figure 1. location of the palo alto sampling station in south san francisco bay

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Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay.

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Page 1: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay.

Page 2: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0

5

10

15

20

25

30

Sal

inity

(pa

rts

per

thou

sand

)Salinity

1994 1995 1996 1997 1998 1999 2000 2001

Figure 2. Water column salinity at Palo Alto from 1994 through 2001.

11

Page 3: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 3. Percent silt/clay, iron and aluminum in sediments at Palo Alto from 1994 through 2001.

JMMJ SN94

JMMJ SN95

JMMJ SN96

J MMJ SN97

JMMJ SN98

J MMJ SN99

JMMJ SN00

JMMJ SN01

Time (months)

0.00

1.50

3.00

4.50

6.00

7.50

9.00

10.50

12.00

Alu

min

um &

Iron

(pe

rcen

t dry

wei

ght)

0

20

40

60

80

100

Per

cent

<10

0 m

Percent aluminum, iron and silt/clay in sediment

Fe Al Silt/Clay

1994 1995 1996 1997 1998 1999 2000 2001

12

Page 4: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 4. Near-total extraction concentrations of chromium, vanadium, and nickel in sediments at Palo Alto from 1994 through 2001.

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0

20

40

60

80

100

120

140

160

180

200

Cr,

V, a

nd N

i in

sedi

men

t (g

/g)

Chromium, vanadium, and nickel in sediment

1996 1997 1998 19991994 1995 2000 2001

13

Page 5: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 5. Near-total and acid-extractable copper concentrations in sediments at Palo Alto from 1977 through 2001.

JMMJ SN94

JMMJ SN95

JMMJ SN96

J MMJ SN97

JMMJ SN98

J MMJ SN99

JMMJ SN00

JMMJ SN01

Time (months)

0

10

20

30

40

50

60

70

80

Cu - Near-total extr

200

280

360C

u in

sed

imen

t - N

ear-

tota

l ext

ract

(g/

g)

0

20

40

60

80

100

Cu

in s

edim

ent -

HC

l ext

ract

(g/

g)

Cu - HCl extract

Copper in sediment

1995 1996 1997 1998 20011994 1999 2000

ERM=270ppm

ERL=34ppm

14

Page 6: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 6. Concentrations of near-total and acid-extractable zinc in sediments at Palo Alto from 1994 through 2001.

JMMJ SN94

JMMJ SN95

JMMJ SN96

J MMJ SN97

JMMJ SN98

J MMJ SN99

JMMJ SN00

JMMJ SN01

Time (months)

0

50

100

150

200

Zn -Near-total ext

400

450

500

Zn

in s

edim

ent

- N

ear-

tota

l ext

ract

(g/

g)

0

20

40

60

80

100

Zn

in s

edim

ent

- H

Cl e

xtra

ct (

g/g)

Zn - HCl extract

Zinc in sediment

1995 1996 1997 1998 20011994 1999 2000

ERM=410ppm

ERL=150ppm

Regional Background=75ppm

15

Page 7: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 7. Acid-extractable silver concentrations in sediments at Palo Alto from 1990 through 2001. Extractions were conducted with 0.6 N Hydrochloric acid.

J M S90

J M S91

J M S92

J M S93

J M S94

J M S95

J M S96

J M S97

J M S98

J M S99

J M S00

J M S01

Time (months)

0.00

0.20

0.40

0.60

0.80

1.003

4

Silv

er in

sed

imen

t (g

/g)Silver in Sediment

HCl extract

Regional Background

ERL=1.0ppm

ERM=3.7ppm

16

Page 8: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 8. Total extraction concentrations of cadmium in sediments at Palo Alto from 1994 through 1999.

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

Time (months)

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

Cad

miu

m in

sed

imen

t (g

/g)

Cadmium in sediment

1995 1997 199919961994 1998

17

Page 9: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 9. Concentrations of selenium and mercury in sediments at Palo Alto from 1994 through 2001.

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

Sel

eniu

m &

Mer

cury

in s

edim

ent (

g/g

) Selenium & Mercury in sediment

Hg Se

1994 1995 1996 1997 1998 1999 2000 2001

18

Page 10: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 10. Annual mean concentrations of copper in the clam Macoma balthica at Palo Alto from 1977 through 2001. Error bars denote the standard error of the mean (SEM).

77 79 81 83 85 87 89 91 93 95 97 99 01

Time (Years)

0

50

100

150

200

250

300

350

400

Cop

per

in c

lam

tis

sue

(g

/g)

Annual Mean Copper in Macoma balthica

19

Page 11: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 11. Annual mean concentrations of silver in the clam Macoma balthica at Palo Alto from 1977 through 2001. Error bars denote the standard error of the mean (SEM).

77 79 81 83 85 87 89 91 93 95 97 99 01

Time (Years)

0

20

40

60

80

100

120

140

Silv

er in

cla

m t

issu

e (g

/g)

Annual Mean Silver in Macoma balthica

20

Page 12: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 12. Concentrations of copper in clams (Macoma balthica) at Palo Alto from 1994 through 2001. Error bars denote the standard error of the mean (SEM).

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0

30

60

90

120

150

Cop

per

in c

lam

tiss

ue (g

/g)

Copper in clams

1994 1995 1996 1997 1998 1999 2000 2001

21

Page 13: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 13. Concentrations of silver in clams (Macoma balthica) at Palo Alto from 1994 through 2001. Error bars denote the standard error of the mean (SEM).

J MM J S N94

J MM J S N95

J MM J S N96

J MM J S N97

J MM J S N98

J MM J S N99

J MM J S N00

J M M J S N01

Time (months)

0

3

6

9

12

15

Silv

er in

cla

m ti

ssue

(g

/g)

Silver in clams

1994 1995 1996 1997 1998 1999 2000 2001

22

Page 14: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 14. Concentrations of zinc in clams (Macoma balthica) at Palo Alto from 1994 through 2001. Error bars denote the standard error of the mean (SEM).

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0

100

200

300

400

500

600

700

Zin

c in

cla

m ti

ssue

(g

/g)Zinc in clams

1994 1995 1996 1997 1998 1999 2000 2001

23

Page 15: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 15. Concentrations of chromium in clams (Macoma balthica) at Palo Alto from 1994 through 2001. Error bars denote the standard error of the mean (SEM).

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0

3

6

9

12

Chr

omiu

m in

cla

m ti

ssue

(g

/g)

Chromium in clams

1994 1995 1996 1997 1998 1999 2000 2001

24

Page 16: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 16. Concentrations of nickel in clams (Macoma balthica) at Palo Alto from 1994 through 2001. Error bars denote the standard error of the mean (SEM).

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0

3

6

9

12

15

Nic

kel i

n c

lam

tis

sue

(g

/g)

Nickel in clams

1994 1995 1996 1997 1998 1999 2000 2001

25

Page 17: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 17. Concentrations of selenium in sediments and clams at Palo Alto from 1994 through 2001. Error bars denote the standard error of the mean (SEM).

J MMJ SN94

J MMJ SN95

J MMJ SN96

J MMJ SN97

J MMJ SN98

J MMJ SN99

J MMJ SN00

J MMJ SN01

Time (months)

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

Sel

eniu

m in

sed

imen

t (g

/g)

0

1

2

3

4

5

6

7

8

9

10

Sel

eniu

m in

cla

m ti

ssue

(g

/g)

Selenium in sediment & clams

Se-sed Se-clam

1994 1995 1996 1997 1998 1999 2000 2001

26

Page 18: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 18. Concentrations of mercury in clams (Macoma balthica) at Palo Alto from 1994 through 2001. Error bars denote the standard error of the mean (SEM).

J M M J S N94

J M M J S N95

J M M J S N96

J M M J S N97

J M M J S N98

J M M J S N99

J M M J S N00

J M M J S N01

Time (months)

0.00

0.20

0.40

0.60

0.80

1.00

Mer

cury

in c

lam

tiss

ue (

g/g)

Mercury in clams

1994 1995 1996 1997 1998 1999 2000 2001

27

Page 19: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 19. Weight of Macoma balthica of 25 mm shell length (condition index) as determined between 1988 through 2001 at Palo Alto.

J M S88

J M S89

J M S90

J M S91

J M S92

J M S93

J M S94

J M S95

J M S96

J M S97

J M S98

J M S99

J M S00

J M S01

Time (months)

0

50

100

150

200

250

300

Tis

sue

wei

ght i

n m

g (2

5 m

m c

lam

)Condition Index

1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001

28

Page 20: Figure 1. Location of the Palo Alto sampling station in South San Francisco Bay

Figure 20. Correlation of maximum condition index in Macoma balthica vs. maximum copper concentrations in the months preceding the determination of maximum condition. Data from Palo Alto and San Jose sites for the period from 1990 through 2001.

0 100 200Copper in clam tissue (g/g)

0

100

200

300C

ondi

tion

Inde

x of

cla

ms

(mg

in 2

5 m

m c

lam

)

Max Cu vs. Max CI: PA & SJ

1990 - 19 1999-200 2001

No Cu effect on CI

Cu reduces CI

29