gamma-ray spectroscopy
DESCRIPTION
Gamma-Ray Spectroscopy. Dr.Ir. Peter Bode Associate Professor Nuclear Science & Engineering. INAA: Semiconductor detectors RNAA: Semiconductor detectors Scintillation detectors. Solid-state ionisation detectors. Principle of a semiconductor detector. Solid-state ionisation detectors. - PowerPoint PPT PresentationTRANSCRIPT
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Gamma-Ray Spectroscopy
Dr.Ir. Peter Bode Associate Professor Nuclear Science &
Engineering
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
INAA:Semiconductor detectors
RNAA:Semiconductor detectorsScintillation detectors
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Principle of a semiconductor detector
Solid-state ionisation detectors
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Solid-state ionisation detectors
N-type Ge:
Impurities such as P and As as electron donors
P-type Ge:
Impurities as B, Al, Ga as positive charge donors
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Solid-state ionisation detectors
Semiconductor detector:
Junction diode with P and N type impurities on either side
Applying a reverse bias:
A P-I-N structure is formed
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
n-type silicon
e
h
-V 0
qe dV1
qh dV2
dq = (qedV1 + qhdV2 )/V
i = dq/dt
n+ contact
p+n junction
reverse bias, fully depleted
• silicon diode
• germanium detector
Solid-state ionisation detectors
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Atomic
number Operating
temperature (K)
Band Gap, eV
Electron mobility,
(cm2V-1s-1)
Hole mobility
(cm2V-1s-1)
Energy to produce an electron-hole pair, eV
Si 14 77 300
1.16 1.12
2.1 .104
1500 1.1.104
500 3.76 3.61
Ge 32 77 0.67 3.6 . 104 4.2.104 2.96
GaAs 21 33 130
300
1.43
8500
400 4.51 4.2
CdTe 48 52 300 1.47 1100 100 4.43
Cd1-x Znx Te 48 30
52 300 1.44 (x=0)
- 2.26
(x=1); typically
1.5-2.2 for x=0.1 -0.2
1350 120 4.43 (x=0) –
(x=1); typically 5.0-5.5 for
x=0.1-0.2
HgI2 80 53 300 2.13 100 100 4.22 Some properties of semiconductor materials
Solid-state ionisation detectors
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Schematic representation of a Ge-semiconductor detector,
Solid-state ionisation detector
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Solid-state ionisation detector
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Solid-state ionisation detectors
Contacts:
n+: diffusion of Li-atoms 700 – 1000 m (dead layer)
p+: implantation of B-atoms 0.3 m
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
•Different types of Ge semiconductor detectors
Solid-state ionisation detector
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Solid-state ionisation detector
Channel number pulse height
No.o
f p
uls
es
(*
10
00
)
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Solid-state ionisation detector
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Solid-state ionisation detector
Pulse height spectra obtained with Si(Li) detectors.Left: X-ray spectrum of 241AmRight: - spectrum of 241Am
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Different types of cryostats for use with Ge-semiconductor detectors
Solid-state ionisation detector
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Energy resolution
Usually:
Full Width on Half Maximum @ 1332 keV of 60Co
@ 122 keV of 57Co
@ 6 keV of 55Fe
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Energy resolution
State-of-the-art:
1332 keV: 1.58 – 2.0 keV, depending on crystal size
122 keV: 0.6 – 1 keV
5.9 keV: 0.2 – 0.5 keV
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Peak Shape
Ratio of :
FWHM/Full Width 0.1 M
FWHM/Full Width (1/50) M
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Gamma-ray peak shape and tail parameters
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Peak Shape
Ratio of :
FWHM/Full Width 0.1 M theoretically: 1.83
FWHM/Full Width (1/50) M theoretically: 2.38
Importance: symmetry !!!
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
High energy (top) and low energy tail parameters
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
High energy tail of pulser peak
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
High energy tail of pulser peak
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Calibration source activity
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Peak-to-Compton ratio
Defined as:
Ratio of peak height at 1332 keV and average peak height in energy range between 1040 and 1096 keV
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Peak-to-Compton ratio
State-of-the-art:
p/C ~ 50-100, depending on size of crystal:
pC = 34.75 + 1.068 (εCo-60) - 4.96.10-3 (εCo-60)2
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Efficiency
Absolute efficiency defined as:
Relative to the efficiency of a 3” x 3 ” NaI(Tl) detector,
defined as 1.2.10-3 counts/1332 keV photon,measured at a source-detector distance of 25 cm
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Determination of photopeak efficiency curve
Absolute: Using calibrated sources with known gamma-ray emission rates and activity values, traceable to Bq
Single gamma-ray emitting radionuclidesPoint sourcesExtended sources
Problem:Many sources contain 60Co and 88Y; corrections for coincidence effects require also the p/T curve
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Determination of photopeak efficiency curve
Relative:
Using mix of sources with well-established gamma-ray intensity ratios
1 source for entire energy range, e.g. 152Eu
2-5 sources, e.g. 182Ta + 133Ba + 75Se + 24Na + … Problem:Intensity ratios not always well established
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Determination of photopeak efficiency curve
Relative:
1 source:advantage: simpledisadvantage: do not always fully cover entire energy range; inter/extra-polation disputable in 80-150 keV range
3-5 sources:advantage: better coverage all energy rangesdisadvantage: more cumbersome, problems with non-matching parts
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Determination of efficiency curves
Relative:
Using mix of sources with well-established gamma-ray intensity ratios
1 source for entire energy range, e.g. 152Eu
2-5 sources, e.g. 182Ta + 133Ba + 75Se + 24Na + …
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
New Tools for Nuclear Spectroscopy
Better and bigger Ge detectors High count rate electronics
High-resolution scintillation detectors (LaBr3(Ce))
Position-sensitive (strip) detectorsMonte Carlo modelingImage processing
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Bigger Ge- Detectors
100 10000.1 %
1 %
10 %
100 %
3000
Absolute photopeak efficiency
75 cm3 (17 %) 4 cm
560 cm3 well
Photon energy, keV
0.3 % 20 %
3 % 90 %
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Typical improvement in detection limits
20 %
100 %
well125 cm3
Arbitrary units
0,01 0,1 1
0,01 0,1 0,25-0,3 1
0,01 0,1 0,15-0,25 1
Bigger Ge-Detectors
well560 cm3
0,01 0,1 1
0,07 - 0,1
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
New Tools for Nuclear Spectroscopy
LaBr3(Ce) scintillation spectra
P.Doorenbos et.al., IEEE Transactions 51 (2004) 1289Developed and Patented by T.U.Delft: produced by Saint Gobain, France
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Preamplifiers
- Resistor feedback- Pulse optical feedback
high resolutions (planar detectors)
- Transistor feedbackhigh count rates
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
NIM bin and power supply
- Adequate capacity
- standard: +/- 24 V +/- 12 V +/- 6 V
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
High Voltage supply
Typically (+/-) 3-5 kV
Different power supplies for Ge and NaI(Tl) detectors
dV/dt networks
LN2 switchoff option
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Spectroscopy Amplifiers
Analogue systems
Digital systems
- Gaussian shaping- Triangular shaping- Gated-integrated shaping
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Baseline retoration and Pole-zero setting
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Spectroscopy Amplifiers
Essential:
- Amplifier and HV at opposite outermost places in NIM-BIN- Match amplifier’s output DC level to ADC’s input DC level
- High time (shaping) constant: better resolution, lower
throughput Often typically set at 3 s for most (coaxial) detectors 6 s for planar detectors
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
ADC
- Linear Approximation or Wilkinson ADC- Successive Approximation ADC
Wilkinson ADC’s : best linearity
Wilkinson ADC: dead time depends on channel no.
Succ. Appr. ADC: fixed dead time per channel.
Settings: zero level, lower level, upper level, conversion gain
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Pulse generators
- Used for dead time/pile-up correction
- Fed into the test input of the preamplifier
- Essential: input peak shape must match detector signal (rise time and fall time (1000-2000 s )
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Dead-time stabilizer
Loss free counting
Digital dead-time stabilizer
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Signals
Use oscilloscope
Track:
- Output signal preamplifier
- Output signal spectroscopy amplifier
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Bad signals
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Low energy tailing:
- wrong baseline restoration- incomplete charge collection
High energy tailing:- wrong baseline restoration
Peak broadening:- increased noise- incomplete charge collection
Shifts/instability:- proportional: gain- constant: DC problems
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Spectral shape
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Photoelectric effect (1)
The photon energy is transferred to an atomic electron
KL
e-
h
3
4
, h
Ze Cross section
Energy photo-electron: be EhE
Photo-electron
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Compton effect (1)h
h’
Ee-
Energy conservation:
Energy Compton electron:
Angular correlation:
)cos1(1
)cos1()(
2
2
2
cmhcmh
E
e
ee
'hvEhv e
Partial energy transferto a ‘free’ electron
2tan1)cot( 2
cm
h
e
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
h
h’
Ee-
Angular distribution of the scattered photons
0
90
180
270
0 1 2
10 MeV
1 MeV0.1 MeV
0.01 MeV
richting invallend
foton
Compton effect (3)
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Only if
• E > 1022 keV
Mainly if• high Z
Pair production
Annihilation
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Interactions of photons
10 -2 10 -1 10 0 10 1 10 2
Photon energy (MeV)
0
20
40
60
80
100A
tom
ic n
um
ber
Z
Photo-Electric Effect
dominantPair Production
dominant
Compton Effect
dominant C =
= C
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Photon interacts with crystal:
• Absorption of all energy by photoelectric effect
• Absorption of all energy by multiple scatteringand subsequent absorption by photoelectric effect
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Photon interacts with crystal:
3. Absorption of part of the energy of the photon due to scattering effects and escape of scattered photon from the crystal
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Photon interacts with crystal:
3. If energy of photon > 1022 keV: pair production effects:
-All energy absorbed- One of the electrons escapes from the crystal: only E- 511 keV deposited- both scattered electrons escape from the crystal:E-1022 keV deposited
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Photon interacts with crystal:
4. Al low energies:
All energy transferred to Ge electrons, but scattered Ge electrons escape from crystal:
E-(Ge-k) keV deposited in crystal
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Coincidence effects
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Coincidence effects
Coincidence count rate: Rc = D.1.2
Random coincidence count rate: Rr = 2..R1.R2
Rr = 2..D2. 1.2
1, 2 : total counting efficiency
(= full energy photopeak efficiency x peak/Total ratio)
Relevant:True coincidence effects: Absolute efficienciesRandom coincidence effects: Count rate + absolute efficiencies
In all cases needed: peak-to-Total ratio
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Measuring the p/T curve
Simple: using e.g. 65Zn or 137Cs
Complex: modeling using MCNP
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Coincidence effects
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Coincidence effects
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Coincidence effects
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Compton suppression systems
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Compton suppression spectometerTiming Electronics
Anti-coincidence
Spectroscopy electronics
Analogue to Digital
converter
Multi-channel pulse-height
analyzer
Annular scintillation detector shield with
plug detector
Sample
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Gamma-ray spectrum of 137Cs, recorded with and without Compton suppression.
Compton suppression spectrometer
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Compton suppression spectrometer
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Compton suppression spectrometer
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Selecting a detector
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
P.Bode, J.Radioanal.Nucl.Chem. 222 (1997) 117-125 + 127-132
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Errors in gamma-ray spectroscopy
- Source-to-detector distance
- Filling height and source-self attenuation effects
- Coincidence summing effects
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Steps to be taken for an NAA laboratory
Vial with comparator
Vial with comparator
Vial with sample
Neutron fluence rate
Estimation neutron fluence rate at sample position
Not necessarily the arithmetic mean of the comparator values !
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Source-detector distance
Source-end-cap distance e.g. R cm
End-cap thickness + end-cap-crystal distance e.g 0.6 cmDistance to average point of complete absorption of photon energy e.g. 2.5 cm
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Steps to be taken for an NAA laboratory
Don’t correct just for difference in distance to end-cap! Include distance to average interaction point inside the Ge crystal (typically at ~ 1.5-2.5 cm (depends on size of detector; add 0.5 cm crystal-end cap distance)
sample standard
10 cm
0.5 cm
0.2 cm
0.5 cm2.5
cm
Correction for count rates: {10+ (0.5/2)+0.5 + 2.5}2/{10+(0.2/2)+0.5 + 2.5}2 = 1.023
Assuming uncertainty in interaction depth 1 cm: correction is then 1.025
Uncertainty of correction is difference between these corrections, viz. 0.2 %
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Source-detector distance
0 5 10 15 201.0
1.5
2.0
2.5
3.0
3.5
Co
rre
ctio
n f
act
or
Source-to-endcap distance (cm)
Source height 0.1 cm 0.2 cm 0.3 cm 0.5 cm 1 cm 2 cm 5 cm
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008
The mot optimal choice
Summer CourseInstrumental Neutron Activation
Analysis
July 7-18, 2008