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Global Excellence In design and manufacture of heat and wear resistant products

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Global ExcellenceIn design and manufacture of

heat and wear resistant products

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:49 Page2

AFE CRONITEis a world leader

in the manufacture of fixtures and parts

in refractory alloys for heat treatment,

incineration, petrochemical,

power generation, steel, automotive andaerospace industries.

Known world-wide under the names CRONITE, KLEFISCH, MANCELLE, NORTH AMERICAN CRONITE,CRONITE CZ, AFE CRONITEhas more than 50 yearsexperience in the design and production of alloy steel parts resistant to high temperatures, abrasion and corrosion and in thedevelopment of new alloys to improve the performance and servicelife of your systems.

AFE CRONITEis present throughout the world, with 550 people based at 10 productionand R&D locations sites in France, GreatBritain, Germany, Czech Republic, China,Mexico and USA. There is also a commercial network in Europe, United States, South America,Asia and an international team ofdesigners, French, German, English,American, Scandinavian, Czech, Chineseand Japanese who work to optimise your solutions.

QUALITY ASSURANCECertificates AFAQ : ISO 9001, 14001

& OHSAS 18001

A F E C r o n i t e

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:49 Page3

Research & Development

Metallurgy

Design

Commercial network Delivery

ProductionEquipment

Process

Manufacturing Plants/R&DAgentsSales

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:49 Page4

I n d u s t r i a lp r o c e s sContinous research

of alloys and materialssuitable for the heat treatment processes

of our customers

“”

Green sand and resin bonded sand

moulding processes

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:49 Page5

LOST WAX CASTING PROCESS

HRZ & 1.4849 - Temp. 950°C • 1 000°C • 1 050°C

30,00

25,00

20,00

15,00

10,00

5,00

0,000 20 40 60 80 100 120 140 160 180 200

% D

isto

rtio

n at

Hig

h Te

mpe

ratu

re

HRZ 1 050°C135 Cycles

HR32 1 050°C147 Cycles

AFE Cronite is equipped withnumerous production techniques:green sand for mass production,chemical sand for items over 2T, lost wax for very accurate parts,carbon fibre composites, machining, welding assembly andsheet metal working facilities.

GRAPHITE & COMPOSITE

WELDED FABRICATIONS

HR32 1 000°C152 Cycles

HRZ 1 000°C149 Cycles

HRZ 950°C152 Cycles

HR32 950°C188 Cycles

CENTRIFUGALCASTING

PROCESS

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:49 Page6

The design objectives :

• Reduce the weight of casting : Q Increase productivity Q Reduce cost Q Reduce cost of energy to heat

• Optimisation of parts treated in respect of heat treatmentconstraints

• Consider means of loading (manual or robotic)

• Take into account customersproduction flow

• Increase service life

A team of 15 designers is available to find solutions

to your needs“ ”

D e s i g nR e s e a r c h &

D e v e l o p m e n t

Our design offices are equipped with 3D CAD systems enabling simulation of mechanical constraints at temperature and rapid CNC machining of patterns

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:49 Page7

M e t a l l u r g y

AFE CRONITEdevelops and produces

a wide range of alloys to maximise life time

and performance of your products

“”

ALLOY CHEMISTRY

AFE AFNOR DIN ASTM JIS C Cr Ni Mn Si Nb/Co

HR 19 Z40CN27-04 1.4823 SCH 11 0,4 27 4 1 1,5 HR 15 Z20CN18-09 1.4825 0,2 18 9 1 1,5 HR 15 B Z40CN22-10 HF SCH 12 0,4 22 10 1 2 Z40CN28-05 HD 0,4 28 5 1 1,5 HR 7 B Z30CN20-14 1.4832 0,3 20 14 1 2 HR 7 Z40CN25-12 1.4837 HH SCH 13A 0,4 25 12 1 1,5 HR 6 Z40CN25-20 1.4848 HK SCH 21 0,4 25 20 1 1,5 HR 25 Z40CNNb24-24-02 1.4855 0,4 24 24 1 1,5 1,5 Z40CN28-10 HE SCH 13 0,4 28 10 1 1,5 HR 18 Z40NC25-20 1.4805 HN 0,4 20 25 1 1,5 HR 9 Z10NCNb32-20-01 1.4859 0,15 20 32 1 1,5 1,5HR 8 Z25NCNb38-18-02 HU 25 SCH 16 Nb 0,25 18 38 1 1,5 2HR 17 Z40NC35-15 1.4806 HT SCH 15 0,4 15 35 1 1,5 HR 5 Z40NC38-18 1.4865 HU SCH 15 0,4 18 38 1 1,8 HR 17 Nb Z40NCNb35-15-02 1.4807 HT SCH 15 Nb 0,4 15 35 1 1,5 2HR 32 Z40NCNb38-18-02 1.4849 HU 0,4 18 38 1 1,5 1,5HR 33 Z40NC35-25 1.4857 HP SCH 24 0,4 25 35 1 1,5 HR 33 Nb Z40NCNb35-25-02 1.4852 SCH 24 Nb 0,4 25 35 1 1,8 1,5HR 4 Z60NC52-17 0,5 18 52 1 1,5 Z30NC55-15 HW 0,3 15 55 1,5 1,5 HR 29 Z30NC66-17 2.4815 HX 50 0,3 17 66 Z50NCW45-25-05 0,5 25 45 1 1,5 HR 23 Z50NCW48-28-05 2.4879 0,5 28 48 CRONIAL 2000 0,5 6 73 1,5 —SUPER CRONITE 0,5 18 55 1,5 1,5 1MANCELLIUM 0,1 17 75 0,5 0,4 —HRZ 0,25 25 22 1 1 yes

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:50 Page8

H e a t t r eS t a n d a r d f i x t u r e s

A l l f u r n a c e t y p e s

AFE CRONITEoffers a range of 4000 standard parts

allowing you to assemble fixturessuitable for different furnace types

We can combine a standard fixture with some specific elements

to suit the parts you are treating

“”

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:50 Page9

a t m e n tS p e c i f i c f i x t u r e s

O p t i m i s a t i o n o f l o a d i n g a n d h e a t t r e a t m e n t

Based on a great and proven experience

and a will for continuous innovation

AFE CRONITE designs solutions dedicated

to any specific furnace layout and parts to be processed

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:50 Page10

AFE CRONITE owns standard patterns for grids,

spiders and segments as well as baskets

and can adapt the fixtures to your needs

• Spiders and segments of diameter 500 to 3000 mm.

• Grids with support columns of diameter 420 mm to 2000 mm.

• Carburising baskets of diameter 490 to 914 mm

• Bell furnaces « square » from 320 x 320 to 630 x 630 or « cylindrical » from 430 to 800 mm.

• Other sizes on request

“”

P i t o r b e l l f u r n a c e s

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:51 Page11

F u r n a c e s p a r t s

AFE CRONITE

manufactures spare partsand makes repairs for

Heat Treatment Furnaces(retorts, muffles…)

“”

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:51 Page12

W a s t e & B i o m a s st o e n e r g y

A i r a n d w a t e r c o o l e d s y s t e m s

Products

• Sand cast burner parts,low pollution oil and pulverisedcoal burner nozzles, air swirlersand large tube support beams

• Lost wax precision cast tubespacers

• Grate bars for waste to Energyand Biomass

Cronite Castings and Mancelle de Fonderie have been supplying fossil fuel power generation industry

and waste to energy incinerators for over 80 years.From cast components for steam powered ship’s boilers

to land based power generation boilers.

Re

stra

ints

Temperature

Martensitic Ferritic

Austeno-Ferritic

Austenitic

Air cooled bars.Low and medium LVH*

Standard mecanicalsolicitations

Air cooled bars.High LVH*

High mecanicalsolicitations.

Weldability needs

Ferritic Austenitic

Martensitic

Water cooledbars

- Weldability +

Creeping +H2 S +

% C

hro

miu

m

% N

icke

l

Austeno-Ferritic

The refractory alloy choice is always a compromise

LVH* : Lower heating value

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:52 Page13

B u r n e r s y s t e m s a n d t u b e s s u p p o r t f i t t i n g s

P o w e r g e n e r a t i o n

Alloys AFE Cronite produces a range

of alloys specific to this industry: • 28Cr and 25Cr/12Ni type alloys

for good wear resistance againstpulverised coal fuels.

• 52Ni / 18Cr for high strength,high temperatures.

• 50Ni / 48Cr / Nb (Type 657) toresist fuel ash corrosion from useof high sulphur and vanadiumpentoxide containing fuels.

Although this market is mature, there is a new demand for advanced burner technology to reduce pollution, in particular the nitrous oxides (Nox) and CO2 in the exhaust gases.These new burner systems are being installed in both existing (retrofit) and new plants, and AFE Cronite is at the forefront of low emission burner developments.

S h o t b l a s t i n g

AFE CRONITE

manufactures parts for mostturbine-operated shot

blasting machines

“”

Manufacturing of most of themarket's replacement parts.Metallurgical mastery of specialirons and manganese steels

Main parts made:• Parts for turbines, blades, cages...• Blade holder• Miscellaneous parts: liners,

brackets, etc.In addition, AFE Cronite designs and makes handling systems for shotblasting equipment:• A-frame racks• Aprons• Tables• Heat treatment jigs adapted to

shotblasting applications

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:52 Page14

C o m p o s i t e a n d T i t a n i u m F o r m i n g

A e r o s p a c e

ALLOY GRADES MATERIALS FOR AEROSPACE

CAST ALLOY COMPOSITION

Alloys • For SPF and hot forming titanium

at temperature between 700°Cand 950°C. 25Cr / 20Ni (HR6),52Ni / 18CR (HR4), 22Cr / 4Ni /9Mn (HR13). HR4 is a proprietaryalloy found to give the best allround performance of strength,durability, hardness, machinabilityand repairability.

• For forming of carbon composites,an alloy was required withminimum coefficient of thermalexpansion between roomtemperature and about 250°C.For this application a range ofaustenitic nickel iron cast alloyshas been developed:HR21 - 32Ni / Fe / CoHR21A - 36Ni / FeTools are also produced incarbon composite using our ownspecialised machining facility.

• For hot press plattens and otherstressed parts in the press we offer several nickel chromealloys that give excellent servicelife and performance.25Cr / 20Ni (HR6)36Ni / 26Cr / 5W / 15Co (HR36A)35Ni / 25Cr (HR33)37Ni / 18Cr / Nb (HR32)

HR4 HR6 HR13 HR33 HR36A HR21 HR21A 1,4848 Invar types

C [%] 0.6 0.46 0.45 0.45 0.5 2.0 2.1 Mn [%] 1.2 1.0 19.9 1.0 0.7 - - Si [%] 1.8 1.7 0.6 1.9 1.0 2.1 2.1 max [%] 0.03 0.03 0.04 0.03 0.02 - - max [%] 0.03 0.025 0.05 0.025 0.02 0.006 0.006 Cr [%] 17.5 25.0 21.5 25.0 26.0 - - Ni [%] 51.0 20.0 4.0 35.0 36.0 32.0 35.0 Nb [%] 1.0 - - - - - - Others W add - - - Co15W5 Co4.5 -

AFE Cronite works closely with theindustry and its subcontract toolsuppliers to design strong, thermallyefficient tools for all forming processes.

Related parts such as plattens, forthe hot presses are also

supplied.

AFE Cronite’s involvement with theaircraft industry started over 30 yearsago with the development of castforming tools for super plastic forming(SPF) and hot creepforming of titanium. With the recentradical change in aircraftmanufacturingtechniques and the introduction ofcarbon compositeparts to replace aluminium,another type of tool is requiredto form these composite structures.

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:53 Page15

P e t r o c h e m i c a l s

AFE Cronite is a long establishedsupplier of high integrity static cast

products to the petrochemicalindustry. This includes tube sheets,

tube support beams, brackets,hangers, U bends, elbows and fittings.Our sister company, Cronite Scomark

Engineering, is a specialist inmanufacture of tubular products

including catalyst tube assemblies,radiant coils, inlet and outlet

manifolds, pigtails and quench fittings.

Together we have the advancedmanufacturing facilities, testing

equipment and welding procedures tosupply a full range of products to the

world petrochemical industry.

Manufacturing process Alphaset sand moulding, castings up to 3 tonnes.Greensand machine moulding Lost wax investment casting Centrifugal casting of tubesFull machining and testing capability

Quality Control Chemical analysis Mechanical testingRoom and high temperatureLiquid penetrant testingRadiographic testing

AlloysA full range of nickel chrome alloys is produced, from thetraditional 25Cr / 12Ni and 25Cr / 20Ni, through to the sulphurand vanadium resistant 48Ni / 48Cr / Nb types.

ALLOY GRADES MATERIALS FOR TUBES

2520MA 2032Nb 2535 2535NbLC 2535NbMA 2535W 3545NbMA 1.4848MA 1.4859 1.5857 1.4852MA 1.4889MA

C [%] 0.38 0.1 0.35 0.1 0.4 0.4 0.4 Mn [%] 1.5 1.0 1.5 1.5 1.5 1.5 1.5 Si [%] 2.0 1.0 2.0 1.5 1.75 2.0 2.2 Pmax [%] 0.03 0.03 0.03 0.03 0.03 0.03 0.03 Smax [%] 0.03 0.03 0.03 0.03 0.03 0.03 0.03 Cr [%] 26.0 21.0 25.0 25.0 25.0 25.0 35.0 Ni [%] 20.0 33.0 25.0 35.0 35.0 35.0 45.0 Nb [%] - 1.5 - 1.5 1.2 - 1.5 Others W.Ti add. - - - Ti.Zr add W 4.5 Ti.Zr add

CAST ALLOY COMPOSITION

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:53 Page16

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AFE CRONITE HEAD OFFICERoute du Lude - BP 75 - F- 72233 Arnage Cedex

[email protected]

MANCELLE DE FONDERIERoute du Lude

BP 75F- 72233 Arnage CedexTel +33(0)2 43 47 58 58Fax +33(0)2 43 21 24 63

[email protected]

NORTH AMERICAN CRONITE37162 Sugar Ridge Road

North RidgevilleOH 44039

USATel +(1) 440 353 6594Fax +(1) 440 353 [email protected]

CRONITE DE MEXICOCarretera Miguel Aleman km 24.5

APOCADA NL 66600 Mexico

Tel +52 818 386 [email protected]

AFE CRONITE ITALYTel +39 0461 269 [email protected]

AFE CRONITE POLANDTel +48 68 453 0833

[email protected]

CRONITE CASTINGSBlacknell Lane,

CrewkerneUK – Somerset TA 18 7 YA

Tel +44 1460 270 300Fax +44 1460 270 344

[email protected]

CRONITE SCOMARKENGINEERINGChurch Street, Church Gresley

SwadlincoteUK – Derbyshire DE11 9NR

Tel +44 1283 218 222Fax +44 1283 229 459

[email protected]

AFE CRONITE CZSkrobarenska 484/8

CZ – 61700 BrnoTel +420 511 120 336

[email protected]

AFE CRONITE NORDICTel +46 87 514 100

[email protected]

AFE CRONITE IBERICATel +34 945 293 400

[email protected]

AFE KLEFISCHSiemensstrasse 1D- 50354 Hürth

Tel +49 2233 699 80Fax +49 2233 699 861

[email protected]

AFE CRONITE WUHANDong Xi Hu District

Jin Yin Tan Economic Zone10th of Yin Tan Road

430023 Wuhan, Hubei ProvinceCHINA

Tel +86 27 8550 [email protected]

BEIJING APSA CHINATel +86 10 6440 5701

[email protected]

AFE JAPANTel +81 3 3254 4892

[email protected]

AFE CRONITE RUSSIATel +79 162 331 974

[email protected]

AFE CRONITE BENELUXTel +44 78 34 500 388

[email protected]

AFECroniteGroup-16P-UK-FLASH-2_AFE Cronite 2010 08/06/10 17:48 Page1