general introduction to organic compound - copy

25
WELCOME TO THE WORLD OF ORGANIC CHEMISTRY!!!

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ORGANIC COMPOUND INTRODUCTION

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Page 1: General Introduction to Organic Compound - Copy

WELCOME TO THE WORLD OF ORGANIC CHEMISTRY!!!

Page 2: General Introduction to Organic Compound - Copy

WHAT IS ORGANIC CHEMISTRY? The study of carbon-containing compounds

- Organic-Inorganic

why is it so important?• Think about how organic compounds affect our daily life:

Page 3: General Introduction to Organic Compound - Copy

***OUR FOOD – CARBOHYDRATES, PROTEINS, TRIGLYCERIDES

SUCROSE PROTEIN

Page 4: General Introduction to Organic Compound - Copy

***OUR MEDICINES

C

OH

O

OHC

O

OH

OCOCH3

(CH3CO2)O

H2SO4

PARACETAMOLASPIRIN

Page 5: General Introduction to Organic Compound - Copy

***OUR CLOTHES – NATURAL AND SYNTHETIC FIBERS

Page 6: General Introduction to Organic Compound - Copy

***OILS, PERFUMES, PAINTS, PLASTICS, DETERGENTS, ETC.

Page 7: General Introduction to Organic Compound - Copy

ORGANIC COMPOUNDS

More than 5,000,000 known organic compounds compared to only about 200,000 to 300,000 known inorganic compounds.

General properties are different from inorganic compounds (ionic salts etc.)

Page 8: General Introduction to Organic Compound - Copy

Organic compounds

Covalent bonding Low melting

points Mainly insoluble

in water Mainly soluble in

organic solvents (e.g., gasoline)

Almost all burn Slower reactions

Inorganic compounds

Ionic bonding High melting

points Mainly soluble in

water Mainly insoluble in

organic solvents Very few burn Very fast reactions

Page 9: General Introduction to Organic Compound - Copy

COVALENT BONDING

A covalent bond involves sharing of a pair of electrons between two atoms

Each atom contributes one electron for sharing

The shared electrons are localised between the two atomic nuclei

Page 10: General Introduction to Organic Compound - Copy

COVALENT BONDING Example

H● + H× H H

H H can be represented as H—H

● ×

● ×

Page 11: General Introduction to Organic Compound - Copy

WHY CARBON?

A carbon atom forms four bonds

Carbon atoms form stable bonds with other carbon atoms (i.e., the C—C covalent bond is strong)

Can form chains and even networks.Examples: diamond and graphite

Page 12: General Introduction to Organic Compound - Copy

WHY CARBON?

• A carbon atom forms four bonds

• Graphite• Diamond

Examples: diamond and graphite

Page 13: General Introduction to Organic Compound - Copy

WHY CARBON?

Carbon atoms also form stable bonds with other atoms (i.e., C—H, C—O, C—N, C—Cl etc. bonds are strong).

Many combinations and arrangements are possible

Page 14: General Introduction to Organic Compound - Copy

EXAMPLES OF ORGANIC COMPOUNDS

Page 15: General Introduction to Organic Compound - Copy

HYDROCARBONS (CNHM)

Extracted from crude oil

Separated according to size for various purposes

Source of energy, plastics, solvents, raw materials, etc.

Page 16: General Introduction to Organic Compound - Copy

ETHANOL C2H5OH

C

H

H C

H

O

H

H

H

Page 17: General Introduction to Organic Compound - Copy

ASPIRIN (ACETYLSALICYLIC ACID)

C

OH

O

OHC

O

OH

OCOCH3

(CH3CO2)O

H2SO4

Page 18: General Introduction to Organic Compound - Copy

CHLOROFLUOROCARBONS(CFCS)

C

F

ClCl

Cl

CFCl3

Page 19: General Introduction to Organic Compound - Copy

WHAT ARE ORGANIC MOLECULES?

Main structure: carbon backbone Each carbon must have 4

covalent bonds (i.e., share an electron with a neighbouring atom)

building blocks attached to each other by covalent bonds

Functional groups with specific properties

Page 20: General Introduction to Organic Compound - Copy

EXAMPLES OF FUNCTIONAL GROUPS

Ester Alkene C=C Alcohol –OH Halogen groups –Cl, –Br Amine –NH2 Carboxylic acid –COOH Amide –CONH etc.

Page 21: General Introduction to Organic Compound - Copy

ESTERS

C OC

O

C

H

H

H

H

H

H

Methylacetate

Page 22: General Introduction to Organic Compound - Copy

ESTERSSynthesised when a carboxylic acidand an alcohol react

R C

O

O H R O H

C O

O

R R H2O

Page 23: General Introduction to Organic Compound - Copy

ESTERS

Structure FlavourBananaOrange

PineappleApple

Raspberry

CH3COOCH2CH2CH(CH3)2

CH3COO(CH2)7CH3

CH2(CH2)2COOCH2CH3

CH3(CH2)2COOCH3

HCOOCH2CH(CH3)2

Responsible for many flavours and fragrances.Generally sweet and pleasant smells.

Page 24: General Introduction to Organic Compound - Copy

ESTERS: OTHER APPLICATIONS

Aspirin, an analgesic (painkiller) Ethyl acetate, a solvent Polyesters---Clothing---Used to make synthetic arteries for

heart surgery---Bio-absorbable staples for surgery

Page 25: General Introduction to Organic Compound - Copy

THANK YOU