geochemical soil sampling for - ontario...geological traverses were carried out by the writer as...

52H14NE2003 2.22956 HAVOC LAKE 010

Geochemical Soil Samplingof

Havoc Lake Propertyfor

East West Resource Corporation

By OR. Middleton, P. Eng. ** "

February 8, 2002

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Table of Contents

IntroductionPurposeProperty Location and AccessClaims

Survey Method Analytical Method Survey Personnel

Previous WorkGeologyInterpretationConclusionReferencesCertificateTable of Soil Sample Descriptions and LocationsTables of Analytical Results - MMI-D

- ICPMS-80

1. Property Location l: l ,000,0002.a. Claim Map l :31,680 (l" = '/2 mile)2. b. Claim Map 1:50,0003. Grid Location l :20,0004. Magnetic Map I'M mile5. Magnetic Profile L 0+00 l :5,0006. Plan of geochemical anomaly locations l :5,000

Introduction

A soil sampling program commenced December 19, 2001 and was completed on January 16, 2002 over selected lines on the Havoc Lake property. Due to the mild fall into December the soil was not frozen which allowed easy collection. However due to severe wind storms a large number of trees had been up rooted or snapped off resulting in extensive "blow down" which covered the previous grid lines. A number of days were spent cutting out access along the lines to get to the sample sites, resulting in slow production.

Purpose

The purpose of the survey was to collect the "B" soil immediately below the humus layer which was often at less than 10 cm depth and analyse using MMI techniques and ICPMS at X RAL Labs in Don Mills, Ontario to test for the presence of Pd, Ni, Co in search for a Noril'sk type deposit. In addition a number of other elements were run to test for rare earths due to the proximity of alkali porphyry intrusions and pervasive hematite alteration suggesting the presence of an Olympic Dam setting.

Property Location and Access

The Havoc property is located near 500 N lat, 890 W long. The property is approximately 150 km north of Thunder Bay and 35 km south of Armstrong. Access is by gravel-sand lumber roads off of Hwy 527. Skidoo trails have been cut out along L400 W and 1600 N for access to 800 E. Several trails and old lumber road reach the south and east part of the property, (see Fig. 3)

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LAKE

Claims

The claims covered by this geochemical Survey are part of a much larger group of claims. The claims covered are 1229591, 1229679, and 1229681.

Claim #

1229578

1229579

1229582

1229590

1229591

1229592

1229678

1229679

1229680

1229681

1229682

1241309

1241310

1241311

1241312

1241313

1244283

1244284

1244285

Due Date

Feb 12, 2002

Feb 12, 2002

Feb 12, 2002

Feb 12, 2002

Feb 12, 2002

Feb 12, 2002

March 25, 2002

March 25, 2002

March 25, 2002

March 25, 2002

March 25, 2002

April 10, 2002

April 10, 2002

April 10,2002

April 10, 2002

April 10, 2002

May 12, 2002

May 12, 2002

May 12, 2002

NORWOOD LAKE

02' of

8?B

tfAVOC LAKF

SWEET

o •l

1229679

l ! 1229592

lit WEST RESOURCES CORPORATION

HAVOC PROPERTY1229590

CO

lCu

; 1229680

233489

————————l II2I6B3Il 121682?f- -© \ IP

I2I6826' I2I6825I |2|6BI4.

5542000 H.

5541500 N-

9541000 N.

5S40SMN-

55*0000 N-

5539500N-

5539000 N.

5533500 N_

55^eDDON..

5537500 N.

5537000 N.

5536500 N-

55^H)OON_

5S35SOON.

5535000 N.

5534500 N.

553*00 N.

5533500 N.

5533000 N.

5532500 H.

5532100 N-

5S31SOOK-

5531000 N.

5530500 N.

1241 1241310309

1241312

1241311

-i-

1244283

1192672

1241313

1229678

1229679 1229680

--QJ

12295921229591 1229

681El

1229682

1229683

1229684

1192673

1192674

1229590

-a—i ~cb

i 1216 ! 828

112168311

l i i1216826! I12168H! 1216825!i___ i___i___

-HP l l

1229579

B—-——- B——————

1244284 1244285 1229582

i i a-- i -•a-- -———i

-. 1,0.35,0.30,0.30,0

S4MPl f rift

.1.0.35,0.30,0.30,0

-N-

SC^LE I : JO 000

-5542DOON

.554150) N

.554100) N

.5540500 N

.554000) N

-5533503 N

-553900] N

-5S3850DN

.5538003 N

.5537500 N

-5536KHN

-553600) N

-5535500 N

-5536000 N

JB34SOON

-S534000N

-5553500 N

J533000H

J53J500N

J532KON

J531500N

J531000K

-5530500N

R S MIDDLETON, P ENG

forEAST WEST RESOURCE CORPORATION

HAVOC LflKE CLAIMS, NIPIGON AREAGaochinical Survay

T h u nd er Bau Hint nig DivisionT h o n .T. r B . y . On t . r ] o

D.I.! J.n 31, 2002 HAP: NTS Orl.n bg! B J C.v.n M.pt;

l: To, o o tf

Survey Method

Soil samples(up to 200 -300 grams) were taken along lines at 800 m spacing that traversed a large magnetic anomaly at 50 m intervals. "B" soils immediately below the humus layer were obtained by removing the humus with a spade and taking the very first brown-tan soil and placing up to 300 grams in plastic "zip lock" bags. In some cases the B soil was a tan coloured clay to silt and in some cases a reddish brown soil (slightly sandy). Some samples were taken of the upper humus layer where soil was more than 4 feet. In the bottom of valleys a black clay layer occurred beneath the humus up to 5 cm thick which may contain manganese. This clay was found to be conductive as well and was analysed in the case of 3 samples.

A total of 122 soil samples were taken On L16N, L8W, LO, L8E, L6N to cover the large east west trending mag high and a north south "tail" to this magnetic high (L6N).

A table of soil sample descriptions is presented here with locations

Survey Personel

The Soil Sampling Program was carried out by a trained crew from Gull Bay, Ontario.

November December 2001

Ken King Nov. 19,26, Dec. 20 - 23, 26 - 31

Roger King Dec. 20 - 23, 26 - 31

January 2002

Ken King Jan. 2-4, 6- 11, 16

Roger King Jan. 2 - 4, 6 - 11

Rita King Jan. 2-4, 16 - 17

James Tyance Jan. 3, 6

Roger Netemegesic Jan. 4, 6, 8, 9

Wayne King Jan. 8-11,16

R. Middleton Dec. 19 - 21, Jan 16, 17,18

Supervision was by Roger King throughout project and R. Middleton, P. Eng.

Report by R. Middleton January 19, 28 - 30, Feb 8

Previous Work

Geological traverses were carried out by the writer as early as August 1999 with D. Pyke and K. Gunnison. In July - August 2000 more mapping was done by the writer with visitations by Dr. Jim Franklin and prospecting was done by Dave Baker assisted by R. Tweedie. Remnant magnetism samples were taken by Baker and all of this work has been summarized by R. Middleton et al. Dec. ,2001.

Ground lines, magnetics and induced polarization - resistivity were contracted to D. Patrie (2000) and further IP magnetics was reported by D. Patrie (2001). Eight 400 m testlines of airborne magnetics - Megatem EM were flown by Fugro Airborne Surveys in August 2001 and merged with the previous data flown on 5 lines in February 2000, R. Caven (2001). The ground and airborne survey outlined a large magnetic feature that is "T" shaped with a north-south tail that appears to demark the Black Sturgeon Fault trace and a possible feeder dike.

The original magnetic anomaly was located by the GSC (1962) on map 2112G."Jack Innes Lake"

Geology

A large part of the property is covered by a Nipigon gabbro (diabase) sill up to 100 m thick however windows into Archean basement occur on the north west boundary of the property near the Kopka River and west of Cry Lake on the Roger King option where mafic volcanics and tuffs occur.

A north south trending valley corresponds to the magnetic high anomaly suggesting that the reversely polarized diabase sills have been removed in the valley exposing positive magnetic values related to other mafic intrusive or iron bearing rocks below. The valley is overburden covered there for future drill testing will be required.

Large boulders of red quartz-feldspar porphyry intrusive and fragmental rocks of the same composition have been found on the property that are interpreted to have originated from the English Bay alkali intrusive complex. Numerous boulders of diabase also occur. The glacial striations indicate that the last ice direction was 2450 which would explain the large preponderance of alkali porphyry boulders from English Bay. The full extent of this alkali intrusion is not known but dikes of porphyry cutting Sibley sediments were found on a new road south of Voogers Lake, as well as outcrops of a fragmental high level phase of the quartz eye- feldspar porphyry. Boulders of conglomerate were also observed containing jasper, iron formation, volcanic pebbles (possibly basal Sibley). The geology has been extensively described by Middleton etal 2001.

\SHEET 52.

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\

Interpretation

Anomalous zones are plotted on l :5,000 plans (Fig. 5) and a location map of the grid relative to claim and local topography is appended., Figure 3. (l :20000). The anomalous Ni values appear to plot on the margin of the magnetic anomaly where as the Co values are also on the eastern margin near a point where a significant north south magnetic trend intersects the main magnetic anomaly. Some zones of elevated barium occur possibly reflecting Sibley material in the soil. The MMI-D extraction give lower values than the MMI-B technique for Pd, Ni, Co and as a result it was decided to do a regular -80 mesh screen sample fraction assaying with ICPMS/80 pkg that also uses multi acid extraction. The anomalous areas from this method are also compiled on the l :5,000 Geochemistry Map (Fig. 5).

The ICPMS80 data that resulted from the analysis of the - 80 mesh soil fraction produced a number of Cu-Co anomalies that are associated with the magnetic high. Of particular note is LO/1650 N, L16N/550E, L16N/650E, L8E/16N - L8E/15N.

A Cu-Zn-Ag anomaly occurs at L16N/1250E that may reflect a different style of mineralization than the magnetic - mafic intrusion hosted Cu-NiJPGE style.

Glaciation and Soil Profile

The grid mainly covers a series of valleys between high hills of Nipigon diabase sills. The over burden is composed of a sandy till which has been exposed by the lumber road accessing the property. An upper Ao humus-moss layer often covers a fine silty tan coloured layer above a browner sandy till. In the lower part of the valley a deep 1.5 m layer of black humus-rotten trees occurs often above a black clay layer 0.2 - 0.3 m thick. This black clay may represent bog manganese + carbon and is conductive.

Reddish brown sandy soils were observed on line 16 N at higher elevations reflecting a significant increase in iron.

The glacial direction is 2450 and numerous boulders of red quartz eye porphyry from the English Bay intrusion (1539 my) are present.

It is possible that deep scouring of valleys has occurred, transporting the bedrock 2-3 miles down ice. This is supported by the fact that boulders of English Bay intrusive rock are also transported 2-3 miles from source.

Analytical Method

Each sample was subjected to a weak partial extraction, scheme method developed in Australia called Mobile Metal Ion or MMI-Method D for Pd, Ni, Co, Nb, Y, Ti, Rb, Mg, Cr, and an additional rare earth package has been appended. No sample preparation such as screening or drying was used. A 50 gram sample was treated with a multi-element extraction. These elements

were extracted from the Mn coatings of the soil grains and from any moisture between soil

particles. Values are determined by ICP/MS in the ppb range.

A second part of the 200 gram sample was screened to -80 mesh and attacked with a multi acid

element extraction and analyzed with an ICP.MS.XRAL Method ICMS80 Multi acid ICP +

ICPMS. The elements analysed for are listed below with detection limits. This combination was

used to confirm MMI results and to test for Cu as well as U and Th in the event that an Olympic

Dam setting was present.

Recommendations

Additional soil sampling on L4E, GE (26N - 6N) should be done and additional lines (N-5) at

16E, 12E, and 24E from Vooges L. shore to 20N. An Au-Pt-Pd analysis should also be done on

all soils -80 mesh fraction. Other lines on the property to be sampled would include L4E, L6E

(angle grid) 1600E to 2000E.

Respectfully Submitted,

R. S. Middleton, P.Eng

ICP MS/80 ELEMENTS MEASURED

ElementAluminumAntimonyArsenicBariumBeryliumBismuthBoronCadmiumCalciumCeriumCesiumChromiumCobaltCopperGallium

Gold Hafnium Indium Iron

AlSbAsBaBeBiBCdCaCeCsGrCoCuGa

Germanium GeAu Hf In Fe

Lanthanum LaLead PbLithium LiLutetium LuMagnesium MgManganese MnMercury HgMolybdenum MoNickel NiNiobium NbPhosphurus PbPotassium KRubidium RbScandium SeSelenium SeSilver AgSodium NaStrontium SrSulphur STantalum TaTellurium TeTerbium TbThallium TlThorium ThTin SnTitanium TiTungsten WUranium UVanadium VYtterbium YbYttrium YbZinc ZnZirconium Zr

Detection Limit*Q.01%-15%

"O.OSppm - r/o**0.2ppm - r/o

*5ppm - r/o*0.1 - 100ppm 0.04 ppm - r/o

0.02 ppm- r/oQ.01%-15%

O.OSppm-0.1 "/o

*1 ppm-r/o0.1 ppm - r/o

0.5 ppm - 500 ppm0.05 ppm - 500 ppm

0.1 ppm-r/o

*0.02ppm - G.05%*0.02ppm - D.05%

0.01 "/o -Wo0.5ppm - Q.1%O.Sppm - r/o1ppm - 507o

0.01 ppm -Q.1%O.or/o-15%*5ppm -1%

O.OSppm - r/o O.Sppm- r/o

0.1 ppm -0.1 "/o SOppm - r/o 0.01 "/o- 15% 0.2ppm - r/o 0.1 ppm - r/o

0.2ppm - Q.1% 0.02ppm - 10ppm

0.01 "/o - 150/00.5ppm - r/oo.or/o-15%0.05ppm -r/o

*0.02ppm - D.05%O.OSppm - -\ 0A0.02ppm-iy00.2ppm - r/o

'O.lppm-0.1%0.01 o/o - 150/00.1 ppm-r/o0.1 ppm-r/o1ppm - r/o

O.Sppm-O.r/oO.lppm-1%lppm-1%

O.Sppm -1"!*)

* Leach is partial for these elements and should be considered partial for other elements** Volatilization may result in losses

Survey Cost Breakdown

Gull River Crew

Time, Truck, Skidos, & sled rental S 11,300.40

Fuel S 713.74

Company Truck

Nov. 19 - Jan. 19 (24 days @ 550/day) S l ,200.00

Shipping of Samples S 78.11

R. Middleton 10 days @ S 250/day S 2,500.00

Food 8i Accomodation for R/ Middleton + crew S 524.77

Assaying 122 samples MMJ-D, ICPMS80, A prep $ 5,770.51

Drafting A Report Preparation S 1,000.00

TOTAL S 23,087.53

Cost per claim breakdown:

66 Samples on 1229591 = S 11,354.40

4f Samples on 1229679 ~ S 7,948.08

10 Samples on 1229681 = S 1,892.40

Total S 23,087.53 1 122 samples = cost per sample S 189.24

Certificate

1. I, Robert S. Middleton am a graduate of the Provincial Institute of Mining (Hailybury, Ontario) (1965)- Mining Diplo; Michigan Technological University 1968, B.S. Applied Geophysics, 1969 M.S. Applied Geophysics.

2. Atended University of Toronto 1970 Ph. D Geological program.

3. Employed during the summers

1965 Selco Exploration-NW Ontario -Magnetics

NE Quebec -EM, Mag, Gravity A Geological mapping

1966 - Selco Exploration- NE Ontario -Geological mapping

1967 Calumet A Hecla Mining Keweenaw IP(drill hole) surface and underground

Michigan - Mag and drill hole IP

4. Employed Ontario Dept. of Mines, 1968 -1971, Mag, Geology, Gravity, Mining Regs.

5. Employed Barringer Research Ltd., 1971 1974, Airborne geophysics, Consulting, Ground Geophysics

6. Employed Rosario Resources Corp., 1974 - 1980,Timmins, Honduras, Nicaragua, Dominican Republic

7. Employed Newmont Exploration of Canada, 1982 - 1983, Quebec, Ontario, Newfoundland, NWT. Manager of Exploration, RC + diamond drill projects, geophysics.

8. Consulting Based from Timmins, 1983 - 1990, various Au, Basemetal projects Manitoba, Quebec, Ontario, USA, Scotland. RC drilling and numerous diamond drill programs.

9. Management Various junior mining Co. 1990-present exploration VMS Cu, Zn, gold, diamonds, Cu-Ni-PGE, Cross Lake discovery Zn,Ag,Cu near Timmins.

lO.Member of Ontario Association of Professional Engineers, Geological Association ofCanada (GAC), Canadian Institute of Professional Engineers, Association of Exploration Geochemists, Society of Economic Geologists, Society of Geological Applied to Ore Deposits.

11 .Special Assignments

1992 Uganda - Evaluation of Kilembi Proterozoic Cu, Ni, Co

1993 Siberia Diamonds A Kimberlites

1995 NWT Valuations of Lac de Gras area projects

1996 Kyrgystan Gold deposit evaluation

R. S. Middleton, P.Eng Date: February l, 2002

References

Caven, R. (Feb 17, 2001) Report on Airborne Geophysical Surveys on the Nipigon Plate Havoc Property Megatem + Mag and Magnetic Survey, Thunder Bay Mining Division.

Caven, R. (2001) A report on new Airborne Geophysical surveys on the Nipigon Plate Property of East West Resource Corporation Havoc Claim group, Thunder Bay Mining Division. Megatem II Sept 21, 2001

GSC (1962) Aeromagnetic Map l" = l mile G2112. Jack innes Lake Sheet

Middleton, R. etal (2001) Geological Report and remnant Magnetism Study on the Havoc Lake Property. Havoc Lake English Bay Area, Thunder Bay Mining Division.

Patrie, D. (2000) Geophysics Report on the Havoc Property, Havoc Lake sheet, District of Thunder Bay, Thunder Bay Mining Division for East West Resource Corporation, Sept. 2000 (IP, Max Min II, EM)

Patrie, D. (2001) Total FieldMagnetometer Survey on the Havoc Property, Havoc Lake sheet,District of Thunder Bay, Thunder Bay Mining Division for East West Resource Corporation, Jan 10, 2001 (Mag)

Sage, R. P., Breaks, F.W., Stott, G.M., Mcwilliams, G.M. and Robertson, D. 1974: Operation Ignance-Armstrong Obonga Lake-Lac des Iles sheet, District of Thunder Bay; Ontario Div. Mines, Preliminary Map P.963 Geol. Sen, Scale l inch to l miles, Geology 1973.

Sample # Line Location Description

363334363335363336363337363338363339363340363341363342363345363346363347363348363349363350363351363352363353363354363355363356363357363358363359363360363361363362363363363364363365363301363302363303363304363305363306363307363308363309363310363311363312363313363314363315363316363317

LOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLOLO

L16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16N

26+00 N25+50 N25+00 N24+50 N24+00 N23+50 N23+00 N22+50 N22+00 N20+50 N20+00 N19+50N19+OON18+50N18+00 N17+50 N17+OON16+50 N15+50N15+OON14+50 N14+00 N13+50N13+OON12+50 N12+00 N11+50N11+OON10+50N10+00 N8+00 W7+50 W7+00 W6+50 W6+00 W5+50 W5+00 W4+50 W4+00 W3+50 W3+00 W2+50 W2+00 W1+50 W1+00 W0+50 W

0+00

fine - siltfine - siltfine - siltfine - siltfine - siltfine - siltclay/finefine - siltfine - siltfine - siltfine - siltfine - silt

-silt

clay max finefine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltclay mixfine - siltclay mixfine - siltsandfine - siltclayclayclayclayfine - siltfine -siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - silt

fine

fine

363318363319363320363321363322363323363324363325363326363327363328363329363330363331363332363333363395363396363397363398363399363400363401363402363403363404363405363406363407363408363409363410363411363412363425363366363367363368363369363370363371363372363373363374363375363376363377363379363380363381363382

L16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL16NL6NL6NL6NL6NL6NL6NL6NL6NL6NL8WL8WL8WL8WL8WL8WL8WL8WL8WL8WL8WL8WL8WL8WL8WL8W

0+50 E1+00 E1+50 E2+00 E2+50 E3+00 E3+50 E4+00 E4+50 E5+00 E5+50 E6+00 E6+50 E7+00 E7+50 E8+00 E8+50 E9+00 E9+50 E10+00 E10+50 E11+00 E11+50 E12+00 E12+50 E13+00 E2+50 W3+00 W3+50 W4+00 W4+50 W5+00 W5+50 W5+87 W6+25 W10+OON10+50N11+OON11+50N12+00 N12+50 N13+OON13+50 N14+00 N14+50 N15+00 N15+50N16+50 N17+OON17+50N18+OON

fine - siltfine - siltfine - clayfine - clayclayfine - siltfine - siltfine -siltfine - siltfine - siltfine - siltfine - siltfine - siltclayfine - siltfine - siltgravel, coarse sandfine - gravelclayclayclaymix fine sand Smix fine sand &mix fine sand Sgravelfine - silthumushumussandy clay - tanfine silt - clayfine silt - clayhumusblack clayfrozen sandbrown sandfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - siltfine - silt

gravelgravelgravel

363383 L8W 18+50N fine - silt363384 L8W 19+00 N fine - silt363385 L8W 19+50 N fine-silt363386 L8W 20+00 N fine-silt363387 L8W 20+50 N fine - silt363388 L8W 21+00 N fine - silt363389 L8W 21+50N fine - silt363390 L8W 22+00 N fine - silt363391 L8W 22+50 N fine - silt363392 L8W 23+00 N fine-silt363393 L8W 23+50 N fine - silt363394 L8W 24+00 N fine-silt363413 L8E 15+50N reddish brown sand363414 L8E 15+00 N reddish brown sand363415 L8E 14+50 N brown black sand363416 L8E 14+00 N reddish brown sand363417 L8E 13+50 N dark brown sand363418 L8E 13+00 N dark brown sand363419 L8E 12+50 N brown red sand363420 L8E 12+00 N brown red sand363421 L8E 11+50N brown sand363422 L8E 11+OON black clay363423 L8E 10+50 N black clay363424 L8E 10+00 N black clay

Sample Ident Scheme Code Analysis Unit Detection Limit 363301 363302 363303 363304 363305 363306 363307 363308 363309 363310 36331 1 363312 363313 363314 363315 363316 363317 363318 363319 363320 363321 363322 363323 363324 363325 363326 363327 363328 363329 363330 363331 363332

Mg Ti MMI-D MMI-D ppb ppb

100 1700 2420 3130 2030 4160 2410 3410 3590 4130 2720 1910 3500 3230 3890 2880 5610 3890 4600 2300 13182 3790 10277 4530 2040 2430 1670 2330 4790 6770 4910 7990 5060

Cr Co MMI-D MMI-D ppb ppb

1 1 23 ^ 19 ^ 25 -d

1 -d 34 ^ 9 ^

45 ^ 52 ^ 13 ^ 6 ^ 8 ^ 33 *:1 67 *:1 19 ^ 16 -d

341 5 9 -el 18 -si 3 ^

<1 <1 21 <1 4 ^

245 2 34 <1 11 <1 2 <1 2 -*1 15 1

139 7 39 <1

219 3 17 *:1

Ni MMI-D ppb

1 3 7 1

<1 3 2 3

el 2

<1 <1 2

<1 3 4 4 1 2 3

d *:1 <1 7 10 4 ^ 2

<1 2 2 22 <1

Rb MMI-D ppb

3 4 O 13 O 14 4 O O O 5 5 O 8 O 5 6 6 5 O O O O O 0 7 10 7 O 3 O 12 ^

Sr Y Nb Pd MMI-D MMI-D MMI-D MMI-D ppb ppb ppb ppb

1 0.1 0.1 0.1 0.1 34 16.2 0.2 0.2 O.1 31 27.2 0.1 0.1 O.1 40 36.5 0.1 0.1 O.1 84 28.5 O.1 ^.1 O.1 24 56.3 0.1 0.1 ^.1 48 35.6 0.1 O.1 ^.1 21 53.4 0.2 0.2 O.1 12 47.7 0.1 0.2 O.1 17 73.3 O.1 ^.1 O.1 58 29.6 O.1 O.1 ^.1 77 50.3 0.1 <0.1 *:0.1 58 62.3 0.3 0.1 ^.1 38 58.9 0.2 0.3 ^.1 61 67.2 0.2 ^.1 *:0.1 27 42.6 ^.1 0.1 ^.1 14 83 0.7 1.1 O.1 40 88.3 0.1 <0.1 O.1 40 109 0.4 ^.1 O.1 57 37.9 O.1 <0.1 O.1 4 178 0.6 ^.1 ^.1

41 91 <0.1 0.1 O.1 26 105 ^.1 ^.1 -:0.1 6 70.2 0.4 0.8 ^.1 33 39.4 0.2 0.1 O.1 28 55.6 0.2 O.1 ^.1 47 37.7 ^.1 <0.1 *:0.1 29 52.1 0.1 <0.1 ^.1 30 51.6 0.2 ^.1 O.1 14 127 0.2 0.5 -sO.I 24 110 0.4 <0.1 <0.1 37 99.8 1.2 0.8 ^A 36 181 0.2 ^.1 *:0/

Ba MMI-D ppb

0.1 139 158 136 105 149 158 151 142 156 163 75.1 136 93.8 217 177 179 218 231 402 64.7 185 79.9 193 181 255 96.9 290 67.2 260

t 99.6 l 173 l 107

Sample IdentScheme CodeAnalysis UnitDetection Limit363333363334363335363336363337363338363339363340363341363342363345363346363347363348363349363350363351363352363353363354363355363356363357363358363359363360363361363362363363363364363365363366

MgMMI-Dppb

10040403100473026602480303035204570217045303530455017703780359045402150152018902400322072801930187019402500336025801635315420159162690

Ti Cr CoMMI-D MMI-D MMI-Dppb ppb ppb

1 137 ^36 -d24 ^16 -M9 <'\

29 *:189 -M

240 -si ^1 ^4 ^

51 *:180 *15 *:1

22 *:14 373 14 *:13 1

75 <1<1 <110 <12 <^

2 <132 <13 <1

11 *19 <^10 <11 <1

:1 <17 <1

11 *1

112552362

*:11

<1<1<11

:1

2216

^12

<121

J1<141

<1<1<1<1

NiMMI-Dppb

3O509OO98^8O1720O0912O5O344170O11151197O

RbMMI-Dppb

120253035283242126832313042286341314838515340584955515556235

49

SrMMI-Dppb

0.188.661.674.649.727.257.454.663.946.213530

40.716

30.357.993.965.715.425.463.966.113859

60.955.314452.235.210710491.762.3

YMMI-DPPb

0.10.50.20.40.4O.10.30.80.3O.10.10.60.10.30.20.10.40.20.10.50.1O.10.3O.10.10.10.10.2O.1O.1O.10.4O.1

NbMMI-Dppb

0.10.10.10.10.1O.10.10.20.80.1O.10.20.30.1O.10.10.3O.1O.10.20.10.10.1O.10.1O.1O.1O.1O.1O.1O.1O.1O.1

PdMMI-Dppb

0.1O.1O.1O.1O.1O.1O.10.1O.1O.10.1O.1O.1O.1O.10.1O.10.1O.10.1O.1O.1O.1O.1O.10.1O.10.10.10.1O.1O.1O.1

BaMMI-Dppb

0.155.518228875.868.311953.598.712620791.785.970.460.577

20721612274.725321112340116329823218320343.541.851.7212


Mg TiMMI-D MMI-Dppb ppb

10037205070353048602940416033403850383038702690980

22904380243028302060222041105460286069303590500026403200345043705550

125711526217471

Cr CoMMI-D MMI-Dppb ppb

1 15 ^

65 226 *:111 *:129 -si16 ^18 ^13 -d33 *:133 -d11 -d2 "^15 "d13 -el35 -d

1 -si12 ^Q ^

23 ^71 -el14 <147 22 <130 <112 -el22 <123 <180 120 <110 t1<1 <12 <1

NiMMI-Dppb

1^432

<12

<11

<11^

122723385

ci32244225^^<1

RbMMI-Dppb

3465O40785OO04O9410O23674764OO5018OO

126303629524332332872254332406239595686252826262928222624332624

SrMMI-DPpb

0.188.377.378.467.746.663.477.773.364.279.541.94.5

25.269

34.634.628.928.266.889.836.410117691.243.838.345.256.812912585.5106

YMMI-Dppb

0.1O.10.20.3O.10.2O.1O.10.10.10.20.1O.1O.10.10.30.10.10.10.20.20.50.30.20.20.40.40.20.4O.10.2O.10.3

NbMMI-Dppb

0.1O.10.20.10.1O.1O.1O.10.1O.10.10.1O.1O.1O.10.2

O.1O.1O.10.10.20.10.1O.1O.1O.10.10.10.30.1O.10.10.1

PdMMI-Dppb

0.1O.1O.1O.1O.1O.1O.10.10.10.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.10.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.1O.1

BaMMI-Dppb

0.125015712620310320127625920421890.576.610213312425921210129612854.858.215011912513851.214413588.680.949.3


MgMMI-Dppb

100394055906830252013509030944010866116551207670501617428904140453072804000484063703360487079101256612596180274400

Ti Gr CoMMI-D MMI-D MMI-Dppb ppb ppb

1 1146 -el31 ^

141 *:127 -el3 *:14 *M24 *:1

1 *:13 ^2 <^5 <^1 *:19 ^

20 ^21 ^171 -:1

3 <1113 *:1121 <123 <1<1 <122 <1<1 -d<1 <1<1 <183 t1

NiMMI-Dppb

133142

*:1<1<1<1^<1<12112^<1<1 d37

<1<1 d3

RbMMI-Dppb

34O5355O40O434505O88O443964

1142124161849

2916131

123723332153277944272821^47

SrMMI-Dppb

0.158.411714335

40.53665

79.282.969.531.489.423.991.274.518291

17110668.418362.661.976.666.838.4

YMMI-Dppb

0.10.3O.10.20.30.20.10.4O.10.10.40.1O.1O.10.10.10.3O.10.10.2O.1O.10.10.10.1O.10.1

NbMMI-Dppb

0.10.50.10.6O.1O.1O.10.1O.1O.1O.1O.1O.1O.1O.1O.10.6O.10.30.3O.1O.1O.1O.1O.1O.10.3

PdMMI-Dppb

0.1O.1O.10.10.10.10.10.10.10.1O.1O.1O.1O.10.1O.1O.1O.10.10.1O.1O.1O.1O.1O.1O.1O.1

BaMMI-Dppb

0.114020918446.120139.950.614987.699.724.859

88.520110212120413299.712053418716914189.794.7

Sample IdentScheme CodeAnalysis UnitDetection LimitDUP-363301DUP-363313DUP-363325DUP-363337DUP-363351DUP-363363DUP-363375DUP-363388DUP-363400DUP-363412DUP-363424

Mg TiMMI-D MMI-Dppb ppb

10017903780227030402550

159713680301042402960

19225

Cr CoMMI-D MMI-Dppb ppb

1 119 ^58 -d13 ^13 -:1

5 *:1•ci *:150 *:112 -ci

149 <111 <1•ci <1

NiMMI-Dppb

122333

*:12

^32

<1

RbMMI-Dppb

30OO

613

4OO

568

SrMMIppb

13335293227

431271537

1

I-D

0.117.268.352.735.463.8107

63.537.961.524.271.7

YMMI-Dppb

0.10.10.10.1

0.1O.1O.1

0.20.40.2

0.10.1

NbMMI-Dppb

0.1O.1

0.2O.1O.1O.1O.1

0.2O.1

0.50.1O.1

PdMMI-Dppb

0.10.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1

BaMMI-Dppb

0.113710724584.5241

49.420957.713183

96.7

Sample IdentScheme CodeAnalysis UnitDetection Limit36330136330236330336330436330536330636330736330836330936331036331 1363312363313363314363315363316363317363318363319363320363321363322363323363324363325363326363327363328363329363330363331363332

LaMMI-Dppb

0.10.30.20.10.10.10.10.30.2

•0.1O.1

0.20.40.30.30.10.80.20.7

O.11.60.20.20.60.30.2

•0.10.20.20.30.41.70.2

T a CeMMI-D MMI-Dppb ppb

0,50. 5O.5O.5•0.5O.5O.50.50.5O.50.50.5O.5O.50.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.50.5O.5O.5O.5O.5O.5

0.10.40.30.30.20.20.30.80.40.20.10.40.70.50.70.21.60.52.10.2

10.40.31.20.50.40.10.30.40.70.74.91.4

PrMMI-Dppb

0.1O.1O.10.10.1O.1O.1O.1O.1O.1O.1O.10.10.1O.10.1

0.2O.1

0.2O.1

0.3O.1O.1

0.1O.1O.1O.1O.1O.1O.1O.1

0.4O.1

NdMMI-Dppb

0.10.30.1

O.10.10.1

O.10.20.1

O.10.10.10.30.20.20.10.70.20.6

0.11.10.10.10.50.20.2

O.10.10.20.20.31.50.2

SmMMI-Dppb

0.1O.10.1O.1O.1O.10.1

0,10.10.10.10.1

0.10,1

0.10,1

0.2O.1

0.20.10.2

O.1O.1

0.10.10.1

O.10.1

O.10,1

O.10.3

O.1

GdMMI-Dppb

0.10.1O.1O.10.10.10.10.1O.1O.1O.1

.•0.10.10.10.10.1

0.20.1O.1O.1

0.2O.1O.1

0.10.10.1O.1O.1O.1O.1O.1

0.3O.1

TbMMI-Dppb

0,10.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.10.1O.10.10.1O.1O.1O.1O.1O.1O.1O.1

ErMMI-Dppb

0.1O.10.1O.1O.10.10.1O.1O.1O.1O.1O.1O.1O.10.10.1O.1O.1O.1O.10.10.10,10,1O.1O.1O.1O.1O.1O.1O.1

0.20.1

YbMMI-Dppb

0.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.1O.10.10.1O.1O.1O.1O.1O.1

0.2O.1

ThMMI-Dppb

0.5O.5O.5O.5O.5O.5O.5O.50.50.5O.50.5O.5O.5O.5O.5O.5O.50. 5O.5O.5O.5O.5O.5O.5O.50. 5O.5O.50. 5O.5

0.6O.5

Sample Ident Scheme Code Analysis Unit Detection Limit363333363334363335363336363337363338363339363340363341363342363345363346363347363348363349363350363351363352363353363354363355363356363357363358363359363360363361363362363363363364363365363366

LaMMI-Dppb

0.10.30.20.60.5

O.10.30.70.5

0.10.20.90.20.40.20.10.50.20.10.50.20.10.50.10.3

O.10.20.30.10.1

0.10.60.1

TaMMI-Dppb

0.50.50. 5O.50. 50. 5O.50. 50. 50. 50. 50.5O.50. 50. 50. 50. 5O.50. 5O.50. 50. 50.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5

CeMMI-Dppb

0.11

0.40.80.90.20.71.61.20.20.31.50.50.70.40.50.90.30.31.30.40.30.60.20.40.20.50.70.20.1

O.10.90.3

PrMMI-DPPb

0.1O.1O.1O.1

0.1O.10.1

0.2O.10.1O.1

0.2O.1O.1O.1O.1

0.10.1O.1

0.1O.1O.1

0.1O.1O.10.1O.1O.1O.1O.10.1

0.1O.1

NdMMI-DPPb

0.10.40.20.40.4

O.10.20,70.4

O.10.10.80.20.30.20.10.50.20.10.50.1

O.10.40.10.2

O.10.20.2

O.10.1O.1

0.50.1

SmMMI-DPPb

0.1O.1O.1

0.20.1

O.10.10.20.1

O.1O.1

0.2O.1O.10.10.1

0.1O.1O.1

0.10.1

O.10.10.1

O.1O.1O.1O.10.1O.1O.1O.10.1

GdMMI-DPPb

0.10.1

O.10.1

0.1O.10.1

0.2O.10.1O.1

0.20.1O.1O.1O.1

0.10.1O.1

0.2O.1O.1O.10.10.1O.1O.1O.1O.10.1O.1O.1O.1

TbMMI-Dppb

0.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.10.10.1O.1O.1O.1O.10.10.1O.1O.1O.10.10.1O.1

ErMMI-DPPb

0.1O.10.10.10,1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1

YbMMI-Dppb

0.1O.10.1O.1O.1O.1O.1

0.1O.1O.1O.1O.1O.1O.10.10.1O.1O.1O.10.10.1O.1O.1O.1O.10.1O.1O.10.1O.10.1O.1O.1

ThMMI-DPPb

0.5O.5O.5O.5O.5O.5O.5O.5O.5O.50. 5O.5O.50.5O.5O.5O.5O.5O.5O.5O.50.5O.5O.5O.5O.5O.5O.5O.5O.5O.50.5O.5


LaMMI-Dppb

0.1O.1

0.20.2

O.10.3

0.10.10.10.10.30.1

O.1O.1

0.10.4

O.10.10.10.40.20.70.40.30.20.50.40.20.60.10.4

0.10.5

TaMMI-Dppb

0.5O.5O.50.5O.5O.50.5•cO.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.50.5O.5O.5O.5O.5O.5

CeMMI-Dppb

0.10.30.30.3

0.10.70.10.50.30.50.40.20.10.10.2

10.10.20.50.60.40.80.80.50.4

11.10.51.30.10.40.10.4

PrMMI-Dppb

0.10.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.10.1O.1O.1

0.1O.1O.1O.1O.1O.1

0.2O.1O.1O.1

0.1O.1O.1

0.1O.1O.10.1

0.1

NdMMI-Dppb

0.1O.1

0.20.1

O.10.3

O.10.1

O.10.10.20.1

O.1O.1

0.10.4

0.10.10.10.30.10.70.30.30.20.40.30.20.4

0.10.3

O.10.4

SmMMI-Dppb

0.1O.1O.10.10.1O.10.10.10.1O.1O.1O.10.1O.10.1

0.1O.1O.1O.1

0.2O.1

0.1O.10.1O.1

0.10.1

O.10.2

O.1O.1O.1

0.1

GdMMI-Dppb

0.10.1O.1O.10.1O.1O.10.10.10.1O.1O.1O.10.1O.1O.1O.1O.10.10.10.1

0.20.1O.1O.1O.10.10.10.1O.10.1O.10.1

TbMMI-Dppb

0.1O.1O.10.1O.10.1O.10.1O.10.1O.1O.1O.10.10.1O.1O.1O.1O.1O.10.10.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1

ErMMI-Dppb

0.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.10.1O.10.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1

YbMMI-Dppb

0.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.1O.1O.1O.1

ThMMI-Dppb

0.50.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.50.5O.5O.5O.5O.50.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5


LaMMI-Dppb

0.10.40.20.40.20.30.10.80.10.30.80.10.1

O.10.10.10.5

O.10.40.30.1

O.10.10.1

O.1O.1

0.3

TaMMI-Dppb

0.5O.5O.5O.5O.5O.50.50.5O.50.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5

CeMMI-Dppb

0.11

0.40.70.80.60.21.30.30.40.70.20.10.20.40.20.9

0.10.50.50.20.10.30.2

O.10.1

0.6

PrMMI-Dppb

0.10.1

O.1O.1O.10.1O.1

0.20.1O.1

0.2O.10.10.1O.1O.1

0.10.1O.1O.10.1O.1O.1O.1O.1O.1O.1

NdMMI-Dppb

0.10.30.10.30.30.3

O.10.60.10.20.7

O.1O.1O.1

0.10.10.4

O.10.20.20.1

0.10.1

0.1O.1O.1

0.2

SmMMI-Dppb

0.10.1

O.10.1

O.10.1

O.10.2

0.1O.1

0.1O.1O.1O.1

0.1O.1

0.1O.1O.1O.1O.1

0.2O.10.10.1O.1O.1

GdMMI-DPpb

0.1O.10.1O.10.10.1O.1

0.1O.1O.1

0.10.10.10.1O.10.1O.1O.1O.1O.1O.1O.10.1O.1O.10.1O.1

TbMMI-Dppb

0.10.1O.1O.10.10.1O.10.1O.10.1O.1O.10.10.10.10.1O.10.1O.1O.1O.1O.10.1O.1O.1O.1O.1

ErMMI-Dppb

0.10.10.1O.1O.10.1O.1O.10.1O.1O.1O.1O.1O.1O.10.10.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1

YbMMI-Dppb

0.1O.1O.10.10.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.1O.10.1O.1O.1O.1O.10.1O.10.1O.1O.1

ThMMI-Dppb

0.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5


LaMMI-Dppb

0.10.20.20.1

0.10.1

O.10.20.60.50.1

O.1

TaMMI-Dppb

0.50.5O.5O.5O.5O.5O.5O.5O.5O.5O.5O.5

CeMMI-Dppb

0.10.30.40.30.20.2

O.10.60.7

10.2

O.1

PrMMI-Dppb

0.1O.1O.10.10.10.1O.1O.1

0.20.1O.1O.1

NdMMI-Dppb

0.10.20.20.1

O.10.1

O.10.20.60.30.1

O.1

SmMMI-Dppb

0.1O.10.1O.10.1

0.1O.1

0.10.20.1

O.1O.1

GdMMI-Dppb

0.10.1O.1O.1O.1O.1O.10.1

0.1O.1O.1O.1

TbMMI-Dppb

0.1O.1O.1O.1O.10.1O.1O.1O.10.1O.10.1

ErMMI-Dppb

0.1O.10.1O.1O.10.1O.1O.1O.10.10.1O.1

YbMMI-Dppb

0.1O.10.1O.1O.10.1O.10.1O.10.10.1O.1

ThMMI-Dppb

0.50.50.5O.5O.50.5O.5O.5O.5O.5O.5O.5

Sample Ident Al Ca Gr Cu Fe K Li Mg Mn Na PScheme Code ICMS80 ICMS80 ICMS80 ICMS80 ICMS80 ICMS80 ICMS80 ICMS80 ICMS80 ICMS80 ICMS80Analysis Unit "/o "/o ppm ppm 07o "/o ppm "/o ppm 0Xo ppmDetection Limit 0.01 0.01 1 0.5 0.01 0.01 1 0.01 5 0.01 50363301 6.51 2.13 82 17.4 5.63 1.19 28 1.67 876 1.47 570363302 6.52 2 80 22.1 6.14 1.16 33 1.71 758 1.37 577363303 6.78 2.03 68 21.6 5.39 1.31 29 1.51 754 1.51 725363304 7.54 2.91 85 35.4 5.46 1.05 28 2.27 741 1.56 668363305 6.42 2.36 85 12 6.33 1.26 26 1.97 1010 1.49 583363306 6.59 2.34 87 13.8 6.52 1.2 28 2.01 862 1.46 642363307 6.96 3.32 95 45.1 6.34 1.08 29 2.62 1030 1.64 743363308 6.96 2.59 73 35.2 5.61 1.34 25 2.11 989 1.7 664363309 6.79 2.03 69 12.6 5.46 1.25 31 1.59 554 1.43 576363310 6.6 1.86 60 15.4 4.65 1.39 35 1.64 857 1.37 909363311 7.02 2.93 71 88.7 4.86 1.04 22 2.03 733 1.66 754363312 6.88 1.72 58 10.9 3.6 1.35 26 1.16 687 1.43 492363313 6.5 2.63 82 23.2 6.39 1.18 25 2.13 796 1.56 770363314 7.39 2.41 75 43.2 5.25 1.16 26 1.79 676 1.59 588363315 6.23 1.94 70 19.1 4.98 1.4 20 1.41 567 1.51 734363316 5.35 1.71 59 21.2 4.33 1.26 17 1.12 581 1.45 435363317 6.78 2.04 79 31.1 4.46 1.3 23 1.5 471 1.54 659363318 7.15 2.01 67 25.9 3.59 1.59 21 1.53 526 1.81 473363319 6.48 1.69 60 17.3 2.71 1.49 22 1.36 405 1.6 382363320 7.45 2.38 70 33.5 3.59 1.64 25 1.8 544 1.85 544363321 6.62 1.54 60 14.7 2.82 1.66 23 1.21 397 1.63 654363322 6.99 1.45 61 14 2.39 2.04 22 1.02 290 1.82 329363323 5.56 1.69 60 9.6 3.89 1.35 17 1.27 536 1.44 261363324 6.26 1.88 72 12.6 5.42 1.26 26 1.38 575 1.47 556363325 6.67 2.01 69 69.8 6.28 1.07 23 1.38 680 1.4 988363326 6.62 2.59 80 29.3 4.8 0.94 18 1.69 718 1.57 602363327 6.57 2.42 81 23.2 6.02 0.95 27 1.78 739 1.5 1050363328 6.95 2.85 14 765 13.9 0.82 27 0.72 1860 1.87 2720363329 6.08 2.23 70 35.4 5 1.18 21 1.46 675 1.62 702363330 7.1 3.24 15 519 11.9 0.67 19 0.61 1620 1.85 2510363331 6.67 1.9 55 110 3.93 1.5 21 1.11 706 1.79 458363332 6.96 3.28 72 76.5 5.89 0.96 23 2.51 903 1.68 414


AlICMS80"/o

0.017.346.156.615.178.318.038.735.116.716.656.235.656.975.776.986.266.638.137.527.296.527.276.946.027.597.366.956.646.947.517.346.75

CaICMS80"/o

0.015.611.771.621.613.222.984.561.862.571.812.331.652.471.842.71.771.582.743.641.82.31.981.61.411.891.652.071.491.691.621.532.47

CrICMS80ppm14542483945332448666159386049745962752866896161407058705563858176

CuICMS80ppm0.513716.552.479.81341562193141.314.455.421.462.524.345.712.83856.332926.431.517.911.49.335.128.528.220.618.52222.220.9

FeICMS80"/o

0.0112.23.644.084.096.527.097.912.64.274.233.312.45.073.114.194.334.296.069.163.265.33.353.012.334.053.014.582.62.843.523.414.69

KICMS80"/O

0.010.741.221.170.780.880.810.661.130.961.211.31.590.931.321.121.371.411.060.791.661.191.61.681.681.581.771.291.8822.192.151.21

LiICMS80ppm11217231418191420182733192019212324321923242121162419252025353825

MgICMS80"/o

0.011.741.110.930.821.021.011.081.191.841.251.871.091.61.192.021.181.12.010.881.541.661.541.220.831.471.091.791.131.091.331.271.74

MnICMS80ppm5194048346749128801730151047560341342536476843567547343768214903879195223843114733615663506388145831080

NaICMS80"/O

0.012.321.661.511.151.921.642.21.341.561.541.691.691.481.571.651.511.531.592.361.791.531.881.841.741.851.961.561.921.791.671.65

PICMS80ppm5018801784627421120914191035065637652620910603236974716068152800563943428330177482264473169473453573752


AlICMS80"/o

0.016.846.256.186.376.145.876.466.36.036.056.847.347.26.96.556.846.426.046.676.046.297.66.769.036.176.28.816.96.397.96.948.03

CaICMS80"/o

0.012.511.571.712.632.042.071.671.972.242.142.212.422.352.452.652.172.182.352.22.452.743.232.54.552.112.284.433.891.622.663.62111

CrICMS80ppm16541518164615669627573747079686369786362704462196160161859637493

CuICMS80ppm0.546.16.822.122.414.310.420.911.123.62019.71722.120.128.23023.338.520.644.456.411218219561.48026115713.667.88033.1

FeICMS80"/o

0.014.533.33.795.524.394.783.554.24.234.635.145.315.65.855.264.464.774.894.5264.727.243.876.054.14.92109.954.44.643.414.1

KICMS80"/o

0.011.171.611.491.161.251.221.561.41.241.251.311.261.271.2511.0810.981.091.0610.791.160.6211.120.731.051.731.51.712.2

LiICMS80ppm12420232624252023222327273030222120182118182017141920211326392738

MgICMS80"/o

0.011.911.021.092.031.561.591.051.361.611.711.761.861.931.851.741.41.381.391.381.541.721.261.430.891.411.540.80.551.032.162.141.75

MnICMS80Ppm55814145228166066956606725737796166686276987255895877105726866501120543108054956513003130415673475839

NaICMS8007o0.011.691.671.581.471.491.471.721.671.61.561.571.581.551.561.661.591.561.641.61.571.681.771.82.191.51.632.552.451.621.71.841.81

PICMS80ppm507206177901210628911790690533471543527590588499620555567562707567903287215065973531604920661527605648

Sample identScheme CodeAnalysis UnitDetection Limit363400363401363402363403363404363405363406363407363408363409363410363411363412363413363414363415363416363417363418363419363420363421363422363423363424363425

AlICMS80"/o

0.015.337.276.377.937.011.352.767.257.427.520.46.066.817.017.126.187.875.856.476.166.996.516.96.527.15.64

CaICMS80"/o

0.012.321.862.354.132.142.462.061.511.571.52.972.712.42.513.282.872.852.042.172.132.142.12.184.342.172.49

CrICMS80ppm1687175135616336174786687371336691637881646574597776

CuICMS80ppm0.515.622.332.752754.18.11917.118.219.115.146.316.323.227528.648.210.91513.240.32528.13033.918

FeICMS80"/o

0.014.224.224.9312.73.860.71.463.173.323.310.422.914.436.1110.24.56.53.394.714.84.514.483.082.933.695.26

KICMS80"/o

0.0111.631.250.641.080.280.542.032.052.20.061.511.461.251.051.231.221.61.521.391.261.371.921.5721.25

LiICMS80ppm114322219164152932311332133231739152528262428213320

MgICMS80"/o

0.011.361.521.280.811.280.230.481.231.281.240.21.031.621.91.161.82.261.221.381.631.81.731.191.891.451.82

MnICMS80ppm5624485771183045253115660362064512575375482214808729225285696485565873635165301170

NaICMS80"/o

0.011.621.651.692.51.690.190.221.811.761.880.041.031.71.542.141.571.541.671.61.511.571.541.631.851.721.55

PICMS80ppm5044867880620203969699314854995415111050326133028608731610487601573464309543535575786


AlICMS80"/o

0.016.056.556.677.796.886.885.976.125.446.767.79

CaICMS80"/o

0.012.012.762.053.071.711.652.242.72.382.452.36

CrICMS80ppm17681694166606765687784

CuICMS80ppm0.517.920.673.711843.218.425.254.618.316.829.5

FeICMS80"/o

0.015.336.966.616.194.342.784.344.524.414.733.98

KICMS80o/o

0.011.121.21.070.841.321.931.250.971.011.452.14

LiICMS80ppm12625241722232317152135

MgICMS8007o0.011.562.131.420.911.210.991.611.591.421.591.56

MnICMS80ppm58408467352690456602584612659766570

NaICMS80"/o

0.011.41.631.441.871.671.951.641.651.681.71.84

PICMS80ppm505207469791100614438526581458319607


BeICMS80ppm0.1110.91.31.11.10.91.21.211.21.211.10.911.21.31.11.71.31.20.81.11.21.21.11.211.21.21.2

BiICMS80ppm0.040.180.150.180.10.140.160.10.170.190.170.120.260.170.120.170.140.110.090.130.110,120.150.170.140.180.090.130.120.120.160.210.08

CdICMS80ppm0.020.180.160.180.160.170.190.190.240.180.170.150.210.190.160.180.190.180.150.230.190.20.20.220.160.220.160.20.350.20.690.330.22

CeICMS80ppm0.0530.533.530.837.239.428.134.732.727.635.141.831.729.731.532.430.435.550.131.868.13541.928.32929.428.631.441.227.4354046.6

CoICMS80ppm0.124.32320.230.322.223.428.821.519.218.426.81825.223.916.514.518.718.413.119.113.710.414.218.224.623.427.749.319.336.315.128.6

CsICMS80Ppm0.052.062.122.142.031.962.011.731.92.092.431.642.42.381.851.781.781.631.792.281.982.22.51.721.862.011.351.572.641.692.661.871.71

GaICMS80ppm0.0516.917.818.11517.217.216.720.919.818.914.815.121.815.718.61714.714.615.815.615.115.517.516.717.814.519.223.615.423.413.515.5

GeICMS80ppm0.10.20.20.10.10.20.10.20.20.20.20.20.10.10.10.20.20.20.10.10.2

^.10.10.10.10.20.20.20.40.10.20.10.2

InICMS80ppm0.020.050.050.040.050.040.050.050.040.050.050.040.040.050.040.040.030.040.030.030.040.030.030.040.040.070.050.050.10.040.080.040.05

LaICMS80ppm0.114.816.915.217.219.713.715.716.113.917.616.21614.314.216.215.215.318.916.330.217.621.114.214.214.213.515.517.513.215.918.717.8

LuICMS80ppm0.010.220.230.190.230.220.210.220.270.20.20.250.190.250.210.210.220.210.210.190.280.190.180.190.20.290.230.250.70.230.620.240.29


BeICMS80ppm0.11.10.91.1110.90.90.81.41.21.210.90.81.2111.31.31.51.11.51.411.41.21.41.11.61.81.81.2

BiICMS80ppm0.040.070.120.140.130.140.160.110.140.10.130.10.140.10.130.090.130.150.130.180.130.150.10.110.120.140.10.130.140.190.210.210.14

CdICMS80ppm0.020.320.140.180.170.250.330.30.260.190.150.220.150.180.170.160.150.170.20.30.140.220.150.140.140.160.130.180.160.170.20.160.16

CeICMS80ppm0.0547.737.232.328.133.130.735.836.441.730.633.131.730.326.349.330.531.428.852.942.740.545.739.83146.336.337.434.66581.175.634.3

CoICMS80ppm0.149.61316.913.34442.636.910.924.119.113.6917.811.822.115.21731.234.715.724.816.612.58.620.11318.79.712.516.913.925.1

CsICMS80ppm0.050.51.131.461.652.582.831.671.641.21.81.711.740.981.481.211.891.652.191.752.022.091.72.011.871.921.91.792.042.463.353.62.25

GaICMS80ppm0.0524.115.415.714.722.422.122.714.913.615.415.113.913.71513.715.21517.424.614.716.414.4151315.113.514.214.814.116.216.315.9

GeICMS80ppm0.10.50.50.30.20.20.40.20.10.20.20.20.50.20.40.20.30.30.40.70.20.30.20.20.20.30.10.40.50.20.20.20.2

InICMS80ppm0.020.120.040.040.040.050.060.070.040.060.040.030.030.050.030.040.040.040.050.080.030.040.040.030.030.040.030.040.030.030.040.040.04

LaICMS80ppm0.120.418.816.513.814.913.816.219.415.81517.115.915.113.217.115.415.813.824.320.919.11917.615.918.117.51717.430.938.342.715.3

LuICMS80ppm0.010.790.210.210.210.330.380.520.20.250.20.220.180.250.20.220.180.170.220.570.220.220.210.180.150.190.160.220.180.230.250.260.2


BeICMS80ppm0.11.31.11.111.31.21.51.1111.11.41.3111.11.11.11.211.11.11.10.810.81.11.611.41.31.8

BiICMS80ppm0.040.110.140.130.180.160.150.120.140.150.140.150.130.160.160.140.10.110.10.110.150.110.130.090.130.110.120.10.160.170.140.160.21

CdICMS80ppm0.020.130.150.170.180.160.170.180.20.150.190.150.150.150.180.170.160.150.130.140.170.160.240.120.240.170.170.340.490.220.240.220.25

CeICMS80ppm0.0538.732.832.831.430.331.138.128.231.732.632.735.838.530.930.330.627.929.933.326.834.831.635.728.732.836.656.580.531.841.567.378.7

CoICMS80ppm0.121.311.914.426.217.72014.817.417.418.920.322.221.523.724.421.120.120.618.119.720.136.317.724.316.317.232.82812.721.718.119.4

CsICMS80ppm0.051.441.732.22.411.91.831.9521.451.9122.12.122.021.641.61.211.321.421.821.151.921.411.581.421.391.951.672.23.232.413.95

GaICMS80ppm0.0514.514.114.217.915.11613.615.815.115.716.816.618.418.916.314.315.414.314.319.814.619.413.521.714.114.625.125.317.41814.917.4

GeICMS80ppm0.10.10.10.10.20.20.2

*:0.10.10.20.10.20.20.10.20.40.10.10.10.10.20.20.30.20.20.10.20.20.30.20.30.20.2

InICMS80ppm0.020.040.050.030.040.040.040.030.040.030.040.040.050.040.040.050.040.040.060.040.040.040.070.040.040.040.040.080.120.030.040.040.04

LaICMS80ppm0.113.81716.415.514.915.115.914.213.515.916.217.518.415.214.21413.212.816.813.118.615.118.413.416.315.525.733.316.525.934.232.3

LuICMS80ppm0.010.210.180.180.220.20.20.180.190.20.20.20.240.220.220.210.210.220.230.220.260.250.340.240.330.220.210.731.240.170.230.30.24


BeICMS80ppm0.10.91.31.41.21.10.411.51.61.40.21.411.11.40.91.30.911.11.31.31.61.31.80.9

BiICMS80ppm0.040.110.140.210.10.090.050.120.180.190.170.070.240.130.160.130.150.230.160.160.130.120.130.160.130.210.18

CdICMS80ppm0.020.20.140.210.340.150.150.350.190.210.170.30.810.170.210.250.220.160.20.180.20.160.170.20.140.190.23

CeICMS80ppm0.0524.437.63143.330.620.453.257.75470.67.0254.93431.649.335.43155.434.235.537.436.474.757.171.533.1

CoICMS80ppm0.11719.320.243.719.33.64.614.514.814.50.810.720.822.631.921.629.81418.518.719.919.713.515.418.223.8

CsICMS80ppm0.051.152.32.541.61.250.651.753.233.453.220.213.862.472.482.372.2831.982.362.531.72.13.141.843.22.54

GaICMS80ppm0.0514.516.817.525.113.72.816161615.20.8413.917.11923.316.918.616.317.817.216.417.214.513.515.715.5

GeICMS80ppm0.10.10.20.20.50.2

0.10.10.10.10.10.10.20.20.10.20.10.20.20.30.10.20.10.10.20.20.2

InICMS80ppm0.020.030.040.040.110.04O.020.02

0.040.040.03

•c0.020.030.030.050.090.040.050.030.040.040.040.040.040.030.040.06

LaICMS80Ppm0.111.916.715.518.915.19.735.325.726.132.75.240.616.715.622.817.815.428.317.718.316.117.735.226.934.116.3

LuICMS80ppm0.010.20.190.220.670.20.070.180.210.20.230.040.260.210.220.560.210.220.220.210.210.260.240.260.240.260.22


BeICMS80ppm0.11.11.11.21.11.11.70.81111.7

BiICMS80ppm0.040.140.160.170.160.10.190.150.090.140.140.22

CdICMS80ppm0.020.20.160.210.230.140.170.130.170.180.190.23

CeICMS80ppm0.0532.527.129.531.836.765.731.631.926.231.876.8

CoICMS80ppm0.122.724.225.643.819.513.217.818.817.921.218.5

CsICMS80ppm0.051.932.272.132.361.282.551.571.111.222.363.4

GaICMS80ppm0.0516.220.918.521.513.815.115.813.315.816.716.4

GeICMS80ppm0.10.10.20.10.20.20.20.30.10.20.20.1

InICMS80ppm0.020.050.040.080.050.040.030.040.040.040.040.04

LaICMS80ppm0.115.813.414.414.115.831.312.717.112.915.136.3

LuICMS80ppm0.010.220.260.290.320.220.230.190.240.220.20.27


MoICMS80ppm0.050.830.850.710.650.780.820.640.860.910.570.540.710.970.680.650.641.160.370.290.260.440.260.950.841.240.590.681.090.661.170.510.5

NbICMS80ppm0.116.215.71614.515.516.11320.116.21414.613.921.416.116.715.416.716.718.120.515.114.717.216.215.41718.221.119.122.712.916.4

NiICMS80Ppm0.541.443.639.459.141.545.659.141.238.334.353.928.346.656.933.328.448.743.43846.737.129.927.736.249.954.956.315.441.717.435.763.8

RbICMS80ppm0.25149.452.149.753.452.140.158.351.1674665.36352.156.269.651.964.675.468.476.787.362.450.64338.840.983.252.868.260.148.8

SbICMS80ppm0.050.410.430.470.290.370.340.350.40.340.340.250.330.260.330.320.320.260.230.240.240.20.250.260.240.320.170.210.240.240.340.20.15

SeICMS80ppm0.20.70.80.50.50.50.60.60.40.60.80.40.60.40.60.30.50.80.60.30.60.50.60.40.60.80.50.51.30.61.80.70,6

SnICMS80ppm0.11.51.61.61.21.61.61.21.81.61.51.21.51.81.31.61.51.31.31.51.41.41.51.61.51.61.21.52.71.52.71.31.3

SrICMS80ppm0.5173168186185170167177196180191198189177182185181183217194224213240181179172187189152191167213190

TaICMS80ppm0.051.151.021.181.071.121.260.951.421.181.081.021.051.511.111.251.091.141.211.271.441.11.121.21.181.121.121.291.521.221.440.771.18

TbICMS80ppm0.050.420.410.370.450.480.40.450.450.360.420.490.370.440.390.390.380.420.430.350.660.370.390.340.350.480.430.461.30.381.070.450.53

TeICMS80ppm0.020.060.110.070.050.050.070.070.070.070.060.040.040.080.070.050.050.030.030.060.050.060.040.060.060.080.040.080.10.060.120.020.04


MoICMS80ppm0.050.950.570.820.751.060.990.760.630.40.770.540.430.710.50.390.730.550.791.150.270.760.290.360.360.440.380.530.310.420.30.40.6

NbICMS80ppm0.111.617.413.815.320.617.613.130.317.816.516.515.114.316.816.714.612.814.116.117.316.815.115.712.913.810.72110.611.813.813.716

NiICMS80ppm0.524.92433.222.132.930.524.122.255.239.635.720.338.726.74633.238.458.118.741.448.842.23321.650.435.742.527.134.241.242.148.3

RbICMS80Ppm0.225.943.141.337.746.862.250.943.340.447.951.269.536.448.84559.655.147.240.271.758.865.268.1716266.353.987.384.210610961.7

SbICMS80ppm0.050.180.210.210.220.230.290.190.20.140.180.170.190.140,160.130.180.180.210.20.170.180.150.160.170.190.150.150.170.220.260.280.19

SeICMS80ppm0.21.60.40.810.90.710.20.40.50.5

-:0.21.30.50.50.60.60.81.90.70.40.70.40.30.80.40.60.60.60.60.40.4

SnICMS80ppm0.121.51.41.31.921.61.511.31.31.31.11.31.11.31.21.32.31.41.51.21.31.51.41.61.41.71.82.93.22.7

SrICMS80ppm0.5176197197132196169195166187195185213160176183197199189213212197221227220228245171231250230227206

TaICMS80ppm0.050.811.0111.061.381.290.972.651.111.21.6511.081.091.311.081.011.141.141.261.191.041.110.891.030.861.320.580.951.151.141.11

TbICMS80ppm0.051.680.390.430.440.650.641.010.370.460.370.450.340.540.330.470.340.340.431.330.480.430.430.370.30.40.330.420.340.570.660.690.4

TeICMS80ppm0.020.080.050.090.050.060.120.080.030.060.02

-c0.02^.02

0.060.030.050.060.030.020.090.040.070.040.05

•c0.020.050.030.060.03O.02

0.06^.02

0.07

Sample (dentScheme CodeAnalysis UnitDetection Limit363367363368363369363370363371363372363373363374363375363376363377363379363380363381363382363383363384363385363386363387363388363389363390363391363392363393363394363395363396363397363398363399

MoICMS80ppm0.050.380.510.550.680.590.60.460.680.480.670.770.650.90.880.670.860.752.380.730.90.560.860.410.730.780.661.11.650.740.690.30.32

NbICMS80ppm0.125.812.613.915.812.816.412.51413.516.214.214.815.717.315.514.716.715.615.215.816.515.315.210.917.115.117.525.113.714.915.115.5

NiICMS80PPm0.549.625.128.957.238.538.33135.136.637.642.144.742.542.547.646.340.63940.636.743.439.441.721.936.54018.41125.144.844.951.2

RbICMS80ppm0.24658.258.371.154.8546157.450.363.152.252.856.458.846.845.736.437.342.948.438.753.344.536.137.340.542.657.174.775.977.1109

SbICMS80ppm0.050.140.20.190.210.170.190.190.190.190.170.210.180.180.20.150.170.140.130.140.180.120.180.130.170.170.150.220.330.210.20.210.3

SeICMS80ppm0.20.50.40.30.50.50.70.30.50.30.50.50.50.60.50.70.60.60.60.60.70.70.911.10.70.81.52.20.50.90.80.4

SnICMS80ppm0.11.61.52.63.42.71.82.42.91.92.13.51.74.83.31.52.61.41.41.22.11.95.11.54.52.11.63.27.83.65.82.22.6

SrICMS80ppm0.5192212195192188188215208183184190186188189188186175174178173187192216189176192204190211229226239

TaICMS80ppm0.053.240.951.021.141.021.110.981.010.961.121.171.191.141.240.930.921.141.010.990.921.140.991.030.791.210.991.31.81.081.131.11.2

TbICMS80ppm0.050.370.330.360.440.380.40.360.340.360.390.410.460.450.420.40.380.40.440.430.430.540.620.470.720.420.421.612.60.350.530.70.59

TeICMS80ppm0.02O.02

0.030.050.060.040.050.050.070.050.050.070.050.070.050.050.040.06O.02

0.050.070.040.11^.02

0.070.060.040.10.120.050.040.040.06


MoICMS80ppm0.050.560.670.771.410.520.40.350.290.540.310.291.380.880.751.480.850.770.460.750.770.690.860.670.350.780.69

NbICMS80ppm0.115.518.316.61513.22.44.613.913.612.70.611.414.218.217.915.917.518.716.817.725.824.513.213.814.615.1

NiICMS80ppm0.536.249.242.913.9487.821.739.539.438.45.437.846.439.417.534.859.129.736.240.15546.136.436.644.743.1

RbICMS80ppm0.241.671.765.945.73812.136.4103110104399.483.158.66578.668.984.392.586.652.471.487.66091.183.5

SbICMS80ppm0.050.190.220.310.210.140.120.210.210.220.250.120.240.20.210.270.260.180.20.20.210.180.220.20.160.20.21

SeICMS80ppm0.20.20.50.61.70.61.11.90.60.70.51.22.20.30.71.50.40.50.4

•c0.20.50.50.42.10.80.60.3

SnICMS80ppm0.11.84.52.67.21.51.91.41.92.73.91.52.73.83.410.584.82.12.12.82.93.12.11.82.63.5

SrICMS80ppm0.519119321918420047.16524222923736.8169203189198211183212203192179179210228219175

TaICMS80ppm0.0511.241.161.040.960.20.411.041.091.09^.05

0.931.081.331.371.171.311.31.231.321.61.441.020.961.141.13

TbICMS80ppm0.050.340.380.41.290.390.170.530.490.460.590.080.660.40.421.280.430.430.50.380.430.420.410.630,570.630.43

TeICMS80ppm0.020.060.060.030.060.03^.02•c0.02

0.040.020.04^.02

0.040.030.020.130.060.040.060.050.020.030.060.050.060.040.04

Sample Ident Scheme CodeAnalysis Unit Detection LimitDUP-363301DUP-363313DUP-363325DUP-363337DUP-363351DUP-363363DUP-363375DUP-363388DUP-363400DUP-363412DUP-363424

Mo ICMS80ppm 0.050.840.961.080.980.410.350.520.530.590.880.82

Nb ICMS80ppm 0.115.320.916.518.815.311.41515.217.41515.7

Ni ICMS80ppm 0.53845,75131.74035.337.440.938.846.244.5

Rb ICMS80ppm 0.249.860.544.343.852.291.153.636.54581.794.9

Sb 1CMS80ppm 0.050.240.20.210.20.120.190.180.10.220.160.23

Se ICMS80ppm 0.20.60.40.90.70.60.60.20.60.30.40.5

Sn ICMS80ppm 0.11.41.71.61.61.21.72.11.923.52.4

Sr ICMS80ppm 0.5173176184194195267200183206203229

Ta ICMS80ppm 0.051.11.391.211.321.230.870.921.031.061.071.18

Tb ICMS80ppm 0.050.410.430.50.630.440.580.360.490.360.380.67

Te ICMS80ppm 0.020.040.070.070.06

•:0.020.040.050.020.050.020.05


PbICMS80ppm0.57.987.65.69.46.46.910.398.16.886.46.89.210.68.17.79.89.610.713.9117.814.26.67.217.311.210.56

SICMS8007o

0.010.030.030.030.040.030.040.040.040.030.030.040.040.040.040.030.030.040.030.030.030.030.020.030.030.030.030.030.030.030.040.020.03

SeICMS80ppm0.114.81412.815.616.515.818.315.812.611.815.510.416.813.312.39.810.8119.812.59.39.410.312.114.71414.314.911.510.810.315.6

TiICMS80"/o

0.010.710.70.640.650.780.720.70.730.590.530.570.490.790.590.70.620.520.490.520.460.420.430.590.720.780.610.691.90.751.860.540.76

VICMS80Ppm1233235200211271263249224198159185123264185207183150124971199684185222180181232262202281120222

YICMS80ppm0.112.812.711.914.514.713,615.314.911.511.815.81114.813.412.511.611.713.21119.110.71110.911.516.112.814.545.513.738.814.217.1

ZnICMS80Ppm1951101007012010983737885668581671057859471036387686195129581262579529010483

ZrICMS80ppm0.511212311310712111193.215411410911212412111115011111912011413111611511412314595.4136249130296141156

AgICMS80ppm0.020.330.380.360.30.370.390.280.460.460.410.360.470.40.40.440.40.420.340.350.380.350.30.350.380.550.320.450.80.360.940.470.44

AsICMS80ppm0.21.81.82.72.422.72.42.832.32.823.22.821.62.321.52.12.31.31.82.42.12,31.73.32.75.21.83.2

BaICMS80ppm5371378416299381368315431407458312435367350421385386442420449483565415394385298345323373345429295


PbICMS80ppm0.5O.5

8.810.66.55.74.11.89.84.19.57.110.45.58.55.68.988.110.29.510.611.29.610.111.19.87.411.915.417.416.68.4

SICMS80"/o

0.010.050.020.040.050.040.040.050.040.030.030.040.020.060.030.040.030.030.040.040.020.030.030.020.020.030.020.030.020.020.020.020.03

SeICMS80ppm0.137.410.99.49.510.814.317.41113.310.111.48.515.310.514.810.39.816.813.911.413.711.19.3811.29.213.28.810.712.311.813.1

TiICMS80"/o

0.011.730.680.580.620.941.070.960.750.510.520.520.50.590.680.520.550.490.641.180.420.740.430.440.460.520.390.590.430.380.440.40.6

VICMS80ppm1536152125131197182215116162154112961581311611621352081081042101119492136951739292113101182

YICMS80ppm0.156.712.113.213.52221.435.111.713.711.414.410.218.211.515.510.19.71443.214.112.813.210.79.211.69.81410.316.118.318.612.8

ZnICMS80ppm1184456864126221145625261100617760537283951445112046484150487346547979107

ZrICMS80ppm0.5169153139100130134173125103126126135107138118121103113218115128124128138111123142133137125113113

AgICMS80ppm0.020.480.410.390.330.440.50.550.320.350.370.310.360.280.330.30.390.340.40.630.360.420.350.340.380.370.350.380.380.370.330.330.35

AsICMS80ppm0.21.81.82.323.12.11.91.61.92.81.51.12.21.61.91.32.12.81.60.82.321.90.92.31.71.80.22.33.73.71.8

BaICMS80ppm5344398412258344343269356289387336451260355293418350345322447387435495482480532348520550581584405


PbICMS80ppm0.57.98.99.98.28.87.710.911.19.39.810.79.512.28.45.89.45.46.68.98.27.76.66.37.99.47.412.112.212.710.713.817

SICMS80"/O

0.010.030.020.030.040.030.030.030.030.030.030.030.030.030.030.040.040.040.030.040.030.040.040.030.060.040.040.050.040.030.040.050.03

SeICMS80ppm0.1139.39.815.112.712.99.611.31212.614.115.714.615.615.212.312.513.111.7141514.412.810.912.612.61515.810.51413.813.6

TiICMS80"/o

0.010.530.490.530.720.550.650.480.560.550.670.630.660.640.70.720.530.610.670.540.730.630.920.590.660.560.531.241.180.510.60.440.46

VICMS80ppm116712713523618519912216216020121119521023423816219218417723719522513115215316824684162148128128

YICMS80ppm0.112.810.21113.711.711.911.111.811.712.112.414.113.613.513.611.913.114.514.314.616.921.11424.813.314.255.394.710.415.722.916.7

ZnICMS80ppm1621041771129699132847074808176102737357705792581085111173801901851081096385

ZrICMS80ppm0.510913512810710911213113711714911812411111211311912210411610411313311890130112276463125104121119

AgICMS80ppm0.020.290.370.410.340.360.360.380.410.370.420.40.40.370.410.330.370.380.330.320.310.340.420.360.320.40.320.791.230.380.370.340.32

AsICMS80ppm0.23.11.323.52.11.41.52.61.41.52.81.921.62.42.82.21.91.92.51.72.31.82.81.22.92.82.51.41.224

BaICMS80ppm5342471432420387405497430354377397379376385312348308294320330285290344278313334306466495444452558


PbICMS80ppm0.59.512.612.810.576.57.814.614.217.8314.910.69.412.812.59.510.68.28.111.611.21410.513.69.5

SICMS80"/o

0.010.030.030.030.040.030.20.140.020.020.020.190.10.030.040.040.040.040.030.030.030.030.040.10.070.060.04

SeICMS80ppm0.112.110.912.420.811.92.76.210.610.611.90.610.113.315.918.815.218.611.41314.111.511.911.810.912.615.1

TiICMS80"/o

0.010.590.520.671.750.520.070.130.40.410.410.020.310.70.761.270.640.780.710.690.720.560.690.390.370.440.82

VICMS80ppm1199145186283139173996991041389217217107174237139202216170186111110127271

YICMS80ppm0.111.312.512.747.711.6515.412.712.416.62.717.812.914.441.413.414.913.112.313.514.613.818.41718.114.1

ZnICMS80ppm1666714427287145270737019117811741739919888941189266654771115

ZrICMS80ppm0.512011011727010122.341.41171111245.692122121182105126159144114150139114115122109

AgICMS80ppm0.020.40.30.410.730.290.110.280.350.350.310.070.620.420.40.610.330.390.480.430.380.460.410.310.320.340.33

AsICMS80ppm0.22.92.53.53.11.81.11.93.13.13.40.52.61.72.52.53.42.11.42.322.42.92.51.62.33

BaICMS80ppm531246844129334612920055855457956485421416389399377483437416402400518418510343


PbICMS80ppm0.58.86.412.96.57.614.58.2710.79.514.6

SICMS80"/o

0.010.030.040.040.040.030.020.030.040.030.030.06

SeICMS80ppm0.114.317.615.59.910.710.112.214.212.913.313.8

TiICMS80"/o

0.010.660.840.80.910.530.360.550.590.610.750.48

VICMS80ppm122429620119612887169177211227141

YICMS80ppm0.112.415.817.920.510.415.11215.91212.119.8

ZnICMS80ppm1898613911575547555718375

ZrICMS80ppm0.5123129161126103123112117106119118

AgICMS80ppm0.020.360.40.560.40.30.350.380.320.380.380.37

AsICMS80ppm0.22.12.92.62.81.92.11.51.42.71.92.5

BaICMS80ppm5360342398331301563370271330409532


ThICMS80ppm0.24.85.14.96.27.54.73.95.34.54.84.75.45.34.35.54.45.16.25.18.45.36.44.64.14.64.55.15.14.15.34.97

TlICMS80ppm0.020.240.230.240.190.230.210.170.230.240.250.180.260.230.20.240.240.220.280.290.310.310.390.270.220.210.160.180.270.220.280.250.18

UICMS80ppm0.11.21.21.21.11.31.111.51.21.311.41.311.51.11.11.11.21,41.21.41.21.11.311.31.51.11.71.41.4

WICMS80ppm0.050.650.640.780.520.70.710.50.780.750.70.50.860.690.570.790.680.70.60.640.790.770.810.740.70.730.50.690.640.60.820.450.53

YbICMS80ppm0.51.41.41.21.51.51.41.41.61.31.31.61.21.71.41.31.41.31.41.41.91.21.21.21.31.81.41.64.61.54.21.41.9


ThICMS80ppm0.23.25.24.83.84.243.76.24.84.65.24.7445.74.44.74.34.77.47.66.35.94.865.35.55.39.412.613.14.6

TlICMS80ppm0.020.10.230.230.210.240.240.150.230.180.210.20.260.150.210.190.230.220.190.140.30.220.290.320.30.290.290.240.330.40.470.490.22

UICMS80ppm0.10.91.41.31.31.31.31.31.411.21.31.311.111.11.21.21.31.31.31.21.21.21.21.21.31.31.41.71.71.1

WICMS80ppm0.050.280.420.560.590.630.740.520.630.420.591.240.570.430.470.40.570.520.520.520.670.680.540.610.580.580.480.480.330.660.860.820.56

YbICMS80ppm0.55.31.31.41.42.22.33.41.21.61.31.51.21.71.21.51.21.11.341.41.51.41.211.211.41.11.51.71.71.3


ThICMS80ppm

0.24.34.75.24.54.75.15.34.33.95.35.15.66.74.94

4.54

3.64.83.74.33.84.73.24.44.15.57.25

5.29.2

13.1

TlICMS80Ppm

0.020.2

0.260.240.220.230.230.240.240.2

0.230.230.230.230.230.170.190.170.170.170.2

0.180.2

0.220.140.210.2

0.160.210.3

0.280.370.5

UICMS80ppm

0.11

1.21.21.11.21.21.21.2

11.31.21.41.31.2

11.2

10.91.11.11.2

11.20.91.31.11.62.31.31.31.51.6

WICMS80ppm

0.050.550.60.6

0.640.530.560.560.640.310.550.620.590.540.590.250.340.490.620.480.360.390.380.420.380.510.410.5

0.630.560.480.560.79

YbICMS80ppm

0.51.41.11.11.41.31.31.11.21.21.31.31.51.51.41.41.41.51.51.41.51.62.21.52.21.41.45

8.31.11.51.91.6


ThICMS80ppm

0.23.5

55.24.35.63.57.3

10.29.4

11.21

12.74.84.94.75.25.7

11.95.85.25.45.4

10.87.9

11.25.1

TlICMS80PPm

0.020.170.290.260.160.21

0.10.2

0.420.430.450.030.420.280.220.190.240.24

0.30.290.250.230.270.39

0.30.430.24

UICMS80ppm

0.11

1.21.31.31.10.93.41.51.61.5

13.31.31.31.41.21.42.11.41.41.21.32.41.51.71.5

WICMS80ppm

0.050.440.590.780.31

0.40.26

0.50.7

0.740.710.191.960.76

0.60.590.590.560.630.630.640.580.68

0.80.57

0.80.59

YbICMS80Ppm

0.51.31.31.44.51.3

0.51.21.41.31.5

O.51.71.31.53.81.41.51.51.41.41.71.61.71.61.71.4

Sample Ident Th Tl U W YbScheme CodeAnalysis UnitDetection LimitDUP-363301DUP-363313DUP-363325DUP-363337DUP-363351DUP-363363DUP-363375DUP-363388DUP-363400DUP-363412DUP-363424

ICMS80 ICMS80 ICMS80 ICMS80 ICMS80ppm ppm

0.25.3

54.5

45.29.84.23.93.94.5

11.6

ppm0.020.220.220.220.23

0.20.41

0.20.160.180.270.44

Ppm0.11.31.31.31.21.21.41.21.11.11.21.9

ppm0.050.570.650.680.560.440.570.250.340.480.580.85

0.51.41.71.92.11.51.51.21.61.51.31.8

Sample Ident Scheme CodeAnalysis Unit Detection Limit363411363422363423363424DUP-363411

Al ICMS80"/o

0.016.476.245.876.836.51

As ICMS80ppm 0.22.81.912.92.6

Ba ICMS80PPm 5537561447540523

Ca ICMS80"/o

0.012.722.152.682.362.75

Cr ICMS80ppm16977677867

Fe ICMS80"/o

0.012.982.93,073.552.97

KICMS80o/o

0.011.71.981.592.071.7

Li ICMS80ppm 13629253336

Mg ICMS80"/o

0.011.151.211.421.581.13

Mn ICMS80ppm 5714354503559720

Mo ICMS80ppm 0.051.242.31.762.31.36

Sample IdentScheme CodeAnalysis UnitDetection Limit36341 1363422363423363424DUP-36341 1

NaICMS80"/O

0.011.091.571.691.691.1

PICMS80ppm5012005714346521170

PbICMS80ppm0.512.312.512.114.411.9

SICMS80"/o

0.010.110.120.070.070.1

SeICMS80ppm0.111.311.511.312.410.9

TiICMS80"/o

0.010.330.380.390.430.34

VICMS80ppm1839710510880

YICMS80ppm0.119.217.516.318.218.7

ZnICMS80ppm1117665067113

ZrICMS80ppm0.595.810511811396.6

AgICMS80ppm0.021.780.951.121.061.92

Sample Ident Scheme CodeAnalysis Unit Detection Limit36341 1363422363423363424DUP-36341 1

Be ICMS80ppm 0.11.41.41.31.61.4

Bi ICMS80ppm 0.040.180.170.130.180.19

Cd ICMS80ppm 0.020.70.240.430.230.69

Ce ICMS80ppm 0.0552.368.555.572.854.7

Co ICMS80ppm 0.19.713.116.11710.5

Cs ICMS80ppm 0.053.692.871.892.93.89

Cu ICMS80ppm 0.540.127.42522.240.8

Ga ICMS80ppm 0.0513.714.213.815.214.6

Ge ICMS80ppm 0.10.20.40.40.20.2

In ICMS80ppm 0.020.040.040.030.040.04

La ICMS80ppm 0.137.633.326.235.139.5

Sample Ident Scheme CodeAnalysis Unit Detection Limit36341 1363422363423363424DUP-363411

Lu ICMS80ppm 0.010.240.240.240.250.25

Nb ICMS80ppm 0.111.213.716.415.712

Ni ICMS80ppm 0.53336.136.541.234.1

Rb ICMS80ppm 0.210287.364.491.2107

Sb ICMS80ppm 0.050.220.240.160.210.23

SeICMS80ppm 0.22.121.10.62.1

Sn ICMS80ppm 0.10.70.60.60.70.7

Sr ICMS80ppm 0.5150164169190152

Ta ICMS80ppm 0.050.971.141.061.231.03

Tb ICMS80ppm 0.050.620.590.550.640.64

Te ICMS80Ppm 0.020.050.080.040.040.04

Sample Ident Th Tl U W YbScheme Code ICMS80 ICMS80 ICMS80 ICMS80 ICMS80Analysis Unit ppm ppm ppm ppm ppmDetection Limit 0.2 0.02 0.1 0.05 0.5363411 10.9 0.49 2.9 0.92 1.5363422 9.8 0.46 2.8 0.78 1.6363423 7.4 0.37 1.6 0.57 1.5363424 10.8 0.48 1.8 0.81 1.7DUP-363411 11.4 0.51 3.1 1.01 1.6

QNTMUO MINISTRY OF NORTHERN DEVELOPMENT AND NUNES

Work Report Summary

Transaction No: W0240. 00252 Status: APPROVED (D)

Recording Date: 2002-FEB-12 Work Done from: 2001-DEC-19

Approval Date: 2002-MAY-1 3 to: 2002-JAN-16

Client(s):

1 28645 EAST WEST RESOURCE CORPORATION

Survey Type(s):

GCHEM

Work Report Details:

Claim*

TB

TB

TB

TB

TB

TB

TB

1229578

1229579

1229590

1229591

1229592

1229679

1229681

Perform

sososo

S12,868

SO

18,327

51,893

S23,088

External Credits:

Perform Approve

S12

S8

S1

S23

SO

sososo

,868

SO

,327

,893

,088

Applied

52,650

54,347

55,508

S4.830

S5,753

SO

SO

523,088

Applied Approve

52,650

S4.347

55,508

S4.830

55,753

SO

SO

523,088

Assign

SO

50

SO

58,038

SO

S8.327

51,893

S1 8,258

Assign Approve

0

0

0

8,038

0

8,327

1,893

518,258

Reserve

SO

soso50SO

50

SO

SO

Reserve Approve

SO

soSO

sosoSO

SO

so

Due Date

2003-FEB-12

2003-FEB-12

2003-FEB-12

2003-FEB-12

2003-FEB-12

2002-MAR-15

2002-MAR-15

Reserve:so

so

Reserve of Work

Total Remaining

Report*: W0240. 00252

Status of claim is based on information currently on record.

52H14NE2003 2.22956 HAVOC LAKE 900

2002-May-23 16:33 Armstrong-d Page 1 of 1

Ministere duDeveloppement du Nord et des Mines

Ministry ofNorthern Developmentand Mines

Date:2002-MAY-15

EAST WEST RESOURCE CORPORATION905 WEST FENDERAPT 402VANCOUVER, BRITISH COLUMBIAV6C 1L6 CANADA

OntarioGEOSCIENCE ASSESSMENT OFFICE 933 RAMSEY LAKE ROAD, 6th FLOOR SUDBURY, ONTARIO P3E 6B5

Tel: (888) 415-9845 Fax:(877)670-1555

Dear Sir or Madam

Submission Number: 2.22956 Transaction Number(s): W0240.00252

Subject: Deemed Approval of Assessment Work

We have approved your Assessment Work Submission with the above noted Transaction Number(s) as per6(7) of the Assessment Work Regulation. Only eligible assessment work is deemed approved for assessment workcredit. The attached Work Report Summary indicates the results of the approval.

NOTE: The report has not been reviewed for technical deficiencies and reported expenses were not evaluated based on the Industry Standard.

At the discretion of the Ministry, the assessment work performed on the mining lands noted in this work report may be subject to inspection and/or investigation at any time.

If you have any question regarding this correspondence, please contact STEVEN BENETEAU by email at [email protected] or by phone at (705) 670-5855.

Yours Sincerely,

Ron GashinskiSenior Manager, Mining Lands Section

Cc: Resident Geologist

East West Resource Corporation (Claim Holder)

Assessment File Library

East West Resource Corporation (Assessment Office)

Robert Stuart Middleton (Agent)

Visit our website at http://www.gov.on.ca/MNDM/LANDS/mlsmnpge.htm Page: 1 Correspondence 10:17066

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MINING LAND TENURE

MAP

Dale /Time of Issue Scp 25 3001

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HAVOC LAKE AREA

14:34h Eastern

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Land Titles/Registry Division THUNDER BAY

Ministry of Natural Resources District THUNDER BAY

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200 r

100 -

60000

EAST WEST RESOURCE CORPORATIONHAVOC PROPERTY

Thunder Bay Mining Division. Ontario

GROUND MAGNETICS LINE O

DATE: February , 2002 FIG. NO.

SCALE: 1:5000

METRES O 100 200

K/e. 1* j i Ve, f^cU

500

400 -

300 -

200

100 -

59000O 1N 2N 3N 4N 5N 6N 7N 8N 9N 10N 11N 24N 25N 26N

52H14NE2003 3.32356 HAVOC

348400E 348800E 349200E 349600E 350000E 350400E 350800E 351200E 351600E 352000E 352400E 352800E 353200E 353600E 35400QE 354400E 354800E 35S200E 355600E

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GRID "A" NORTH

EAST WEST RESOURCES CORPORATION

HAVOC PROPERTY

ARMSTRONG, ONTARI

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2100N

2000N (|

TB 1229678_____ 19QQN r-

TB 1229592

1800N

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1700N

1600N

1500N

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1200N

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363393

363392

363391

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363387

J363386

363385

L 363384

-363383

363382

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363380 |

363379 ^ *, vA& "o *0 *0

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363377

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-363374

363373

363372

363371

•363370

363369

363368

•363367

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363334

363335

363336

^ 363337

-363338

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-363340

363341

363342

-363345

- J 363346

- 363347

- 363348

363349

363350 ^--~-

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-363352

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363355

363356

363357

363358

363359

363360

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363363

363364

363365

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to 33 l Q) O *-- in 1 ^ c?

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^ Claim post arfljT line363415 * J|} -

Sample site, Ticket M®* ,O\ | Zn^ 363416 ^^ - ^ ^^

(Ni " ) MMI Anomaly + Element O" 'V j

• -

363417 ^-^

363418 z Tn -80 mesh Soil ICPMS 80 Anomaly363419

O-*- PropoieJ D//// W o! e- 363420 ~ l

----,,

- - ^^

"^ —.-,

363421 Note: Grid is rotated 005' west of NorthEocal magnetic declination is 2.5* W363422

363423 ^

363424 y\ /\

METRES

0 100 200 300 400 500l

EAST WEST RESOURCE CORPORATION

HAVOC PROPERTYThunder Bay Mining Division, Ontario

Ns, sx—— o u, GEOCHEMICAL SOIL SURVEYg g 1 S l *™ 1 1 sllliliglillll MMI-D, ICPMS 80

DATE: JAN. 16/2002 EIGURE NO. 6

geochemical soil sampling for - ontario...geological traverses were carried out by the writer as...

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