final project work

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HANDLING FUGITIVE EMISSIONS IN THE JUBILEE FIELD OFFSHORE GHANA: SELECTING THE RIGHT SEALS AND OTHER ALTERNATIVES. A Project Report presented to the DEPARTMENT OF PETROLEUM ENGINEERING Faculty of Chemical and Materials Engineering College of Engineering KWAME NKRUMAH UNIVERSITY OF SCIENCE AND TECHNOLOGY by HERMINIA NCHAMA ELA (MISS) AND BRUKUM DANIEL in Partial Fulfillment of the Requirements for the Degree of Bachelor of Science (HONS) Petroleum Engineering. UNDER THE SUPERVISION OF MR. ABDUL HAMEED MUSTAPHA

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Page 1: Final Project work

HANDLING FUGITIVE EMISSIONS IN THE JUBILEE FIELD OFFSHORE GHANA: SELECTING THE RIGHT SEALS AND OTHER ALTERNATIVES.

A Project Report presented to the

DEPARTMENT OF PETROLEUM ENGINEERING

Faculty of Chemical and Materials Engineering

College of Engineering

KWAME NKRUMAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

by

HERMINIA NCHAMA ELA (MISS)

AND

BRUKUM DANIEL

in Partial Fulfillment of the Requirements

for the Degree of

Bachelor of Science (HONS)

Petroleum Engineering.

UNDER THE SUPERVISION OF MR. ABDUL HAMEED MUSTAPHA

KUMASI, GHANA.

©April, 2015.

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DECLARATION

We hereby declare that the project work entitled “HANDLING FUGITIVE EMISSIONS IN

THE JUBILEE FIELD OFFSHORE GHANA: SELECTING THE RIGHT SEALS AND

OTHER ALTERNATIVES” submitted to the Department of Petroleum Engineering – Kwame

Nkrumah University of Science and Technology, is a record of an original work done by us

under the supervision of Mr. Abdul Hameed Mustapha, a lecturer of the Petroleum Engineering

program, College of Engineering, and this project work is submitted in partial fulfillment of the

requirements for the award of Bachelor of Science Degree in Petroleum Engineering. The results

embodied in this project report have not been submitted to any other University or Institute for

the award of any degree or diploma.

Date: ……………………….

HERMINIA NCHAMA ELA (MISS) ……………………………..

BRUKUM DANIEL ……………………………..

It is certified that this project has been prepared and submitted under my supervision.

MR. ABDUL HAMEED MUSTAPHA

…….…………………………………….

Date..........................................................

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ACKNOWLEDGMENT

We give thanks to God Almighty for graciously guiding us through our studies and for a

successful completion of this project.

The success and final outcome of this project couldn’t have been possible without the assistance

of our supervisor, Mr. Abdul Hameed Mustapha who gave us the inspiration to pursue the

project. We are sincerely grateful for the initiative and the zeal he filled us with.

Our heartfelt gratitude also goes out to our parents, family and friends for their understanding,

encouraging and supporting us to pursue our vision of becoming petroleum engineers.

We are very grateful, God bless you all.

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ABSTRACT

Fugitive Emissions (FE) from oil and gas operations are a source of direct and indirect

greenhouse gas emissions (GHG) which can lead to climate change. Fugitive emissions can

cause significant damage to the environment or harm the health of plant workers and the general

public. Also these emissions can cause regional or local concern for the air quality

decolorisation and global warming potential.

Unfortunately, these emissions are difficult to quantify with a high degree of accuracy, despite

the considerable effort made to detect, measure accurately and monitor such emissions. Also not

all the fugitive emissions are covered to the same extent i.e. flaring and venting vs. equipment

leaks. Regulations are based on an economic model rather than on a need to address

environmental impact issues. Again, according to Good Practice Guidance and Uncertainty

Management in National Greenhouse Gas Inventories “the oil and gas industry is very diverse

and complex making it difficult to ensure complete and accurate results”( of fugitive emissions).

In finding ways to mitigate the effects of these spurious emissions, there is the need to employ

the best measures in ensuring that the integrity of the sealing system associated with equipment

leaks and other sources are addressed. Other alternatives for handling fugitive emissions will be

underscored in this project. The quality of air will be improved upon as the quantities of air

pollutants are released into the atmosphere are reduced to the barest minimum. The Jubilee Field

offshore Ghana will be used as a case study.

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LIST OF ACRONYMS

API - American Petroleum Institute

AAQM - Air Ambient Quality Monitoring

AMR - Annual Monitoring Report

AMSE - American Mechanical Society of Engineers

ANSI - American National Standards Institute

BOPD - Barrels of Oil Per Day

BTEX - Benzene, Toluene, and Ethyl-xylene

CAPCOA - California Air Pollution Control Officers Association

DI&M - Direct Inspection and Maintenance

DIAL - Direct Absorption of Light

DWT - Deep Water Tano

EAs - Environmental Aspects

EI - Environmental Impact

EMP - Environmental Management Practices

FE - Fugitive Emissions

FPSO - Floating Production Storage Offloading

GHG - Green House Gases

GNPC - Ghana National Petroleum Corporation

GTG - Gas Turbine Generator

IFC - International Financial Corporation

IPCC - Intergovernmental Panel on Climate Change

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ISO - International Standards Organization

LDAR - Leak Detection and Repair

LPG - Liquefied Petroleum Gas

OGI - Optical Gas Imaging

PBP - Pay Back Period

PM - Particulate Matter

SCF - Standard Cubic Feet

SGS - Société Générale de Surveillance

TAMPSS – Temperature, Application, Medium, Pressure, Size and Speed

TGL - Tullow Ghana Limited

TOC - Total Organic Compound

U.S. EPA - United State Environmental Protection Agency

UNEP - United Nation Environmental Policy

VOC - Volatile Organic Compound

WAFCO - West African Fuel Company

WCTP - West Cape Three Points

WMO - World Meteorological Organization

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LIST OF FIGURES

Figure 1. Breakdown of oil and gas process (fugitive and vented) emissions by sector.

Figure 2. Location of the Jubilee Field

Figure 3. Graphical representation showing breakdown of GHG emissions from production operations at the Jubilee Field in 2012

Figure 4. Percentage of flared volumes to produced volumes at the Jubilee Field

Figure 5. Seal Selection can be based on the Fluid’s Specific Gravity and the Maximum Allowable VOC Emission Levels

Figure 6. DI & M Decision Tree

Figure 7. Pipeline Integrity Systems

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TABLE OF CONTENTS

DECLARATION.......................................................................................................................................... I

ACKNOWLEDGMENT............................................................................................................................. II

ABSTRACT............................................................................................................................................... III

LIST OF ACRONYMS.............................................................................................................................. IV

LIST OF FIGURES....................................................................................................................................VI

TABLE OF CONTENTS.................................................................................................................................VII

1 CHAPTER ONE..................................................................................................................................1

1.1 INTRODUCTION.......................................................................................................................1

1.2 AIMS AND OBJECTIVES.........................................................................................................2

1.2.1 Main Objective....................................................................................................................2

1.2.2 Specific Objectives..............................................................................................................2

1.3 PROBLEM STATEMENT..........................................................................................................3

1.3.1 Fugitive Emissions...............................................................................................................3

1.3.2 Seals.....................................................................................................................................3

1.4 CONCEPTS AND THEORIES...................................................................................................4

1.4.1 Potential breakdown of emissions from Crude oil and natural gas resources.......................4

1.4.2 Toxic and Non-toxic Fugitive emission gases......................................................................5

2 CHAPTER TWO.................................................................................................................................6

2.1 LITERATURE REVIEW....................................................................................................................6

2.1.1 Global concern for Fugitive emission..................................................................................6

2.1.2 GHANA.................................................................................................................................6

2.2 HISTORY OF CRUDE OIL DISCOVERY IN GHANA............................................................7

2.2.1 The Jubilee Field..................................................................................................................8

2.2.2 Air quality...........................................................................................................................10

2.2.3 History of flaring and venting at the jubilee field...............................................................12

2.2.4 Oil Spills at the Jubilee Field...............................................................................................14

2.3 OVERVIEW OF SOURCES.....................................................................................................14

2.3.1 Fugitive equipment leaks...................................................................................................15

2.3.2 Flaring and Venting...........................................................................................................16

2.3.3 Evaporation losses at production facilities.........................................................................17

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2.4 DETECTION OF FUGITIVE EMISSIONS..............................................................................17

2.4.1 Soap Solutions...................................................................................................................18

2.4.2 Odorants.............................................................................................................................18

2.4.3 Portable Analyzers.............................................................................................................18

2.4.4 Static Leak Indicators........................................................................................................18

2.4.5 Electronic Screening Devices............................................................................................19

2.5 EMISSION FLOW MEASUREMENT..............................................................................................20

2.6 ENVIRONMENTAL IMPACT OF FUGITIVE EMISSIONS..................................................20

3 CHAPTER THREE...........................................................................................................................22

3.1 METHODOLOGY....................................................................................................................22

3.1.1 METHODOLOGIES AND PROCEDURES THAT THE INDUSTRY RELIES ON IN PREPARING EMISSION INVENTORIES FOR FUGITIVE EMISSIONS.....................................22

3.1.2 THE USA EPA AND API ASSESSMENT.......................................................................23

3.1.3 THE INTERGOVERNMENTAL PANEL ON CLIMATE CHANGE (IPCC) ASSESSMENT..................................................................................................................................25

3.2 KEY CHALLENGES DURING THE ASSESSMENT OF FUGITIVE EMISSIONS..............26

3.3 SEALS.......................................................................................................................................28

3.3.1 PROCESS EQUIPMENT LEAKS.....................................................................................28

3.3.2 OTHER POTENTIAL FUGITIVE EMISSION SOURCES.............................................................33

3.3.3 SELECTION FACTORS OR PARAMETERS FOR SEALS IN THE OIL AND GAS INDUSTRY..........34

3.3.4 SELECTION OF THE RIGHT SEAL..........................................................................................36

3.3.5 Causes of Premature failure of Process equipment...........................................................38

3.3.6 OTHER TECHNOLOGICALLY IMPROVED ALTERNATIVES FOR DETECTING AND MEASURING FE 41

4 CHAPTER FOUR.............................................................................................................................43

4.1 REDUCING EQUIPMENT LEAK EMISSIONS......................................................................43

4.1.1 DIRECT INSPECTION &MAINTENANCE (DI&M) PROGRAM.................................43

4.1.2 LEAK DETECTION AND REPAIR PROGRAM (LDAR)..............................................45

4.1.3 THE CONCEPT OF LEAK...............................................................................................45

4.1.4 PIPE LINE INTEGRITY..........................................................................................................46

4.1.5 LEAK REPAIRS AND ECONOMIC ANALYSIS...........................................................47

5 CHAPTER FIVE...............................................................................................................................49

5.1 CONCLUSION AND RECOMMENDATION.........................................................................49

5.1.1 Conclusion.........................................................................................................................49

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5.1.2 Recommendation and further work....................................................................................50

REFERENCES..........................................................................................................................................51

APPENDIX...............................................................................................................................................52

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1 CHAPTER ONE

1.1 INTRODUCTION

Knowledge and best practices in the oil and gas industry are constantly changing. New research

and experience tend to widen our understanding, brings changes in research methodologies and

improves upon professional practices. All these processes are jeered towards developing the best

technologies for exploiting the ‘black gold’, solving and containing any problems that may be

associated with their aftereffects. In evaluating such information and methodologies, players in

the industry should be mindful of their own safety, thus, the safety of their workers, that of the

equipment being worked with and most importantly the safety of the environment in which they

are working.

According to ISO 14001, Environmental Aspects (EAs) are ‘‘elements of an organization’s

activities, products or services that can interact with the environment’’, for example, waste

management, worker protection, compliance, public safety, property damage, global warming,

process emission, toxic material management, etc. Also, the charter goes on to define

Environment Impact (EI) as ‘‘any change of the environment, whether adverse or beneficial,

wholly or partially resulting from an organization’s activities, products or services.’’ One thing

that should be worth noting is that significant EAs are the most important ones that cause the

highest EIs. The petroleum industry is among the highest generators of pollution. Whilst the

industry has made major strides to reduce hazardous waste generation and emissions, it continues

to be a culprit of generating significant levels of toxic air emissions and poorly manage its other

EAs practices.

Fugitive emissions, which is a major component of process emissions, are sources of gases and

vapour from pressurised equipment due to leaks and other unintended or irregular release of

gases, mostly from industrial activities. Oil and gas operations are direct and indirect sources of

greenhouse gas emissions of which fugitive emissions play a chief part in. It has been observed

that quantification of these emissions to a high degree of accuracy remains substantially

uncertain in the values available for some of the major oil and gas producing countries. This is

partly due to the types of sources being considered. Furthermore, the oil and gas industry is very

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large, diverse and complex making it difficult to ensure complete and accurate results. (D. Picard

et al, 2006). Leaks from pressurized process equipment generally occur through valves, pipe

connections, mechanical seals, or related equipment. Fugitive emissions also occur at

evaporative sources such as waste water treatment ponds and storage tanks. Because of the huge

number of potential leak sources at large industrial facilities and the difficulties in detecting and

repairing some leaks, fugitive emissions can be a significant proportion of total emissions.

Though the quantities of leaked gases may be small, gases that have serious health or

environmental impacts can cause significant environmental problems such as climate change,

global warming potential and regional or global concern for air quality decolorisation. Fugitive

emissions are deemed to be an important part of the debate on climate change, because they

represent a significant portion of greenhouse gas emissions contributed by the oil and gas

industry.

Technological innovations in the past decade have enhanced the opportunity for companies to

reduce fugitive emissions from their operations and facilities, but uncertainty remains around the

scope of the problem and how to address it. The first step in controlling fugitive equipment leaks

is to minimize potential for leaks by applying proper design and material-selection standards, to

follow the manufacturer’s specifications for the installation, use and maintenance of components

and to implement practicable control technologies. The greatest challenge now experienced by

stakeholders in the oil and gas industry is how to detect, measure, monitor, control and reduce

the amounts of fugitive emissions released into the environment.

1.2 AIMS AND OBJECTIVES

1.2.1 Main Objective

This project is aimed at analysing how fugitive emissions are handled at the Jubilee Field

Offshore Ghana, the selection of the right seals to control these emissions and providing other

alternatives to reduce any further spurious emissions of process fluids.

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1.2.2 Specific Objectives

To know the potential breakdown of hydrocarbon related fugitive emissions in the world

To know how and why fugitive emissions occur

Detecting and monitoring fugitive emissions

To determine the current inventory methodologies for quantifying fugitive emissions

Selection of right seals for trapping spurious emission

Selection of other alternatives for controlling and minimizing fugitive emission

Retrofitting detected leakages

1.3 PROBLEM STATEMENT

1.3.1 Fugitive Emissions

The majority of air emissions from the oil and gas industry are from fugitive emissions which are

emissions from equipment leaks, process venting, evaporation losses, disposal of waste gas

(venting or flaring), accidents and equipment failures. The main activities in the industry related

to such spurious emissions are as follows:

Oil and gas production

Crude oil transportation and refining

Natural gas processing, transportation and distribution

Storage and tanker loading

Pressure relief and blow outs

Some problems associated with the effects of fugitive emissions are:

Greenhouse effect which leads to a phenomenon called global warming resulting in

climate change

Health hazards caused by air pollution

Economic cost of loss of commodities on the part of the Operating company

Risk of fire and accidents such as explosions

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1.3.2 Seals

Minimizing emissions to the atmosphere from machinery has been long effected by seals. In

trying to meet stricter environmental regulations for the release of Volatile Organic Compounds

(VOCs), a range of advanced technologies have been developed and made available in seal

design and materials. But the best of seals can fail, especially when neglected thus when not

monitored and repaired in time. The type of seal selected depends on the pumped medium,

operating temperature, pressure and speed of operation. These factors when not checked to

specification of operation can mal the functioning of seals.

1.4 CONCEPTS AND THEORIES

1.4.1 Potential breakdown of emissions from Crude oil and natural gas resources

Worldwide concern for the implications of the increase in global warming, greenhouse effects,

climate change and general air quality has necessitated the identification of some sources of

emitted gases arising from industrial activities. Potential emissions in the industry are from these

gaseous components:

1. Methane (CH4) emissions, from natural gas production, processing, transmission and

distribution, oil production, forms the majority of petroleum fugitive and vented

emissions. CH4 emissions can be intentional (process venting) or unintentional (fugitive

leaks, system malfunctions).

2. Carbon dioxide (CO2) emissions by the oil and gas industry are primarily combustion

related for compressor and equipment operation. Fugitive and vented CO2 is a relatively

small source (e.g., acid gas removal during processing).

3. Carbon monoxide (CO) is generated as a result of incomplete combustion. It is a toxic

gas, reducing oxygen in the atmosphere.

4. Volatile Organic Compounds (VOCs) are organic compounds that are capable of the

formation of photochemical oxidants (ozone) by reactions with nitrogen oxides in the

presence of sunlight. Certain VOCs, in addition to having a global warming potential, are

harmful to health and are stratospheric ozone depletion substances, for example benzene.

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5. Nitrogen Oxides (NOx) is a general name for nitric oxide (NO) and nitrogen dioxide

(NO2). These emissions occur almost exclusively from the combustion of fossil fuels for

industry, transport and from the burning of biomass.

6. Sulphur dioxide (SO2) is an acidic gas produced during the combustion of fuels which

contain sulphur compounds.

7. Hydrogen Sulphide (H2S) is a toxic gas with an extremely low odour threshold at low

concentration occurring during decomposition. The odour threshold increases with

increasing concentration. Natural gas is normally treated to remove this H2S to form

sulphur or it can be burned. H2S forms SO2 during the combustion process or

photochemically when released to the atmosphere.

1.4.2 Toxic and Non-toxic Fugitive emission gases

The gases included in the fugitive emissions category can be divided into two broad groups:

1. Toxic: Hydrogen Sulphide, sulphur dioxide, Volatile Organic Compounds (VOCs), and

Benzene, Toluene, and Ethyl-xylene (BTEX)

2. Non-toxic: methane, carbon dioxide, and ethane.

The toxic and non-toxic distinction is important, because the odour of toxic gases makes them

easier to identify and monitor than non-toxic gases. Moreover, there is a more compelling

motivation for companies and governments to deal with toxic gases when an immediate public

safety or health concern surfaces. The public is more likely to react to the risk, because it is

noticed as an imminent threat. This is less the case with invisible, odourless gases like methane

which, while less to non-toxic, are less noticed, and thus can be more easily ignored, though their

environmental impacts can be quite significant.

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Figure 1-1. Breakdown of oil and gas process (fugitive and vented) emissions by sector (Gas Star Production Technology Transfer Workshop May 11, 2010.

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2 CHAPTER TWO

2.1 LITERATURE REVIEW

2.1.1 Global concern for Fugitive emissionAs the world grows and economies develop, future demand for energy will continue to grow

dramatically. The International Energy Agency and others predict that the world’s total energy

demand will grow by 35% in 2030 higher than it is today, and the oil and natural gas sector is

expected to account for 60% of total energy through 2030 (Glass J.S. Jr., 2009). This implies that

fugitive emissions must be minimized in order to preserve scarce resources and address the

global climate challenge. Because of the predicted growth in emissions in the coming decades,

70-80% will come in developing countries. (T. Arrowsmith, 2009).

The amount of methane emissions released by the natural gas (NG) industry is a critical and

uncertain value for various industry and policy decisions, such as for determining the climate

implications of using NG over coal. Previous studies have estimated fugitive emissions rates

(FER) the fraction of produced NG (mainly methane and ethane) escaped to the atmosphere

between 1 and 9%. Most of these studies rely on few and outdated measurement and some may

represent only temporal/regional NG industry snapshots. The IPCC has established with a high

degree of certainty that greenhouse gas emissions have risen steadily since pre-industrial times

by 70% between 1970 and 2004 (IPCC, 2007).

2.1.2 GHANAFrom the 2000-inventory year, Ghana’s current total national emission was 12.2 MtCO2e for five

direct greenhouse gases namely CO2, CH4, N2O, CF4, and C2F6. It increased to 23.9MtCO2e in

2006 which is of 0.05% of global emissions. This emission levels indicated a 243% increase

from the 1990 levels. The energy sector is the major GHG emissions source followed by land use

change and forestry and agriculture (National Greenhouse Gas Inventory 2006).

From the GHG inventory done in 2006, Ghana’s emissions were low compared to other

countries, but there was a potential for the emissions to grow and peak across sectors considering

emerging economic prospects for Ghana under for example the oil and gas industry. Carbon

dioxide was the major greenhouse emissions in Ghana however; methane was predicted to

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contribute significantly to the national greenhouse emissions in the coming years as a result of

increased activities in the oil and gas industry. The energy sector was the largest source of

greenhouse emissions as at 2006 and it was predicted to dominate over time. Fugitive emissions

from the oil and gas production were expected to reflect as a major source of methane emissions

as commercial oil and gas exploitation comes on stream by the end of 2010.

2.2 HISTORY OF CRUDE OIL DISCOVERY IN GHANA

Ghana is a small country with population of about 24 million in the Western part of Africa along

the coast of Gulf of Guinea which has been prospecting for oil since 1890 (Samuel, 2008).

Historical records of petroleum exploration in Ghana dates beyond 100 years ago. West Africa

and Fuel Company (WAFCO) in 1896 initiated petroleum exploration in the then Gold Coast of

Africa (today Ghana). Even though it is difficult to agree on the pioneer role of WAFCO, per the

available data, their contribution is traced to the five drilled wells in onshore Tano fields in the

Western part of Ghana between 1896 and 1903 (Osei, B. D. 2011).

Hydrocarbon deposits are found in four main regions of sedimentary basins; three offshore

basins namely Tano-Cape Three Points Basin (Western Region), Saltpond/Central Basin (Central

Region) and Accra-Keta Basin (Eastern Region), and an onshore basin called Voltaian Basin

(Northern Region). After several decades of oil exploration, Ghana finally struck oil in

commercial quantities in her offshore West Atlantic Coast in 2007 in conjunction with some

multinational oil and gas companies. Kosmos Energy, a US-based oil and gas company,

discovered crude oil in commercial quantities in the West Cape Three Points Basin. Immediately

afterwards, Tullow Oil (United Kingdom) intensified its exploratory works and struck oil in the

neighboring Deep Water Tano Basin. From data and other studies it was concluded that both

discoveries were likely from a single continuous trap. The find was named the Jubilee Field

because the year in which ‘the black gold’ was struck in commercial quantities happened to be

the same year the country celebrated her fiftieth year independence from Britain.

Before this, in 1980, a minor oil discovery and subsequent production by Saltpond Oil Company

led to the production of oil in small quantities but fell short of domestic demand. The Saltpond

field was discovered in 1970 following the drilling of the Signal Amoco Well approximately 100

km west of Accra.

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2.2.1 The Jubilee Field

The Jubilee Field straddles the West Cape Three Points (WCTP) and the Deep Water Tano

(DWT) basins. The field is at deep water depth of 1100 m at an approximate distance of 16 km

from onshore Ghana and recoverable reserves are estimated to be more than 370 million barrels

with an upside potential of 1.8 billion barrels. The WCTP license is operated by Kosmos Energy

(30.88%). Partners on this license include Tullow Oil (22.9%), Anadarko Petroleum (30.785%),

Sabre Oil & Gas (1.85%), Ghana National Petroleum Corporation (10%) and EO Group (3.5%).

On the other hand, Tullow (49.95%) operates the DWT block. Other partners include Kosmos

Energy (18%), Anadarko Petroleum (18%), Sabre Oil and Gas (4.05%) and Ghana National

Petroleum Corporation (10%).

The discovered crude oil and gas resources in the two blocks were found to be in pressure

communication and as such concluded to be in the same reservoir. Per the Petroleum Law,

petroleum resources discovered under such circumstances are required to be produced as a unit

to reduce cost and maximize the recovery of oil and gas from the field, hence the unit Jubilee

Field. Tullow Oil was appointed as the unit operator and Kosmos Energy the technical operator

for the Jubilee Field development under a unitization agreement.

Jubilee was to be developed using a field proven subsea production and control system tied back

to a turret moored FPSO (Floating, Production, Storage and Offloading) vessel. MODEC was

awarded the engineering, procurement and construction contract to provide an FPSO. The tanker

vessel Ohdoh (owned and operated by Mitsui Ocean Development and Engineering, Japan) was

converted to FPSO Kwame Nkrumah MV21 for the Jubilee Field. During the conversion

process, a water treatment plant, a turret, a 120-room accommodation module, a crude oil

separation plant, gas processing unit and a power generation plant were installed. MODEC is

responsible for all operational and maintenance works of the FPSO.

The FPSO was installed in November 2010, at a water depth of 1,100m to subsea production

facilities. It is designed to operate for 20 years. The facility processes 120,000 BOPD and 120

MMSCF per day of gas, and has a storage capacity of 1.6 million barrels of oil. It injects more

than 230,000 barrels of water a day.

The Jubilee field contains substantial amounts of gas deposits and the country is expected to

have a higher stake in the gas from subsequent production. The government of Ghana has a

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policy of zero flaring but since production of oil from Jubilee from the last quarter of 2010, this

has not been realized. On the FPSO vessel, oil and gas are separated and the worthful oil is

shipped. Part of the gas is used to power some engines on the FPSO and part used for reinjection

into three gas injection wells for enhanced oil recovery. The rest must be transported, stored or

disposed off (through venting or flaring). Out of the 120 units of associated gas produced, about

20 are used to power the FPSO, 30 for well injection and the remaining 70 flared or vented.

Ghana National Gas Company (Ghana Gas) was established in July, 2011 through a government

initiative. The company’s task is to build, own and operate natural gas infrastructure to process,

transport and market the gas to satisfy high domestic and industrial demand. This aims to ensure

that gas associated with the country’s oil is harnessed to the fullest. (Ministry of Energy, Ghana,

2012). Currently, infrastructure has been put in place (construction begun in 2011) to transport

gas from the FPSO, which consists of a pipeline to the shore, a processing plant at Atuabo and a

power plant at Aboadze. The gas processing plant has not begun full operation but it has been

test run. It is hoped that by 2016, the gas processing plant will begin full operation so that the

direct release of excess natural gas into the atmosphere and its associated controlled burning will

be curtailed to enforce the ‘no flaring policy’ in the country.

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Figure 2-2. Location of Jubilee Field (Jubilee Field EIA, Project Information Posters)

2.2.2 Air qualityEMP Air Quality monitoring requirements at the Jubilee Field are based on two main factors;

1. Emission testing, which includes monitoring point source emissions from combustion

devices on board, point emissions sources from onshore activities, fugitive emissions and

flaring

2. Ambient air quality monitoring at FPSO and shore base.

Emission Testing

D’Appolonia S.p.A, an external independent monitoring group, according to its Tullow Ghana

Jubilee Project Report in 2013, came out with the conclusion that the Jubilee Field Project is

consistently reporting the Green House Gases (GHG) emissions data within the AMR and

statutory report. The GHG quantification is based on the use of empirical formulas starting from

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the fuel type and quantities used at each combustion source. The following data shows the GHG

emissions according to various activities under the operations of TGL;

Figure 3-3 Graphical representation showing breakdown of GHG emissions from production operations at the Jubilee Field in 2012

Adding up to this study in November 2012, a stack and fugitive emission crusade was also done

to evaluate the emission levels from the Gas Turbine Generator (GTG), Emergency Boilers and

Port Side Crane. From these sources, the measurement of O2, CO, NO, NO2, CO2, CH4 and VOC

fugitive samples were the visible emissions that were documented.

Results from the study indicated that, reference limits of the Project were not exceeded with the

exception of NOX measured at GTG C (117 mg/dsm3) and at GTG B (123.5mg/dsm3). The GTG

has a reference limit of 51 mg/dsm3 (IFC applicable guidelines). For a similar campaign carried

out in the year 2013, exceeded amounts were reported at GTG A (71 mg/Nm3) and at GTG C

(89mg/Nm3). (Tullow Ghana Jubilee Project report 2013, 2014).

Flaring

Flaring activities on the FPSO is restricted to situations whereby there are incidences of process

upsets and in case of maintenance of equipment or tanks. Although no specific flaring limit is

being enforced by GH EPA and IFC, a maximum flaring volume of 2.5% of the total gas

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produced has been independently assumed by the Project. Thus, the volumes of fluid stream to

be flared must not exceed 2.5% of the total gas production for the specific period. It must be

noted that, GH EPA policy guidance is for TGL to avoid routine flaring. Non-routine flaring is

allowable on safe grounds but it has to be limited to minimal amounts possible.

Ambient Air Quality Monitoring (AAQM)

AAQM is aimed at evaluating the degrees of NOX, NO2, SO2 and VOC as postulated by the EMP

for the FPSO and its surroundings. According to a comprehensive report written by SGS for

TGL after a sampling campaign carried out in April 2012, the following decisions were made;

1. All locations onshore and offshore had acceptable ambient air quality levels in respect of

the parameters tested, except at the commercial port area, where lime was being

discharged during the sampling campaign and therefore could have accounted for the

high levels of particulate matter.

2. The TSP and PM10 level recorded at the commercial port area was the highest and

exceeded the EPA recommended limit set at 230 and 70 µg/m3 respectively. All other

locations recorded concentration lower than the EPA limits

3. The concentration of both SO2 and NO2 recorded at all locations offshore and onshore

were lower than the EPA guideline limit

4. Concentrations of CO at all offshore and onshore locations were lower than the EPA

guideline limit

5. Volatile Organic compounds concentrations measured at the offshore and onshore

locations were below the recommended WHO limit

6. The SGS study also provided recommendations on the possible adoption by TGL of a

continuous monitoring system to ensure more representative data are collected.

2.2.3 History of flaring and venting at the jubilee field

Flaring is a safety measure used in petroleum industries to ensure that gases are safely disposed

off. Since first oil production at the Jubilee Field late 2010, there has been flaring but only for

safety and testing reasons and within clear limits set by Ghana EPA. The agreements between

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Ghana and the operators of the Jubilee Field emphasize on the policy of zero gas flaring.

However, according to GNPC and Tullow Ghana Ltd, there are not existing infrastructures to

convert the natural gas into LPG to meet part of the country’s energy demands. On the other

hand, re-injection of the produced gas back into the oil wells is not encouraged because it can

damage the reservoir and a subsequence reduction of production. Also the Jubilee Field’s

reservoir had reached unsafe levels for gas to still be re-injected into it. The only option available

in this situation is the flaring of gas. Tullow Ghana received a permission to flare 500 Millions of

standard cubic feet of gas per month in May 2014 to save its infrastructure from collapsing.

Routine gas flaring started in February 2015 however there are concerns this could be dangerous

for the environment.

FPSO tanks are maintained in a pressurized state and the vapour space created in the storage

tanks of the FPSO is filled with an inert gas to avoid the potential for fire or explosion, excess

inert gas is vented during cargo tank filling operations. Air pollutant emissions from the drilling

rigs and the FPSO are expected to be rapidly diluted and dispersed in the offshore atmosphere.

There may be some decrease in air quality within several hundred meters around these emission

sites.

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0

10

20

30

40

50

60

Figure 4 Percentage of flared volumes to total produced gas volumes at the Jubilee Field

2011 2012 2013 2014

2.2.4 Oil Spills at the Jubilee Field

Oil tankers, underwater pipelines, offshore oil drilling rigs and coastal storage facilities can

unintentionally release crude oil into the sea, and a significant portion of the environment, both

offshore and onshore. Over the years, oil and gas industry has witnessed oil spills that have cause

considerable damage to the environment. The offshore Jubilee field Ghana has for some time

now experienced some environmental challenges as a result of oil spills during operations. The

first oil spill was encountered in December 2009 when Kosmos Energy spilled 600 barrels of

low toxicity oil-based mud during the exploration in the jubilee field in Western Region of

Ghana. (EPA, 2010). Tullow Oil also spilled some 37 liters of oil on January 1, 2010 due to the

breakage of their link pipes. In March 2010, some quantity of oil was again spilled into the sea

by Kosmos. Again two oil recordable spills event occur respectively on 06/02/2012 (63.4

barrels) and 08/07/201 2 (20 barrels). Both oil spills were reported by TGL.(Anon, 2010).

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2.3 OVERVIEW OF SOURCES

The sources of fugitive emissions in the oil and gas systems include, but are not limited to,

equipment leaks, evaporation and flashing losses, venting, flaring, incineration and accidental

releases (e.g., pipeline dig-ins, well blow-outs and spills). While some of these emission sources

are engineered or intentional (e.g., tank, seal and process vents and flare systems), and therefore

relatively well characterized, the quantity and composition of the emissions is generally subject

to significant uncertainty. This is due, in part, to the limited use of measurement systems in these

cases, and where measurement systems are used, the typical inability of these to cover the wide

range of flows and variations in composition that may occur.

Even where some of these losses or flows are tracked as part of routine production accounting

procedures, there are often inconsistencies in the activities which get accounted for and whether

the amounts are based on engineering estimates or measurements.

In general, fugitive emissions from oil and gas operations offshore are attributed to the following

primary type of sources:

1. Fugitive equipment leaks

2. Process venting

3. Evaporation losses

4. Disposal of waste gas streams (venting and flaring)

5. Accidents and equipment failures (well blowouts, tank explosions, pipeline breaks)

There are also additional sources which may be encountered at oil and gas facilities, but these

sources do not contribute to the major GHG emissions in the oil and gas industry. These may

include: land disposal of solid waste and methane emissions from wastewater handling.

2.3.1 Fugitive equipment leaks

Fugitive equipment leak is defined as the uncontrolled loss of fluid through the sealing

mechanisms separating the process fluid from the atmosphere. Leakage from equipment may be

due to the characteristics of the equipment itself or may result from faulty equipment or

inadequately maintenance of the equipment. Process equipment components that are sources of

fugitive emissions through leaks include:

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Pumps

Compressors

Valves

Pressure relief valves

Pipe connections

2.3.1.1 Pumps

Pumps are used extensively by industries to move organic liquids. The most widely is the

centrifugal pump. Most pumps have a moving shaft which is exposed to the atmosphere. The

fluid being moved inside a pump must be isolated from the atmosphere. This requires a seal.

Leaks can occur at the point of contact between the moving shaft and stationary casing.

2.3.1.2 Compressors

Compressors are basically pumps that are used in gas service. Gas compressors used in process

unit can be driven by rotary or reciprocating shaft. Rotary shafts may use either packed or

mechanical seals, while reciprocating shaft must use packed seals. As with the seals in pumps,

the seals in compressors are likely to be sources of fugitive emissions from compressors.

2.3.1.3 Pressure relief valves

These are devices designed to open when the process pressure exceeds a set pressure. This

allows the release of vapors or liquids until the system pressure is reduced to its normal operating

level. When the normal pressure is retained, the valve resets, and a seal is again formed. There

are two potential causes of leakage from relief valves. One is when the system pressure is being

close to the set pressure of the valve. This occurs when the operating pressure exceeds the set

pressure for a short period. The other cause of leakage is improper valve reseating after a

relieving operation.

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2.3.1.4 Pipe connections

2.3.1.4.1 Agitators

They are commonly used to stir or bend chemicals. Like pumps and compressors, agitator may

leak organic chemicals at the point where the shaft penetrates the casing. Consequently, seals are

required to minimize fugitive emissions from agitators.

2.3.1.4.2Flanges

Flanges are bolted, gasket-sealed junctions between sections of pipe and pieces of equipment.

They are used wherever pipe or equipment components (pumps, valves, vessels) require isolation

or removal. The possibility of a leak through the gasket seal makes them a potential source of

FE.

Normally pumps/ compressors account for 10%, flanges-5%, tanks-10%, relief valves-15% and

valves-60% of the total fugitive emissions in a processing facility (Fluid Sealing Association,

2008). Valves which represents 60% of fugitive emissions presents the greatest opportunity for

reducing fugitive emissions.

2.3.2 Flaring and Venting

Venting is the controlled release of gases into the atmosphere in the course of oil and gas

production operations. These gases might be natural gas or other hydrocarbon vapours, water

vapour, and other gases, such as carbon dioxide, separated in the processing of oil or natural gas.

In venting, the natural gases associated with the oil production are released directly to the

atmosphere and not burned. Venting is normally not a visible process. However, it can generate

some noise, depending on the pressure and flow rate of the vented gases. In some cases, venting

is the best option for disposal of the associated gas.

Flaring is the controlled burning of natural gas in the course of routine oil and gas production

operations. A flare is normally visible and generates both noise and heat. During flaring, the

burned gas generates mainly water vapour and carbon dioxide. For environmental and resource

conservation reasons, flaring and venting should always be minimized as much as practicable,

consistent with safety considerations. Flaring and venting can have local environmental impacts,

as well as producing emissions which have the potential to contribute to global warming.

Available data indicate that, on a worldwide basis, gas flaring contributes only 1% of

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anthropogenic carbon dioxide emissions, and flaring and venting contribute only 4% of

anthropogenic methane emissions.

2.3.3 Evaporation losses at production facilities

Production facilities are often equipped with one or more fixed-roof tanks for temporary storage

of the produced hydrocarbon liquids (i.e., oil or condensate). If these tanks are vented to the

atmosphere, they are sources of storage losses (i.e., product is lost to the atmosphere due to

evaporation effects). Such losses are a major source of emissions in the upstream oil and gas

industry accounting for about 24% of all total hydrocarbons losses emissions by the industry.

Moreover, they constitute a loss of potential revenue. In some cases there may be an attractive

economic benefit to controlling these losses.

2.4 DETECTION OF FUGITIVE EMISSIONS

A variety of approaches are used for leak detection. Advances in environmental technologies

over the past decade or so have made it increasingly possible to overcome some of the key

obstacles in identifying, measuring, and monitoring fugitive emissions in the oil and gas

industry. As a result, companies are now better able to construct economic evaluations of the

costs to take action to reduce these emissions, if they so choose.

Below is a brief description of some of the technologies used to identify and measure fugitive

emissions (intentional and unintentional).

2.4.1 Soap Solutions

A soap solution is applied directly on the component and leaks are detected by the appearance of

bubbles. This technique is qualitative only but leak rates can be evaluated by the degree of

bubbling action.

2.4.2 Odorants

Odorants are usually used in gas distribution systems for leak detection in consumer sites. The

odorants are powerful sulphur containing components that are readily detected in small

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concentrations by humans. While it is impractical to inject odorants on a continuous basis it may

be useful to periodically inject some into a gas stream to help provide a gross indication of where

there are leaks occurring.

2.4.3 Portable Analyzers

For many regulations with leak detection provisions, the primary methods for monitoring to

detect leaking components is EPA Reference Method 21. Method 21 is a procedure used to

detect VOC leaks from process equipment using analyzer. A portable analyzer is a monitoring

instrument is used to detect hydrocarbons leaks from individual pieces of equipment. These

instrument are intended to locate and classify leaks based on the leak definition of the equipment

as specified regulation, and are not used as a direct measure of mass emission rate from

individual sources.

The instrument provides a reading of the concentration of the leak in either parts per million,

percent concentration or parts per billion. The analyzer requires responding to the compounds

being processed, being capable of measuring the leak definition concentration specified in the

regulation, being readable to ±2.5% of the specified leak definition concentration and being

equipped with an electrically driven pump to ensure that a sample is provided to the detector at a

constant flow rate.

2.4.4 Static Leak Indicators

This includes a number of technologies used to detect higher risk leak sources as soon as they

occur:

Bag and Streamer: An impermeable expandable bladder, such as a wide rubber band, or

plastic material can be wrapped around the flange and sealed. As a leak develops the

bladder expands and provides a visual display. A small hole in the side of the bag

provides a means for the gas to escape without rupturing the bag. This hole could also

contain a whistle or a streamer to provide an audible or visual signal.

Color Indicating Tape: A chemical agent that reacts in the presence of natural gas, or a

lack of oxygen, and changes color can be added to one side of a transparent tape. This

tape can be wrapped around the flange with the reagent exposed to the vapor space inside

the flange. If a leak occurs, the reagent changes color indicating a leak.

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Chronic Leak Monitoring: Continuous monitoring on individual potential leak sources

may be possible utilizing equipment to detect a leak at a specific source which sends an

electronic signal or triggers an audible alarm for the operator. Various detection

principles may be used such as combustible detectors, ultrasonic/sonic, thermal

conductivity, vibration, or infrared.

2.4.5 Electronic Screening Devices

There are a variety of hand held instruments that can be used to check leaks where a soap

solution fails such as leaks with large holes or gaps.

Gas Monitors: Various handheld gas monitors or “sniffers” are available. A sample of a

gas stream in the area of a suspected leak is drawn into the device and one of a number of

analyzers is used to determine if a hydrocarbon is present. Most detectors will provide a

positive response if a gas other than air is encountered.

Ultrasonic Leak Detectors: Ultrasonic detectors can listen for leaks using acoustic

analysis. The main use for these devices is to check for leakage from relief valves and

other devices that might allow gas to be lost to flare or other relief or closed collection

systems. The devices allow the survey technician to hear the flow through the valve even

though there may be no external indication (ice build-up or vibration).

Laser or Infrared Detectors: New devices have been developed and are coming into

greater use; they allow the plume from the leak to be detected at a distance. These

systems are generally mobile and are better for detecting leaks outdoors and in hard to

reach locations where use of hand-held devices would be difficult or require cranes or

lifts.

2.5 EMISSION FLOW MEASUREMENT

Once a leak has been detected some of them may be easily stopped by simply fastening a fitting

packing or flange. Sometimes it may also be suitable to define the leakage rate, particularly if the

repair and reduction or decrease of the leak needs a process unit shut down or any other action

that would make repairs high-priced. Various methods are available for quantify leak rates.

Hi-Flow Sampler: this method measures the leak with accuracy. The device used

captures the total leak and ambient air around the leak by the used of vacuum. It is

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totally portable with battery power that allows the collection of sample. A hot wire

anemometer is usually used to determine flow rate.

Bagging: An impermeable bag of a given volume is attached to the leaking source. Then

the time it takes to fill the bag is recorded to find the flow rate. The contents of the bag

can then be sub sampled for compositional analysis or by a hand held monitor to

determine combustible gas content.

Rotameters: They are devices that allow for a quick and moderately precise flow

measurement based on a variable area principle. The device is positioned in the vertical

position and the flow to be measured is brought in from the bottom. While the flow

increases, the flow begins to increase and ascent and allows the gas to pass between the

float and inside walls of the tapered tube. The height of the float in the tube can be

correlated to a flow rate and is read off a scale on the side of the pointed tube.

2.6 ENVIRONMENTAL IMPACT OF FUGITIVE EMISSIONS

The oil and gas industry is the major source of greenhouse gas emissions. These emissions

include substances that are limited to global warming and others with local effects such as

acidification of lakes and forest. The oil and gas industry is an important source of volatile

organic compounds (VOC). Volatile organic compounds when combined with nitrogen oxides

they can contribute to the generation of ground-level ozone. Also nitrogen oxides contribute to

acidification and eutrophication.

Flaring and venting can have a local environmental impact in such a way that flaring produces

predominantly carbon dioxide emissions while venting produces mostly methane emissions.

Both carbon dioxide and methane are known as greenhouse gases associated with concerns about

global warming whereas the two gases have different effects on the environment, however the

global warming potential of methane when compare to that of carbon dioxide suggest that flaring

is more environmentally friendly option than venting.

Emissions to the atmosphere from the oil and gas industry are increasingly becoming a very

important subject to both national government and the industry because of the negative effect on

climate. During the production of hydrocarbons at the Jubilee Field, the principal emissions that

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comes along with flared gas contain toxic byproducts such as methane and benzene also generate

carbon dioxide, carbon monoxide, volatile organic compounds, sulphur dioxide, nitrogen

sulphide and nitrogen oxide. As we said earlier some of these gases can contribute to the effect

of global warming while the sulphur gases and carbon dioxide can contribute to the formation of

acid rain which is detrimental to soil fertility and vegetation when they become in contact with

water. Therefore, for example, the Ankasa Forest Reserve and the surrounding vegetation and

farmlands that are located near the border with Cote D’Ivoire, could be damaged due to gas

flaring and venting activities from the Jubilee Field.

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3 CHAPTER THREE

3.1 METHODOLOGY

3.1.1 METHODOLOGIES AND PROCEDURES THAT THE INDUSTRY RELIES ON IN

PREPARING EMISSION INVENTORIES FOR FUGITIVE EMISSIONS

The reason for preparing an accurate emission inventory is not just to satisfy statutory reporting

requirements. The objective of environmental acts, laws and regulations is to protect the general

public at large. Regulators in the industry are concerned with relying on reported emission values

to assess the risks of air pollution and in effect devise ways of reducing these risks. When oil or /

and gas fields, gas processing plants, refineries and industries under-report their emission rates

and values, the health of the public is placed in danger since the actual emissions from the

operations of these sectors are not made known.

Emission inventory refers to the mass rate accounting of priority pollutants from the different

sources within a manufacturing process (Cheremisinoff and Rosenfeld, 2009). In the preparation

of emission inventories for industries, emission factors to volume or mass production rates are

applied. According to USA EPA, “An emission factor is a representative value that relates the

quantity of a pollutant released to the atmosphere with an activity associated with the release of

that pollutant. These factors are usually expressed as the weight of pollutants divided by a unit

weight, volume, distance or duration of the activity emitting the pollutant (e.g. kilograms of

particulate emitted per megagram of coal burned). Such factors facilitate estimation of emissions

from various sources of air pollution. In most cases, these factors are simply averages of all

available data of acceptable quality, and are generally assumed to be representative of long-term

averages for all facilities in the source category (i.e. a population average).”

The following general data are required for fugitive emission estimation calculation:

a. The number of each service type of component ( e.g. valves, flanges, etc.) in each process

unit

b. The service each component is in (e.g. gas, light liquid, heavy liquid, water or oil)

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c. The weight fraction of total organic compounds (TOCs) within the stream

d. Operational hours for particular streams (e.g. hours/year)

Two guidelines that will be underscored in this discourse are:

(i) The method adopted in the USA for the industry sector by the US Environmental

Protection Agency (EPA) in the 1995 and the American Petroleum Institute (API) in

1996 (Method 21)

(ii) The Intergovernmental Panel on Climate Change (IPCC) in 1988.

Both guidelines have been reviewed and renewed over the years after they were first introduced.

3.1.2 THE USA EPA AND API ASSESSMENT

Four different methods have been devised that can be used in applying estimations to fugitive

emissions and these are:

1. Average Emission Factor Method

2. Screening Value Range Method

3. Correlation Equation Method

4. The Unit-specific Correlation Equation

3.1.2.1 The Average Emission Factor MethodHere, emission factors are combined with equipment counts to calculate emissions. This method

is normally recommended when no screening data are available and as such is the least-cost

methodology. Facilities that rely on this method are normally deemed to be irresponsible. This is

because there are no technological reasons why a facility is not able to perform screening audits.

In addition to the general data required for the calculation of fugitive emissions, the following

steps are used:

1. The number of components in each service type group is multiplied by the

corresponding average emission factor to obtain the subtotal of emissions from the

group.

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2. The subtotals of the various emissions groups are then added together to provide the

total emission from the facility.

As an example, CAPOA (1999) investigated 5000 components at a refinery. The components

were inventoried into eight groups of component type or service type corresponding to the USA

EPA Protocol of average emission factors. The number in each group is multiplied by the

appropriate corresponding average emission factor in Appendix A. The total emission estimate

for the refinery was estimated to be 0.0944 kg/h. The subtotals in each group can also be further

multiplied by the number of operational hours in a year or quarterly in other to determine the

mass emissions for the period.

3.1.2.2 The Screening Value Range MethodThe Screening Value Range Method was previously referred to as the Leak/No Leak Method. It

relies on the screening data from Organic Vapour Analyzers (OVAs) to estimate the mass

emission rates based on the component leak level. A leak below 10,000ppm is defined as no leak

while those equal to or greater than 10,000ppm are classified as leak (USA EPA). This fugitive

emission estimation method is also listed under the least-cost emission methodology inventory.

In the application of this method, the following steps are followed (Appendix B):

1. The total number of components in each group (component type and service type) with

their corresponding screening values (whether below 10,000ppm or above 10,000ppm)

are determined.

2. The total number of components under each group is multiplied by their corresponding

screening value emission factor.

3. The subtotals of emissions from all subgroups are added to estimate the total fugitive

emissions from the facility.

3.1.2.3 Correlation Equation MethodIn the Correlation Equation Method, screening values for all equipment components are

singularly used in correlation equations or counted as either defaults zeros or pegged

components. Following recommended guidelines published in the CAPCOA guidance document:

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Default zero factors are applied only when the screening value, corrected for

background , equals 0.0ppm (this implies that the screening value detected at the

component is indistinguishable from the background reading)

Correlation equations which apply to actual screening values, corrected for background

and 9,999ppm. This is used for components that are detected to have screening values up

to 9,999ppm.

Pegged factors that apply for screening values, corrected for background, which is equal

to or greater than 10,000ppm and 100,000ppm. For the 10,000ppm pegged factors, the

screening value is between the background and 9,999ppm while the 100,000ppm pegged

factors are based on screening values between the background emission and 99,999ppm.

The following procedure is applied in this method (Appendix C):

1. Each individual components screening value is recorded.

2. The data is grouped into the three categories of screening ranges, thus, default zero range,

correlation equation range and pegged source range.

3. The number of components in the default zero range is multiplied by their appropriate

default zero factors.

4. The individual component screening value within the correlation range is entered into the

appropriate correlation equation.

5. The number of components with the screening values in the pegged rang is multiplied by

the appropriate pegged value emission factors.

6. The total fugitive emissions from the facility can then be estimated by summing up all the

calculated emissions from each subcategory.

3.1.2.4 The Unit-specific Correlation Equation MethodIn the Unit-specific Correlation Equation Method, a particular set of individual equipment

component are selected for screening from which screening and actual mass emissions are

measured directly from. Unit-specific correlation equations and some pegged source factors are

then used to estimate emissions.

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3.1.3 THE INTERGOVERNMENTAL PANEL ON CLIMATE CHANGE (IPCC)

ASSESSMENT

The IPCC was established by the World Meteorological Organization (WMO) and the United

Nations Environment Program (UNEP) in 1988. Its main objective was to assess scientific,

technical and socio-economic information relevant to the understanding of human-induced

climate change, potential impacts of climate change and options for mitigation and adaptation

(Cheremisinoff and Rosenfeld, 2009).

A three-tier approach has been devised by IPCC for estimating fugitive emissions from the

operations of the oil and gas industry;

1. Top-down average emission factor approach

2. Mass balance approach

3. Rigorous bottom-up approach

3.1.3.1 Top-down average emission factor approach

The Tier 1 is a top-down approach where average production-based factors are applied to

reported oil and gas production volumes. It is typically applied in countries with very limited oil

and gas industries.

3.1.3.2 Mass balance approach

Tier 2, which considers a mass balance approach, is intended primarily for systems where the

majority of gas production is flared or vented. The total amount of gas produced with oil is

assessed and then control factors are applied to account for conserved, re-injected and utilized

volumes. The results is a determination of the amount of gas either flared or lost directly to the

environment.

3.1.3.3 Rigorous bottom up approach

Tier 3 is a rigorous assessment of fugitive emissions from individual sources or components

using a bottom-up approach that requires infrastructure data and detailed production data.

Results are aggregated from individual facilities to determine total emissions.

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3.2 KEY CHALLENGES DURING THE ASSESSMENT OF FUGITIVE EMISSIONS

A number of challenges have been faced by the industry, government and other stakeholders

when addressing fugitive emissions. The main challenges are as follows.

The identification of sources

When the leak occurs in a large facility area the source may be quite complex when there are

thousands or hundred components. The only way that the leak can be detected is when the

leaking fluid is toxic. How detection can be done effectively and economically also represent a

key challenge for the oil and gas industry as part of the challenge the industry need to conduct an

early detection and repair system.

Measurement of fugitive emissions

When assessing fugitive emissions both intentional and unintentional, accuracy is difficult to

achieve technically and practically. Even when using the most advance technology there is a

substantial amount of uncertainty involved. The uncertainty is due to the fact that there is an

absence of activity data. Also the complexity of the facility and the type of emissions could be a

factor.

Return on the investment

Setting up fugitive emissions management programs which can deliver the expected return-on-

investment is such that the allocation of financial resources to those programs knowing that the

return on investment is very poor than that for other possible allocations represent a particular

challenge to the industry. Again the time to see the reward is longer than any other plant

production related activities.

Lack of public engagement

Whenever the leaking fluid is of a toxic nature or when the event that occurs affects the plant

workers there is always public welfare to increase awareness, regulators and companies so that

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they can take action. However when the leaking fluid is non-toxic it is difficult for such

procedures to be implemented.

Technology

The advance technology used to detect and measure fugitive emissions in the oil and gas industry

notably provide an accurate measurement of volumes and also the capacity to determine the

potential economic benefits for acting to minimize these emissions. But the crucial issue about

technology is the cost.

3.3 SEALS

Liquids and gases mostly transferred by rotating equipment make use of seals to isolate the fluid

medium from the atmosphere during the operation of the process equipment. Pumps,

compressors and valves make use of seals in preventing leakages of process fluids from being

introduced into the environment. Generally, seals are devices that are used in connecting systems

or mechanisms so as to minimize or stop leakages in a structure which is under pressure. The oil

and gas industry has certain commonalities driven from experience for selecting the right sealing

system for the right job.

3.3.1 PROCESS EQUIPMENT LEAKS

There are various types of seals that are employed in isolating process fluids in pumps,

compressors, valves, pressure relief devices, agitators from leaking to the atmosphere.

3.3.1.1 PUMP SEALSOne of the most common piece of equipment sold for use in the industry for offshore operations

are pumps. Packing and mechanical seals are the two generic pump seals used to mitigate

leakages between the moving shaft elements and stationary housings. These packing and

mechanical seals must be used to ensure that leakages are controlled. The rotating element

extends through the stationary housing of the pump in which a sealing device can be installed.

Packing Seals

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Packing seals is used on both reciprocating and centrifugal pumps. The stuffing box (cavity) of

the pump contains tightly compacted packing material to form a seal around the rotational drive

shaft. The compression applied in the stuffing box to the seal is made possible by a packing

gland. To prevent frictional heat accumulation between the moving shaft and the seal of the

pump, a sufficient amount of either the process fluid or a supplementary liquid (lubricant) is

allowed to flow between the packing and the moving shaft. The sealing system here is parallel to

the moving shaft.

Mechanical Seals

Currently, mechanical seals are the most widely used seals in pumps. There are two types of

mechanical seals in use; single mechanical seals and double or dual mechanical seals. The single

mechanical seals are made up of two sealing elements which are the mating ring (stationary) and

the primary ring (rotating). A nearly all over seal is created where the surfaces of the two ring

element contacts are lapped. This ensures a very high degree of flatness to maintain contact over

the entire material surface.

Double mechanical seals are much more efficient than single mechanical seals in controlling

leakages. Double mechanical seal are arranged in either back-to-back or in tandem. In a back-to-

back arrangement, the inner and outer seals (both containing stationary and rotating rings) face

each other in the opposite direction. There is a closed cavity between the two seals. A seal liquid,

such as oil or water, is circulated through this seal-housing cavity. In order for the seal to

function, the seal liquid must be at a pressure greater than the operating pressure of the liquid

being pumped at the stuffing box. This lubricant is called a barrier fluid. As a result, some liquid

will leak across the seal faces passing into the stuffing box and also out past the outer seal face to

the atmosphere.

The inner and outer seals face the same direction in the tandem mechanical seal arrangement.

The inner seal is located in the stuffing box housing rather than in the seal housing. The fluid

used for lubrication is of a lower pressure than as compared to the pressure of the pumped

medium. The lubricant in this case is called a buffer fluid.

The sealing elements in mechanical seal are perpendicular to the moving shaft of the pump.

Also, mechanical seals can be equipped with secondary seals. Secondary seals prevent leakage

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between the rotating ring and shaft, the stationary ring and gland plate, and the stuffing box

housing and gland ring. The secondary seals are often flexible O-ring. Mechanical seals even

equipped with secondary seals are not leak-proof.

3.3.1.2 COMPRESSOR SEALSAs with seals in pumps, compressor seals are potential sources of fugitive emissions. Shaft seals

for compressor seals maybe labyrinth seals, restrictive carbon ring seals, liquid film seals and

mechanical contact seals. One point worth mentioning is that all seals used in the various

operations are leak restrictive devices which may not completely get rid of leakages but aimed at

ensuring that emissions from such sources are greatly reduced. Compressors are normally

equipped with ports in the seal area to evacuate gases that will be accumulated there.

Discharging of gases from these ports should be done with care to prevent venting into the

atmosphere.

Labyrinth Seals

Labyrinth seals are composed of a series of close tolerance, interlocking teeth that limit the flow

of gas streams along the shaft. A whole lot of teeth design and materials of construction are

available. Of the different types of compressor seals, labyrinth seals have the largest leak

potential but when properly applied variations in tooth configuration and shape can drastically

reduce leak potential to about 40% of the other types.

Restrictive Carbon Ring Seals

Restrictive carbon ring seals are made up of a series of stationary carbon rings with close shaft

clearances. This type of seal may be operated dry or with a sealing fluid. A restrictive carbon

ring seal normally attain a lower leak rate than the labyrinth type.

Liquid Film Seals

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Liquid film seals are usually fitted in centrifugal compressors. The seal constitutes a film of oil

between the rotating shaft and stationary gland. The process gas can be discharged into the

atmosphere when the circulating oil is returned to the oil reservoir. To mitigate this occurrence

from the seal oil system, the oil reservoir can be vented to a control device.

Mechanical Contact Seal

Mechanical contact seals for compressors and mechanical seals described previously for pumps

are alike. The clearance between the rotating and stationary elements is essentially reduced to

naught by the seal. Mechanical contact seals, like mechanical seals in pumps, can achieve the

lowest leak rates even though they may not be suited for all processing conditions.

3.3.1.3 VALVE SEALSMany different types of valves exist, however, they can be classified into three functional

groups:

1. Block valves are used for on and off control of process equipment. Typically, these

valves are used occasionally, such as when there is a process change (i.e., unit shutdown).

2. Control valves are used for flow rate control.

3. Check valves are used for directional control purposes.

Valves are activated by a valve stem. All the various categories of valves have stem except check

valves. The valve stem maybe in rotational or linear motion. Process fluids that flow through the

valve stem must be isolated from the atmosphere. This is where valve seals come in. Check

valves are wrapped within process piping and as such are not considered to be a potential source

of fugitive emissions. Sealing valve stems is achieved by applying a packing material or O-ring

seal. The packing material is installed around the stem area of the valve and compressed to form

a tight seal by the help of a packing gland. The packing material used depends on the valve

application and configuration. The packing gland must be tightened to continue providing a tight

seal during the self-life of the valve.

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Elastomeric O-rings

These provide good seals in process valves but are not suited where sliding motion occurs

through the packing gland. As a result, Elastomeric O-rings are seldomly used in high pressure

service. The O-ring material also limits the operating temperature of this device.

Bellows seals

Bellows seals are described as having a more effective sealing system for preventing process

fluid leaks than any conventional packing or any gland-seal arrangements. This seal incorporates

a formed metal bellows that make a barrier between the disc and body bonnet joint. The bellows

is the weak point of the arrangement and its service life can be quite varying. The bellows seal is

often backed on a packing gland and usually fitted with a leak detector in case the seal fails.

AGITATOR SEALS

In the operation of agitators in stirring or blending chemicals, leakages may occur at the point

where the shaft penetrates the casing body. Seals are therefore required to minimize fugitive

emission from agitators. Four seals commonly used with agitators are packed seals, mechanical

seals, hydraulic seals and lip seals. Of all these, mechanical seals are the most expensive.

Mechanical seals greatly reduce leakage rate. This compensates for the high cost. Packed and

mechanical seals used with agitators are similar in design and application to those for pumps and

compressors.

Hydraulic seals

Hydraulic seal is the simplest and least used agitator shaft seal. For this seal, an annular cup

fixed to the process vessel contains a seal liquid which is in close interaction with an inverted

cup attached to the rotating agitator shaft. The principal advantage of this seal over the other

agitator seals is that it is a non-contact seal. Hydraulic seals function best in low temperature and

pressure conditions and can handle only very small pressure fluctuations. Process fluids which

pass through the rotating shaft may contaminate the seal liquid and further released into the

atmosphere as fugitive emissions.

Lip seals

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The sealing element of the lip seal is a spring-loaded elastomer. It is usually installed on a top-

entering agitator as a dust or vapor seal. This type of seal is relatively inexpensive and easy to

install as well. The lip seal when set up for use is in continuous contact with the rotating agitator

shaft. Fugitive emissions could be released through this seal when it wears excessively as a result

of the operational pressure and temperature exceeding that of the seal’s set pressure and

temperature limits. The set pressure and temperature limits are dependent on the characteristics

of the elastomer.

3.3.2 OTHER POTENTIAL FUGITIVE EMISSION SOURCES

FLANGES

Flanges are bolted, gasket-sealed junctions between sections of pipe and pieces of equipment.

They are used whenever pipe or equipment components (vessels, pumps, valves, heat

exchangers, etc.) may require isolation or removal. Since there is a possibility of a leak through

the gasket seal, flanges are rendered a potential source of fugitive emissions. Although there are

many of flanges in a processing unit system, their overall contribution to emission rate is small

than as compared to valves. Most flanges cannot be isolated from the process to allow for gasket

replacement. The ideal procedures to undertake when repairing a flange which is found to leak

are to tighten any loosed flange bolts or inject a sealing fluid. Much remedial works can be done

on flanges when the process operation is shut down or during maintenance operations.

COOLING TOWERS

A cooling tower extracts heat from water that is intended to be used to cool process equipment

such as heat exchangers, condensers or reactors. The cooling water is circulated through some of

the process units in tubes and delivered to the cooling tower where the water is cooled. In the

cooling tower, as air is circulated through the now tempered to hot water to remove the heat, a

portion of this water is evaporated to the atmosphere. The not used up water is cooled by

furnishing the heat for this evaporation process. Fugitive emissions can be released into the

atmosphere as contaminated water vaporizes in the tower. The contamination of the cooling

water could be the results of organic fluids entering the cooling water from leaking process

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equipment or directly using contaminated process water as makeup water for the cooling tower.

To counteract this happening, the amount of hydrocarbons entering the cooling tower must be

reduced. In doing this, all nearby potential equipment leak sources should be fixed if damaged

and monitored regularly. Also, cooling towers that make use of indirect (non-contact)

condensation will greatly reduce the amount of contaminated water entering the tower.

3.3.3 SELECTION FACTORS OR PARAMETERS FOR SEALS IN THE OIL AND GAS INDUSTRY

The problem of controlling fugitive emission from seals is acknowledged by the oil and gas

sealing industry as one of the most important technical challenges. To control fugitive emissions,

correct selection and use of the appropriate sealing technology is fundamental. Without them,

pumps will leak, valves will release chemicals into the air, flanges would spray process fluids

and oil would drip from gearboxes, among others. The process of selecting the right device for

any given application begins with defining the expected level of performance and identifying

service conditions. A simple acronym, TAMPSS (Temperature, Application, Medium, Pressure,

Size and Speed) provides a general guide to assuring selection of the correct sealing device for

your application (Drago J and Tones M, 2007).

Temperature

The first consideration should be the temperature of the fluid contacting the seal, which in

rotating equipment will increase due to frictional heat. The frictional heat generated by the

rotating equipment will increase the temperature of the fluid contacting the seal. Temperature

data will immediately limit the number of viable seals for an application.

Application

Knowing how the seal is to be used and the function it is expected to perform are keys to making

the right selection. This type of information points up the anomalies of an application and the

special requirements for optimal seal performance. Defining the parameters of a particular

application requires information about where the seal will be installed. For example, if the

application is a valve, selection of the stem, whether its motion is reciprocating, helical or

continuous, and whether a specific level of leakage must be attained to meet environment

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regulations. This is extremely important sine 70% of gasket failure is attributed to insufficient

load (Drago, J, 2009).

Media

Either the common or chemical name of the gas, liquid or solid that will come into contact with

the seal can be used to determine its compatibility with the seal material. Also considered should

be any secondary media to which the seal may be exposed, such as fluids that are intermittently

present during chemical or steam/hot-water flushing. Sometimes, the sensitivity of the media to

color contamination or extracted materials that may leach from the seal must also be considered.

Pressure

This refers to the internal pressure a seal must contain. Most systems operate at fairly consistent

pressure, but as with temperature, it is important to know if the seal will be subject to pulses and

other variations as a normal part of operation.

Size

There are standard sizes for ASME flanges, API valves stems, ANSI pump shafts and others.

Non-standard sizes are best conveyed to the sealing manufacturer in the form of dimensional

drawings. Most pumps and valves conform to API/ANSI standards. Otherwise, they must be

field measured.

Speed

The speed of a rotating shaft or reciprocating rod must be taken into account when selecting oil

seals, mechanical seals or compression packing for dynamic applications. High speeds call for

sealing materials that can withstand and effectively dissipate frictional heat.

Steps to be taken with every application

1. Materials that are chemically compactible with the process fluid and will handle the

pressure requirement and consistency (slurry, viscosity, specific gravity) must be chosen.

2. Choose the design or style which is appropriate in size to fit the equipment and

engineered to handle the process fluid

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3. The seal should be installed into a piece of equipment that is in good mechanical

condition.

4. The best environmental controls should be provided and applied to ensure that the seal is

working in the best possible environment.

For example, in flanges, you may have the best design, installed properly in good equipment

with the very best environment controls, but if the gasket chosen for operation is not compatible,

there will be leakage denoting that the job was not done properly.

3.3.4 SELECTION OF THE RIGHT SEAL

Figure 5. Seal Selection can be based on the Fluid’s Specific Gravity and the Maximum Allowable VOC

Emission Levels

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Mechanical seals have long played a major role in minimizing emissions to the atmosphere from

rotating equipment specially pumps. Within a decade, regulators have gone from little or no

concern about fugitive hazardous emissions to making them the center of restrictions,

particularly for VOC. To meet environmental regulations, the seal industry has developed and

made available a range of technological advances in seal design and materials. To select the

correct type of mechanical seal, install the proper environmental controls, choose the right

materials for your application, and install the seal correctly there is the need to define the sealing

specifications. Greater care need to be taken during the seal installation and maintenance. The

key to a successful seal life is to minimize the types of motion transferred to the seal but the best

mechanical seal can fail due to various reasons:

1. One of the seal materials become damaged

2. The lapped seal faces open and allow the product to leak

3. Wrong selection and improper application

4. Poor installation and adequate maintenance practices that are applied to sealing system;

These problems can be overcome through a better understanding of the types of sealing material

available, redefine selection procedures and the consistent application of sound replacement and

maintenance practices.

After taking into account the various seals categories the best seal category that should be used at

the Jubilee Field is the Dual seal in case of a leak. The reasons why we selected the double seal

are as follows:

1. Dual mechanical seals can act as a spare seal in situations when the facility cannot yield

an unexpected shutdown.

2. They are designed with a two way hydraulic balance.

3. Double mechanical seals can reduce leakage to almost zero when operating properly.

4. When using this technology, there are no significant amounts of direct or indirect

increase in emissions.

After we choose the seal type the next step is to select the seal material that is chemically

compatible with all the fluids that will be passing through the process equipment. There are

various materials that can be looked at but for the sake of this project Nitrile is the best choice.

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The reasons behind this option are; Nitrile oil seals combine excellent resistance to petroleum

based oils and fuels, silicon greases, hydraulic fluids, water and alcohols. Also it has good

working balance properties such as low compression set, high tensile strength, and excellent

abrasion wear resistance with an operating temperature range of -40 0C to 135 0C with a low

relatively cost.

There is also the need to take into account important environmental controls during the selection

of the right seal. Some of these environmental controls are as described below.

The first environmental control is to check the temperature in the stuffing box area. The

temperature can rise, lower or kept it within certain limits that will be prescribed by the seal

design and product characteristics. This environmental control is the most important when the

pump is shut down and the pumping fluids can either cools or heats up due to ambient

temperature.

The next environmental control is the pressure in the stuffing box area. There are many

occasions where we will want to control stuffing box pressure to stop a fluid from vaporizing,

flashing or evaporating. We seldom have to let down the stuffing box pressure, but in a case

where is too high for a conventional balanced seal, it would be better off going to a special high

pressure design.

The last factor account for environmental control is cleaning up of the product in the stuffing

box. Clean products are less problematic to seal. Flushing is one of the options, although there

are more. Any of the environmental controls suggested will work better in a case where the

installation of an oversizing stuffing box on the pump is made correctly. Note that the seal need

lots of radial room to allow centrifugal force to throw solids away from the lapped seal faces and

to lessen the propagation of heat in the stuffing box. Also note that heat is a major cause of

problems with both centrifugal pumps and mechanical seals. Anything that can be done to help

remove heat from the stuffing box will add to the life of the seal and pumps bearings.

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3.3.5 Causes of Premature failure of Process equipment

Coupling Misalignment

Seal and bearing failures are frequently caused by improperly aligned couplings. Vibrations that

are generated by misalignment cause chipped or broken faces as well as overheated and damaged

bearings. The solution to this problem is making sure that equipment components to be installed

are aligned in the proper orientation and by following the manufactures’ guidelines for

installation.

Heat

All seals have temperature limits which they can operate. Also, most applications have limits

above or below which negative results will be realized. For example, O-rings can overheat,

compression set or cook. Furthermore, metal parts can grow and hence hinder seal flexibility and

faces to be loosen from their carriers. Some of the ways in which heat can be generated above

system temperature and adversely affect seal performance are running a mechanical seal dry,

running a single seal with a vacuum in the seal chamber, limited flow through the seal chamber

due to front and rear wear bushing or rings and poor start-up procedures among others.

Cavitation

Cavitation is a condition created by insufficient available head (pressure) at the suction side of a

pump, to satisfy discharge demand. This causes gas bubbles in areas where pressure decreases

abruptly. The bubbles collapse (implode) when they reach areas of higher pressure, causing

hammering, vibration and damage to pump parts (impeller, volute and back plate). It sounds like

pumping rocks. (Klozure-Mechanical seal-Tech-Man). This process causes low level in supply

source, build-up obstruction or some type of restriction of flow to suction or impeller discharge

into supply tank is done improperly and air entrapment because of poor piping design. Vibration

that occurs from cavitation is transmitted along the shaft to the seal, bearings, coupling and the

motor. As this continues, the pump parts are damaged and cause seal and pump failure.

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Air Entrapment or Entrainment

Whenever air is trapped in the suction piping of a pump, cavitation is developed (as mentioned

above). Usually, air entrainment is caused by positioning the return to the supply tank in a poor

elevation or above the fluid level. The return line to the tank should discharge below the fluid

level and away from the tank outlet.

Over pumping

Pumps used to deliver fluids beyond its design or recommendable limits often than not leads to

the overheating of bearings, cavitation, seal and motor failure. Over pumping operations should

be avoided at all cost.

Pipe Strain

Piping at various discharge or suction points when not properly aligned with flanges will result

in a phenomenon known as pipe strain. Its causes include improper support, thermal growth,

poor installation and settling of old system. Some of the consequences of this condition are

vibrations caused by pipe deflection and misalignment, overheating of bearings as a result of side

loading and impeller binds in casing. Pipe strain can be curbed when proper support (hangers)

and proper piping alignments are affected in the installation of process equipment.

Bearing Failure

When pump bearing fails, it loses its ability to support the rotating shaft. The rotating element

will whip unpredictably making rotating parts to strike stationary parts. In such a situation, the

quality of the seal being used matters less since the damage to the equipment has already

occurred.

Poor Gasket Area

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In flanges, a good gasket surface perpendicular to the shaft is essential. Gaskets to be used for

operations should be such that the surface area is rid of pit, rough, mar or any erosion. If the

gasket surface area is eroded, a facing tool or a lathe can be used to recondition it to the desired

state.

Improper Installation

Before process equipment are installed for operations, they need to be checked for:

1. Dirty or damaged faces

2. Secondary seal (elastomer) damage

3. Seal set at wrong working length

4. Improper environmental controls

5. Seal improperly aligned

6. Wrong seal for application

3.3.6 OTHER TECHNOLOGICALLY IMPROVED ALTERNATIVES FOR DETECTING AND MEASURING FE

The differential absorption light detection and ranging (DIAL) technology and enhanced infrared

video imaging appear to offer more precise methods for the identification of emission sources. It

has been used to remotely measure concentration profiles of hydrocarbons for refinery survey in

Europe for over 15 years. DIAL method is the only technique that empowers mass emissions

fluxes to be obtained directly. This technique is non-invasive and single-ended, and gives

concentration profiles of hydrocarbons and mass emissions of various forms in the area being

studied. A pilot study carried out in 2005 using this approach found that the actual emissions at a

refinery were fifteen times higher than those previously reported using the emission factor

method. (Cheremisinoff and Rosenfeld, 2009).

Currently, portable analyzers provide an effective approach for both locating and measuring the

concentration of leaks from oil and natural gas production sites. There are several other technologies

being used to detect leaks for the oil and natural gas sectors. These technologies include optical

gas imaging (OGI) and ambient/mobile monitoring. OGI is a technology that operates much like

a consumer video-camcorder and provides a real-time visual image of gas emissions or leaks to

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the atmosphere. The OGI camera works by using spectral wavelength filtering and an array of IR

detectors to image the IR absorption of hydrocarbons and other gaseous compounds. As the gas

absorbs radiant energy at the same waveband that the filter transmits to the detector, the gas and

motion of the gas is imaged. The OGI can be used for monitoring a large array of equipment and

components at a facility and is effective means of detecting leaks when the technology is used

suitably.

The detection of the OGI camera is based on a variety of factors such as detector capability, gas

characteristics of the leak, optical of the plume and the temperature difference between the gas

and the background. Further investigations are currently studying OGI technology in order to

find its limitations and capabilities.

The OGI provide a technology that can potentially minimize the time and cost efficient method

for locating leak than traditional technologies, such as portable analyzes. By increasing the

number of equipment that can be viewed per hour the OGI system could potentially reduce the

cost of identifying leaks in upstream oil and gas facilities when compared to other equipment.

However, there are limitations to this technology.

The OGI system is sensitive to the ambient conditions around the equipment that is being audited

or inspected. Thus the higher the temperature difference between the leaking gas and the

contrasting background, the easier the leaking gas is to see. Additionally variable wind

conditions can reduce the optical depth and make it difficult for gas leak to be distinguished.

Also the effectiveness of an OGI instrument is dependent on the training and expertise of the

operator. (US EPA, 2014).

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4 CHAPTER FOUR

4.1 REDUCING EQUIPMENT LEAK EMISSIONS

There are three primary techniques for reducing equipment leak emissions:

(1) Modifying or replacing existing equipment

(2) Implementing programs such as: Leak Detection and Repair (LDAR) program and Direct

Inspection and Maintenance program (DI&M) and

(3) Selecting the right sealing system

4.1.1 DIRECT INSPECTION &MAINTENANCE (DI&M) PROGRAM

The first step is to determine which types of components will be targeted. The targeted

components are those components with high levels of leakages. The objective is to minimize the

potential for leaks in the most practicable manner possible. This is done by focusing efforts on

the types of components and service applications most likely to offer significant cost-effective

control opportunities. Non-target components are subjected to coarse or less frequent screening.

Typically, a facility will phase the DI&M program over a certain number of years by

progressively adding to the list of target components until all key potential contributors are being

targeted. Once a leak is detected, regardless of whether it is a target or non-target component, the

Decision Tree reproduced under Figure should be followed to determine if a leak need to be

repaired. Once a leak is determined to need fixing, this should be done within a reasonable

period of time, or at the next facility turnaround if a major shutdown is required. A facility may

choose to simply repair or fix the leak. If it is not a simple repair or fix, an operator may choose

to program the repair at the next shut down without quantification or, alternatively, the leak

should be measured or estimated to determine if it is economical to repair. Where an operator

believes that it may not be economical to repair, this should be documented based on reliable

quantification of the amount of leakage and the repair cost. If a leak poses a health, safety, or

environmental concern, then it needs to be repaired regardless of whether it is economical to fix.

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Figure 6. DI&M Decision Tree

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Source: Management of Fugitive Emissions at Upstream Oil and Gas Facilities, 2007.4.1.2 LEAK DETECTION AND REPAIR PROGRAM (LDAR)

An LDAR program is a structured program to detect and repair equipment that is identified as

leaking beyond acceptable limits. It is designed to identify pieces of equipment that are emitting

sufficient amounts of material to warrant reduction of the emissions through repair. The site

LDAR program consists of the activities that the site initiates to stay in compliance with fugitive

emission standards. Thus, the purpose of the agency LDAR program is to monitor and verify the

effectiveness of the site's LDAR program. To effectively evaluate the source LDAR program,

workers must be able to:

I. Determine which equipment leak regulations are applicable

2. Understand the overall approach of using both equipment standards and leak detection and

repair standards

3. Determine if a source is complying with all the requirements of component identification,

component marking, equipment design, monitoring, repair, recordkeeping, and reporting as part

of a source LDAR program

4. Understand the analyzer performance specifications required by Federal Reference Method 21

5. Evaluate source personnel's calibration procedures and records

6. Evaluate field monitoring procedures used by source personnel to detect leaks from regulated

components.

Those programs are best applied to equipment types that can be repaired on line, resulting in

immediate emissions reduction, and/or to equipment types for which equipment modifications

are not feasible. An LDAR program has proved to be best suited for centralized facilities where

there are a large number of sources under high pressures such as valves and pumps, and can also

be implemented for connectors.

4.1.3 THE CONCEPT OF LEAK Fugitive emissions control is becoming more common as a condition of a facility’s operating

approval. Firstly, a leak could be defined as a screening concentration of 10,000 ppm or more for

the purposes of deciding whether to measure the emission rate and evaluate the practicability of

making repairs. Below this threshold the emissions generally become too small to quantify.

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Moreover, usually only the top 5 to 10 percent of leaking components account for 80 to 90

percent of the emissions at a facility. Consequently, there is limited value in dedicating resources

to measure or estimate emissions from components that do not achieve the screening value

identified. However facilities may still choose to repair these below 10,000 ppm emissions

without measurement.

4.1.4 PIPE LINE INTEGRITYPipeline integrity can be ensured by appropriate design, construction and operation; the use of a pipe-

in-pipe system with annular-space leak sensing would, significantly cut down or entirely eliminate the

possibility of fluid release to the general environment. Whilst this approach can be applied to new

pipelines, it is much more difficult to retrofit an existing pipeline to ensure inherent integrity. Most

integrity systems are therefore based on specific instrumentation and methodologies to reduce the

likelihood of pipeline failure and minimize the consequences of such an event. Pipeline integrity systems

can therefore be split up into Before-the-event and After-the-event systems as indicated in the figure.

Figure 7. Pipeline Integrity Systems

Before-the-event systems are aimed at ensuring the integrity of a pipeline and use a combination

of operational procedures, maintenance procedures, and dedicated hardware and software as part

of an overall pipeline integrity management system (PIMS) to provide advance warming of any

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PIPELINE INTEGRITY

BEFORE THE EVENT SYSTEM AFTER THE EVENT SYSTEM

AVOID AN EVENT REDUCE EFFECT OF AN EVENT

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events or changes in the physical state of the pipeline which may lead to a loss of integrity.

After-the-event systems are aimed at detecting and locating leaks caused by a loss of integrity

and can be based on dedicated sensors or a combination therefore form a central part of the total

strategy and the selection of one or more leak detection system must be made within the context

of an overall PIMS.

4.1.5 LEAK REPAIRS AND ECONOMIC ANALYSIS

The decision to repair the leaking components is made when the leak poses a health, safety, or

environmental concern. Where feasible, replacements need to be done within 45 days starting

from the time the leak was detected. In case that the repair required a shutdown of the plant to

alleviate the work, the replacement may be delayed and wait till the next planned shutdown,

given that the leak does not affect any safety, health, or environmental issues. The economics of

replacing the leaking components is based on the market value of the process fluid that is been

lost, the repair, the replacement cost, and the life expectancy of the applied solution. In the case

that a leak repair has a payback of less than 1 year, should be deemed economical to repair and

should be repaired as soon as possible. The payback period is given by the following expression

PBP= Estimated repair costLeak rate+net value of lost gas

Where,

PBP = payback period (years).

Estimated repair cost or Cost of control = direct repair or replacement costs + gas vented during

repair + cost of lost production due to shutdown ($)

Annual Leak Rate or Leak Rate = amount of gas/vapour emitted directly to the atmosphere or

that leaked into a vent or flare system which does not have vent or flare gas recovery (m3/year)

Net Value of Lost Gas or Gas Price = current market price of the gas based on criteria specified

by the midstream industry, processing fee or margin received ($/103m3).

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The payback period calculation of individual repair assumes that the effect of inflation rates and

discount rates are neglected for simplification purposes.

Sample calculation of a payback period for individual repairs

Tag ID

Component type

Nominal size

Stream type

Hydrocarbons leak rate(m3/hr.)

Hydrocarbons leak rate(103m3/yr.)

Net value lost $/103m3

Estimated repair cost($)

PBP

1991 Gate Valve 8 Wet Gas

0.0046 0.0407 149.60 353 58.0

1992 Flange 8 Wet Gas

0.0026 0.0228 149.60 100 29.3

1993 Ball Valve 0.5 Wet Gas

0.0028 0.0241 149.60 60 16.6

1995 Gate Valve 8 Wet Gas

0.0090 0.0785 149.60 353 30.1

1996 Gate Valve 8 Wet Gas

0.0015 0.0129 149.60 353 182.9

1997 Flange 8 Wet Gas

0.0036 0.0313 149.60 100 21.4

1998 3-Way Control valve

8 Wet Gas

0.0021 0.0187 149.60 350 125.1

Source from Best Management Practice for Fugitive Emissions Management, 2007.

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5 CHAPTER FIVE

5.1 CONCLUSION AND RECOMMENDATION

5.1.1 Conclusion

The world’s share energy challenge of fugitive emissions will require long-term planning and

steadfast commitments. This will involve developing and deploying of new technologies,

encouraging environmental friendly policies and regulations, increasing and sustaining the vast

alternative sources of energy, and as well embracing good management practices. This will in

turn meet multiple objectives of minimizing emissions, sustaining the global energy demand, and

saving the industry many millions of dollars. With all these and more in place we will be able to

address the fugitive emission challenges of our time, and achieve our shared aspiration of a

brighter future for all.

The flared and vented gas volumes at the FPSO, since 2011 to 2014, exceeded the regulated limit

agreed upon by the Jubilee Field Unit Project partners and Ghana EPA.

5.1.1.1 BENEFITS OF THE PROJECT

A successful implementation of a detailed comprehensive fugitive emission inventory and

monitoring program when applied to the Jubilee Field would enable the production facility to

achieve the following remarkable benefits:

Reduce the risk to the entire facility and neighboring environment.

Significantly contribute to the diminution of the ground level ozone which is hazardous

to human health

A significant contribution to the improvement of air quality in the immediate environs of

the FPSO as well as to the residential communities onshore.

Cut down cost to the facility through the reduction in the loss of sealable, valuable

products.

Improve maintenance routine and help to comply with the environmental laws of Ghana

and the world in a whole.

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5.1.2 Recommendation and further work

Stipulation and enforcement of regulations to reduce fugitive emissions released from

process equipment and other sources at oil and gas industries: The Government of Ghana

in conjunction with GH EPA should issue a comprehensive directive on fugitive

emissions. These directives should be applied to the maintenance, repair and upgrade at

existing production facilities, in this case the FPSO at the Jubilee Field. Same should be

applied to processing plants and refineries all over the country. This will be aimed at

improving upon the management of industrial processes and ensure higher level of

protection for the environment.

Increase the Development of Alternative Energy: The energy demand can be achieved by

improving alternative sources of energy and also developing new options. Ghana also

needs a more diverse energy mix which will help energy security to address the issue of

climate change. Using existing non-fossil fuel technologies including renewable, wind,

solar and cleaner fuels technologies will necessarily make a significant and growing

contribution.

Improving Good Management Practice: The knowledge that is used between developed

and developing countries should be one of the importance if the wider problem of FE and

GHS is to be solved. Hence, best management practices, such as leak detection and

management programs and the direct inspection and maintenance programs that take

advantage of improved emission reduction technology must be passed on. Although there

are some challenges associated with those programs, they would mitigation such air

pollution challenges. These studies also suggest that an active approach to fix large leaks

would be the most practicable way of reducing FE.

Including Technology Development and Deployment: We believe that the best hope for

addressing the tremendous dual challenge of meeting growing energy demand while

mitigating emissions is through development and deployment of advanced and new

technologies. Such technologies as TAMPSS for the selection of the right sealing devices

and OGI for detection of leaks from production sites.

Jubilee Field Partners are called upon to develop a comprehensive fugitive emission

inventory program when developing their annual GHG emission inventory. GH EPA

should regulate this campaign.

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REFERENCES1. David Picard (Clearstone Engineering Ltd.), 2006, Good Practice Guidance and

Uncertainty Management in National Greenhouse Gas Inventories, pg. 103

2. N. P. Cheremisinoff and P. Rosenfeld, 2009, Best Practices in the Petroleum Industry,

pgs. 5, 128-139, 157.

3. Canada School of Energy and Environment, Feb. 10-11, 2011, Defining, measuring and

reducing Fugitive Emissions in the oil and gas sector.

4. Management at upstream oil and gas facilities. January, 2007.

5. Mechanical shaft seal types and sealing systems pdf.

6. Osei, B.D. 2011, A Concise History of Oil and Gas Exploration in Ghana.

7. www.offshore-technology.com/jubileefield Accessed: 18 th December, 2014

8. National Greenhouse Gas Inventory Report for 1990-2006 (2011)

9. www.epa.gov/airquality/oilandgas/2014papers/201415leakks.pdf Accessed: 6 th April,

2015

10. Klozure Mechanical Seal Technical Manual

11. www.mcnallyinstitue.com/hmtl/Choosing the seal.hmtl Accessed: 4 th April, 2015

12. National Greenhouse Gas Inventory Report for 1990-2006 (2011)

13. Report for Oil and Natural Gas Sector Leaks April 2014, prepared by US EPA Office of

Air Quality Planning and Standards (OAQPS), pgs. 39-40.

14. ARPN Journal of science and Technology Vol 3, NO. 1 January 2013 pg. 22

15. International Finance Corporation, External Independent Monitoring Tullow Oil Jubilee

Project, April 2013, pgs. 40, 41, 42

16. P.A. Sakyi et al, 2012, West African Journal of Applied Ecology, Vol. 20(1), pg. 62,65

17. Mark Irvine, Albert de Jong and others, Nov 2009, Jubilee Field EIA-Summary, pg. xx

18. CSEE- Carbon Talks, Feb 2011, Fugitive Emissions Discussion Guide, pg. 9, 12

19. Drago, J.; Tones, M.; The Search For Better Sealing Solutions, Maintenance Technology,

(April, 2007), pgs.,24-29

20. Drago, J.; Understanding Sealing Solutions, Chemical Engineering Progress, (July,

2009), pgs., 58-60

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21. Arrowsmith, T., Copenhagen: The Challenge Awaits Us, Future Fuels and Energies, issue

no. 25, (Oct/Dec., 2009), pgs., 30

22. Glass, S. J. Jr., Meeting Industry Challenges through Innovation and Operational

Excellence. Proceedings of the 30th Oil and Money Conference, October 2009, London.

23. Fluid Sealing Association, Are you playing Offense or Defense with your Leak Detection

and Repair? , Pumps and Systems, (October, 2008)

APPENDIX

APPENDIX A

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APPENDIX B

APPENDIX C

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APPENDIX D

YEAR

TOTAL GAS PRODUCTION PER YEAR

TOTAL OIL PRODUCTION PER

YEAR

GAS, MMscf OIL, bbls

2011 22878.81 39218969.00

2012 27705.96 22322118

2013 47430.26 64618526.8

2014 55783.26 37186000

YEAR

RE-INJECTED GAS VOLUMES (MMscf) PER

YEAR

2011 10991.19

2012 24411.6

2013 41351.89

2014 45536.07

YEAR

UTILISED GAS VOLUMES (FOR POWER

GENERATION)

DIESEL/metric tons GAS/MMscf

2011 10318 1608.2

2012 844 2348.4

2013 20527.16 2702.87

2014 2148.3

YEAR

VOLUMES OF GAS (MMscf) FLARED PER

YEAR

2011 12014.72

2012 698.56

2013 3535.88

2014 5205.71

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SOURCE GHANA EPA

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