gas sampling results, 1st quarter 2003, w/tl to d basinger ... · work order summary client: phone:...

"Gardner, Tom"<[email protected]>

07/01/2003 07:27 AM

SFUND RECORDS CTR

2066401

To: David Basinger/R9/USEPA/US@EPA, SteveWall/R9/USEPA/US@EPA, "Sandra Doty (E-mail)"<[email protected]>

cc: "Gaddy, Alan" <[email protected]>Subject: Landfill Gas Analysis

«0301202_d.pdf» «0301202COC.pdf» «lq2003h2s .pdf»«lQ20031fganalysis .pdf » «!Q2003sunlfgCOC.pdf »David, attached are electronic copies of the analytical data from the firstquarter of 2003. If you still want copies of the 4th quarter 2002, let meknow. I do not have electronic copies of the 4th quarter 2 0 0 2 . I will faxto you the last 5 well reading logs. If you have any other requests, pleaselet me know. Thanks. Tomg.

0301202_d.pdf 0301202COC.pdf 1q2003h2s.pdf 1Q2003lfganalysis.pdf 1Q2003sunlfgCOC.pdf

AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY

Air Toxics Ltd. Introduces the Electronic Report

Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail.This document is provided in Portable Document Format which can be viewed with Acrobat Reader byAdobe.

This electronic report includes the following:• Work order Summary;• Laboratory Narrative;• Results; and• Chain of Custody (copy).

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific

E-mail to:[email protected]

@ AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY

WORK ORDER #: 0301202

Work Order Summary

CLIENT:

PHONE:

FAX:

DATE RECEIVED:DATE COMPLETED:

Mr. Rob TidwellEnvironmental Technologies of Nevada,Inc.770 East Sahara AvenueLas Vegas, NV 89104

702-734-5400

702-735-4523

1/8/03

1/8/03

BILL TO:

P.0.#

PROJECT #

CONTACT:

Mr. Rob TidwellEnvironmental Technologies of Nevada,Inc.770 East Sahara AvenueLas Vegas, NV 89104

10199007.01 Task 21 Sunrise Mtn Landfill

Karen Burden

FRACTION #01A02A03A

NAMEFlare R2Lab BlankLCS

TESTModified ASTMD-5504Modified ASTMD-5504Modified ASTMD-5504

RECEIPTVACJPRES.Tedlar Bag

NANA

CERTIFIED BY: DATE: 01/08/03

Laboratory Director

Certfication numbers: AR DEQ, CA NELAP - 02110CA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892

Name of Accrediting Agency: NELAP/Florida Department of Health, Scope of Application: Clean Air Act,Accreditation number: E87680, Effective date: 07/01/02, Expiration date: 06/30/03

Air Toxics Ltd. certifies that the test results contained in this report meet all requirements of the NELAC standards

This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Pase 1 of 5

LABORATORY NARRATIVEModified ASTM D-5504

Environmental Technologies of Nevada, Inc.Workorder# 0301202

One 1 Liter Tedlar Bag sample was received on January 08, 2003. The laboratory performed the analysis ofsulfur compounds via Modified ASTM D-5504 using GC/SCD. The method involves direct injection of the airsample into the GC via a fixed 1.0 mL sampling loop. See the data sheets for the reporting limits for eachcompound.

Receiving Notes

There were no receiving discrepancies.

Analytical Notes

There were no analytical discrepancies.

Definition of Data Qualifying Flags

Seven qualifiers may have been used on the data analysis sheets and indicate as follows:B - Compound present in laboratory blank greater than reporting limit.J - Estimated value.E - Exceeds instrument calibration range.S - Saturated peak.Q - Exceeds quality control limits.U - Compound analyzed for but not detected above the detection limit.M - Reported value may be biased due to apparent matrix interferences.File extensions may have been used on the data analysis sheets and indicatesas follows:a-File was requantifiedb-File was quantified by a second column and detectorrl-File was requantified for the purpose of reissue

Page 2 of 5

AIR TOXICS LTD.SAMPLE NAME: Flare R2

ID#: 0301202-01A

SULFUR GASES BY MODIFIED ASTM D-5504 GC/SCD

File Name:Oil. Factor.

Compound

b010809„ t 10000 •J * gfk

Rpt. Limit(ppbv)

-'«.» Datg of Collection: 1/7/03Date of Analysis: 1/8/03

Amount(ppbv)

Hydrogen Sulfide 40000 6300000

Container Type: 1 Liter Tedlar Bag

Page 3 of 5

AIR TOXICS LTD.SAMPLE NAME: Lab Blank

ID#: 0301202-02ASULFUR GASES BY MODIFIED ASTM D-5504 GC/SCD

FIlaName:Ml. Factor

Compound

Hydrogen Sulfide

b0108041.00

Rpt. Limit(ppbv)

4.0

Date of Collection: NADate of Analysis: 1/8/03

Amount

Not Detected

Container Type: NA - Not Applicable

Page 4 of 5

AIR TOXICS LTD.SAMPLE NAME: LCS

ID#: 0301202-03ASULFUR GASES BY MODIFIED ASTM D-5504 GC/SCD

File Name:Oil. Factor.

Compound

«&,. 1-°° V, "/Nf^IxT »Rpt. Limit

(ppbv)

^ '^ Date of Collection: NA^ffxffKt Date of Analysis: 1/8/03

%Recovery

Hydrogen Sulfide 4.0 79


Page 5 of 5



Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report bye-mail. This document is provided in Portable Document Format which can be viewed with Acrobat Readerby Adobe.






WORK ORDER #: 0303267A

Work Order Summary

CLIENT:

PHONE:

FAX:

DATE RECEIVED:DATE COMPLETED:

Mr. Ty SalazarWestmark Environmental Services Inc.3642 North Rancho Dr.Suite 102Las Vegas, NV 89130

702-839-2960

702-839-2962

03/14/03

03/21/03

BELL TO:

P.O.*

PROJECT #

CONTACT:

Mr. Tom GardnerEnvironmental Technologies of Nevada,Inc.770 East Sahara AvenueLas Vegas, NV 89104

Sunrise Gas Samples

Kelly Buettner

FRACTION #01A02A03A04A

NAMEFlare Main-2SUNGW02Lab BlankLCS

TESTModified ASTM D-5504Modified ASTM D-5504Modified ASTM D-5504Modified ASTM D-5504

RECEIPTVAC./PRES.Tedlar BagTedlar Bag

NANA


Laboratory Director

Certfication numbers: AR DEQ, CA NELAP - 0211 OCA, LA NELAP/LELAP- AI 30763, NJ NELAP - CA004NY NELAP - 11291, UT NELAP - 9166389892



This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd.

180 BLUE RAVINE ROAD. SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1 of6


Environmental Technologies of Nevada, Inc.Workorder# 0303267A

Two 1 Liter Tedlar Bag samples were received on March 14, 2003. The laboratory performed the analysisof sulfur compounds via Modified ASTM D-5504 using GC/SCD. The method involves direct injection olthe air sample into the GC via a fixed 1.0 mL sampling loop. See the data sheets for the reporting limits foreach compound.

RequirementDetection

Standards

Initial Calibration

Dilution

ASTMD-5504Less than 5 pgS/sensitivity

Permeation tubeCompressed cylindergas

External StandardSingle point at leastonce per day; The RFof each compoundshould be within 1 0 %of RF for DimethylSulfide.

Via split injection

ATL Modifications4 ppbv

Standards may also be formulated from liquid stock andblended in a Tedlar bag

External Standard Multi points (3compounds </= 30%; %RSD </=The low point of the curve is theLimit.

- 5) Average % RSD for all30 % for Hydrogen Sulfide.same as the Reporting

Bag or syringe dilution with N2

Receiving Notes

Samples Flare Main-2 and SUNGW02 were received past the recommended hold time of 24 hours. Thediscrepancy was noted in the Login email and the analysis proceeded.

Analytical Notes

There were no analytical discrepancies.


Seven qualifiers may have been used on the data analysis sheets and indicate as follows:B - Compound present in laboratory blank greater than reporting limitJ - Estimated value.E - Exceeds instrument calibration range.S - Saturated peak.Q - Exceeds quality control limits.U - Compound analyzed for but not detected above the detection limitM - Reported value maybe biased due to apparent matrix interferences.File extensions may have been used on the data analysis sheets and indicatesas follows:a-File was requantifiedb-File was quantified by a second column and detectorrl-File was requantified for the purpose of reissue

Page 2 of 6

AIR TOXICS LTD.SAMPLE NAME: Flare Main-2

ID#: 0303267A-01A


File Name:DH. Factor:

Compound

~"C /. ' ' 2*5600 T~" " A ~-~* r t<* " *"£

Rpt. Limit(ppbv)

Date of Collection: 3/12/03Date of Analysis: 3/14/03

Amount(ppbv)



Page 3 of 6

AIR TOXICS LTD.SAMPLE NAME: SUNGW02

ID#: 0303267A-02A


Fit* Name:Oil. Factor:

Compound

b03140650.0

Rpt. Limit(PPbv)


Amount(ppbv)



Page 4 of 6


ID#: 0303267A-03A


File Name:Oil. Factor:

Compound

b031403

1.00 * ISL >

Rpt. Limit<PPbv)

, Date of Collection: NADate of Analysis: 3/14/03

Amount(ppbv)

Hydrogen Sulfide 4.0 Not Detected


Page 5 of 6


ID#: 0303267A-04A


Flla Name:Oil. Factor:

Compound

b0314021.00

Rpt. Limit(ppbv)


%Recovery

Hydrogen Sulfide 4.0 116


Page 6 of 6



Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing your report by e-mail.This document is provided in Portable Document Format which can be viewed with Acrobat Reader byAdobe.






WORK ORDER #: 0303267BR1

Work Order Summary

CLIENT:

PHONE:

FAX:

DATE RECEIVED:

DATE COMPLETED:

DATE REISSUED:

FRACTION #01A02A03A04A

Mr. Ty SalazarWestmark Environmental Services Inc.3642 North Rancho Dr.Suite 102Las Vegas, NV 89130

702-839-2960

702-839-2962

3/14/03

3/27/03

3/27/03

NAMEFlare Main-2SUNGW02Lab BlankLCS

BILL TO:

P.O.#

PROJECT #

CONTACT:

Mr. Tom GardnerEnvironmental Technologies of Nevada,Inc.770 East Sahara AvenueLas Vegas, NV 89104

Sunrise Gas Samples

Kelly Buettner

IEJSIModified ASTM D-1945Modified ASTM D-1945Modified ASTM D-1945Modified ASTM D-1945

RECEIPTVAC/PRES.Tedlar BagTedlar Bag

NANA


Laboratory Director

Certfication numbers: AR DEQ, CA NELAP - 0211 OCA, LA NELAP/LELAP- AI30763, NJ NELAP - CA004NY NELAP -11291, UT NELAP - 9166389892



This report shall not be reproduced, except in full, without the written approval of Air Toxics Ltd

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1 of 7


Environmental Technologies of Nevada, Inc.Workorder# 0303267BR1

Two 1 Liter Tedlar Bag samples were received on March 14, 2003. The laboratory performed analysis viamodified ASTM Method D-1945 for Methane and fixed gases in natural gas using GC/FID or GC/TCD.The method involves direct injection of up to 1.0 mL of sample. With the exception of analyses conducted inaccordance with AFCEE 3.0, all reported compound quantifications were calculated from response factorsderived from the first Continuing Calibration Verification of each relevant analytical batch. See the datasheets for the reporting limits for each compound.

RequirementNormalization

Sample analysis

Sample calculation

Standard preparation

ASTM D-1945Sum of original valuesShould not differ from100.0% by more than1.0%

Equilibrate samples to20-50° F. above sourcetemperature at fieldsampling

Response factor iscalculated using peakheight for C5 andlighter compounds.

Prepared by blendingpure standards

ATL ModificationsSum of original values may range between 75-125%.

No heating of samples is performed.

Peak areas are used for all target analytes toconcentrations.

Purchased blend certified to ± 5% accuracy

quantitate

or better

Receiving Notes

There were no receiving discrepancies.

Analytical Notes

Sample Flare Main-2 was diluted due to a high level of Hydrogen Sulfide. Diluted results for Nitrogen andOxygen are not accurate and therefore not reported since ambient air concentrations of these elements arehigh. Since Nitrogen and Oxygen are not reported, results were not normalizied and do not equal 100% asper ASTM-D1945 protocol. An estimated BTU value was reported per client's request.

Due to high sulfur concentration in samples Flare Main-2 and SUNGW02 , the nickel catalyst was bypassed,resulting in a higher reporting limit of 0.1% for Carbon Monoxide and Carbon Dioxide. Sampleconcentrations were based on the response of a single point calibration for all analytes.

Sample SUNGW02 results are normalized to total 100% per ASTM D-1945 protocol.

RE-ISSUED ON MARCH 26, 2003 TO CORRECT THE DILUTION FACTOR FOR SAMPLEFLARE MAIN-2.


Six qualifiers may have been used on the data analysis sheets and indicate as follows:

Page 2 of 7

J - Estimated value.E - Exceeds instrument calibration range.S - Saturated peak.Q - Exceeds quality control limits.U - Compound analyzed for but not detected above the detection limitM - Reported value may be biased due to apparent matrix interferences.

File extensions may have been used on the data analysis sheets and indicatesas follows:a-File was requantifiedb-File was quantified by a second column and detectorrl-File was requantified for the purpose of reissue

Page 3 of 7

AIR TOXICS LTD.SAMPLE NAME: Flare Main-2

ID#: 0303267BR1-01ANATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945

File Name:DII. Factor

3031418R1500


CompoundRpt. Limit Amount

OxygenNitrogenCarbon MonoxideMethaneCarbon DioxideEthanePropaneIsobutaneButaneNeopentaneIsopentanePentaneC6+

Estimated BTU/Cu.F.= 550Estimated Sp. Gravity= 0.30Container Type: 1 Liter Tedlar Bag

5050

0.500.0500.500.500.500.500.500.500.500.505.0

Not DetectedNot DetectedNot Detected

54Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

Page 4 of 7

AIR TOXICS LTD.SAMPLE NAME: SUNGW02

ID#: 0303267BR1-02ANATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945

File Name:Oil. Factor

30314171.00

jate of Collection: 3/12/03Date of Analysis: 3/14/03


OxygenNitrogenCarbon MonoxideMethaneCarbon DioxideEthanePropaneIsobutaneButaneNeopentane

IsopentanePentaneC6+

Total BTU/Cu.F.= 3.7Total Sp. Gravity= 1.0Container Type: 1 Liter Tedlar Bag

0.00100.00100.010

2377

Not Detected0.0440.24

Not DetectedNot DetectedNot DetectedNot DetectedNot Detected

6.0026Not Detected

0.066

Page 5 of 7


ID#: 0303267BR1-03A

NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945

File Nam«:

DII. Factor3031416

1.00





Total BTU/Cu.F.= NATotal Sp. Gravity= NAContainer Type: NA - Not Applicable

0.100.100.10

0.000100.100.00100.00100.00100.00100.00100.00100.00100.010

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

Page 6 of 7


ID#: 0303267BR1-04A

NATURAL GAS ANALYSIS BY MODIFIED ASTM D-1945

File Name:Oil. Factor

30314141.00

Date of Collection: NA

Bate of Analysis: 3/14/03

CompoundRpt. Limit

%Recovery


0.100.100.10

0.00010

0.100.0010

0.0010

0.0010

0.0010

0.0010

104100100100971009810310194


Total BTU/Cu.F.= NATotal Sp. Gravity= NAContainer Type: NA - Not Applicable

0.00100.00100.010

9899106

Page 7 of 7

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