flame retardant concentrations in house dust: before and ... · california revised the state’s...
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Flame Retardant Concentrations in House Dust: Before and After Replacing Upholstered Furniture
Rebecca Moran*, Deborah Bennett*, Thomas Young*, Kathryn Rodgers +
*University of California, Davis+Silent Spring Institute
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MotivationCalifornia revised the state’s furniture flammability standard (TB117), which can now be met without adding flame retardants to foam (TB117-2013). As a result, flame retardant-free couches are available.
Study Goals• Determine whether flame retardant concentrations in dust decrease
when couches or seat cushion foam are replaced• Collaborate with Biomonitoring California to measure flame retardants
in blood and urine from a subset of participants (FREES: Foam Replacement Environmental Exposure Study)
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Flame Retardants• Polybrominated Diphenyl Ethers (PBDEs)
• Firemaster 550 (FM550)• Organophosphate Flame Retardants (OPFRs)
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20051975
TB 117
2015
TB 117-2013PBDEs
OPFRs/FM550
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Two Groups RecruitedBay Area/Sacramento Area• Currently owned a couch likely to contain flame retardants• Planning to replace couch OR foam within 1 year of recruitment• Willing to replace couch OR foam with a flame retardant-free option • Participants responsible for couch or foam replacement -> time to replace couch varied
San Jose• Currently owned a couch likely to contain flame retardants• Lived in one of two low-income apartment complexes • Willing to have couch replaced with a flame retardant-free couch supplied by study • All homes were on same timeline for home visits and couch replacements
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Recruitment Pre-replacement visit Couch replaced 6-month visit 12-month visit 18-month visit
Dust sample collected
No sample collected
Study Timeline
5.1
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July 2015-August 2016
Dust sample collected
No sample collected
Recruitment Pre-replacement visit Couch replaced 6-month visit 12-month visit 18-month visit
Bay Area/Sacramento
Study Timeline
5.2
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27% 1 month or less50% 2-6 months
23% 7-12 monthsMedian 2.8 months
July 2015-August 2016
Bay Area/Sacramento
18 days-1 year
Dust sample collected
No sample collected
Recruitment Pre-replacement visit Couch replaced 6-month visit 12-month visit 18-month visit
Study Timeline
5.3
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Recruitment Pre-replacement visit Couch replaced 6-month visit 12-month visit 18-month visit
July 2015-August 2016
18 days-1 year
Median 2.8 monthsAugust 2015-November 2016
6 months after replacement
12 months after replacement
18 months after replacement
tableBay Area/Sacramento
Dust sample collected
No sample collected
Study Timeline
5.4
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All initial visits done at same time and all furniture replaced at
same time
May 2016 July 2016
San Jose
January 2017 February 2018July 2017
Dust sample collected
No sample collected
Recruitment Pre-replacement visit Couch replaced 6-month visit 12-month visit 18-month visit
Study Timeline
5.5
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May 2016 July 2016
San Jose
January 2017 February 2018July 20172 months
Recruitment Pre-replacement visit Couch replaced 6-month visit 12-month visit 18-month visit
Dust sample collected
No sample collected
July 2015-August 2016
August 2015-November 2016
Bay Area/Sacramento
6 months after replacement
12 months after replacement
18 months after replacement
18 days-1 year
Median 2.8 months
Study Timeline
5.6
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Household RetentionBay Area/Sacramento AreaEvent Activity Lost to follow-up/
Completed Moved/Dropped outConsent 28 --Initial Visit 28 06-month Visit 22 612-month Visit 21 118-month Visit 21 0
Replacement Type
Total
Couch 8
Foam 12
Removal 2
San JoseEvent Activity
CompletedLost to follow-up/ Moved/Dropped out
Consent 14 --Initial Visit 13 16-month Visit 11 212-month Visit 11 018-month Visit 8 3
Replacement couch provided by study
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Study Dust Collection: Mighty-Mite Vacuum Method
Crevice tool attachment
Thimble
O-ringCrevice tool attachment
*Photos from Joe Allen
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Dust Sample Collection
• Main living area• Equivalent of room’s floor
surface area
• NO upholstered furniture• NOT under furniture
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Dust Analytical Methods
Instrumental Analysis:-Agilent 7200B GC-qTOF-MS-Column: HP-5MS (30m x 0.25 mm, 0.25 µm)-Temperature: gradient, linear increase 35 – 325 °C-Data Acquisition: 80 minutes, EI mode (70 eV)
Target Compound Analysis:-7 Brominated flame retardants (BDEs)-7 Non-brominated flame retardants
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Flame Retardant Chemicals Analyzed
Class Compound Name Abbreviation
PBDEs
2,2',4,4'-Tetrabromodiphenyl ether BDE-47
2,2’,4,4’,5-Pentabromodiphenyl ether BDE-99
2,2’,4,4’,6-Pentabromodiphenyl ether BDE-100
2,2’,4,4’,5,5’-Hexabromodiphenyl ether BDE-153
OPFRs
Tris (1-chloro-isopropyl) phosphate TCIPP
Triphenyl phosphate TPHP
Tris(2-chloroethyl) phosphate TCEP
Tris(1,3-dichloro-2-propyl) phosphate TDCPP
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Bay Area/Sacramento Results: Flame Retardant Levels Over Time
pre pre pre pre
TrendFR decrease in house FR increase in house
Notes: Preliminary results – do not cite or quoteNon-detects (i.e., < Method Reporting Limit
[MRL]) not shown; values between the MRL and Limit of Quantification (LOQ) are included
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San Jose Results: Flame Retardant Levels Over Time
pre pre pre pre
TrendFR decrease in house FR increase in house
Notes: Preliminary results – do not cite or quoteNon-detects (i.e., < Method Reporting Limit
[MRL]) not shown; values between the MRL and Limit of Quantification (LOQ) are included
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Foam Sample Collection
LocationFoam collected from existing couch
Bay Area/Sacramento 13/22
San Jose 11/11
• Bay Area/Sacramento• Small pieces of seat cushion foam• If participant was willing and foam was accessible
• San Jose• Large block of seat cushion foam• Arm rest foam• Fabric: seat, arm rest, backing, and decking
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Detections of flame retardants in existing couches - Bay Area/Sacramento
TCEP TCIPP TDCIPP TPHP BDE-47 BDE-99 BDE-100BDE-153
A cushion x
B cushion x
C cushion x
D cushion x
E cushion x x x
F cushion x
G cushion x
H cushion x x x x x
I cushion x x x x x
J cushion x
K cushion x x
L cushion x x x x x
M cushion x
Percent Detect 8% 15% 46% 54% 23% 23% 23% 23%14
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Detections of flame retardants in existingcouches- San Jose
TCEP TCIPP TDICPP TPHP BDE-47 BDE-99 BDE-100 BDE-153
A cushion xother x x x x x
B cushion x xother x x x
C cushion xother x
D
cushion xother x x xcushion xother x x
E cushion x xother x
F cushion xother x x x x x x x
G cushion xother x x
H cushion x xother x x
I
cushion x x xother x x x xcushion x x x x xother x x x x x
J cushion xother x
K cushion xother x x x x x
Percent Detect 23% 38% 62% 92% 31% 31% 23% 23%15
Not found in seat cushion sample, but found in other samples taken from couch
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San Jose Results: Flame Retardants Found in Couch
TrendFR decrease in house FR increase in house
Notes: Preliminary results – do not cite or quoteNon-detects (i.e., < Method Reporting Limit
[MRL]) not shown; values between the MRL and Limit of Quantification (LOQ) are included
pre pre pre pre 16
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Bay Area/Sacramento Results: Flame Retardants Suspected in Couch
pre pre pre pre
TrendFR decrease in house FR increase in house
Notes: Preliminary results – do not cite or quoteNon-detects (i.e., < Method Reporting Limit
[MRL]) not shown; values between the MRL and Limit of Quantification (LOQ) are included
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Conclusions• Timing for people to replace foam or purchase couch was variable and
complicated logistics• Good completion rates for the homes that replaced foam or bought own
couch• Overall decreases in dust concentrations after homes replaced couch or
foam• Incorporating flame retardants detected in couches helps interpret data
• limited by the samples collected from couches in the Bay Area/ Sacramento group, as the more detailed foam and fabric analysis in the San Jose group indicated different compounds were used in different couch components
• Unexpected increases in some homes; we will further investigate home surveys to identify other potential sources of flame retardants
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Thank You!
• Participants• Myrto Petreas• June-Soo Park• Arlene Blum
• Katya Roudneva• Tasha Stoiber• Veronica Chin
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