flambeau mining company · 2121 innovation court, suite 300 po box 5095 depere, wi 54115 5095...
TRANSCRIPT
January 29, 2015
Mr. Philip Fauble
Hydrogeologist
Wisconsin Department of Natural Resources
101 S. Webster Street – WA/5
P.O. Box 7921
Madison, WI 53707-7921
RE: Flambeau Mining Company
Environmental Monitoring (Fourth Quarter 2014)
Dear Phil:
Enclosed please find copies of the Fourth Quarter 2014 environmental monitoring
groundwater data which include analyses of groundwater collected from wells
surrounding the backfilled pit and pore water from the monitoring wells constructed
in the backfill. The fourth quarter groundwater sampling was completed
October 31, 2014.
Certification is attached and electronic monitoring is enclosed.
Duplicate samples were collected for MW1002G (MW DUP) and MW1014B
(Backfill Dup).
If you have any questions, please contact me at 801-204-2526 or Sharon Kozicki, of
Foth Infrastructure & Environment, LLC, at 920-496-6737.
Sincerely
Dave Cline
Vice President – Flambeau Mining Company
Enclosures
Flambeau Mining Company 4700 Daybreak Parkway South Jordan, UT 84095 801-204-2526
Mr. Philip Fauble
January 29, 2015
Page 2
cc: Sharon Kozicki, Foth Infrastructure and Environment, LLC
Al Christianson, City of Ladysmith (w/o enclosures)
Kyle McLaughlin, WDNR (w/o enclosures)
Zoe C McManama, WDNR (w/o enclosures)
Randy Tatur, Rusk Co. (w/o enclosures)
Tom Riegel, Town of Grant (w/o enclosures)
CeCe Tesky, Rusk Co. Zoning (w/o enclosures)
Attachment 1
Fourth Quarter 2014 GW Analytical Data
Flambeau Mining Company
Fourth Quarter 2014 Environmental Monitoring
October 31, 2014
Reviewer’s Key
Groundwater Quality Wells
MW-1010P, MW-1000PR, MW-1000R (West Wall)
MW-1004, MW-1004S, MW-1004P (North Wall)
MW-1002, MW-1002G (South Gravel Pit)
MW-1005, MW-1005S, MW-1005P (Highway 27; Background)
MW-1015A, MW-1015B (Adjacent to NW Compliance
Boundary)
Backfill Wells
MW-1013, MW-1013A, MW-1013B, MW-1013C (West Pit)
MW-1014, MW-1014A, MW-1014B, MW-1014C (East Pit)
Duplicate Groundwater Samples
MW-1014B (Backfill Dup) and MW-1002G (MW Dup) were
sampled in duplicate.
Turbidity, Color, and Odor
If there was any notable turbidity, color or odor, the results are
provided in the Units column.
Wetland Water Level Elevation
WT-5 designates the remaining staff gauge from which readings
are taken of water elevations in Wetland 1. Wetland water
elevations are read three times per year – spring, summer and fall.
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 1 of 17
COC: 175909:1 Matrix: GW
COC: 175909:2 Matrix: GW
MW-1014A NLS ID: 828919
MW-1014B NLS ID: 828920
Collected: 10/30/14 10:20 Received: 10/31/14
Collected: 10/30/14 10:35 Received: 10/31/14
20526.398.8510ND21414.01300[0.019]466.671800910yes
27756.029.2510ND29205102000ND120006.4127001400yes
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Parameter
Parameter
111511111111100
111511151111200
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/20/1410/31/1411/20/1411/20/1411/20/1411/20/1410/31/1411/03/1411/03/1411/15/14
10/30/1410/30/1410/30/1411/04/1411/20/1410/31/1411/20/1411/25/1411/20/1411/20/1410/31/1411/03/1411/03/1411/15/14
Analyzed
Analyzed
5.01.0*
1.0*1.0*0.018*1.0*
2.0*25
5.01.0*
1.0*5.0*0.018*1.0*
2.0*50
102.0* 2.0*2.0*0.064*2.0*
50
102.0* 2.0*10*0.064*2.0*
100
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 2 of 17
COC: 175909:3 Matrix: GW
COC: 175909:4 Matrix: GW
MW-1014C NLS ID: 828921
MW-1013C NLS ID: 828922
Collected: 10/30/14 11:20 Received: 10/31/14
Collected: 10/30/14 12:30 Received: 10/31/14
9676.399.6270231002ND5304.916006.64650210yes
29056.1810.1510263118ND20001396006.5730001500yes
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Parameter
Parameter
11151111111150
111511151111200
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/20/1410/31/1411/20/1411/20/1411/20/1411/20/1410/31/1411/03/1411/03/1411/15/14
10/30/1410/30/1410/30/1411/04/1411/20/1410/31/1411/20/1411/25/1411/20/1411/20/1410/31/1411/03/1411/03/1411/15/14
Analyzed
Analyzed
5.01.0*
1.0*1.0*0.018*1.0*
2.0*13
5.01.0*
1.0*5.0*0.018*1.0*
2.0*50
102.0* 2.0*2.0*0.064*2.0*
25
102.0* 2.0*10*0.064*2.0*
100
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 3 of 17
COC: 175909:5 Matrix: GW
COC: 175909:6 Matrix: GW
MW-1013 NLS ID: 828923
MW-1013A NLS ID: 828924
Collected: 10/30/14 12:40 Received: 10/31/14
Collected: 10/30/14 12:50 Received: 10/31/14
10606.0111.3600ND1111195602.9260006.2568023yes
9146.399.1330ND9403.84600.09942006.64620190yes
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Parameter
Parameter
11151111111110
11151111111120
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/03/1410/31/1411/03/1411/03/1411/03/1411/03/1410/31/1411/03/1411/03/1411/01/14
10/30/1410/30/1410/30/1411/04/1411/20/1410/31/1411/20/1411/20/1411/20/1411/20/1410/31/1411/03/1411/03/1411/15/14
Analyzed
Analyzed
5.01.0*
1.0*1.0*0.018*1.0*
2.0*2.5
5.01.0*
1.0*1.0*0.018*1.0*
2.0*5.0
102.0* 2.0*2.0*0.064*2.0*
5.0
102.0* 2.0*2.0*0.064*2.0*
10
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersSW846 9040FLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 4 of 17
COC: 175909:7 Matrix: GW
COC: 175909:8 Matrix: GW
MW-1013B NLS ID: 828925
MW-1004P NLS ID: 828926
Collected: 10/30/14 13:00 Received: 10/31/14
Collected: 10/30/14 13:25 Received: 10/31/14
29636.039.4600ND31276102100[0.036]410006.2132001600yes
3116.938.3170ND300ND1400.431107.17130ND
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Parameter
Parameter
111511121111200
11111111111110
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/03/1410/31/1411/03/1411/03/1411/03/1411/03/1410/31/1411/03/1411/03/1411/01/14
10/30/1410/30/1410/30/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
Analyzed
Analyzed
5.01.0*
1.0*2.0*0.018*1.0*
2.0*50
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
102.0* 2.0*4.0*0.064*2.0*
100
2.01.0* 2.0*2.0*0.064*2.0*
5.0
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 5 of 17
COC: 175909:9 Matrix: GW
COC: 175909:10 Matrix: GW
MW-1000R NLS ID: 828927
MW-1015B NLS ID: 828928
Collected: 10/30/14 14:10 Received: 10/31/14
Collected: 10/30/14 14:45 Received: 10/31/14
7355.951055.0230ND76383360ND110006.43500160
5447.378.0180ND555ND1500.22597.49310ND
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Parameter
Parameter
11121111111120
11111111111110
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/06/1411/06/14
10/30/1410/30/1410/30/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
Analyzed
Analyzed
2.00.50*
1.0*1.0*0.018*1.0*
2.0*5.0
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
4.01.0* 2.0*2.0*0.064*2.0*
10
2.01.0* 2.0*2.0*0.064*2.0*
5.0
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
EPA 120.1SW846 9040EPA 170.1SM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 6 of 17
COC: 175911:1 Matrix: GW
COC: 175911:2 Matrix: GW
MW-1002 NLS ID: 828929
MW-1002G NLS ID: 828930
Collected: 10/29/14 10:15 Received: 10/31/14
Collected: 10/29/14 09:45 Received: 10/31/14
1886.3911.669ND182ND80NDND6.98955.6
2456.419.593ND289ND120NDND6.651707.8
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Parameter
Parameter
11111111111110
11111111111110
Dilution
Dilution
10/29/1410/29/1410/29/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
10/29/1410/29/1410/29/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
Analyzed
Analyzed
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
2.01.0* 2.0*2.0*0.064*2.0*
5.0
2.01.0* 2.0*2.0*0.064*2.0*
5.0
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 7 of 17
COC: 175911:3 Matrix: GW
COC: 175911:4 Matrix: GW
MW-1015A NLS ID: 828931
MW-1005S NLS ID: 828932
Collected: 10/29/14 14:45 Received: 10/31/14
Collected: 10/29/14 15:50 Received: 10/31/14
1906.788.280ND189ND830.117.76.951307.8
3446.778.81802.5331ND1504.62306.92210ND
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Parameter
Parameter
11111111111110
11111111111110
Dilution
Dilution
10/29/1410/29/1410/29/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
10/29/1410/29/1410/29/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
Analyzed
Analyzed
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
2.01.0* 2.0*2.0*0.064*2.0*
5.0
2.01.0* 2.0*2.0*0.064*2.0*
5.0
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
EPA 120.1SW846 9040EPA 170.1SM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 8 of 17
COC: 175911:5 Matrix: GW
COC: 175911:6 Matrix: GW
COC: 175911:7 Matrix: GW
MW-1005 NLS ID: 828933
MW-1005P NLS ID: 828934
MW-DUP NLS ID: 828935
Collected: 10/29/14 16:30 Received: 10/31/14
Collected: 10/29/14 16:55 Received: 10/31/14
Collected: 10/29/14 00:00 Received: 10/31/14
9785.8610.6531.9976ND290164106.0466014
4696.9610.5260ND457ND2201.5687.03220ND
94ND287ND130NDND6.681707.7
Result
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
mg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Alkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Parameter
Parameter
Parameter
11111111111110
11121111111110
11111111110
Dilution
Dilution
Dilution
10/29/1410/29/1410/29/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
10/29/1410/29/1410/29/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
11/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
Analyzed
Analyzed
Analyzed
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
2.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
2.01.0* 2.0*2.0*0.064*2.0*
5.0
4.01.0* 2.0*2.0*0.064*2.0*
5.0
2.01.0* 2.0*2.0*0.064*2.0*
5.0
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
SM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
Method
Method
Method
LOD
LOD
LOD
LOQ
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 9 of 17
COC: 175911:8 Matrix: GW
COC: 175911:9 Matrix: GW
MW-1010P NLS ID: 828936
MW-1000PR NLS ID: 828937
Collected: 10/30/14 09:05 Received: 10/31/14
Collected: 10/30/14 09:35 Received: 10/31/14
3416.988.416023358ND180ND297.5319029
7776.119.22306.6831ND4102.423006.68570200
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Parameter
Parameter
11111111111110
11121111111150
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
10/30/1410/30/1410/30/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
Analyzed
Analyzed
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
2.00.50*
1.0*1.0*0.018*1.0*
2.0*13
2.01.0* 2.0*2.0*0.064*2.0*
5.0
4.01.0* 2.0*2.0*0.064*2.0*
25
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersFLD-SOP-othersEPA 170.1SM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 10 of 17
COC: 175911:10 Matrix: GW
COC: 175910:1 Matrix: GW
MW-1014 NLS ID: 828938
MW-1004 NLS ID: 828939
Collected: 10/30/14 10:05 Received: 10/31/14
Collected: 10/30/14 15:25 Received: 10/31/14
6005.9610.0160ND6339.4290ND13006.40420110yes
1266.3111.935ND1005.340[0.021]ND6.548010
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Parameter
Parameter
11121111111120
11111111111110
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/20/1410/31/1411/20/1411/20/1411/20/1411/20/1410/31/1411/03/1411/03/1411/15/14
10/30/1410/30/1410/30/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
Analyzed
Analyzed
2.01.0*
1.0*1.0*0.018*1.0*
2.0*5.0
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
4.02.0* 2.0*2.0*0.064*2.0*
10
2.01.0* 2.0*2.0*0.064*2.0*
5.0
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
Method
Method
LOD
LOD
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 11 of 17
COC: 175910:2 Matrix: GW
COC: 175910:3 Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
MW-1004S NLS ID: 828940
Backfill - DUP NLS ID: 828941
MW-1001 NLS ID: 833444
MW-1001G NLS ID: 833445
MW-1001P NLS ID: 833446
Collected: 10/30/14 15:55 Received: 10/31/14
Collected: 10/30/14 00:00 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
2125.8210.251ND201[1.3]83NDND6.1811035
550[1.1]29755201900ND120006.4028001400yes
1121.28
1119.94
1120.38
Result
Result
Result
Result
Result
[email protected] Cmg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
mg/Lug/Lumho@25Cug/Lmg/Lmg/Lug/Ls.u.mg/Lmg/L
ft. MSL
ft. MSL
ft. MSL
Units
Units
Units
Units
Units
Field conductivity by othersField pH by othersField temperature by othersAlkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)
Alkalinity, tot. as CaCO3 (filtered)Arsenic, dis. as As by ICP-MSConductivity, labCopper, dis. as Cu by ICP-MSHardness, tot. recoverable as CaCO3 (calc/filt/icpms)Iron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSpH, LabSolids, tot. dis. (TDS)Sulfate, as SO4 (filtered)Metals digestion - dissolved ICP-MS
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Parameter
Parameter
Parameter
Parameter
Parameter
11111111111110
511151111200
1
1
1
Dilution
Dilution
Dilution
Dilution
Dilution
10/30/1410/30/1410/30/1411/04/1411/02/1410/31/1411/02/1411/02/1411/02/1411/02/1410/31/1411/03/1411/03/14
11/04/1411/20/1410/31/1411/20/1411/25/1411/20/1411/20/1410/31/1411/03/1411/03/1411/15/14
10/20/14
10/20/14
10/20/14
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
1.00.50*
1.0*1.0*0.018*1.0*
2.0*2.5
5.01.0*
1.0*5.0*0.018*1.0*
2.0*50
2.01.0* 2.0*2.0*0.064*2.0*
5.0
102.0* 2.0*10*0.064*2.0*
100
NANANA721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460721026460
NA
NA
NA
Lab
Lab
Lab
Lab
Lab
FLD-SOP-othersFLD-SOP-othersFLD-SOP-othersSM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056
SM 2320-B 20edEPA 200.8, Rev 5.4SM 2510B 20edEPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4EPA 200.8, Rev 5.4SW846 9040SM 2540-C 20edSW846 9056EPA 200.8M, Rev 5.4
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
Method
Method
Method
Method
Method
LOD
LOD
LOD
LOD
LOD
LOQ
LOQ
LOQ
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 12 of 17
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
OW-10 NLS ID: 833447
OW-39 NLS ID: 833448
OW-42 NLS ID: 833449
OW-7 NLS ID: 833450
PZ-1008 NLS ID: 833451
PZ-1008G NLS ID: 833452
PZ-R1 NLS ID: 833453
PZ-S1 NLS ID: 833454
PZ-S3 NLS ID: 833455
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
1095.89
1102.42
1102.29
1118.59
1139.66
1139.38
1090.56
1096.55
1125.93
Result
Result
Result
Result
Result
Result
Result
Result
Result
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
Units
Units
Units
Units
Units
Units
Units
Units
Units
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
1
1
1
1
1
1
1
1
1
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
NA
NA
NA
NA
NA
NA
NA
NA
NA
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
Method
Method
Method
Method
Method
Method
Method
Method
Method
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 13 of 17
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
SANDPOINT NLS ID: 833456
ST-9-23 NLS ID: 833457
ST-9-23A NLS ID: 833458
ST-9-26 NLS ID: 833459
PZ-1012 NLS ID: 833460
MW-1003 NLS ID: 833461
MW-1003P NLS ID: 833462
CLAY PIPE NLS ID: 833463
OW-43 NLS ID: 833464
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
1086.23
1127.19
1127.31
1119.21
1110.20
1113.58
1113.68
NA
1089.79
Result
Result
Result
Result
Result
Result
Result
Result
Result
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
Units
Units
Units
Units
Units
Units
Units
Units
Units
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
1
1
1
1
1
1
1
1
1
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
NA
NA
NA
NA
NA
NA
NA
NA
NA
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
Method
Method
Method
Method
Method
Method
Method
Method
Method
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 14 of 17
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
WT-5 NLS ID: 833465
PZ-1006 NLS ID: 833466
PZ-1007S NLS ID: 833467
PZ-1006S NLS ID: 833468
PZ-1006G NLS ID: 833469
PZ-1009 NLS ID: 833470
PZ-1009G NLS ID: 833471
PZ-1011 NLS ID: 833472
MW-1014A NLS ID: 835611
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
NA
dry
1117.65
1135.94
1137.10
1144.38
1144.48
1139.60
1120.32
Result
Result
Result
Result
Result
Result
Result
Result
Result
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
Units
Units
Units
Units
Units
Units
Units
Units
Units
Field Static Water Level by others
Dry
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
1
1
1
1
1
1
1
1
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
NA
NA
NA
NA
NA
NA
NA
NA
NA
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
Method
Method
Method
Method
Method
Method
Method
Method
Method
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 15 of 17
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
MW-1014B NLS ID: 835635
MW-1014C NLS ID: 835636
MW-1013C NLS ID: 835637
MW-1013 NLS ID: 835638
MW-1013A NLS ID: 835639
MW-1013B NLS ID: 835640
MW-1004P NLS ID: 835641
MW-1000R NLS ID: 835642
MW-1015B NLS ID: 835643
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
1117.92
1112.66
1102.61
1114.88
1099.70
1100.08
1107.81
1089.92
1089.21
Result
Result
Result
Result
Result
Result
Result
Result
Result
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
Units
Units
Units
Units
Units
Units
Units
Units
Units
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
1
1
1
1
1
1
1
1
1
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
10/20/14
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
NA
NA
NA
NA
NA
NA
NA
NA
NA
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
Method
Method
Method
Method
Method
Method
Method
Method
Method
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 16 of 17
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
Matrix: GW
MW-1002 NLS ID: 835644
MW-1002G NLS ID: 835645
MW-1015A NLS ID: 835646
MW-1005S NLS ID: 835647
MW-1005 NLS ID: 835648
MW-1005P NLS ID: 835649
MW-1010P NLS ID: 835650
MW-1000PR NLS ID: 835651
MW-1014 NLS ID: 835652
Collected: 10/21/14 Received: 10/31/14
Collected: 10/21/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/21/14 Received: 10/31/14
Collected: 10/21/14 Received: 10/31/14
Collected: 10/21/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
1093.06
1092.99
1089.11
1140.02
1140.32
1139.75
1088.36
1088.60
1124.11
Result
Result
Result
Result
Result
Result
Result
Result
Result
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
ft. MSL
Units
Units
Units
Units
Units
Units
Units
Units
Units
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Field Static Water Level by others
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
Parameter
1
1
1
1
1
1
1
1
1
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
Dilution
10/21/14
10/21/14
10/20/14
10/21/14
10/21/14
10/21/14
10/20/14
10/20/14
10/20/14
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
Analyzed
NA
NA
NA
NA
NA
NA
NA
NA
NA
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
Lab
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
FLD-SOP-others
Method
Method
Method
Method
Method
Method
Method
Method
Method
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOD
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
LOQ
Foth Infrastructure & Environment LLC (DePere)Attn: Sharon Kozicki2121 Innovation Court, Suite 300PO Box 5095DePere, WI 54115 5095
Client:
11750NLS Customer:
4th Quarter 2014 GW Sampling Flambeau MineProject:
230465NLS Project:
WDNR Laboratory ID No. 721026460ANALYTICAL REPORTNORTHERN LAKE SERVICE, INC.Analytical Laboratory and Environmental Services400 North Lake Avenue - Crandon, WI 54520Ph: (715)-478-2777 Fax: (715)-478-3060
12/19/14Printed: Code: NNNN-S
EPA Laboratory ID No. WI00034WDATCP Laboratory Certification No. 105-330
Phone:Fax: 715 920 496 6737532 6885
Page 17 of 17
Matrix: GW
Matrix: GW
MW-1004 NLS ID: 835653
MW-1004S NLS ID: 835654
Collected: 10/20/14 Received: 10/31/14
Collected: 10/20/14 Received: 10/31/14
1109.43
1109.50
Result
Result
ft. MSL
ft. MSL
Units
Units
Field Static Water Level by others
Field Static Water Level by others
Parameter
Parameter
1
1
Dilution
Dilution
10/20/14
10/20/14
Analyzed
Analyzed
NA
NA
Lab
Lab
FLD-SOP-others
FLD-SOP-others
Method
Method
LOD = Limit of Detection LOQ = Limit of Quantitation ND = Not Detected (< LOD) 1000 ug/L = 1 mg/LDWB = Dry Weight Basis NA = Not Applicable %DWB = (mg/kg DWB) / 10000MCL = Maximum Contaminant Levels for Drinking Water Samples. Shaded results indicate >MCL.
Values in brackets represent results greater than or equal to the LOD but less than the LOQ and are within a region of "Less-Certain Quantitation". Results greater than or equal to the LOQ are consideredto be in the region of "Certain Quantitation". LOD and/or LOQ tagged with an asterisk(*) are considered Reporting Limits. All LOD/LOQs adjusted to reflect dilution.
Authorized by: R. T. Krueger President________________________________
LOD
LOD
LOQ
LOQ
Reviewed by:
Fourth Quarter 2014
Environmental Monitoring Results
TAD Exceedances
TAD Readable
Chain of Custody Documents
.csv Excel Data File
Notes: site = site assigned PAL/ES : well = well assigned PAL/ES : NR140 = NR140.1 PAL/ES
Flambeau Mining Company4th Quarter 2014 GW Sampling
01-OCT-14
01-OCT-14Collected:03180License:
855034730FID:
NLS Project:Lab ID: 721026460
230465
EXCEEDANCES:
Backfill - DUPBackfill - DUPBackfill - DUPBackfill - DUPMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000RMW-1000RMW-1004PMW-1004PMW-1005MW-1005MW-1005MW-1005PMW-1005PMW-1005SMW-1005SMW-1005SMW-1010PMW-1013MW-1013MW-1013AMW-1013AMW-1013BMW-1013BMW-1013BMW-1013CMW-1013CMW-1013CMW-1013CMW-1014MW-1014AMW-1014BMW-1014BMW-1014BMW-1014CMW-1014C
Well IDArsenic, dis.Copper, dis.Manganese, dis.Sulfate, dis.Arsenic, dis.Iron, dis.Manganese, dis.Sulfate, dis.Manganese, dis.Sulfate, dis.Iron, dis.Manganese, dis.Arsenic, dis.Iron, dis.Manganese, dis.Iron, dis.Manganese, dis.Arsenic, dis.Iron, dis.Manganese, dis.Arsenic, dis.Iron, dis.Manganese, dis.Manganese, dis.Sulfate, dis.Copper, dis.Manganese, dis.Sulfate, dis.Arsenic, dis.Iron, dis.Manganese, dis.Sulfate, dis.Manganese, dis.Sulfate, dis.Copper, dis.Manganese, dis.Sulfate, dis.Arsenic, dis.Iron, dis.
Parameterug/Lug/Lug/Lmg/Lug/Lmg/Lug/Lmg/Lug/Lmg/Lmg/Lug/Lug/Lmg/Lug/Lmg/Lug/Lug/Lmg/Lug/Lug/Lmg/Lug/Lug/Lmg/Lug/Lug/Lmg/Lug/Lmg/Lug/Lmg/Lug/Lmg/Lug/Lug/Lmg/Lug/Lmg/L
Units1.15201200014006.62.42300200110001600.431101.9164101.5682.54.6230232.92600042001906104100016002613960015001300910510120001400234.9
Result1130601251.156012560125.15601.1560.15601.15601.156060125130601251.156012560125130601251.15
PAL10130030025010.3300250300250.330010.3300.330010.330010.3300300250130030025010.3300250300250130030025010.3
ESNR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140NR140
CommentsACL
Notes: site = site assigned PAL/ES : well = well assigned PAL/ES : NR140 = NR140.1 PAL/ES
Flambeau Mining Company4th Quarter 2014 GW Sampling
01-OCT-14
01-OCT-14Collected:03180License:
855034730FID:
NLS Project:Lab ID: 721026460
230465
EXCEEDANCES:
MW-1014CMW-1014CMW-1015B
Well IDManganese, dis.Sulfate, dis.Iron, dis.
Parameterug/Lmg/Lmg/L
Units16002100.22
Result60125.15
PAL300250.3
ESNR140NR140NR140
CommentsACL
TAD PRINTOUT Page 1 of 7Flambeau Mining CompanyCLIENT: 4th Quarter 2014 GW SamplingPROJECT: 10/20/14COLLECTED:230465
MW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PRMW-1000PR
MW-1000PRMW-1000PRMW-1001MW-1001GMW-1001PMW-1002MW-1002MW-1002MW-1002MW-1002MW-1002MW-1002MW-1002MW-1002MW-1002MW-1002MW-1002
MW-1002MW-1002MW-1002GMW-1002GMW-1002GMW-1002GMW-1002GMW-1002GMW-1002GMW-1002GMW-1002GMW-1002GMW-1002GMW-1002G
MW-1002GMW-1002GMW-DUPMW-DUPMW-DUPMW-DUPMW-DUP
Well NameField temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Conductivity, labpH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MS
Parameter9.27778316.116.682006.6<1.02.423001088.60410
2305701121.281119.941120.3811.61881826.396.985.6<0.50<1.0<0.018<1.01093.0680
69959.52452896.416.657.8<0.50<1.0<0.018<1.01092.99120
931702876.687.7<0.50<1.0
Resultdeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Lft.MSLft.MSLft.MSLdeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/LumhospH unitsmg/Lug/Lug/L
Units802802802802802802802802802802802802
802802803804805806806806806806806806806806806806806
806806807807807807807807807807807807807807
807807807807807807807
Well ID000100009400095004000040300946010000104001046010560418922413
3903670295041890418904189000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
39036702950009500403009460100001040
PCODE141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141020141020141020141029141029141029141029141029141029141029141029141029141029141021141029
141029141029141029141029141029141029141029141029141029141029141029141029141021141029
141029141029141029141029141029141029141029
Date828937828937828937828937828937828937828937828937828937828937835651828937
828937828937833444833445833446828929828929828929828929828929828929828929828929828929828929835644828929
828929828929828930828930828930828930828930828930828930828930828930828930835645828930
828930828930828935828935828935828935828935
NLS Sample563617505130504002538183821382538672038
2003860676767563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
20038601750305040025381838
NLS Code
TAD PRINTOUT Page 2 of 7Flambeau Mining CompanyCLIENT: 4th Quarter 2014 GW SamplingPROJECT: 10/20/14COLLECTED:230465
MW-DUPMW-DUPMW-DUP
MW-DUPMW-DUPMW-1003MW-1003PMW-1004MW-1004MW-1004MW-1004MW-1004MW-1004MW-1004MW-1004MW-1004MW-1004MW-1004MW-1004
MW-1004MW-1004MW-1004SMW-1004SMW-1004SMW-1004SMW-1004SMW-1004SMW-1004SMW-1004SMW-1004SMW-1004SMW-1004SMW-1004S
MW-1004SMW-1004SMW-1004PMW-1004PMW-1004PMW-1004PMW-1004PMW-1004PMW-1004PMW-1004PMW-1004PMW-1004PMW-1004PMW-1004P
MW-1004PMW-1004P
Well NameIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field Static Water Level by othersField Static Water Level by othersField temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)
Parameter<0.018<1.0130
941701113.581113.6811.91261006.316.5410<0.505.30.021<1.01109.4340
358010.22122015.826.1835<0.501.3<0.018<1.01109.5083
511108.33113006.937.17<2.5<0.50<1.00.431101107.81140
170130
Resultmg/Lug/Lmg/L
mg/Lmg/Lft.MSLft.MSLdeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/L
Units807807807
807807808809810810810810810810810810810810810810
810810811811811811811811811811811811811811
811811812812812812812812812812812812812812
812812
Well ID010460105622413
39036702950418904189000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295
PCODE141029141029141029
141029141029141020141020141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030
Date828935828935828935
828935828935833461833462828939828939828939828939828939828939828939828939828939828939835653828939
828939828939828940828940828940828940828940828940828940828940828940828940835654828940
828940828940828926828926828926828926828926828926828926828926828926828926835641828926
828926828926
NLS Sample213825382038
20038606767563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
2003860
NLS Code
TAD PRINTOUT Page 3 of 7Flambeau Mining CompanyCLIENT: 4th Quarter 2014 GW SamplingPROJECT: 10/20/14COLLECTED:230465
MW-1005MW-1005MW-1005MW-1005MW-1005MW-1005MW-1005MW-1005MW-1005MW-1005MW-1005MW-1005
MW-1005MW-1005MW-1005SMW-1005SMW-1005SMW-1005SMW-1005SMW-1005SMW-1005SMW-1005SMW-1005SMW-1005SMW-1005SMW-1005S
MW-1005SMW-1005SMW-1005PMW-1005PMW-1005PMW-1005PMW-1005PMW-1005PMW-1005PMW-1005PMW-1005PMW-1005PMW-1005PMW-1005P
MW-1005PMW-1005PMW-1010PMW-1010PMW-1010PMW-1010PMW-1010PMW-1010PMW-1010PMW-1010P
Well NameField temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MS
Parameter10.69789765.866.04141.9<1.0164101140.32290
536608.83443316.776.92<2.52.5<1.04.62301140.02150
18021010.54694576.967.03<2.5<0.50<1.01.5681139.75220
2602208.43413586.987.532923<1.0
Resultdeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/L
Units813813813813813813813813813813813813
813813814814814814814814814814814814814814
814814815815815815815815815815815815815815
815815816816816816816816816816
Well ID000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
39036702950001000094000950040000403009460100001040
PCODE141029141029141029141029141029141029141029141029141029141029141021141029
141029141029141029141029141029141029141029141029141029141029141029141029141021141029
141029141029141029141029141029141029141029141029141029141029141029141029141021141029
141029141029141030141030141030141030141030141030141030141030
Date828933828933828933828933828933828933828933828933828933828933835648828933
828933828933828932828932828932828932828932828932828932828932828932828932835647828932
828932828932828934828934828934828934828934828934828934828934828934828934835649828934
828934828934828936828936828936828936828936828936828936828936
NLS Sample563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
20038605636175051305040025381838
NLS Code
TAD PRINTOUT Page 4 of 7Flambeau Mining CompanyCLIENT: 4th Quarter 2014 GW SamplingPROJECT: 10/20/14COLLECTED:230465
MW-1010PMW-1010PMW-1010PMW-1010P
MW-1010PMW-1010PPZ-1006PZ-1006GPZ-1006SPZ-1007SPZ-1008PZ-1008GPZ-1009PZ-1009GPZ-1011PZ-1012PZ-R1PZ-S1PZ-S3SANDPOINTST-9-23ST-9-23AST-9-26OW-7OW-10OW-39OW-42OW-43MW-1000RMW-1000RMW-1000RMW-1000RMW-1000RMW-1000RMW-1000RMW-1000RMW-1000RMW-1000RMW-1000RMW-1000R
MW-1000RMW-1000RMW-1013MW-1013MW-1013MW-1013MW-1013MW-1013MW-1013MW-1013MW-1013
Well NameIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)DryField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField Static Water Level by othersField temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MS
Parameter<0.018291088.36180
16019001137.101135.941117.651139.661139.381144.381144.481139.601110.201090.561096.551125.931086.231127.191127.311119.211118.591095.891102.421102.291089.791055.07357635.956.43160<0.5083<0.018110001089.92360
23050011.3106011116.016.2523<1.0192.9
Resultmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldescr.ft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLft.MSLdeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/L
Units816816816816
816816817818819820821822823824825826827828829830831832833836837838839840860860860860860860860860860860860860
860860861861861861861861861861861
Well ID01046010560418922413
390367029500006041890418904189041890418904189041890418904189041890418904189041890418904189041890418904189041890418904189000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046
PCODE141030141030141020141030
141030141030141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141020141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030141030
Date828936828936835650828936
828936828936833466833469833468833467833451833452833470833471833472833460833453833454833455833456833457833458833459833450833447833448833449833464828927828927828927828927828927828927828927828927828927828927835642828927
828927828927828923828923828923828923828923828923828923828923828923
NLS Sample21382538672038
200386022676767676767676767676767676767676767676767563617505130504002538183821382538672038
200386056361750513050400253818382138
NLS Code
TAD PRINTOUT Page 5 of 7Flambeau Mining CompanyCLIENT: 4th Quarter 2014 GW SamplingPROJECT: 10/20/14COLLECTED:230465
MW-1013MW-1013MW-1013
MW-1013MW-1013MW-1013AMW-1013AMW-1013AMW-1013AMW-1013AMW-1013AMW-1013AMW-1013AMW-1013AMW-1013AMW-1013AMW-1013A
MW-1013AMW-1013AMW-1013BMW-1013BMW-1013BMW-1013BMW-1013BMW-1013BMW-1013BMW-1013BMW-1013BMW-1013BMW-1013BMW-1013B
MW-1013BMW-1013BMW-1013CMW-1013CMW-1013CMW-1013CMW-1013CMW-1013CMW-1013CMW-1013CMW-1013CMW-1013CMW-1013CMW-1013C
MW-1013CMW-1013CMW-1014MW-1014
Well NameManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by others
Parameter260001114.88560
6006809.19149406.396.64190<1.03.80.09942001099.70460
3306209.4296331276.036.211600<1.06100.036410001100.082100
600320010.1290531186.186.57150026<1.01396001102.612000
510300010.0600
Resultug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhos
Units861861861
861861862862862862862862862862862862862862
862862863863863863863863863863863863863863
863863864864864864864864864864864864864864
864864865865
Well ID010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
39036702950001000094
PCODE141030141020141030
141030141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030
Date828923835638828923
828923828923828924828924828924828924828924828924828924828924828924828924835639828924
828924828924828925828925828925828925828925828925828925828925828925828925835640828925
828925828925828922828922828922828922828922828922828922828922828922828922835637828922
828922828922828938828938
NLS Sample2538672038
2003860563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
20038605636
NLS Code
TAD PRINTOUT Page 6 of 7Flambeau Mining CompanyCLIENT: 4th Quarter 2014 GW SamplingPROJECT: 10/20/14COLLECTED:230465
MW-1014MW-1014MW-1014MW-1014MW-1014MW-1014MW-1014MW-1014MW-1014MW-1014
MW-1014MW-1014MW-1014AMW-1014AMW-1014AMW-1014AMW-1014AMW-1014AMW-1014AMW-1014AMW-1014AMW-1014AMW-1014AMW-1014A
MW-1014AMW-1014AMW-1014BMW-1014BMW-1014BMW-1014BMW-1014BMW-1014BMW-1014BMW-1014BMW-1014BMW-1014BMW-1014BMW-1014B
MW-1014BMW-1014BBackfill - DUPBackfill - DUPBackfill - DUPBackfill - DUPBackfill - DUPBackfill - DUPBackfill - DUPBackfill - DUP
Backfill - DUP
Well NameConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Conductivity, labpH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)
Parameter6335.966.40110<1.09.4<0.01813001124.11290
1604208.8205221416.396.67910<1.04.00.019461120.321300
51018009.2277529206.026.411400<1.0510<0.018120001117.922000
510270029756.4014001.1520<0.018120001900
550
Resultumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/LumhospH unitsmg/Lug/Lug/Lmg/Lug/Lmg/L
mg/L
Units865865865865865865865865865865
865865866866866866866866866866866866866866
866866867867867867867867867867867867867867
867867867867867867867867867867
867
Well ID00095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
39036702950009500403009460100001040010460105622413
39036
PCODE141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141030141030141030141030141030141030141030141030
141030
Date828938828938828938828938828938828938828938828938835652828938
828938828938828919828919828919828919828919828919828919828919828919828919835611828919
828919828919828920828920828920828920828920828920828920828920828920828920835635828920
828920828920828941828941828941828941828941828941828941828941
828941
NLS Sample17505130504002538183821382538672038
2003860563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
20038601750305040025381838213825382038
200
NLS Code
TAD PRINTOUT Page 7 of 7Flambeau Mining CompanyCLIENT: 4th Quarter 2014 GW SamplingPROJECT: 10/20/14COLLECTED:230465
Backfill - DUPMW-1014CMW-1014CMW-1014CMW-1014CMW-1014CMW-1014CMW-1014CMW-1014CMW-1014CMW-1014CMW-1014CMW-1014C
MW-1014CMW-1014CMW-1015AMW-1015AMW-1015AMW-1015AMW-1015AMW-1015AMW-1015AMW-1015AMW-1015AMW-1015AMW-1015AMW-1015A
MW-1015AMW-1015AMW-1015BMW-1015BMW-1015BMW-1015BMW-1015BMW-1015BMW-1015BMW-1015BMW-1015BMW-1015BMW-1015BMW-1015B
MW-1015BMW-1015B
Well NameSolids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)Field temperature by othersField conductivity by othersConductivity, labField pH by otherspH, LabSulfate, as SO4 (filtered)Arsenic, dis. as As by ICP-MSCopper, dis. as Cu by ICP-MSIron, dis. as Fe by ICP-MSManganese, dis. as Mn by ICP-MSField Static Water Level by othersHardness, tot. recoverable as CaCO3(calc/filt/icpms)Alkalinity, tot. as CaCO3 (filtered)Solids, tot. dis. (TDS)
Parameter28009.696710026.396.6421023<1.04.916001112.66530
2706508.21901896.786.957.8<0.50<1.00.117.71089.1183
801308.05445557.377.49<2.5<0.50<1.00.22591089.21150
180310
Resultmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/Ldeg Cumhosumhoss.u.pH unitsmg/Lug/Lug/Lmg/Lug/Lft.MSLmg/L
mg/Lmg/L
Units867868868868868868868868868868868868868
868868869869869869869869869869869869869869
869869870870870870870870870870870870870870
870870
Well ID70295000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295000100009400095004000040300946010000104001046010560418922413
3903670295
PCODE141030141030141030141030141030141030141030141030141030141030141030141020141030
141030141030141029141029141029141029141029141029141029141029141029141029141020141029
141029141029141030141030141030141030141030141030141030141030141030141030141020141030
141030141030
Date828941828921828921828921828921828921828921828921828921828921828921835636828921
828921828921828931828931828931828931828931828931828931828931828931828931835646828931
828931828931828928828928828928828928828928828928828928828928828928828928835643828928
828928828928
NLS Sample3860563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
2003860563617505130504002538183821382538672038
2003860
NLS Code
Attachment 2
Certification of Fourth Quarter 2014
Environmental Monitoring Results
ENVIRONMENTAL MONITORING DATA CERTIFICATION Form 4400-231(R 1/04)
03180License No. / Monitoring ID
855034730Facility ID [FID]
Flambeau Mining CompanyFacility Name
MAY -20-2014
Actual sampling dates (e.g., July 2-6, 2003
State of WisconsinDepartment of Natural ResourcesNotice: Personally identifiable information collected will be used for program administration and enforcement purposes. The department mayalso provide this information to requesters as required under Wisconsin's Open Records law, ss. 19.31 to 19.39, Wis. Stats.When submitting monitoring data, the owner or operator of the facility, practice or activity is required to notify the Department in writing that a groundwater standard or an explosive gas level has been attained or exceeded, as specified in ss. NR 140.24(1)(a); NR 140.26(1)(a); NR507.30; NR635.14(9)(a); NR 635.18(20) and NR 507.30, Wis. Adm. Code. Failure to report may result in fines, forfeitures or other penaltiesresulting from enforcement under ss. 289.97, 291.97 or 299.95, Wis. Stats.
Instructions:* Prepare one form for each license or monitoring ID.* Please type or print legibly.* Attach a notification of any values that attain or exceed groundwater standards (that is, preventive action limits, enforcement standards or alternative concentration limits). The notification must include a preliminary analysis of the cause and significance of each value.* Attach a notification of any gas values that attain or exceed explosive gas levels.* Send the original signed form, any notification, and Electronic Data Deliverable [EDD] to: GEMS Data Submittal Contact - WA/3 Bureau of Waste and Materials Management Wisconsin Department of Natural Resources 101 South Webster Street P.O. Box 7921 Madison, WI 53707 - 7921
Monitoring Data Submittal InformationName of entity submitting data (laboratory, consultant, facility owner):Northern Lake Service, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:Name: Chris Geske Phone: 715-478-2777E-mail: [email protected]
The enclosed results are for sampling required in the month(s) of: (e.g., June 2003)
Type of Data Submitted (Check all that applyGroundwater monitoring data from monitoring wellsGroundwater monitoring data from private water supply wellsLeachate monitoring data
Gas monitoringdataAir monitoring data
Notification attached?No. No groundwater standards or explosive gas limits were exceeded.Yes, a notification of values exceeding a groundwater standard is attached. It includes a list of monitoring points, dates, sample values, groundwater standard and preliminary analysis of the cause and significance of any concentration.Yes, a notification of values exceeding an explosive gas limit is attached. It includes the monitoring points, dates, sample values and explosive gas limits.
CertificationTo the best of my knowledge, the information reported and statements made on this data submittal and attachementsare true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceedinggroundwater standards or explosive gas levels, and a preliminary analysis of the cause and significant of concentrations exceeding groundwater standards.
Facility Representative Name (Print) Title (Area Code) Telephone No.
Signature Date
FOR DNR USE ONLY. Check action taken, and record date and your initials. Describe on back side if necessary.Found uploading problems on ________________________ Initials ________________________Notified contact of problems on _______________________ Uploaded data successfully on ___________________
EDD format(s): Diskette CD (initial submittal and follow-up) E-mail (follow-up only) Other _______________
MAY -2014
MAY -19-2014through