give the major organic product(s) of the following reaction. give …jpenn/chem 234...
TRANSCRIPT
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A B
C D E
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
F - None of these products are a major product of the reaction that is shown.
2016-10-31 Q1
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A B
C D E
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
F - None of these products are a major product of the reaction that is shown.
2016-10-31 Q1
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Exam 3
• Time: – Tuesday, November 8: 7:00 – 9:00PM OR – Wednesday, November 9: 7:00 – 9:00PM OR – Thursday, November 10: 7:00 – 10:00PM
• Location – Soc/Anthro Testing Center – Chapters will be covered in this order: Chapter 17, 18
• Practice Exams are Posted – Ex3A Practice Exam 3A – Ex3B Practice Exam 3B
• Deadline for alternate arrangements is Monday, 11/7/2016 at 4:30 PM (i.e., close of business)
• An oral make-up exam will be required for making up the exam for all students not taking the exam on the above dates or having already made prior arrangements
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Ex3-01-B7-17-01A Ketone Aldehyde Naming Friday, October 22
Ex3-01-B7-17-01B Aldehyde Ketone Naming Saturday, October 22
Ex3-02-B7-17-02A Ald Ket Rxns O-Nucl Saturday, October 23
Ex3-02-B7-17-02B Ald Ket O-Nucleophiles Sunday, October 24
Ex3-02-B7-17-02C Ald Ket Rxns O-Nucl Monday, October 25
Ex3-03-B7-17-03A Ald Ket with N-Nucl Tuesday, October 26
Ex3-03-B7-17-03B Ald Ket with N-Nucl Wednesday, October 27
Ex3-03-B7-17-03C Ald Ket with N-Nucl Thursday, October 28
Ex3-04-B7-17-04A Ald Ket with C-Nucl Friday, October 29
Ex3-04-B7-17-04B Ald Ket with C-Nucl Saturday, October 29
Ex3-04-B7-17-04C Ald Ket with C-Nucl Sunday, October 30
Ex3-05-B7-18-01 Tautomers Sunday, October 30
Ex3-06-B7-18-02B Alpha-Bromination Monday, October 31
Ex3-06-B7-18-02C Alpha-Bromination Tuesday, November 1
Ex3-07-B7-18-03B Alkylation Alpha-C=O Wednesday, November 2
Ex3-07-B7-18-03C Alkylation Alpha-C=O Thursday, November 3
Ex3-08-B7-18-04B Malonic Ester Synthesis Friday, November 4
Ex3-08-B7-18-04C Malonic Ester Synthesis Saturday, November 5
Ex3-09-B7-18-05 Fatty Acids Sunday, November 6
Exam 3 November 8, 9, 10
Exam 3 Lecture
Planning
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A B
EDC
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
F - None of these products are a major product of the reaction that is shown.
2016-10-31 Q2
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X
Too high in energy
Methyl ketone
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A B
EDC
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
F - None of these products are a major product of the reaction that is shown.
2016-10-31 Q2
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No Class Friday
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H3O+
heat
CH3CH2I
A B C D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
E - None of these products are a major product of the reaction that is shown.
2016-10-31 Q3
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H3O+
heat
CH3CH2I
A B C D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
E - None of these products are a major product of the reaction that is shown.
2016-10-31 Q3
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CH3I
heat
H3O+
A B C D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
E - None of these products are a major product of the reaction that is shown.
2016-10-31 Q4
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CH3I
heat
H3O+
A B C D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
E - None of these products are a major product of the reaction that is shown.
2016-10-31 Q4
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heatno reaction
heat
heatno reaction
enol
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Which of the following compounds would be expected to eliminate CO2
when heated? 2016-10-31 Q5
A B C
D E F
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Which of the following compounds would be expected to eliminate CO2
when heated? 2016-10-31 Q5
A B C
D E F
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Malonic Ester Synthesis
CH3I (1 mole)
heatAny substitutable halide
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Final Product Depends on Work-up Conditions
CH3OH
H3O+
heat
CH3OH
CH3OH CH3OH
-OH
heat
-OH
heat H3O+
H3O+
heatCH3OH
-OH
heatCH3OH
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heat
A
C D
B
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
E - None of these products are a major product of the reaction that is shown.
2016-10-31 Q6
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heat
A
C D
B
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
E - None of these products are a major product of the reaction that is shown.
2016-10-31 Q6
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1) NaOMe
2) CH3I
3) H3O+, heat?
A
B CD
E F G
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
H - None of these products are a major product of the reaction that is shown.
2016-10-31 Q7
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1) NaOMe
2) CH3I
3) H3O+, heat?
A
B CD
E F G
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx ab)
H - None of these products are a major product of the reaction that is shown.
2016-10-31 Q7
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1 2 3 4
AB
CD
E
CoACoA
CoACoA
CoA
CoA
CoA
Consider the biological reaction shown below which converts fatty acids to larger fatty acids. Give the Correct identities for 1, 2, 3, and 4 in that order. (Example: xxxx ab)
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1 2 34
AB
CD
E
CoA CoA
CoACoA
CoA
CoA
CoA
Consider the biological reaction shown below which converts fatty acids to larger fatty acids. Give the Correct identities for 1, 2, 3, and 4 in that order. (Example: xxxx ab)
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NaOMe H3O+
heat?
A CB D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
E - None of these products are a major product of the reaction that is shown.
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NaOMe H3O+
heat?
A B C D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
E - None of these products are a major product of the reaction that is shown.
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NaOMe
?
A B C D
H3O+
heat
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
E - None of these products are a major product of the reaction that is shown.
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HCN
A B C
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
D - None of these products are a major product of the reaction that is shown.
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?
A BC
D E
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
F - None of these products are a major product of the reaction that is shown.
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NaNH2
heat
A B
C D E F
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
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H+
heat
?
A B C D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
E - None of these products are a major product of the reaction that is shown.
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NaOMe
heat
A
BC
D
heat
NaOH H3O+
heat
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
E - None of these products are a major product of the reaction that is shown.
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Ph3P+CH3 Br-n-BuLi ?
A B
C
D
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
E - None of these products are a major product of the reaction that is shown.
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NaOMe
heat
AB C
D
EF
H3O+NaOH
CH3Br
(1 mole)
heatheat
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
+
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Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
2016-10-28 Q2
F E D
A B C
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Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
2016-10-28 Q2
F E D
A B C
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Give the minor organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
2016-10-28 Q3
F E D
A B C
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Give the minor organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
2016-10-28 Q3
F E D
A B C
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Lithium Di-isopropylamide (LDA)
H2
A. Strong base (N- is not that happy, since N is not that electronegative and doesn’t want a negative charge)
B. Non-nucleophilic, b/c of steric hindrance of isopropyl groups
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LDA as a base for H’s α to a carbonyl
1) LDA (1 mole)
2)
3) H+ (work-up)
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A B
C D E
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
F - None of these products are a major product of the reaction that is shown.
2016-10-28 Q4
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A B
C D E
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
F - None of these products are a major product of the reaction that is shown.
2016-10-28 Q4
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1) Br2, PBr3, heat
2) H3O+
A
F
B
EDC
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
2016-10-28 Q5
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1) Br2, PBr3, heat
2) H3O+
A
F
B
EDC
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
G - None of these products are a major product of the reaction that is shown.
2016-10-28 Q5
![Page 45: Give the major organic product(s) of the following reaction. Give …jpenn/Chem 234 files/2016/Fall/2016-10-31... · 2016-10-31 · A B C D E Give the major organic product(s) of](https://reader034.vdocuments.us/reader034/viewer/2022050602/5fa934d72700d6616e2af25e/html5/thumbnails/45.jpg)
1)
2) NaOH, H2O2
A B
C D
E F G H
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
I - None of these products are a major product of the reaction that is shown.
2016-10-14 Q11
![Page 46: Give the major organic product(s) of the following reaction. Give …jpenn/Chem 234 files/2016/Fall/2016-10-31... · 2016-10-31 · A B C D E Give the major organic product(s) of](https://reader034.vdocuments.us/reader034/viewer/2022050602/5fa934d72700d6616e2af25e/html5/thumbnails/46.jpg)
1) Li
2)
3) H+
A B
CD
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
E - None of these products are a major product of the reaction that is shown.
2016-10-14 Q12
![Page 47: Give the major organic product(s) of the following reaction. Give …jpenn/Chem 234 files/2016/Fall/2016-10-31... · 2016-10-31 · A B C D E Give the major organic product(s) of](https://reader034.vdocuments.us/reader034/viewer/2022050602/5fa934d72700d6616e2af25e/html5/thumbnails/47.jpg)
DC E
GF
A
1)
B2) H+
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b)
H - None of these products are a major product of the reaction that is shown.
2004-10-22 Q2