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Fix Leaks Fast!

Pipe Repair Bandages

Rapp-it is the Ultimate Pipe Repair System for your temporary emergency pipe repair needs. Quick and simple to use with no mixing or measuring required. A successful pipe repair can be achieved in only 30 mins.

Rapp-it Pipe Repair System includes a woven fiberglass bandage impregnated with a water-activated polyurethane resin and a 50mm (2”) stick of Rapp-it Steel Putty. Rapp-it Steel Putty is hand-mixable, steel- reinforced epoxy putty that can be moulded into any shape to fill cavities, cracks or holes for a more successful repair.

Rapp-it can be used on all types of pipes including stainless steel, copper, PVC, steel, rubber, concrete, metal, galvanised, fiberglass, and polypropylene. It can be applied on cracked, fractured, corroded, damaged and leaking pipes, around difficult shapes including straight lengths, tee and elbow joints, couplings and clamps. Rapp-it is suitable for use on wet or dry pipes. It can even be applied underwater, in fresh or saltwater!

About Rapp-it

“A successful pipe repair can be

achieved in only 30 minutes!”

FIVE CONVENIENT SIZES PART No.

50mm x 3.6m (2”x 12’) RAP 122

75mm x 3.6m (3”x 12’) RAP 123

100mm x 3.6m (4”x 12’) RAP 124

100mm x 4.8m (4”x 16’) RAP 164

100mm x 9.0m (4”x 30’) RAP 304

Rapp-it Application, Hints & Tips 2

FAQS 3

Why use Rapp-it? 4

Market Places 5

Testimonials 6

Rapp-it Testing 8

Rapp-it Bandage MSDS 9

Rapp-it Steel Putty MSDS 14

Contents

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RAPP-IT PIPE REPAIR BANDAGE SPEcIfIcATIoNS

catalyst Water

Resin Makeup Polyurethane

Heat Resistance 150°c (300°f)

Pressure Resistance 360 psi (2500 kPa)

Bonds Steel Galvanised Copper, Concrete, PVC, Polypipe, Fibreglass Clay

Set Time 20 – 30 minutes, sets under water

chemical resistance Most diluted chemicals and fuels

NATo Stock Number 4730-66-1257893

RAPP-IT STEEl PuTTy SPEcIfIcATIoNS

Hardness, Shore D (full cure) 75 – 85

Heat Resistance 150°C (300°F)

Set Time Approximately 3 minutes

chemical resistance Resistant to hydrocarbons, ketones, alcohols, esters, halocarbons, aqueous salt solutions, and dilute acids and bases

DIREcTIoNS foR uSE

Identify leak area and shut down relevant pipe or hoses immediately. If pipe cannot be shut down turn pressure as low as possible.

1. Clean and roughen the damaged area of the pipe with a metal file or wire brush. A clean roughened surface helps result in a successful repair.

2. Open and knead Rapp-it Steel Putty until it is a uniform grey colour.

3. Apply to the pipe leak site within two minutes of mixing, forcing it into any cracks or holes.

4. Open foil pouch and immerse Rapp-it Bandage in temperate water for 15-20 seconds, squeeze the bandage to allow water soak in evenly.

5. Apply Rapp-it Bandage immediately around the damaged pipe area extending up to 50mm (2”) either side of the leak. It is important to apply the bandage before the putty is cured.

6. When wrapping, pull each layer tightly and firmly, using your hand to mould and squeeze the layers together in a tightening motion. Continue to apply pressure during application and upon completion.

for best results, the completed bandage application should be no less than 10mm thick (12-15 wraps). Allow 30 minutes for Rapp-it Pipe Repair System to set rock-hard.

HINTS AND TIPS foR RAPP-IT PIPE REPAIR APPlIcATIoN:

• The tightness of the wrap is very important to ensure adhesion of Rapp-it Bandage and Rapp-it Steel Putty to the pipe surface.

• Rapp-it Bandage has a 4-5 minute work life, with full cure in 30 minutes. Water temperature can affect the bandage cure time. Colder water can result in a slower curing time, higher water temperatures can result in a faster cure time.

• Rapp-it Steel Putty has a 4-7 minute work life, with full cure in 30 minutes.

• Rapp-it Steel Putty can be mixed by hand and then moulded into a variety of shapes to fill cracks and holes. When applying to damp, wet or slowly leaking areas work Rapp-it Steel Putty forcefully into the surface and apply pressure until adhesion begins to take effect.

• Difficult or large applications may require multiple bandages.

Rapp-it Application

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can Rapp-it be used as permanent repair? Rapp-it is intended as a temporary pipe repair for onsite emergency situations. However, Rapp-it has been known to last many years, providing sound structural pipe repairs. Ultimately, this is up to the discretion of the user.

If the leaking pipe (live line) cannot be isolated, can Rapp-it Pipe Repair still be used? Yes, Rapp-it can be used to stem the flow of the pipe leak until an alternative procedure can be completed. Isolating the pipes is the most effective repair however we understand this cannot always be done. In that instance simply turn down the pressure as low as possible when applying Rapp-it.

If the pipe has a small leak and is unable to be completely dry, can Rapp-it be used? Absolutely. Rapp-it Pipe Repair is ideal for use in wet applications. We suggest the pipe be cleaned and roughened first to ensure a successful repair.

can Rapp-it Pipe Repair be used underwater? Yes, both Rapp-it Pipe Repair Bandage and Rapp-it Steel Putty can be used underwater in either fresh or salt water. Curing time may vary according to the temperature of the water, cold water will increase the cure time, and hot water will reduce the cure time.

What is the recommended thickness of Rapp-it? Our recommended Rapp-it repair thickness is a minimum of 10mm or approximately 12-15 wraps around the pipe. We also recommend the repair extend 50mm either side of the wound area.

What is the cure time for Rapp-it Pipe Repair System? As soon as the foil bandage packet is opened the bandage will start to cure. Rapp-it Bandage has a working life of 4-5 minutes and a full cure time of 30 minutes. Rapp-it Steel Putty has a working life of 4-7 minutes and a full cure time of 30 minutes.

can Rapp-it Pipe Repair be used on pipes with larger diameters? Yes. We supply the RAP304 (100mm x 9m) for larger diameter pipes and elbows. Multiple bandages may be required for very large pipes.

can I repair my pipe using only the bandage? Yes, Rapp-it Pipe Repair Bandage can be used alone. We do recommend the combination of Rapp-it Steel Putty along with our Rapp-it Pipe Repair bandage to ensure a more successful pipe repair.

How can I remove Rapp-it once it’s cured? Rapp-it Pipe Repair Bandages can be removed with a hacksaw or angle grinder. Hammer and coal chisel is also an effective method of removing the bandage. When using an angle grinder, always use a respirator during the removal. All ways check the fluid/gas in the pipe first as fluid or medium may be flammable and ensure appropriate PPE (Personal Protection Equipment) is worn at all times.

Does Rapp-it have an expiry date? Rapp-it’s shelf life is approximately 2 years from date of purchase if stored below 25°C (77°F), and the foil pouch is not punctured.

can Rapp-it be used on an underground or buried pipe? Yes, however as Rapp-it is a temporary repair we recommend a job and location report be filed so the repair location is recorded for when a permanent repair is arranged at a later date.

What liquids/gas can I use Rapp-it on? Rapp-it can safely handle all Fluids/mediums from Potable Water (Drinking Water) to Sulphuric / Hydrochloric Acid and all industrial slurry.

FAQs

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RAPP-IT IS THE SMART TEMPoRARy AlTERNATIvE To cHANGE ouTS oNSITE.

use Rapp-it to delay changing out pipes

• Allows time for more effective shut down planning

• Fewer shut downs save time and money

• Supplies can be ordered rather than stored on site, reducing overheads

• Extends life of the pipe

Rapp-it as a temporary solution has many other benefits:

• 30 minute repair

• Able to be applied by any apprentice applicator

• Versatile – can go on different pipe sizes, shapes (elbows etc) and substrates

• Cost efficient

• OHS benefits – leaks are stopped faster

• On hand at all times – 2 years shelf life

over 80% of processing mine sites in Australia use Rapp-it Pipe Repair Bandages

Why Use Rapp-it?

“Rapp-it can be used on all types

of pipes including stainless steel,

copper, PVC, steel, rubber, concrete,

metal, galvanised, fibreglass or

polypropylene.”

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coAl MINES Coal preparation wash plants: MDISC, water, steam, slurry and sludge lines etc. Emergency repairs to leaking pipes.

GolD MINES Processing plant: chemical, sludge, slurry and by-product/waste pipes. Emergency repairs to chemical supply lines.

BAuXITE MINES Processing plant: refinery/alumina section and smelter/aluminum section. Emergency repairs to sludge & chemical lines.

coAl, coPPER & ZINc SMElTING Processing: blast furnaces, water, steam, sludge and slurry lines. Emergency repairs.

STEEl SMElTER WoRKS Processing: blast furnaces, water, steam and waste product pipes. Emergency repairs until shutdown.

STEEl SHEET & coIl MANufAcTuRING Processing: steam and water pipes. Emergency repairs to burst pipes.

PETRolEuM Oil, gas and water supply lines. Emergency repairs to fuel, oil and gas lines during 24 hour shift.

SuGAR MIllS Corrosive fluid lines, abrasive product pipes, low pressure, water and steam lines. Emergency repairs to corrosive, water, steam and abrasive lines.

POWER STATIONS Ash transfer systems, pulverised fuel tubes and cooling water lines. Emergency repairs to transfer systems and lines.

MERcHANT SHIPPING Engine room. Emergency repairs while at sea to fuel, oil, water and waste lines. Damage control within engine room and fire fighting facilities.

Marketplaces

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Additional to leak repairs, Rapp-it can also be used as corrosion protection and noise reduction.

RuSSEll WIlTSHIRE Supply Supervisor, BHP Billiton

“We have been using Rapp-it Pipe Repair Bandage for leakage applications for the past four years. It has been extremely reliable with regards to pipe repairs. Approximately $20,000 annually are saved on costly downtime”.

WAyNE RAISBAcK Bluescope Steel, Port Kembla NSW

“Our processing plant utilizes nine different chemical baths and over 40 recirculating fluid systems that together have over forty kilometres of piping systems in Cast Steel, Stainless Steel, PVC and ABS plastics. Our mechanical department have been using Rapp-it Bandages for a number of years with almost perfect results on all our piping systems and chemicals. We have literally had situations where $100,000 worth of downtime was averted by a small foil package.”

What our Customers say

“They use so much

Rapp-it there that they have

their own Rapp-it Response Team”

Shayne Evers, Rapp-it Sales

Representative

“The first thing I did as Maintenance Manager was put Rapp-it onsite”

GlENN D. Iron ore Mine, Pilbara, Western Australia

“Rapp-it is the Panadol for the Maintenance Managers, it cures most headaches”

MoNTy l. coal Mine, Bowen Basin, Queensland.

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EDWARD G. coal Preparation Plant, Queensland

“I work in a Coal Preperation Plant in Middlemount, Queensland. Pipes are hard wearing and we patch them with Rapp-it Bandages regularly. They do an excellent job stopping the bad leaks until we shut down for a maintenance day to repair or replace.”

PAul S. Pulp & Paper Mill, victoria

“During a Saturday night shift a pipe bridge was damaged after it had been struck by a tip truck. The structure was secured into position by chain blocks but the 200mm spiral wound stainless pipe had been kinked and was pouring liquor onto the ground. This liquor is an environmental hazard and had to be stopped from getting into nearby stormwater drain. To call a boilermaker in would take time and cost money and as well as production down time. With the use of two 100mm Fibreglass bandages along with the steel putty the pipe was repaired and put back into service 45 minutes later. Great product which got us out of trouble again.”

lISA D. Nickel Plant, Western Australia

“This is a tailings line out to the thickeners discharge. We placed 6 Rapp-it Bandages on the pipe which resulted in a positive seal – no leaks!”

“No Rapp-it, no plant” AllAN S. Nickel Processing Plant, Western Australia

“There is more Rapp-it than steel in my plant” DAvE M. Base and Precious Metals Mining operation, Western Australia

“Rapp-it Pipe Repair Bandages have been on some pipes for more than two years and are still going strong.

Even in a difficult spot, Rapp-it still does the job!” MIcHAEl J. fly Ash Handling System, Queensland

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Rapp-it Testing

“Rapp-it is suitable for use on wet or dry pipes. It can even be applied

underwater, in fresh or saltwater.”

PoTABlE (DRINKING) WATER

Rapp-it Bandages and Rapp-it Steel Putty are safe for use on potable (drinking) water. Our Rapp-it Bandage is compliant to Australian Standard AS/NZS 4020:2005. Our Rapp-it Steel Putty is compliant to US Standard NSF 61.

PRESSuRE TESTING

Proof pressure test successful at 565 PSI (3895 kPa) on 50mm poly pipe with 10mm drilled hole.

Proof pressure test successful at 1160 PSI (8000 kPa) on 25mm poly pipe with 10mm drilled hole.

*Pressure rating will change according to type of pipe and type of damage.

for more information, please contact us on +61 7 3262 3755.

TEMPERATuRE TESTING

Three Simultaneous Thermal Analysis tests were performed on Rapp-it Pipe Repair System. The resulting continuous temperature limit is 150 degrees Celsius. Rapp-it can withstand intermittent temperatures up to 250 degrees Celsius. Please refer to MSDS for more information.

RAPP-IT BANDAGE cHEMIcAl RESISTANcE

50mm (2”) Rapp-it Pipe Repair Bandages were rolled to five layers and submerged in the following chemicals for a period of one month. The changes, if any, are outlined below.

IMMERSIoN TESTING RESulTS

Hydrochloric Acid 30% Severe discolouration No softening of bandage (bandage turned deep yellow-green)

Sulfuric Acid 92% Severe discolouration No softening of bandage

Caustic Soda 50% Slight colour change No softening of bandage

Ethyl Alcohol No visible change No softening of bandage

MEK Moderate discolouration No softening of bandage

Acetone No visible change No softening of bandage

Toluene No visible change No softening of bandage

Gasoline No visible change No softening of bandage

Diesel Fuel Slight colour change No softening of bandage

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MATERIAl SAfETy DATA SHEET – RAPP-IT PIPE REPAIR BANDAGE

Infosafe No ™ lPXZ9 Issue Date: April 2014 ISSuED by MARININD PAGE: 1 of 5

Product Name : RAPP-IT PIPE REPAIR BANDAGE classified as Hazardous

1. IDENTIfIcATIoN

GHS Product RAPP-IT PIPE REPAIR BANDAGE

Identifier Company Name MARINE & INDUSTRIAL MARKETING (ABN 32051 014 049)

Address 12/14 Argyle Street, Albion, Queensland 4010

Telephone/Fax Number Tel: (07) 3262 3755 Fax: (07) 3262 3255

Emergency Phone Number Poisons Centre – 13 11 26 – 24 hours

Recommended use of the Used for emergency pipe repair to fluid control pipes. chemical and restrictions on use

2. HAZARD IDENTIfIcATIoN

Classification of the Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS)substance or mixture including Work, Health and Safety regulations, Australia

Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition)

Classification: Acute Toxicity - Inhalation: Category 4 Sensitization - Respiratory: Category 1 Sensitization - Skin: Category 1 Carcinogenicity: Category 2 Skin Corrosion/Irritation: Category 2 Eye Damage/Irritation: Category 2A STOT Repeated Exposure Category 2 STOT Single Exposure Category 3 (respiratory tract irritation)

Signal Word(s) Danger

Hazard Statement(s) H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure by inhalation

General P101 If medical advice is needed, have product container or label at hand.

Precautionary P102 Keep out of reach of children.

Statement(s) P103 Read label before use.

Pictogram(s) Exclamation mark, Health hazard Precautionary Statement – P201 Obtain special instructions before use.Prevention P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash contaminated skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection.

Precautionary Statement – P308+P313 IF exposed or concerned: Get medical advice/ attention.Response P314 Get medical advice/attention if you feel unwell. P331 Do NOT induce vomiting. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

MSDS

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P337+P313 If eye irritation persists: Get medical advice/attention.

P302+P352 IF ON SKIN: Wash with plenty of soap and water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before re-use.

Precautionary Statement – P405 Store locked up.Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary Statement – P501 Dispose of contents/container to an approved waste disposal plant.Disposal

3. coMPoSITIoN/INfoRMATIoN oN INGREDIENTS

Information on Composition The dry product is not classified as hazardous. When the product is used to repair pipes it reacts with water and hardens. This hardening process can generate some heat and may generate 4,4’-Methylenediphenyl diisocyanate (CAS 101-68-8) which is hazardous. After hardening, exposure to isocyanates is not expected.

Ingredients Name CAS Proportion Polyester polyol 0-70 % Propylene Oxide, Polymer with 9082-00-2 0-70 % Ethylene Oxide and Glycerol 1,3-Di[4- 31107-36-5 0-70 % [(p-isocyanatophenyl)methyl Glass, oxide 65997-17-3 30-60 %

4. fIRST AID MEASuRES

Inhalation If inhaled, remove affected person from contaminated area. Apply artificial respiration if not breathing. Seek medical attention.

Ingestion Unlikely to occur due to the physical state of the product. However, if ingested, rinse mouth with water. Do NOT induce vomiting. Seek medical attention.

Skin Exposure to wet product: Remove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. If product adheres to skin remove as soon as possible with acetone or alcohol. Wash contaminated clothing before reuse or discard. Seek medical attention.

Eye contact Exposure to wet product: If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed out completely. Seek medical attention.

First Aid Facilities Eye wash fountain and normal washroom facilities.

Advice to Doctor Treat symptomatically.

Other Information For advice in an emergency, contact a Poisons Information Centre (Phone Australia 13 1126) or a doctor at once.

5. fIRE fIGHTING MEASuRES

Suitable Extinguishing Media Use carbon dioxide, dry chemical or foam.

Hazards from Combustion Under fire conditions this product may emit toxic and/or irritating fumes including carbon monoxide, carbon dioxide, Products oxides of nitrogen, isocyanates and hydrogen cyanide.

Specific Hazards arising Combustible solid. This product will burn if exposed to fire.from the chemicalDecomposition Temp. Not available.Precautions in connection Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode with Fire and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat-

exposed containers. Fight fire from safe location.

6. AccIDENTAl RElEASE MEASuRES

Personal precautions, Remove all sources of ignition. Increase ventilation. Evacuate all unprotected personnel. Do not breathe dust or protective equipment and vapour. Wear respiratory protection and full protective clothing to minimise exposure. Collect material avoiding dustemergency procedures generation - then transfer material in to suitable vapour tight labelled containers for subsequent recycling or disposal.

Dispose of waste according to applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations.

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7. HANDlING AND SToRAGE

Precautions for Safe Handling Wear appropriate protective clothing and equipment to prevent inhalation, skin and eye exposure. Avoid inhalation of dust generated when removing the product from pipes, and skin or eye contact. Use disposable gloves. Product will adhere on contact with skin or clothing. If product adheres to skin remove as soon as possible with acetone or alcohol. Maintain high standards of personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities.Avoid exposure. Do not handle until all safety precautions have been read and understood.

Conditions for Safe Storage Store in a cool, dry, well-ventilated area away from sources of ignition, oxidising agents, strong acids, foodstuffs, and

including an Incompatibilities clothing. Keep containers closed when not in use and securely sealed and protected against physical damage. Avoid contact with moisture or water as product will harden. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. Ensure that storage conditions comply with applicable local and national regulations.

8. EXPoSuRE coNTRolS/PERSoNAl PRoTEcTIoN

Occupation Exposure No exposure value assigned for this material by Safe Work, Australia. However, the available exposure limits for Limit Values ingredients are listed below:

Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Isocyanates, - 0.02 - 0.07 Sen all (as NCO) TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day week.

STEL (Short Term Exposure Limit): The average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight-hour workday.

‘Sen’ Notice: The substance may cause sensitisation by skin contact or by inhalation.

Biological Limit Values No biological limit allocated.

Appropriate Engineering Provide sufficient ventilation to keep airborne levels as low as possible. Where vapours, mists or dusts are generated, Controls particularly in enclosed areas, and natural ventilation is inadequate, a local exhaust ventilation system is required.

Respiratory Protection If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable mist/particulate filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances.

Eye Protection Safety glasses with side shields or chemical goggles should be worn. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.

Hand Protection Wear disposable gloves of impervious material. Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.

Body Protection Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled.

9. PHySIcAl AND cHEMIcAl PRoPERTIES

Appearance A knitted fibreglass substrate with a polyurethane resinOdour Characteristic faint odourDecomposition Not availableTemperature Freezing Point Not availableBoiling Point Not availableSolubility in Water Reacts with water.Specific Gravity 1.12 at 25°CpH Not availableVapour Pressure Not availableVapour Density (Air=1) Not availableEvaporation Rate Not availableOdour Threshold Not availablePartition Coefficient: Not availablen-octanol/water

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Flash Point >200°CFlammability Not flammableAuto-Ignition Temperature Not availableFlammable Limits - Lower Not availableFlammable Limits - Upper Not available

10. STABIlITy AND REAcTIvITy

Reactivity Curing reaction occurs with water. Chemical resistance test results for the cured bandage for exposure for 1 month: 1. Exposure to ethyl alcohol, acetone, toluene, xylene, gasoline, mineral spirits, 20% sodium hydroxide, distilled water: No change in bandage. 2. Exposure to 30% hydrochloric acid and 50% caustic soda: No softening of bandage. Some colour change. 3. Exposure to 50% nitric acid: Blistering.

Chemical Stability Stable under normal conditions of storage and handling.

Conditions to Avoid Avoid moisture or water before use. This will cause unwanted hardening.

Incompatible Materials Uncured bandage: Acids and bases, amines, alcohols and strong oxidizing agents.

Hazardous Decomposition Under fire conditions this product may emit toxic and/or irritating fumes including carbon monoxide, carbon dioxide, Products oxides of nitrogen, isocyanates and hydrogen cyanide.

Hazardous Polymerization Will not occur.

11. ToXIcoloGIcAl INfoRMATIoN

Toxicology Information No toxicity data available for this material.

Ingestion Ingestion unlikely due to form of product. Ingestion of this product may irritate the gastric tract causing nausea and vomiting.

Inhalation Isocyanates are harmful by inhalation and irritating to respiratory system. Inhalation of isocyanates may cause sensitisation, and asthma-like symptoms in some individuals. Exposure to isocyanates can occur when the product reacts with water.

Skin Exposure to isocyanates can occur when the product reacts with water. Isocyanates are irritating to the skin and skin contact may cause redness, itching and swelling. Repeated exposure may cause skin dryness and cracking and may lead to dermatitis. May cause sensitisation by skin contact.

Eye Exposure to isocyanates can occur when the product reacts with water. Isocyanates are irritating to eyes and on eye contact, can cause tearing, stinging, blurred vision, and redness.

Respiratory Sensitisation May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Skin Sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity Not considered to be a mutagenic hazard.

Carcinogenicity 4,4’-Methylenediphenyl diisocyanate is classified as a Category 3 Carcinogen according to National Occupational Health and Safety Commission (NOHSC). That is, there is some evidence from appropriate animal studies that human exposure to this substance may result in the development of cancer, but this evidence is insufficient to place the substance in Category 2. Category 3 Carcinogens are substances that cause concern for humans owing to possible carcinogenic effects.

Reproductive Toxicity Not considered to be toxic to reproduction.

STOT-single Exposure May cause respiratory irritation

STOT-repeated Exposure May cause damage to organs through prolonged or repeated exposure by inhalation.

Aspiration Hazard Not expected to be an aspiration hazard.

12. EcoloGIcAl INfoRMATIoN

Ecotoxicity No ecological data are available for this material.Persistence and Degradability Not availableMobility Not availableBioaccumulative Potential Not availableEnvironmental Protection Prevent this material entering waterways, drains and sewers.

13. DISPoSAl coNSIDERATIoNS

Disposal Considerations The disposal of the spilled or waste material must be done in accordance with applicable local and national regulations.

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14. TRANSPORT INFORMATION

Transport Information Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea.

IMDG Marine Pollutant No

15. REGulAToRy INfoRMATIoN

Regulatory Information Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP)

Poisons Schedule Not Scheduled AICS (Australia) All components of this product are listed on the Inventory or exempted.

16. oTHER INfoRMATIoN

Date of preparation or SDS Amendment: July 2014last revision of SDS 1. Identification of the Material and Supplier

SDS Reviewed: April 2014 Supersedes: October 2011

Literature References Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice Standard for the Uniform Scheduling of Medicines and Poisons. Australian Code for the Transport of Dangerous Goods by Road & Rail. Model Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals.

Workplace exposure standards for airborne contaminants, Safe work Australia. American Conference of Industrial Hygienists (ACGIH) Globally Harmonised System of classification and labelling of chemicals.

...END of MSDS...

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MATERIAl SAfETy DATA SHEET – RAPP-IT STEEl PuTTy

Infosafe No ™ A00Av Issue Date: August 2011 ISSuED by MARININD PAGE: 1 of 3

Product Name : RAPP-IT STEEl PuTTy Not classified as hazardous

1. IDENTIfIcATIoN

Product Name RAPP-IT STEEL PUTTY

Product Code RAPSTP001

Company Name MARINE & INDUSTRIAL MARKETING (ABN 32051 014 049)

Address 12/14 Argyle Street, Albion, Queensland 4010

Telephone/Fax Number Tel: (07) 3262 3755 Fax: (07) 3262 3255

Emergency Phone Number Poisons Centre – 13 11 26 – 24 hours

Recommended Use Not available

2. HAZARDS IDENTIfIcATIoN

Hazard Classification Not classified as hazardous NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. Not Classified as Hazardous according to criteria of National Occupational Health & Safety Commission, Australia (NOHSC). Not Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition)

3. coMPoSITIoN/INfoRMATIoN oN INGREDIENTS

Ingredients Name CAS Proportion Diglycidyl ether of bisphenol A 25036-25-3 7-13 % Diglycidyl ether of bisphenol A 25085-99-8 5-10 % 2,4,6-Tri(dimethyl aminomethyl) phenol 90-72-2 0.5-1.5 % Ingredients determined not to be hazardous. Balance

4. fIRST AID MEASuRES

Inhalation If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms persist seek medical attention.

Ingestion Do not induce vomiting. Wash out mouth thoroughly with water. If symptoms develop seek medical attention.

Skin Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention.

Eye If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed out completely. If symptoms develop and persist seek medical attention.

First Aid Facilities Eye wash and normal washroom facilities.

Advice to Doctor Treat symptomatically.

5. fIRE fIGHTING MEASuRES

Suitable Extinguishing Media Carbon dioxide, foam and dry chemicals.

Hazards from Combustion Under fire conditions this product may emit toxic and/or irritating fumes and gases including carbon monoxide, Products carbon dioxide, oxides of nitrogen and sulfur.

Specific Hazards Combustible paste. This product will readily burn under fire conditions.

Precautions in connection Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode with Fire and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down

heat-exposed containers. Fight fire from safe location. This product should be prevented from entering drains and watercourses.

6. AccIDENTAl RElEASE MEASuRES

Emergency Procedures Wear appropriate personal protective equipment and clothing to prevent exposure. Extinguish or remove all sources of ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Place inert absorbent, non-combustible material onto spillage. Use clean non-sparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water authorities and EPA in accordance with local regulations.

15




7. HANDlING AND SToRAGE

Precautions for Safe Handling Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up of mists or vapours in the work atmosphere. Avoid inhalation of vapours and mists, and skin or eye contact. Do not use near ignition sources. Do not pressurise, cut, heat or weld containers as they may contain hazardous residues. Maintain high standards of personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities.

Conditions for Safe Storage Store in a cool, dry, well-ventilated area away from sources of ignition, oxidising agents, strong acids, foodstuffs, and clothing. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. For information on the design of the storeroom, reference should be made to Australian Standard AS1940 - The storage and handling of flammable and combustible liquids. Reference should also be made to all applicable local and national regulations.

8. EXPoSuRE coNTRolS/PERSoNAl PRoTEcTIoN

National Exposure Standards No exposure standards have been established for this material. As with all chemicals, exposure should be kept to the lowest possible levels.

Biological Limit Values No biological limits allocated.

Engineering Controls Provide sufficient ventilation to keep airborne levels as low as possible. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a flameproof exhaust ventilation system is required. Refer to AS 2004 - The storage and handling of flammable and combustible liquids for further information concerning ventilation requirements.

Respiratory Protection If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable mist/dust filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances.

Eye Protection Safety glasses with side shields, goggles or full-face shield as appropriate recommended. Final choice of appropriate eye/face protection will vary according to individual circumstances i.e. methods of handling or engineering controls and according to risk assessments undertaken. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.

Hand Protection Wear nitrile gloves . Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.

Body Protection Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled.

9. PHySIcAl AND cHEMIcAl PRoPERTIES

Appearance Putty

Odour Mercaptan/sulfur

Melting Point Not available

Boiling Point Not applicable

Solubility in Water Insoluble

Specific Gravity 2.25

pH Value Not available

Vapour Pressure Not available

Vapour Density (Air=1) Not available

Volatile Component Volatile organic compounds (VOC): <0.1%

Flash Point >60°C

Flammability Combustible

Auto-Ignition Temperature Not applicable

Flammable Limits - Lower Not applicable

Flammable Limits - Upper Not applicable

16




10. STABIlITy AND REAcTIvITy

Chemical Stability Stable under normal conditions of storage and handling.

Conditions to Avoid Heat and other sources of ignition.

Incompatible Materials Strong oxidising agent

Hazardous Decomposition Under fire conditions this product may emit toxic and/or irritating fumes and gases including Products carbon monoxide, carbon dioxide, oxides of nitrogen and sulfur.

Hazardous Polymerization Will not occur.

11. ToXIcoloGIcAl INfoRMATIoN

Toxicology Information No toxicity data available for this product.

Inhalation Inhalation of product vapours may cause irritation of the nose, throat and respiratory system.

Ingestion Ingestion of this product may irritate the gastric tract causing nausea and vomiting.

Skin May be irritating to skin. The symptoms may include redness, itching and swelling.

Eye May be irritating to eyes. The symptoms may include redness, itching and tearing.

Chronic Effects Not available

12. EcoloGIcAl INfoRMATIoN

Ecological Information No ecological data are available for this material.

Ecotoxicity Not available

Persistence / Degradability Not available

Mobility Not available

Environ. Protection Do not discharge this material into waterways, drains and sewers.

13. DISPoSAl coNSIDERATIoNS

Disposal Considerations The disposal of the spilled or waste material must be done in accordance with applicable local and national regulations.

14. TRANSPORT INFORMATION

Transport Information Not classified as a Dangerous Good, according to the Australian Code for the Transport of Dangerous Goods by Road and Rail (7th Edition).

15. REGulAToRy INfoRMATIoN

Regulatory Information Not classified as Hazardous Not classified as Hazardous according to criteria of National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).

Poisons Schedule Not Scheduled

AICS (Australia) All components of this product are listed on the Australian Inventory of Chemical Substances (AICS).

16. oTHER INfoRMATIoN

Date of preparation or SDS Amendment: July 2014last revision of MSDS 1. Identification of the Material and Supplier

MSDS Reviewd: August 2011 Supersedes: June 2011

Contact David Huybers

Person/Point Tel: (07) 3262 3755

...END of MSDS...

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