scope for the

entire multi-disciplinary design team. The relevant disciplines to consider these shaded items

include: civil, electrical, structural & architectural.

The proposed facility can be classified as a Manifest Quantity Workplace as defined in the New

South Wales Work Health and Safety Regulations 2011.

The risk to persons, property, and the environment posed by this proposed service station are

mitigated to an acceptable level of risk provided the following recommendations are

implemented.

A spill containment holding tank of 9,500 litre capacity shall be provided to mitigate the risk

of a fuel tanker compartment sized major spill event from migrating off site and

contaminating the environment or causing damage to persons and/or property.

Instructional signage and training in the use of the facilities shall be provided and

maintained.

Hazchem signage and placarding to be installed in accordance with the New South Wales

Work Health and Safety Regulations 2011.

CCTV with remote monitoring; back-to-base alarm systems and emergency stop button

activation; remote automatic tank gauging for net stock management; active leak

monitoring on the product delivery systems, all with 24 hour reporting and response

capabilities, mitigate the risks present in a service station facility such as this.

A site manifest shall be provided to reflect the on-site refuelling facilities.

An Emergency Plan shall be provided to ensure procedures are in place if an incident was

to occur. Staff training in the implementation of this emergency procedure shall be carried

out and recorded. This Emergency Plan shall be reviewed on a regular basis, when changes

occur on site, or after an incident has occurred.

General:

Provide line marking and directional signage on the forecourt.

Forecourt hardstand surfaces to be designed to be as slip resistant as possible.

Clearly identify entry to shop with pedestrian line marking.

Minimise use of kerbs in areas commonly used by pedestrians. Kerbs in paths of travel shall

be painted in high visibility colour (yellow). Install tactile indicators to Australian Standards.

Spill Containment:

Install an under canopy catchment area that drains to a stormwater treatment system

where the spillage is contained and dealt with in line with specifically formulated

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 8 of 39

Emergency Plan. Impervious concrete pavements will be installed on the tanker hardstand

and fuel compound areas.

Fill points are to be installed within a spill safe fill box draining back into the fuel system. This

spill safe fill box is to be located within the under canopy catchment area.

Provide an emergency spill kit on site that is directly accessible from the dispensers. Provide

training on its use to site staff and tanker drivers.

Console operator to monitor forecourt and immediately clean up any minor spill using

existing on site spill kit.

If a major spill occurs, operator to shut down site and follow emergency procedures.

Check tank excavation observation wells and ground water monitoring wells regularly for

contamination.

Provide product reconciliation procedures (auto tank gauging, manual dip) and ensure

product reconciliation is performed daily.

Provide accurately calibrated tank dips or auto tank gauging.

Provide overfill protection within the tanks.

Fuel System

Install sufficient bollards around dispensers and vents to provide mechanical protection.

Shear valves and flame arrestors are to be provided at the dispenser bases.

Provide dispenser nozzles with safety cut out attitude valve.

Remove latching mechanism from dispenser nozzles.

The fuel tanks are made from non-corrosive materials.

Fuel supply pressure pipework shall be:

I. Double contained underground, non-corrodible pipes

Pressure line leak detection shall be installed to all fuel supply pressure pipework.

Auto tank gauging and line leak detection is to be provided to tanks and pipework.

Vents shall be installed to Australian Standards in a well-ventilated location, away from

potential ignition sources and in a protected area away from vehicles in a landscaping

area of the site.

Statutory Signage

Provide statutory signage at dispensers forbidding smoking on site, use of mobile phones or

other electronic device at dispensers, and the filling of non-compliant containers.

Provide signage on dispensers stating that the latch is not to be locked open and left

unattended.

Provide signage near the vents forbidding smoking on site.

Fill points are to be clearly marked to Australian Standards.

Placarding shall be provided.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 9 of 39

Emergency contact details shall be provided.

Tanker unloading:

Implement strict tanker unloading operation controls.

Provide suitable driver training as to traffic awareness and unloading procedures.

Ensure tanker drivers are trained in site-specific conditions.

Place signage at crossovers warning entering traffic of the presence of the tanker.

Fuel tanker driver to place traffic cones 4m from fuel fill point area and tanker. Close off any

refuelling positions within 4m of the tanker unloading position.

Tanker driver to stand by to monitor fuel transfer operation.

Provide tanker drivers with high visibility clothing.

Operation:

Console operator to shut down dispenser if someone is smoking at dispenser.

Console operator to shut down dispenser if someone is using a mobile phone or other

electronic device at dispenser.

Console operator to shut down dispenser if someone is attempting to fill non-compliant

containers.

Console operator to shut down dispenser if the dispenser is not used appropriately.

Console operator to shut down site and proceed with emergency plan, evacuate if

necessary.

Ensure all staff are trained in spill response.

Maintenance:

Ensure maintenance personnel use traffic cones and signage to barricade off dispenser.

Ensure maintenance personnel use high visibility clothing while on site.

Ensure any electrical work done on dispensers is performed by maintenance personnel with

suitable qualifications and training.

Ensure appropriate work permits are obtained.

Ensure area around the dispensers is adequately ventilated and there is no vehicle parked

close by during maintenance.

Ensure all potential ignition sources are excluded from the area while maintenance is

conducted.

Only appropriately qualified personnel to access confined spaces after a thorough risk

assessment has been completed.

Ensure breathing apparatus and P.P.E. is used where required for confined space entry.

Ensure an appropriately qualified observer is present with appropriate training in emergency

response.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 10 of 39

Manifest and Emergency Plan.

Locate the red weatherproof manifest box immediately adjacent the entry to the site from

the direction of approach of the emergency vehicles.

Ensure the manifest for the site is reviewed at regular intervals.

Provide an emergency plan and ensure training of workers in its use. Records of this training

are maintained on site.

Ensure the Emergency Plan for the site is reviewed at regular intervals.

Security:

Provide CCTV monitoring of the console area.

Provide safe haven behind counter for physical protection.

Provide duress button behind counter and within safe haven.

Provide training to console operators to help recognise suspicious behaviour.

Provide "dead man" system at console.

Fire extinguishers are visible from the console or security camera.

Fire extinguishers to be located in highly visible locations within the viewing range of the

security cameras.

Fire extinguishers are installed in a well-lit area.

Ensure fire fighting equipment is tested regularly to Australian Standards.

LPG Exchange Bottle Cages:

Locate LPG exchange bottle cages in an area with good ventilation, away from ignition

sources, and where they are unlikely to be struck by vehicle.

Provide heavy duty bollards around LPG exchange bottle cages.

Perform a visual check on LPG exchange bottles at delivery to ensure that all have factory

seals on their valves, also check for LPG odours.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 11 of 39

5. Methodology

Risks associated with the hazards identified in this report have been rated using a

frequency/severity matrix illustrated below.

RISK LEVEL GUIDE: FREQUENCY

SEV

ER

ITY

V LOW → EXTREME

0-3 Low, risk level acceptable, no

action required.

V L

OW

1 2 3 4 5

4-6 Medium, requires monitoring, may

require minor remedial action. 2 4 6 8 10

7-10 High, requires action. ↓ 3 6 9 12 15

11 + Unacceptable, activity must stop,

immediate action required. EX

TREM

E

4 8 12 16 20

5 10 15 20 25

Risks have been grouped into one or more of the following risk categories:

1. People - The risk is to any person who may be on site whether they are employees,

maintenance personnel or the general public accessing the site.

2. Property - The risk is to assets of the owner, operator, supplier or any person accessing the

site for any reason.

3. Environment - The risk poses potential harm to the environment including potentially harmful

emissions to air, water or ground. Risks can be both catastrophic, and systemic.

The Risk Assessment process is designed to minimise risks to people, property, and the environment

by the implementation of the following steps as outlined in AS/NZS ISO 31000 - Risk Management -

Principles and guidelines.

Identify all hazards

- Assess all the risks with the use of the hierarchy of control measures of:

- Elimination

- Substitution

- Engineering Controls

- Administration Controls

- Personal Protection Equipment

Document, maintain and monitor the control measures implemented on a regular basis to

ensure associated risks are kept to a minimum.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification and Risk Assessment Report - Fuel Based Activities Page 12 of 39

6. Site Manifest

Tank/

Storage

No.

Type Description Capacity (litres) Average

Storage

(litres)

Type or category of

hazardous chemical

Equivalent

Dangerous Goods

Class/ Division/

Packaging Group

UN No. Hazchem

1/a Underground Automotive Ultimate Diesel

[Diesel]

50,000 47,500 Flammable Liquids

Category 4

C1 UN 3082 •3Z

1/b Underground Automotive Diesel

[Diesel]

40,000 38,000 Flammable Liquids

Category 4

C1 UN 3082 •3Z

1/c Underground AdBlue

[Diesel Exhaust Fluid]

20,000 19,000 N/A N/A N/A N/A

2/a Underground Automotive Ultimate Diesel

[Diesel]

60,000 57,500 Flammable Liquids

Category 4

C1 UN 3082 •3Z

2/b Underground Automotive Diesel

[Diesel]

50,000 47,500 Flammable Liquids

Category 4

C1 UN 3082 •3Z

3/a Underground Automotive Diesel

[Diesel]

60,000 57,500 Flammable Liquids

Category 4

C1 UN 3082 •3Z

3/b Underground Automotive Ultimate Diesel

[Diesel]

50,000 47,500 Flammable Liquids

Category 4

C1 UN 3082 •3Z

4/a Underground Premium Unleaded

Petrol(95 Octane)

40,000 38,000 Flammable Liquids

Category 2

3 PGII UN 1203 3[Y]E

4/b Underground Unleaded Petrol (91

Octane)

40,000 38,000 Flammable Liquids

Category 2

3 PGII UN 1203 3[Y]E

4/c Underground Ethanol Blended Unleaded

Petrol (E10)

30,000 28,500 Flammable Liquids

Category 2

3 PGII UN 1203 3[Y]E

5/a Underground Premium Unleaded

Petrol(98 Octane)

60,000 57,500 Flammable Liquids

Category 2

3 PGII UN 1203 3[Y]E

5/b Underground Automotive Ultimate Diesel

[Diesel]

50,000 47,500 Flammable Liquids

Category 4

C1 UN 3082 •3Z

6 Exchange bottle

cage (30 bottles)

Liquefied Petroleum Gas <528` <528 Flammable Gases

Category 1

2.1 UN 1075 2YE

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 13 of 39

7 Small Package

Store

Miscellaneous Automotive

Fluids

270 270 Flammable Liquids

Category 4

C2 Varies Varies

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 14 of 39

7. Hazard Identification and Risk Assessment

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Section 1 - Operation

1.1 Vehicle

movements on

site

Dispenser is struck Dispenser requires repair or

replacement.

Spilt fuel is ignited causing

injury or death and

destruction of property.

People in vehicle are injured.

Vehicle is damaged.

Product is spilt to the

environment.

Level 8.

People.

Property.

Environment.

Install bollards around

dispensers to provide

mechanical protection.

Provide line marking and

directional signage on the

forecourt.

Shear valves and flame

arrestors are to be provided

at the dispenser bases.

Install spill containment

catchment area that drains

to a treatment system where

the spillage is contained

and dealt with in line with

specifically formulated

emergency procedures.

Dispensers are physically

protected.

Intent for the correct use of site is

made obvious through signage.

Risk of spill and explosion is

minimised by the installation of

shear valves.

Risk of fuel spill is minimised

through collection of spills by the

treatment system.

Level 2-3.

People.

Property.

Environment.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 15 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Tanker parked on

site is struck

Rupture of tanker

compartment causing major

spill.

Spilt fuel is ignited causing

injury or death and

destruction of property.

Damage to tanker trailer

requiring repair.

People in vehicle are injured

or killed.

Level 10.

People.

Property.

Environment.

Lower speed limit on site to

10km/hour.

Implement strict tanker

unloading operation

controls.

Fuel tanker driver to place

traffic cones from fill point

area and tanker.

Place signage at crossovers

warning entering traffic of

the presence of the tanker.

Close off any refuelling

positions within 4m of the

fuel tanker unloading

position.

Locate fill point within the

compound catchment area

that drains to a treatment

system where the spillage is

contained and dealt with in

line with specifically

formulated emergency

procedures.

Low speed of traffic on site allows

collisions to be avoided, allows

people time to get out of the

way of moving vehicles and

minimises the effects of collisions.

Entering traffic has plenty of

warning that there is a tanker on

site.

Visual cues are in place directing

traffic away from the tanker

location.

The physical presence of the

tanker vehicle also provides a

deterrent to irresponsible vehicle

operation on site.

Appropriate procedures and

physical controls are in place to

enable major spills to be

managed as safely as possible.

Risk of fuel spill is minimised

through collection of spills by the

treatment system.

Level 4.

People.

Property.

Tanker driver is

struck

Tanker driver is injured or

killed.

Level 10.

People.

Lower speed limit on site to

10km/hour.

Provide suitable driver

training as to traffic

awareness and unloading

procedures.

Provide tanker drivers with

high visibility clothing.

Low speed of traffic on site allows

collisions to be avoided, allows

people time to get out of the

way of moving vehicles and

minimises the effects of collisions.

Driver is visible and traffic is aware

of driver’s presence.

Level 5.

People.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 16 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Tanker transfer

hose is struck

Transfer hose is ruptured

causing major spill.

Spilt fuel is ignited causing

injury or death and

destruction of property.

Transfer hose is damaged

requiring repair or

replacement.

Level 8.

People.

Property.

Environment.

Implement strict tanker

unloading operation

controls.

Access to tanker hardstand

is to be secured so no

vehicle is allowed during

fuel unloading.

Fuel tanker driver to place

traffic cones 4m from fill

point area and tanker.

Place signage at crossovers

warning entering traffic of

the presence of the tanker.

Close off any refuelling

positions within of the fuel

tanker unloading position.

Tanker driver to stand by to

monitor fuel transfer

operation.

Locate fill point within the

compound catchment area

that drains to a treatment

system where the spillage is

contained and dealt with in

line with specifically

formulated emergency

procedures.

Entering traffic has plenty of

warning that there is a tanker on

site.

Visual cues are in place directing

traffic away from the tanker

location.

The physical presence of the

tanker vehicle also provides a

deterrent to irresponsible vehicle

operation on site.

Tanker driver is positioned such

that he is protected and can

direct traffic away from

unloading area.

Appropriate procedures and

physical controls are in place to

enable major spills to be

managed as safely as possible.

Risk of fuel spill is minimised

through collection of spills by the

treatment system.

Level 4.

People.

Property.

Environment.

Person using the

site or their vehicle

is struck.

Person is injured or killed.

Damage to private property

on site.

Level 10.

People.

Property.

Limit speed on site to

10km/h.

Low speed of traffic on site allows

collisions to be avoided, allows

people time to get out of the

way of moving vehicles and

minimises the effects of collisions.

Level 2-3.

People.

Property

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 17 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

1.2 Use of dispensers Smoking at

dispenser

Vapour ignites causing injury

or death and damage to

property.

Level 12.

People.

Property.

Provide statutory signage at

dispensers forbidding

smoking on site.

Console operator to shut

down dispenser if someone

is smoking at dispenser.

Provide CCTV monitoring at

refuelling position.

People are made aware of the

danger regarding smoking on

site.

The situation is able to be

controlled by the console

operator by shutting down the

dispenser.

Risk eliminated if there is no

smoking on site.

Level 1.

People.

Property.

Use of mobile

phone or potential

source of flame at

dispenser

Vapour ignites causing injury

or death and damage to

property.

User is distracted from the

task of fuelling.

Level 8.

People.

Property.

Provide statutory

signage/highly visible

signage at dispensers

forbidding use of mobile

phones or other potential

source of flame such as pilot

lights, gas refrigerators and

other electrical device at

dispensers

Console operator to shut

down dispenser if someone

is using a mobile phone or

other electronic device at

dispenser.

Provide CCTV monitoring at

refuelling position.

People are made aware of the

danger regarding the use of

mobile phones and other

electronic devices at dispenser.

The situation is able to be

controlled by the console

operator by shutting down the

dispenser.

Risk eliminated if there is no use of

mobile phones and other

electronic devices on site.

Level 1.

People.

Property.

Filling of non-

compliant

container(s)

Hydrocarbons may dissolve

container causing spillage

and releasing vapour.

Hydrocarbons may react

with container causing fire.

Level 6.

People.

Property.

Provide statutory signage at

dispensers forbidding the

filling of non-compliant

containers.

Console operator to shut

down dispenser if someone

is attempting to fill non-

compliant containers.

People are made aware of the

danger regarding the filling of

non-compliant container(s).

The situation is able to be

controlled by the console

operator.

Level 3.

People.

Property.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 18 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Misuse of nozzle or

leaving dispenser

unsupervised while

discharging fuel

Spillage of fuel onto

forecourt or people causing

fire hazard and risk of injury.

Damage to nozzle requiring

repair or replacement.

Release of vapour leading to

fire hazard and risk of injury

and damage to property.

Hydrocarbons could find

their way into waterways

causing environmental harm.

Level 9.

People.

Property.

Environment.

Provide highly visible

warning signage and

instructions at the dispenser.

Console operator to monitor

forecourt and shut down

dispenser is not used

appropriately.

Install nozzles with safety cut

out attitude valve

Remove latching

mechanism from nozzle.

Provide signage stating that

the latch is not to be locked

open and left unattended.

Provide readily accessible

spill kit on site.

The situation is able to be

controlled by the console

operator.

Risk of fuel spill is minimised

through collection of spills by the

treatment system.

Appropriate procedures and

physical controls are in place to

enable major spills to be

managed as safely as possible.

Level 4.

People.

Property.

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Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 19 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Product spill onto

forecourt.

Slip hazard leading to risk of

injury.

Release of vapour leading to

fire hazard and risk of injury

and damage to property.

Hydrocarbons could find

their way into waterways

causing environmental harm.

Level 9.

People.

Property.

Environment.

Console operator to monitor

forecourt activity and

immediately clean up any

minor spill using the spill kit

readily accessible from the

dispenser.

If a major spill occurs,

operator to shut down site

and follow emergency

procedures.

Install a under canopy

catchment area that drains

to a treatment system where

the spillage is contained

and dealt with in line with

specifically formulated

emergency procedures.

Provide highly visible

warning signage and

instructions at the dispenser.

Any minor spills are contained

and removed quickly.

Risk of fuel spill is minimised

through collection of spills by the

treatment system.

Appropriate procedures and

physical controls are in place to

enable major spills to be

managed as safely as possible.

Level 6.

People.

Property.

Environment.

Drive-off fuel theft Loss of income. Level 8.

Property.

Console operator to monitor

forecourt activity for ‘drive

offs’.

Installation of CCTV

monitoring of refuelling

positions to capture ‘drive

offs’/theft.

If a ‘drive off ‘occurs the number

plate of the vehicle is recorded

and is likely to be witnessed.

Incident is recorded and

offenders are identified.

Level 4.

Property.

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Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 20 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

1.3 Tanker

unloading

Minor fuel spill (up

to 20l.)

Vapour from spill could ignite

causing injury or damage to

property.

Hydrocarbons could find

their way into stormwater

system and waterways

causing environmental harm.

Level 6.

People.

Property.

Environment.

Provide an emergency spill

kit on site that is readily

accessible from the

dispensers. Provide training

on its use to site staff and

tanker drivers.

Fill points are to be located

within a spill safe fill box

draining back into the fuel

system.

Appropriate procedures and

physical controls are in place to

enable minor spills to be

managed as safely as possible.

Level 3.

People.

Property.

Environment.

Major fuel spill

(over 20l.)

Vapour from spill could ignite

causing injury or damage to

property.

Hydrocarbons could find

their way into stormwater

system causing a potential

explosive atmosphere within

pipework.

Hydrocarbons could find

their way into waterways

causing environmental harm.

Level 10.

People.

Property.

Environment.

Provide an emergency plan

and ensure training of

workers in its use.

Console operator to shut

down site and proceed with

emergency plan, evacuate

if necessary.

Ensure all fill points are

installed within the

catchment area that drains

to a treatment system.

Spillage is contained and

dealt with in line with

specifically formulated

emergency procedures.

Appropriate procedures and

physical controls are in place to

enable major spills to be

managed as safely as possible.

Level 5.

People.

Property.

Environment.

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No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Incorrect product

introduced into

storage tank

Possible damage to private

property caused by use of

incorrect fuel.

Level 6.

Property.

Ensure tanker drivers are

trained in site-specific

conditions.

Fill points are clearly marked

to Australian Standards.

Provide tanker driver with

correct, up to date fill point

sketch.

Any discrepancy between

the fill point markers and the

fill point sketch to be notified

and fuel transfer is not to

proceed.

Tanker driver can clearly see the

product arrangement and has

the ability to cross check the fill

point arrangement.

Level 3.

Property

Storage tank is

overfilled

Potential fuel spillage

causing risk of ignition or

harm to the environment.

Lack of ullage space may

cause storage tank to

rupture due to thermal

expansion of hydrocarbon.

Level 9.

Property.

Environment.

Ensure product

reconciliation is performed

daily.

Provide accurately

calibrated tank dips or auto

tank gauging.

Tanker driver to confirm

product volumes prior to

performing a fuel transfer.

Provide overfill protection

within the tanks.

Overfilling of the tanks becomes

very difficult.

Level 3.

Property.

Environment.

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No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

1.4 Console

operation

Robbery Physical and psychological

harm to the console

operator.

Loss of income.

Level 12.

People.

Property.

Provide CCTV monitoring of

the console area.

Provide safe haven behind

counter for physical

protection.

Provide duress button

behind counter and within

safe haven.

Provide training to console

operators to help recognise

suspicious behaviour.

Console operator has the means

to protect their self.

Level of security has a deterrent

effect.

Level 8.

People.

Property.

Operator is

incapacitated

during lone shift

Operator may be unable to

access emergency medical

help.

Potential for theft if there is

no one visibly on duty.

Level 8.

People.

Property.

Provide "dead man" system

at console.

In the case of incapacitation,

emergency services are notified

automatically, although the time

lapse still represents a risk.

Level 4.

People.

Property.

1.5 Maintenance

access to

dispensers

Maintenance

person being struck

by vehicle

Maintenance person could

be injured or killed.

Level 12.

People.

Ensure maintenance

personnel use traffic cones

and signage to barricade

off dispenser.

Ensure maintenance

personnel use high visibility

clothing while on site.

Ensure an appropriately

qualified observer is present

with appropriate training in

emergency response.

Ensure appropriate work

permits are obtained.

The work area and personnel are

highly visible to any traffic on site.

Level 4.

People.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

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No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Electrocution Maintenance person could

be injured or killed.

Equipment is damaged.

Level 12.

People.

Property.

Ensure any electrical work

done on dispensers is

performed by maintenance

personnel with suitable

qualifications and training.

Ensure appropriate work

permits are obtained.

Risks to maintenance personnel

and equipment are minimised

through the use of correctly

trained personnel and safe work

procedures.

Level 3.

People.

Property.

Exposure to

explosive

atmosphere within

dispenser housing

Maintenance person could

be injured or killed.

Possible damage to

property.

Level 16.

People.

Property.

Ensure area around the

dispensers is adequately

ventilated and that there

are no vehicles parked

close by during

maintenance.

Ensure all potential ignition

sources are excluded from

the area.

Ensure appropriate work

permits are obtained.

Vapours are being dispersed.

The potential for ignition is greatly

reduced.

Level 6.

People.

Property.

1.6 Maintenance

entry into tanks

Exposure to

explosive

atmosphere

Maintenance person could

be injured or killed.

Possible damage to

property.

Level 10.

People.

Property.

Only appropriately qualified

personnel to access

confined spaces.

Ensure appropriate entry

and work permits are

obtained.

Ensure all safety clothing

and breathing apparatus

are used.

Ensure an appropriately

qualified observer is present

with appropriate training in

emergency response.

Risks to personnel are minimised

through the use of correctly

trained personnel and safe work

procedures.

Level 4.

People.

Property.

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No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Inhalation of

vapour

Could result in various health

problems relating to

respiration and central

nervous system, potential for

fatality.

Level 10.

People.

Ensure breathing apparatus

is used.

Ensure an appropriately

qualified observer is present

with appropriate training in

emergency response.

Risks to personnel are minimised

through the use of appropriate

safety equipment and safe work

practices.

Level 4.

People.

Maintenance

person being struck

by vehicle

Maintenance person could

be injured or killed.

Level 12.

People.

Ensure maintenance

personnel use traffic cones

and signage to barricade

off dispenser.

Ensure maintenance

personnel use high visibility

clothing while on site.

Ensure an appropriately

qualified observer is present

with appropriate training in

emergency response.

Ensure appropriate work

permits are obtained.

The work area and personnel are

highly visible to any traffic on site.

Level 4.

People.

1.7 Customer safety Customer being

struck by tanker or

other vehicle

Customer could be injured or

killed

Level 12.

People.

Clearly identify entry to shop

with pedestrian line marking.

Limit speed on site to

10km/h.

Keep area clear of trip

hazards and unnecessary

items.

Provide CCTV monitoring at

forecourt.

Customer is visible and traffic is

aware.

Low speed of traffic on site allows

collisions to be avoided, allows

people time to get out of the

way of moving vehicles and

minimises the effects of collisions.

Activity at the forecourt is

monitored and the console

operator is made aware of

potential danger.

Level 5.

People.

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No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

1.8

Manual Car

Wash

Chemical Handling

Eye & Skin irritation caused

by exposure from cleaning

chemicals

Level 6.

People

Eye wash available

Gloves available if required

(must be used for sensitive

skin)

Employees to be trained to

used equipment safely

Risk minimised by employee

training.

PPE available to minimise

exposure.

Eyewash can be administered to

avoid injury.

Level 4

People.

High pressure hose Injury to employees

Damage to Cars by loss of

pressure hose control

Level 6.

People

Property

Employees to be trained to

used equipment safely

Eye protection must be worn

Risk minimised by employee

training.

PPE available to minimise

exposure.

Level 4

People.

Property

Wet Surfaces Slips/Trips

Personal Injury

Level 8.

People

Slip resistant surfaces

(coarse broom finished

concrete).

Signage to restrict public

access.

Appropriate Safety

footwear.

Mechanical Sweep and

Scrub

Insure floors are well drained

to avoid water pooling

Work surface minimised to

reduce slipping.

Public access restricted.

PPE required.

Area clean of hazards by

mechanical sweeping to

minimise incidents.

Level 3.

People

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 26 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Electrocution Employee could be injured

or killed.

Equipment is damaged.

Level 12.

People.

Property.

Circuit RCD protected.

Equipment is serviced every

six months.

Safety training to employees

on how to operate

electrical equipment.

Minimise water where

electrical connections are

by means of safety

procedures

Risks to maintenance personnel

and equipment are minimised

through the use of correctly

trained personnel and safe work

procedures.

Level 3.

People.

Property

Vehicle Damage to vehicles driving

thru carwash

Damage to

buildings/surrounds from

vehicles

People being injured from

vehicles.

Level 9.

People.

Property

Speed limits in place.

Signage to restrict non-

employers from driving in &

to restrict pedestrian access.

Install speed bumps.

Install bollards.

Limited to employers only by use

of signage.

Speed bumps and limits enforced

to reduce speeds to harmful

accidents occurring.

Bollards in place to protect

surrounding buildings.

Level 3.

People.

Property

Section 2 – The Installation

2.1

Concrete

forecourt

Slippery surfaces

due to spillage

Possible slip and fall causing

injury.

Vehicle accessing the site

could lose control causing

possible injury to persons on

site or damage to property.

Level 8.

People.

Property.

Spill kits are provided on site

and are readily accessible

from the dispensers.

Ensure all staff is trained in

spill response.

Forecourt surfaces to be

designed to be slip resistant.

The time between a spill and

clean-up is minimised.

Surface provides as much grip as

possible.

Level 4.

People.

Property.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

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No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Trip hazard at kerbs Possible trip and fall causing

injury.

Level 8.

People.

Kerbs in paths of travel to be

painted in high visibility

colour (yellow).

Install indicators to Australian

Standards.

Minimise use of kerbs in

areas commonly used by

pedestrians.

Trip hazards are visible and their

number is minimised.

Level 3.

People.

2.2 Underground

fuel tanks and

pipework

Structural failure of

tanks and/or

pipework

Possibility of hydrocarbon

being spilt to ground causing

environmental harm.

Level 8.

Property.

Environment.

The liquid fuel tanks are

made from non-corrosive

materials.

Auto tank gauging and line

leak detection is to be

provided to tanks and

pipework.

Provide product

reconciliation procedures

(auto tank gauging, manual

dip).

Check tank excavation

observation wells regularly.

Should failure occur checks are in

place for product reconciliation,

leak detections, and the

surrounding area is being

monitored to minimise harm.

Level 3.

Property.

Environment.

2.3

Fire extinguishers

Misuse of

equipment

May cause extinguisher to

fail or run out during

emergency.

Fire extinguisher discharge

would require clean up.

Fire extinguisher would

require recharging.

Level 6.

Property.

Fire extinguishers are visible

from the console or security

camera.

Fire extinguishers are

installed in a well-lit area.

Fire extinguishers can be

monitored.

Location in well-lit area acts as a

deterrent to potential misuse.

Location where visible increases

likelihood of any misuse being

witnessed.

Level 4.

Property.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

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No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Theft of equipment Fire fighting equipment may

be unavailable during an

emergency.

Cost of replacing fire

extinguisher.

Level 6.

Property.

Fire extinguishers are visible

from the console or security

camera.

Fire extinguishers are

installed in a well-lit area.

Fire extinguishers can be

monitored.

Location in well-lit area acts as a

deterrent to potential theft.

Location where visible increases

likelihood of any theft being

witnessed.

Level 3.

Property.

Failure of

equipment

Personnel unable to respond

to a fire emergency causing

damage to property and

possible injury or death.

Level 8.

People.

Property.

Ensure fire fighting

equipment is tested

regularly to Australian

Standards.

If fire extinguishers are required

their correct operation is ensured.

Level 2.

Property.

Vandalism Fire extinguisher could fail

during emergency.

Level 6.

Property.

Fire extinguishers are visible

from the console or security

camera.

Fire extinguishers are

installed in a well-lit area.

Fire extinguishers can be

monitored.

Location in well-lit area acts as a

deterrent to potential vandals.

Location where visible increases

likelihood of any vandalism being

witnessed.

Level 3.

Property.

2.4

Tank vents

Vents being struck

by vehicle

Could result in injury and

damage to property.

Level 6.

People.

Property.

Vents are installed in a

protected area away from

vehicles in a landscaping

area of the site.

Install bollards around vents

to provide mechanical

protection.

It is very unlikely that the vents will

be struck.

Level 2.

Property.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 29 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

Vapour igniting Could result in injury and

damage to property.

Level 8.

People.

Property.

Vents are installed away

from any potential ignition

source.

Vents are installed to

appropriate Australian

Standards.

Provide signage near the

vents forbidding smoking on

site.

Risk of ignition is minimal. Level 2.

Property.

Inhalation of

vapour

Vapour inhalation can result

in headaches, dizziness,

weakness, nausea, blurred

vision, shortness of breath

and effects to central

nervous system. Refer to

material safety data sheets.

Level 10.

People.

Vents are installed to

appropriate Australian

Standards.

Vents are installed in a well-

ventilated location.

The likelihood of vapour

inhalation is minimal.

Level 2.

People.

2.5 LPG exchange

bottle cages

LPG exchange

bottle cages being

struck by vehicle

Could result in explosion,

injury and damage to

property.

Level 10.

People.

Property.

Locate LPG exchange

bottles in an area unlikely to

be struck by vehicle.

Install bollards around LPG

exchange bottle cage and

cylinders to provide

mechanical protection.

The likelihood of LPG exchange

bottle cage and cylinders being

struck is minimal.

Level 3.

People.

Property.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 30 of 39

No Hazard Risks Consequences Risk Level

and Type

Action Re-assessment of Consequences Revised Risk

Level

LPG exchange

bottle leaking

Could result in explosion,

injury and damage to

property.

Level 10.

People.

Property.

LPG exchange bottles are

located in an area with

good ventilation.

LPG exchange bottles are

located away from ignition

sources.

Ensure statutory signage on

the LPG exchange bottle

cage forbidding smoking.

Perform a visual check on

LPG exchange bottles at

delivery to ensure that all

have factory seals on their

valves, also check for LPG

odours.

Good ventilation reduces the risk

of leaking gas pooling.

The likelihood of leaking LPG

exchange bottles being ignited is

reduced.

Level 3.

People.

Property.

2.6 Site Manifest An emergency

situation could

occur requiring

information of site

specific hazards.

Emergency services unable

to access site specific

information for the

hazardous chemical storage

in the event of an

emergency.

Level 8.

People.

Property.

Locate the red

weatherproof manifest box

immediately adjacent the

entry to the site from the

direction of approach of the

emergency vehicles.

Ensure the manifest for the

site is reviewed at regular

intervals.

The manifest is easy to find and

accessible.

The manifest is up to date with

product types and volumes

stored on site.

Level 3.

People.

Property.

2.7 Emergency Plan An emergency

situation could

occur requiring a

site specific

response.

Workers are unaware of

emergency response

procedures.

Level 8.

People.

Property.

Ensure the Emergency Plan

for the site is reviewed at

regular intervals.

Ensure workers on site are

trained in the Emergency

Plan and records of this

training are maintained on

site.

In the event of an incident,

workers know what procedures

are in place and how to respond

to minimise the effects of the

incident.

Level 3.

People.

Property.

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 31 of 39

8. SEPP 33 Preliminary screening

Refer to SEPP 33 Preliminary screening report attached

Level 4 66 Clarence Street Sydney NSW Australia 2000 www.meinhardtgroup.com Tel: 61 (02) 9699 3088 Fax: 61 (02) 9319 7508

Introduction

This letter report sets out the results of the SEPP33 preliminary screening on the proposed service station

development at 6 Honeman Close, Huntingwood, NSW.

The Hazardous and Offensive Development Application Guidelines - Applying SEPP 33 (January 2011)

NSW Dept. of Planning (the guidelines) provides a risk screening method to assist in determining whether

a proposed development is potentially hazardous and thus determine whether SEPP 33 applies.

For development proposals classified as ‘potentially hazardous industry’ the policy establishes a

comprehensive test by way of a preliminary hazard analysis (PHA) to determine the risk to people,

property and the environment at the proposed location and in the presence of controls. SEPP 33 applies

to any proposals which fall under the policy’s definition of ‘potentially hazardous industry’ or ‘potentially

offensive industry’.

Hazard Identification – Preliminary Screening

To determine if a proposed facility is potentially hazardous a number of steps are followed using the risk

screening method given in the guideline.

The steps include;

o collate information;

o identify hazardous materials and the type of hazard;

o group and total by class, activity and location;

o compare with screening threshold;

o consider transportation issues; and

o determine whether SEPP 33 applies

A preliminary screen of the proposed development has found that the proposed service station

development at 6 Honeman Close, Huntingwood, NSW is “not potentially hazardous” as defined under

SEPP33.

29 May 2017

SEPP33 Preliminary Screen ; Project No. 117878 Proposed BP Service Station Development; 6 Honeman Close, Huntingwood, NSW (11034 SK009, Issue D 17/05/2017).

117878 - l01 - huntingwood sepp33 2

Assessment of Data. Table 1 displays hazardous materials to be stored on-site and quantities. Table 1: Material quantities and classifications.

Tank Material Classification Quantity

Mode of storage Volume (kL) Mass (tonnes)

T1a Diesel 3PGII 50 42# Underground tank

T1b Diesel 3PGII 40 34# Underground tank

T1c AdBlue - 20 - Underground tank

T2a Diesel 3PGII 60 50# Underground tank

T2b Diesel 3PGII 50 42# Underground tank

T3a Diesel 3PGII 60 50# Underground tank

T3b Diesel 3PGII 50 42# Underground tank

T4a ULP95 3PGIII 40 30* Underground tank

T4b ULP91 3PGIII 40 30* Underground tank

T4c E10 3PGIII 30 22* Underground tank

T5a ULP95 3PGIII 60 44* Underground tank

T5b Diesel 3PGII 50 42# Underground tank

# Specific gravity used was 0.84. *Specific gravity used was 0.737 As petrol and diesel belong to Class 3 Flammable liquids stored in the same general location, the

quantities are normally assessed as a whole. In this instance, since each tank compartment has

separate isolation valve the quantities can be treated separately. The greatest mass of fuel is

stored in tank compartments T2a and T3a and since each compartment has an isolation valve, the

screen will be conducted using the mass of diesel found in compartment T2a. As the diesel is to be

stored underground, the total mass is divided by 5 and multiplied by 0.95 to reflect 95% safe filling

limit ((50/5)0.95 = 9.5 Tonnes) for screening purposes.

The critical locations within the service station in terms of screening for diesel and petrol are the

location of the dispenser/pump positions and the tank fill points with respect to the site boundary.

The shortest distance to a site boundary is 20m between a fuel dispenser (diesel) and the

boundary (southern side). The fill point is approximately 40m from the closest boundary (southern

side). Undeveloped bushland adjoins on the southern and western boundaries. Reservoir Road

adjoins the eastern boundary and The Great Western Highway the northern boundary. Commercial

properties are located to the east beyond Reservoir Road and to the north beyond The Great

Western Highway.

The guidelines specify that for class 3PGII and 3PGIII chemicals (e.g. petrol and diesel), Figure 9

in the guidelines is to be used for screening purposes (Dept. Planning 1993).

Considering a total effective mass of 9.5 tonnes and a minimum distance of 20m from the adjoining

property, the proposal is not considered potentially hazardous for surrounding sensitive or

commercial uses.

117878 - l01 - huntingwood sepp33 3

Finally in consideration of the transportation issues, the number of vehicle movements were

considered against the transportation screening thresholds (Table 2 in the guidelines). The

expected deliveries of 3 per week are below the number required to trigger SEPP33.

Conclusions

A preliminary SEPP33 screen was carried out to assess the proposed service station development

at 6 Honeman Close, Huntingwood, NSW. The proposed service station was found to be non

hazardous for surrounding residential and commercial industrial uses as defined under SEPP33.

As the service station is bounded by roads to the north and east and the nearest adjoining property

to the diesel tank fill points and fuel dispensers is at least 20 m, the proposed service station is

considered non-hazardous and so will not be subject to SEPP33.

Should you have any queries regarding this report, please contact undersigned on

(02) 8252 0442.

Regards,

Meinhardt Infrastructure & Environment Pty Ltd

Dr. Santo Ragusa

Senior Associate Environment

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification and Risk Assessment Report - Fuel Based Activities Page 32 of 39

9. Appendix A - Legislation

The design, construction, operation and supply of Hazardous Chemicals to service stations in New

South Wales shall comply with, but not be limited to, the latest edition of the following legislation,

regulations, standards and codes.

New South Wales Occupational Health and Safety Regulation 2000

New South Wales Occupational Health and Safety Amendment (Dangerous Goods) Act

2003

New South Wales EPA – Protection of the Environment Operations Act

Australian Dangerous Goods Code 7th edition.

National Construction Code.

AS1692-2006 Tanks for flammable and combustible liquids.

AS1940-2004 The storage and handling of flammable and combustible liquids.

AS4897-2008 Design Installation and Operation of Underground Petroleum Storage Systems.

AS4977-2008 Petroleum Products - Pipeline, road tanker compartment and underground

tank identification.

AS/NZS60079.10.1-2009 Explosive atmospheres - Classification of areas - Explosive gas

atmospheres (IEC 60079-10-1, Ed.1.0(2008) MOD).

AS/NZS1841.5-2007 Portable fire extinguishers - Specific requirements for powder type

extinguishers.

AS2444-2001 Portable Fire Extinguishers and fire blankets

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 33 of 39

10. Appendix B - Proposed Site Plan

Refer to Proposed Site plan drawings attached

ISSUE

D FOR

scale

date

drawn

checked

job no.

dwg no.

issue

project description

drawing title

client

acn: 111 372 064 abn: 43 111 372 064

project address

DO NOT SCALE

Membership No. 563QBCC Lic. No. 1272165

COPYRIGHT © 2016

building designers'association of

queensland inc.

FULL SIZE @ A1

DEVE

LOPM

ENT A

PPRO

VAL

Studio 24/115 Wickham Street,PO Box 724,Fortitude Valley, QLD 4006T: 1800 616 760E: [email protected]: www.cadway.com.au

@ A1

9/06/2017 12:34:43 PM

C:\Users\jcroft\Documents\[email protected]

B

BP HUNTINGWOODSERVICE STATION

GREAT WESTERN HIGHWAY,HUNTINGWOOD,NSW, 2148

JOHN AND ANNAARCIDIACONO

PERSPECTIVES - SHEET 1

05/24/17

AC

JC

11034

11034 SK018

ISS

DATE

AMEN

DMEN

TCK

DA

02.06

.17IS

SUE

FOR

DA A

PPRO

VAL

JCB

09.06

.17IS

SUE

FOR

CLIE

NT A

PPRO

VAL

JC

@ A12 SERVICE STATION SITE ENTRY PERSPECTIVE

@ A11

INTERSECTION RESERVOIR ROAD AND GREAT WESTERN HIGHWAYPERSPECTIVE

CAR

CANO

PYSERVICESTATION

TRUC

K CA

NOPY

CAR WASH

ENTR

Y

475m²

MIDSIGN

CAR PARK(7)

136° 21' 00"29.64 m

112° 35' 15"121.52 m

BIN

STOR

E/PL

ANT

AREA

DUAL FILLPOINT

5x110KL TANK FARM

CAR

PARK

(11)

LANDSCAPING

FUEL VENTS

LANDSCAPING

DELIV

ERY

(REF

ER D

RAW

ING

1103

4-SK

014)

(REF

ER D

RAW

ING

1103

4-SK

014)

LINE OF ESTIMATED RMS ROAD RESUMPTION (TO BE CONFIRMED WITH RMS)

(REFER DRAWING11034-SK013)(REFER DRAWING 11034-SK014)

PROP

OSED

BOU

NDAR

Y

WEIGHBRIDGE

LANDSCAPING

LANDSCAPING

MID SIGN

SERVICE STATION ENTRY

SERVICE STATIONTRUCK EGRESS

SERVICE STATION CAR

ENTRY/EGRESS

AIR/WATER

PROPOSED BOUNDARY

CAR PARK(9)

SIGN

ISSUE

D FOR

scale

date

drawn

checked

job no.

dwg no.

issue

project description

drawing title

client

acn: 111 372 064 abn: 43 111 372 064

project address

DO NOT SCALE

Membership No. 563QBCC Lic. No. 1272165

COPYRIGHT © 2016

building designers'association of

queensland inc.

FULL SIZE @ A1

DEVE

LOPM

ENT A

PPRO

VAL

Studio 24/115 Wickham Street,PO Box 724,Fortitude Valley, QLD 4006T: 1800 616 760E: [email protected]: www.cadway.com.au

1 : 200 @ A1

9/06/2017 12:40:35 PM

C:\Users\jcroft\Documents\[email protected]

C

BP HUNTINGWOODSERVICE STATION

GREAT WESTERN HIGHWAY,HUNTINGWOOD,NSW, 2148

JOHN AND ANNAARCIDIACONO

STAGE 1 SITE PLAN

05/24/17

AC

JC

11034

11034 SK012 1 : 200 @ A11 CONCEPT MASTER PLAN

0 10m 20m1:200

ISS

DATE

AMEN

DMEN

TCK

DA

02.06

.17IS

SUE

FOR

DA A

PPRO

VAL

JCB

06.06

.17FL

OOR

PLAN

DET

AILS

JCC

09.06

.17IS

SUE

FOR

CLIE

NT A

PPRO

VAL

JC

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 34 of 39

11. Appendix C - Safety Data Sheets

Refer to Company Safety Data sheets attached

Material Safety Data Sheet

1 . Identification of the material and supplier

AdBlueProduct name

0000003947SDS no.

Product use Reactant for reducing NOx-emissions.

BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616

Technical Helpline Number: 1300 139 700www.bp.com.au

Supplier

1800 638 556EMERGENCY TELEPHONE NUMBER

Product code 0000003947

Hazards identification2 .

NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.Statement of hazardous/dangerous nature

Composition/information on ingredients3 .

Water and Urea (31.8 - 33.2%)

This product does not contain any hazardous ingredients at or above regulated thresholds.

Skin contact

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses.Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation develops.

4 .

If inhaled, remove to fresh air. Get medical attention if symptoms appear. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Inhalation

Eye contact

First-aid measures

Ingestion Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.

Advice to doctor Treatment should in general be symptomatic and directed to relieving any effects.

Fire-fighting measures5 .

No action shall be taken involving any personal risk or without suitable training. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.

Special fire-fighting procedures

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Protection of fire-fighters

Unusual fire/explosion hazards

In a fire or if heated, a pressure increase will occur and the container may burst.

Hazardous decomposition products

Combustion products may include the following: carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)nitrogen oxides

Extinguishing media

Suitable In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.

Do not use water jet.Not suitable

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(ENGLISH)(Australia)

6 . Accidental release measures

Environmental precautions

Personal precautions

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses,basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Put on appropriate personal protective equipment (see Section 8).

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,soil or air).

Large spill

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Handling

Handling and storage

Storage

7 .

Put on appropriate personal protective equipment.

Store and use only in equipment/containers designed for use with this product. Keep away from heat and direct sunlight. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Store in accordance with local regulations. Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10).

Not suitable Prolonged exposure to elevated temperature.

8 . Exposure controls/personal protection

Occupational exposure limits No exposure standard allocated.

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits.

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.

The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Occupational exposure controls

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Biological Limit Values No biological limit allocated.

Personal protective equipment

Respiratory protective equipment is not normally required where there is adequate natural or local exhaust ventilation to control exposure.In case of insufficient ventilation, wear suitable respiratory equipment.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Respiratory protection

Use of protective clothing is good industrial practice.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.

Skin and body

Wear protective gloves if prolonged or repeated contact is likely.

The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Hand protection

Safety glasses with side shields.Eye protection

Exposure controls

Date of issue 16 September 2013

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Version 1 Format LanguageAustralia

0000003947

ENGLISH

(ENGLISH)(Australia)

Physical and chemical properties9 .

Colour Clear. Colourless.

Physical state Liquid.

Odour Ammoniacal. [Slight]

Not available.Boiling point / range

Not available.Melting point / range

1094 kg/m³ (1.094 g/cm³) at 20°CDensity

Vapour density Not available.

Not available.Vapour pressure

Solubility Soluble in water.

<1Partition coefficient (LogKow)

pH 9.5

Relative density/Specific gravity

Not available.

Stability and reactivity10 .

The product is stable.Stability

Conditions to avoid Avoid contamination by any source including metals, dust and organic materials.

Incompatibility with various substances/Hazardous Reactions

No hazardous reactions identified.

Combustion products may include the following: carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)nitrogen oxides

Hazardous decomposition products

Toxicological information11 .Eyes No significant health hazards identified.

No significant health hazards identified.Skin

Inhalation No significant health hazards identified.

Ingestion of large quantities may cause nausea and diarrhoea.Ingestion

Other chronic toxicity data Overexposure to the inhalation of airborne droplets or aerosols may cause irritation of the respiratory tract.

Mutagenic effects No known significant effects or critical hazards.

No component of this product at levels greater than or equal to 0.1% is identified as a carcinogen by ACGIH, the International Agency for Research on Cancer (IARC), the European Commission (EC),or the National Occupational Health and Safety Commission (Australia).

Carcinogenic effects

Acute toxicity Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.

Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to dermatitis.

Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.

At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its low volatility. May be harmful by inhalation if exposure to vapour, mists or fumes resulting from thermal decomposition products occurs.

Chronic toxicity

Ecological information

Ecotoxicity

12 .

Not classified as environmentally hazardous in accordance with the ‘Approved Criteria for Classifying Hazardous Substances’ [NOHSC (1008)/2004 as amended and adapted].

LogPow BCF Potential

Bioaccumulative potential

Product/ingredient nameAdBlue <1 - low

Biodegradability

Persistence/degradability Expected to be biodegradable.

Mobility

Bioaccumulative potential

Soluble in water.

This product is not expected to bioaccumulate through food chains in the environment.

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ENGLISH

(ENGLISH)(Australia)

Disposal considerations13 .

The generation of waste should be avoided or minimised wherever possible. Disposal of this product,solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way.Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal considerations /Waste information

No additional special precautions identified.Special Precautions for Landfill or Incineration

14 . Transport information

International transport regulations

Not classified as dangerous for transport (ADG, IMDG, ICAO/IATA).

No known special precautions required. See Section: "Handling and storage" for additional information.

Special precautions for user

Regulatory information15 .Standard Uniform Schedule of Medicine and Poisons

Not regulated.

ScheduleNo Listed Substance

Other regulations

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

Ingredient name

Control of Scheduled Carcinogenic Substances

Australia inventory (AICS)

Canada inventory

China inventory (IECSC)

Japan inventory (ENCS)

Korea inventory (KECI)

Philippines inventory (PICCS)

United States inventory (TSCA 8b)

REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.

Other information16 .

AMP = Acceptable Maximum PeakACGIH = American Conference of Governmental Industrial Hygienists, an agency that promulgates exposure standards.ADG = Australian Code for the Transport of Dangerous Goods by Road and RailADG Code = Australian Code for the Transport of Dangerous Goods by Road and RailCAS Number = Chemical Abstracts Service Registry NumberHAZCHEM Code = Emergency action code of numbers and letters which gives information to emergency services. Its use is required by the ADG Code for Dangerous Goods in bulk.ICAO = International Civil Aviation Organization.IATA = International Air Transport Association, the organization promulgating rules governing shipment of goods by air.IMDG = International Maritime Organization Rules, rules governing shipment of goods by water.IP 346 = A chemical screening assay for dermal toxicity. The European Commission has recommended that Method IP 346 be used as the basis for labelling certain lubricant oil base stocks for carcinogenicity. The EU Commission has stipulated that the classification as a carcinogen need not apply if it can be shown that the substance contains less than 3% DMSO extract as measured by IP 346. (See Note L, European Commission Directive 67/548/EEC as amended and adapted.)DMSO is a solvent.NOHSC = National Occupational Health & Safety Commission, AustraliaTWA = Time weighted averageSTEL = Short term exposure limitUN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods.

Key to abbreviations

History

Date of issue

Date of previous issue

Prepared by Product Stewardship

Notice to reader

16/09/2013.

No previous validation.

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(ENGLISH)(Australia)

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from us.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken.

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Ultimate 98 petrol

SAFETY DATA SHEET

GHS product identifier

Section 1. Identification

Ultimate 98 petrol

Manufacturer

Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616

www.bp.com.au

Technical Helpline Number: 1300 139 700

1800 638 556EMERGENCY TELEPHONE NUMBER

Fuel for spark ignition engines. NOT for aviation use.For specific application advice see appropriate Technical Data Sheet or consult our company representative.

Use of the substance/mixture

0000002791Product code

0000002791SDS no.

Relevant identified uses of the substance or mixture and uses advised against

Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 1SKIN CORROSION/IRRITATION - Category 2GERM CELL MUTAGENICITY - Category 1BCARCINOGENICITY - Category 1BTOXIC TO REPRODUCTION (Fertility) - Category 2TOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word DANGER

Hazard statements H224 - Extremely flammable liquid and vapour.H315 - Causes skin irritation.H340 - May cause genetic defects.H350 - May cause cancer.H361 - Suspected of damaging fertility or the unborn child.H304 - May be fatal if swallowed and enters airways.H336 - May cause drowsiness or dizziness.

Hazard pictograms

Precautionary statements

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1%

General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.

Product name

Date of issue

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ENGLISH

(ENGLISH)

Product code

Version 1 Format LanguageAustralia

0000002791

(Australia)

09/11/2016

Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.

P261 - Avoid breathing vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothingP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P240 - Ground/bond container and receiving equipment.P273 - Avoid release to the environment.

Response P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.

Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.P235 - Keep cool.P405 - Store locked up.

Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.

Other hazards which do not result in classification

Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including leukaemia.

Supplemental label elements

Not applicable.

Section 3. Composition and ingredient information

Gasoline > 99 86290-81-5Contains:toluene < 20 108-88-3n-hexane < 5 110-54-3Benzene < 1 71-43-2tert-butyl methyl ether(MTBE) < 1 1634-04-42-methylpropan-2-ol < 1 75-65-0diisopropyl ether < 1 108-20-3Polycyclic aromatic hydrocarbons (PAHs) < 1 mixture

Ingredient name CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

% (w/w)

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.

If inhaled, remove to fresh air. Get medical attention.

If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.

Section 4. First aid measures

Eye contact

Inhalation

Description of necessary first aid measures

Product name

Date of issue

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ENGLISH

(ENGLISH)

Product code

Version 1 Format LanguageAustralia

0000002791

(Australia)

09/11/2016

Section 4. First aid measures

Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.

Skin contact

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Specific treatments No specific treatment.

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

See Section 11 for more detailed information on health effects and symptoms.

Section 5. Firefighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.

Extremely flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.

Special protective equipment for fire-fighters

In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Hazchem code 3YE

Product name

Date of issue

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ENGLISH

(ENGLISH)

Product code

Version 1 Format LanguageAustralia

0000002791

(Australia)

09/11/2016

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.

Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment. Collect spilled product by absorbing with specific floating absorbents. If possible, large spillages in open waters should be contained with floating barriers or other mechanical means.If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.

Large spill

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.

Small spill

Methods and material for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Protective measures Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container.

Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Store and use away from heat, sparks, open flame

Precautions for safe handling

Product name

Date of issue

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ENGLISH

(ENGLISH)

Product code

Version 1 Format LanguageAustralia

0000002791

(Australia)

09/11/2016

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.

or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid exposure during pregnancy. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage.Never siphon by mouth.

Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hours. Issued/Revised:5/1996 TWA: 890 mg/m³ 8 hours. Issued/Revised:5/1996 STEL: 500 ppm 15 minutes. Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minutes. Issued/Revised: 5/1996

toluene Safe Work Australia (Australia). Absorbed through skin.

Section 8. Exposure controls and personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits

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Section 8. Exposure controls and personal protection STEL: 574 mg/m³ 15 minutes. Issued/Revised: 8/2005 STEL: 150 ppm 15 minutes. Issued/Revised: 8/2005 TWA: 191 mg/m³ 8 hours. Issued/Revised:8/2005 TWA: 50 ppm 8 hours. Issued/Revised:8/2005

n-hexane Safe Work Australia (Australia). TWA: 72 mg/m³ 8 hours. Issued/Revised:11/2001 TWA: 20 ppm 8 hours. Issued/Revised:11/2001

Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hours.

Benzene Safe Work Australia (Australia). TWA: 3.2 mg/m³ 8 hours. Issued/Revised:4/2003 TWA: 1 ppm 8 hours. Issued/Revised:4/2003

tert-butyl methyl ether(MTBE) Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minutes. Issued/Revised: 4/2002 STEL: 75 ppm 15 minutes. Issued/Revised:4/2002 TWA: 92 mg/m³ 8 hours. Issued/Revised:4/2002 TWA: 25 ppm 8 hours. Issued/Revised:4/2002

2-methylpropan-2-ol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 150 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 100 ppm 8 hours. Issued/Revised:5/1995

diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 310 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 250 ppm 8 hours. Issued/Revised:5/1995

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.

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Section 8. Exposure controls and personal protection

Hand protection Wear chemical resistant gloves.

Do not re-use gloves. Protective gloves must give suitable protection against mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use.

Recommended: splash gogglesEye/face protection

Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: nitrile rubber

Recommended: Gloves made from fluoroelastomer resistant to hydrocarbons and a wide range of chemicals.Wear a chemically resistant multi-layer laminate inner glove inside an outer nitrile glove. The purpose of the outer glove is to protect the inner glove from cuts and mechanical damage. The presence of aromatic hydrocarbons in the product will significantly shorten the length of time that nitrile gloves will provide protection. Do not re-use nitrile gloves if exposed to aromatic hydrocarbons.

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Section 8. Exposure controls and personal protectionUse with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.Recommended: full-face mask

Respiratory protection

Recommended: Avoid breathing of vapours, mists or spray. Select and use respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist (Type P1) filters. Filter capacity and respirator type depends on exposure level.

Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337

Section 9. Physical and chemical properties

Physical state

Melting point

Vapour pressure

Relative density

Vapour density

Solubility

Not available.

Not available.

Hydrocarbon.Odour

pH

Pale Yellow.Colour

Evaporation rate Not available.

Auto-ignition temperature

Flash point

>350°C (>662°F)

Closed cup: <-40°C (<-40°F)

Not available.

Not available.

Viscosity

Not available.Odour threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point >30 to < 210°C (>86 to < 410°F)

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Lower: 1.4%Upper: 7.6%

Decomposition temperature Not available.

Liquid. Clear and Bright

Not applicable. Based on - Physical state

30 to 100 kPa (225 to 750 mm Hg)

750 kg/m³ (0.75 g/cm³)

insoluble in water.

Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C

Remarks Reid vapor pressure (RVP): 55 to 100 kPa (40 oC )

Not available.

Density

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Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.

Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.

Reactive or incompatible with the following materials: oxidising materials.

Section 11. Toxicological information

Information on likely routes of exposure

Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.

Ingestion

Skin contact Causes skin irritation.

No known significant effects or critical hazards.Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact Adverse symptoms may include the following:pain or irritationwateringredness

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Gasoline Category 3 Not applicable. Narcotic effectstoluene Category 3 Not applicable. Narcotic effectsn-hexane Category 3 Not applicable. Narcotic effectsBenzene Category 3 Not applicable. Respiratory tract

irritation and Narcotic effects

tert-butyl methyl ether(MTBE) Category 3 Not applicable. Narcotic effectsdiisopropyl ether Category 3 Not applicable. Narcotic effects

Name Category

Name Category

toluene Category 2 Not determined hearing organsn-hexane Category 2 Inhalation peripheral nervous

systemBenzene Category 1 Not determined blood system

Aspiration hazard

Name Result

Gasoline ASPIRATION HAZARD - Category 1toluene ASPIRATION HAZARD - Category 1n-hexane ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Route of exposure

Target organs

Information on toxicological effects

Routes of entry anticipated: Dermal, Inhalation.

Potential acute health effects

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Section 11. Toxicological information

This product contains n-hexane. Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. Animal studies have also shown that n-hexane overexposure may cause testicular injury. However, animal studies conducted with commercial hexane, containing 53% n-hexane, showed neither peripheral nervous system damage nor testicular injury at inhalation exposures up to 9000 ppm. Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce serious central nervous system effects, including unconsciousness, and possibly death.

General

May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity

May cause genetic defects.Mutagenicity

Suspected of damaging the unborn child.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects Suspected of damaging fertility.

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

Adverse symptoms may include the following:nausea or vomitingreduced foetal weightincrease in foetal deathsskeletal malformations

Adverse symptoms may include the following:irritationrednessreduced foetal weightincrease in foetal deathsskeletal malformations

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Eye contact

Vapour, mist or fume may irritate the nose, mouth and respiratory tract.

If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.

Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.

Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

Inhalation

Skin contact

Ingestion

Gasoline - Excess exposure to vapors may produce headaches, dizziness, nausea,drowsiness, irritation of eyes, nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.

In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause

Other information

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Section 11. Toxicological informationthese kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects.Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard.The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.

Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.

Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.

Gasoline: Additional toxicity information on the components:

Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very high levels can result in unconsciousness and death.

Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic exposures to high levels of benzene have been reported to cause adverse blood effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however, exposure to higher dosage levels resulted in a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not altered in rats exposed to benzene at the same level. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.

Toluene: Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material. Deliberate inhalation of high concentrations of toluene has been linked to damage of the brain, liver and kidney. Inhalation of very high concentrations of toluene, such as in cases of solvent abuse, has resulted in sudden death which may be a result of cardiac arrhythmia or central nervous system depression. Mental and/or growth retardation has been reported in children of women who deliberately inhale toluene during pregnancy (usually at thousands of ppm). Foetal developmental toxicity was observed when pregnant rats were exposed to toluene at levels of 1500 ppm. Maternal toxicity was also observed at this concentration. Prolonged, high level exposure to toluene in laboratory animals

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Section 11. Toxicological informationhas resulted in hearing loss. Exposure studies in rats have resulted in adverse effects on the kidney, liver and central nervous system. Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired colour vision and decreased performance in some neurobehavioural tests.There are occupational studies which report an association between inhalation exposure to toluene and adverse effects on reproduction including spontaneous abortion. The methodology of these studies and the reliability of the results have been questioned. In a two-generation study in rats, inhalation of toluene at levels up to 2000 ppm did not produce adverse effects on fertility or reproductive performance.

Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapour becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.

Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations; however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.

Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations,but no malformations. Because of the high exposure levels used in these studies,we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.

Xylene and its isomers are not genotoxic.

Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.

Ethylbenzene - The National Toxicology Program (NTP) conducted a 13-week inhalation study with male and female rats and mice at exposure concentrations ranging from 100 to 1000 ppm ethylbenzene. No rats or mice died during the study.Kidney, liver, and lung weights were increased in the exposed rats, while weight increases were observed only in the livers of exposed mice. Treatment-related histopathologic changes were not observed in any tissues of rats and mice.NTP also exposed male and female rats and mice by inhalation to 0, 75, 250, or 750 ppm ethylbenzene for 2 years. There was a statistically significant increase in the number of kidney tumors in male and female rats at 750 ppm. There were also increased incidences of lung tumors in male mice and liver tumors in female mice that were statistically significant at 750 ppm. Except for the male rat kidney tumors,the incidence of the tumors were within the range observed for non-exposed animals from other studies conducted by NTP. The significance of these findings to humans is unknown. Ethylbenzene is not genotoxic. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and found it to be possibly carcinogenic to humans (Group 2B).

Ethylbenzene is not genotoxic.

Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits.Ingestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye

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Section 11. Toxicological informationirritation. Naphthalene exposure has been associated with cataracts in animals and humans.

Section 12. Ecological information

Mobility Spillages may penetrate the soil causing ground water contamination.

Bioaccumulative potential

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Gasoline - - Inherent

Persistence and degradability

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

This product is not expected to bioaccumulate through food chains in the environment.

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.

Expected to be biodegradable. Non-persistent per IMO criteria

Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

Special Precautions for Landfill or Incineration

No additional special precautions identified.

Section 14. Transport information

MOTOR SPIRIT or GASOLINE or PETROLMARINE POLLUTANT

3

MOTOR SPIRIT or GASOLINE or PETROL

UN1203

3

UN1203

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

ADG

UN1203

MOTOR SPIRIT or GASOLINE or PETROL

3

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Section 14. Transport informationII II

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

Emergency schedules (EmS)F-E; S-E

The environmentally hazardous substance mark may appear if required by other transportation regulations.

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of Marpol and the IBC Code

Yes. No.

Not available.

MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gasoline and spirits

Proper shipping name

II

No.

Hazchem code3YE

Initial emergency response guide14

Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons

Model Work Health and Safety Regulations - Scheduled Substances

No listed substance

International lists

National inventory

REACH Status

Canada inventory

Australia inventory (AICS) Contact local supplier or distributor.

China inventory (IECSC) At least one component is not listed.

Japan inventory (ENCS) At least one component is not listed.

Korea inventory (KECI) At least one component is not listed.

Philippines inventory (PICCS)

At least one component is not listed.

For the REACH status of this product please consult your company contact, as identified in Section 1.

Taiwan Chemical Substances Inventory (TCSI)

Not determined.

Not scheduled When packed in containers having capacity of greater than 20 litres.

S5. When packed in containers having capacity of less than 20 litres. Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.

United States inventory (TSCA 8b)

Not determined.

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Section 16. Any other relevant information

09/11/2016

History

Date of printing

Date of issue/Date of revision

Version

Prepared by

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2

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No previous validation

1

Procedure used to derive the classification

Classification Justification

Flam. Liq. 1, H224 Expert judgmentSkin Irrit. 2, H315 Expert judgmentMuta. 1B, H340 Expert judgmentCarc. 1B, H350 Expert judgmentRepr. 2, H361 (Fertility) Expert judgmentRepr. 2, H361 (Unborn child) Expert judgmentSTOT SE 3, H336 Expert judgmentAsp. Tox. 1, H304 Expert judgment

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.

Product Stewardship

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BP Ultimate Diesel

SAFETY DATA SHEET

GHS product identifier

Section 1. Identification

BP Ultimate Diesel

Manufacturer

Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616

www.bp.com.au

Technical Helpline Number: 1300 139 700

1800 638 556EMERGENCY TELEPHONE NUMBER

Fuel for compression ignition diesel engines.Use of the substance/mixture

0000002790Product code

0000002790SDS no.

Relevant identified uses of the substance or mixture and uses advised against

Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 4ACUTE TOXICITY (inhalation) - Category 4SKIN CORROSION/IRRITATION - Category 2CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bone marrow,liver and thymus) - Category 2ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word DANGER

Hazard statements H227 - Combustible liquid.H332 - Harmful if inhaled.H315 - Causes skin irritation.H351 - Suspected of causing cancer.H304 - May be fatal if swallowed and enters airways.H373 - May cause damage to organs through prolonged or repeated exposure.(bone marrow, liver, thymus)

Hazard pictograms

Precautionary statements

GHS label elements

General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.

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Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.

P260 - Do not breathe vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment.P273 -Avoid release to the environment.

Response P314 - Get medical attention if you feel unwell.P308 + P313 - IF exposed or concerned: Get medical attention.P304 + P340 + P312 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting.P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water.Take off contaminated clothing. Wash contaminated clothing before reuse.P332 + P313 - If skin irritation occurs: Get medical attention.

Storage P405 - Store locked up.P403 - Store in a well-ventilated place.P235 - Keep cool.

Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.

Other hazards which do not result in classification

This material may contain significant quantities of polycyclic aromatic hydrocarbons,some of which have been shown by experimental studies to induce skin cancer.Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency.See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data Sheet.

Supplemental label elements

Not applicable.

Section 3. Composition and ingredient information

Fuels, diesel > 95 68334-30-5Alkanes, C10-20-branched and linear 0 - 20 928771-01-1

Ingredient name CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

% (w/w)

May also contain small quantities of proprietary performance additives. Contains small quantities of polycyclic aromatic hydrocarbons (PAHs).

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.

If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Get medical attention.

Section 4. First aid measures

Eye contact

Inhalation

Description of necessary first aid measures

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Section 4. First aid measures

Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.

Skin contact

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful with extensive subcutaneous necrosis.Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes.

Specific treatments No specific treatment.

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

See Section 11 for more detailed information on health effects and symptoms.

Section 5. Firefighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.

Combustible liquid. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.

In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Suitable extinguishing media

Unsuitable extinguishing media

Do not use water jet.

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Section 5. Firefighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.

Special protective equipment for fire-fighters

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.

Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment.Collect spilled product by absorbing with specific floating absorbents. If possible,large spillages in open waters should be contained with floating barriers or other mechanical means. If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.

Large spill

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.

Small spill

Methods and material for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

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Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

As a precaution, tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging)and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks). Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Avoid contact of spilt material and runoff with soil and surface waterways. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container.Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment.Use only non-sparking tools. Do not breathe vapour or mist. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not swallow. Aspiration hazard if swallowed.Can enter lungs and cause damage. Never siphon by mouth.

Precautions for safe handling

Fuels, diesel ACGIH TLV (United States). Absorbed through skin. TWA: 100 mg/m³, (measured as total hydrocarbons) 8 hours. Issued/Revised:1/2007 Form: Inhalable fraction and vapor

Section 8. Exposure controls and personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits

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Section 8. Exposure controls and personal protection

Hand protection Wear chemical resistant gloves.

Protective gloves must give suitable protection against mechanical risks (i.e.abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis.The frequency of replacement will depend upon the circumstances of use.

Chemical splash goggles.Eye/face protection

Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Recommended: Nitrile gloves.

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Section 8. Exposure controls and personal protection

Use with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Respiratory protection

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Recommended: If ventilation is inadequate, use respirator that will protect against organic vapour and dust/mist.

Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337

Section 9. Physical and chemical properties

Physical state

Melting point

Vapour pressure

Relative density

Vapour density

Solubility

Liquid.

Not available.

Not available.

MildOdour

pH

Clear and BrightColour

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: >61.5°C (>142.7°F) [Pensky-Martens.]

Not available.

Not available.

Viscosity

Not available.Odour threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point 108 to 380°C (226.4 to 716°F)

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Lower: 0.5%Upper: 7.5%

Decomposition temperature Not available.

Not applicable. Based on - Physical state

0.1 kPa (0.755 mm Hg)

820 to 850 kg/m³ (0.82 to 0.85 g/cm³) at 15°C

Very slightly soluble in water

Kinematic: 2 to 4.5 mm2/s (2 to 4.5 cSt) at 40°C

0.83

Density

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Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.

Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.

Reactive or incompatible with the following materials: oxidising materials.

Section 11. Toxicological information

Acute toxicity

Fuels, diesel LC50 Inhalation Dusts and mists Rat 4.1 mg/l 4 hours LD50 Dermal Rabbit >4300 mg/kg -LD50 Dermal Rabbit >4300 mg/kg -LD50 Oral Rat 17900 mg/kg -LD50 Oral Rat 7600 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Fuels, diesel Positive - Dermal -Unspecified

Mouse - 2 years

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary Suspected of causing cancer.

Mutagenicity

Fuels, diesel OECD 471 Experiment: In vitro PositiveSubject: Non-mammalian species

Equivalent to OECD 476

Experiment: In vitro Negative

Subject: Mammalian-AnimalCell: Germ

not guideline Experiment: In vivo NegativeSubject: UnspecifiedCell: Somatic

Product/ingredient name Test Experiment Result

Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.

Irritation/Corrosion

Fuels, diesel Skin - Irritation Rabbit - - -Skin - Irritation Rabbit - - -Eyes - Non-irritating to the eyes.

Rabbit - - -

Eyes - Non-irritating to the eyes.

Rabbit - - -

Product/ingredient name Result Score Exposure Observation

Skin Causes skin irritation.

Sensitisation

Fuels, diesel skin Guinea pig Not sensitisingskin Guinea pig Not sensitising

Product/ingredient name Route of exposure

Species Result

Species

Information on toxicological effects

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Section 11. Toxicological informationReproductive toxicity

Product/ingredient name Maternal toxicity

Fertility Developmental toxin

Species

Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are not met.Fertility: Not classified. Based on available data, the classification criteria are not met.Effects on or via lactation: Not classified. Based on available data, the classification criteria are not met.

Dose Exposure

Fuels, diesel - - Negative Rat Dermal 20 days- - Negative Rat Dermal 10 days- - Negative Rat Dermal 10 days

Information on likely routes of exposure

Inhalation Harmful if inhaled.

Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.

Ingestion

Skin contact Causes skin irritation.

No known significant effects or critical hazards.Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

Adverse symptoms may include the following:nausea or vomiting

Adverse symptoms may include the following:irritationredness

Eye contact Adverse symptoms may include the following:pain or irritationwateringredness

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Specific target organ toxicity (repeated exposure)

Name Category

Fuels, diesel Category 2 Not determined bone marrow, liver and thymus

Aspiration hazard

Name Result

Fuels, diesel ASPIRATION HAZARD - Category 1Alkanes, C10-20-branched and linear ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Routes of entry anticipated: Oral, Dermal, Inhalation.

Potential acute health effects

Eye contact Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.

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Section 11. Toxicological information

May cause damage to organs through prolonged or repeated exposure. Vapour,mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.

General

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Carcinogenicity

No known significant effects or critical hazards.Mutagenicity

No known significant effects or critical hazards.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Numerical measures of toxicity

Inhalation (dusts and mists) 2.211 mg/l

Route ATE value

Acute toxicity estimates

Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer. Vapour, mist or fume may irritate the nose,mouth and respiratory tract.

If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.

As with all such products containing potentially harmful levels of polycyclic aromatic hydrocarbons, prolonged or repeated skin contact may eventually result in dermatitis or more serious irreversible skin disorders including cancer.

Inhalation

Skin contact

Ingestion

Section 12. Ecological informationToxicity

Fuels, diesel EL50 >1000 mg/l Nominal Fresh water Micro-organism 40 hours NOELR 3.217 mg/l Nominal Fresh water

Micro-organism 40 hours

Acute EL50 22 mg/l Nominal Fresh water

Algae 72 hours

Acute EL50 210 mg/l Nominal Fresh water

Daphnia 48 hours

Acute EL50 68 mg/l Nominal Fresh water

Daphnia 48 hours

Acute ErL50 78 mg/l Nominal Fresh water

Algae 72 hours

Acute LL50 65 mg/l Nominal Fresh water

Fish 96 hours

Acute LL50 21 mg/l Nominal Fresh water

Fish 96 hours

Acute NOELR 10 mg/l Nominal Fresh water

Algae 72 hours

Acute NOELR 1 mg/l Nominal Fresh water

Algae 72 hours

Acute NOELR 46 mg/l Nominal Fresh water

Daphnia 48 hours

Chronic NOEL 0.083 mg/l Nominal Fresh water

Fish 14 days

Chronic NOELR 0.2 mg/l Nominal Fresh water

Daphnia 21 days

Product/ingredient name SpeciesResult Exposure

Conclusion/Summary Toxic to aquatic life with long lasting effects.

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Section 12. Ecological information

Mobility Spillages may penetrate the soil causing ground water contamination. This material may accumulate in sediments.

Bioaccumulative potential

Persistence and degradability

Fuels, diesel OECD 301 F 60 % - Readily - 28 days 30 mg/l -OECD 301 F 57.5 % - Not readily - 28 days 25 mg/l -Equivalent to EPA OTS 796.3100

35 % - Not readily - 28 days 5 mg/l -

Product/ingredient name Test DoseResult Inoculum

Conclusion/Summary Non-persistent per IMO criteria

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

This product is not expected to bioaccumulate through food chains in the environment.

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.

Partially biodegradable.

Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

Special Precautions for Landfill or Incineration

Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty packaging and should not be removed.

Section 14. Transport information

ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)

ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)

UN3082UN3082

IMDG IATA

UN number

UN proper shipping name

ADG

Not regulated.

-

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Section 14. Transport information9

III

9

III

This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.

Emergency schedules (EmS)F-A, S-F

This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of Marpol and the IBC Code

Yes. Yes.

Not available.

MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gas oils, including ship's bunkers

Proper shipping name

-

-

No.

RemarksCombustible liquid Class C1 (AS 1940).

Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons

Model Work Health and Safety Regulations - Scheduled Substances

No listed substance

International lists

National inventory

REACH Status

Canada inventory At least one component is not listed.

Australia inventory (AICS) Contact supplier for regulatory information.

China inventory (IECSC) Not determined.

Japan inventory (ENCS) At least one component is not listed.

Korea inventory (KECI) At least one component is not listed.

Philippines inventory (PICCS)

Not determined.

For the REACH status of this product please consult your company contact, as identified in Section 1.

Taiwan Chemical Substances Inventory (TCSI)

Not determined.

Not scheduled

Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.

United States inventory (TSCA 8b)

All components are listed or exempted.

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Section 16. Any other relevant information

18/04/2016

History

Date of printing

Date of issue/Date of revision

Version

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2

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07/04/2016

2

Procedure used to derive the classification

Classification Justification

Flam. Liq. 4, H227 On basis of test dataAcute Tox. 4, H332 Calculation methodSkin Irrit. 2, H315 Calculation methodCarc. 2, H351 Calculation methodSTOT RE 2, H373 (bone marrow, liver and thymus) Calculation methodAsp. Tox. 1, H304 Calculation method

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.

Product Stewardship

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Date of issue

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SAFETY DATA SHEET

GHS product identifier

Section 1. Identification

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Manufacturer

Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616

www.bp.com.au

Technical Helpline Number: 1300 139 700

1800 638 556EMERGENCY TELEPHONE NUMBER

Fuel for spark ignition engines. NOT for aviation use.For specific application advice see appropriate Technical Data Sheet or consult our company representative.

Use of the substance/mixture

0000002734Product code

0000002734SDS no.

876Historic SDS no.

Relevant identified uses of the substance or mixture and uses advised against

Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 1SKIN CORROSION/IRRITATION - Category 2GERM CELL MUTAGENICITY - Category 1BCARCINOGENICITY - Category 1BTOXIC TO REPRODUCTION (Fertility) - Category 2TOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word DANGER

Hazard statements H224 - Extremely flammable liquid and vapour.H315 - Causes skin irritation.H340 - May cause genetic defects.H350 - May cause cancer.H361 - Suspected of damaging fertility or the unborn child.H304 - May be fatal if swallowed and enters airways.H336 - May cause drowsiness or dizziness.

Hazard pictograms

Precautionary statements

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1%

General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.

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Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.

P261 - Avoid breathing vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothingP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P240 - Ground/bond container and receiving equipment.P273 - Avoid release to the environment.

Response P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.

Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.P235 - Keep cool.P405 - Store locked up.

Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.

Other hazards which do not result in classification

Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including leukaemia.

Supplemental label elements

Not applicable.

Section 3. Composition and ingredient information

Gasoline > 99 86290-81-5Contains:toluene < 20 108-88-3n-hexane < 5 110-54-3Benzene < 1 71-43-2tert-butyl methyl ether(MTBE) < 1 1634-04-42-methylpropan-2-ol < 1 75-65-0diisopropyl ether < 1 108-20-3Polycyclic aromatic hydrocarbons (PAHs) < 1 mixture

Ingredient name CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

% (w/w)

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.

If inhaled, remove to fresh air. Get medical attention.

If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.

Section 4. First aid measures

Eye contact

Inhalation

Description of necessary first aid measures

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Section 4. First aid measures

Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.

Skin contact

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Specific treatments No specific treatment.

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

See Section 11 for more detailed information on health effects and symptoms.

Section 5. Firefighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.

Extremely flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.

Special protective equipment for fire-fighters

In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Hazchem code 3YE

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Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.

Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment. Collect spilled product by absorbing with specific floating absorbents. If possible, large spillages in open waters should be contained with floating barriers or other mechanical means.If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.

Large spill

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.

Small spill

Methods and material for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Protective measures Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container.

Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Store and use away from heat, sparks, open flame

Precautions for safe handling

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Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.

or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid exposure during pregnancy. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage.Never siphon by mouth.

Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hours. Issued/Revised:5/1996 TWA: 890 mg/m³ 8 hours. Issued/Revised:5/1996 STEL: 500 ppm 15 minutes. Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minutes. Issued/Revised: 5/1996

toluene Safe Work Australia (Australia). Absorbed through skin.

Section 8. Exposure controls and personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits

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Section 8. Exposure controls and personal protection STEL: 574 mg/m³ 15 minutes. Issued/Revised: 8/2005 STEL: 150 ppm 15 minutes. Issued/Revised: 8/2005 TWA: 191 mg/m³ 8 hours. Issued/Revised:8/2005 TWA: 50 ppm 8 hours. Issued/Revised:8/2005

n-hexane Safe Work Australia (Australia). TWA: 72 mg/m³ 8 hours. Issued/Revised:11/2001 TWA: 20 ppm 8 hours. Issued/Revised:11/2001

Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hours.

Benzene Safe Work Australia (Australia). TWA: 3.2 mg/m³ 8 hours. Issued/Revised:4/2003 TWA: 1 ppm 8 hours. Issued/Revised:4/2003

tert-butyl methyl ether(MTBE) Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minutes. Issued/Revised: 4/2002 STEL: 75 ppm 15 minutes. Issued/Revised:4/2002 TWA: 92 mg/m³ 8 hours. Issued/Revised:4/2002 TWA: 25 ppm 8 hours. Issued/Revised:4/2002

2-methylpropan-2-ol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 150 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 100 ppm 8 hours. Issued/Revised:5/1995

diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 310 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 250 ppm 8 hours. Issued/Revised:5/1995

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.

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Section 8. Exposure controls and personal protection

Hand protection Wear chemical resistant gloves.

Do not re-use gloves. Protective gloves must give suitable protection against mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use.

Recommended: splash gogglesEye/face protection

Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: nitrile rubber

Recommended: Gloves made from fluoroelastomer resistant to hydrocarbons and a wide range of chemicals.Wear a chemically resistant multi-layer laminate inner glove inside an outer nitrile glove. The purpose of the outer glove is to protect the inner glove from cuts and mechanical damage. The presence of aromatic hydrocarbons in the product will significantly shorten the length of time that nitrile gloves will provide protection. Do not re-use nitrile gloves if exposed to aromatic hydrocarbons.

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Section 8. Exposure controls and personal protectionUse with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.Recommended: full-face mask

Respiratory protection

Recommended: Avoid breathing of vapours, mists or spray. Select and use respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist (Type P1) filters. Filter capacity and respirator type depends on exposure level.

Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337

Section 9. Physical and chemical properties

Physical state

Melting point

Vapour pressure

Relative density

Vapour density

Solubility

Not available.

Not available.

Hydrocarbon.Odour

pH

Pale Yellow.Colour

Evaporation rate Not available.

Auto-ignition temperature

Flash point

>350°C (>662°F)

Closed cup: <-40°C (<-40°F)

Not available.

Not available.

Viscosity

Not available.Odour threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point >30 to < 210°C (>86 to < 410°F)

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Lower: 1.4%Upper: 7.6%

Decomposition temperature Not available.

Liquid. Clear and Bright

Not applicable. Based on - Physical state

30 to 100 kPa (225 to 750 mm Hg)

750 kg/m³ (0.75 g/cm³)

insoluble in water.

Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C

Remarks Reid vapor pressure (RVP): 55 to 100 kPa (40 oC )

Not available.

Density

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Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.

Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.

Reactive or incompatible with the following materials: oxidising materials.

Section 11. Toxicological information

Information on likely routes of exposure

Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.

Ingestion

Skin contact Causes skin irritation.

No known significant effects or critical hazards.Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact Adverse symptoms may include the following:pain or irritationwateringredness

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Gasoline Category 3 Not applicable. Narcotic effectstoluene Category 3 Not applicable. Narcotic effectsn-hexane Category 3 Not applicable. Narcotic effectsBenzene Category 3 Not applicable. Respiratory tract

irritation and Narcotic effects

tert-butyl methyl ether(MTBE) Category 3 Not applicable. Narcotic effectsdiisopropyl ether Category 3 Not applicable. Narcotic effects

Name Category

Name Category

toluene Category 2 Not determined hearing organsn-hexane Category 2 Inhalation peripheral nervous

systemBenzene Category 1 Not determined blood system

Aspiration hazard

Name Result

Gasoline ASPIRATION HAZARD - Category 1toluene ASPIRATION HAZARD - Category 1n-hexane ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Route of exposure

Target organs

Information on toxicological effects

Routes of entry anticipated: Dermal, Inhalation.

Potential acute health effects

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Section 11. Toxicological information

This product contains n-hexane. Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. Animal studies have also shown that n-hexane overexposure may cause testicular injury. However, animal studies conducted with commercial hexane, containing 53% n-hexane, showed neither peripheral nervous system damage nor testicular injury at inhalation exposures up to 9000 ppm. Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce serious central nervous system effects, including unconsciousness, and possibly death.

General

May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity

May cause genetic defects.Mutagenicity

Suspected of damaging the unborn child.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects Suspected of damaging fertility.

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

Adverse symptoms may include the following:nausea or vomitingreduced foetal weightincrease in foetal deathsskeletal malformations

Adverse symptoms may include the following:irritationrednessreduced foetal weightincrease in foetal deathsskeletal malformations

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Eye contact

Vapour, mist or fume may irritate the nose, mouth and respiratory tract.

If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.

Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.

Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

Inhalation

Skin contact

Ingestion

Gasoline - Excess exposure to vapors may produce headaches, dizziness, nausea,drowsiness, irritation of eyes, nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.

In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause

Other information

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Section 11. Toxicological informationthese kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects.Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard.The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.

Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.

Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.

Gasoline: Additional toxicity information on the components:

Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very high levels can result in unconsciousness and death.

Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic exposures to high levels of benzene have been reported to cause adverse blood effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however, exposure to higher dosage levels resulted in a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not altered in rats exposed to benzene at the same level. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.

Toluene: Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material. Deliberate inhalation of high concentrations of toluene has been linked to damage of the brain, liver and kidney. Inhalation of very high concentrations of toluene, such as in cases of solvent abuse, has resulted in sudden death which may be a result of cardiac arrhythmia or central nervous system depression. Mental and/or growth retardation has been reported in children of women who deliberately inhale toluene during pregnancy (usually at thousands of ppm). Foetal developmental toxicity was observed when pregnant rats were exposed to toluene at levels of 1500 ppm. Maternal toxicity was also observed at this concentration. Prolonged, high level exposure to toluene in laboratory animals

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Section 11. Toxicological informationhas resulted in hearing loss. Exposure studies in rats have resulted in adverse effects on the kidney, liver and central nervous system. Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired colour vision and decreased performance in some neurobehavioural tests.There are occupational studies which report an association between inhalation exposure to toluene and adverse effects on reproduction including spontaneous abortion. The methodology of these studies and the reliability of the results have been questioned. In a two-generation study in rats, inhalation of toluene at levels up to 2000 ppm did not produce adverse effects on fertility or reproductive performance.

Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapour becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.

Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations; however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.

Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations,but no malformations. Because of the high exposure levels used in these studies,we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.

Xylene and its isomers are not genotoxic.

Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.

Ethylbenzene - The National Toxicology Program (NTP) conducted a 13-week inhalation study with male and female rats and mice at exposure concentrations ranging from 100 to 1000 ppm ethylbenzene. No rats or mice died during the study.Kidney, liver, and lung weights were increased in the exposed rats, while weight increases were observed only in the livers of exposed mice. Treatment-related histopathologic changes were not observed in any tissues of rats and mice.NTP also exposed male and female rats and mice by inhalation to 0, 75, 250, or 750 ppm ethylbenzene for 2 years. There was a statistically significant increase in the number of kidney tumors in male and female rats at 750 ppm. There were also increased incidences of lung tumors in male mice and liver tumors in female mice that were statistically significant at 750 ppm. Except for the male rat kidney tumors,the incidence of the tumors were within the range observed for non-exposed animals from other studies conducted by NTP. The significance of these findings to humans is unknown. Ethylbenzene is not genotoxic. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and found it to be possibly carcinogenic to humans (Group 2B).

Ethylbenzene is not genotoxic.

Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits.Ingestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye

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Section 11. Toxicological informationirritation. Naphthalene exposure has been associated with cataracts in animals and humans.

Section 12. Ecological information

Mobility Spillages may penetrate the soil causing ground water contamination.

Bioaccumulative potential

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Gasoline - - Inherent

Persistence and degradability

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

This product is not expected to bioaccumulate through food chains in the environment.

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.

Expected to be biodegradable. Non-persistent per IMO criteria

Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

Special Precautions for Landfill or Incineration

No additional special precautions identified.

Section 14. Transport information

MOTOR SPIRIT or GASOLINE or PETROLMARINE POLLUTANT

3

MOTOR SPIRIT or GASOLINE or PETROL

UN1203

3

UN1203

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

ADG

UN1203

MOTOR SPIRIT or GASOLINE or PETROL

3

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Section 14. Transport informationII II

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

Emergency schedules (EmS)F-E; S-E

The environmentally hazardous substance mark may appear if required by other transportation regulations.

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of Marpol and the IBC Code

Yes. No.

Not available.

MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gasoline and spirits

Proper shipping name

II

No.

Hazchem code3YE

Initial emergency response guide14

Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons

Model Work Health and Safety Regulations - Scheduled Substances

No listed substance

International lists

National inventory

REACH Status

Canada inventory At least one component is not listed.

Australia inventory (AICS) Contact local supplier or distributor.

China inventory (IECSC) At least one component is not listed.

Japan inventory (ENCS) At least one component is not listed.

Korea inventory (KECI) At least one component is not listed.

Philippines inventory (PICCS)

At least one component is not listed.

For the REACH status of this product please consult your company contact, as identified in Section 1.

Taiwan Chemical Substances Inventory (TCSI)

Not determined.

Not scheduled When packed in containers having capacity of greater than 20 litres.

S5. When packed in containers having capacity of less than 20 litres. Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.

United States inventory (TSCA 8b)

Not determined.

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Section 16. Any other relevant information

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History

Date of printing

Date of issue/Date of revision

Version

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2

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No previous validation

1

Procedure used to derive the classification

Classification Justification

Flam. Liq. 1, H224 Expert judgmentSkin Irrit. 2, H315 Expert judgmentMuta. 1B, H340 Expert judgmentCarc. 1B, H350 Expert judgmentRepr. 2, H361 (Fertility) Expert judgmentRepr. 2, H361 (Unborn child) Expert judgmentSTOT SE 3, H336 Expert judgmentAsp. Tox. 1, H304 Expert judgment

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.

Product Stewardship

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Unleaded 91

SAFETY DATA SHEET

GHS product identifier

Section 1. Identification

Unleaded 91

regular unleaded petrolOther means of identification

Manufacturer

Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616

www.bp.com.au

Technical Helpline Number: 1300 139 700

1800 638 556EMERGENCY TELEPHONE NUMBER

Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning agent.For specific application advice see appropriate Technical Data Sheet or consult our company representative.

Use of the substance/mixture

0000002733Product code

0000002733SDS no.

875; 0000002889Historic SDS no.

Relevant identified uses of the substance or mixture and uses advised against

Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 1SKIN CORROSION/IRRITATION - Category 2GERM CELL MUTAGENICITY - Category 1BCARCINOGENICITY - Category 1BTOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word DANGER

Hazard statements H224 - Extremely flammable liquid and vapour.H315 - Causes skin irritation.H340 - May cause genetic defects.H350 - May cause cancer.H361 - Suspected of damaging the unborn child.H304 - May be fatal if swallowed and enters airways.H336 - May cause drowsiness or dizziness.

Hazard pictograms

Precautionary statements

GHS label elements

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Section 2. Hazard(s) identification

Prevention P201 - Obtain special instructions before use.P261 - Avoid breathing vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothingP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P240 - Ground/bond container and receiving equipment.P273 - Avoid release to the environment.

Response P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.

Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.P235 - Keep cool.P405 - Store locked up.

Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.

Other hazards which do not result in classification

Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including leukaemia.

General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.

Supplemental label elements

Not applicable.

Section 3. Composition and ingredient information

Gasoline >90 86290-81-5Contains:Benzene <1 71-43-2tert-butyl methyl ether(MTBE) <1 1634-04-42-methylpropan-2-ol <1 75-65-0diisopropyl ether <1 108-20-3Polycyclic aromatic hydrocarbons (PAHs) <1 mixture

Ingredient name CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

% (w/w)

A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon numbers predominantly between C4 and C12. May contain oxygenates. May also contain small quantities of proprietary performance additives.

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.

If inhaled, remove to fresh air. Get medical attention.

If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.

Section 4. First aid measures

Eye contact

Inhalation

Description of necessary first aid measures

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Section 4. First aid measures

Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.

Skin contact

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Specific treatments No specific treatment.

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

See Section 11 for more detailed information on health effects and symptoms.

Section 5. Firefighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.

Extremely flammable liquid and vapour. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.

Special protective equipment for fire-fighters

In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Hazchem code 3YE

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Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use explosion-protected equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.

Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment.Collect spilled product by absorbing with specific floating absorbents. If possible,large spillages in open waters should be contained with floating barriers or other mechanical means. If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.

Large spill

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use explosion-protected equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.

Small spill

Methods and material for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Protective measures Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container.

Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges. Avoid contact of spilt material and runoff with soil and surface waterways. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not

Precautions for safe handling

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Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is explosion-protected (i.e. will not produce sparks). Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.

in use. Do not reuse container. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid exposure during pregnancy. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage.Never siphon by mouth.

Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hours. Issued/Revised:5/1996 TWA: 890 mg/m³ 8 hours. Issued/Revised:5/1996 STEL: 500 ppm 15 minutes. Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minutes. Issued/Revised: 5/1996

Benzene Safe Work Australia (Australia).

Section 8. Exposure controls and personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits

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Section 8. Exposure controls and personal protection TWA: 3.2 mg/m³ 8 hours. Issued/Revised:4/2003 TWA: 1 ppm 8 hours. Issued/Revised:4/2003

Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hours.

diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 310 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 250 ppm 8 hours. Issued/Revised:5/1995

2-methylpropan-2-ol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 150 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 100 ppm 8 hours. Issued/Revised:5/1995

tert-butyl methyl ether(MTBE) Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minutes. Issued/Revised: 4/2002 STEL: 75 ppm 15 minutes. Issued/Revised:4/2002 TWA: 92 mg/m³ 8 hours. Issued/Revised:4/2002 TWA: 25 ppm 8 hours. Issued/Revised:4/2002

Recommended: splash gogglesEye/face protection

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

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Section 8. Exposure controls and personal protectionHand protection

Use with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.Recommended: full-face mask

Wear chemical resistant gloves.

Protective gloves must give suitable protection against mechanical risks (i.e.abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis.The frequency of replacement will depend upon the circumstances of use.

Respiratory protection

Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: nitrile rubber

Recommended: Gloves made from fluoroelastomer resistant to hydrocarbons and a wide range of chemicals.Wear a chemically resistant multi-layer laminate inner glove inside an outer nitrile glove. The purpose of the outer glove is to protect the inner glove from cuts and mechanical damage. The presence of aromatic hydrocarbons in the product will significantly shorten the length of time that nitrile gloves will provide protection. Do not re-use nitrile gloves if exposed to aromatic hydrocarbons.

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Section 8. Exposure controls and personal protectionRecommended: Avoid breathing of vapours, mists or spray. Select and use

respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist (Type P1) filters. Filter capacity and respirator type depends on exposure level.

Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337

Section 9. Physical and chemical properties

Physical state

Melting point

Vapour pressure

Relative density

Vapour density

Solubility

Not available.

Not available.

Hydrocarbon.Odour

pH

Pale Yellow. to Pale Red.Colour

Evaporation rate Not available.

Auto-ignition temperature

Flash point

>350°C (>662°F)

Closed cup: <-40°C (<-40°F)

Not available.

Not available.

Viscosity

Not available.Odour threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point >30 to 210°C (>86 to 410°F)

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Lower: 1.4%Upper: 7.6%

Decomposition temperature Not available.

Liquid. Clear and Bright

Not applicable. Based on - Physical state

30.1 to 100.3 kPa (225.6 to 752 mm Hg)

710 to 750 kg/m³ (0.71 to 0.75 g/cm³)

insoluble in water.

Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C

Remarks Reid vapor pressure (RVP): 55 to 100 kPa (40 oC )

Not available.

Density

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.

Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.

Reactive or incompatible with the following materials: oxidising materials.

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Section 11. Toxicological information

Acute toxicity

Gasoline LC50 Inhalation Vapour Rat >7630 mg/m³ Nominal

4 hours

LC50 Inhalation Vapour Rat >5610 mg/m³ analytical

4 hours

LD50 Dermal Rabbit >2000 mg/kg -LD50 Oral Rat >5000 mg/kg -

diisopropyl ether LC50 Inhalation Vapour Rat 40.5 mg/m³ 1 hoursLD50 Dermal Rabbit 2000 mg/kg -LD50 Oral Rat 8470 mg/kg -

2-methylpropan-2-ol LD50 Oral Rabbit 3559 mg/kg -LD50 Oral Rat 2743 mg/kg -

tert-butyl methyl ether(MTBE)

LC50 Inhalation Vapour Rat 85 mg/l 4 hours

LD50 Dermal Rat >2000 mg/kg -LD50 Oral Rat >2000 mg/kg -

Product/ingredient name Result Species Dose Exposure

Mutagenicity

Gasoline Equivalent to OECD 476

Experiment: In vitro Negative

Subject: Mammal - species unspecified

Equivalent to OECD 471

Experiment: In vitro Negative

Subject: Non-mammalian speciesEPA OPPTS 870.5395 Experiment: In vivo Negative

Subject: UnspecifiedCell: Germ

Equivalent to OECD 475

Experiment: In vivo Negative

Subject: UnspecifiedCell: Germ

tert-butyl methyl ether(MTBE)

EU B 13/14 Experiment: In vitro Negative

Subject: Non-mammalian speciesOECD 471 Experiment: In vitro Negative

Subject: Non-mammalian speciesOECD 476 Experiment: In vitro Negative

Subject: Non-mammalian speciesEquivalent to OECD 473

Experiment: In vitro Negative

Subject: Non-mammalian speciesEquivalent to OECD 486

Experiment: In vivo Negative

Subject: UnspecifiedCell: Somatic

Product/ingredient name Test Experiment Result

Irritation/Corrosion

Gasoline Skin - Irritant Rabbit - - -Eyes - Non-irritating to the eyes.

Rabbit - - -

tert-butyl methyl ether(MTBE)

Skin - Irritation Rabbit - - -

Eyes - Non-irritating to the eyes.

Rabbit - - -

Product/ingredient name Result Score Exposure Observation

Skin Causes skin irritation.

Species

Information on toxicological effects

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Section 11. Toxicological information

Carcinogenicity

Gasoline Negative - Inhalation -Unspecified

Rat - 113 weeks

Negative - Dermal -Unspecified

Mouse - 102 weeks

tert-butyl methyl ether(MTBE)

Positive - Inhalation -Unspecified

Rat - 2 years

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary May cause cancer

Equivalent to EPA OPPTS 870.5385

Experiment: In vivo Negative

Subject: UnspecifiedCell: Somatic

Equivalent to EPA OPPTS 798.5385

Experiment: In vivo Negative

Subject: UnspecifiedCell: Somatic

Conclusion/Summary May cause genetic defects.

Reproductive toxicity

Product/ingredient name Maternal toxicity

Fertility Developmental toxin

Species Dose Exposure

Gasoline - Negative - Rat Inhalation 2 generation

- - Negative Rat Inhalation 14 daystert-butyl methyl ether(MTBE)

- Negative - Rat Inhalation 2 generation

- - Negative Rat Inhalation 9 days

Information on likely routes of exposure

Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Skin contact Causes skin irritation.

No known significant effects or critical hazards.Eye contact

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Gasoline Category 3 Not applicable. Narcotic effectsBenzene Category 3 Not applicable. Respiratory tract

irritation and Narcotic effects

diisopropyl ether Category 3 Not applicable. Narcotic effectstert-butyl methyl ether(MTBE) Category 3 Not applicable. Narcotic effects

Name Category

Name Category

Benzene Category 1 Not determined blood system

Aspiration hazard

Name Result

Gasoline ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Route of exposure

Target organs

Routes of entry anticipated: Dermal, Inhalation.

Potential acute health effects

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Section 11. Toxicological informationIrritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.

Ingestion

Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce serious central nervous system effects, including unconsciousness, and possibly death.

General

May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity

May cause genetic defects.Mutagenicity

Suspected of damaging the unborn child.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

Adverse symptoms may include the following:nausea or vomitingreduced foetal weightincrease in foetal deathsskeletal malformations

Adverse symptoms may include the following:irritationrednessreduced foetal weightincrease in foetal deathsskeletal malformations

Eye contact Adverse symptoms may include the following:pain or irritationwateringredness

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Eye contact

Vapour, mist or fume may irritate the nose, mouth and respiratory tract.

If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.

Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.

Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

Inhalation

Skin contact

Ingestion

Gasoline - Excess exposure to vapors may produce headaches, dizziness, nausea,drowsiness, irritation of eyes, nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.

In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related

Other information

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Section 11. Toxicological informationkidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause these kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects.Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard.The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.

Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.

Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.

Gasoline: Additional toxicity information on the components:

Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very high levels can result in unconsciousness and death.

Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic exposures to high levels of benzene have been reported to cause adverse blood effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however, exposure to higher dosage levels resulted in a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not altered in rats exposed to benzene at the same level. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.

Toluene: Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material. Deliberate inhalation of high concentrations of toluene has been linked to damage of the brain, liver and kidney. Inhalation of very high concentrations of toluene, such as in cases of solvent abuse, has resulted in sudden death which may be a result of cardiac arrhythmia or central nervous system depression. Mental and/or growth retardation has been reported in children

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Section 11. Toxicological informationof women who deliberately inhale toluene during pregnancy (usually at thousands of ppm). Foetal developmental toxicity was observed when pregnant rats were exposed to toluene at levels of 1500 ppm. Maternal toxicity was also observed at this concentration. Prolonged, high level exposure to toluene in laboratory animals has resulted in hearing loss. Exposure studies in rats have resulted in adverse effects on the kidney, liver and central nervous system. Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired colour vision and decreased performance in some neurobehavioural tests.There are occupational studies which report an association between inhalation exposure to toluene and adverse effects on reproduction including spontaneous abortion. The methodology of these studies and the reliability of the results have been questioned. In a two-generation study in rats, inhalation of toluene at levels up to 2000 ppm did not produce adverse effects on fertility or reproductive performance.

Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapour becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.

Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations; however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.

Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations,but no malformations. Because of the high exposure levels used in these studies,we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.

Xylene and its isomers are not genotoxic.

Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.

Ethylbenzene - The National Toxicology Program (NTP) conducted a 13-week inhalation study with male and female rats and mice at exposure concentrations ranging from 100 to 1000 ppm ethylbenzene. No rats or mice died during the study.Kidney, liver, and lung weights were increased in the exposed rats, while weight increases were observed only in the livers of exposed mice. Treatment-related histopathologic changes were not observed in any tissues of rats and mice.NTP also exposed male and female rats and mice by inhalation to 0, 75, 250, or 750 ppm ethylbenzene for 2 years. There was a statistically significant increase in the number of kidney tumors in male and female rats at 750 ppm. There were also increased incidences of lung tumors in male mice and liver tumors in female mice that were statistically significant at 750 ppm. Except for the male rat kidney tumors,the incidence of the tumors were within the range observed for non-exposed animals from other studies conducted by NTP. The significance of these findings to humans is unknown. Ethylbenzene is not genotoxic. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and found it to be possibly carcinogenic to humans (Group 2B).

Ethylbenzene is not genotoxic.

Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits.

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Section 11. Toxicological informationIngestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye irritation. Naphthalene exposure has been associated with cataracts in animals and humans.

Section 12. Ecological informationToxicity

Gasoline Acute EC50 15.41 mg/l Nominal Fresh water

Micro-organism 40 hours

Acute EL50 3.1 mg/l Nominal Fresh water

Algae 72 hours

Acute EL50 3.7 mg/l Nominal Fresh water

Algae 96 hours

Acute EL50 4.5 mg/l Nominal Fresh water

Daphnia 48 hours

Acute LL50 10 mg/l Nominal Fresh water

Fish 96 hours

Acute LL50 8.2 mg/l Nominal Fresh water

Fish 96 hours

Acute NOELR 0.5 mg/l Nominal Fresh water

Algae 72 hours

Acute NOELR 0.5 mg/l Nominal Fresh water

Daphnia 48 hours

Chronic EL50 10 mg/l Nominal Fresh water

Daphnia 21 days

Chronic EL50 >40 mg/l Nominal Fresh water

Daphnia 21 days

Chronic EL50 10 mg/l Nominal Fresh water

Fish 21 days

Chronic LL50 5.2 mg/l Nominal Fresh water

Fish 14 days

Chronic NOELR 2.6 mg/l Nominal Fresh water

Daphnia 21 days

Chronic NOELR 16 mg/l Nominal Fresh water

Daphnia 21 days

Chronic NOELR 2.6 mg/l Nominal Fresh water

Fish 14 days

Chronic NOELR 2.6 mg/l Nominal Fresh water

Fish 21 days

Chronic PNEC >0.4 mg/kg soil, plants -tert-butyl methyl ether(MTBE) Acute EC50 472 mg/l Fresh water Daphnia 48 hours

Acute LC50 200 mg/l Marine water Crustaceans 96 hours Acute LC50 672 mg/l Fresh water Fish 96 hours Acute LC50 574 mg/l Marine water Fish 96 hours Chronic NOEC 26 mg/l Marine water Crustaceans 28 days Chronic NOEC 51 mg/l Fresh water Daphnia 21 days

Product/ingredient name SpeciesResult Exposure

Conclusion/Summary Toxic to aquatic life with long lasting effects.

Persistence and degradability

Product/ingredient name Test DoseResult Inoculum

Expected to be biodegradable. Non-persistent per IMO criteria

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Section 12. Ecological information

Mobility Spillages may penetrate the soil causing ground water contamination.

LogPow BCF Potential

Bioaccumulative potential

Product/ingredient name

Gasoline 2 to 7 - highBenzene 2.13 11 lowdiisopropyl ether 2.4 - low2-methylpropan-2-ol 0.317 - lowtert-butyl methyl ether(MTBE) 1.04 - low

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Gasoline - - Inherent

tert-butyl methyl ether(MTBE) not guideline 100 % - 1.25 days - -Modelled data 61 to 69 % - 151 days - -OECD 301 D 9.24 % - Not readily - 28 days - -OECD 301 D 1.8 % - Not readily - 28 days - -OECD 301 D 0 % - Not readily - 28 days - -Modelled data 0 % - 250 days - -

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

This product is not expected to bioaccumulate through food chains in the environment.

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.

Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

Special Precautions for Landfill or Incineration

No additional special precautions identified.

Section 14. Transport information

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Section 14. Transport information

MOTOR SPIRIT or GASOLINE or PETROLMARINE POLLUTANT

3

II

MOTOR SPIRIT or GASOLINE or PETROL

UN1203

3

II

UN1203

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

Emergency schedules (EmS)F-E,S-E

The environmentally hazardous substance mark may appear if required by other transportation regulations.

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of Marpol and the IBC Code

Yes. No.

Not available.

MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gasoline and spirits

Proper shipping name

ADG

UN1203

MOTOR SPIRIT or GASOLINE or PETROL

3

II

No.

Hazchem code3YE

Initial emergency response guide14

Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons

Model Work Health and Safety Regulations - Scheduled Substances

Ingredient name Schedule

No listed substance -

International lists

National inventory

REACH Status

Canada inventory At least one component is not listed.

Australia inventory (AICS) Contact local supplier or distributor.

China inventory (IECSC) At least one component is not listed.

Japan inventory (ENCS) At least one component is not listed.

Korea inventory (KECI) At least one component is not listed.

For the REACH status of this product please consult your company contact, as identified in Section 1.

Not scheduled. When packed in containers having capacity of greater than 20 litres.

S5. When packed in containers having capacity of less than 20 litres.

Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.

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Section 15. Regulatory informationPhilippines inventory (PICCS)

At least one component is not listed.

Taiwan Chemical Substances Inventory (TCSI)

Not determined.

United States inventory (TSCA 8b)

Not determined.

Section 16. Any other relevant information

01/09/2016

History

Date of printing

Date of issue/Date of revision

Version

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2

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29/06/2016

3

Procedure used to derive the classification

Classification Justification

Flam. Liq. 1, H224 Expert judgmentSkin Irrit. 2, H315 Expert judgmentMuta. 1B, H340 Expert judgmentCarc. 1B, H350 Expert judgmentRepr. 2, H361 (Unborn child) Expert judgmentSTOT SE 3, H336 Expert judgmentAsp. Tox. 1, H304 Expert judgment

Product Stewardship

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Section 16. Any other relevant informationAll reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.

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Material Safety Data Sheet

1 . Identification of the material and supplier

BP Unleaded 91 with up to 10% EthanolProduct name

E10, E10MSynonyms

0000002889SDS no.

Product use Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning agent.

BP Australia Pty Ltd (ABN 53 004 085 616)717 Bourke StreetDocklands VIC 3008Australia Tel: +61 (03) 9268 4111Fax: +61 (03) 9268 3321

Supplier

1800 638 556EMERGENCY TELEPHONE NUMBER

Product code 0000002889

Hazards identification2 .

HAZARDOUS SUBSTANCE. DANGEROUS GOODS.Statement of hazardous/dangerous nature

R12- Extremely flammable.R45- May cause cancer.R46- May cause heritable genetic damage.R63- Possible risk of harm to the unborn child.R65- Also harmful: may cause lung damage if swallowed.R38- Irritating to skin.R67- Vapours may cause drowsiness and dizziness.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Risk phrases

S2- Keep out of the reach of children.S16- Keep away from sources of ignition - No smoking.S23- Do not breathe gas/fumes/vapour/spray.S24- Avoid contact with skin.S29- Do not empty into drains.S36/37- Wear suitable protective clothing and gloves.S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).S61- Avoid release to the environment. Refer to special instructions/safety data sheet.S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

Safety phrases

Composition/information on ingredients3 .

A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon numbers predominantly between C4 and C12. May contain oxygenates. May also contain small quantities of proprietary performance additives.

Gasoline 86290-81-5 > 90Ethanol 64-17-5 < 10

Contains:Toluene 108-88-3 5 - 15Benzene 71-43-2 < 1tert-butyl alcohol 75-65-0 < 1tert-butyl methyl ether 1634-04-4 < 1diisopropyl ether 108-20-3 < 1Polycyclic aromatic hydrocarbons (PAHs) mixture < 1

Ingredient name CAS no. %

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Skin contact

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse.Get medical attention immediately.

4 .

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Inhalation

Eye contact

First-aid measures

Ingestion If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention.

Advice to doctor Treatment should in general be symptomatic and directed to relieving any effects.

Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment.Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Fire-fighting measures5 .

DO NOT FIGHT FIRE WHEN IT REACHES MATERIAL. Withdraw from fire and let it burn. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move people out of line-of-sight of the scene and away from windows.

Special fire-fighting procedures

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Protection of fire-fighters

Unusual fire/explosion hazards

Extremely flammable liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Hazchem code 3YE

Hazardous decomposition products

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Extinguishing media

Suitable In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.

Do not use water jet.Not suitable

6 . Accidental release measures

Environmental precautions

Personal precautions

Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area.Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,soil or air). Water polluting material. May be harmful to the environment if released in large quantities.

Large spill

Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Small spill

Handling

Handling and storage

Storage

7 .

Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not ingest. If ingested, do not induce vomiting. Avoid contact with skin and clothing. Use only with adequate ventilation. Do not breathe vapour or mist. Keep away from heat, sparks and flame. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Avoid contact of spilt material and runoff with soil and surface waterways. Wash thoroughly after handling.

Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Store and use only in equipment/containers designed for use with this product. Do not remove warning labels from containers.

Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an oxygen concentration of at least 20% volume.

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Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks.

When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.

If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard.

Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use.

This product must be handled in compliance with Australian Standard: The storage and handling of flammable and combustible liquids [Standard 1940-2004 as amended and adapted].

Additional information-Storage

8 . Exposure controls/personal protection

Ingredient name Occupational exposure limits

Ethanol Safe Work Australia (Australia). TWA: 1880 mg/m³ 8 hour(s). Issued/Revised: 5/1995 TWA: 1000 ppm 8 hour(s). Issued/Revised: 5/1995

Benzene Safe Work Australia (Australia). TWA: 3.2 mg/m³ 8 hour(s). Issued/Revised: 4/2003 TWA: 1 ppm 8 hour(s). Issued/Revised: 4/2003

Toluene Safe Work Australia (Australia). Absorbed through skin. STEL: 574 mg/m³ 15 minute(s). Issued/Revised: 8/2005 STEL: 150 ppm 15 minute(s). Issued/Revised: 8/2005 TWA: 191 mg/m³ 8 hour(s). Issued/Revised: 8/2005 TWA: 50 ppm 8 hour(s). Issued/Revised: 8/2005

tert-butyl alcohol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minute(s). Issued/Revised: 5/1995 STEL: 150 ppm 15 minute(s). Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hour(s). Issued/Revised: 5/1995 TWA: 100 ppm 8 hour(s). Issued/Revised: 5/1995

tert-butyl methyl ether Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minute(s). Issued/Revised: 4/2002 STEL: 75 ppm 15 minute(s). Issued/Revised: 4/2002 TWA: 92 mg/m³ 8 hour(s). Issued/Revised: 4/2002 TWA: 25 ppm 8 hour(s). Issued/Revised: 4/2002

diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minute(s). Issued/Revised: 5/1995 STEL: 310 ppm 15 minute(s). Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hour(s). Issued/Revised: 5/1995 TWA: 250 ppm 8 hour(s). Issued/Revised: 5/1995

Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hour(s).

Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hour(s). Issued/Revised: 5/1996 TWA: 890 mg/m³ 8 hour(s). Issued/Revised: 5/1996 STEL: 500 ppm 15 minute(s). Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minute(s). Issued/Revised: 5/1996

For information and guidance, the ACGIH values are included. For further information on these please consult your supplier.

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits.Ensure that eyewash stations and safety showers are close to the workstation location.All chemicals should be assessed for their risks to health and appropriate control measures put in place to prevent or adequately control exposure. A hierarchy of control measures exists (e.g.elimination, substitution, general ventilation, containment, systems of work, changing the process or activity) that must be considered before use of personal protective equipment. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible. The above information is provided to

Occupational exposure controls

Biological Limit Values Benzene :S-Phenylmercapturic acid in urine - End of shift: 25 µg/g creatinine (ACGIH)t,t-Muconic acid in urine - End of shift: 500 µg/g creatinine (ACGIH)

Polycyclic aromatic hydrocarbons (PAHs): 1-Hydroxypyrene (1-HP) in urine (with hydrolysis) - End of shift at end of workweek: Nonquantitative (ACGIH)ACGIH “Nonquantitative” Biological Exposure Indices (BEI®): Biological monitoring should be considered for this compound based on the review; however, a specific BEI® could not be determined due to insufficient data.

Whilst specific OELs for certain components are included in this SDS, it should be noted that other components of the preparation will be present in any mist, vapour or dust produced. For this reason, the specific OELs may not be applicable to the product and are provided for guidance purposes.

Exposure controls

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assist the customer in conducting its own assessment of risk to the health and safety of workers for the substance or preparation, and protection of the environment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Hygiene measures

Personal protective equipment

Use only with adequate ventilation. Avoid breathing of vapours, mists or spray. Select and use respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist filters. Filter capacity and respirator type depends on exposure level.

Respiratory protection

Do not get on skin or clothing. Wear clothing and footwear that cannot be penetrated by chemicals or oil. Wear face shield.

Skin and body

Wear gloves that cannot be penetrated by chemicals or oil.

The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Hand protection

Safety glasses with side shields.Eye protection

Physical and chemical properties9 .

Auto-ignition temperature >350°C (>662°F)

Flash point <-40 °C (Closed cup) Pensky-Martens.

Colour Purple. or Red.

Physical state Liquid.

Odour Gasoline [Strong]

30 to 210°C (86 to 410°F)Boiling point / range

Not available.Melting point / range

750 kg/m³ (0.75 g/cm³)Density

Vapour density Not available.

Not available.Vapour pressure

Solubility insoluble in water.

pH Not available.

Relative density/Specific gravity

Not available.

Viscosity Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C

Stability and reactivity10 .

The product is stable.Stability

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.

Incompatibility with various substances/Hazardous Reactions

Reactive or incompatible with the following materials: oxidising materials.

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Hazardous decomposition products

Toxicological information11 .

Eyes Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.

Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).

Skin

Inhalation Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled. May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.

Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.Ingestion

Gasoline as a mixture is classified as a 2B (possible human) carcinogen by IARC.Gasoline engine exhaust is classified as possibly carcinogenic to humans by IARC (2B). This classification is based primarily on animal and in vitro studies of gasoline engine exhaust condensates/extracts. Studies of the gaseous exhaust stream in animals did not provided sufficient evidence for classification as a carcinogen.

Exposure to benzene may result in effects to the hematopoietic system causing blood disorders including anaemia and leukaemia.Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.IARC assessment: benzene - carcinogenic to humans (Group 1)

Carcinogenic effects

Effects and symptoms

Chronic toxicity

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Mutagenic effects Contains material which may cause heritable genetic effects. (Benzene)

Other information Contains material which may cause birth defects based on animal data. (Toluene)

Excess exposure to vapors may produce headaches, dizziness, nausea, drowsiness, irritation of eyes,nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.

In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause these kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects. Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard. The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g., phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.

Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.

Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.

Gasoline: Additional toxicity information on components.

Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs.Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired color vision and decreased performance in some neurobehavioral tests.Prolonged high level exposure to toluene or xylene has caused some degree of hearing loss in experimental animals.Inhalation of very high concentrations of gasoline vapors and some of its components can result in cardiac sensitization and irregular heartbeats, leading to potentially fatal changes in heart rhythms.Injection of adrenaline-like agents may enhance this effect.

Ecological information

Ecotoxicity

12 .

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Biodegradability

Persistence/degradability The biodegradability of this material has not been determined.

Mobility

Bioaccumulative potential

Spillages may penetrate the soil causing ground water contamination.

This product is not expected to bioaccumulate through food chains in the environment.

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.

Disposal considerations13 .

The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal considerations /Waste information

No additional special precautions identified.Special Precautions for Landfill or Incineration

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14 . Transport information

International transport regulations

ADG Classification

Regulatory information

UN number Proper shipping name Class PG* Additional information

UN 1203 PETROL 3 II Hazchem code3YE

Initial emergency response guide14

Label

IMDG Classification

UN 1203 Gasoline or Motor Spirit.Marine pollutant

3 II Emergency schedules (EmS)F-E, S-E

-II3Gasoline or Motor SpiritUN 1203IATA/ICAO Classification

PG* : Packing group

No known special precautions required. See Section: "Handling and storage" for additional information.

Special precautions for user

Regulatory information15 .Standard for the Uniform Scheduling of Medicines and Poisons

5

ScheduleBenzene Schedule: 2. when used as a

feedstock containing more than 50% of benzene by volume

Other regulations

All components are listed or exempted.

Not determined.

At least one component is not listed.

Not determined.

At least one component is not listed.

Not determined.

Not determined.

Ingredient name

Control of Scheduled Carcinogenic Substances

Australia inventory (AICS)

Canada inventory

China inventory (IECSC)

Japan inventory (ENCS)

Korea inventory (KECI)

Philippines inventory (PICCS)

United States inventory (TSCA 8b)

REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.

Other information16 .

AMP = Acceptable Maximum PeakACGIH = American Conference of Governmental Industrial Hygienists, an agency that promulgates exposure standards.ADG = Australian Code for the Transport of Dangerous Goods by Road and RailADG Code = Australian Code for the Transport of Dangerous Goods by Road and RailCAS Number = Chemical Abstracts Service Registry NumberHAZCHEM Code = Emergency action code of numbers and letters which gives information to emergency services. Its use is required by the ADG Code for Dangerous Goods in bulk.ICAO = International Civil Aviation Organization.IATA = International Air Transport Association, the organization promulgating rules governing shipment of goods by air.IMDG = International Maritime Organization Rules, rules governing shipment of goods by water.IP 346 = A chemical screening assay for dermal toxicity. The European Commission has recommended that Method IP 346 be used as the basis for labelling certain lubricant oil base stocks for carcinogenicity. The EU Commission has stipulated that the classification as a carcinogen need

Key to abbreviations

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not apply if it can be shown that the substance contains less than 3% DMSO extract as measured by IP 346. (See Note L, European Commission Directive 67/548/EEC as amended and adapted.)DMSO is a solvent.NOHSC = National Occupational Health & Safety Commission, AustraliaTWA = Time weighted averageSTEL = Short term exposure limitUN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods.

History

Date of issue

Date of previous issue

Prepared by Product Stewardship

Notice to reader

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from us.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken.

05/10/2012.

10/02/2011.

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Automotive Diesel Fuel

SAFETY DATA SHEET

GHS product identifier

Section 1. Identification

Automotive Diesel Fuel

G10, BP 10 ppm diesel fuel,Ultra Low Sulphur diesel Fuel, Automotive Diesel Fuel AD 20 , AD40, ALPINE DIESEL, Biodiesel B5

Other means of identification

Manufacturer

Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616

www.bp.com.au

Technical Helpline Number: 1300 139 700

1800 638 556EMERGENCY TELEPHONE NUMBER

Fuel for compression ignition diesel engines.Use of the substance/mixture

0000002718Product code

0000002718SDS no.

AD0K1Historic SDS no.

Relevant identified uses of the substance or mixture and uses advised against

Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 4ACUTE TOXICITY (inhalation) - Category 4SKIN CORROSION/IRRITATION - Category 2CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bone marrow,liver and thymus) - Category 2ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word DANGER

Hazard statements H227 - Combustible liquid.H332 - Harmful if inhaled.H315 - Causes skin irritation.H351 - Suspected of causing cancer.H304 - May be fatal if swallowed and enters airways.H373 - May cause damage to organs through prolonged or repeated exposure.(bone marrow, liver, thymus)

Hazard pictograms

Precautionary statements

GHS label elements

General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.

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Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.

P260 - Do not breathe vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment.P273 -Avoid release to the environment.

Response P314 - Get medical attention if you feel unwell.P308 + P313 - IF exposed or concerned: Get medical attention.P304 + P340 + P312 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting.P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water.Take off contaminated clothing. Wash contaminated clothing before reuse.P332 + P313 - If skin irritation occurs: Get medical attention.

Storage P405 - Store locked up.P403 - Store in a well-ventilated place.P235 - Keep cool.

Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.

Other hazards which do not result in classification

This material may contain significant quantities of polycyclic aromatic hydrocarbons,some of which have been shown by experimental studies to induce skin cancer.Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency.See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data Sheet.

Supplemental label elements

Not applicable.

Section 3. Composition and ingredient information

Fuels, diesel > 95 68334-30-5Alkanes, C10-20-branched and linear 0 - 20 928771-01-1

Ingredient name CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

% (w/w)

May contain Fatty Acid Methyl Esters (FAME). May also contain small quantities of proprietary performance additives.Contains small quantities of polycyclic aromatic hydrocarbons (PAHs).

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.

If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Get medical attention.

Section 4. First aid measures

Eye contact

Inhalation

Description of necessary first aid measures

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Section 4. First aid measures

Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.

Skin contact

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful with extensive subcutaneous necrosis.Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes.

Specific treatments No specific treatment.

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed, if necessary

See Section 11 for more detailed information on health effects and symptoms.

Section 5. Firefighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.

Combustible liquid. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Suitable extinguishing media

Unsuitable extinguishing media

Do not use water jet.

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Section 5. Firefighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.

Special protective equipment for fire-fighters

Special protective actions for fire-fighters

Hazchem code 3z

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.

Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.

Large spill

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.

Small spill

Methods and material for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Avoid contact of spilt material and runoff with soil and surface waterways. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container.Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment.Use only non-sparking tools. Do not breathe vapour or mist. Avoid exposure -

Precautions for safe handling

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Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

As a precaution, tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging)and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks). Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.

obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not swallow. Aspiration hazard if swallowed.Can enter lungs and cause damage. Never siphon by mouth.

Fuels, diesel ACGIH TLV (United States). Absorbed through skin. TWA: 100 mg/m³, (measured as total hydrocarbons) 8 hours. Issued/Revised:1/2007 Form: Inhalable fraction and vapor

Section 8. Exposure controls and personal protection

Ingredient name Exposure limits

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.The final choice of protective equipment will depend upon a risk assessment. It is

Control parameters

Occupational exposure limits

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Section 8. Exposure controls and personal protection

Hand protection

Use with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory

Wear chemical resistant gloves.

Protective gloves must give suitable protection against mechanical risks (i.e.abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis.The frequency of replacement will depend upon the circumstances of use.

Chemical splash goggles.Eye/face protection

Respiratory protection

Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

important to ensure that all items of personal protective equipment are compatible.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Recommended: Nitrile gloves.

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Section 8. Exposure controls and personal protectionequipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Recommended: If ventilation is inadequate, use respirator that will protect against organic vapour and dust/mist.

Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337

Section 9. Physical and chemical properties

Physical state

Melting point

Vapour pressure

Relative density

Vapour density

Solubility

Liquid.

Not available.

Not available.

MildOdour

pH

Water white to straw including fluorescent green, blue or yellow.Colour

Evaporation rate Not available.

Auto-ignition temperature

Flash point

240°C (464°F)

Closed cup: >61.5°C (>142.7°F) [Pensky-Martens.]

Not available.

Not available.

Viscosity

Not available.Odour threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point 180 to 380°C (356 to 716°F)

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Lower: 0.5%Upper: 7.5%

Decomposition temperature Not available.

Not applicable. Based on - Physical state

0.1 kPa (0.755 mm Hg)

820 to 850 kg/m³ (0.82 to 0.85 g/cm³) at 15°C

Not available.

Kinematic: 2 to 4.5 mm2/s (2 to 4.5 cSt) at 40°C

0.83

Density

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.

Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.

Reactive or incompatible with the following materials: oxidising materials.

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Section 11. Toxicological information

Acute toxicity

Fuels, diesel LC50 Inhalation Dusts and mists Rat 4.1 mg/l 4 hours LD50 Dermal Rabbit >4300 mg/kg -LD50 Dermal Rabbit >4300 mg/kg -LD50 Oral Rat 17900 mg/kg -LD50 Oral Rat 7600 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Fuels, diesel Positive - Dermal -Unspecified

Mouse - 2 years

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary Suspected of causing cancer.

Mutagenicity

Fuels, diesel OECD 471 Experiment: In vitro PositiveSubject: Non-mammalian species

Equivalent to OECD 476

Experiment: In vitro Negative

Subject: Mammalian-AnimalCell: Germ

not guideline Experiment: In vivo NegativeSubject: UnspecifiedCell: Somatic

Product/ingredient name Test Experiment Result

Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.

Reproductive toxicity

Product/ingredient name Maternal toxicity

Fertility Developmental toxin

Species

Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are not met.Fertility: Not classified. Based on available data, the classification criteria are not met.Effects on or via lactation: Not classified. Based on available data, the classification criteria are not met.

Dose Exposure

Fuels, diesel - - Negative Rat Dermal 20 days- - Negative Rat Dermal 10 days- - Negative Rat Dermal 10 days

Irritation/Corrosion

Fuels, diesel Skin - Irritation Rabbit - - -Skin - Irritation Rabbit - - -Eyes - Non-irritating to the eyes.

Rabbit - - -

Eyes - Non-irritating to the eyes.

Rabbit - - -

Product/ingredient name Result Score Exposure Observation

Skin Causes skin irritation.

Sensitisation

Fuels, diesel skin Guinea pig Not sensitisingskin Guinea pig Not sensitising

Product/ingredient name Route of exposure

Species Result

Species

Information on toxicological effects

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Section 11. Toxicological information

Information on likely routes of exposure

Inhalation Harmful if inhaled.

Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.

Ingestion

Skin contact Causes skin irritation.

No known significant effects or critical hazards.Eye contact

May cause damage to organs through prolonged or repeated exposure. Vapour,mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer. Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.

General

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness

Adverse symptoms may include the following:nausea or vomiting

Adverse symptoms may include the following:irritationredness

Eye contact Adverse symptoms may include the following:pain or irritationwateringredness

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Specific target organ toxicity (repeated exposure)

Name Category

Fuels, diesel Category 2 Not determined bone marrow, liver and thymus

Aspiration hazard

Name Result

Fuels, diesel ASPIRATION HAZARD - Category 1Alkanes, C10-20-branched and linear ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Routes of entry anticipated: Oral, Dermal, Inhalation.

Potential acute health effects

Eye contact

Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer. Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.Vapour, mist or fume may irritate the nose, mouth and respiratory tract.

If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.

Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.

As with all such products containing potentially harmful levels of polycyclic aromatic hydrocarbons, prolonged or repeated skin contact may eventually result in dermatitis or more serious irreversible skin disorders including cancer.

Inhalation

Skin contact

Ingestion

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Section 11. Toxicological informationSuspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Carcinogenicity

No known significant effects or critical hazards.Mutagenicity

No known significant effects or critical hazards.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Numerical measures of toxicity

Inhalation (dusts and mists) 1.895 mg/l

Route ATE value

Acute toxicity estimates

Section 12. Ecological informationToxicity

Fuels, diesel EL50 >1000 mg/l Nominal Fresh water Micro-organism 40 hours NOELR 3.217 mg/l Nominal Fresh water

Micro-organism 40 hours

Acute EL50 22 mg/l Nominal Fresh water

Algae 72 hours

Acute EL50 210 mg/l Nominal Fresh water

Daphnia 48 hours

Acute EL50 68 mg/l Nominal Fresh water

Daphnia 48 hours

Acute ErL50 78 mg/l Nominal Fresh water

Algae 72 hours

Acute LL50 65 mg/l Nominal Fresh water

Fish 96 hours

Acute LL50 21 mg/l Nominal Fresh water

Fish 96 hours

Acute NOELR 10 mg/l Nominal Fresh water

Algae 72 hours

Acute NOELR 1 mg/l Nominal Fresh water

Algae 72 hours

Acute NOELR 46 mg/l Nominal Fresh water

Daphnia 48 hours

Chronic NOEL 0.083 mg/l Nominal Fresh water

Fish 14 days

Chronic NOELR 0.2 mg/l Nominal Fresh water

Daphnia 21 days

Product/ingredient name SpeciesResult Exposure

Conclusion/Summary Toxic to aquatic life with long lasting effects.

Persistence and degradability

Fuels, diesel OECD 301 F 60 % - Readily - 28 days 30 mg/l -OECD 301 F 57.5 % - Not readily - 28 days 25 mg/l -Equivalent to EPA OTS 796.3100

35 % - Not readily - 28 days 5 mg/l -

Product/ingredient name Test DoseResult Inoculum

Conclusion/Summary Non-persistent per IMO criteria

Partially biodegradable.

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Section 12. Ecological information

Mobility Spillages may penetrate the soil causing ground water contamination. This material may accumulate in sediments.

Bioaccumulative potential

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

This product is not expected to bioaccumulate through food chains in the environment.

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.

Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

Special Precautions for Landfill or Incineration

Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty packaging and should not be removed.

Section 14. Transport information

ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)

9

III

ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)

UN3082

9

III

UN3082

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards

Yes. Yes.

ADG

Not regulated.

-

-

-

No.

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Section 14. Transport informationThis product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.

Emergency schedules (EmS)F-A, S-F

This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.

Additional information

Special precautions for user

Transport in bulk according to Annex II of Marpol and the IBC Code

Not available.

MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gas oils, including ship's bunkers

Proper shipping name

RemarksCombustible liquid Class C1 (AS 1940).

Hazchem code3Z

Initial emergency response guide47

Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons

Model Work Health and Safety Regulations - Scheduled Substances

No listed substance

International lists

National inventory

REACH Status

Canada inventory All components are listed or exempted.

Australia inventory (AICS) All components are listed or exempted.

China inventory (IECSC) Not determined.

Japan inventory (ENCS) Not determined.

Korea inventory (KECI) Not determined.

Philippines inventory (PICCS)

Not determined.

For the REACH status of this product please consult your company contact, as identified in Section 1.

Taiwan Chemical Substances Inventory (TCSI)

All components are listed or exempted.

Not scheduled

Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.

United States inventory (TSCA 8b)

All components are listed or exempted.

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Section 16. Any other relevant information

07/04/2016

History

Date of printing

Date of issue/Date of revision

Version

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2

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1

Procedure used to derive the classification

Classification Justification

Flam. Liq. 4, H227 On basis of test dataAcute Tox. 4, H332 Calculation methodSkin Irrit. 2, H315 Calculation methodCarc. 2, H351 Calculation methodSTOT RE 2, H373 (bone marrow, liver and thymus) Calculation methodAsp. Tox. 1, H304 Calculation method

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.

Product Stewardship

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Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 35 of 39

12. Appendix D - Enviropacific Services Fuel Experience

Enviropacific Services has contributed to the success of hundreds of convenience store, service

station, truck stop, highway service centre and retail food projects throughout Australia. Since 1989

our architectural design abilities have been well known within the retail petroleum industry. Our

project list boasts major oil companies, government organisations and independent operators alike

and currently shows in excess of 900 projects, the vast majority of these Oil Industry projects.

As an experienced service station design consultancy, our clients have access to the latest ideas

and innovations as they happen within the industry. Enviropacific Services is at the forefront of

many of these innovations. We aim to give our clients “something special”, something the market

will notice and admire. The Enviropacific Services design skills and attention to detail has been

recognized by many BDAQ State and Regional Design Awards. We are currently working with

clients in Queensland, New South Wales and Victoria on numerous service station, convenience

store and highway service centre projects.

Fuel system design and services co-ordination is another area of extensive experience for

Enviropacific Services. We have delivered scores of highly successful projects. We were, for

example, engaged as fuel system designers for the four Major BP highway service centres

completed in 2001 in Queensland. These are some of the largest retail petroleum facilities in

Australia and have set a new benchmark for highway service centres in this country.

Enviropacific Services, as a registered nationwide building design practice, performs a Lead

Consultant role in most projects we are involved with. As a sub-consultant, we also provide

specialist service station and fuel system design and certification services. Another project role

Enviropacific Services performs is that of the architectural documentation consultant working within

the project design team, under the control of the leader consultant.

High quality project design coordination is a priority for all Enviropacific Services projects. All

services and design drawings from all consultants should read together without error or conflicting

information. This is our goal and although many acknowledge its importance, few actual achieve

consistent success. At Enviropacific Services coordination is not simply a concept – it is an

OBSESSION!

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 36 of 39

13. Appendix E - Enviropacific Services Fuel Industry Clients

Enviropacific Services oil Industry clients include (independent operators excluded):

• BP Australia • Caltex Australia • Pacific Petroleum

Products

• Avis Australia

• Air BP • Woolworths Ltd • United Petroleum • ECL Fuelquip

• Reliance

Petroleum

• Caltex Energy • Advance Petroleum • Gilbarco

• Westoil Petroleum • Central Petroleum

Queensland

• Independent Fuel

Supplies

• JF TA

• AA Petroleum • Matilda Petroleum • Ergon Energy • Tank Solutions

• Jasbe Petroleum • Qld Fuels Group • Energex • Lanskey

Constructions

• SEQ Fuel Supplies • Shell Australia (Go

Gas)

• Emerald Shire Council • Petroleum

Constructions

• Central Petroleum

Queensland

• Rampage Pty Ltd • Night Owl

Convenience Stores

• Castrol • Pacific Fuels • Swap n’ Go

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 37 of 39

14. Appendix G - Enviropacific Services Fuel Industry Projects

Below are details of a select number of Oil Industry projects that Enviropacific Services has provided

design services for:

Project Scope Client Site Scope of Services Project

Value

Brisbane Area

Fuel System Design BP Australia Pty

Ltd

Caboolture North & South Proposed twin highway

service centres & WBC

counter upgrades

$25m

Fuel System Design BP Australia Pty

Ltd

Coomera, Staplyton Proposed twin highway

service centres & WBC

counter upgrades

$25m

Lead Consultant BP Australia Pty

Ltd

Whinstanes, Hendra Office Fitouts $250k

Architectural

Design

BP Australia Pty

Ltd

Helensvale, Major Modifications $500k

Architectural

Design

Fuel System Design

BP Australia Pty

Ltd

Various Sites including Ferny

Grove, Springwood,

Maroochydore, Hamilton,

Virginia, Bribie Island, Palms

Corner, Oxenford, Morayfield,

Loganholme, Aspley,

Narangba, Labrador, Moggill

Road, Blacksoil, Nerang,

Chinderah South (NSW)

Connect Upgrades, Juice

Offers, Wild Bean

Upgrades, Major

Modifications, Raze &

Rebuilds, Café Zips

$30m

Fuel System

Certification

Woolworths

Petroleum

Various Sites including

Chermside, Bowen, Mackay,

Dalby, Noosaville, Gladstone,

Gympie

Fuel System License

Compliance Checks

$5m

Lead Consultant United

Petroleum

Ayr, Springfield, Crestmead,

Maryborough

New Service Station

Developments and Fuel

System Upgrades

$5m

Lead Consultant

Swap ‘N’ Go Hemmant LPG Cylinder Processing

Plant

-

Fuel System Design

Shell Engineering Tewantin, Burleigh Waters,

Victoria Point, Toowoomba,

Loganholme, Kallangur

Autogas Installation $1m

Lead Consultant South East

Queensland

Fuels

Yatala Proposed Truck Refuelling

Facility and Unmanned

Refuelling facility

$300k

Lead Consultant PHF East Brisbane, Wamuran Autogas and Pump &

Tank Layout

$1m

Master Planning Colin Loel

Architects

Gateway Motorway, Nundah Highway Service Centre $8m

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 38 of 39

Fuel System Design Pratt & Whitney Eagle Farm Fuel Farm and Spill Trench $500k

Fuel System Design PECC Burbank, Eagle Farm Proposed Diesel

Refuelling Facility

$250k

Lead Consultant Pinnaroo Estate Rainbow Waters Resort Multi Residential

Documentation

$25m

Lead Consultant Freedom Fuels Inala, Beenleigh, Acacia

Ridge

Food Offer Revitalisation $1m

Fuel System Design Caltex Carseldine Service Station $1m

Master Planning Hallmark

Properties

Plainland Highway Service

Centre

Highway Service Centre $6m

Sydney Area

Lead Consultant XL Development

Group

Newcastle Proposed Truck Stop $6m

Architectural

Design

Merino

Properties

Golburn Proposed Service Station

Development

$5m

Architectural

Design

Jasbe Petroleum Auburn, Silverwater, Oakes,

Baulkham Hills, Warwick Farm,

Lansvale, Willoughby

Raise & Rebuilds $10m

Lead Consultant Westoil

Petroleum

Young, Lithgow, Mudgee Retail Network Review &

Revitalisation

$3m

Fuel System

Designer

GOGAS

Australia

Strathfield, Terrigal, Berkshire

Park, Buladelah

Autogas Installation $500k

Melbourne Area

Lead Consultant Jasbe Petroleum Frankston (Big Pine) Proposed Service Station

Redevelopment

$2m

Lead Consultant Jasbe Petroleum Highbluff Proposed Service Station

Redevelopment

$1m

Lead Consultant AA Petroleum Pakenham Zip/Connect Upgrade $2m

Architectural

Documentation

and Coordination

BP Australia Pty

Ltd (MEL)

Standards ST29, ST31 Drawings -

Lead Consultant AA Petroleum Oakleigh, Burwood East Proposed Service Station

Redevelopment

$2.5m

Lead Consultant Morphic Capital Longworry Proposals for twin

Highway Service Stations

$12m

Architectural

Design

Jasbe Petroleum Supremacy, Lyndhurst, Service Station Interior

Fitouts

$10m

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW

Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 39 of 39

Lead Consultant Rampage

Enterprises Pty

Ltd

Rockbank Proposal for twin Highway

Service Stations

$15m

Fuel System Design Advance

Petroleum

Geelong Depot Upgrade to existing diesel

facility

$250k

Darwin Area

Architectural

Design

BP Australia Pty

Ltd

Nightcliff Raise & Rebuild -

Architectural

Design

BP Australia Pty

Ltd

Ludmilla Raise & Rebuild -

Architectural

Design

Gilbarco RAAF Base Tindal As Constructed $5.5m

Perth Area

Fuel System Design Cronin

Construction

Star Track Fuel System & Autogas

facilities

$500k

Townsville Area

Fuel System Design BP Australia Pty

Ltd

BP Cluden Truck stop Truck Stop $8m

Lead Consultant BP Australia Pty

Ltd

BP Express Aitkenvale Service Station $3m

Lead Consultant BP Australia Pty

Ltd

BP Southern gateway Service Station $1.5m

Please visit our Company Website at www.cadway.com.au for additional information about

Enviropacific Services, our expertise, experience and previous project involvement.