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ThyssenKrupp UhdeThyssenKrupp Uhde
German African Energy Forum
applying ThyssenKrupp Uhde‘s Gasification Technologies for the Gas- and Oil Downstream Sector
Hamburg, 9 April 2013
ThyssenKrupp Uhde2
Facts and figures 2010/2011
1921 Friedrich Uhde engineering firm, Dortmund
1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG
1996 Acquisition of Uhde GmbH by Fried. Krupp AG Hoesch-Krupp
1997 Uhde and Krupp Koppers merge to form Krupp Uhde GmbH
1999 Krupp and Thyssen merge to form ThyssenKrupp AG
2002 Name changes back to Uhde GmbH
2011 Name changes to ThyssenKrupp Uhde GmbH
Business year 2010/2011 (ThyssenKrupp Uhde Group)
1) acc. to IFRS
History
� Order intake €1,613.3m
� Net sales €1,427.6m 1)
� Equity capital €556.6m 1)
� Workforce 2)
ThyssenKrupp Uhde group (total) ~5,600
- of which ThyssenKrupp Uhde GmbH ~1,800
� Engineering approx. 7.1 million
capacity engineering hours/year 2) Figures incl. non-permanent staff
5,600
2,900
World
Europe
Germany 2,300
ThyssenKrupp Uhde3
Order intake of the ThyssenKrupp Uhde Group according to regions (in € million)
America
Central and Southern Africa
Eastern Europe & Central Asia
South East Asia,the Pacific & Australia
Western Europe
Middle East & North Africa
€ million
06/ 07 07/ 08 08/ 09 09/ 10 10/ 11
104
233275
55
179
€ million
06/ 07 07/ 08 08/ 09 09/ 10 10/ 11
165
530
105127
315
€ million
06/ 07 07/ 08 08/ 09 09/ 10 10/ 11
5195
21104 140
€ million
06/ 07 07/ 08 08/ 09 09/ 10 10/ 11
1.579
1.216
689
549480
€ million
06/ 07 07/ 08 08/ 09 09/ 10 10/ 11
207 201
1919 67
€ million
06/ 07 07/ 08 08/ 09 09/ 10 10/ 11
428
293347308
432
ThyssenKrupp Uhde4
ThyssenKrupp Group
Materials Technologies
ThyssenKrupp AG
Business Services
Steel Europe
Steel Americas
Stainless Global
Materials Services
Elevator Technology
Plant Technology
Components Technology
Marine Systems
Workforce: ~180,000Sales: €49.1 bn
ThyssenKrupp Uhde
ThyssenKrupp Uhde5
� Gasification
- Coal, petcoke
- Biomass
- Oil, residues
� Syngas applications
• Gas treatment for
- Fuel gas, hydrogen, SNG
- Sulphur recovery
- Coal-to-Liquids- Ammonia, methanol
� PDH (propane dehydrogenation)
ThyssenKrupp Uhde is a technology-driven engineering company we offer more than 250 processes
Gas Technologies
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Coal and Biomass will need to play a greater role: Resources and Consumption in Comparison
Source: Energierohstoffe 2009, Hamburg World Economic Institute,
Energy Resources Strategy 2030
EJ = Exa-Joule = 1018 J
World Consumption
500 EJ
30%
2%
36%
26%
6%
Hard Coal
Lignite
Oil
Natural Gas
Uranium
Resources
572 000 EJ
67%
9%
1%
2%
2%
18%
1%
Hard Coal
Lignite
Conventional Oil
Oil Sands / Shale Oil
Conventional Natural Gas
Non-conventional Natural Gas / Shale Gas
Nuclear
ThyssenKrupp Uhde8
Market Outlook GasificationObservations April 2013
In the U.S.A., shale gas has reduced the cost of gas and of coal significantly.
With the exception of the U.S., coal demand grows steadily worldwide
By 2017, coal will surpass oil as world‘s no.1 energy resource
CTL and BTL are within a new global commercialisation phase
Gasification can use a wide range of coal qualities, biomass and other
feedstocks.
CTL is clean – and can be permitted as Minor Source
Gasification enables feasible CO2 capture, and with biomass, CO2 „neutrality“
2nd Generation BTL expects new boost from most recent EU politics
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ThyssenKrupp Uhde: broad feedstock flexibility
for the entire syngas product slate
DieselNaphtha
Waxes
Lubes
Ammonia Urea
GasolineLPG
Methanol
MTO
MTG
H2
SNG
IGCC/Power
Syngas(CO+H2)
DieselNaphtha
Fischer-
Tropsch
Naphtha
Hard Coal
Uhde Steam Reformer
PRENFLO
Gasification
HTW
Gasification
Biomass
Brown Coal
Wastes
Petcoke
Gas
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PRENFLO®
Entrained-Flow Gasification
Oil Gasification
HTW™
(High-Temperature Winkler)
Fluidised Bed Gasification
Different Feedstocks require Different Gasification TechnologyThyssenKrupp Uhde‘s Gasification Portfolio
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ThyssenKrupp Uhde’s firsts in Coal Gasification:
1909: first Koppers Gas Generators (a total of 536 built)
1941: Invention of first Entrained-Flow Gasification:
Koppers-Totzek: dry-fed, membrane wall, multiple burners
Development, Design and Construction of
first Koppers-Totzek Coal Gasification Plant
first Rummel-Otto Slag Bath Coal Gasification Plant
first Saarberg-Otto Coal Gasification Plant
first Texaco (GE) Coal Gasification Plant
first HTW Coal Gasification Plant
first Shell-Koppers Coal Gasification Plant
first PRENFLO Coal Gasification Plant
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Project Phase Feasibility Study Process Design Package
Basic Engineering EPC
Costing
EPC Execution
Service provided by
Uhde
From the idea to a successful project execution
⌧• Gasification projects are mega projects – usually several hundred
million, often several billion, US-Dollars need to be financed
• Minimisation of interfaces, risk and cost is even more important to
project financing under „post-financial crisis“ requirements
• Uhde is Licensor and EPC provider from a single source and can thus
offer any project-specific, tailor-made seamless interface and
package
This unique concept
• significantly reduces cost and schedule prior to Financial Closure
• Allows to “wrap” the entire process chain
⌧ ⌧ ⌧ ⌧
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ThyssenKrupp Uhde‘s Proprietary Gasification Technologies
PSG PDQ HTW™
Entrained-Flow Fluidised Bed
PRENFLO®
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ThyssenKrupp Uhde‘s Gasification Experience
Koppers-Totzek gasificationModderfontein, South Africacoal-to-ammonia/fertilisers
Texaco (GE) coal gasificationOberhausen, Germanycoal-to-hydrogen & oxochemicals
HTW coal gasificationBerrenrath, Germanycoal-to-methanol
PRENFLO coal gasificationFürstenhausen, Germanycoal-to-syngas
PRENFLO IGCCPuertollano, Spainpetcoke/coal-to-energy/hydrogen
HTW MSW gasificationNiihama, Japanwaste-to-energy
Over 100 Gasifiers designed, built and put into successful operation by Uhde
ThyssenKrupp Uhde15
World‘s largest single-train IGCC: PRENFLO GasificationElcogas, Puertollano, Spain
Feedstock: petcoke / coal with addition of biomass
PRENFLO Gasifier
Gas Treatment
Coal PreparationASU
Combined
Cycle
New CO2 capturePilot Plant started-up
Oct 2010
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Gasification Focus: Coal-to-Liquids (CTL)
applying ThyssenKrupp Uhde‘s Gasification Technologies for the Gas- and Oil Downstream Sector
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CTL Technologies: 2 Main Principles for Indirect Liquefaction
PRENFLO
Gasification
Methanol to
Gasoline (MTG)
Oxygen
Coal or other
solid feedstocks
• Both are 3 Step Processes
• Thermal Efficiencies are Essentially Governed by Thermal Efficiencies of the
Syngas Production Process and by the Feedstock
Primarily
Gasoline
Fischer
Tropsch
Methanol
Synthesis
Product
Work-upPrimarily
Diesel
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Gasification CO-Shift
Coal
Condensate
Stabilizer
Hydro Cracker
Gas Turbine
Steam Syst.
Power
Steam
Fuel Gas
Fra
ctio
natio
n
Acid Gas
Removal
FT Offgas
FT Unit
Optional
FT Water
Stripper
Hydrogen
Stabilizer
Offgas
Stripper
Offgas
Coal to Liquids via Fischer Tropsch
FT operates
on gaseous
feedstock
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PRENFLOwith Direct Quench
1200 MWthermal 42 bar
PDQ
PRENFLO PDQ Features
• dry powder feeding
• 4 horizontal co-annular burners
• membrane wall
• direct water quench
• operation pressure flexible to requirements (25 - 42 bar)
• raw gas temperature outlet of quench (200 - 250 °C)
• slag lock-hopper system
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Coal to Liquids is not new Over 50% of Germany‘s fuels were made from coal by the mid 1900‘s
Source: Walter Teltschik, Geschichte der deutschen Großchemie, VCH
Germany‘s Coal-to-Liquids
Capacities in the mid 1900‘s:
• 4.275 million t/a applying
Bergius-Pier Direct Liquefaction and
• 1.55 million t/a applying
Fischer-Tropsch Synthesis
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World‘s Largest CTL complex: Sasol, South Africa150,000 Barrels per day of coal derived products
Sasol Synfuels Secunda
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Integrated Process Chain for the Production of Second Generation Synthetic Biofuels
Coal
Petcoke
Wood
Straw, etc.
Feedstocks Pretreatment Gasification Gas Treatment
Torrefaction
Synthesis
GaselTM
Fischer-
Tropsch (F-T)
Synthesis
and product
upgrading
(Hydrocra-
cking and
Hydroisome-
rization)
Bio-diesel,
Bio-kerosene
CO-Shift
AGR
Final
PurificationMilling
Liquid
Residues
2nd generation Biofuels: BioTfueL B-XTL process chain
PRENFLOTM
PDQ
PD
Q G
asif
ier
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SGC Energia
ThyssenKrupp Uhde and SGC Energia enter
into Master License and Supply Agreement for
multiple CTL projects applying PRENFLO® PDQ
and SGCE‘s Fischer-Tropsch Process
�SGCE’s proprietary XTLH™ solution
September 2011: License and Supply
Agreement for 9,500 barrels/day CTL
Plant in Mozambique effectiveE N E R G I AE N E R G I AE N E R G I AE N E R G I A
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CTL Project Mozambique
Adansonia digitata Trees, Mozambique, Africa
PRENFLO® PDQ licensed
High-ash coal (37 %) will be utilised for
generating clean Fischer-Tropsch fuels for
domestic and export use
Plant Capacity: 9,500 barrels/day
Plant Location: Mozambique, Southern Africa
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Coal to Liquids via MTG
MTG essentially un-coupled
with intermediate storage tank
MTG operates on liquid
feedstock (methanol)
Gasification CO-Shift
Coal
MTG Reactors
Hvy. Gasoline
Treating
Gas Turbine
Steam Syst.
Gasoline
Power
Steam
Fuel Gas
Fractionation
Gasoline
Blending
Acid Gas
Removal
Hvy. Gasoline
Fuel Gas Fuel Gas
LPGMethanol
Synthesis
MTG Plant
Optional
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Naphtha
Reforming
HDT/HDCDEWAX
Polygas
Process
Naphtha
Reforming
HDTHDT/HDC
Naphtha
Reforming
HDT/HDC
Recovery
RE
FIN
ER
YC
OA
L T
O L
IQU
ID
Date Sources: FT Date Sasol 2004 publication. H-Coal data from HRI1982 publication
Gasoline
Fischer Tropsch Fischer Tropsch
Co Catalyst @220C Fe Catalyst@340C
Fuel Gas 6 15 1.1
LPG 6 23 10.0
Naphtha 19 36 88.8 36.7
Distillate 22 16 43.3
Fuel Oil/Wax 46 5 20
Oxygenates 1 5 0.1 0.34
MTG H-Coal™ Direct
Liquefaction
MTG Product and Process Simplicity
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Uhde/EMRE provide full range service for synfuel projects
MTG Co-operation for over 30 years
ThyssenKrupp Uhde30
Summary
CTL is a proven technology with decades of experience in
successfully operating plants worldwide
CTL will produce sulphur and lead free gasoline
CTL can use a wide range of coal qualities, biomass and other
feedstocks
CTL is clean – projects already are permitted as Minor Source
CTL captures market ready CO2
(a substantial amount of CO2 is reused in the process)
Plants are scheduled to start operation in 2017
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Thank you for your attention
www.prenflo.com
PRENFLO Gasification Plant, Puertollano, Spain
April 2013