forestry 485
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Forestry 485. Lecture 2-5: Specific Types of Adhesives. Chemical Nature of Wood Adhesives. Organic, Polymeric Chemicals Natural origin, e.g., blood protein, milk protein, starch (carbohydrate) Synthetic origin, e.g., phenol formaldehyde, isocyanate, polyvinyl acetate (“Elmer’s glue”) - PowerPoint PPT PresentationTRANSCRIPT
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Forestry 485Forestry 485
Lecture 2-5: Specific Types of Lecture 2-5: Specific Types of AdhesivesAdhesives
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Chemical Nature of Wood Chemical Nature of Wood AdhesivesAdhesives
Organic, Polymeric ChemicalsOrganic, Polymeric Chemicals Natural origin, e.g., blood protein, milk protein, starch Natural origin, e.g., blood protein, milk protein, starch
(carbohydrate)(carbohydrate) Synthetic origin, e.g., phenol formaldehyde, Synthetic origin, e.g., phenol formaldehyde,
isocyanate, polyvinyl acetate (“Elmer’s glue”)isocyanate, polyvinyl acetate (“Elmer’s glue”)
Thermoplastic (soften upon heating, harden Thermoplastic (soften upon heating, harden upon cooling, re-soften upon heating)upon cooling, re-soften upon heating)
Thermosetting (chemically reactive, once Thermosetting (chemically reactive, once hardened, they do not soften upon subsequent hardened, they do not soften upon subsequent re-heating)re-heating)
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Polymers
from Latin Poly = Many; Meros = Units
General Definition – molecules with high molecular weight composed of many smaller repeating units.
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Classification by OriginClassification by Origin
NaturalNatural CarbohydrateCarbohydrate
StarchStarchCelluloseCellulose
ProteinProteinPlant-based (e.g., soybeans)Plant-based (e.g., soybeans)Animal-basedAnimal-based
Protein from hides, bones, Protein from hides, bones, sinewsinew
Liquid (“hide” glue)Liquid (“hide” glue)Solid (“hot animal Solid (“hot animal glues)glues)
BloodBlood Casein (milk)Casein (milk)
Lignocellulosic ExtractsLignocellulosic ExtractsTanninsTanninsLigninLignin
SyntheticSynthetic Polyvinyl acetate (PVA)Polyvinyl acetate (PVA) Elastomeric contact adhesives Elastomeric contact adhesives
(e.g., styrene butadiene)(e.g., styrene butadiene) Elastomeric mastic Elastomeric mastic
(construction adhesives)(construction adhesives) Hot meltsHot melts EpoxyEpoxy Urea formaldehydeUrea formaldehyde Phenol formaldehydePhenol formaldehyde Polymeric isocyanatePolymeric isocyanate ResorcinolResorcinol MelamineMelamine PolyurethanePolyurethane
Vick, 1999. Table 9-3
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Classification by Use CategoryClassification by Use Category
StructuralStructural Fully ExteriorFully Exterior
Phenol formaldehydePhenol formaldehydeResorcinol formaldehydeResorcinol formaldehydePRFPRFIsocyanate emulsionIsocyanate emulsionMelamine formaldehydeMelamine formaldehyde
Limited ExteriorLimited ExteriorMUFMUFIsocyanateIsocyanateEpoxyEpoxy
InteriorInteriorUrea formaldehydeUrea formaldehydeCaseinCasein
Semi-structuralSemi-structural Cross-linked PVACross-linked PVA PolyurethanePolyurethane
NonstructuralNonstructural PVAPVA Animal protein (except Animal protein (except
casein)casein) Plant proteinPlant protein Elastomeric constructionElastomeric construction Elastomeric contactElastomeric contact Hot meltHot melt Starch/carbohydrateStarch/carbohydrate
Vick, 1999. Table 9-2
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Major Synthetic Major Synthetic Resins Used in Resins Used in Composite Panels:Composite Panels: Phenol formaldehydePhenol formaldehyde Urea formaldehydeUrea formaldehyde IsocyanateIsocyanate
White, 1995
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Adhesive AdditivesAdhesive Additives
Catalysts: Increase chemical reaction rate of adhesive Catalysts: Increase chemical reaction rate of adhesive during cure (e.g., ammonium chloride used for UF during cure (e.g., ammonium chloride used for UF resins)resins)Extenders: Low cost additives that enhance adhesive Extenders: Low cost additives that enhance adhesive handling, flow, or working characteristics and provide handling, flow, or working characteristics and provide some adhesive function (e.g., wheat flour)some adhesive function (e.g., wheat flour)Fillers: Low cost additive that modify adhesive working Fillers: Low cost additive that modify adhesive working characteristics but do not provide adhesive function characteristics but do not provide adhesive function (e.g., corn cob powder)(e.g., corn cob powder)Other additives may include plasticizers, tackifiers, Other additives may include plasticizers, tackifiers, antioxidants, formaldehyde scavengers, colorants, antioxidants, formaldehyde scavengers, colorants, wetting agents, defoamers, etc. wetting agents, defoamers, etc.