h & m chemical restrictions - 2009-12-14

Chemical Restrictions

Quality Department

14 December 2009

H&M Chemical Restrictions, 14 December 2009 2(52)

Index

General ................................................................................................... 3 Commitment............................................................................................4 More Information and Guidelines ................................................................4 Abbreviations and definitions in this document .............................................5

Part 1: Apparel/Accessories/Footwear/Interior Products ...................... 6 Textile (Natural & Synthetic), incl. pigment print ..........................................6 Leather ...................................................................................................8 Plastic, Rubber, Paint & Surface coating ......................................................9 Metal ....................................................................................................11 Paper & Wood ........................................................................................11 Fusing, Padding, Feather & Down .............................................................12 Glass & Crystal.......................................................................................12 Additional Requirements – all Material.......................................................13 Recycled Material ...................................................................................13

Part 2: Food Contact Products............................................................... 14 Requirements - all Food Contact Material...................................................14 Ceramic & Glass .....................................................................................14 Metal ....................................................................................................15 Paper & Board........................................................................................15 Plastic ...................................................................................................16 Wood ....................................................................................................18

Part 3: Cosmetic Products ..................................................................... 19 Cosmetic Products ..................................................................................19 Additional Requirements..........................................................................23

Part 4: Toys........................................................................................... 24 Additional Requirements..........................................................................24

Part 5: Electrical and Electronic Products.............................................. 25 Additional Requirements..........................................................................25

Part 6: Packaging .................................................................................. 26 Glass ....................................................................................................26 Metal ....................................................................................................26 Paper & Wood ........................................................................................26 Plastic, Rubber, Paint & Surface coating ....................................................27 Additional Requirements – all Material.......................................................28

Part 7: Restricted Substances in Production.......................................... 29

Appendix A - Restricted Substances and CAS no. .................................. 30 A.1. Apparel/Accessories/Footwear/Interior ...............................................30 A.2. Food Contact Products......................................................................35 A.3. Cosmetic Products ...........................................................................36 A.6. Packaging .......................................................................................38 A.7. Restricted Substances in Production ...................................................40

Appendix B - Test Methods.................................................................... 41 B.1. Apparel/Accessories/Footwear/Interior ...............................................41 B.2. Food Contact Products......................................................................44

Appendix C – Permitted Colorants in Cosmetic Products ....................... 46

Substance/Requirement Index ............................................................. 49


General

General

H&M has with concern for the health of customers as well as for the environment

and working conditions, established Chemical Restrictions for all H&M products.

H&M Chemical Restrictions consist of seven parts:

Part 1: Apparel/Accessories/Footwear/Interior Products

Part 2: Food Contact Products

Part 3: Cosmetic Products

Part 4: Toys

Part 5: Electrical and Electronic Products

Part 6: Packaging

Part 7: Restricted Substances in Production

The Apparel/Accessories/Footwear/Interior Products and Food Contact Products

are divided into materials. The restrictions in Part 1 also applies to Part 2, 4 and 5

products. If the product is sold in a packaging, it must also comply with part 6. All

products must comply with Part 7. Each limit in H&M Chemical Restrictions is

valid for homogeneous parts of the concerned product.

Individual restricted substances with CAS no are specified in Appendix A.

Test methods are found in Appendix B.

All details on your product must comply with H&M Chemical Restrictions, see

example below for a padded jacket, a water bottle and a lip gloss. The examples

do not claim to be complete.

Apparel/Accessories/Footwear/Interior Products

� Fabric & lining: Follow Textile restrictions in Part 1 � Painted zipper & press buttons: Follow Metal restrictions in Part 1

for the metal. Follow the Plastic, Rubber, Paints & Surface coating restrictions in Part 1 for the paint.

� Drawstring, stoppers & possible placement print: Follow Plastic,

Rubber, Paints & Surface coating restrictions in Part 1

� Padding: Follow Fusing, Padding, Feather and Down

restrictions in Part 1

Food Contact Products

� Lid and bottle: Follow Plastic, Rubber, Paints & Surface coating restrictions in Part 1

� PE lid: Follow PE plastic restrictions in Part 2

� PP bottle: Follow PP plastic restrictions in Part 2

Cosmetic Products

� Lip gloss: Follow restrictions for cosmetic products in Part 3. � Lid and bottle: Follow restrictions for packaging in Part 6.


General

Commitment

When signing H&M Standard Purchase Conditions Compliance Commitment, the

H&M supplier commits to comply with H&M Chemical Restrictions. It is the

supplier’s responsibility to inform all their downstream suppliers and

subcontractors about the content of the restrictions and to assure compliance.

By signing H&M Standard Purchase Conditions Compliance Commitment, each

supplier acknowledges that H&M reserves the right to:

� Check any product, any part of production and/or packaging, by any listed/appropriate method, at any time or stage of production.

� Cancel the ordered product or, if already delivered, return the goods if the product, production and/or packaging do not correspond to the restrictions.

� Hold the manufacturer/exporter responsible for any damage caused by the ordered product if the product, production and/or packaging do not

correspond to the restrictions.

� Receive the complete product information and Material Safety Data Sheets (MSDS) about all products (dyes, colorants, solvents, chemicals etc.) included

in the production of a specific order and/or batch.

In the case of contradictory test result, H&M’s test result will prevail.

More Information and Guidelines

Part 1, Apparel/Accessories/Footwear/Interior Products

Information about the restricted substance and guidelines on how to work

proactively with fulfilling H&M Chemical Restrictions is found in the

“Implementation Toolkit for H&M Chemical Restrictions – Part 1

Apparel/Accessories/Footwear/Interior products”.

Part 2, Food Contact Products

Guidelines on how to work with Food Contact Products, as well as information

about Good Manufacturing Practice (GMP) and labelling is found in

“Implementation Toolkit for H&M Chemical Restrictions – Part 2 Food contact

products”.

Part 3, Cosmetic Products

Guidelines on how to work with Cosmetic Products, as well as information product

information files, ingredient lists, Good Manufacturing Practice (GMP), etc. is

found in “Implementation Toolkit for H&M Chemical Restrictions – Part 3 Cosmetic

Products”.

Part 4, Toys

More information is found in “H&M Safety Requirements for Baby’s and Children’s

wear” and “H&M Quality Standards and Requirements”.

Part 6, Packaging

More information is found in “H&M PIM – Packing Instructions Manual”.

Part 7, Restricted Substances in Production

This part of the Chemical Restrictions is assured in cooperation between the

Quality Assurance and CSR department.


General

Abbreviations and definitions in this document

CAS no Chemical Abstracts Service number, an identification number for

chemicals in this database.

cfu Colony forming units. The content of bacteria, mould and yeast in a

product is measured by counting the number of colonies formed in

the sample. This is the unit for this counting.

CI no Colour Index number

cl Centilong

cSt centiStokes, which is the same as 1mm2/s. This is the unit used for

kinematic viscosity.

GMP Good Manufacturing Practice

Homogeneous Uniform composition throughout, i.e. a material that can not be

mechanically disjointed into different materials.

IU International Unit. A unit used when measuring vitamins.

Kinematic

viscosity

Describes how fast a fluid is spread on a flat surface in relation to its

mass, i.e. weight.

Organoleptic Refers to any sensory property of a product, including smell, taste,

colour and feel.

ppm Parts per million, which is the same as mg/kg.

REACH Registration, Evaluation, Authorisation and restriction of Chemicals

Reporting limit The lowest concentration at which an analyte is reported.

SML Specific Migration Limit in food or in food simulants.

SML(T) Total Specific Migration Limit in food or in food simulant. SML(T) is

the maximum permitted amount of a given substance originating

from the release of several given substances from a material or

article into food or a food stimulant.

SVHC Substances of Very High Concern

Usage ban Means that the substance must not be added to the product nor

used in production.


Part 1 Apparel/Accessories/Footwear/Interior Products

Part 1: Apparel/Accessories/Footwear/Interior Products

If a group of substances is marked with an asterisk* in the table below each included substance is

specified in Appendix A.1.

Textile (Natural & Synthetic), incl. pigment print

Restricted substance Limit

Alkylphenol Ethoxylates / Alkylphenols (APEO/AP)

Nonylphenol Ethoxylates (NPE) 100 ppm

Octylphenol Ethoxylates (OPE) 100 ppm

Nonylphenol (NP) Not detected

Octylphenol (OP) Not detected

Cationic Surfactants* Not detected, sum of listed surfactants

Chlorinated Aromatic Hydrocarbons* 2 ppm, per listed substance group

Chloroparaffins

Short chained (SCCPs) C10-C13 Not detected

Medium chained (MCCPs) C14-C17 1000 ppm

Chromium VI (Cr6+) Not detected

Dyes

Azo Dyes & Pigments* 20 ppm, per listed amine

Disperse Dyes* 1 mg/l extract, per listed disperse dye

Other Dyes* Not detected, per listed other dye

Flame Retardants*1 Not detected

Formaldehyde

Products for children aged 0-3 years, incl. bed linen (e.g. 50-98 cl)

(A-A0)<0.052

Products for children above 3 years (e.g. 104-170 cl) and products for adults with direct skin contact,

incl. bed linen

75 ppm

Products for adults without direct skin contact (e.g. outer wear, curtains)

300 ppm

1 Supplier must always get an approval from H&M before using any flame retardant, even if it is not listed in Appendix A.1. No flame retardants are allowed on babies’ and children’s products.

2 Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured according to test method.




Metals, Extractable Amount

Antimony (Sb) 30 ppm3

Arsenic (As) 0.2 ppm

Chromium (Cr) 1 ppm4

Cobalt (Co) 1 ppm

Copper (Cu) 25 ppm5

Lead (Pb) 0.2 ppm

Mercury (Hg) 0.02 ppm

Nickel (Ni) 1 ppm

Metals, Total Amount

Antimony (Sb) 260 ppm3

Arsenic (As) 1 ppm

Cadmium (Cd) 1 ppm

Chromium (Cr) 100 ppm4

Lead (Pb) 90 ppm


Octamethylcyclotetrasiloxane 1000 ppm

Organotin Compounds*

Dibutyltin (DBT) 1 ppm

Dioctyltin (DOT) 1 ppm

Sum of other listed organotins Not detected

Sum of other not listed tri-substituted

organotins

1 ppm

Perfluoro Compounds

Perfluorooctane Sulfonate (PFOS) and

PFOS related substances

1 µg/m2

Perfluorooctanoic Acid (PFOA) 1 µg/m2

Pesticides*

Dieldrine 0.01 ppm

Sum of listed pesticides <1 ppm

pH 4.0 ≤ pH ≤ 7.5

Phenols

Pentachlorophenol (PCP) and its salts and

esters

Not detected

Tetrachlorophenol (TeCP) and its salts

and esters

Not detected

o-Phenylphenol (OPP) 50 ppm

Phthalates* 500 ppm, per phthalate.

The sum of phthalates ≤ 1000 ppm

3 For 100% polyester the total Sb limit applies (for 50% polyester the limit is 130 ppm etc.). For all other textile materials the extractable Sb limit applies.

4 For polyamide, polyamide blends (min 5% PA) and worsted wool the extractable Cr limit applies.

For all other materials, chromium based dyes are not accepted, and the total Cr limit applies. 5 Extractable Cu limit applies only to woven baby wear up to size 98




Polychlorinated Biphenyls (PCB)

Polychlorinated Triphenyls (PCT)

The sum < 0.5 ppm

Polyvinylchloride (PVC)

and similar chlorinated polymers, e.g.

Polyvinylidenchloride

Not detected

Triclosan Not detected

Leather







Chlorinated Aromatic Hydrocarbons* 2 ppm, per listed substance group

Chloroparaffins




Dyes

Azo Dyes & Pigments* 20 ppm, per listed amine

Other Dyes* Not detected, per listed other dye


Formaldehyde

Products for children aged 0-3 years (e.g. 50-98 cl) 20 ppm


incl. bed linen

75 ppm


300 ppm


Cobalt (Co) 1 ppm

Nickel (Ni) 1 ppm

6 Supplier must always get an approval from H&M before using any flame retardant at all, even if it is not listed in Appendix

A.1. No flame retardants are allowed on babies’ and children’s products.





Arsenic (As) 1 ppm

Cadmium (Cd) 1 ppm

Lead (Pb) 90 ppm







organotins

1 ppm

Pesticides*

Dieldrine 0.01 ppm

Sum of listed pesticides <1 ppm

Perfluoro Compounds



1 µg/m2


Phenols


esters

Not detected


and esters

Not detected




The sum < 0.5 ppm

Plastic, Rubber, Paint & Surface coating7







Bisphenol-A (BPA) Not detected

Chloroparaffins



7 Surface coating includes paint and print, excluding reactive print and electroplating.




Dimethylformamide (DMF) 100 ppm


Formaldehyde


(A-A0)<0.059


incl. bed linen

75 ppm


300 ppm

Isocyanates* Not detected, sum of listed isocyanates

Metals, Total amount

Cadmium (Cd) 75 ppm

Lead (Pb) 90 ppm

Mercury (Hg) 10 ppm






organotins

1 ppm

Phenols


esters

Not detected


and esters

Not detected


Phthalates* 500 ppm, per phthalate


Polyaromatic Hydrocarbons (PAH) *

Benzo(a)pyrene 1 ppm

Sum of other listed PAHs The sum < 10 ppm



The sum < 0.5 ppm


And similar chlorinated polymers, e.g.


Not detected


8 Supplier must always get an approval from H&M before using any flame retardant at all, even if it is not listed in Appendix A.1. No flame retardants are allowed on babies’ and children’s products.




Metal



Cadmium (Cd) 75 ppm

Lead (Pb):

Decorative10 items 90 ppm

Functional11 items 300 ppm


Nickel (Ni), Extractable Amount

In metal products or parts of products in direct and prolonged skin contact

Maximum release: 0.5 µg/cm2/week

In metal jewellery parts intended to be used for body piercing

Maximum release: 0.2 µg/cm2/week

Paper & Wood


Formaldehyde 150 ppm


Cadmium (Cd)

Lead (Pb)

Mercury (Hg)

Chromium VI (Cr6+)

Sum ≤ 100 ppm

Perfluoro Compounds



1 µg/m2


Phenols


esters

Not detected




Not detected

10 Decorative items are items that are not needed for a specific function, for example jewelleries. 11 Functional items are items needed for a specific function, for example belt buckles, buttons, zippers and rivets used to strengthen seems.



Fusing, Padding, Feather & Down







Cationic Surfactants* Not detected, sum of listed surfactants

Feather and Down

Products filled with down and/or feathers

Oxygen index number12 20

Mesophil aerobic bacteria count <1 000 000 CFU/g

Faecal streptococci count <100 CFU/g

Sulphite reducing clostridium count <100 CFU/g

Presence of salmonella Absent in 20 g


Formaldehyde


(A-A0)<0.0514

Products for children above 3 years (e.g. 104-170cl) and products for adults with direct skin contact, incl. bed linen

75 ppm


300 ppm







organotins

1 ppm

Phthalates* 500 ppm per phthalate


Glass & Crystal

For children (0-14 years):

Glass or Crystal may not be used in baby’s and children’s wear according to the “H&M

Safety Requirements for baby’s and children’s wear size 44-170 cl”

For adults:

Glass or Crystal that exposes humans to unsafe amounts of Lead (Pb), considering worst case

scenario, i.e. if swallowed, may not be used.

12 If the oxygen index number is ≤ 20, no further analysis of the microbiological state is necessary 13 Supplier must always get an approval from H&M before using any flame retardant at all, even if it is not listed in Appendix A. No flame retardants are allowed on babies’ and children’s products.




Additional Requirements – all Material

Requirement/Restricted

substance

Limit/Requirement

Anti bacterial treatment in the

finished product

Supplier must get an approval from H&M before using

anti bacterial treatment, even if it is not listed in

Appendix A.

Dimethylfumarate (DMFu) Not detected

Discolouration No change in colour caused by chemicals

Mineral Oils Mineral oils with a kinematic viscosity below

7 cSt (40°C) are not allowed

Mould Spores and mycelia of mould not detected

Odour Grade 2 - not unpleasant

REACH SVHC Usage ban for all substances listed on the Candidate List

of Substances of Very High Concern (SVHC).

Check the ECHA website for the updated list15

Recycled Material

For recycled materials16, the restrictions are the same as for other materials, with below mentioned

exceptions. These exceptions are only valid for orders where H&M explicitly specify on the product

that recycled material is used.

Restricted substance Details of exception

Alkylphenol Ethoxylates /

Alkylphenols (APEO/AP) *

Provided that no additional APEO has been used

after the collection of the waste, the APEO-

restriction does not apply.

Cationic Surfactants* Provided that no additional banned cationic

surfactants have been used after the collection of

the waste, the restriction about cationic

surfactants does not apply.


Chromium (Cr) Provided that no additional Chromium dyes have

been used after the collection of the waste, the

restriction about total chromium does not apply.

The restriction for extractable Chromium applies,

regardless of waste type.

15 http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp

16 Recycled materials is both pre- and post-consumer waste defined as follows: Pre-consumer waste: The reintroduction of manufacturing scrap, such as waste from textile production, back into the yarn manufacturing process. Post-consumer waste: A waste produced by the end consumer of a material stream such as used PET bottles or worn out garments.


Part 2 Food Contact Products

Part 2: Food Contact Products

Materials and articles intended to come in contact with food must comply with the EU framework

regulation no 1935/2004. The following restrictions and requirements are a summary and also

additions to the EU legislation on specific substances.

Food contact products must also fulfil Part 1.

If a group of substances is marked with an asterisk* in the table below each included substance is

specified in Appendix A.1 or Appendix A.7. For all other CAS no see Appendix A.2.

Requirements - all Food Contact Material

Requirement Limit/Requirement

Good Manufacturing Practice (GMP)

Food contact products must be produced according to GMP – Good manufacturing Practice, EC

2023/2006. Consult H&M Implementation toolkit Part 2 for more information.

REACH SVHC

Usage ban for all substances listed on the Candidate List of Substances of Very High Concern

(SVHC).


Sensory test No change in smell or taste of food

Ceramic & Glass

Must comply with 84/500/EC Council Directive of 15 October 1984, relating to

ceramic articles intended to come into contact with foodstuffs.


Cadmium (Cd) Cat 1. 0.07 mg/dm2

Cat 2. 0.3 mg/l

Cat 3. 0.1 mg/l

Lead (Pb) Cat 1. 0.8 mg/dm2

Cat 2. 4.0 mg/l

Cat 3. 1.5 mg/l

Cat 1. Objects which can be filled and objects that can not be filled, whose internal depth

measured between the lowest point and the horizontal plane passing through the upper edge is

less than or equal to 25 mm

Cat 2. Fillable objects other than 1) packaging or storage containers with a capacity up to 3 l 2)

Cooking utensils

Cat 3. Cooking utensils; packaging and storage containers with a capacity up to 3 l.

Cobalt (Co) 0.1 mg/l

Lead (Pb), Cadmium (Cd) (Drinking Rim

Area)

Pb: 2mg/l

Cd: 0.2 mg/l




Metal


Aluminium (Al)

(only for Al-container in contact with fruit

juices)

8 ppm

Cadmium (Cd) 0.005 mg/dm2

Chromium (Cr) 0.45 mg/dm2

Lead (Pb) 0.01 mg/dm2

Nickel (Ni) 0.1 mg/dm2

Paper & Board


Antimicrobial Effect No release of anti-microbial substances

Azo Dyes & Pigments* 20 ppm

Cadmium (Cd) 0.5 ppm

Chromium VI (Cr6+)

Chromium III (Cr3+)

Not detected

4 µg/dm2

Colour Fastness Fastness Grade 5 (Grey scale accd. EN 20105)

Di-isobutyl Phthalate (DIBP) Migration 1 ppm

Diisopropylnaphthalene (DIPN) 50 ppm

Formaldehyde 1 mg/dm2

Glyoxal 1.5 mg/dm2

Lead (Pb) 3 ppm


Organoleptic test No change in the composition of the food or its

organoleptic properties.

Pentachlorophenol (PCP) Not detected

Polychlorinated Biphenyls (PCB) 2 ppm

Primary Aromatic Amines Release Not detected (0.02 ppm)



Plastic


All Plastics

Must comply with 2002/72/EC on plastic materials that come into contact with food,

and its amendments.

Global Migration 10 mg/dm2

PAH* content

0.2 ppm

0.2 to 10 ppm18: Test specific migration PAH.19

Specific Migration PAH* 5 µg/kg

Specific Migration Phthalates*

BBP: 30 ppm

DEHP: 1.5 ppm

DBP: 0.3 ppm

DINP/DIDP: 9 ppm

ODP/DnDP/DnOP: 5 ppm

Acetal Resins

Boron (B) 0.008 %

Zinc (Zn) 1 %

Acryl Resins

Peroxide Not detected

Volatile Organic Matter (VOM) 0.5 %

Melamine Resins

Specific Migration Formaldehyde 15 ppm

Specific Migration Melamine 30 ppm

Phenolic Resins

Specific Migration Formaldehyde 15 ppm

Polyamide (PA)


Specific Migration Caprolactam 15 ppm

Specific Migration Primary Aromatic

Amines

0.01 ppm per simulant

Polyethylene (PE)

Chromium (Cr) 10 ppm


Vanadium (V) 20 ppm

18 Fail test result if PAH content is >10 ppm 19 Compliant test result if specific migration result is ≤5 µg/kg




Zirconium (Zr) 100 ppm

Polyethylene Terphthalate (PET)

Total Lead (Pb) 40 ppm as PbO

Total Zinc (Zn) 1 %

Polyoxymethylene (POM)

Boron (B) 0.008 %

Zinc (Zn) 1%

Polypropylene (PP)

Chromium (Cr) 10 ppm

Hafnium (Hf) 100 ppm


Vanadium (V) 20 ppm

Zirconium (Zr) 100 ppm

Polystyrene (PS)


Volatile Organic Matter (VOM) 15 mg/dm2

Polyurethane (PU)

Isocyanates* 1 ppm NCO


Primary Aromatic Amines Release 0.01 ppm

Rubber

Organotin Compounds* Not detected

Specific Migration Formaldehyde 3 ppm (aqueous solution only)


Amines

50 µg/l

Total Lead (Pb) For rubber: 0.003%

For rubber with mouth contact: 0.001%

Zinc (Zn) 1 %

Silicone

Extractable Matter 0.5 %





Volatile Organic Matter (VOM) 0.5 %

Temperature Resistant Coatings

Specific Migration Chromium VI (Cr6+) Not detected

Specific Migration Chromium III (Cr3+) Not detected

Specific Migration Formaldehyde 15 mg/dm2

Specific Migration Lithium (Li) 0.5 mg/extract

Specific Migration Perfluorooctanoic Acid

(PFOA)

0.005 mg/dm2

Specific Migration Phenolic Substances*

0.05 mg/dm2


Amines

0.01 mg/dm2

Thermoplastic Elastomer (TPE)

Specific Migration Formaldehyde 3 ppm (Aqueous simulants only)

Zinc (Zn) 1%

Wood


Pentachlorophenol (PCP) Not detected

Polychlorinated biphenyls (PCB)* 15 ppm

Specific Migration of Formaldehyde and

Hexamethylenetetramine

SML(T) 15 ppm


Part 3 Cosmetic Products

Part 3: Cosmetic Products

All cosmetic products must comply with the EU Cosmetic Regulation20. The following restrictions

and requirements are an addition to this regulation.

Only the Permitted Colorants in Appendix C should be used in Cosmetic Products.

For CAS no see Appendix A.3.

Cosmetic Products


Acetanilide

in all types of products except when used to

stabilize hydrogen peroxide

Usage ban

to stabilize hydrogen peroxide 0.4 %

Adenosine

in all types of products except anti wrinkle

products

Usage ban

in anti wrinkle products 0.1 %

Aloe Barbadensis (Aloe Vera Gel) Shall not contain any Anthraquinone Glycosides

Antimony (Sb)

in all types of products except glitter products

with polyester ingredient

Total content: 10 ppm

in glitter products with polyester ingredient Total content, except the polyester ingredient:

10 ppm

Polyester ingredient (i.e. glitter flakes) Total content: 260 ppm

Arachis Hypogaea Oil/Flour21

(Peanut oil/flour and all other substances

containing traces of peanut)

Shall not contain any Cyanogen bounds.

Arsenic (As) Total content: 5 ppm

Beta-sitosterol

in all types of products except skin creams Usage ban

in skin creams 0.1 %

Cadmium (Cd) Total content: 5 ppm

Camphor 3 %

Chlorofluorocarbon propellants

(halogenated alkanes)

Usage ban

Chromium (Cr) Total content: 10 ppm


CI 77288 Usage ban

20 The regulation was adopted on the 30 November 2009, but not yet published at the time of this publication. 21 Supplier must inform H&M before use of any peanut containing substance.




CI 77289 Usage ban

Cinnamyl Anthranilate Usage ban

Cobalt (Co) Total content: 10 ppm

Cyclomethicone Usage ban

Cyclopentasiloxane Usage ban

Formaldehyde Usage ban

in all types of products originated from

Formaldehyde releasers22

<0.05 % (500 ppm)

free or possible release of formaldehyde

(calculated content)23

Formaldehyde releasers22, i.e. some

preservatives

in leave-on products for face Usage ban

in leave-on products for children under 3

years of age

Usage ban

Fragrance Allergens,

as defined in EU Cosmetic Regulation

The calculation of the concentration of the fragrance allergens shall take into account all possible

sources of the fragrance allergens. I.e. not only the perfume and/or aroma can contribute to the

concentration of them. Possible other sources include, but are not limited to, ingredients, herbal

extracts and essential oils.

in all deodorants and anti-perspirants aimed

to be used under arms

0 fragrance allergens to be labelled on product.

in all children’s products Max 4 fragrance allergens to be labelled on

product.

in all leave-on products except children’s

products

Max 6 fragrance allergens to be labelled on

product.

in all rinse-off products except children’s

products

Max 8 fragrance allergens to be labelled on

product.

Lead (Pb) Total content: 5 ppm

Melaleuca Alternifolia Oil (Tea Tree Oil)24

in oral hygiene products 0.5 %

in all types of products except oral hygiene

products

2.0 %

Mercury (Hg) Total content: 1 ppm

Methylchloroisothiazolinone/

Methylisothiazolinone (MCI/MI),

(Kathon CG)

Usage ban

Methylisothiazolinone (MI) Usage ban

22 Formaldehyde releasers are for example: 2-Bromo-2-Nitropropane-1,3-Diol, Diazolidinyl Urea, DMDM Hydantoin,

Imidazolidinyl Urea. The manufacturer must always control with their raw material supplier if the preservative used is a Formaldehyde releaser. If it is the raw material supplier will give them all necessary information.

23 0.05% (500 ppm) free or possible release of formaldehyde (calculated content) demands the warning: “Contains formaldehyde”.

24 Shall not be used in products for children below 12 years.




Methyl Salicylate

in all types of products except mouth water

and skin cream products

Usage ban

in mouth water 0.05 %

in skin creams 1.0 %

Nickel (Ni) Total content: 10 ppm

2-Nitro-1,4-Benzenediamine or

2-Nitro-p-Phenylenediamine

Usage ban

4-Nitro-1,2-Benzenediamine or

4-Nitro-o-Phenylenediamine

Usage ban

See also EU Cosmetic regulation.

Nitrosamines Shall not be formed during the lifetime of the

product.

Nonylphenol Ethoxylates (NPE)

and its degradation products

Usage ban

Octylphenol Ethoxylates (OPE)

and its degradation products

Usage ban

Phenylmercuric salts

(including borate)

Usage ban

Phenyl Salicylate

in all types of products except oral hygiene

products

Usage ban

in oral hygiene products 1.5 %

Phthalates

except Diethyl Phthalate

Usage ban

Prunus Armeniaca Kernel Oil

(Apricot kernel oil)

Shall not contain any Cyanogen bounds

Residual Monomers

e.g. Acrylamide, Acrylates

Shall not be in the product.

Residual Solvents

e.g. Benzene, Toluene

Shall not be in the product.

Retinol (Vitamin A) 10 000 IU/g equals 0.3 %

Retinyl Palmitate (Vitamin A) 10 000 IU/g equals 0.7 %

Salicylic Acid25

when used as a preservative See EU Cosmetic Regulation

in all types of products except when used as

a preservative

2.0 %

Sucralfate

in all types of products except skin products Usage ban

in skin products 2 %

Symphytum Officinale (Comfrey) Shall not contain any Pyrrolizidine Alkaloids

Talc Must at least be of cosmetic purity grade

See also EU Cosmetic regulation

Thimerosal Usage ban

25 See EU Cosmetic Regulation.




Thioctic Acid

in all types of products except anti wrinkle

products

Usage ban

in anti wrinkle products 5 %

Toluene Usage ban

1,1,1-Trichloroethane Usage ban

Triclosan Usage ban

Urea 10 %

Products intended to be diluted >10 %

Viscum Album

in all types of products except shampoos Usage ban

in shampoo 0.1 %

Vitamins (e.g. Vitamin E)

except Vitamin A, C and D

5.0 %

Xanthin derivatives

e.g. Caffeine, Theophylline,

Aminophylline, Theobromine and

Methylsilanol

3.0 %



Additional Requirements

Requirement/Restricted substance Limit/Requirement

Fragrance Oils All fragrance oils must fulfil IFRA standard.

Good Manufacturing Practice (GMP)

Must follow ISO 22716:2007 Cosmetics – GMP – Good Manufacturing Practices.

Microbiological Quality26

For products specifically intended to be used in the eye area27, on mucous membranes28, or for

children under 3 years:

Total viable count for Aerobic Mesophyllic

microorganisms

<100 CFU/g or ml

in 0.5 g or 0.5 ml of the product

Pseudomonas aeruginosa

Staphylococcus aureus

Candida albicans

not detected


For other products than those specified above:

Total viable count for Aerobic Mesophyllic

microorganisms

<1 000 CFU/g or ml


Pseudomonas aeruginosa

Staphylococcus aureus

Candida albicans

not detected


Product Information files (PI-files)

All products must have a complete PI-file.

Stability test To deliver, stability test must be OK after 12 w.

Total stability test period is 52 w. Report to H&M

if any deviation is found.

26 Test method: ISO 21149:2009, ISO 22717:2009, ISO 22718:2009, ISO 18416:2009 27 Eye area includes eye lid, eye lashes, and the area below the eye down to the cheek bone. 28 Mucous membranes include the intimate/genital area and the oral cavity of the mouth.


Part 4 Toys

Part 4: Toys

Toys must comply with the European Standard EN 71. Below is a summary of the chemical

restrictions and requirements that have to be fulfilled for toys. This table does not claim to be

complete.

Toys must also fulfil Part 1.

Restricted substance CAS no Limit Test method

Extractable Metals See EN 71-3 See EN 71-3 See EN 71-3

Flame Retardants See EN 71-9 See EN 71-9 EN 71-10 & 11

Colorants See EN 71-9 See EN 71-9 EN 71-10 & 11

Primary Aromatic

Amines

See EN 71-9 See EN 71-9 EN 71-10 & 11

Monomers See EN 71-9 See EN 71-9 EN 71-10 & 11

Solvents – Migration See EN 71-9 See EN 71-9 EN 71-10 & 11

Solvents – Inhalation See EN 71-9 See EN 71-9 EN 71-10 & 11

Wood Preservatives See EN 71-9 See EN 71-9 EN 71-10 & 11

Preservatives See EN 71-9 See EN 71-9 EN 71-10 & 11

Plasticizers - Migration See EN 71-9 See EN 71-9 EN 71-10 & 11



REACH SVHC Usage ban for all substances listed on the Candidate

List of Substances of Very High Concern (SVHC).




Part 5 Electrical and Electronic Products

Part 5: Electrical and Electronic Products

Electrical and Electronic Products must comply with the EU directive 2002/95/EC (RoHS)30,

which is closely linked to the EU directive 2002/96/EC (WEEE)31. Below table is a summary of

RoHS directive and it does not claim to be complete.

Electrical and Electronic Products must also fulfil Part 1.

Restricted substance CAS no Limit Test method

Lead (Pb) 7439-92-1 1000 ppm EN 62321

Cadmium (Cd) 7440-43-9 100 ppm EN 62321

Mercury (Hg) 7439-97-6 1000 ppm EN 62321

Chromium VI (Cr6+) 7440-47-3 1000 ppm EN 62321

Polybrominated Diphenyl

Ethers (PBDE) and

Polybrominated Biphenyls

(PBB)

Various 1000 ppm EN 62321






30 EU directive 2002/95/EC – Directive on the Restriction of the use of certain Hazardous Substances in electrical and electronic equipment (RoHS) 31 EU directive 2002/96/EC – Directive on Waste Electrical and Electronic Equipment (WEEE) 32 http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp


Part 6 Packaging

Part 6: Packaging

Below restrictions and requirements are valid for all packaging that the customer brings home

with the product.

The container/packaging33 of cosmetic products is considered to be a part of the cosmetic

product. Therefore it must comply with both EU Cosmetic Regulation and below restrictions and

requirements.

If a group of substances is marked with an asterisk* in the table below each included substance

is specified in Appendix A.6.

Glass


Total Lead (Pb) 100 ppm

Metal


Metal containers/packages

for cosmetic products

Not corrode, i.e. must be of non-corroding material

Metals, total amount

Cadmium (Cd) 75 ppm

Lead (Pb) 300 ppm


Paper & Wood



Metals, Total amount

Cadmium (Cd)

Lead (Pb)

Mercury (Hg)

Chromium VI (Cr6+)

Sum ≤ 100 ppm

Perfluoro Compounds



1 µg/m2


Phenols


esters

Not detected

33 The container/packaging of cosmetic products includes both primary and secondary packaging, but excludes transportation packaging.


Part 6 Packaging





Not detected

Plastic, Rubber, Paint & Surface coating







Bisphenol-A (BPA) Not detected

Dimethylformamide (DMF) 100 ppm



Cadmium (Cd) 75 ppm

Lead (Pb) 90 ppm

Mercury (Hg) 10 ppm






organotins

1 ppm

Phenols


esters

Not detected

Tetrachlorophenol (TeCP) and its salts and

esters

Not detected


Phthalates* 500 ppm, per phthalate




The sum < 0.5 ppm




Not detected



Part 6 Packaging

Additional Requirements – all Material

Requirement/Restricted

substance

Limit/Requirement

Cobalt Dichloride34 Not detected

Dimethylfumarate35 (DMFu) Not detected

Discolouration No change in colour caused by chemicals


Fumigation No fumigation of raw materials or finished product is

allowed36

Mould Spores and mycelia of mould not detected

Odour Grade 2 - not unpleasant

No release of any substance to the content Primary container/package

for cosmetic products Not react in any way with the content, i.e. must be

inert




34 Mainly used in silica gel. 35 Mainly used in humidity reducing sachets. 36 If supplier believes fumigation is necessary, contact H&M. More info and restrictions regarding fumigation can be found in “H&M PIM – Packing Instruction Manual”.



Part 7 Restricted Substances in Production

Part 7: Restricted Substances in Production

Certain substances are especially harmful for the workers and/or the environment. Following

substances are therefore restricted to use in production.

If a group of substances is marked with an asterisk* in the table below each included substance

is specified in Appendix A.7.

Requirement/Restricted substance Limit/Requirement

Alkylphenol Ethoxylates /

Alkylphenols (APEO/AP)*

Usage ban

Usage ban Chlorinated Bleaching Agents

Finishing treatments with chlorinated bleaching

agents can be used in denim production only.

Glues

Solvent based systems shall be exchanged to water based systems.38

Organic Solvents In glues, spot removers, paints, lacquers etc.

Benzene (Benzol)

1,4-Butanediol

Dimethylacetamide (DMAC)

Dimethylformamide (DMF)

Ethylene glycol monoethyl ether

n-Hexane

4,4’methylenebis(2-chloraniline)

(MOCA)

Methylene chloride

Phenol

Tetrachloroethylene (PERC)

Tetrachloromethane

Trichloroethylene (TRIS)

Usage ban

Toluene (Toluol) Usage ban in glues

Sand Blasting

The abrasive material must contain less than 1% crystalline silica, i.e. quartz, trydimite

and christobalite.

38 Supplier must always get an approval from H&M before using any non-water based systems.


Appendix A – Restricted Substances and CAS numbers

Appendix A - Restricted Substances and CAS no.

This is an overview of the restricted substances with known CAS numbers. Substance groups

marked with an asterisk* in the Part 1-7 are specified here.

A.1. Apparel/Accessories/Footwear/Interior

Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) Name CAS no.

Nonylphenol Ethoxylates (NPE) Various

Octylphenol Ethoxylates (OPE) Various

Nonylphenol (NP) 25154-52-3

Octylphenol (OP) 27193-28-8

Azo Dyes & Pigments Name CAS no.

4-Aminodiphenyl 92-67-1

Benzidine 92-87-5

4-Chloro-o-toluidine 95-69-2

2-Naphthylamine 91-59-8

o-Aminoazotoluene 97-56-3

2-Amino-4-nitrotoluene 99-55-8

2,4-Diaminoanisole 615-05-4

4,4’-Diaminodiphenylmethane 101-77-9

3,3’-Dichlorobenzidine 91-94-1

3,3’-Dimethoxybenzidine (o-Dianisidine) 119-90-4

3,3’-Dimethylbenzidine (o-Tolidine) 119-93-7

3,3’-Dimethyl-4,4’-diaminodiphenylmethane 838-88-0

p-Chloroaniline 106-47-8

p-Cresidine 120-71-8

4,4’-Methylene-bis-(2-chloroaniline) 101-14-4

4,4’-Oxydianiline 101-80-4

4,4’-Thiodianiline 139-65-1

2,4-Toluenediamine 95-80-7

o-Toluidine 95-53-4

2,4,5-Trimethylaniline 137-17-7

o-Anisidine 90-04-0

p-Aminoazobenzene 60-09-3

2,4-Xylidine 95-68-1

2,6-Xylidine 87-62-7

Bisphenol-A (BPA) Name CAS no.

BPA 80-05-7

Cationic Surfactants Name CAS no.

Distearyldimethyl ammouniumchloride (DSDMAC) 107-64-2

Ditallowdimethyl ammoniumchloride (DTDMAC) 68783-78-8

Dihydrogenated tallowdimethyl ammouniumchloride (DHTDMAC)

61789-80-8

Chlorinated Aromatic Hydrocarbons Name CAS no.

Chlorobenzenes Various

Chloronaphthalenes Various

Chlorotoluenes Various

Chloroxylenes Various

Chloroparaffins Name CAS no.

Short chained (SCCPs) C10-C13 85535-84-8

Medium chained (MCCPs) C14-C17 85535-85-9



Chromium VI (Cr6+) Name CAS no.

Cr6+ 18540-29-9

Dimethylformamide (DMF) Name CAS no.

Dimethylformamide (DMF) 68-12-2

Dimethylfumarate (DMFu) Name CAS no.

Dimethylfumarate (DMFu) 624-49-7

Disperse Dyes Name CI NO CAS no.

Disperse Blue 1 64 500 2475-45-8

Disperse Blue 3 61 505 2475-46-9

Disperse Blue 7 62 500 3179-90-6

Disperse Blue 26 63 305 3860-63-7

Disperse Blue 35 12222-75-2




Disperse Brown 1 23355-64-8

Disperse Red 1 11 110 2872-52-8

Disperse Red 11 62 015 2872-48-2

Disperse Red 17 11 210 3179-89-3

Disperse Orange 1 11 080 2581-69-3



Disperse Orange 37 11 132 12223-33-5

Disperse Orange 76 (previously designated Orange 37) 51811-42-8

Disperse Orange 149 85136-74-9

Disperse Yellow 1 10 345 119-15-3




Disperse Yellow 39 12236-29-2

Disperse Yellow 49 54824-37-2

Flame Retardants Name CAS no.

Tris(2,3-dibromopropyl)phosphate (TRIS) 126-72-7

Bis(2,3-dibromopropyl)phosphate 5412-25-9

Tris-(aziridinyl)-phosphineoxide (TEPA) 5455-55-1

Polybrominated Diphenyl Ethers (PBDE) Various

Tetrabromobisphenol A (TBBP A) 79-94-7

Polybrominated Biphenyls (PBB) Various

Tri-o-cresyl phosphate 78-30-8

Tris(2-chloroethyl)phosphate (TCEP) 115-96-8

Hexabromocyclododecane 3194-55-6

2,2-Bis(bromomethyl)-1,3-propanediol 3296-90-0

Tris(1,3-dichloroisopropyl)phosphate (TDCP) 13674-87-8

Triphenyl phosphate (TPhP) 115-86-6

Formaldehyde Name CAS no.

Formaldehyde 50-00-0



Isocyanates Name CAS no.

Diphenylmethane diisocyanate (MDI) 101-68-8

Hexamethylene diisocyanate (HMDI) 822-06-0

Isophorone diisocyanate (IPDI) 4098-71-9

Tetramethylxylene diisocyanate (TMXDI) 2778-42-9

2,4-Toluene diisocyanate (2,4 TDI) 2,6-Toluene diisocyanate (2,6 TDI)

584-84-9 91-08-7

Metals Name CAS no.

Antimony (Sb) 7440-36-0

Arsenic (As) 7440-38-2

Cadmium (Cd) 7440-43-9

Chromium (Cr) 7440-47-3

Cobalt (Co) 7440-48-4

Copper (Cu) 7440-50-8

Lead (Pb) 7439-92-1

Mercury (Hg) 7439-97-6

Nickel (Ni) 7440-02-0

Octamethylcyclotetrasiloxane Name CAS no.

Octamethylcyclotetrasiloxane 556-67-2

Organotin Compounds Name CAS no.

Dibutyltin (DBT) 1002-53-5

Dioctyltin (DOT) -

Tributyltin (TBT) 56573-85-4

Tricyclohexyltin (TCyHT) 6056-50-4

Trioctyltin (TOT) 250252-89-2

Triphenyltin (TPhT) 668-34-8

Tripropyltin (TPT) -

Other tri-substituted organotins Various

Other Dyes Name CI NO CAS no.

Acid Red 26 16 150 3761-53-3

Basic Red 9 42 500 569-61-9

Basic Violet 14 45 510 632-99-5

Direct Black 38 30 235 1937-37-7

Direct Blue 6 22 610 2602-46-2

Direct Brown 95 30 145 16071-86-6

Direct Red 28 22 120 573-58-0

Solvent Yellow 1 11 000 60-09-3



p-Phenylenediamine 76 060 106-50-3

Perfluoro Compounds Name CAS no.

Perfluorooctane Sulfonate (PFOS) and PFOS related substances

Various

Perfluorooctanoic Acid (PFOA) 335-67-1

Pesticides Name CAS no.

Aldrine 309-00-2

Captafol 2425-06-1

Chlordane 57-74-9

Chlordecone (Kepon) 143-50-0

Chlordimerform 6164-98-3

Chlorobenzilate 510-15-6

DDD 72-54-8

DDE 72-55-9



Pesticides Name CAS no.

DDT 50-29-3

Dibromochloropropane (DBCP) 96-12-08

Dieldrine 60-57-1

Dinoseb 88-85-7

DTTB-(Timiperone) 57648-21-2

Endrine 72-20-8

Endosulphane 115-29-7, 33213-65-9

Ethylene dibromide 106-93-4

Heptachlor 76-44-8

Heptachloroepoxide 1024-57-3

Hexachlorobenzene 118-74-1

α-Hexachlorcyclohexane 319-84-6

β-Hexachlorcyclohexane 319-85-7

δ-Hexachlorcyclohexane 319-86-8

Lindane (γ-Hexachlorcyclohexane) 58-89-9

Isodrin 465-73-6

Kelevane 4234-79-1

Metamidophos 10265-92-6

Methoxychlor 72-43-5

Mirex 2385-85-5

Monocrotophos 6923-22-4

Monomethyldibromodiphenylmethane 99688-47-8

Monomethyldichlorodiphenylmethane -

Monomethyltetrachlorodiphenylmethane 76253-60-6

Parathion 56-38-2

Parathion-methyl 298-00-0

Perthane (Ethylane) 72-56-0

Phosphamidone 13171-21-6

Quintozene 82-68-8

Strobane 8001-50-1

Telodrin (Isobenzan) 297-78-9

Toxaphene (Camphechlorine) 8001-35-2

Halogenated biphenyls with the formula C12HnX10-n x=halogen, n=1,2,...9

Various

Halogenated terphenyls with the formula C18HnX14-n x=halogen, n=1,2,...13

Various

Halogenated naphthalenes with the formula C10HnX8-n x=halogen, n=1,2,...7

Various

2-(2,4,5-Trichlorophenoxy) propionic acid and its salts and 2-(2,4,5-Trichlorophenoxy) propionyl compunds (2,4-D)

Various

2,4,5-Trichlorophenoxyacetic acid and its salts and 2,4,5-Trichlorophenoxyacetyl compounds (2,4,5-T)

Various

Phenols Name CAS no.

Pentachlorophenol (PCP) and its salts and esters 87-86-5

Tetrachlorophenol (TeCP) and its salts and esters 58-90-2, 25167-83-3

o-Phenylphenol (OPP) 90-43-7

Phthalates Name CAS no.

Di-isononyl phthalate (DINP) 28553-12-0

Di(ethylhexyl) phthalate (DEHP) 117-81-7

Di-n-octyl phthalate (DNOP) 117-84-0

Di-iso-decyl phthalate (DIDP) 26761-40-0

Butyl benzyl phthalate (BBP) 85-68-7

Dibutyl phthalate (DBP) 84-74-2

All other phthalates (all other esters of o-phthalic acid Various

Polyaromatic Hydrocarbons (PAH) Name CAS no.

Benzo(a)pyrene 50-32-8

Benzo(e)pyrene 192-97-2

Benzo(a)anthracene 56-55-3

Chrysene 218-01-9

Benzo(b)fluoranthene 205-99-2



Polyaromatic Hydrocarbons (PAH) Name CAS no.

Benzo(j)fluoranthene 205-82-3

Benzo(k)fluoranthene 207-08-9

Dibenzo(a,h)anthracene 53-70-3

Naphthalene 91-20-3

Acenaphthylene 208-96-8

Acenaphthene 83-32-9

Fluorene 86-73-7

Phenanthrene 85-01-8

Anthracene 120-12-7

Fluoranthene 206-44-0

Pyrene 129-00-0

Benzo(g,h,i)perylene 191-24-2

Indeno(1,2,3-c,d)pyrene 193-39-5

Polychlorinated Compounds Name CAS no.

Polychlorinated Biphenyls (PCB) 1336-36-3

Polychlorinated Triphenyls (PCT) 61788-33-8

Polyvinylchloride (PVC) Name CAS no.

Polyvinylchloride (PVC) 9002-86-2

Polyvinylidenchloride 9002-85-1

Triclosan Name CAS no.

Triclosan 3380-34-5



A.2. Food Contact Products

Restricted Substance

Name CAS no.

Aluminium (Al) 7429-90-5

Bisphenol-A (BPA) 7440-43-9

Boron (B) 7440-42-8


Caprolactam 105-60-2


Chromium III (Cr3+) 16065-83-1

Chromium VI (Cr6+) 18540-29-9

Cobalt (Co) 7440-48-4

Diisopropylnaphthalene 38640-62-9


Glyoxal 107-22-2

Hafnium (Hf) 7440-58-6

Hexamethylenetetramine 100-97-0

Lead (Pb) 7439-92-1

Lithium (Li) 7439-93-2

Melamine 108-78-1


Nickel (Ni) 7440-02-0

Pentachlorophenol (PCP) 87-86-5



Vanadium (V) 7440-62-2

Zinc (Zn) 7440-66-6

Zirconium (Zr) 7440-67-7



A.3. Cosmetic Products


Name CAS no.

Acetanilide 103-84-4

Adenosine 58-61-7

Aloe Barbadensis 85507-69-3

Antimony (Sb) 7440-36-0

Arachis Hypogaea Oil/Flour 8002-03-7

Arsenic (As) 7440-38-2

Beta-sitosterol 83-46-5


Camphor 76-22-2

Chlorofluorocarbon propellants Various


Chromium VI (Cr6+) 18540-29-9

CI 77288 1308-38-9

CI 77289 12001-99-9

Cinnamyl Anthranilate 87-29-6

Cobalt (Co) 7440-48-4

Cyclomethicone 69430-24-6

Cyclopentasiloxane 541-02-6


Formaldehyde releasers e.g.: Various e.g.:

2-Bromo-2-Nitropropane-1,3-Diol 52-51-7

Diazolidinyl Urea 78491-02-8

DMDM Hydantoin 6440-58-0

Imidazolidinyl Urea 39236-46-9

Fragrance allergens:

See EU Cosmetic Regulationfor all substances. Various, see EU Cosmetic Regulation

Lead (Pb) 7439-92-1

Melaleuca Alternifolia Oil 85085-48-9


Methylchloroisothiazolinone/Methylisothiazolinone (MCI/MI), also called Kathon CG

26172-55-4/2682-20-4

Methylisothiazolinone (MI) 2682-20-4

Methyl Salicylate 119-36-8

Nickel (Ni) 7440-02-0

2-Nitro-1,4-Benzenediamine or 2-Nitro-p-Phenylenediamine

5307-14-2

4-Nitro-1,2-Benzenediamine or 4-Nitro-o-Phenylenediamine

99-56-9

Nitrosamines Various



Phenylmercuric salts (including borate) Various

Phenyl Salicylate 118-55-8

Phthalates, except Diethyl Phthalate (DEP, CAS no. 84-66-2):







All other phthalates (all other esters of o-phthalic acid except Diethyl Phthalate (DEP, CAS no 84-66-2)

Various

Prunus Armeniaca Kernel Oil 72869-69-3

Residual Monomers e.g.: Various e.g.:

Acrylamide 79-06-1

Methyl acrylate 96-33-3

Ethyl acrylate 140-88-5

Butyl acrylate 141-32-2

Residual Solvents e.g.: Various e.g.:

Benzene 71-43-2

Toluene 108-88-3

Retinol (Vitamin A) 68-26-8/11103-57-4

Retinyl Palmitate (Vitamin A) 79-81-2

Salicylic Acid 69-72-7

Sucralfate 54182-58-0



Restricted Substance Name CAS no.

Symphytum Officinale (Comfrey) 84696-05-9

Talc 14807-96-6

Thioctic Acid 1077-28-7

Thimerosal 54-64-8

Toluene 108-88-3

1,1,1-Trichloroethane 71-55-6

Triclosan 3380-34-5

Urea 57-13-6

Viscum Album 84929-55-5

Vitamins, except Vitamin A, C and D, e.g.: Various e.g.:

Vitamin B1, thiamine 59-43-8

Vitamin B2, riboflavin 83-88-5

Vitamin B6, adermine 8059-24-3

Vitamin B12 68-19-9

Vitamin E, tocopherol 59-02-9/ 119-13-1/ 1406-18-4/ 10191-41-0

Vitamin K 58-27-5/ 84-80-0/ 11104-38-4/ 12001-79-5

Biotin, Vitamin B7/H 58-85-5

Folic acid, L-Glutamic acid 59-30-3

Niacin, Vitamin B5 59-67-6

Pantothenic acid, Vitamin B3/B5 79-83-4

Xanthin derivates e.g.: Various e.g.:

Aminophylline 317-34-0

Caffeine 58-08-2

Theobromine 83-67-0

Theophylline 58-55-9

Methylsilanol Various



A.6. Packaging

Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) Name CAS no.





Bisphenol-A (BPA) Name CAS no.

BPA 80-05-7

Dimethylformamide (DMF) Name CAS no.


Dimethylfumarate (DMFu) Name CAS no.

Dimethylfumarate (DMFu) 624-49-7

Formaldehyde Name CAS no.


Isocyanates Name CAS no.

Diphenylmethane diisocyanate (MDI) 101-68-8

Hexamethylene diisocyanate (HMDI) 822-06-0

Isophorone diisocyanate (IPDI) 4098-71-9

Tetramethylxylene diisocyanate (TMXDI) 2778-42-9

2,4-Toluene diisocyanate (2,4 TDI) 2,6-Toluene diisocyanate (2,6 TDI)

584-84-9 91-08-7

Metals Name CAS no.



Lead (Pb) 7439-92-1


Organotin Compounds Name CAS no.

Dibutyltin (DBT) 1002-53-5

Dioctyltin (DOT) -

Tributyltin (TBT) 56573-85-4

Tricyclohexyltin (TCyHT) 6056-50-4

Trioctyltin (TOT) 250252-89-2

Triphenyltin (TPhT) 668-34-8

Tripropyltin (TPT) -

Other tri-substituted organotins Various

Perfluoro Compounds Name CAS no.

Perfluorooctane Sulfonate (PFOS) and PFOS related substances

Various


Phenols Name CAS no.

Pentachlorophenol (PCP) and its salts and esters 87-86-5

Tetrachlorophenol (TeCP) and its salts and esters 58-90-2, 25167-83-3

o-Phenylphenol (OPP) 90-43-7



Phthalates Name CAS no.







All other phthalates (all other esters of o-phthalic acid Various

Polychlorinated Compounds Name CAS no.


Polychlorinated Triphenyls (PCT) 61788-33-8

Polyvinylchloride (PVC) Name CAS no.

Polyvinylchloride (PVC) 9002-86-2

Polyvinylidenchloride 9002-85-1

Triclosan Name CAS no.

Triclosan 3380-34-5



A.7. Restricted Substances in Production


Name CAS no.

Organic Solvents:

Benzene (Benzol) 71-43-2

1,4-Butanediol 110-63-4

Dimethylacetamide (DMAC) 127-19-5


Ethylene glycol monoethyl ether 110-80-5

n-Hexane 110-54-3

4,4’methylenebis(2-chloraniline) (MOCA) 101-14-4

Methylene chloride 75-09-2

Phenol 108-95-2

Tetrachloroethylene (PERC) 127-18-4

Tetrachloromethane 56-23-5

Trichloroethylene (TRIS) 79-01-6

Toluene (Toluol) 108-88-3

Alkylphenol Ethoxylates / Alkylphenols (APEO/AP):






Appendix B - Test methods

Appendix B - Test Methods

B.1. Apparel/Accessories/Footwear/Interior


Test Method Reporting Limit

Textiles, leather: Methanol/CAN extraction followed by LC-MS

50 mg/kg

APEO Plastic, prints: THF/ACN extraction followed by LC-MS

50 mg/kg

Textiles, leather: Methanol/CAN extraction followed by GC/MS

5 mg/kg

AP Plastic, prints: THF/ACN extraction followed by GC-MS

5 mg/kg

Bisphenol-A Solvent extraction and analysis by GC-MS

0.2 mg/kg

Cationic Surfactants Methanol extraction and analysis by LC-MS

10 mg/kg

Chlorinated Aromatic Hydrocarbons

Draft DIN 54232: 2007-07 Solvent extraction followed by GC-MS analysis

0.2 mg/kg

Chloroparaffins (SCCP and MCCP)

N-hexane extraction, ultra sound (40C, 30min) and analysis by GC-MS using NCI (Negative Chemical Ionization)

100 mg/kg

Leather: DIN EN 17075: 2008-02 Aging test: Draft CEN/TC 309 WG 2N 90: 2007-10

3 mg/kg

Chromium VI (Cr6+) Paper: Total metal content by microwave digestion with HNO3/H2O2 and ICP-MS analysis, confirmation analysis by CEN/TS 14495

3 mg/kg

Dimethylformamide Ultrasound extraction using ethylacetate followed by GC-MS analysis

10 mg/kg

Dimethylfumarate DIN and CEN Draft BVCPS Germany Solvent extraction, GC/MS analysis

0.03 mg/kg

Dyes

Textiles in general: EN 14362-1:2003

10 mg/kg

Polyester textiles: EN 14362-2:2003

10 mg/kg

Leather: ISO/DIS 17234-1 ISO/DIS 17234-2

10 mg/kg

Azo Dyes & Pigments

Detection of p-Aminoazobenzene: LFBG B 82.02-9

10 mg/kg

Disperse Dyes

DIN 54231: 2005-11 BVL B 82.02-10: 2007-03

1 mg/l

Other Dyes

DIN 54231 BVL B 82.02-10: 2007-03 Except for p-phenylenediamine: Methanol extraction and analysis by GC-MS

1-5 mg/l





TRIS, Bis(2,3-dibromopropyl) phosphate: Methanol extraction and analysis with GC-MS

10 mg/kg

TEPA: Potassium Hydroxide digestion followed by GC-MS Headspace analysis of Ethyleneimine

10 mg/kg

PBDEs, TBBP A: Acetonitril extraction and analysis by LC-DAD-MS and confirmation with GC-MS

10 mg/kg 10 mg/kg

Flame Retardants

PBBs, Tri-o-cresyl phosphate, TCEP, Hexabromocyclododecane, 2,2-Bis(bromomethyl)-1,3-propanediol, TDCP, TPhP: Methanol extraction and analysis by GC-MS

10 mg/kg (GC)

Textile, non-woven, prints: Products for children 0-3 years, incl. bed linen: JIS L 1041-1983, Method A

(A-A0) < 0,02

39 (5 mg/kg)

Textile, non-woven, prints: Products for children above 3 years and products for adults with direct skin contact incl. bed linen: ISO 14184-1

16 mg/kg

Leather: ISO 17226-2

20 mg/kg

Formaldehyde

Paper: EN 645 and EN 1541

20 mg/kg

Isocyanates ISO 10283

3 mg/kg

Draft DIN 5433-3 Extractable with artificial sweat solution by ISO 105-E04 Metal content by ICP-MS analysis

Reporting limit: 0.1 mg/kg Except Hg/Cd: 0.02 mg/kg


Nickel: Nickel release by EN 1811. Abrasion of coated items by EN 12472:2005 + A1:2009

0.05 µg/cm2/week

Total metal content by microwave digestion with HNO3/H2O2 and ICP-MS analysis

Cd, Pb,Cr,Sb, As: 1 mg/kg Hg: 0.1 mg/kg

Metals, Total Metal Lead in paint and surface coating: CPSIA Section 101 16 CFR 1303: CPSIA Standard Operating Procedure for Determining Lead in Paint

Mineral Oils Not applicable , check physical data info on the MSDS

Mould Test

1. Smell test SNV 195651

2. Light microscope analysis for suspicious spots 3. Staining with lactophenol blue followed by microscope analysis

1. Suspicious smell/

no suspicious smell 2. Little spots 3. Spores and mycelia of mould detected/not detected

Odour

Smell test done according to: SNV 195 651

1. no odour 2. slight odour, not unpleasant 3. endurable odour, slightly unpleasant 4. pestering odour, unpleasant 5. insufferable odour, very unpleasant

Octamethyl cyclotetrasiloxane Contact H&M

50 mg/kg

Organotin Compounds Ethanol extraction, derivatisation and analysis by GC-MS

0.05 mg/kg

39 Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured according to test

method.





Organic Solvents Extraction with ethylacetate followed by GC-MS screening and/or headspace-GC/MS analysis

1 mg/kg

Perfluoro Compounds

Draft CEN/TS 15968 Methanol extraction and analysis by LC/MS or LC/MS/MS

1 µg/m2

Pesticides

U.S. EPA Method 8081a, 8151a, 8141a & 8270 c or Analysis of organochloro pesticides by GC-MS or LC-MS

0.2 mg/kg

pH

ISO 3071-1980 Specify in the test report which solution (water or KCl) that has been used.

Textile, plastics, paper: BVL B 82.02-08 (modified) PCP, TeCP: Potassium Hydroxide extraction direct LC-MS analysis

PCP: 0.05 mg/kg TeCP: 0.05 mg/kg

OPP: BVL B 82.02-08 (modified) Acetone extraction, derivatisation followed by GC-MS analysis

5 mg/kg

Phenols

Leather: BVL B 82.02-08 (modified) PCP, TeCP, OPP: Acetone extraction, derivatisation followed by GC-MS analysis

PCP: 0.05 mg/kg TeCP: 0.05 mg/kg

Textile articles (surface coating): ISO 15777

Depends on the matrix

Phthalates

All other materials: Extraction with THF/CAN and analysis by HPLC-DAD-MS, confirmation test for DBP using GC-MS

50 mg/kg

PCB, PCT Solvent extraction and analysis by GC-MS 0.1 mg/kg

0.5 mg/kg

Polyaromatic Hydrocarbons (PAH)

ZEK 01_02-08 Extraction with toluene followed by GC-MS analysis

0.2 mg/kg

PVC Beilsteins test and infrared spectroscopy (IR) with or without chemical separation

qualitative

Triclosan Solvent extraction, derivatisation followed by GC-MS analysis

10 mg/kg



B.2. Food Contact Products


Test Method

Sensory Test

EN 10955 in combination with EN 1230.1 & 2

Global Migration

EN 1186-1 to 15

Specific Migration

CEN/TS 13130

Bisphenol-A EN 13130-13

Caprolactam EN 13130-16

Chromium (Cr) EN 13130 + ICP/MS

Chromium VI (Cr6+) EN 13130 + photometric detection

Formaldehyde EN 13130-23

Formaldehyde and Hexamethylenetetramine EN 13130-23

Lithium (Li) EN 13130 + ICP/MS

Melamine EN 13130-27

Organotin Compounds EN 1186-1 + ICP/MS, if detected – derivatisation + GC/MS

Perfluorooctanoic Acid (PFOA) EN 13130 + LC/MS

Phenolic Substances EN 13130 + photometric detection

Phthalates EN 13130 + GC/MS resp. LC/MS

Polyaromatic Hydrocarbons (PAH) EN 13130 + GC/MS

Primary Aromatic Amines

EN 13130 xx (draft). Photometric determination and identification with GC/MS resp. LC/MS

Metals

Aluminium (Al) EN 1388-1, ICP/MS

Boron (B) Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS

Cadmium (Cd) Paper and Board: EN 12498 Ceramics and Glass: EN 1388-1 and-2, 84/500/EEC, Drinking rim area: DIN 51031 Metals: EN 1388-1, ICP/MS

Chromium VI (Cr6+) Chromium III (Cr3+)

DIN 17075 EN 645 + ICP-MS

Cobalt (Co) According to EN 1388-1 and -2

Hafnium (Hf) Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS

Lead (Pb) Paper and Board: EN 12498 and EN645 [cold water extract] & EN647 [hot water extract] Ceramics and Glass: EN 1388-1 and-2, 84/500/EEC, Drinking rim area: DIN 51031 Metals: EN 1388-1, ICP/MS Plastic: Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS

Mercury (Hg) EN 12497

Nickel (Ni) EN 1388-1, ICP/MS

Vanadium (V) Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS

Zinc (Zn) Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS

Zirconium (Zr) Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS




Test Method

Other Test Methods

Antimicrobial Effect EN 1104

Azo Dyes & Pigments EN 14362 part 1 & 2, LFGB ASU 82.02-8

Di-isobutyl Phthalate (DIBP) Migration DIN PREN 14719

Diisopropylnaphthalene (DIPN) DIN PREN 14719

Extractable Matter Gravimetric

Formaldehyde EN 645 + EN 1541

Glyoxal DIN 54603

Isocyanates EN 13130-8 modified

Organoleptic Test EN 1230-1 and -2 in combination with EN 10955

Organotin Compounds DIN 38407-13

Pentachlorophenol (PCP) LFBG 82.02.8

Peroxide Ph. Eur. Method 2.5.5

Polyaromatic Hydrocarbons (PAH) ZEK 01.2-08 (Harmonized method of the Central district for information exchange of accredited institutions in accordance with EN 1186 ff)

Polychlorinated Biphenyls (PCB) ISO 15318

Primary Aromatic Amines Release EN 1186-1

Volatile Organic Matter (VOM) Gravimetric Method (90°C, 24 hrs)


Appendix C - Permitted Colorants in Cosmetic Products

Appendix C – Permitted Colorants in Cosmetic Products

All substances listed below are permitted as colorants in Cosmetic Products under the specific

restrictions and requirements laid down.

The numbers under the column “Field of application” mean:

1) Colouring agents permitted in all cosmetics products.

2) Colouring agents permitted in all cosmetics products, except those intended for use in the area of eye (eye lid, eye lashes and area below the eye down to the cheek bone).

3) Colouring agents permitted only in externally applied cosmetic products. They should not intend to come into contact neither with the mucous membrane (includes the intimate/genital area and the oral cavity of the mouth) nor with the lips.

4) Colouring agents permitted only in externally applied cosmetic products, except those intended for use in the area of

eye. They should not intend to come into contact neither with the mucous membrane nor with the lips.

Field of Application41 Permitted Colorants40

Colour

1 2 3 4

Other Requirements42

CI 10316 43 Yellow X See also 21 CFR 74.2707a. All lakes are permitted as the ordinary colour, see 21 CFR 82.2051.

CI 12085 43 Red X Maximum level in the finished cosmetic product should not exceed 3.0%. Also permitted in lip products at a maximum level of 3.0% in the finished product. See also 21 CFR 74.2336. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 14700 Red X See also 21 CFR 74.2304. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051 and 21 CFR 82.51.

CI 15510 43 Orange X See also 21 CFR 74.2254. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 15800 Red X See also 21 CFR 74.2331. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

Red X See also 21 CFR 74.2306. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 15850 43, 44

Red X See also 21 CFR 74.2307. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.


CI 15985 43 Yellow X E 110. See also 21 CFR 74.2706. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051 and 21 CFR 82.51.

CI 16035 Red X Shall not be exposed to oxidising or reducing agents or any other condition that may affect their integrity. The aluminium lake of this colour is permanently permitted in cosmetics intended for use in the area of the eye. See also 21 CFR 74.2340.

40 Permitted colorants are named by their CI no. or other commonly used denomination. The lakes and salts of the permitted colorants, using substances not prohibited in Annex II or not regulated in Annex V of EU Cosmetic Regulation, are also permitted except if otherwise specified under the headline “Other requirements”.

41 If there is no cross in the columns below the headline “Field of application” appropriate restrictions and conditions of use will be found under the headline “Other requirements”.

42 Colorants whose number is preceded by the letter “E” in accordance with the EU Directive of 1962 concerning foodstuffs and colouring matters must fulfil the purity requirements laid down in those Directives. They continue to be subject to the general criteria set out in Annex III to the 1962 Directive concerning colouring matters where the letter “E” has been deleted there from. See also EU Cosmetic Regulation Annex IV for more information about the limitations and purity requirements in Europe for each colorant specified above.

43 The insoluble Barium, Strontium and Zirconium lakes, salts and pigments of these colorants shall also be permitted. They must pass test for insolubility, which will be determined by the procedure laid down in Article 8 in the EU Cosmetic Regulation.

44 This colorant has two different names as a certified colorant in USA. Therefore this colorant has two different criteria regarding purity, other requirements, limitations and field of application.




Colour

1 2 3 4


CI 17200 43 Red X Also permitted in lip products at a maximum level of 3.0% in the finished product. And permitted in mouthwashes (including breath fresheners) and dentifrices. See also 21 CFR 74.2333. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 19140 43 Yellow X E 102. The aluminium lake of this colour is permanently permitted in cosmetics intended for use in the area of the eye. See also 21 CFR 74.2705. All other lakes are permitted in all cosmetics, except those intended for use in the area of the eye, see 21 CFR 82.1051 and 21 CFR 82.51.

CI 40800 Orange X See also 21 CFR 73.2095.

CI 42053 Green X See also 21 CFR 74.2203. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051 and 21 CFR 82.51.

Blue X See also 21 CFR 74.2104. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 42090 44

Blue X The aluminium lake of this colour is permanently permitted in cosmetics intended for use in the area of the eye. See also 21 CFR 74.2101. All other lakes are permitted in all cosmetics, except those intended for use in the area of the eye, see 21 CFR 82.1051 and 21 CFR 82.51.

Yellow X Maximum level in the finished cosmetic product should not exceed 6%. See also 21 CFR 74.2707. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 45350 44

Yellow X Maximum level in the finished cosmetic product should not exceed 6%. See also 21 CFR 74.2708. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 45370 43 Orange X Also permitted in lip products at a maximum level of 5.0% in the finished product. And permitted in mouthwashes and dentifrices that are to be ingested.

Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and

2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid.

See also 21 CFR 74.2255. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

Red X Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and

2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2321. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 45380 43, 44





CI 45410 43, 44



Red X Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 3% 2-(iodo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid.


CI 45425 44

Red X Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 3% 2-(iodo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid.


CI 47000 Yellow X See also 21 CFR 74.2711.




Colour

1 2 3 4


CI 47005 Yellow X E 104. See also 21 CFR 74.2710. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 59040 Green X Maximum level in the finished cosmetic product should not exceed 0.01%. See also 21 CFR 74.2208.

CI 60725 Violet X See also 21 CFR 74.2602. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 60730 Violet X See also 21 CFR 74.2602a.

CI 61565 Green X See also 21 CFR 74.2206. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051.

CI 61570 Green X See also 21 CFR 74.2205. All lakes are permitted in all cosmetics, except those intended for use in the area of the eye, see 21 CFR 82.1051.


CI 75120 Orange X E 160 b.See also 21 CFR 73.2030.

CI 75130 Orange X E 160 a. See also 21 CFR 73.2095.

CI 75170 White X See also 21 CFR 73.2329.

CI 75470 Red X E 120. See also 21 CFR 73.2087.

CI 75810 Green Only to be used in cosmetic dentifrices at a maximum level of 0.1% and only together with*:

Water. Glycerine. Sodium carboxymethylcellulose. Tetrasodium pyrophosphate. Sorbitol.

Magnesium phosphate, tribasic. Calcium carbonate. Calcium phosphate, dibasic. Sodium N-lauroyl sarcosinate. Artificial sweeteners*. Flavours*. Preservatives* (see chapter 3.1.).

E 140 and E 141. *See also 21 CFR 73.2125.

CI 77000 White X E 173. See also 21 CFR 73.2645.

CI 77007 Blue X See also 21 CFR 73.2725.


CI 77266 black X See also 21 CFR 74.2052.

Brown X See also 21 CFR 73.2646. CI 77400 44

Brown X See also 21 CFR 73.2647.

CI 77489 Orange X E 172. See also 21 CFR 73.2250.

CI 77491 Red X E 172. See also 21 CFR 73.2250.

CI 77492 Yellow X E 172. See also 21 CFR 73.2250.

CI 77499 Black X E 172. See also 21 CFR 73.2250.

CI 77510 Blue X Free from cyanide ions. See also 21 CFR 73.2299.

CI 77742 Violet X See also 21 CFR 73.2775.

CI 77820 White Permitted in fingernail polishes at a maximum level of 1.0% in the finished product. E 174. See also 21 CFR 73.2500.

CI 77891 White X E 171. See also 21 CFR 73.2575.


Caramel Brown X E 150. See also 21 CFR 73.2085.

Mica Opaque X See also 21 CFR 73.2496.


Substance/Requirement Index


1

1,1,1-Trichloroethane, 22, 37 1,4-Butanediol, 29, 40

2

2-(2,4,5-Trichlorophenoxy) propionic acid, 33 2-(2,4,5-Trichlorophenoxy) propionyl compunds (2,4-D), 33

2,2-Bis(bromomethyl)-1,3-propanediol, 31, 42 2,4,5-Trichlorophenoxyacetic acid, 33 2,4,5-Trichlorophenoxyacetyl compounds (2,4,5-T), 33 2,4,5-Trimethylaniline, 30 2,4-Diaminoanisole, 30 2,4-Toluene diisocyanate (2,4 TDI), 32, 38 2,4-Toluenediamine, 30 2,4-Xylidine, 30 2,6-Toluene diisocyanate (2,6 TDI), 32, 38 2,6-Xylidine, 30 2-Amino-4-nitrotoluene, 30 2-Bromo-2-Nitropropane-1,3-Diol, 20, 36 2-Naphthylamine, 30 2-Nitro-1,4-Benzenediamine, 21, 36 2-Nitro-p-Phenylenediamine, 21, 36

3

3,3’-Dichlorobenzidine, 30 3,3’-Dimethoxybenzidine (o-Dianisidine), 30 3,3’-Dimethyl-4,4’-diaminodiphenylmethane, 30 3,3’-Dimethylbenzidine (o-Tolidine), 30

4

4,4’-Diaminodiphenylmethane, 30 4,4’methylenebis(2-chloraniline) (MOCA), 29, 40 4,4’-Methylene-bis-(2-chloroaniline), 30 4,4’-Oxydianiline, 30 4,4’-Thiodianiline, 30 4-Aminodiphenyl, 30 4-Chloro-o-toluidine, 30 4-Nitro-1,2-Benzenediamine, 21, 36 4-Nitro-o-Phenylenediamine, 21, 36

A

Acenaphthene, 34 Acenaphthylene, 34 Acetanilide, 19, 36 Acid Red 26, 32 Acrylamide, 21, 36 Acrylates, 21 Adenosine, 19, 36

Aerobic Mesophyllic microorganisms, 23 Aldrine, 32 Alkylphenol Ethoxylates / Alkylphenols, 6, 8, 9, 12, 13, 27, 29, 30, 38, 40

Aloe Barbadensis, 19, 36 Aloe Vera Gel, 19 Aluminium (Al), 15, 35, 44 Aminophylline, 22, 37 Anthracene, 34 Anthraquinone Glycosides, 19 Antibacterial, 13 Antimicrobial, 15, 45 Antimony (Sb), 7, 19, 32, 36 AP, 6, 8, 9, 12, 13, 27, 29, 30, 38, 40, 41 APEO, 6, 8, 9, 12, 13, 27, 29, 30, 38, 40, 41 Apricot kernel oil, 21 Arachis Hypogaea Oil/Flour, 19, 36

Arsenic (As), 7, 9, 19, 32, 36 Azo Dyes & Pigments, 6, 8, 15, 30, 41, 45

B

Basic Red 9, 32 Basic Violet 14, 32 BBP, 16, 33, 36, 39 Benzene, 21, 29, 36, 40 Benzidine, 30 Benzo(a)anthracene, 33 Benzo(a)pyrene, 10, 33 Benzo(b)fluoranthene, 33 Benzo(e)pyrene, 33 Benzo(g,h,i)perylene, 34 Benzo(j)fluoranthene, 33 Benzo(k)fluoranthene, 34 Beta-sitosterol, 19, 36 Biotin, Vitamin B7/H, 37 Bis(2,3-dibromopropyl)phosphate, 31 Bisphenol-A, 9, 27, 30, 35, 38, 41, 44 Boron (B), 16, 17, 35, 44 BPA, 9, 27, 30, 35, 38 Butyl acrylate, 36 Butyl benzyl phthalate, 33, 36, 39

C

Cadmium (Cd), 7, 9, 10, 11, 14, 15, 19, 25, 26, 27, 32, 35, 36, 38, 44

Caffeine, 22, 37 Camphor, 19, 36 Candida albicans, 23 Caprolactam, 16, 35, 44 Captafol, 32 Caramel, 48 Cationic Surfactants, 6, 12, 13, 30, 41 Chlordane, 32 Chlordecone (Kepon), 32 Chlordimerform, 32 Chlorinated Aromatic Hydrocarbons, 6, 8, 30, 41 Chlorinated Bleaching Agents, 29 Chlorobenzenes, 30 Chlorobenzilate, 32 Chlorofluorocarbon propellants, 19, 36 Chloronaphthalenes, 30 Chloroparaffines, 6, 8, 9, 30, 41 Chlorotoluenes, 30 Chloroxylenes, 30 Chromium (Cr), 7, 13, 15, 16, 17, 18, 19, 32, 35, 36, 38, 44

Chromium III (Cr3+), 15, 35, 44 Chromium VI (Cr6+), 6, 8, 11, 15, 18, 19, 25, 26, 31, 35, 36, 41, 44

Chrysene, 33 CI 10316, 46 CI 12085, 46 CI 14700, 46 CI 15510, 46 CI 15800, 46 CI 15850, 46 CI 15880, 46 CI 15985, 46

CI 16035, 46 CI 17200, 47 CI 19140, 47 CI 40800, 47 CI 42053, 47 CI 42090, 47 CI 45350, 47 CI 45370, 47 CI 45380, 47 CI 45410, 47 CI 45425, 47 CI 47000, 47



CI 47005, 48 CI 59040, 48 CI 60725, 48 CI 60730, 48 CI 61565, 48 CI 61570, 48 CI 73360, 48 CI 75120, 48 CI 75130, 48 CI 75170, 48 CI 75470, 48 CI 75810, 48 CI 77000, 48 CI 77007, 48 CI 77163, 48 CI 77288, 19, 36 CI 77289, 20, 36 CI 77400, 48 CI 77489, 48 CI 77491, 48 CI 77492, 48 CI 77499, 48 CI 77510, 48 CI 77742, 48 CI 77820, 48 CI 77891, 48 CI 77947, 48 Cinnamyl Anthranilate, 20, 36 Cobalt (Co), 7, 8, 14, 20, 32, 35, 36, 44 Cobalt Dichloride, 28 Colorants, 24, 46 Colour Fastness, 15 Copper (Cu), 7, 32 Crystal, 12 Cyclomethicone, 20, 36 Cyclopentasiloxane, 20, 36

D

DBP, 16, 33, 36, 39, 43 DBT, 7, 9, 10, 12, 27, 32, 38 DDD, 32 DDE, 32 DDT, 32 DEHP, 16, 33, 36, 39 DEP, 36 Di(ethylhexyl) phthalate, 33, 36, 39 Diazolidinyl Urea, 20, 36 Dibenzo(a,h)anthracene, 34 DIBP, 15, 45 Dibromochloropropane (DBCP), 33 Dibutyl phthalate, 33, 36, 39 Dibutyltin, 7, 9, 10, 12, 27, 32, 38 DIDP, 16, 33, 36, 39 Dieldrine, 7, 9, 33 Diethyl Phthalate, 21, 36 Dihydrogenated tallowdimethyl ammouniumchloride (DHTDMAC), 30

Di-isobutyl Phthalate, 15, 45 Di-iso-decyl phthalate, 33, 36, 39 Di-isononyl phthalate, 33, 36, 39 Diisopropylnaphthalene, 15, 35, 45 Dimethylacetamide (DMAC), 29, 40 Dimethylformamide, 10, 27, 29, 31, 38, 40, 41 Dimethylfumarate, 13, 28, 31, 38, 41 Di-n-octyl phthalate, 33, 36, 39 Dinoseb, 33 DINP, 16, 33, 36, 39 Dioctyltin, 7, 9, 10, 12, 27, 32, 38 Diphenylmethane diisocyanate (MDI), 32, 38 DIPN, 15, 45 Direct Black 38, 32 Direct Blue 6, 32

Direct Brown 95, 32 Direct Red 28, 32

Discolouration, 13, 28 Disperse Blue 1, 31 Disperse Blue 102, 31 Disperse Blue 106, 31 Disperse Blue 124, 31 Disperse Blue 26, 31 Disperse Blue 3, 31 Disperse Blue 35, 31 Disperse Blue 7, 31 Disperse Brown 1, 31 Disperse Dyes, 6, 31, 41 Disperse Orange 1, 31 Disperse Orange 11, 31 Disperse Orange 149, 31 Disperse Orange 3, 31 Disperse Orange 37, 31 Disperse Orange 76, 31 Disperse Red 1, 31 Disperse Red 11, 31 Disperse Red 17, 31 Disperse Yellow 1, 31 Disperse Yellow 23, 31 Disperse Yellow 3, 31 Disperse Yellow 39, 31 Disperse Yellow 49, 31 Disperse Yellow 9, 31 Distearyldimethyl ammouniumchloride (DSDMAC), 30 Ditallowdimethyl ammoniumchloride (DTDMAC), 30 DMDM Hydantoin, 20, 36 DMF, 10, 27, 29, 31, 38, 40 DMFu, 13, 28, 31, 38 DnDP, 16 DnOP, 16 DNOP, 33, 36, 39 DOT, 7, 9, 10, 12, 27, 32, 38 DTTB-(Timiperone), 33

E

Endosulphane, 33 Endrine, 33 Ethyl acrylate, 36 Ethylene dibromide, 33 Ethylene glycol monoethyl ether, 29, 40 Extractable Matter, 17, 45

F

Feather and Down, 12 Flame Retardants, 6, 8, 10, 12, 24, 31, 42 Fluoranthene, 34 Fluorene, 34 Folic acid, L-Glutamic acid, 37 Formaldehyde, 6, 8, 10, 11, 12, 15, 16, 17, 18, 20, 26, 28, 31, 35, 36, 38, 42, 44, 45

Fragrance Allergens, 20 Fragrance Oils, 23 Fumigation, 28

G

Glass, 12, 14, 26 Glues, 29 Glyoxal, 15, 35, 45 Good Manufacturing Practice (GMP), 14, 23

H

Hafnium (Hf), 17, 35, 44 Halogenated biphenyls, 33 Halogenated naphthalenes, 33 Halogenated terphenyls, 33 Heptachlor, 33 Heptachloroepoxide, 33



Hexabromocyclododecane, 31, 42 Hexachlorobenzene, 33 Hexamethylene diisocyanate (HMDI), 32, 38 Hexamethylenetetramine, 18, 35, 44

I

Imidazolidinyl Urea, 20, 36 Indeno(1,2,3-c,d)pyrene, 34 Inhalation, 24 Isocyanates, 10, 12, 17, 27, 32, 38, 42, 45 Isodrin, 33 Isophorone diisocyanate (IPDI), 32, 38

K

Kathon CG, 20, 36 Kelevane, 33

L

Lead (Pb), 7, 9, 10, 11, 12, 14, 15, 17, 20, 25, 26, 27, 32, 35, 36, 38, 44

Lindane (γ-Hexachlorcyclohexane), 33 Lithium (Li), 18, 35, 44

M

Medium chained (MCCPs) C14-C17, 6, 8, 9, 30 Melaleuca Alternifolia Oil, 20, 36 Melamine, 16, 35, 44 Mercury (Hg), 7, 9, 10, 11, 15, 20, 25, 26, 27, 32, 35, 36, 38, 44

Metal containers/packages, 26 Metals, 7, 8, 9, 10, 11, 13, 24, 26, 27, 32, 38, 42, 44 Metamidophos, 33 Methoxychlor, 33 Methyl acrylate, 36 Methyl Salicylate, 21, 36 Methylchloroisothiazolinone, 20, 36 Methylene chloride, 29, 40 Methylisothiazolinone, 20, 36 Methylsilanol, 22, 37 Mica, 48

Microbiological Quality, 23 Migration, 15, 16, 17, 18, 24, 44, 45 Mineral Oils, 13, 42 Mirex, 33 Monocrotophos, 33 Monomers, 24 Monomethyldibromodiphenylmethane, 33 Monomethyldichlorodiphenylmethane, 33 Monomethyltetrachlorodiphenylmethane, 33 Mould, 13, 28, 42

N

Naphthalene, 34 n-Hexane, 29, 40 Niacin, Vitamin B5, 37 Nickel (Ni), 7, 8, 11, 15, 21, 32, 35, 36, 44 Nitrosamines, 21, 36 Nonylphenol (NP), 6, 8, 9, 12, 27, 30, 38, 40 Nonylphenol Ethoxylates (NPE), 6, 8, 9, 12, 21, 27, 30, 36, 38, 40

O

o-Aminoazotoluene, 30 o-Anisidine, 30

Octamethylcyclotetrasiloxane, 7, 32, 42 Octylphenol (OP), 6, 8, 9, 12, 27, 30, 38, 40 Octylphenol Ethoxylates (OPE), 6, 8, 9, 12, 21, 27, 30, 36, 38, 40

Odour, 13, 28, 42 ODP, 16 o-Phenylphenol, 7, 9, 10, 27, 33, 38 OPP, 7, 9, 10, 27, 33, 38, 43 Organoleptic, 15, 45 Organotin Compounds, 7, 9, 10, 12, 17, 27, 32, 38, 42, 44, 45

Other Dyes, 6, 8, 32, 41 o-Toluidine, 30

P

PAH, 10, 16, 33, 43, 44, 45 p-Aminoazobenzene, 30, 41 Pantothenic acid, Vitamin B3/B5, 37 Parathion, 33 Parathion-methyl, 33 PBB, 25, 31 PBDE, 25, 31 PCB, 8, 9, 10, 15, 27, 34, 35, 39, 43, 45 p-Chloroaniline, 30 PCP, 7, 9, 10, 11, 15, 18, 26, 27, 33, 35, 38, 43, 45 p-Cresidine, 30 PCT, 8, 9, 10, 27, 34, 39 Pentachlorophenol, 7, 9, 10, 11, 15, 18, 26, 27, 33, 35, 38, 45

Perfluoro Compounds, 7, 9, 11, 26, 32, 38, 43

Perfluorooctane Sulfonate, 7, 9, 11, 26, 32, 38 Perfluorooctanoic Acid, 7, 9, 11, 18, 26, 32, 35, 38, 44 Peroxide, 16, 17, 18, 45 Perthane (Ethylane), 33 Pesticides, 7, 9, 32, 43 PFOA, 7, 9, 11, 18, 26, 32, 35, 38, 44 PFOS, 7, 9, 11, 26, 32, 38 pH, 7, 43 Phenanthrene, 34 Phenol, 29, 40 Phenolic Substances, 18, 44 Phenols, 7, 9, 10, 11, 26, 27, 33, 38, 43 Phenyl Salicylate, 21, 36 Phenylmercuric salts, 21, 36 Phosphamidone, 33 Phthalates, 7, 10, 12, 16, 21, 27, 33, 36, 39, 43, 44 Plasticizers, 24 Polyaromatic Hydrocarbons, 10, 33, 43, 44, 45 Polybrominated Biphenyls, 25, 31 Polybrominated Diphenyl Ethers, 25, 31 Polychlorinated Biphenyls, 8, 9, 10, 15, 27, 34, 35, 39, 45

Polychlorinated Compounds, 34, 39 Polychlorinated Triphenyls, 8, 9, 10, 27, 34, 39 Polyvinylchloride, 8, 10, 11, 27, 34, 39 Polyvinylidenchloride, 8, 10, 11, 27, 34, 39 p-Phenylenediamine, 32 Preservatives, 24 Primary Aromatic Amines, 15, 16, 17, 18, 24, 44, 45 Primary container/package, 28 Product Information files (PI-files), 23 Prunus Armeniaca Kernel Oil, 21, 36 Pseudomonas aeruginosa, 23 PVC, 8, 10, 11, 27, 34, 39, 43 Pyrene, 34 Pyrrolizidine Alkaloids, 21

Q

Quintozene, 33

R

REACH SVHC, 13, 14, 24, 25, 28 Residual Monomers, 21, 36 Residual Solvents, 21, 36 Retinol (Vitamin A), 21, 36 Retinyl Palmitate (Vitamin A), 21, 36



S

Salicylic Acid, 21, 36 Sand Blasting, 29 Sensory, 14, 44 Short chained (SCCPs) C10-C13, 6, 8, 9, 30 Solvent Yellow 1, 32 Solvent Yellow 2, 32 Solvent Yellow 3, 32 Solvents, 24, 29, 40, 43 Stability test, 23 Staphylococcus aureus, 23 Strobane, 33 Sucralfate, 21, 36 Symphytum Officinale (Comfrey), 21, 37

T

Talc, 21, 37 TBT, 32, 38 TCyHT, 32, 38 Tea Tree Oil, 20 TeCP, 7, 9, 10, 27, 33, 38, 43 Telodrin (Isobenzan), 33 Tetrabromobisphenol A (TBBP A), 31 Tetrachloroethylene (PERC), 29, 40 Tetrachloromethane, 29, 40 Tetrachlorophenol, 7, 9, 10, 27, 33, 38 Tetramethylxylene diisocyanate (TMXDI), 32, 38 Theobromine, 22, 37 Theophylline, 22, 37 Thimerosal, 21, 37 Thioctic Acid, 22, 37 Toluene, 21, 22, 29, 36, 37, 40 TOT, 32, 38 Toxaphene (Camphechlorine), 33 TPhT, 32, 38 TPT, 32, 38 Tributyltin, 32, 38 Trichloroethylene (TRIS), 29, 40 Triclosan, 8, 10, 22, 27, 34, 37, 39, 43 Tricyclohexyltin, 32, 38 Tri-o-cresyl phosphate, 31, 42 Trioctyltin, 32, 38 Triphenyl phosphate (TPhP), 31 Triphenyltin, 32, 38 Tripropyltin, 32, 38 Tris(1,3-dichloroisopropyl)phosphate (TDCP), 31 Tris(2,3-dibromopropyl)phosphate (TRIS), 31 Tris(2-chloroethyl)phosphate (TCEP), 31 Tris-(aziridinyl)-phosphineoxide (TEPA), 31

V,W

Vanadium (V), 16, 17, 35, 44 Viscum Album, 22, 37 Vitamin B1, thiamine, 37 Vitamin B12, 37 Vitamin B2, riboflavin, 37 Vitamin B6, adermine, 37 Vitamin E, tocopherol, 37 Vitamin K, 37 Vitamins, 22, 37 Volatile Organic Matter (VOM), 16, 17, 18, 45

X

Xanthin derivatives, 22

Z

Zinc (Zn), 16, 17, 18, 35, 44 Zirconium (Zr), 17, 35, 44

αααα

α-Hexachlorcyclohexane, 33

ββββ

β-Hexachlorcyclohexane, 33

δδδδ

δ-Hexachlorcyclohexane, 33

h & m chemical restrictions - 2009-12-14

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