ferries - mhisafety msds book 2015...safety data sheet (sds) date prepared/revised: 1/9/2015 version...

Ferries

2015 MSDS Collection

Ferry Crew Index 2015

Manufacturer Product Name Revision Date

Aervoe Industries Aervoe 860 Glass & Surface Cleaner – Aerosol

January 09, 2015

Amteco Inc. White Zero Rust Aerosol March 01, 2014 Boss Lubricants. Hi-Performance Synthetic

Engine Oil 10W-30 August 28, 2012

Calument Lubricants Co. Calumet Lantern Fuel February 28, 2014

Chatterson Janitoria C-THRU Liquid Glass Cleaner

February 03, 2014

Co-op Refineries D-MO November 13, 2012

Co-op Refineries Diesel Distillate December 18, 2012 Co-op Refineries HD7 October 02, 2012

Co-op Refineries Industrial Hydraulic Oil July 31, 2012 Co-op Refineries Sonic 2 Cycle Oil January 08, 2015

Co-op Refineries Sonic ATF August 22, 2012

Co-op Refineries Sonic Blue Guard May 20, 2014 Co-op Refineries Sonic Industrial Gear Oil May 20, 2014

Co-op Refineries Trans Hydraulic Fluid January 08, 2015 Degil Safety Products

Canada Croc Bloc Heavy Duty

Insect Repellent Aerosol January 29, 2015

Degil Safety Products Canada

Croc Bloc Insect Repellent Foam

January 29, 2015

Degil Safety Products Canada

Croc Bloc SPF30 Spray Lotion

January 29, 2015

Dow Corning Corp. Do Coming 732 Multi- Purpose Sealant-Clear

April 05, 2013

Energizer Battery Manufacturing Inc.

Eveready Energizer Battery

January 01, 2014

Ferrellgas Propane November 01, 2014

General Paint Corp 70-052R Breeze Exterior October 03, 2012

Gojo Industries Purell Instant Hand Sanitizer

April 29, 2013

Grime Eater (Tm) Gel With Pumice Hand Cleanser

January 01, 2014

Gunk. hydraulic jack oil J132C July 11, 2013

Henkel USA Corp Loctite 592 Thread August 29, 2014

Sealant.

Imperial Oil Products Hydraul 56 August 28, 2014

Imperial Oil Products Middle Distillate November 26, 2014

Imperial Oil Products Unirex EP 0 November 10, 2014

Imperial Oil Products Unirex EP 2 November 29, 2012 Imperial Oil Products Unleaded Gasoline February 23, 2015

Imperial Oil Products Block Grease S-100 September 10, 2012

Imperial Oil Products Commercial Propane June 07, 2013

Jelmar. CLR – Calcium Lime & Rust

October 01, 2012

KIK Custom Products. Glass Cleaner October 07, 2014

Kleen-Flo Tumbler Industries Ltd.

Silicone Gasket Maker (Clear) (472)

January 02, 2015


ACE Starting Fluid (735) January 02, 2015


Brake & Parts Kleen (313) January 02, 2015


Dot 3 Super Heavy Duty Brake Fluid 525 -527-528-

529-530

January 02, 2015


Kleen-Start Starting Fluid (730)

January 02, 2015

Lawson Products Inc. Moly Coat May 01, 2013

Nemco Resources Ltd. SR-1 Antifreeze and Coolant

October 01, 2013

NeoChem Enercon Water treatment Ltd. ChemTronic

March 01, 2013

Oatey Co All-purpose cement September 12, 2012

Permatex Canada Inc. PC Fast Orange lotion with Pumice 443 ml

March 31, 2015

Permatex Inc. Fast Orange Pumice Lotion

May 17, 2013

Permatex Inc. Fast Orange Smooth Lotion.

May 16, 2013

Permatex Inc. Spray Nine. March 25, 2014

Radiator Speciality Co. Motor Flush July 18, 2013

Rechochem Inc Universal Gas Line Antifreeze

April 02, 2013

Rechochem Inc 60-40 Premixed Universal Antifreeze Coolant

May 01, 2013

Rechochem Inc Paint Thinner November 24, 2014

Rechochem Inc Solvent November 24, 2014

Rust Check Corp. Rust Inhibitor Aerosol (1043)

April 10, 2015

Rust-Oleum Corp. Enamel 1-Gl 2Pk Flat White

August 14, 2014

Rust-Oleum Corp. Enamel 1-Gl 2Pk High Gloss White

August 15, 2014

Rust-Oleum Corp. Enamel 1-Gl 2Pk Semigl White SemiGloss

September 17, 2014

Rust-Oleum Corp. Enamel 5-Gl High Gloss Black

August 13, 2014

Rust-Oleum Corp Enamel Qt 4Pk Gloss White

August 07, 2012

Rust-Oleum Corp Enamel Qt 4Pk Gloss Safety Orange

August 07, 2012

Rust-Oleum Corp. Enamel 5-Gl High Gloss White

August 14, 2014

S.C. Johnson and Son OFF! Deep Woods 3 Insect Repellent

September 14, 2012

S.C. Johnson and Son Raid Max Wasp & Hornet Foam Bug Killer

November 21, 2014

S.C. Johnson and Son Windex December 05, 2012

Merck Consumer Care Products Canada

Muskol Aerosol, 23.5% DEET

March 11, 2014

Texas Refinery Corp Power Cleanse November 15, 2013

The Procter & Gamble Co. Mr. Clean Antibacterial Multi-Surfaces

Disinfectant Multi-Surfaces Liquid

March 11, 2013

Univar Canad Ltd. Sulphuric Acid 98% January 13, 2014

WD-40 Products Ltd. WD-40 Aerosol March 27, 2014

ZEP Inc. Reach NPE Free February 12, 2014

Discontinued or Out of Date

Manufacturer Product Name Last Revision Date

Boss Lubricants Hi-Performance Synthetic Engine Oil 10W-30

January 01, 2012

Co-op Refineries Ltd. Gasoline – Ethanol Blended

July 19, 2012

Co-op Refineries Ltd.

Kerosene July 07, 2012

Co-op Refineries Ltd. Solvent July 12, 2012

Esso Imperial Oil Products Gear Oil GX Extra 75W-90 April 01, 2009 General Paint Corp. 06-134 Q.D. Shop Primer

– Red February 27, 2012

General Paint Corp 06-154 Anti- Corrosive Primer-Red

February 27, 2012

General Paint Corp 10-010 Marine Enamel – White

June 17, 2010

General Paint Corp 10-122 Marine Rust - White

June 17, 2010

General Paint Corp 10-134 Marine Rust Mild Blue

October 06, 2010

General Paint Corp 11-890 Low Sheen Non-slip En. Q.D.Grey

June 17, 2010

General Paint Corp 32-001 Exterior Allkyd Primer

June 17, 2010

Imperial Oil Products. Heavy Duty Antifreeze 60-40

May 18, 2012

Imperial Oil Products. XD-3 Extra Engine Oil 10W-30

May 03, 2011

Kemsol Products Ltd. San-I-Can Porcelain Cleaner

June 01, 2012

Momentive Performance Silicone Moldmaking Material

June 13, 2008

Permatex Canada Inc. PC Fast Orange Pumice Cream 400GR

October 28, 2010

R.B. Howes & Co. Inc. Howes Lubricator Diesel Treat

July 05, 2012

Rust oleum Corp. Enamel 5-GL Flat Black April 02, 2012

S.C. Johnson and Son OFF! Deep Woods Pump Spray Insect Repellent 4

June 08, 2012

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Product identifier: Aervoe Glass & Surface Cleaner - Aerosol Product name: 860 Glass & Surface Cleaner Relevant identified uses of the substance: Use to clean all glass and baked enamel objects, auto windshields, porcelain,vinyl, Plexiglas, laminated surfaces, chrome, stainless steel, tile, and bumpers. Uses advised against: Poorly ventilated areas CAS No: Not Applicable (mixture) EC No: Not Applicable (mixture) Index No: Not Applicable (mixture) Manufacturer/Supplier: Aervoe Industries Incorporated Street address/P.O. Box: 1100 Mark Circle Country ID/Postcode/Place Gardnerville, Nevada 89410 Telephone number: 001 (0) 1-775-782-0100 e-mail: [email protected] National contact: Aervoe industries Incorporated For Product Information: 001 (0) 1-800-227-0196 Emergency telephone number: 001 (0) 1-800-424-9300 (CHEMTREC – 24 hrs) English Language Service

Classifications Physical Hazards: Aerosol - Category 2 Flam. Gas. 1 Press. Gas Flam Liq 2 Health Hazards: Acute Tox 4 Carc. 1B Muta. 1B Eye Irrit. 2 STOT SE 3 Environmental Hazards: N/AV Labeling Signal Word: Danger

1.) Identification of the Mixture and of the Company

2. Hazards identification

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Hazard Statements: H220 – Extremely flammable gas H223 – Flammable aerosol H225 – Highly flammable liquid and vapour. H229 - Pressurized container: may burst if heated H312 – Harmful in contact with skin. H319 – Causes serious eye irritation. H332 – Harmful if inhaled. H336 – May cause drowsiness or dizziness. H340 – May cause genetic defects H350 – May cause cancer Precautionary Statements: P101 - If medical advice is needed, have product container or label at hand P102 - Keep out of reach of children P103 - Read label before use

P210 - Keep away from heat/sparks/open flames/hot surfaces - no smoking

P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P262 - Do not get in eyes, on skin, or on clothing P264 - Wash … thoroughly after handling P280 - Wear protective gloves/eye protection/face protection P303+P361+P353 - If on skin or hair, remove/takeoff immediately all contaminated clothing. Rinse skin with water/shower.

P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF

P501 - Dispose of contents/container in accordance with local/regional/national/international regulation

Symbols/Pictograms:

3. Composition / Information on Ingredients

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Composition Chemical Synonyms CAS Number EINECS

Number Weight Percent

Hazard Category H-Code

Hydrocarbon Propellant

LPG 68476-86-8 270-705-8 1-5% Press. Gas Flam. Gas 1 Carc. 1B Muta. 1B

H220 H350 H340

Isopropanol Isopropyl Alcohol

67-63-0 200-661-7 1-5% Flam. Liq. 2 Eye Irrit. 2 STOT SE 3

H225 H319 H336

2-Butoxyethyl Acetate

Butyl Glycol Acetate

112-07-2 203-933-3 1-5% Acute Tox. 4 * Acute Tox. 4 *

H332 H312

Ethanol Ethyl Alcohol

64-17-5 200-578-6 1-5% Flam. Liq. 2 H225

Other Product Information Chemical Identity: Mixture

General Advice: If symptoms persist, always call a doctor. Inhalation First Aid: Remove victim to fresh air and provide oxygen if breathing is difficult. If not breathing, give artificial respiration, preferably mouth to mouth. Get medical attention immediately. Skin Contact First Aid: Wash with soap and water. Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Eye Contact First Aid: If contact with eyes, immediately flush eyes with plenty of water for at least 15 minutes, while holding eyelids open. Get medical attention immediately. Ingestion First Aid: If swallowed, wash out mouth with water provided the person is conscious. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. Most Important Symptoms/Effects: Exposure may cause slight irritation to the skin, eyes, and respiratory tract.

Excessive exposure may cause central nervous system effects.

Flammable Properties: Aerosol Auto Ignition Temperature: Not Available Suitable extinguishing media: Carbon dioxide, dry chemical, water spray. Unsuitable extinguishing media: None known Special hazards arising from the

4.) First Aid Measures

5. Fire Fighting Measures

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) substance or mixture: None known Hazardous combustion products: Carbon dioxide, Carbon monoxide Fire & Explosion Hazards: Closed Containers may rupture due to the buildup of pressure from extreme temperatures. Precautions for fire-fighters: Use water spray to cool containers exposed to heat or fire to prevent pressure build up. In the event of a fire, wear full protective clothing and NIOSH- approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

PERSONAL PRECAUTIONARY MEASURES: 1) Follow personal protective equipment recommendations found in section 8. 2) Maintain adequate ventilation. SPILL CLEAN-UP PROCEDURES: 1.) Evacuate unprotected personnel from the area. 2.) Remove sources of ignition if safe to do so. 3.) Pickup spilled materials using non-sparking tools and place in an appropriate container for disposal. 4.) Contain spill to prevent material from entering sewage or ground water systems. 5.) Always dispose of waste materials in accordance with all EU, National and Local Regulations.

Handling: Flammable Aerosol, use in a well ventilated area.

Do not use near sources of ignition. Do not to eat, drink and smoke while working with this material. Wash hands after use.

Conditions for safe storage, including any incompatibilities: Store out of direct sunlight. Storage Temperature: 32° to 120°F (0° to 49°C). No known incompatibilities.

Appropriate engineering controls: Ensure adequate ventilation. A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Keep away from sources of ignition. Take precautionary measures against static discharge. Personal Protection: Eye & face protection devices such as safety glasses, safety goggles or face shield are recommended.

6. Accidental Release Measures

7. Handling and Storage

8. Exposure Controls / Personal Protection

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Skin protection Wear the appropriate protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection: Use only in an adequately ventilated area. For unknown vapor concentrations use a positive-pressure, pressure-demand, self-contained breathing apparatus (SCBA). Hazardous Ingredient CAS

Number ACGIH TLV (TWA)

ACGIH TLV (STEL)

OSHA PEL (TWA)

OSHA PEL (STEL)

Hydrocarbon Propellant 68476-86-8

N/AV N/AV N/AV N/AV

Isopropanol 67-63-0 200ppm 400ppm 400ppm N/AV 2-Butoxyethyl Acetate 112-07-2 20ppm N/AV N/AV N/AV Ethanol 64-17-5 N/AV N/AV N/AV N/AV *Values are based on the 2014 Guide to Occupational Exposure Values by ACGIH

Appearance: Clear Odor: Bouquet Odor Threshold: N/AV pH: Not Applicable (solvent Base) Melting Point: N/AV Freezing Point: N/AV Initial Boiling Point: N/AV Boiling Point Range: N/AV Flash Point: <0° F (-18° C) Evaporation Rate: Slower than n-Butyl

Acetate Flammability Solid/Gas: Flammable gas LEL: N/AV UEL: N/AV Vapor Pressure: N/AV Vapor Density: Heavier Than Air Relative Density: N/AV Solubility: Negligible Partition Coefficient: n-octanol/ water: N/AV

Auto-ignition Temperature: N/AV

Decomposition Temperature: N/AV Viscosity: N/AV Explosive Properties: N/AV Oxidizing Properties: N/AV

Possibility of hazardous reactions: Hazardous polymerization will not occur under normal conditions Chemical stability: Stable under normal conditions Conditions to avoid: Heat and ignition sources Incompatible materials: Strong Oxidizing Agents Hazardous decomposition products: Will not occur

Reports have associated repeated and prolonged overexposure to solvents with permanent brain and

9. Information on Basic Physical and Chemical Properties

10. Stability & Reactivity

11. Toxicological Information

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart and blood Routes of exposure: Eyes, skin, ingestion, and/or inhalation Acute toxicological data: (2-Butoxyethyl Acetate)CD50: 2400mg/kg

(Rat-Oral) (2-Butoxyethyl Acetate) LC50:450ppm,4h (Rat-Oral)

Eye irritation data: N/AV Skin irritation/sensitization/absorption data: N/AV Reproductive toxicity data: N/AV Mutagenicity data: Muta 1B Symptoms associated with physical contact: N/AV Acute/chronic effects from short/long term exposure: Irritating to skin. Prolonged/repeated contact may cause defatting of the skin which can lead to dermatitis. Not expected to be a skin sensitizer. Known reportable carcinogens via the following agencies: NTP: N/AV IARC: N/AV OSHA: N/AV * Petroleum distillates may contain chemical carcinogens in limited quantities (< 0.01%). These quantities are determined by the supplier/fraction/purity of the distillate during the manufacturing process. Chemicals that may be present within distillates are listed on California’s prop 65 list such as ETHYLBENZENE, BENZENE, and TOLUENE.

Ecotoxicity: No Data Available Persistence and degradability: No Data Available Bioaccumulative potential: No Data Available Mobility in soil: No Data Available Results of PBT and vPvB assessment: No Data Available Other adverse effects: No Data Available

12. Ecological Information

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-)

Waste Disposal: Dispose of material in accordance with EU, national and local requirements. For proper disposal of used material, an assessment must be completed to determine the proper and permissible waste management options permitted under applicable rules, regulations and/or laws governing your location. Product / Packaging disposal: Dispose of packaging in accordance with federal, state and local requirements, regulations and/or laws governing your location.

US DOT UN Number

Proper Shipping Name Hazard Class

Packing Group

Marine Pollutant

Special Provisions

UN1950 Aerosols 2.1 Not Applicable

Not Applicable

Reference 49 CFR 172.101

IMDG UN Number


Packing Group

Marine Pollutant

Special Provisions

UN1950 Aerosols 2.1 Not Applicable

Not Applicable

Reference IMDG code part 3

IATA: UN Number


Packing Group

Marine Pollutant

Special Provisions

UN1950 Aerosols, Flammable 2.1 Not Applicable

Not Applicable

Reference IATA Dangerous Goods Regulation

Workplace classification: This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). The Occupational Safety and Health Administration's interpretation of the product's hazard to workers. SARA Title 3: Section 311/312 Categorizations (40 CFR 372): This product is a hazardous chemical under 29 CFR 1910.1200, and is categorized as an immediate and delayed health, and flammability physical hazard. Superfund Amendment and Reauthorization Act (SARA) category. SARA requires reporting any spill of any hazardous substance. TSCA status: All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

13. Disposal Considerations

14. Transportation Information

15. Regulatory Information

Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) WHMIS: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the (M)SDS contains all of the information required by the CPR. PROP 65 (CA): WARNING: This product may contain chemicals know to the state of California to cause cancer, birth defects or other reproductive harm.

This SDS has been completed in accordance with GHS Rev04 (2011): U.S OSHA, CMA, ANSI, Canadian WHMIS standards, and European Directives. Date of Preparation/Revision 1/9/2015 Supersedes: (-) To the best of our knowledge, the information contained herein is believed to be accurate. However, the above data does not imply any guarantee or warranty of any kind, expressed or implied. The final determination of the suitability of any material is the sole responsibility of the user. All materials made present un-known hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee these are the only hazards existing.

16. Other Information

M A T E R I A L S A F E T Y D A T A S H E E T

Page: 1 Date Printed: 1/3/2014

Product Code: Product Name:

24-hour Emergency Phone:

HMIS RATING: H-2 F-4 R-0

WHITE ZERO RUST AEROSOL 67SP

Manufacture : AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069

1-800-424-9300

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

(See top of page)

2. COMPOSITION/INFORMATION ON INGREDIENTS

3. HAZARDS IDENTIFICATION

This product is classified as hazardous under OSHA regulations. FLAMMABLE

liquid and vapor. Harmful if inhaled. Overexposure may cause nervous system

effects. Harmful or fatal if swallowed. Can cause eye and skin irritation.

Causes respiratory tract irritation. May cause serious heart rhythm

disturbances.

ROUTES OF EXPOSURE: Exposure may be by INHALATION and/or SKIN or EYE contact,

depending on conditions of use. To minimize exposure, follow recommendations for

proper use, ventilation, and personal protective equipment.

EFFECTS OF OVEREXPOSURE: Irritation of eyes, skin and upper respiratory system.

May cause nervous system depression. Extreme overexposure may result in

unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE:

Headache, dizziness, nausea, and loss of coordination are indications of

excessive exposure to vapors or spray mists. Redness and itching or burning

sensation may indicate eye or excessive skin exposure.

AGGRAVATED MEDICAL CONDITION:

The following diseases or disorders may be aggravated by exposure to this

product: Skin, Eye, Liver, Kidney, Nervous system, Respiratory system, Lung

(asthma-like conditions).

REPRODUCTION INFORMATION: This material (or a component) may be harmful to

the human fetus based on positive results with laboratory animal.

CARCINOGENICITY: This product could contain trace amounts of ethyl benzene,

which has been shown to cause cancer in lab animals by inhalation and is

listed as a suspect carcinogen by IARC.

CAS No. Ingredient Wt% MAX ACGIH TLV <STEL> OSHA PEL <STEL> Vapor Pressure (mm

Hg 20C)

74-98-6 Propane 16 2500 ppm 1000 ppm 760

106-97-8 Butane 7 800 ppm 800 ppm 760

75-28-5 Isobutane 5 NE NE 760

108-88-3 Toluene 9 50 ppm 100 ppm <150 ppm> 22

67-64-1 Acetone 22 500 ppm <750 ppm> 1000 ppm 180

108-65-6 PM Acetate 4 NE NE 3.8 @ 77F

64742-95-6

Solvent Naptha Light Aromatic 5 200 ppm 200 ppm 4.8@ 100F

123-86-4 n-Butyl Acetate 3 150 ppm <200 ppm> 150 ppm <200 ppm> 8.4

107-87-9 Methyl Propyl Ketone 3 200 ppm 200 ppm 26.9






Manufacture : AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069 1-800-424-9300

4. FIRST AID MEASURES

EYES: Move individual away from exposure and into fresh air. Flush eyes

gently with water for 15 minutes while holding eyelids apart. If symptoms

persist or there is any visual difficulty, seek medical attention immediately.

SKIN: Remove contaminated clothing. Rinse exposed areas with large amounts

of water. If skin is damaged or symptoms persist, seek medical attention.

Launder clothing before reuse.

INGESTION: Seek medical attention immediately! Never give anything by mouth to

a drowsy or unconscious person. Do not induce vomiting. If possible, do not

leave individual unattended.

INHALATION: Immediately move individual away from exposure and into fresh air.

Seek immediate medical attention. Keep person warm and quiet. If not

breathing, begin artificial respiration. If breathing is difficult,

administer oxygen.

NOTE TO PHYSICIANS: Inhalation of high concentrations could occur in enclosed

spaces or during deliberate abuse could cause cardiac arrhythmias. This

material is an aspiration hazard.

5. FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES: FLASH POINT: <0 F Method: TCC Tag Closed Cup

FLAMMABLE LIMITS: ND Upper ND

HAZARDOUS COMBUSTION PRODUCTS: Formation of toxic gases is possible during

heating or in case of fire.

EXTINGUISHING MEDIA: Foam, Carbon Dioxide (CO2), Dry Chemical, Sand

FIREFIGHTING INSTRUCTIONS: Wear self contained breathing apparatus.

Containers may explode if heated above 120F. Water may be used to keep

containers cool. During emergency conditions overexposure to decomposition

products may cause a health hazard.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Eliminate all ignition sources (flares, flames including

pilot lights, electrical sparks). Person not wearing protective equipment

should be excluded from area of spill until clean-up has been completed. Stop

spill at the source. Prevent from entering drains, sewers, streams or other

bodies of water. Prevent from spreading. If runoff occurs, notify authorities

as required. Remove with inert absorbent. Use only non sparking tools for

clean up.

7. HANDLING AND STORAGE

HANDLING AND STORAGE: Keep out of reach of children. Keep away from heat,

sparks and flames. Vapors will accumulate readily and may ignite explosively.

During use and until all vapors are gone – Keep area well ventilated – Do Not

Smoke – Extinguish all flames, pilot lights and heaters – Turn off stoves,

electrical tools and appliances, and any other source of ignition. Consult

NFPA Code. Use approved bonding and grounding procedures.






Manufacture: AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069 1-800-424-9300

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL ADVICE: These recommendations provide general guidance for handling

this product. Personal protective equipment should be selected for

individual applications and should consider factors which affect exposure

potential, such as handling practices, chemical concentrations and

ventilation. It is ultimately the responsibility of the applicator to follow

regulatory guidelines established by local authorities.

ENGINEERING CONTROLS: Local exhaust preferable. General exhaust acceptable if

the exposure to materials in Section 2 is maintained below applicable exposure

limits.

RESPIRATORY PROTECTION: If personal exposure cannot be controlled to below

applicable limits by ventilation, war a properly fitter organic

vapor/particulate respirator approved by NIOSH/MSHA for protection against

materials in Section 2. When sanding or abrading the dried film, wear a

dust/mist respirator approved by NIOSH/MSHA for dust that may be generated by

this product, underlying paint or adhesive.

SKIN PROTECTION AND BODY PROTECTION: Wear impermeable chemical resistant

gloves such as neoprene coated gloves to prevent repeated or prolonged skin

contact. Liquid may penetrate clothes, shoes and leather causing delayed

irritation. Remove immediately if product gets insides. Then wash thoroughly

with soap and water and put on clean clothing or shoes. User should remove

personnel protective equipment immediately after handling this product. Wash

the outside the outside of gloves before removing.

EYE PROTECTION: Use safety eye ware with side-shields to protect against

chemical splash of liquids and spray mist.

WORK/HYGIENIC PRACTICES: Wash hands before and after eating, smoking and using

the bathroom.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: LIQUID/GAS VAPOR DENSITY: HEAVIER THAN AIR SOLUBILITY IN WATER: INSOLUBLE SPECIFIC GRAVITY: 0.757 EVAPORATION RATE: SLOWER THAN ETHER ODOR: STRONG SOLVENT ODOR

Contents under pressure. Do not puncture, incinerate or expose to

temperatures above 120F. Heat from sunlight, radiators, stoves, hot water

and other heat sources could cause containers to burst. Do not take

internally. Category – NFPA 30B Level 2 Aerosol

10. STABILITY AND REACTIVITY

CHEMICAL STABILITY (CONDITIONS TO AVOID): STABLE

CONDITIONS TO AVOID: DO NOT EXPOSE TO TEMPERATURES ABOVE 120F

MATERIALS TO AVOID: STRONG ACIDS, OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, Carbon monoxide, Oxides of

Nitrogen.

HAZARDOUS POLYMERIZATION: WILL NOT OCCUR






MANUFACTURE : AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069 1-800-424-9300

11. TOXICOLOGICAL INFORMATION

CHRONIC/CARCINOGENICITY: This product may contain trace amounts of ethyl

benzene which has been shown to cause cancer in lab animals by inhalation and

is listed as a suspect carcinogen by IARC. Overexposure may cause adverse

effects of the liver, urinary and flood forming systems. Reports have

associated repeated and prolonged overexposure to solvents with permanent

brain and nervous system damage.

12. ECOLOGICAL INFORMATION

ECOLOGY WARNING: Hazardous for water. Do not allow product to reach ground

water, water course or sewage system. Danger to drinking water if even small

quantities leak into the ground.

13. DISPOSAL CONSIDERATIONS

Dispose of according to Federal, State and Local regulations. Must not be

disposed of together with household garbage. Do not allow product to reach

sewage system. Do not incinerate. Depressurize container. Waste from this

product may be hazardous as defined under the Resource Conservation and

Recovery Act (RCRA) 40 CFR 261.

14. TRANSPORT INFORMATION (Not meant to be all inclusive)

DOT GROUND CONSUMER COMMODITY ORM-D

IATA AEROSOLS, FLAMMABLE, UN1950, 2.1

IMDG AEROSOLS, FLAMMABLE, UN1950, 2.1

15. REGULATORY Information(Not meant to be all inclusive - selected regulations

represented) U.S. FEDERAL REGULATIONS:

CERCLA: SARA HAZARD CATEGORY: SECTION 313: *Xylene * Indicates toxic chemical(s) subject to the reporting requirements of

Section 313 of Title III and of 40 CFR 372.

16. DISCLAIMER

TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.

HOWEVER, AMTECO DOES NOT ASSUME ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR

COMPLETENESS OF THE INFORMATION CONTAINED HEREIN. FINAL DETERMINATION OF THE

SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY O THE USER.

1 | P a g e

MATERIAL SAFETY DATA SHEET

*** SECTION 1: PRODUCT AND COMPANY IDENTIFICATION ***

PRODUCT NAME: BOSS HI-PERFORMANCE 5000 ENGINE OIL

Includes Grades 5W-20, 5W-30, 10W-30, 10W-40, 20W-50

SYNONYMS:

Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant.

PRODUCT CODE:

Prefix 21

PRODUCT USE: For lubricating passenger car motors.

If these products are used in combination with other products, refer to the Material Safety Data

Sheet for those products.

SUPPLIER: BOSS Lubricants

6303 30 Street SE

Suite 112

Calgary, AB T2C 1R4

1-800-844-9457

www.bosslubricants.com

TECHNICAL INFORMATION: 1-800-844-9457

ISSUE: August 28, 2012

ORIGINAL ISSUE: October 31, 1998 SUPERSEDES: November 1, 2010

*** SECTION 2: HAZARDS IDENTIFICATION ***

EMERGENCY OVERVIEW

APPEARANCE

Liquid, amber, petroleum odor.

CAUTION!

HEALTH HAZARDS

May irritate eyes and skin.

May be harmful if swallowed.

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OSHA Regulated Chemicals

No information is available.

POTENTIAL HEALTH EFFECTS

INHALATION

(BREATHING):

EYES:

SKIN:

These products are not likely to present an inhalation hazard at normal temperatures and pressures.

However, when aerosolizing, misting, or heating these products, high concentrations of generated vapor

or mist may irritate the respiratory tract (nose, throat, and lungs).

May cause irritation.

May cause irritation. Not likely to be absorbed through the skin in harmful amounts.

INGESTION

(SWALLOWING):

May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing respiratory tract (nose,

throat, and lungs), eye, and/or skin disorders may have increased susceptibility to the effects of exposure.

CHRONIC: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation,

and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the

membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin

contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis).

CANCER

INFORMATION:

No known carcinogenicity. For more information, see SECTION 11: CARCINOGENICITY.

Also see SECTION 15: CALIFORNIA.

POTENTIAL ENVIRONMENTAL EFFECTS

Not available. Also see SECTION 12: ECOLOGICAL INFORMATION.

*** SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS ***

AS # Component Synonym Wt. Percent*

64742-58-1 Lubricating oils, petroleum,

hydrotreated spent

Hydrotreated paraffinic base oil 56-85

Trade Secret Mineral oil Trade Secret 0-35

64742-01-4 Residual oils (petroleum), solvent Bright Stock 0-25

Mixture** Base oil, mixture Not Available 0-25

64742-62-7 Residual oils (petroleum), solvent

dewaxed

Bright Stock 0-25

72623-83-7 Lubricating oils, (petroleum), C>25,

hydrotreated bright stock

Bright Stock 0-25

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72623-86-0 Neutral oil Not Available 0-25

Trade Secret Acrylic copolymer Not Available 0-25

64742-54-7 Petroleum distillates, heavy paraffinic,

C20-C50

Not Available 0-25

64742-55-8 Petroleum distillates, light paraffinic,

C15-C30

Not Available 0-25

68649-42-3 Phosphorodithioic acid, O,O-di-C114-

alkyl esters, zinc salts

Dialkyl (C1-C14) dithiophosphoric acid,

zinc salt

0-6

Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Oil mist, mineral (8012-95-1). *Even though

the concentration range does not fall under the ranges prescribed by WHMIS, this is the actual range which varies with each batch of the product. **The base oil may be a mixture of the following CAS#s: 8042-47-5, 64742-46-7, 64742-47-8, 64742-52-5, 64742-54-7, 72623-84-8, 72623-85-9,

72623-86-0, 72623-87-1, 178603-64-0, 178603-66-2, 17603-65-1, and 445411-73-4

*** SECTION 4: FIRST AID MEASURES ***

INHALATION

(BREATHING):

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give

oxygen. Oxygen should only be administered by qualified personnel. Someone should stay with

victim. Get medical attention if breathing difficulty persists.

EYES: If irritation or redness from exposure to vapor develops, move away from exposure into fresh air.

Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15

minutes. Get medical attention.

SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical

attention if irritation or pain develops or persists. If product is injected under pressure into or

under the skin, or into any part of the body, regardless of the appearance of the wound or its size, a

physician should immediately evaluate the individual as a medical emergency.

INGESTION

(SWALLOWING):

Do NOT induce vomiting. Immediately get medical attention. Call 1-800-844-9457 for additional

information. If spontaneous vomiting occurs, keep head below hips to avoid breathing the product

into the lungs. Never give anything by mouth to an unconscious person.

NOTE TO

PHYSICIANS:

Treat symptomatically and supportively. Treatment may vary with condition of victim and

specifics of incident. Call 1-800-844-9457 for additional information.

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*** SECTION 5: FIRE FIGHTING MEASURES ***

*** SECTION 6: ACCIDENTAL RELEASE MEASURES ***

Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear

protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE

CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering.

Ventilate area and avoid breathing vapor or mist. Contain spill away from surface water and sewers. Contain spill as a liquid

for possible recovery, or absorb with compatible sorbent material and shovel with a clean, sparkproof tool into a sealable

container for disposal.

Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal.

HAZARDOUS COMBUSTION

PRODUCTS:

Decomposition and combustion materials may be toxic. Burning may produce

aldehydes, hydrogen sulfide, alkyl mercaptans, sulfides, carbon monoxide, and

oxides of sulfur, calcium and zinc and other unidentified organic compounds.

CONDITIONS OF FLAMMABILITY: Sparks, or flame. Product may burn, but does not ignite readily.

PROTECTIVE EQUIPMENT FOR

FIREFIGHTERS:

A positive-pressure, self-contained breathing apparatus (SCBA) and full-body

protective equipment are required for fire emergencies.

EXTINGUISHING MEDIA: Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or

foam may cause frothing.

NFPA 704

HAZARD IDENTIFICATION:

This information is intended solely for the use by individuals trained in this

system.

1 0

1

REACTIVITY

(YELLOW)

HEALTH HAZARD

( BLUE)

SPECIFIC

HAZARD

(WHITE)

FIRE

HAZARD

(RED)

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*** SECTION 7: HANDLING AND STORAGE ***

HANDLING: Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe for

such locations should be used. Use clean tools. These products have a low vapor pressure and are

not expected to present an inhalation hazard under normal temperatures and pressures. However,

when aerosolizing, misting, or heating these products, do not breathe vapor or mist. Use in a well-

ventilated area. Avoid contact with eyes, skin, clothing, and shoes.

SHIPPING AND

STORING:

Keep container tightly closed when not in use and during transport. Store containers in a cool, dry

place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away

from flame, sparks, static electricity, or other sources of ignition. Empty product containers may

retain product residue and can be dangerous.

*** SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ***

EXPOSURE GUIDELINES: Component

Exposure Limits

Lubricating oils, petroleum, hydrotreated spent (64742-58-1)

ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral)

10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral)

OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA

Vacated: 5 mg/m3 TWA (related to Oil mist, mineral)

NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral)

10 mg/m3 STEL (related to Oil mist, mineral)

Mineral oil (Not Available)

ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral)

10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral)

OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA

Vacated: 5 mg/m3 TWA (related to Oil mist, mineral)

NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral)


Lubricating oils, (petroleum), C>25, hydrotreated brightstock (72623-83-7)

ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist,

mineral)


FIRE FIGHTING INSTRUCTIONS: Keep storage containers cool with water spray.

FIRE AND EXPLOSION HAZARDS:

Heated containers may rupture. "Empty"

containers may retain residue and can be

dangerous. Products are not sensitive to mechanical

impact or static discharge.

6 | P a g e

OSHA: 5 mg/m3 TWA (related to Oil mist, mineral)

NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral)

10 mg/m3 STEL (related to Oil mist (mineral)

Residual oils (petroleum), hydrotreated (64742-54-7)


mineral)



NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral)

10 mg/m3 STEL (related to Oil mist (mineral) Neutral oil

(72623-86-0)


mineral)



NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral))


Residual oils (petroleum), solvent dewaxed (64742-62-7)

ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10

mg/m3 STEL (related to Oil mist, mineral)


NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral))


ENGINEERING

CONTROLS:

Provide general ventilation needed to maintain concentration of vapor or mist below applicable

exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local

exhaust ventilation, or other engineering controls to control airborne levels below applicable

exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

RESPIRATORY

PROTECTION:

Not normally needed. Use NIOSH-certified P- or R- series particulate filter and organic vapor

cartridges when concentration of vapor or mist exceeds applicable exposure limits. Protection

provided by air purifying respirators is limited. Do not use N-rated respirators. Selection and use of

respiratory protective equipment should be in accordance in the USA with OSHA General Industry

Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4.

EYE

PROTECTION:

Where eye contact is likely, wear chemical goggles; contact lens use is not recommended.

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SKIN

PROTECTION:

Where skin contact is likely, wear neoprene, nitrile or equivalent protective gloves; use of natural

rubber or equivalent gloves is not recommended.

When products are heated and skin contact is likely, wear heat-insulating, gloves, boots, and other

protective clothing.

To avoid prolonged or repeated contact where spills and splashes are likely, wear appropriate

chemical-resistant faceshield, boots, apron, coveralls, long sleeve shirts, or other protective clothing.

PERSONAL

HYGIENE:

Use good personal hygiene. Wash thoroughly with soap and water after handling product and before

eating, drinking, or using tobacco products. Clean affected clothing, shoes, and protective equipment

before reuse. Discard leather articles, such as shoes, saturated with these products.

OTHER

PROTECTIVE

EQUIPMENT:

Where spills and splashes are likely, facilities storing or using these products should be equipped with

an emergency eyewash and shower, both equipped with clean water, in the immediate work area.

*** SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES ***

PHYSICAL STATE,

APPEARANCE, AND ODOR: Liquid, amber, petroleum odor.

ODOR THRESHOLD: Not available

MOLECULAR WEIGHT: Not applicable

SPECIFIC GRAVITY: 0.88 (water = 1) (approximately)

DENSITY: 7.3 LB/US gal (880 g/l) (approximately)

VAPOR DENSITY: Not available

VAPOR PRESSURE: less than 0.1 mmHg at 68ºF (20ºC)

BOILING POINT: 475ºF (246ºC) (minimum)

FREEZING/MELTING POINT: Not available [pour point 0ºF (-18ºC) (maximum)].

pH: Not available.

EVAPORATION RATE: Not available

SOLUBILITY IN WATER: Insoluble

FLASH POINT: 383ºF (195ºC) (minimum) Cleveland Open Cup

FLAMMABLE LIMITS IN AIR:

LOWER: Not available UPPER: Not available

AUTOIGNITION TEMPERATURE: Not available

*** SECTION 10: STABILITY AND REACTIVITY ***

STABILITY: Stable under normal temperatures and pressures.

CONDITIONS TO

AVOID:

Avoid sparks or flame when not in use.

INCOMPATIBILITY: Avoid oxidizing agents, acids and reactive halogens.

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REACTIVITY: Polymerization is not known to occur under normal temperature and pressures. Not reactive

with water.

HAZARDOUS

DECOMPOSITION

PRODUCTS:

None under normal temperatures and pressures. See also SECTION 5:

HAZARDOUS COMBUSTION PRODUCTS.

*** SECTION 11: TOXICOLOGICAL INFORMATION ***

TOXICITY DATA:

Component Analysis - LD50/LC50


Oral LD50 Rat >2000 mg/kg

Dermal LD50 Rat >2000 mg/kg

Dermal LD50 Rabbit >4480 mg/kg


Inhalation LC50 Rat: 2.18 mg/L/4H

Oral LD50 Rat:>5000 mg/kg

Dermal LD50 Rabbit:>2000 mg/kg

Lubricating oils (petroleum), C>25, hydrotreated bright stock (72623-83-7) Oral LD50

Rat:>5000 mg/kg

Residual oils (petroleum), hydrotreated (64742-54-7)


Oral LD50 Rat: >2000 mg/kg

Dermal LD50 Rabbit: >2000 mg/kg

Lubricating oils, petroleum, C15-30, hydrotreated neutral oil-based (72623-86-0)


Oral LD50 Rat: >5000 mg/kg

Dermal LD50 Rabbit: >2000 mg/kg

Residual oils (petroleum), solvent refined (64742-01-4)


Oral LD50 Rat:>5000 mg/kg

Dermal LD50 Rabbit:>2000 mg/kg

Mineral oil (Not Available)

Oral LD50 Mouse 22 g/kg (related to Oil mist, mineral)

ACUTE EFFECTS: These products are not likely to present an inhalation hazard at normal

temperatures and pressures. However, when aerosolizing, misting, or heating

these products, high concentrations of generated vapor or mist may irritate the

respiratory tract (nose, throat, and lungs). May cause eye and skin irritation. Not

likely to be absorbed through the skin in harmful amounts. May be harmful if

swallowed. May cause throat irritation, nausea, vomiting, and diarrhea.

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REPEATED DOSE EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue

inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact

may cause inflammation of the membrane lining the eyelids and covering the

eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying,

cracking, redness, itching, and/or swelling (dermatitis).

Experimental evidence suggests that these products do not cause mutagenesis.

Based on best current information, there is no known sensitization, reproductive

toxicity, or teratogenicity associated with these products.

CARCINOGENICITY: Based on best current information, there is no known carcinogenicity as

categorized by ACGIH A1 or A2 substances; as categorized by IARC Group 1,

Group 2A, or Group 2B agents; or as listed by NTP as either known

carcinogens or substances for which there is limited evidence of

carcinogenicity in humans or sufficient evidence of carcinogenicity in

experimental animals.

Also see SECTION 15: CALIFORNIA.

TARGET ORGAN EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung

tissue inflammation, and/or fibrous tissue formation.

*** SECTION 12: ECOLOGICAL INFORMATION ***

ECOTOXICITY: No information available for the product.

Component Analysis - Ecotoxicity - Aquatic Toxicity


Test & Species Results Conditions

96 Hr LC50 Brachydanio rerio 79.6 mg/L semi-static

96 Hr LC50 Pimephales promelas 3.2 mg/L semi-static



96 Hr LC50 Oncorhynchus mykiss >5000 mg/L



96 Hr LC50 Pimephales promelas >5000 mg/L

Lubricating oils, petroleum, C>25. hydrotreated bright stock (72623-83-7)

Test & Species Conditions

96 Hr LC50 Lepomis macrochirus >10000 mg/L



96 Hr LC50 Oncorhynchus mykill >5000 mg/L

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3)

10 | P a g e


96 Hr LC50 Pimephales promelas 1-5 mg/L static

Residual oils (petroleum), solvent refined (64742-01-4)


96 Hr LC50 Oncorhynchus >5000 mg/L mykiss

Petroleum distillates, hydrotreated heavy paraffinic (64742-54-7)


96 Hr LC50 Pimephales promelas >5000

PERSISTENCE/ DEGRADABILITY:

No information available.

BIOACCUMULATION/ ACCUMULATION:

No information available.

MOBILITY IN

ENVIRONMENTAL MEDIA: No information available.

OTHER ADVERSE EFFECTS: Not available.

OCTANOL/WATER Not available PARTITION COEFFICIENT:

VOLATILE ORGANIC Negligible.

COMPOUNDS:

*** SECTION 13: DISPOSAL CONSIDERATIONS ***

DISPOSAL: Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also

apply to empty containers. The responsibility for proper waste disposal lies with the owner of the

waste. Contact Safety-Kleen regarding proper recycling or disposal.

USEPA WASTE

CODE(S):

These products, if discarded, are not expected to be a characteristic or listed hazardous waste. If

recycled in the USA, they must be managed in accordance with 40 CFR Part 279. Processing, use, or

contamination by the user may change the waste code(s) applicable to the disposal of these products.

*** SECTION 14: TRANSPORT INFORMATION ***

DOT: Shipping Name: Not regulated

TDG: Shipping Name: Not regulated

EMERGENCY RESPONSE GUIDE Not applicable.

NUMBER: Reference North American Emergency Response Guidebook

*** SECTION 15: REGULATORY INFORMATION ***

USA REGULATIONS

11 | P a g e

OSHA OSHA Regulated Chemicals

No information is available.

SARA SECTIONS 302

AND 304:

Based on the ingredient listed in SECTION 3, this product does not contain any

"extremely hazardous substances" listed pursuant to Title III of the Superfund

Amendments and Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified

in 40 CFR Part 355, Appendix A and B.

SARA SECTIONS 311

AND 312:

These products pose the following health hazard(s) as defined in 40 CFR Part 370 and are subject

to the requirements of sections 311 and 312 of Title III of the Superfund Amendments and

Reauthorization Act of 1986 (SARA):

Immediate (Acute) Health Hazard

Delayed (Chronic) Health Hazard

SARA SECTION 313: These products contain "toxic" chemical(s) subject to the requirements of section 313 of Title III

of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372.

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-4203)

1.0% de minimis concentration (Chemical Category N982) (related to Zinc compounds)

CERCLA: Based on the ingredient(s) listed in SECTION 3, this product does not contain any "hazardous

substances" listed pursuant to the Comprehensive Environmental Response, Compensation and

Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.

TSCA: All the components of this product are listed on, or are exempted from the requirement to be

listed on, the TSCA Inventory.

CALIFORNIA: This product does not contain detectable amounts of any chemical known to the State of

California to cause cancer.

This product does not contain detectable amounts of any chemical known to the state of

California to cause birth defects or other reproductive harm.

CANADIAN REGULATIONS

These products have been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and

the MSDS contains all information required by the CPR.

CANADIAN The components of this product are listed on, or are exempted from the requirements to

ENVIRONMENTAL be listed on, the Canadian Domestic Substances List (DSL).

PROTECTION ACT

(CEPA):

12 | P a g e

*** SECTION 16. OTHER INFORMATION ***

REVISION INFORMATION: This MSDS has been revised in the following sections:

Section 1, (Address, Date); Section 7 (Handling)

LABEL/OTHER INFORMATION: Not available

User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information contained herein is accurate. However,

BOSS Lubricants assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representations or warranties,

either express or implied, or merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the

product to which information refers. The data contained on this sheet apply to the product(s) as supplied to the user.

Calumet Lantern Fuel

0170-00-V

Petrochemical industry: Petroleum refining. Solvent.

Calumet Specialty Products Partners, L.P.2780 Waterfront Pkwy E. Dr.Suite 200Indianapolis, Indiana 46214 USATechnical Services: 317-328-5660

24hr. CHEMTREC 1-800-424-9300 / International 1-703-527-3887

Material Safety Data Sheet

Product name

Supplier

Material uses

Product code

Validation date

In case of emergency

1. Product and company identification


:

:

:

:

:

:

Product type : Liquid.

2/28/2014.

Version : 1

Signal word


Routes of entry

Potential acute health effects

Can cause central nervous system (CNS) depression. Irritating to respiratory system.

Irritating to eyes.

Can cause central nervous system (CNS) depression. Aspiration hazard if swallowed.Can enter lungs and cause damage.

Irritating to skin.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid. [Mobile liquid.]

See toxicological information (Section 11)

DANGER!

EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH FIRE. INHALATION CAUSES HEADACHES, DIZZINESS,DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

:

:

:

:

:

:

:

Odor : Characteristic. Hydrocarbon.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Color : Clear. Colorless to light yellow.

Emergency overview

Hazard statements :

Precautionary measures : Do not breathe vapor or mist. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep away from heat, sparks and flame. Keep container tightly closed. Wash thoroughly after handling.

Eyes, Skin, Ingestion, Inhalation

1/102/28/2014. 0170-00-V


Distillates (petroleum), light distillate hydrotreating process, low-boiling 68410-97-9 60 - 70isopentane 78-78-4 5 - 10pentane 109-66-0 5 - 10cyclohexane 110-82-7 5 - 10Distillates (petroleum), hydrotreated light 64742-47-8 1 - 5

3. Composition/information on ingredients

Name CAS number % by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.

4. First aid measuresEye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Use dry chemical, CO₂, water spray (fog) or foam.

5. Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

Hazardous thermal decomposition products

: Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Flammability of the product :

2/102/28/2014. 0170-00-V


No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Environmental precautions

6. Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Personal precautions :

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods for cleaning up

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking.Remove contaminated clothing and protective equipment before entering eating areas.Do not breathe vapor or mist. Do not swallow. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

7. Handling and storageHandling

Storage

:

:

8. Exposure controls/personal protection

3/102/28/2014. 0170-00-V


8. Exposure controls/personal protection

Distillates (petroleum), light distillate hydrotreating process, low-boiling

ACGIH TLV (United States). TWA: 200 ppm 8 hours.

isopentane ACGIH TLV (United States, 3/2012). TWA: 600 ppm 8 hours.

pentane ACGIH TLV (United States, 3/2012). TWA: 600 ppm 8 hours.OSHA PEL (United States, 6/2010). TWA: 1000 ppm 8 hours. TWA: 2950 mg/m³ 8 hours.

cyclohexane ACGIH TLV (United States, 3/2012). TWA: 100 ppm 8 hours.OSHA PEL (United States, 6/2010). TWA: 300 ppm 8 hours. TWA: 1050 mg/m³ 8 hours.

Distillates (petroleum), hydrotreated light ACGIH TLV (United States). TWA: 200 ppm 8 hours.

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.When there is a risk of ignition from static electricity, wear anti-static protective clothing.For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Personal protection

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Recommended monitoring procedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards.Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Ingredient Exposure limits

4/102/28/2014. 0170-00-V


8. Exposure controls/personal protectionEnvironmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

37.778 to 176.67°C (100 to 350°F)

Liquid. [Mobile liquid.]

0.715

Insoluble in the following materials: cold water and hot water.

Characteristic. Hydrocarbon.

Clear. Colorless to light yellow.

Boiling/condensation point

Kinematic (40°C (104°F)): <0.1 cm2/s (<10 cSt)

9. Physical and chemical propertiesPhysical state

Relative density

Viscosity

Solubility

Odor

Color

:

:

:

:

:

:

:

Flash point : Closed cup: <-18°C (<-0.4°F) [Tagliabue.]

66.3:API Gravity @60°F

The product is stable.

Highly reactive or incompatible with the following materials:oxidizing materials

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

10. Stability and reactivityChemical stability

Conditions to avoid

Incompatible materials

Hazardous decomposition products

:

:

:

:

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

11. Toxicological informationAcute toxicity

Distillates (petroleum), light distillate hydrotreating process, low-boiling

LC50 Inhalation Vapor Rat >7.63 mg/l 4 hours

LD50 Dermal Rabbit >2000 mg/kg -LD50 Oral Rat 5170 mg/kg -

isopentane LC50 Inhalation Vapor Rat 280000 mg/m³ 4 hourspentane LC50 Inhalation Vapor Rat 364 g/m³ 4 hoursDistillates (petroleum),hydrotreated light

LD50 Dermal Rabbit >2000 mg/kg -

LD50 Oral Rat >5000 mg/kg -cyclohexane LD50 Dermal Rabbit >180000 mg/kg -

LD50 Oral Rat 6240 mg/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Not available.

Chronic toxicity


Carcinogenicity


Mutagenicity


5/102/28/2014. 0170-00-V


11. Toxicological informationTeratogenicity


Reproductive toxicity


12. Ecological informationEcotoxicity : No known significant effects or critical hazards.

Aquatic ecotoxicity

cyclohexane Acute LC50 4530 µg/l Fresh water Fish - Pimephales promelas 96 hours

Product/ingredient name SpeciesResult Exposure


Persistence/degradability


The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Waste disposal

13. Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

RCRA classification : D001 [Flammable]

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

14. Transport informationRegulatory information

UN number Proper shipping name

Classes PG* Label Additional information

6/102/28/2014. 0170-00-V


14. Transport information3 Reportable quantity

11086.5 lbs / 5033.3 kg [1859.6 gal / 7039.5 L]Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity)transportation requirements.

Limited quantityYes.

Packaging instructionPassenger aircraftQuantity limitation: 5 L

Cargo aircraftQuantity limitation: 60 L

Special provisions144, IB2, T7, TP1,TP8, TP28

DOT Classification Petroleum distillates,n.o.s. RQ(Cyclohexane)

II

IMDG Class PETROLEUM DISTILLATES, N.O.S.

3 II

Petroleum distillates,n.o.s.

UN1268IATA-DGR Class 3 II

UN1268 Emergency schedules (EmS)F-E, S-E

Passenger and Cargo AircraftQuantity limitation: 5 LPackaging instructions: 353Cargo Aircraft OnlyQuantity limitation: 60 LPackaging instructions: 364Limited Quantities -Passenger AircraftQuantity limitation: 1 LPackaging instructions: Y341

UN1268

PG* : Packing group

7/102/28/2014. 0170-00-V


Flammable liquidIrritating materialTarget organ effects

HCS Classification

15. Regulatory information

U.S. Federal regulations

The following components are listed: CYCLOHEXANE; ISOPENTANE; PENTANE

WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer.WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.

Clean Water Act (CWA) 307: benzene

Clean Water Act (CWA) 311: cyclohexane; benzene

Clean Air Act (CAA) 112 regulated flammable substances: isopentane; pentane

Massachusetts

SARA 302/304: No products were found.SARA 311/312 Hazards identification: Fire hazard, Immediate (acute) health hazard,Delayed (chronic) health hazard

:

:

SARA 313

:

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

benzene Yes. Yes. 6.4 µg/day (ingestion)13 µg/day (inhalation)

24 µg/day (ingestion)49 µg/day (inhalation)

Ingredient name Cancer Reproductive No significant risk level

Maximum acceptable dosage level

cyclohexane 110-82-7 5 - 10

cyclohexane 110-82-7 5 - 10

Form R - Reporting requirements

Supplier notification

California Prop. 65

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

: Not listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

New York : The following components are listed: Cyclohexane; Benzene, hexahydro-

New Jersey : The following components are listed: CYCLOHEXANE; ISOPENTANE; BUTANE,2-METHYL-; PENTANE

Pennsylvania : The following components are listed: CYCLOHEXANE; BUTANE, 2-METHYL-;PENTANE

State regulations

TSCA 8(a) PAIR: pentane

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

8/102/28/2014. 0170-00-V


15. Regulatory information

The following components are listed: Cyclohexane; Pentane (all isomers); Pentane (all isomers); Hydrotreated light distillate

Australia inventory (AICS): All components are listed or exempted.China inventory (IECSC): All components are listed or exempted.Japan inventory: Not determined.Korea inventory: All components are listed or exempted.Malaysia Inventory (EHS Register): Not determined.New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.Philippines inventory (PICCS): All components are listed or exempted.Taiwan inventory (CSNN): Not determined.

WHMIS (Canada) Class B-2: Flammable liquidClass D-2B: Material causing other toxic effects (Toxic).

International regulations

International lists :

Canada

Canadian NPRI

CANADA INVENTORY (DSL)

: All components are listed or exempted.

Chemical Weapons Convention List Schedule I Chemicals

: Not listed

Chemical Weapons Convention List Schedule II Chemicals

: Not listed

Chemical Weapons Convention List Schedule III Chemicals

: Not listed

CEPA Toxic substances None of the components are listed.

Canadian lists

Europe inventory (EINECS)

: All components are listed or exempted.

16. Other information

Hazardous Material Information System (U.S.A.)

2

3

0

Health

Flammability

Physical hazards

EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH FIRE. INHALATION CAUSES HEADACHES, DIZZINESS,DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

Label requirements :

Date of issue :

:

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

2/28/2014.

9/102/28/2014. 0170-00-V


16. Other information

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Date of previous issue

Version :

:

Indicates information that has changed from previously issued version.

No previous validation.

1

Prepared by : Technical Department

10/102/28/2014. 0170-00-V


Section 1 Product Information

Product Name/Identifier: C-THRU Liquid Glass Cleaner Concentrate

Manufactured For: Chatterson Janitorial Supplies, 2810 Dewdney, Regina, SK. S4T 0X7

Product Use: Glass, mirror, countertops, and enamelled surface cleaner

Section 2 Hazardous Ingredients

Chemical Name Concentration % CAS and Product ID

Number50 50LD LC

Methyl Alcohol 7 - 15 67-56-1 Oral (Rat) 6200 mg/kg

Not available

Isopropyl Alcohol 3 - 15 67-63-0 Oral (Rat) 4720 mg/kg

Not available

Section 3 Physical Data

Physical State: Liquid Odour and Appearance: Clear blue liquid, scented

Odour threshold: Not Available Specific Gravity: 0.970 @ 25º C Water = 1

Vapour Pressure: Not Available Vapour Density (Air=1): Not Available

Evaporation Rate(Water=1):

Not Available Boiling Point: 100º C Melting Point: N/A

pH: 7.5 (basic) Coefficient of Water/Oil Distribution: Not Available

Section 4 Fire and Explosion Hazard

Flammability: Yes Means of Extinction: Water, Fog, Foam, Dry Chemical

Flash Point (°C)and Method of Determination: 55 COC

Upper Flammable Limit (% byvolume):

Not Available Lower Flammable Limit (% byvolume):

Not Available

Auto Ignition Temperature (0ºC): Not Available Hazardous Combustion Products: Not Available

Explosion Data-Sensitivity to Mechanical Impact: Not Available

Sensitivity to Static Discharge: Not Available

Section 5 Reactivity Data

Chemical Stability: This product is stable Compatibility to Other Substances: Not Available

Conditions of Reactivity: Not available Hazardous Decomposition Products: Not available

NOTICEChatterson Janitorial Supplies and the manufacturer expressly disclaims any injury, damage or death because of theimproper use of this product. The proper use of this product is described on the label of the container.

ChattersonJANITORIAL SUPPLIES

Section 6 Toxicological Properties

Route of Entry: / Skin Contact: Slight irritant / Skin Absorption: Not Applicable

/ Eye Contact: Slight Irritant / Inhalation: Not Applicable

/ Ingestion: Slightly toxic

Exposure Limits: Not Available Irritancy of Products: Slight

Sensitization to Product: Not Available Synergistic Products: Not Available

Carcinogenicity, Reproductive Toxicity, Teratogenicity, Mutagenicity: Not Available

Section 7 Preventative Measures

Personal Protective / Gloves: No / Respiratory: No

Equipment : / Eyes: No / Clothing: No

/ Footwear: No

Engineering Controls: General ventilation normally adequate

Leak and Spill

Procedure:Mop up spillage. Rinse spill area with water and allow to dry.

Waste Disposal: Flush with water into waste systems in accordance with municipal, provincial, and federalregulations.

Storage and HandlingRequirements:

Normal handling processes. Inside storage at 1-40º C recommended.

Special ShippingInformation:

Not Regulated

Section 8 First Aid Measures

Eyes: Flush with water. If irritation persists, call a physician.

Skin: Flush with water. If irritation persists, call a physician.

Inhalation: Not applicable.

Ingestion: Do not induce vomiting. Drink 3 - 4 glasses of milk or water. Call a physician immediately.

Section 9 Preparation Information

Prepared by: A. Taylor Telephone: 306 - 525 - 3568 Date: February 03, 2014

NOTICEChatterson Janitorial Supplies and the manufacturer expressly disclaims any injury, damage or death because of theimproper use of this product. The proper use of this product is described on the label of the container.


1. Product and Company Identification

Material name D-MO

Version # 02

Issue date 01-04-2012

Revision date 11-13-2012

Supersedes date 01-04-2012

CAS # Mixture

Product code 189

Product use Lubrication oil.

Synonym(s) SAE 10W, 20W-20, 30, 40, 50, Sonic D-MO

Manufacturer information

Manufacturer Consumers' Co-operative Refineries Limited

Address P.O. Box 260; 9th Avenue North

Regina, SK S4P 3A1 Canada

Telephone (306) 721-5353

Supplier Federated Co-operatives Limited

Address P.O. Box 1050, 401 - 22nd Street East

Saskatoon SK S7K 3M9 Canada

Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec

2. Hazards Identification

Physical state Liquid.

Appearance Oily liquid.

Emergency overview WARNING

Causes skin and eye irritation.

OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.

Potential health effects

Routes of exposure Eye contact. Skin contact. Ingestion. Inhalation.

Eyes Causes eye irritation.

Skin Causes skin irritation.

Inhalation May cause respiratory tract irritation.

Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Chronic effects No data available.

Potential environmental effects No special environmental precautions required.

Components CAS # Percent


68649-42-3 1-5Zinc Alkyldithiophosphate

4. First Aid Measures

First aid procedures

Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptomsoccur.

CPH MSDS NA

1 / 5

D-MO CPH MSDS NA

906163 Version #: 02 Revision date: 11-13-2012 Issue date: 01-04-2012

Skin contact In case of contact, flush skin with plenty of water for at least 20 minutes, while removingcontaminated shoes and clothes. Wash contaminated skin with soap and water. Washcontaminated clothing before reuse. Thoroughly clean shoes before reuse. Get medical attentionif irritation develops and persists.

Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.

Notes to physician Treat symptomatically.

General advice If you feel unwell, seek medical advice (show the label where possible).


Extinguishing media

Suitable extinguishing

mediaExtinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.

Unsuitable extinguishing

mediaNone.

Protection of firefighters

Specific hazards arising

from the chemicalBy heating and fire, toxic vapors/gases may be formed.

Fire fighting

equipment/instructionsFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

Hazardous combustion

productsNo data available.


Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.

Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a widearea (e.g. by containment or oil barriers).

Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.

Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.

Other information Clean up in accordance with all applicable regulations.


Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.

Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.


Occupational exposure limits No exposure limits noted for ingredient(s).

Engineering controls General ventilation is normally adequate.

Personal protective equipment

Eye / face protection Wear approved safety glasses or goggles.

Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.Neoprene or nitrile gloves are recommended.

Respiratory protection No personal respiratory protective equipment normally required.

General hygiene

considerationsHandle in accordance with good industrial hygiene and safety practices.

9. Physical & Chemical Properties



Form Liquid.

Color Brown.

Odor Mild.

Odor threshold Not available.

CPH MSDS NA

2 / 5

D-MO CPH MSDS NA


pH Not available.

Vapor pressure Not available.

Vapor density Not available.

Boiling point Not available.

Melting point/Freezing point -4 °F (-20 °C)

Solubility (water) Slight

Specific gravity 0.88 - 0.89

Flash point > 296.6 °F (> 147 °C) Open Cup

Flammability limits in air,

upper, % by volume

Not available.


lower, % by volume

Not available.

Auto-ignition temperature 775.4 °F (413 °C)

10. Chemical Stability & Reactivity Information

Chemical stability Material is stable under normal conditions.

Conditions to avoid Contact with incompatible materials.

Incompatible materials Strong oxidizing agents.

Hazardous decomposition

productsNone expected under normal conditions of use.

Possibility of hazardous

reactionsWill not occur.


Sensitization No data available.

Acute effects Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Local effects Causes skin and eye irritation.

Chronic effects Chronic effects are not expected when this product is used as intended.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

Mutagenicity Not expected to be mutagenic.

Neurological effects No data available.

Reproductive effects Contains no ingredient listed as toxic to reproduction.

Teratogenicity Not classified.


Ecotoxicity No data on possible environmental effects have been found.

Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulation /

AccumulationNot available.


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.

Waste from residues / unused

productsDispose of waste and residues in accordance with local authority requirements.

Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.

14. Transport Information

DOT

Not regulated as a hazardous material by DOT.

CPH MSDS NA

3 / 5

D-MO CPH MSDS NA


IATA

Not regulated as dangerous goods.

IMDG


TDG



US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration

Zinc Alkyldithiophosphate (CAS 68649-42-3) 1.0 % N982

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance

Zinc Alkyldithiophosphate (CAS 68649-42-3) N982 Listed.

CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)

None

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

Section 302 extremely

hazardous substance (40

CFR 355, Appendix A)

No

Section 311/312 (40 CFR

370)No

Drug Enforcement

Administration (DEA) (21 CFR

1308.11-15)

Not controlled

Canadian regulations Canadian NPRI: The following components are listed: Zinc.

WHMIS status Controlled

WHMIS classification D2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory status

Country(s) or region Inventory name On inventory (yes/no)*

Australian Inventory of Chemical Substances (AICS) YesAustralia

Domestic Substances List (DSL) YesCanada

Non-Domestic Substances List (NDSL) NoCanada

Inventory of Existing Chemical Substances in China (IECSC) YesChina

European Inventory of Existing Commercial ChemicalSubstances (EINECS)

YesEurope

European List of Notified Chemical Substances (ELINCS) NoEurope

Inventory of Existing and New Chemical Substances (ENCS) NoJapan

Existing Chemicals List (ECL) YesKorea

CPH MSDS NA

4 / 5

D-MO CPH MSDS NA



New Zealand Inventory YesNew Zealand

Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesPhilippines

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)

Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico

State regulations

US - California Hazardous Substances (Director's): Listed substance

Zinc Alkyldithiophosphate (CAS 68649-42-3) Listed.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance

Not listed.

US - New Jersey RTK - Substances: Listed substance


US. Massachusetts RTK - Substance List

Not regulated.

US. New Jersey Worker and Community Right-to-Know Act

Zinc Alkyldithiophosphate (CAS 68649-42-3) 500 LBS

US. Pennsylvania RTK - Hazardous Substances

Not regulated.


Further information HMIS® is a registered trade and service mark of the NPCA.

HMIS® ratings Health: 2Flammability: 1Physical hazard: 0Personal protection: X

NFPA ratings Health: 2Flammability: 1Instability: 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.

CPH MSDS NA

5 / 5

D-MO CPH MSDS NA




Material name Diesel/Bio-diesel/Distillate

Version # 04




CAS # Mixture

Product code 2181

Product use Fuel. Refinery feedstock.

Synonym(s) Premium Diesel, EP 3000, Railroad Diesel, Seasonal Diesel, Premium Mine Diesel, Mine Diesel,Summer Diesel, Winter Diesel, Dyed (Purple) Diesel, Export Diesel, Electric Generating Diesel,ARDS Light Distillate, ARDS Heavy Distillate/Diesel, Crude Straight run Diesel, MDUUnifinate/Diesel, CAT light Cycle oil, Low Pour Distillate, High Pour Diesel, #2 Fuel Oil.





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec

Telephone Number: (306) 244-3447

Emergency telephone (613) 996-6666

Federated Co-operatives Ltd.Supplier

P.O. Box 1050

401 - 22nd Street East

Saskatoon

S7K 3M9

CA



Emergency overview WARNING! Combustible liquid and vapor. Aspiration hazard: Harmful if swallowed - may enterlungs if swallowed or vomited. High vapor concentrations may cause drowsiness and irritation ofthe eyes or respiratory tract. Prolonged or repeated skin contact may cause drying, cracking, orirritation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.



Routes of exposure Ingestion. Eye contact. Inhalation. Skin contact.

Eyes May cause eye irritation. Contact may cause irritation with redness, tearing, pain, and/or blurredvision.

Skin Prolonged or repeated contact may dry skin and cause irritation.

Inhalation Vapors may cause headache, fatigue, dizziness and nausea. May cause central nervous systemeffects.

Ingestion Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungs must be avoided aseven small quantities may result in aspiration pneumonitis.

Potential environmental effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

CPH MSDS NA

1 / 7

Diesel/Bio-diesel/Distillate CPH MSDS NA




68334-30-5 95 - 100Fuels, diesel

129828-16-6 0 - 5Canola Oil - Fatty Acid Methyl Ester

73891-99-3 0 - 5Rapeseed Oil - Fatty Acid Methyl Ester

67784-80-9 0 - 5Soy Methyl Esters from Vegetable Oil



Eye contact Immediately flush with plenty of water for at least 15 minutes. Remove any contact lenses. Getmedical attention immediately.

Skin contact Remove contaminated clothing. Wash with soap and water. Get medical attention if irritationdevelops and persists. Wash contaminated clothing before reuse. Destroy or thoroughly cleancontaminated shoes.

Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention immediately!

Ingestion Rinse mouth thoroughly with water and give large amounts of milk or water to people notunconscious. DO NOT induce vomiting because of danger of aspirating liquid into lungs. Call aphysician or poison control center. If vomiting occurs naturally, have victim lean forward to reducerisk of aspiration. Never give anything by mouth to an unconscious person.

Notes to physician Treat symptomatically. The effects might be delayed.

General advice Get medical attention if any discomfort develops.


Flammable properties The product is combustible, and heating may generate vapors which may form explosive vapor/airmixtures. Material will float and can be re-ignited on surface of water.

Extinguishing media


mediaCarbon dioxide, regular foam, dry chemical, water spray, or water fog.


mediaDo not use water jet as an extinguisher, as this will spread the fire.



from the chemicalVapors may form explosive mixtures with air. Vapors are heavier than air and may travel along thefloor and in the bottom of containers. Vapors may be ignited by a spark, a hot surface or anember.

Protective equipment and

precautions for firefightersSelf-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting

equipment/instructionsMove containers from fire area if you can do it without risk. Use water spray to cool unopenedcontainers. Cool containers with flooding quantities of water until well after fire is out.


productsCarbon monoxide and carbon dioxide.


Personal precautions Stay upwind. Ventilate closed spaces before entering them. Wear suitable protective clothing,gloves and eye/face protection. For personal protection, see section 8 of the MSDS.

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. bycontainment or oil barriers). Do not contaminate water. Contact local authorities in case of spillageto drain/aquatic environment.

Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Prevententry into waterways, sewer, basements or confined areas.

CPH MSDS NA

2 / 7



Methods for cleaning up Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.

Small Spills: Absorb spillage with non-combustible, absorbent material.

Large Spills: Remove with vacuum trucks or pump to storage/salvage vessels. Use anon-combustible material like vermiculite, sand or earth to soak up the product and place into acontainer for later disposal. Wash area with soap and water. Ensure that waste and contaminatedmaterials are collected and removed from the work area as soon as possible in a suitably labeledcontainer.


Handling Access to work area should be restricted to people handling the product only. Should be handledin closed systems, if possible. Avoid contact with eyes, skin, and clothing. Avoid inhalation ofvapors. Wear appropriate personal protective equipment. Ground container and transferequipment to eliminate static electric sparks. The product is a combustible liquid. Take thenecessary precautionary measures. Vapors are heavier than air and may travel along the floorand in the bottom of containers. Immediately change contaminated clothes. Do not eat, drink orsmoke when using the product. Be aware of potential for surfaces to become slippery. Observegood industrial hygiene practices.

Storage Keep away from heat, sparks and open flame. Keep in a cool, well-ventilated place. Keep awayfrom food, drink and animal feeding stuffs. Store away from incompatible materials.


Occupational exposure limits

US. ACGIH Threshold Limit Values

ValueType FormComponents

TWA 100 mg/m3 Inhalable fraction andvapor.

Fuels, diesel (CAS68334-30-5)

Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

ValueTypeComponents

TWA 100 mg/m3Fuels, diesel (CAS68334-30-5)

Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and

Safety Regulation 296/97, as amended)


TWA 100 mg/m3 Vapor and aerosol.Fuels, diesel (CAS68334-30-5)

Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)


TWA 100 mg/m3 Inhalable fraction andvapor.

Fuels, diesel (CAS68334-30-5)

Engineering controls Provide adequate ventilation and minimize the risk of inhalation of vapors and oil mist. Provideeasy access to water supply and eye wash facilities. Use explosion-proof equipment.


Eye / face protection Wear approved safety goggles.

Skin protection Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.Contact glove manufacturer for specific information.

Respiratory protection Do not breathe mist or vapor. In case of inadequate ventilation or risk of inhalation of vapors, usesuitable respiratory equipment. Wear NIOSH approved respirator appropriate for airborneexposure at the point of use.

General hygiene

considerationsDo not eat, drink or smoke when using the product. Wash hands after handling. Laundercontaminated clothing before reuse. Handle in accordance with good industrial hygiene and safetypractices.


Appearance Not available.


Form Not available.

CPH MSDS NA

3 / 7



Color Straw.

Odor Hydrocarbon-like.


pH Not Applicable

Vapor pressure < 2 psia


Boiling point 300.2 - 752 °F (149 - 400 °C)

Melting point/Freezing point Not Applicable

Solubility (water) Insoluble

Specific gravity 0.839 - 0.887 @ 15.6 °C

Flash point > 104 °F (> 40 °C) Pensky-Martens Closed Cup


upper, % by volume

7.6 %


lower, % by volume

0.6 %

Auto-ignition temperature Not available.

Viscosity 1 - 10 cSt @ 40 °C

Other data

Flash point class Combustible II

Structural formula ( Water = 1)


Chemical stability Stable under normal storage and handling conditions.

Conditions to avoid Heat, sparks, flames, elevated temperatures. Contact with incompatible materials. Do notpressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks,static electricity, or other sources of ignition; they may explode and cause injury or death.

Incompatible materials Strong acids. Strong oxidizing agents.


productsThermal decomposition or combustion may liberate carbon oxides and other toxic gases orvapors.


reactionsPolymerization will not occur. No dangerous reaction known under conditions of normal use.


Sensitization May cause eczema-like skin disorders (dermatitis).

Acute effects Swallowing or vomiting of the liquid may result in aspiration into the lungs. Breathing of highconcentrations may cause dizziness, light-headedness, headache, nausea and loss ofcoordination. Continued inhalation may result in unconsciousness.

Local effects Prolonged or repeated contact may dry skin and cause irritation.


Fuels, diesel (CAS 68334-30-5) Can be absorbed through the skin.

Chronic effects Prolonged or repeated contact with skin may cause redness, itching, irritation, eczema/chappingand oil acne.

Carcinogenicity IARC, NTP and OSHA: Not listed.

ACGIH Carcinogens

Fuels, diesel (CAS 68334-30-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.

Epidemiology Pre-existing skin conditions including dermatitis might be aggravated by exposure to this product.

Mutagenicity Knowledge about mutagenicity is incomplete.

Reproductive effects Knowledge about reproductive effects is incomplete.

Further information Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.


Ecotoxicity Oil spills are generally hazardous to the environment.

CPH MSDS NA

4 / 7



Environmental effects The product contains volatile organic compounds which have a photochemical ozone creationpotential.

Persistence and degradability The degradability of the product has not been stated.

Bioaccumulation /

AccumulationNo data available on bioaccumulation.

Mobility in environmental

mediaThe product is insoluble in water. It will spread on the water surface while some of thecomponents will eventually sediment in water systems. The volatile components of the product willspread in the atmosphere.


Disposal instructions Disposal of this product, solutions, or containers must at all times comply with the requirements ofthe environmental protection and waste disposal legislation and any regional local authorityrequirements.


productsThe generation of waste should be avoided or minimized wherever possible. Empty containers orliners may retain some product residues. This material and its container must be disposed of in asafe manner (see: Disposal instructions).


DOT

UN1202UN number

Basic shipping requirements:

Diesel FuelProper shipping name

Combustible LiquidHazard class

IIIPacking group

144, B1, IB3, T2, TP1Special provisions

Additional information:

150Packaging exceptions

203Packaging non bulk

242Packaging bulk

IATA

UN1202UN number

Diesel FuelUN proper shipping name

3Transport hazard class(es)

IIIPacking group

3LERG code

IMDG

UN1202UN number

Diesel FuelUN proper shipping name


IIIPacking group

F-E, S-EEmS

TDG

Diesel FuelProper shipping name

3Hazard class

UN1202UN number

IIIPacking group


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.


Not regulated.


None

CPH MSDS NA

5 / 7




Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No




No


370)No

Drug Enforcement


1308.11-15)

Not controlled

Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.


WHMIS classification B3 - Combustible LiquidsD2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory status


Australian Inventory of Chemical Substances (AICS) NoAustralia





NoEurope



Existing Chemicals List (ECL) NoKorea

New Zealand Inventory NoNew Zealand


NoPhilippines



State regulations


Not listed.


Not regulated.


Not regulated.


Fuels, diesel (CAS 68334-30-5) Listed.


HMIS® ratings Health: 2Flammability: 2Physical hazard: 0


CPH MSDS NA

6 / 7



Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.

CPH MSDS NA

7 / 7



HD7SAE 10W30; 5W30; 10W; 20W20; 30; 40; 50

185

Product nameSynonym

Code

In case of emergency

Product and company identification

Responsible name Atrion Regulatory Services, Inc.:::

::

1 .

Conforms to ANSI Z400.5-2004 Standard (Canada).

CANUTEC (613) 996-6666

SupplierFederated Co-operatives LimitedP. O. Box 1050; 401 - 22nd StreetEastSaskatoon, SK S7K 3M9 Canada(306) 244-3447

:Supplier/ManufacturerMaterial uses : Lubrication oil.

Material Safety Data SheetHD7

ManufacturerConsumers' Co-operative Refineries LimitedP.O. Box 260; 9th Avenue NorthRegina, SK S4P 3A1 Canada(306) 721-5353

Dermal contact. Eye contact. Inhalation. Ingestion.

Emergency overview

Hazards identification

Routes of entryPotential acute health effects

No known significant effects or critical hazards.

Zinc C1-C14 Alkydithiophosphate is an eye irritant at concentration of 5% or greater.

Low oral toxicity; vomiting may present an aspiration hazard. Vomiting may result inaspiration into lungs causing chemical pneumonitis.No known significant effects or critical hazards.

EyesSkin

InhalationIngestion

Physical state Liquid. [Oily liquid.]

NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHENTHE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED.No known significant effects or critical hazards. Avoid prolonged contact with eyes, skinand clothing.

:

:

:

::

::

Odor : Mild.

2 .

Potential chronic health effects

Carcinogenicity : There is no data to indicate any component present at greater than 0.1% that maypresent a carcinogenic risk.

Mutagenicity : There are no ingredients present which, within the current knowledge of the supplier andin the concentrations applicable, are classified as hazardous to health or theenvironment and hence require reporting in this section.

Teratogenicity : There are no ingredients present which, within the current knowledge of the supplier andin the concentrations applicable, are classified as hazardous to health or theenvironment and hence require reporting in this section.

Developmental effects : There are no ingredients present which, within the current knowledge of the supplier andin the concentrations applicable, are classified as hazardous to health or theenvironment and hence require reporting in this section.

Chronic effects : May cause skin irritation, especially under repeated or prolonged contact or whenmoisture is present.

Fertility effects : No known significant effects or critical hazards.Over-exposure signs/symptoms

Ingestion : No specific data.Skin : No specific data.Eyes : No specific data.

Inhalation : No specific data.

Date of issue : 07/23/2009 Page: 1/610/02/2012

HD7

Hazards identification2 .

See toxicological information (section 11)

Medical conditionsaggravated by over-exposure

None known.:

Composition/information on ingredients3 .

There are no ingredients present which, within the current knowledge of the supplier and in the concentrationsapplicable, are classified as hazardous to health or the environment and hence require reporting in this section.

No hazardous ingredient

Name

First aid measures

No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.

Notes to physician :

4 .

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Check for and remove any contact lenses. Immediately flush eyes with plenty of waterfor at least 20 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention if symptoms occur.In case of contact, immediately flush skin with plenty of water for at least 20 minuteswhile removing contaminated clothing and shoes. Wash contaminated skin with soapand water. Wash clothing before reuse. Clean shoes thoroughly before reuse. Getmedical attention if symptoms occur.Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Seek medical attention.Wash out mouth with water. Give 1/2 glass of milk./Give two glasses of water to drink.Never give anything by mouth to an unconscious person. Do not induce vomiting unlessdirected to do so by medical personnel. If spontaneous vomiting occurs, have victimlean forward so that their head is between their knees. Vomiting may result in aspirationinto lungs causing chemical pneumonitis. Keep victim at rest. Seek medical attention.

Use an extinguishing agent suitable for the surrounding fire. Carbon dioxide, water sprayor fog, dry chemical or foam. Cool closed containers exposed to fire with water. Movecontainers from fire area if this can be done without risk.

Fire-fighting measures

Extinguishing media

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Do not spray water directly into containers due to the danger of slop over.

Suitable :

Not suitable :Hazardous thermaldecomposition products

: Incomplete combustion may produce: Calcium, nitrogen oxides, carbon oxides, sulfuroxides, phosphorus oxides, magnesium, sodium and zinc.

May form combustible mixtures with air at temperatures at or above the flashpoint. Heator contact with oxidizing materials will greatly increase fire and explosion hazards.Vapors may accumulate in low or confined areas or travel a considerable distance to asource of ignition and flash back.

:Flammability of the product


HD7

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Avoid all possible sources of ignition (spark or flame). Do not touch or walkthrough spilled material. Avoid breathing vapor or mist. Wear appropriate respiratorwhen ventilation is inadequate. Provide adequate ventilation. Put on appropriatepersonal protective equipment (see section 8). Wear protective equipment includingrubber boots.

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas. Washspillages into an effluent treatment plant or proceed as follows. Contain and collectspillage with non-combustible, absorbent material e.g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations(see section 13). Dispose of via a licensed waste disposal contractor. Contaminatedabsorbent material may pose the same hazard as the spilled product. Note: see section1 for emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).


Large spill :

6 .

Stop leak if without risk. Move containers from spill area. Pump up using an explosion-proof pump. Absorb with an inert material and place in an appropriate waste disposalcontainer. Dispose of via a licensed waste disposal contractor.

Small spill :Methods for cleaning up

Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Do not ingest. Avoid contact with eyes, skin and clothing. Wear chemical resistantclothing if prolonged skin contact is likely. Chemical splash goggles. Avoid breathingvapor or mist. Wear appropriate respirator when ventilation is inadequate. Use withadequate ventilation. Wash thoroughly after handling. Launder contaminated clothingbefore reuse. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Empty containers retainproduct residue and can be hazardous. Do not reuse container.

Handling and storageHandling

Storage

:

:

7 .

Exposure controls/personal protectionConsult local authorities for acceptable exposure limits.

8 .

Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product contains ingredientswith exposure limits, use process enclosures, local exhaust ventilation or otherengineering controls to keep worker exposure below any recommended or statutorylimits. Use of mechanical ventilation is recommended.

Recommended monitoringprocedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.


HD7

Exposure controls/personal protection8 .

Personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.

Eyes

Personal protectiveequipment (Pictograms)

:

Wear chemical resistant clothing if prolonged skin contact is likely.

Neoprene gloves./ Nitrile gloves.

A respirator is not needed under normal and intended conditions of product use. Wearan appropriate NIOSH approved respirator if concentration levels exceed the safeexposure limits.

Splash goggles. Safety glasses with side shields.

:

SkinRespiratory

:::

Hands

HMIS Code/Personalprotective equipment

: x

Liquid. [Oily liquid.]

-18°C (-0.4°F)0.88Partially soluble in the following materials: cold water and hot water.

Mild.Brown.

Melting/freezing point

Physical and chemical propertiesPhysical state

Specific gravitySolubility

OdorColor

:

:::::

Flash point : Open cup: >147°C (>296.6°F)413°C (775.4°F):Auto-ignition temperature

9 .

The product is stable.Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

Heat or contact with oxidizing materials will greatly increase fire and explosion hazards.

Stability and reactivityStability

Conditions to avoid

Hazardous decompositionproducts

Hazardous polymerization:

:

:

:

10 .

:Materials to avoid Reactive or incompatible with the following materials: oxidizing materials.

Toxicological information11 .Acute toxicity

Inhalation No known significant effects or critical hazards.Low oral toxicity; vomiting may present an aspiration hazard. Vomiting may result inaspiration into lungs causing chemical pneumonitis.

No known significant effects or critical hazards.Skin

Ingestion

:

::


HD7

Toxicological information11 .Zinc C1-C14 Alkydithiophosphate is an eye irritant at concentration of 5% or greater.Eyes :

Ecological informationEnvironmental effects : No known significant effects or critical hazards.

12 .

The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products viaa licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.

Waste disposal

Disposal considerations


:

13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.

Transport information14 .AERG

IATA :TDG / IMDG/ Not regulated.

: Not applicable.Regulatory information

Regulatory information

CEPA Toxic substances: None of the components are listed.Canadian ARET: None of the components are listed.Canadian NPRI: None of the components are listed.Alberta Designated Substances: None of the components are listed.Ontario Designated Substances: None of the components are listed.Quebec Designated Substances: None of the components are listed.

WHMIS (Canada) Not controlled under WHMIS (Canada).

International regulationsInternational lists

:

:

Canada

15 .

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulationsand the MSDS contains all the information required by the Controlled Products Regulations.

Canadian lists :

Canada inventory(DSL/NDSL)

: Canada inventory: All components are listed or exempted.

This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).

Other informationNOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHENTHE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED.

Label requirements :

16 .


HD7

Other information16 .

References

Hazardous MaterialInformation System (U.S.A.)

01

0

National Fire ProtectionAssociation (U.S.A.)

Health

Special

Instability

Flammability

:

:

:The customer is responsible for determining the PPE code for this material.

4- Extreme3- Serious

2- Moderate1- Slight

0- MinimalSee section 8 for more detailed

information on personal protection.

HAZARD RATINGS

Health

Physical Hazard

0

1Fire hazard

x

0

Health

Personal protection

Date of issueDate of previous issueVersion :

::

07/23/200905/15/20082

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of theuser. All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.

ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -Canada Gazette Part II, Vol. 122, No. 2. Registration SOR/88-64, 31 December 1987.Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of DangerousGoods, Regulations and Schedules, Clear Language version 2005.


10/02/201207/23/200903



Material name INDUSTRIAL HYDRAULIC OIL

Version # 02




CAS # Mixture

Product code 184

Product use Hydraulic oil.

Synonym(s) ISO GRADES 22, 32, 46, 68, 100, 150, MV22, HVI 36





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec




Emergency overview Low hazard for usual industrial or commercial handling by trained personnel.

OSHA regulatory status This product is not hazardous according to OSHA 29CFR 1910.1200.



Eyes Direct contact with eyes may cause temporary irritation.

Skin Prolonged skin contact may cause temporary irritation.


Ingestion Under normal conditions of intended use, this material does not pose a risk to health.




The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.






CPH MSDS NA

1 / 5

INDUSTRIAL HYDRAULIC OIL CPH MSDS NA






Extinguishing media




mediaNone.




Fire fighting





















General hygiene





Form Liquid.

Color Brown.

Odor Mild.


pH Not available.




CPH MSDS NA

2 / 5



Melting point/Freezing point 14 °F (-10 °C)

Solubility (water) Partially soluble in cold and hot water.

Specific gravity 0.86

Flash point > 296.6 °F (> 147 °C) Open Cup


upper, % by volume

Not available.


lower, % by volume

Not available.




Conditions to avoid No data available.

Incompatible materials None known.




reactionsWill not occur.



Acute effects No data available.

Local effects None known.











Bioaccumulation /








DOT


IATA


IMDG


CPH MSDS NA

3 / 5



TDG



US federal regulations This product is not hazardous according to OSHA 29CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.


Not regulated.


None






No


370)No

Drug Enforcement


1308.11-15)

Not controlled

WHMIS status Non-controlled

Inventory status





Inventory of Existing Chemical Substances in China (IECSC) NoChina


YesEurope


Inventory of Existing and New Chemical Substances (ENCS) YesJapan




YesPhilippines


Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico

State regulations


Not listed.


Not regulated.


Not regulated.


Not regulated.

CPH MSDS NA

4 / 5








CPH MSDS NA

5 / 5





Material name PROPANE- LIQUEFIED PETROLEUM GAS

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 127

Product use Various.

Synonym(s) Unstenched Propane * Stenched Propane * HD-5 Propane * Standard Propane





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec


Physical state Gas.

Appearance Colorless liquefied gas.

Emergency overview DANGER

Extremely flammable gas. High pressure gas. Gas reduces oxygen available for breathing.

Contact with liquefied gas might cause frostbites, in some cases with tissue damage. In a fire or ifheated, a pressure increase will occur and the container may burst or explode.Static accumulating flammable materials can become electrostatically charged even in bondedand grounded equipment. Sparks may ignite material and vapor may cause flash fire (orexplosion).



Routes of exposure Inhalation. Eyes. Skin.

Eyes Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn").

Skin Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn").

Inhalation Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels. Nasal and respiratory tract irritation, central nervous system effectsincluding excitation, euphoria, contracted eye pupils, dizziness, drowsiness, blurred vision,fatigue, nausea, headache, loss of reflexes, tremors, convulsions, seizures, loss ofconsciousness, coma, respiratory arrest and sudden death could occur as a result of long termand/or high concentration exposure to vapors. May also cause anemia and irregular heart rhythm.

Ingestion This material is a gas under normal atmospheric conditions and ingestion is unlikely.

Target organs Respiratory tract. Eyes. Central nervous system.

Chronic effects May cause central nervous system effects. Components have been shown to be weak cardiacsensitizers which can result in cardiac arrhythmia and ventricular fibrillation.

Potential environmental effects Not expected to be harmful to aquatic organisms.

CPH MSDS NA

1 / 6

PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA

909445 Version #: 01 Revision date: - Issue date: 07-19-2012



74-98-6 100Propane

75-08-1 0.005Ethanethiol



Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention immediately.

Skin contact Wash frost-bitten areas with plenty of water. Do not remove clothing. Get medical attentionimmediately.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.Call a physician or poison control center immediately.

Ingestion Ingestion is not a typical route of exposure for gases or liquefied gases.



Flammable properties Extremely flammable gas. Gas forms mixtures with air which can catch fire and burn withexplosive violence. Vapors are heavier than air and invisible mixture spreads easily and mayaccumulate in low or confined areas, travel considerable distance to source of ignition and flashback. Runoff to sewer may create fire or explosion hazard.

Extinguishing media


mediaDry chemical, CO2, water spray, fog, or foam.

Fire fighting

equipment/instructionsSelf-contained breathing apparatus, operated in positive pressure mode and full protectiveclothing must be worn in case of fire.

Move container from fire area if it can be done without risk.

Do not extinguish fires unless gas flow can be stopped safely; explosive re-ignition may occur.Promptly isolate the scene by removing all persons from the vicinity of the incident. No actionshall be taken involving any personal risk or without suitable training. For fires involving thismaterial, do not enter any enclosed or confined fire space without proper protective equipment,including self-contained breathing apparatus. Stop flow of material. Use water to keep fireexposed containers cool and to protect personnel effecting shutoff. If a leak or spill has notignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak.Prevent runoff from fire control or dilution from entering streams, sewers or drinking water supply.


productsCarbon oxides.


Personal precautions Evacuate the area promptly. No action shall be taken involving any personal risk or withoutsuitable training. Keep unnecessary personnel away.

Ensure adequate ventilation. In case of inadequate ventilation, use respiratory protection. Wearappropriate personal protective equipment (See Section 8).

Environmental precautions Should not be released into the environment. Prevent further leakage or spillage if safe to do so.Prevent from entering into soil, ditches, sanitary sewers, waterways and/or groundwater.

Methods for cleaning up Ventilate well, stop flow of gas or liquid if possible. Immediately contact emergency personnel.


Handling Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment.These alone may be insufficient to remove static electricity.Wear appropriate personal protective equipment (See Section 8). Eating, drinking, and smokingshould be prohibited in areas where this material is handled, stored, and processed. Do notbreathe gas. Do not get in eyes, on skin, on clothing. Use only with adequate ventilation.

Storage Store in accordance with local, regional, national, and international regulations. Secure cylindersin an upright position at all times, close all valves when not in use. Store in a cool, dry,well-ventilated place. Keep container tightly closed and sealed until ready for use. Protectcylinders from damage.

CPH MSDS NA

2 / 6






ValueTypeComponents

TWAPropane (CAS 74-98-6) 1000 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueTypeComponents

PELPropane (CAS 74-98-6) 1800 mg/m3

1000 ppm


ValueTypeComponents




ValueTypeComponents



ValueTypeComponents


Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)

ValueTypeComponents

TWAPropane (CAS 74-98-6) 1800 mg/m3

1000 ppm

Engineering controls Use process enclosures, local exhaust ventilation, or other engineering controls to controlairborne levels below recommended exposure limits. The engineering controls also need to keepgas, vapor, or dust concentrations below any lower explosive limits.



Skin protection Wear protective clothing appropriate for the risk of exposure.

Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.

General hygiene

considerationsDo not eat, drink or smoke when using the product. Wash thoroughly after handling. Provideeyewash station and safety shower. Handle in accordance with good industrial hygiene and safetypractices.


Appearance Colorless liquefied gas.

Physical state Gas.

Form Compressed liquefied gas.

Color Colorless

Odor Boiling cabbage if stenched.

Odor threshold 4800 ppm

pH Not available.

Vapor pressure 1034.1 - 1241 kPa

Vapor density 1.6

Boiling point -43.6 °F (-42 °C)

Melting point/Freezing point -292 °F (-180 °C) / -302.6 °F (-185.89 °C)

Solubility (water) 6.5 % v/v (20 °C)


Flash point -150 °F (-101.1 °C) Pensky-Martens Closed Cup


upper, % by volume

9.5 %

CPH MSDS NA

3 / 6




lower, % by volume

2.2 %


VOC 100 %

Evaporation rate > 1 (Ether (anhydrous)=1)

Molecular weight 44.11 g/mol

Molecular formula C3-H8

Other data

Critical temperature 205.9 °F (96.6 °C)


Chemical stability Stable under normal temperature conditions and recommended use.

Conditions to avoid In a fire or if heated, a pressure increase will occur and the container may burst or explode.

Incompatible materials Oxidizing agents. Reducing agents. Acids. Alkalis.


productsNone known.


reactionsPolymerization will not occur.


Test Results

Toxicological data

Components Species

Propane (CAS 74-98-6)

LC50 Rat

Inhalation

Acute

> 1442.847 mg/l, 15 Minutes

Sensitization Not available.

Acute effects Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels. Exposure to rapidly expanding gas or vaporizing liquid may causefrostbite ("cold burn").

Chronic effects May cause central nervous system effects.


Ecotoxicity Not expected to be harmful to aquatic organisms.

Persistence and degradability Not available.

Bioaccumulation /


Partition coefficient

Propane 2.36


Waste codes D001: Waste Flammable material with a flash point <140 °F

Disposal instructions Dispose in accordance with all applicable regulations. Empty containers may contain productresidues. Do not puncture or incinerate even when empty. This material and/or its container mustbe disposed of as hazardous waste. Return the empty cylinder to the supplier.


DOT

UN1978UN number


PropaneProper shipping name

2.1Hazard class

19, T50Special provisions



CPH MSDS NA

4 / 6




314, 315Packaging bulk

100Reportable quantity

IATA

UN1978UN number

PropaneUN proper shipping name

2.1Transport hazard class(es)

10LERG code

IMDG

UN1978UN number

PROPANEUN proper shipping name

2.1Transport hazard class(es)

F-D, S-UEmS No.

TDG

PROPANEProper shipping name

2.1Hazard class

UN1978UN number

NoMarine pollutant


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.


Not regulated.


Propane: 100


Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - YesReactivity Hazard - No




Yes


370)Yes

Clean Water Act (CWA) Section

112(r) (40 CFR 68.130)Hazardous substance

Drug Enforcement


1308.11-15)

Not controlled



WHMIS classification A - Compressed GasB1 - Flammable Gases

WHMIS labeling

CPH MSDS NA

5 / 6



Inventory status







YesEurope






YesPhilippines



State regulations


Not listed.


Propane (CAS 74-98-6) Listed.




Propane (CAS 74-98-6) 500 LBS








CPH MSDS NA

6 / 6





Material name SONIC 2 CYCLE OIL

Version # 02

Issue date 13-December-2011

Revision date 08-January-2015

Supersedes date 13-December-2011

CAS # Mixture

Product code 111

Product use 2 cycle lubricant.





Telephone (306) 721-5353/(306) 719-4353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec




Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed orvomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.



Routes of exposure Inhalation. Skin contact. Ingestion.


Skin Prolonged or repeated contact may dry skin and cause irritation.

Inhalation Overexposure to mists/vapors of this product may cause headache, dizziness, nausea, andrespiratory tract irritation.

Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.

Target organs Contains material which causes damage to the following organs: kidneys, liver, upper respiratorytract, skin, central nervous system (CNS), eye, lens or cornea. Health studies have shown thatmany petroleum hydrocarbons pose potential human health risks which may vary from person toperson. As a precaution, exposure should be minimized.

Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms may bedelayed.

Carcinogenicity, Mutagenicity and Teragenocity: There is no data to indicate that any componentpresent at greater than 0.1% may present a risk.

Signs and symptoms Overexposure to mists/vapors of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation. Dropletsof the product aspirated into the lungs through ingestion or vomiting may cause a serious chemicalpneumonia.


SONIC 2 CYCLE OIL CPH MSDS NA

906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 1 / 7



8052-41-3 10-30Stoddard solvent

Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.



Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.

Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.

Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fullyconscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.



Flammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containersmay explode when heated.

Extinguishing media


media

Carbon dioxide (CO2). Foam. Dry chemical. Water fog.


media

Do not use water jet as an extinguisher, as this will spread the fire.

Fire fighting

equipment/instructions

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.


products

Carbon oxides.


Personal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS forPersonal Protective Equipment.

Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.

Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry intowaterways, sewer, basements or confined areas.

Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustiblematerial like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).

Never return spills to original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination.

Other information Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.


Handling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrialhygiene practices.

Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container atroom temperature. Store away from incompatible materials.






ValueTypeComponents

TWA 100 ppmStoddard solvent (CAS8052-41-3)


ValueTypeComponents

PEL 2900 mg/m3Stoddard solvent (CAS8052-41-3)

500 ppm


ValueTypeComponents

TWA 572 mg/m3Stoddard solvent (CAS8052-41-3)

100 ppm



ValueTypeComponents

STEL 580 mg/m3Stoddard solvent (CAS8052-41-3)

TWA 290 mg/m3

Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)

ValueTypeComponents



ValueTypeComponents



ValueTypeComponents

TWA 525 mg/m3Stoddard solvent (CAS8052-41-3)

100 ppm

Mexico. Occupational Exposure Limit Values

ValueTypeComponents

STEL 1050 mg/m3Stoddard solvent (CAS8052-41-3)

200 ppm

TWA 523 mg/m3

100 ppm

Biological limit values No biological exposure limits noted for the ingredient(s).

Engineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk ofinhalation of vapors.


Eye / face protection Use approved safety goggles or face shield.

Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.

Respiratory protection In case of inadequate ventilation, use respiratory protection.

Hand protection Wear appropriate chemical resistant gloves. Butyl rubber gloves are recommended, but be awarethat the liquid may penetrate the gloves. Frequent change is advisable.



General hygiene

considerations

Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.




Form Liquid.

Color Blue.

Odor Solvent.


pH Not available.


Vapor density > 1 ( Air=1)



Solubility (water) Slight


Flash point 109.0 °F (42.8 °C) Closed Cup


upper, % by volume

Not available.


lower, % by volume

Not available.




Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.



products

No hazardous decomposition products are known.


reactions

Will not occur.


Sensitization None known.

Acute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contactmay dry skin and cause irritation. Overexposure to mists/vapors of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.There is no data to indicate that any component present at greater than 0.1% may present a risk.

IARC Monographs. Overall Evaluation of Carcinogenicity

Stoddard solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Mutagenicity There is no data to indicate that any component present at greater than 0.1% may present a risk.

Teratogenicity There is no data to indicate that any component present at greater than 0.1% may present a risk.


Ecotoxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Persistence and degradability No data available.

Bioaccumulation /

accumulation

No data available.



Bioaccumulative potential

Octanol/water partition coefficient log Kow

Stoddard solvent (CAS 8052-41-3) 3.16 - 7.15

Mobility in environmental

media

No data available.


Waste codes D001: Waste Flammable material with a flash point <140 °F

Disposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competentauthorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.


products

Dispose of waste and residues in accordance with local authority requirements.



DOT

UN1993UN number


Flammable liquids, n.o.s. (Stoddard solvent)Proper shipping name

3Hazard class

3Labels required

IIIPacking group

NoMarine pollutant

Environmental hazards

B1, B52, IB3, T4, TP1, TP29Special provisions




242Packaging bulk

IATA

UN1993UN number

Flammable liquid, n.o.s. (Stoddard solvent)UN proper shipping name


IIIPacking group

NoEnvironmental hazards

3LERG code

IMDG

UN1993UN number

FLAMMABLE LIQUID, N.O.S. (Stoddard solvent)UN proper shipping name


IIIPacking group

NoMarine pollutant


F-E, S-EEmS

TDG

UN1993UN number

FLAMMABLE LIQUID, N.O.S. (Stoddard solvent)Proper shipping name

3Hazard class

IIIPacking group

NoMarine pollutant




Not regulated.




Not regulated.


None


Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous

chemical

Yes

Drug Enforcement


1308.11-15)

Not controlled



WHMIS classification B3 - Combustible LiquidsD2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory status







YesEurope






YesPhilippines

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).


State regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.


Stoddard solvent (CAS 8052-41-3) Listed.


Not listed.


Stoddard solvent (CAS 8052-41-3) Listed.


Stoddard solvent (CAS 8052-41-3)

US. Pennsylvania Worker and Community Right-to-Know Law

Stoddard solvent (CAS 8052-41-3)




HMIS® ratings Health: 2*Flammability: 2Physical hazard: 0Personal protection: X

NFPA ratings

02

2


Prepared by Not available.





Material name SONIC ATF

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 1221

Product use Automatic Transmission Fluid.

Synonym(s) SONIC ATF DEXRON III/MERCON; SONIC ATF DEX III


Manufacturer CHS Inc.

Address P.O. Box 64089 - Mail station 525

St. Paul, MN 55164-0089

Telephone (651) 424-8438


Address P. O. Box 1050; 401 - 22nd Street East

Saskatoon, SK S7K 3M9 Canada

Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec



Appearance Liquid.


OSHA regulatory status This product is not hazardous according to OSHA 29CFR 1910.1200.











64742-65-0 60-100Distillates (petroleum), solvent-dewaxed heavy paraffinic





CPH MSDS NA

1 / 5

SONIC ATF CPH MSDS NA







Extinguishing media




mediaNone.




Fire fighting


















TWA 5 mg/m3 Inhalable fraction.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)



PEL 5 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)



STEL 10 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)

TWA 5 mg/m3 Mist.

CPH MSDS NA

2 / 5





STEL 10 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)

TWA 5 mg/m3 Mist.






General hygiene



Appearance Liquid.


Form Liquid.

Color Red / yellow.

Odor Mild.


pH Not available.

Vapor pressure < 0.13 kPa

Vapor density > 1 ( Air=1)


Melting point/Freezing point 5 °F (-15 °C)



Flash point > 379.4 °F (> 193 °C) Closed Cup


upper, % by volume

Not available.


lower, % by volume

Not available.

Auto-ignition temperature > 500 °F (> 260 °C)

Evaporation rate < 1 (ether (anhydrous) = 1)


Chemical stability Material is stable under normal conditions. Handling temperatures should not exceed 175ºF (80ºC). Storage temperatures should not exceed 212º F (45º C).

Conditions to avoid No data available.

Incompatible materials None known.




reactionsUnder normal conditions of storage and use, hazardous polymerization will not occur.



Acute effects No data available.




CPH MSDS NA

3 / 5











Bioaccumulation /








DOT


IATA


IMDG


TDG



US federal regulations This product is not hazardous according to OSHA 29CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.


Not regulated.


None






No


370)No

Drug Enforcement


1308.11-15)

Not controlled


CPH MSDS NA

4 / 5



Inventory status







YesEurope






YesPhilippines



State regulations


Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)

Listed.


Not listed.



Listed.



Listed.


Not regulated.


Not regulated.






CPH MSDS NA

5 / 5





Material name SONIC BLUE GUARD

Version # 02

Issue date 19-September-2011

Revision date 20-May-2014

Supersedes date 19-September-2011

CAS # Mixture

Product code 1696

Product use Multi-purpose grease

Synonym(s) GREASE, MULTIPURPOSE


Manufacturer CHS Inc.

Address P.O. Box 64089, Mail station 525

St. Paul, MN 55164-0089

Telephone (651) 355-8438


Address P.O. Box 1050, 401 - 22nd Street

East Saskatoon SK S7K 3M9 Canada

Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec


Physical state Solid.

Appearance Gel-like solid.




Routes of exposure Eye contact. Skin contact.






Potential environmental effects The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.



64742-52-5 60-100Distillates (petroleum), hydrotreated heavy naphthenic

Composition comments * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.



Eye contact Immediately rinse with water for several minutes.



SONIC BLUE GUARD CPH MSDS NA

904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 1 / 6





Extinguishing media


media

Extinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.


media

None.



from the chemical

By heating and fire, toxic vapors/gases may be formed.

Fire fighting


Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.



products

No data available.



Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a wide area(e.g. by containment or oil barriers).











TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)



PEL 5 mg/m3 Mist.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)

2000 mg/m3

500 ppm



STEL 10 mg/m3 Mist.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)

TWA 5 mg/m3 Mist.



Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)


TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)




TWA 5 mg/m3 Mist.




TWA 5 mg/m3 Mist.




Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.


General hygiene

considerations

Handle in accordance with good industrial hygiene and safety practices.


Appearance Gel-like solid.

Physical state Solid.

Form Gel.

Color Blue.

Odor Slight petroleum odor.


pH Not available.

Vapor pressure < 0.13 kPa (< 1mm Hg)

Vapor density > 1 (Air = 1)

Boiling point > 600.8 °F (> 316 °C)

Melting point/Freezing point > 500 °F (> 260 °C)



Flash point > 399.2 °F (> 204.0 °C) Pensky-Martens Closed Cup


upper, % by volume

Not available.


lower, % by volume

Not available.


Evaporation rate < 1 (Ether = 1.0)



Conditions to avoid Prolonged excessive heat may cause product decomposition.





products

None expected under normal conditions of use.


reactions

Will not occur.


Sensitization Not a skin or respiratory sensitizer.

Acute effects May be harmful if swallowed.




ACGIH Carcinogens

Distillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)

A4 Not classifiable as a human carcinogen.



3 Not classifiable as to carcinogenicity to humans.



Reproductive effects Not classified.






Bioaccumulation /

Accumulation

Not available.


Waste codes Not regulated.



products




DOT


IATA


IMDG


TDG





Not regulated.




Not regulated.


None


Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


Not listed.


chemical

Yes

Drug Enforcement


1308.11-15)

Not controlled


Inventory status







YesEurope






YesPhilippines






Listed.


Not listed.



Listed.


Not listed.


Not listed.


Further information The classification for health and environmental hazards is derived by a combination of calculationmethods and test data, if available.



NFPA Ratings

0

1

1






Material name SONIC INDUSTRIAL GEAR OIL

Version # 02

Issue date 19-September-2011

Revision date 20-May-2014

Supersedes date 19-September-2011

CAS # -

Product code 182

Product use Gear lubricant

Synonym(s) ISO GRADES 100, 150, 220, 320, 460





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec



Appearance Dark viscous liquid.




Routes of exposure Eye contact. Skin contact. Ingestion.






Potential environmental effects The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.



64742-62-7 100Residual oils (petroleum), solvent-dewaxed



Eye contact Immediately rinse with water for several minutes.




SONIC INDUSTRIAL GEAR OIL CPH MSDS NA





Extinguishing media


media



media

None.



from the chemical


Fire fighting





products

No data available.














PEL 5 mg/m3 Mist.Residual oils (petroleum),solvent-dewaxed (CAS64742-62-7)



STEL 10 mg/m3 Mist.Residual oils (petroleum),solvent-dewaxed (CAS64742-62-7)

TWA 5 mg/m3 Mist.




TWA 5 mg/m3 Mist.




TWA 5 mg/m3 Mist.






TWA 5 mg/m3 Mist.




Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.


General hygiene

considerations



Appearance Dark viscous liquid.


Form Liquid.

Color Dark.

Odor Slight.


pH Not available.

Vapor pressure < 0 mm Hg (20 °C)



Solubility (water) Nil in water.


Flash point > 294.0 °F (> 145.6 °C)


upper, % by volume

Not available.


lower, % by volume

Not available.

Auto-ignition temperature 755 °F (401.67 °C)

VOC Nil.

Viscosity 2636 SUS (100 °F)

491.4 cSt (40 °C)

Pour point 15.8 °F (-9 °C)

Bulk density 7.42 lb/gal

Molecular weight 690 g/mol



Conditions to avoid Prolonged excessive heat may cause product decomposition.



products



reactions

Will not occur.


Sensitization Not a skin or respiratory sensitizer.

Acute effects May be harmful if swallowed.








Reproductive effects Not classified.






Bioaccumulation /

Accumulation

Not available.


Waste codes Not regulated.



products




DOT


IATA


IMDG


TDG





Not regulated.


Not regulated.


None


Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No


Not listed.


chemical

Yes

Drug Enforcement


1308.11-15)

Not controlled




Inventory status







YesEurope






YesPhilippines





Residual oils (petroleum), solvent-dewaxed (CAS64742-62-7)

Listed.


Not listed.


Residual oils (petroleum), solvent-dewaxed (CAS64742-62-7)

Listed.


Residual oils (petroleum), solvent-dewaxed (CAS 64742-62-7)


Residual oils (petroleum), solvent-dewaxed (CAS 64742-62-7)


Further information The classification for health and environmental hazards is derived by a combination of calculationmethods and test data, if available.

NFPA Ratings

0

1

1






Material name TRANS HYDRAULIC FLUID

Version # 02

Issue date 04-January-2012

Revision date 08-January-2015

Supersedes date 04-January-2012

CAS # Mixture

Product code 62

Product use Transmission and hydraulic oil.

Synonym(s) (NO DYE)





Telephone (306) 721-5353/(306) 719-4353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec




Emergency overview WARNING

Causes skin and eye irritation.




Eyes Causes eye irritation.

Skin Causes skin irritation.


Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.





68649-42-3 1-5Zinc Alkyldithiophosphate




Skin contact In case of contact, flush skin with plenty of water for at least 20 minutes, while removingcontaminated shoes and clothes. Wash contaminated skin with soap and water. Washcontaminated clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention ifirritation develops and persists.

TRANS HYDRAULIC FLUID CPH MSDS NA

906148 Version #: 02 Revision date: 08-January-2015 Issue date: 04-January-2012 1 / 5






Extinguishing media


media



media

None.



from the chemical


Fire fighting





products

No data available.












Biological limit values No biological exposure limits noted for the ingredient(s).






Hand protection Wash hands after handling.

General hygiene

considerations





Form Liquid.

Color Brown.

Odor Mild.




pH Not available.





Solubility (water) Sligthly soluble in cold and hot water


Flash point > 298.4 °F (> 148.0 °C) Open Cup


upper, % by volume

Not available.


lower, % by volume

Not available.




Conditions to avoid Contact with incompatible materials.



products



reactions

Will not occur.



Acute effects Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Local effects Causes skin and eye irritation.



OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.









Bioaccumulation /

accumulation

Not available.




products






DOT


IATA


IMDG


TDG





Not regulated.


Not regulated.


Zinc Alkyldithiophosphate (CAS 68649-42-3) 1.0 % N982


Zinc Alkyldithiophosphate (CAS 68649-42-3) N982 Listed.


None




Not listed.


chemical

No

Drug Enforcement


1308.11-15)

Not controlled


WHMIS classification D2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory status







YesEurope









YesPhilippines



State regulations




Not listed.


Not regulated.


Zinc Alkyldithiophosphate (CAS 68649-42-3)


Not listed.



HMIS® ratings Health: 2Flammability: 1Physical hazard: 0Personal protection: X

NFPA ratings

02

1


Prepared by Not available.



MATERIAL SAFETY DATA SHEET 12435 INSECT REPELLENT HD AEROSOL 1 of 2

DEGIL SAFETY PRODUCTS 200 ZENWAY BLVD. UNIT 1 PH. 905-856-1511

www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC HEAVY DUTY INSECT REPELLENT AEROSOL UPC CODECHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET)PRODUCT USE PackagingMOLECULAR WEIGHT NOT APPLICABLE 24 CANS / CASEFORMULA NOT APPLICABLECNFC SECTION 3 3.5 LEVEL 3NFPA CODE 30B LEVEL 3T.D.G. CLASS ORM-D CONSUMER COMMODITY (AEROSOLS, UN1950, CLASS 2.1)WHMIS CLASSIFICATION NOT APPLICABLEHMIS RATING: FLAMMABILITY 4 SEVERE HAZARDHMIS RATING: HEALTH 2 MODERATE HAZARDHMIS RATING: REACTIVITY 0 MINIMAL HAZARDSECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species

N,N-DIETHYL m-TOLUAMIDE 28.5 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT

ETHANOL 30 - 60 1000ppm 64-17-5 7060mg/kg ORAL - RAT 31623ppm (4hr) INHAL - RAT

ISOBUTANE 10 - 30 1000ppm 75-28-5 NOT AVAILABLE 142500 ppm (4hr) INHAL - RAT

PROPANE 1 - 5 1000ppm 74-98-6 >5000mg/kg DERMAL-RABBITS NOT AVAILABLESECTION THREE PHYSICAL DATAPHYSICAL STATE AEROSOLAPPEARANCE CLEAR - COLOURLESSODOR FRAGRANTODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 78.5°CEVAPORATION RATE GREATER THAN 1VAPOUR PRESSURE (PSIG) AEROSOL 40 - 50 @ 20° CVAPOUR DENSITY (AIR=1) GREATER THAN 1AEROSOL % VOC (w/w) 79 - 80AEROSOL % VOLATILE 79 - 80SOLUBILITY IN WATER NOT AVAILABLEpH NOT APPLICABLESPECIFIC GRAVITY (LIQUID) 0.83 - 0.87SPECIFIC GRAVITY (AEROSOL) 0.75 - 0.79COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLESECTION FOURAEROSOL FLAME PROJECTION > 15cm BUT < 100cmFLASHBACK NOT APPLICABLEFLAMMABILITY EXTREMELY FLAMMABLEIF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAMEAUTO IGNITION TEMPERATURE (° C) LOWEST KNOWN VALUE IS 422°C (ETHANOL)EXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, FOAMUPPER FLAMMABLE LIMIT 19.0 (% BY VOLUME)LOWER FLAMMABLE LIMIT 3.3 (% BY VOLUME)EXPLOSION DATA SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE SENSITIVITY TO IMPACT NOT APPLICABLEHAZARDOUS COMBUSTIONPRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETE.FLASH POINT (° C) TAG CLOSED CUP - LOWEST KNOWN VALUE IS ETHANOL @ 13°C(CONCENTRATE)SPECIAL PROCEDURES WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS

TO PREVENT BUILD UP IF EXPOSED TO EXTREME TEMPERATURES. FULLPROTECTIVE EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARATUSSHOULD BE WORN IN A FIRE INVOLVING THIS MATERIAL.

INSECTICIDE

FIRE & EXPLOSION HAZARD DATA

Reviewed On: 1/29/201511:22 AM ITEM# 12435 DEGIL SAFETY PRODUCTS

MATERIAL SAFETY DATA SHEET 12435 INSECT REPELLENT HD AEROSOL 2 of 2

SECTION FIVE STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETECHEMICAL STABILITY YES

UNDER NORMAL CONDITIONSCOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLESECTION SIX HEALTH DATAROUTE OF ENTRYINGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & WEAKNESSINHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLENT IS SIMPLE ASPHYXIANTEYE CONTACT MAY CAUSE IRRITATIONSKIN CONTACT MAY CAUSE IRRITATIONEFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYESEFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITISEXPOSURE LIMIT OF MATERIAL SEE SECTION TWOCARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS

CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOTREGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETYAND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BYIARC, (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BYACGIH (AMERICAN CONFERENCE OF GOVERNMENTALINDUSTRIAL HYGIENISTS).

REPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVEEFFECTS ARE ANTICIPATED.

IRRITANCY OF MATERIAL SLIGHTTERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITY

EFFECTS ARE ANTICIPATED.MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC

EFFECTS ARE ANTICIPATED.SYNERGISTIC MATERIALS NONE KNOWNSECTION SEVEN EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES CHEMICAL RESISTANT GLOVESRESPIRATORY IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE

RESPIRATOR (NIOSH/MSHA TC-23C OR EQUIVALENT) IS RECOMMENDED.EYE SAFETY GLASSESENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF INDOORS ON A CONTINUOUS BASIS)FOOTWEAR NOT NORMALLY REQUIREDOTHER NOT REQUIREDSECTION EIGHTLEAK / SPILL REMOVE ALL SOURCES OF IGNITION, USE AN INERT ABSORBENT MATERIAL AND NON -

SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSESTORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMSHANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.EQUIPMENTSHIPPING INSTRUCTIONS SEE SECTION ONE TDG CLASSIFICATIONWASTE DISPOSAL DO NOT PUNCTURE OR INCINERATE PACKAGES EVEN WHEN EMPTY. DISPOSE OF IN

ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONSSECTION NINEEMERGENCY FIRST AID PROCEDURE

SECTION TEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.It does not constitute a warranty, express or implied, as to the accuracy of the informationcontained herein. Actual conditions of use and handling are beyond seller's control.User is responsible to evaluate all available information when using product for anyparticular use and to comply with all Federal, State, Provincial and local laws andregulations.

Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED ON: JANUARY 29/2015

INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.

HANDLING AND STORAGE

FIRST AID MEASURES IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY

Reviewed On: 1/29/201511:22 AM ITEM# 12435 DEGIL SAFETY PRODUCTS

MATERIAL SAFETY DATA SHEET 12415 INSECT REPELLENT FOAM 1 of 2

1/29/201510:57 AM ITEM# 12415 DEGIL SAFETY PRODUCTS


www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC INSECT REPELLENT FOAM UPC CODECHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET)PRODUCT USE PackagingMOLECULAR WEIGHT NOT APPLICABLE 48 CANS / CASEFORMULA NOT APPLICABLECNFC SECTION 3 3.5 LEVEL 1NFPA CODE 30B LEVEL 1T.D.G. CLASS ORM-D CONSUMER COMMODITYWHMIS CLASSIFICATION NOT APPLICABLEHMIS RATING: FLAMMABILITY 1 SLIGHT HAZARDHMIS RATING: HEALTH 2 MODERATE HAZARDHMIS RATING: REACTIVITY 0 MINIMAL HAZARDSECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species

N,N-DIETHYL m-TOLUAMIDE 9.50 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT

ISOPROPYL MYRISTATE 1.5 N/A 110-27-0 NOT AVAILABLE NOT AVAILABLE INHAL - RAT

ISOBUTANE 3 - 7 N/A 75-28-5 NOT AVAILABLE 142500 ppm (4hr) INHAL - MOUSE

PROPANE 1 - 5 1000ppm 74-98-6 NOT AVAILABLE NOT AVAILABLESECTION THREE PHYSICAL DATAPHYSICAL STATE AEROSOLAPPEARANCE OFF-WHITE LIQUIDODOR INSECTICIDEODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 100EVAPORATION RATE LESS THAN 1VAPOUR PRESSURE (PSIG) AEROSOL 55 - 65 @ 20° CVAPOUR DENSITY (AIR=1) GREATER THAN 1AEROSOL % VOC (w/w) 24.25AEROSOL % VOLATILE NOT AVAILABLESOLUBILITY IN WATER SOLUBLEpH 7.3 - 8.3SPECIFIC GRAVITY (LIQUID) 0.98 - 1.02SPECIFIC GRAVITY (AEROSOL) 0.90 - 0.94COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLESECTION FOURAEROSOL FLAME PROJECTION CLASSIFIED AS 0 CmFLASHBACK NOT APPLICABLEFLAMMABILITY NOT A FLAMMABLE PRODUCT (AS PER CANADIAN AEROSOL REGULATIONS)IF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAMEAUTO IGNITION TEMPERATURE (° C) NOT AVAILABLEEXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, FOAMUPPER FLAMMABLE LIMIT 9.5 (% BY VOLUME)LOWER FLAMMABLE LIMIT 0.8 (% BY VOLUME)EXPLOSION DATA SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE SENSITIVITY TO IMPACT NOT APPLICABLEHAZARDOUS COMBUSTIONPRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETE.FLASH POINT (° C) NOT AVAILABLE(CONCENTRATE)SECTION FIVE STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETECHEMICAL STABILITY YES

UNDER NORMAL CONDITIONSCOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLE

INSECTICIDE

FIRE & EXPLOSION HAZARD DATA

MATERIAL SAFETY DATA SHEET 12415 INSECT REPELLENT FOAM 2 of 2

1/29/201510:57 AM ITEM# 12415 DEGIL SAFETY PRODUCTS

SECTION SIX HEALTH DATAROUTE OF ENTRYINGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & WEAKNESSINHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLENT IS SIMPLE ASPHYXIANTEYE CONTACT VAPOURS MAY IRRITATESKIN CONTACT MAY CAUSE IRRITATIONEFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYESEFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITISEXPOSURE LIMIT OF MATERIAL SEE SECTION TWOCARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS


REPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVEEFFECTS ARE ANTICIPATED.

IRRITANCY OF MATERIAL SLIGHTTERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITY

EFFECTS ARE ANTICIPATED.MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC

EFFECTS ARE ANTICIPATED.SYNERGISTIC MATERIALS NONE KNOWNSECTION SEVEN EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES CHEMICAL RESISTANT GLOVESRESPIRATORY IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE

RESPIRATOR (NIOSH/MSHA TC-23C OR EQUIVALENT) IS RECOMMENDED.EYE SAFETY GLASSESENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF INDOORS ON A CONTINUOUS BASIS)FOOTWEAR NOT NORMALLY REQUIREDOTHER NOT REQUIREDSECTION EIGHTLEAK / SPILL REMOVE ALL SOURCES OF IGNITION, USE AN INERT ABSORBENT MATERIAL AND NON -

SPARKING TOOLS. AVOID BREATHING FUMES, VENTILATE AREASTORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMSHANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.EQUIPMENTSHIPPING INSTRUCTIONS SEE SECTION ONE TDG CLASSIFICATIONWASTE DISPOSAL DO NOT PUNCTURE OR INCINERATE PACKAGES EVEN WHEN EMPTY. DISPOSE OF IN

ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONSSECTION NINEEMERGENCY FIRST AID PROCEDURE

SECTION TEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.It does not constitute a warranty, express or implied, as to the accuracy of the informationcontained herein. Actual conditions of use and handling are beyond seller's control.User is responsible to evaluate all available information when using product for anyparticular use and to comply with all Federal, State, Provincial and local laws andregulations.

Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED JANUARY 29/2015





Original Date: 3/28/13 Revision Date: 1/29/15

S e c t i o n 1 - I d e n t i f i c a t i o n

PRODUCT NAME: Croc Bloc SPF30 Spray Lotion Broad Spectrum

FORMULA: 12330-10 Proprietary Cosmetic Mixture Containing Active Ingredients: Octinoxate, Octisalate, Avobenzone,

Octocrylene, and Benzophenone-3

PRODUCT USE DESCRIPTION: Sunscreen MANUFACTURER: Croc Bloc Products Inc. 200 Zenway Blvd. Unit #1 Vaughan, ON, Canada L4H 0L6 Phone 800 332 1810 EMERGENCY (24 HOUR) PHONE: Emergency Chemical Response 800 535 5053

S e c t i o n 2 – H a z a r d ( s ) I d e n t i f i c a t i o n NFPA Hazard Classification Health: 0 Fire: 0 Reactivity: 0 Specific Hazard: None ACUTE INHALATION: Low volatility makes vapor inhalation unlikely. ACUTE SKIN CONTACT: Product assumed to be practically non-irritating to minimally irritating ACUTE EYE CONTACT: Product assumed to be minimally to slightly irritating INGESTION: Product assumed to be practically non-toxic CHRONIC OVEREXPOSURE: N. Av.

RESPONSE: INHALATION: Not expected route of exposure. If vapors or mist cause irritation or distress, remove subject to fresh air. Give oxygen or

artificial respiration if needed. SKIN CONTACT: Remove contaminated clothing and wash contact area with soap and fresh water. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, seek medical attention. INGESTION: No harmful affects expected. Drink water or milk to calm stomach.

S e c t i o n 3 – C o m p o s i t i o n / I n f o r m a t i o n o n I n g r e d i e n t s APPEARANCE:

White to Off-White Uniform Spray Lotion

PH: 6.5 to 7.5 SPEC. GRAVITY: 1.020 +/- 0.020 @ 25C FREEZING POINT: N. Av. VAPOR PRESSURE: N. Av. BOILING POINT: 100 C + VAPOR DENSITY: N. Av. WATER SOLUBILITY: Partly Miscible EVAP. RATE: N. Av.

S e c t i o n 4 – F i r s t - A i d M e a s u r e s INHALATION:

Not expected route of exposure. If vapors or mist cause irritation or distress, remove subject to fresh air. Give oxygen or artificial respiration if needed.

SKIN CONTACT: Remove contaminated clothing and wash contact area with soap and fresh water.

EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, seek medical attention.

INGESTION: No harmful affects expected. Drink water or milk to calm stomach.

S e c t i o n 5 – F i r e - F i g h t i n g M e a s u r e s

FLASH POINT: >200 F A.I. TEMPERATURE: N. Av. EXTINGUISHING MEDIA: Use water spray, foam, CO2, or dry chemical extinguishing media SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL HAZARDS: None

S e c t i o n 6 – A c c i d e n t a l R e l e a s e M e a s u r e s

GENERAL: Spills should be contained. Absorb with inert material and collect for disposal. Flush area with water. Prevent

washing from entering waterways.

WASTE DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.

CONTAINER DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.

S e c t i o n 7 – H a n d l i n g a n d S t o r a g e GENERAL: Store in a cool dry place. Keep containers tightly closed when not in use. Avoid contact with eyes. Avoid freezing and localized overheating. OTHER PRECAUTIONS: None known

S e c t i o n 8 – E x p o s u r e C o n t r o l s / P e r s o n a l P r o t e c t i o n CLOTHING: Gloves, coveralls, aprons, boots as necessary to minimize contact

EYES: Chemical goggles, full face shield

RESPIRATION: If vapors or mist are generated, wear an approved respirator

VENTILATION: Use adequate exhaust to control vapor/mist

EXPLOSION PROOFING: None required

S e c t i o n 9 – P h y s i c a l a n d C h e m i c a l P r o p e r t i e s Appearance: White to Off-White Uniform Spray Lotion Odor: Matches Standard Odor Threshold: N.Av. Vapor Pressure: N.Av. Vapor Density: N.Av. pH: 6.5 to 7.5 Relative Density: 1.020 +/- 0.020 @25C Melting Point/Freezing Point: N.Av. Solubility(ies): Partly Miscible in water Initial Boiling Point and Boiling Range: 100C+ Flash Point: >200F Evaporation Rate: N.Av. Flammability (solid, gas): N.Av. Upper/Lower Flammability or Explosive Limits: N.Av. Auto-ignition Temp: N.Av. Partition Coefficient:(n-octanol/water) N.Av. Decomposition Temp: N.Av. Viscosity: SP #2 @10rpm: 50 to 2000

S e c t i o n 1 0 – S t a b i l i t y a n d R e a c t i v i t y STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None INCOMPATIBILITY: None HAZARDOUS DECOMPOSITION PRODUCTS: None

S e c t i o n 1 1 – T o x i c o l o g i c a l I n f o r m a t i o n No data is available on the mixture.

S e c t i o n 1 2 – E c o l o g i c a l I n f o r m a t i o n No data is available on the mixture.

S e c t i o n 1 3 – D i s p o s a l C o n s i d e r a t i o n s WASTE DISPOSAL:

Dispose in accordance with Local, State, and Federal regulations.

CONTAINER DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.

S e c t i o n 1 4 – T r a n s p o r t I n f o r m a t i o n DOT Hazard Class: Non-Regulated DOT Shipping Name: N/A

S e c t i o n 1 5 - R e g u l a t o r y I n f o r m a t i o n We certify that all components of this mixture are listed on the TSCA inventory.

S e c t i o n 1 6 – O t h e r I n f o r m a t i o n The information herein is given in good faith but no warranty is expressed or implied. History: Original. Rev 1: Changed Formula Number Rev 2: Changed Formula Number End of Report

MATERIAL SAFETY DATA SHEET 12435A INSECT REPELLENT LIQUID SPRAY 1 of 2


www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC INSECT REPELLENT LIQUID PUMP SPRAY UPC CODECHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET) 7 76285 12455 6PRODUCT USE PackagingMOLECULAR WEIGHT NOT APPLICABLE 12 BOTTLES / BOXFORMULA MIXTURET.D.G. CLASSIFICATION ISOPROPANOL SOLUTION, CLASS 3, UN 1219, PACKING GROUP IIWHMIS CLASSIFICATION NOT REGULATEDHMIS RATING: HEALTH 2 MODERATE HAZARDHMIS RATING: FLAMMABILITY 2 MODERATE HAZARDHMIS RATING: REACTIVITY 0 MINIMAL HAZARDSECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species

ISOPROPANOL 30 - 60 400 ppm 67-63-0 >4720 mg/kg ORAL - RAT 12000 ppm (8hr) INHAL - RAT

N,N-DIETHYL m-TOLUAMIDE 30 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT

SECTION THREE HAZARDOUS IDENTIFICATIONROUTE OF ENTRYINGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING AND WEAKNESSINHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATIONEYE CONTACT MAY CAUSE IRRITATIONSKIN CONTACT MAY CAUSE IRRITATIONEFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYESEFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITISEXPOSURE LIMIT OF MATERIAL SEE SECTION TWOSECTION FOUREMERGENCY FIRST AID PROCEDURE

SECTION FIVEAUTO IGNITION TEMPERATURE (° C) 399SPECIAL PROCEDURES WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED

CONTAINERS TO PREVENT BUILD-UP IF EXPOSED TO EXTREMETEMPERATURES. FULL PROTECTIVE EQUIPMENT INCLUDING SELFCONTAINED BREATHING APPARATUS SHOULD BE WORN IN A FIREINVOLVING THIS MATERIAL.

FLAMMABILITY CAUTION-FLAMMABLEIF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAMEEXTINGUISHING MEDIA WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAMUPPER FLAMMABLE LIMIT 12 % BY VOLUME.LOWER FLAMMABLE LIMIT 2.0 % BY VOLUME.EXPLOSION DATA SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE SENSITIVITY TO IMPACT NOT APPLICABLEHAZARDOUS COMBUSTIONPRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETE.FLASH POINT ( C ), TAG CLOSED-CUP >14(CONCENTRATE)SECTION SIX ACCIDENTAL RELEASE MEASURESLEAK/SPILL REMOVE ALL SOURCES OF IGNITION. USE AN INERT ABSORBENT MATERIAL,

AND NON-SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSE

SECTION SEVENSTORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMSENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF USED INDOORS ON A CONTINUOUS BASIS)HANDLING PROCEDURES ANDEQUIPMENT STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.SYNERGISTIC MATERIALS NONE KNOWNWASTE DISPOSAL DISPOSE OF IN ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS



INSECT REPELLENT

FIRE FIGHTING MEASURES


1/29/201511:24 AM ITEM# 12435A DEGIL SAFETY PRODUCTS

MATERIAL SAFETY DATA SHEET 12435A INSECT REPELLENT LIQUID SPRAY 2 of 2

SECTION EIGHT EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES NOT NORMALLY REQUIREDRESPIRATORY NOT NORMALLY REQUIREDEYE SAFETY GLASSESFOOTWEAR NOT NORMALLY REQUIREDOTHER NOT REQUIRED

SECTION NINE PHYSICAL AND CHEMICAL PROPERTIESPHYSICAL STATE LIQUIDAPPEARANCE CLEAR, PALE YELLOW LIQUIDODOR FRAGRANTODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 83EVAPORATION RATE LESS THAN 1n-BUTYL ACETATE = 1VAPOUR DENSITY (AIR=1) GREATER THAN 1(BY WEIGHT)SOLUBILITY IN WATER g/L (20°C) NOT AVAILABLEpH NOT APPLICABLESPECIFIC GRAVITY (LIQUID) 0.88 - 0.92COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLEAEROSOL PERCENT VOLATILE 69 - 70(BY WEIGHT)SECTION TEN STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETECHEMICAL STABILITYYES UNDER NORMAL CONDITIONSNO, WHICH ONES? NOT APPLICABLECOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLESECTION ELEVEN TOXICOLOGICAL INFORMATIONREPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVE

EFFECTS ARE ANTICIPATED.IRRITANCY OF MATERIAL SKIN/EYE IRRITANTSENSITIZING CAPABILITY OF MATERIAL UNKNOWNCARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS


TERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITYEFFECTS ARE ANTICIPATED.

MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENICEFFECTS ARE ANTICIPATED.

SECTION SIXTEEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.It does not constitute a warranty, express or implied, as to the accuracy of the informationcontained herein. Actual conditions of use and handling are beyond seller's control.User is responsible to evaluate all available information when using product for anyparticular use and to comply with all Federal, State, Provincial and local laws andregulations.

Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED JANUARY 29/2015

1/29/201511:24 AM ITEM# 12435A DEGIL SAFETY PRODUCTS

Date Printed: 4/2/2012


24 Hour Assistance:

1-847-367-7700

Rust-Oleum Corp.

www.rustoleum.com

1. Identification

4/2/2012Product Name: ENAMEL 5-GL SAFETY ORANGE Revision Date:

Identification Number: 956300

Product Use/Class: Topcoat/Alkyd

Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA


Supplier: Manufacturer:

Preparer: Regulatory Department

2. Hazard Identification

EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea.

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs.

EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B).

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

3. Composition/Information On Ingredients

Chemical Name CAS-No.Weight %Less Than

ACGIH TLV-TWA

ACGIH TLV-STEL

OSHA PEL-TWAOSHA PEL-CEILING

Stoddard Solvents 8052-41-3 35.0 100 ppm N.E. 500 ppm N.E.Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.Ethylbenzene 100-41-4 1.0 100 ppm 125 ppm 100 ppm N.E.

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.

FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.

FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention.

Page 1 / 4


5. Fire-fighting Measures

Flash Point, °F 104 (Setaflash)

EXTINGUISHING MEDIA: Dry Chemical, Foam, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed.

SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance.


STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.

STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use.

8. Exposure Controls/Personal Protection

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.

Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.

SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking.

9. Physical and Chemical Properties

Vapor Density HEAVIER THAN AIR Odor: Solvent Like

Appearance: Liquid Evaporation Rate: Slower than Ether

Solubility in Water: Slight Freeze Point: N.D.

Specific Gravity: 0.933 pH: N.A.

Physical State: Liquid

(See section 16 for abbreviation legend)

10. Stability and Reactivity

Page 2 / 4


CONDITIONS TO AVOID: Avoid all possible sources of ignition.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.

HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.


Chemical Name LD50 LC50

Stoddard Solvents >5000 mg/kg (Rat, Oral) N.E.

Mineral Spirits >5000 mg/kg (Rat, Oral) >1400 ppm (Rat, Inhalation, 4Hr)

Xylene 4300 mg/kg (Rat, Oral) 5000 ppm (Rat, Inhalation, 4Hr)

Ethylbenzene 3500 mg/kg (Rat, Oral) N.E.


ECOLOGICAL INFORMATION: Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems.


Domestic (USDOT) Air (IATA)International (IMDG)

Proper Shipping Name: Not Regulated Paint Paint

Hazard Class: N.A. 3 3

UN Number: N.A. UN1263 UN1263

Packing Group: N.A. III III

Limited Quantity: No No No


U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:

Fire Hazard, Acute Health Hazard, Chronic Health Hazard

SARA SECTION 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

No Sara 313 components exist in this product.

TOXIC SUBSTANCES CONTROL ACT:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:

Page 3 / 4


No TSCA 12(b)components exist in this product.

International Regulations:

CANADIAN WHMIS:

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.

Canadian WHMIS Class: B3 D2A


HMIS Ratings:

Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X

NFPA Ratings:

Health: 2 Flammability: 2 Instability 0

VOLATILE ORGANIC COMPOUNDS, g/L: 445

REASON FOR REVISION: Regulatory Update

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to beaccurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, andstorage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damageincurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracyor reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used withcaution. The information and recommendations in this material safety data sheet are offered for the users’ consideration andexamination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicableinternational, federal, state, and local laws and regulations.

Page 4 / 4

DOW CORNING CORPORATION Material Safety Data Sheet

Page: 1 of 8 Version: 1.10

Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR

1. PRODUCT AND COMPANY IDENTIFICATION Dow Corning Corporation South Saginaw Road Midland, Michigan 48686

24 Hour Emergency Telephone:

Customer Service: Product Disposal Information:

CHEMTREC:

(989) 496-5900 (989) 496-6000 (989) 496-6315 (800) 424-9300

MSDS No.: 01890573

Revision Date: 2013/04/05

Generic Description: Silicone elastomer Physical Form: Paste

Color: Colorless Odor: Acetic acid odor

NFPA Profile:

Health 1 Flammability 1 Instability/Reactivity 0

Note: NFPA = National Fire Protection Association 2. HAZARDS IDENTIFICATION

POTENTIAL HEALTH EFFECTS

Acute Effects Eye:

Direct contact may cause mild irritation.

Skin:

May cause mild irritation.

Inhalation:

No significant effects expected from a single short-term exposure.

Oral:

Low ingestion hazard in normal use.

Prolonged/Repeated Exposure Effects Skin:

No known applicable information.

Inhalation:


Oral:


Signs and Symptoms of Overexposure


Medical Conditions Aggravated by Exposure





The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.


CAS Number Wt % Component Name

17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane

4253-34-3 1.0 - 5.0 Methyltriacetoxysilane

The above components are hazardous as defined in 29 CFR 1910.1200.

4. FIRST AID MEASURES Eye:

Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while holding the eyelid(s) open. Obtain medical attention.

Skin: No health effects expected. If irritation does occur flush with lukewarm, gently flowing water for 5 minutes. If irritation persists, obtain medical advice.

Inhalation: If symptoms are experienced remove source of contamination or move victim to fresh air. If irritation persists, obtain medical advice.

Oral: If irritation or discomfort occur, obtain medical advice.

Notes to Physician: Treat according to person's condition and specifics of exposure.

5. FIRE FIGHTING MEASURES Flash Point:

Not applicable. Not applicable.

Autoignition Temperature:

Not determined.

Flammability Limits in Air:

Not determined.

Extinguishing Media:

On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

Fire Fighting Measures:

Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool.




Unusual Fire Hazards:

None.

6. ACCIDENTAL RELEASE MEASURES Containment/Clean up:

Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements.

Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required.

7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Keep container closed and store away from water or moisture.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name

Exposure Limits

17689-77-9 Ethyltriacetoxysilane

See acetic acid comments.

4253-34-3 Methyltriacetoxysilane

See acetic acid comments.

Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.

Engineering Controls Local Ventilation: None should be needed. General Ventilation: Recommended.

Personal Protective Equipment for Routine Handling




Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended.

Suitable Gloves:


Inhalation:

No respiratory protection should be needed.

Suitable Respirator:

None should be needed.

Personal Protective Equipment for Spills Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended.

Inhalation/Suitable Respirator:

No respiratory protection should be needed.

Precautionary Measures: Avoid eye contact. Avoid skin contact. Use reasonable care.

Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection.

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions.


Physical Form:

Paste

Color: Colorless Odor: Acetic acid odor

Specific Gravity @ 25°C: 1.04 Viscosity: Not determined.

Freezing/Melting Point: Not determined. Boiling Point: Not determined.

Vapor Pressure @ 25°C: Not determined. Vapor Density: Not determined.

Solubility in Water: Not determined. pH: Not determined.

Volatile Content: Not determined. Flash Point: Not applicable. Not applicable.

Autoignition Temperature: Not determined. Flammability Limits in Air: Not determined.




Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.

10. STABILITY AND REACTIVITY Chemical Stability:

Stable.

Hazardous Polymerization:

Hazardous polymerization will not occur.

Conditions to Avoid:

None.

Materials to Avoid:

Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8.

Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde.

11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components


12. ECOLOGICAL INFORMATION Environmental Fate and Distribution

Complete information is not yet available.

Environmental Effects


Fate and Effects in Waste Water Treatment Plants


Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC50) High Medium Low Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100 Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.




This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material.

13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional information is required.

14. TRANSPORT INFORMATION DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. Call Dow Corning Transportation, (989) 496-8577, if additional information is required.

15. REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA

Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances (40 CFR 355): None. Section 304 CERCLA Hazardous Substances (40 CFR 302):

None.

Section 311/312 Hazard Class (40 CFR 370):

Acute: No Chronic: No




Fire: No Pressure: No Reactive: No

Section 313 Toxic Chemicals (40 CFR 372):

None present or none present in regulated quantities. Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold. Supplemental State Compliance Information California

Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm.

None known. New Jersey

CAS Number

Wt %

Component Name

70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated

7631-86-9 7.0 - 13.0 Silicon dioxide

17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane

4253-34-3 1.0 - 5.0 Methyltriacetoxysilane

Pennsylvania CAS Number

Wt %

Component Name

70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated

7631-86-9 7.0 - 13.0 Silicon dioxide




16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate.

(R) indicates Registered Trademark

of 4

Alkaline Batteries January 2014

©2014 Energizer

PRODUCT SAFETY DATA SHEET

PRODUCT NAME: Eveready / Energizer Battery Type No.: Volts: TRADE NAMES: ENERGIZER, ENERGIZER e², INDUSTRIAL ZMA, HERCULES, EVEREADY, WONDER

Approximate Weight:

CHEMICAL SYSTEM: Alkaline Manganese Dioxide-Zinc Designed for Recharge: No

SECTION 1 - MANUFACTURER INFORMATION

Energizer Battery Manufacturing, Inc. Telephone Number for Information: 25225 Detroit Rd. Westlake, OH 44145

800-383-7323 (USA / CANADA)

Date Prepared: January 2014

SECTION 2 – HAZARDS IDENTIFICATION

Under normal conditions of use, the battery is hermetically sealed.

Ingestion: Swallowing a battery can be harmful. Contents of an open battery can cause serious chemical burns of mouth, esophagus, and gastrointestinal tract. Inhalation: Contents of an open battery can cause respiratory irritation. Skin Contact: Contents of an open battery can cause skin irritation and/or chemical burns. Eye Contact: Contents of an open battery can cause severe irritation and chemical burns.

SECTION 3 - INGREDIENTS

IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful.

MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.

Graphite (CAS# 7782-42-5)

15 mg/m3 TWA (total dust) 5 mg/m3 TWA (respirable fraction)

2 mg/m3 TWA (respirable fraction)

2-6

Manganese Dioxide (CAS# 1313-13-9)

5 mg/m3 Ceiling (as Mn) 0.2 mg/m3 TWA (as Mn) 30-45

Potassium Hydroxide (CAS# 1310-58-3)

None established 2 mg/m3 Ceiling 4-8

Zinc (CAS# 7440-66-6)

15 mg/m3 TWA PNOR* (total dust) 5 mg/m3 TWA PNOR* (respirable fraction)

10 mg/m3 TWA PNOC** (inhalable particulate) 3 mg/m3 TWA PNOC** (respirable particulate)

12-25

Non-Hazardous Components Steel (iron CAS# 7439-89-6) Water, Paper, Plastic and Other

None established None established

None established None established

18-22 Balance

* PNOR: Particulates not otherwise regulated **PNOC: Particulates not otherwise classified

of 4


©2014 Energizer

SECTION 4 – FIRST AID MEASURES

Ingestion: Do not induce vomiting or give food or drink. Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-3333) collect day or night. Inhalation: Provide fresh air and seek medical attention. Skin Contact: Remove contaminated clothing and wash skin with soap and water. If a chemical burn occurs or if irritation persists, seek medical attention. Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention.

SECTION 5 - FIRE FIGHTING MEASURES

In case of fire, it is permissible to use any class of extinguishing medium on these batteries or their packing material. Cool exterior of batteries if exposed to fire to prevent rupture. Fire fighters should wear self-contained breathing apparatus.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

To cleanup leaking batteries:

Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries.

Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container.

SECTION 7 - HANDLING AND STORAGE

Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life.

Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery Manufacturing, Inc. representative for precautionary suggestions. Batteries normally evolve hydrogen which, when combined with oxygen from the air, can produce a combustible or explosive mixture unless vented. If such a mixture is present, short circuits, high temperature, or static sparks can cause an ignition.

Do not obstruct safety release vents on batteries. Encapsulation (potting) of batteries will not allow cell venting and can cause high pressure rupture.

Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices.

If soldering or welding to the battery is required, consult your Energizer Battery Manufacturing, Inc. representative for proper precautions to prevent seal damage or short circuit.

Charging: This battery is manufactured in a charged state. It is not designed for recharging. Recharging can cause battery leakage or, in some cases, high pressure rupture. Inadvertent charging can occur if a battery is installed backwards.

Labeling: If the Eveready / Energizer Battery label or package warnings are not visible, it is important to provide a package and/or device label stating:

WARNING: do not install backwards, charge, put in fire, or mix with other battery types. May explode or leak causing injury. Replace all batteries at the same time.

Where accidental ingestion of small batteries is possible, the label should include:

Keep away from small children. If swallowed, promptly see doctor; have doctor phone (202) 625-3333 collect.

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©2014 Energizer

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

Ventilation Requirements: Not necessary under normal conditions. Respiratory Protection: Not necessary under normal conditions.

Eye Protection: Not necessary under normal conditions. Gloves: Not necessary under normal conditions.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point @ 760 mm Hg (°C) Not applicable for an Article

Vapor Pressure (mm Hg @ 25°C) Not applicable for an Article

Vapor Density (Air = 1) Not applicable for an Article

Density (g/cm3) 2.0 – 3.0

Percent Volatile by Volume (%) Not applicable for an Article

Evaporation Rate (Butyl Acetate = 1) Not applicable for an Article

Physical State Solid

Solubility in Water (% by weight) Not applicable for an Article

pH Not applicable for an Article

Appearance and Odor Solid object / no odor

SECTION 10 – STABILITY AND REACTIVITY

Alkaline batteries do not meet any of the criteria established in 40 CFR 261.2 for reactivity.

SECTION 11 – TOXICOLOGICAL INFORMATION

Alkaline batteries are not hazardous waste. Under normal conditions of use, alkaline batteries are non-toxic.

SECTION 12 – ECOLOGICAL INFORMATION

Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles.

SECTION 13 – DISPOSAL CONSIDERATIONS

Dispose of in accordance with all applicable federal, state and local regulations. Appropriate disposal technologies include incineration and land filling.

of 4


©2014 Energizer

SECTION 14 – TRANSPORT INFORMATION

In general, all batteries in all forms of transportation (ground, air, or ocean) must be packaged in a safe and responsible manner. Regulatory concerns from all agencies for safe packaging require that batteries be packaged in a manner that prevents short circuits and be contained in “strong outer packaging” that prevents spillage of contents. All original packaging for Energizer alkaline batteries has been designed to be compliant with these regulatory concerns. Alkaline batteries (sometimes referred to as “Dry cell” batteries) are not listed as dangerous goods under the ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road, the IMDG International Maritime Dangerous Goods Code, UN Dangerous Good Regulations, IATA Dangerous Goods Regulations, ICAO Technical Instructions and the U.S. hazardous materials regulations (49 CFR). These batteries are not subject to the dangerous goods regulations provided they meet the requirements contained in the following special provisions.

Regulatory Body Special Provisions

ADR Not regulated

IMDG Not regulated

UN Not regulated

US DOT 49 CFR 172.102 Provision 130

IATA A123

ICAO Not regulated

All Energizer alkaline batteries are packed in such a way to prevent short circuits or the generation dangerous quantities of heat and meet the special provisions listed above. In addition, the IATA Dangerous Goods Regulations and ICAO Technical Instructions require the words “not restricted” and the Special Provision number A123 be provided on the air waybill, when an air waybill is issued.

SECTION 15 - REGULATORY INFORMATION

Batteries marketed by Energizer Battery Manufacturing, Inc. are not classified as dangerous goods by the US Department of Transportation or the major international regulatory bodies and are therefore not regulated. SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To-Know Act.

SECTION 16 - OTHER INFORMATION

None. Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. As defined in OSHA Hazard Communication Standard, Section 1910.1200 (c), Eveready/Energizer batteries are manufactured articles, which do not result in exposure to a hazardous chemical under normal conditions of use. The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC., MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT.

1

BOSS LUBRICANTS: MATERIAL SAFETY DATA SHEET

Date Issued: 01/01/2012

PRODUCT INFORMATION

Product Trade Name: BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30

Product Use: Lubricating oil

COMPOSITION/INFORMATION ON INGREDIENTS

OSHA Hazardous Components (29 CFR 1910.1200)

1-Decene, Homopolymer, Hydrogenated Base,

CAS # Mixture, 85-95%

HAZARDS IDENTIFICATION

Potential health effects: Minor eye, inhalation and skin irritant.

FIRST AID MEASURES

EYE: Flush with water for 15-20 minutes.

Seek medical attention if irritation develops.

SKIN: Wash immediately with soap and water.

Remove contaminated clothing and launder before reuse.

Discard shoes and leather articles saturated with the product.

Obtain medical advice if irritation occurs.

INHALATION: Remove exposed person to fresh air.

If breathing is labored give oxygen. If breathing has stopped apply artificial

respiration.

Get immediate medical attention.

INGESTION: DO NOT INDUCE VOMITING.

If conscious, give 2 glasses of water. If vomiting does occur, keep head below

hips to reduce risk of aspiration. Get immediate medical attention.

FIRE FIGHTING MEASURES

FLAMMABILITY PROPERTIES:

Flash Point 236ºC

Method COC ASTM-D-92

LFL/IFL Not determined

Auto-ignition Temperature Not determined

BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30

2


EXTINGUISHING MEDIA

Carbon dioxide, dry chemical, and alcohol foam.

FIREFIGHTING EQUIPMENT

Full bunker gear recommended including a positive pressure self-contained

breathing apparatus.

ACCIDENTAL RELEASE MEASURES

Isolate spill area. Provide adequate ventilation. Wear appropriate personal protection. Recover

free product for recycle and/or disposal. Add sand, earth or other suitable to spill area.

Prevent entry into sewers and waterways. Check under Transportation and Labeling

(DOT/CERCLA) and other Regulator Information Section (SARA) for hazardous substances to

determine regulatory reporting requirements for spill.


HANDLING: Keep containers closed.

Avoid contact with eyes, skin or clothing.

Wash hands after handling.

Empty container may retain product residue, which may exhibit

hazards of product.

STORAGE: Keep away from heat or flame.

EXPOSURE CONTROLS/PERSONAL PROTECTION

VENTILATION: Use adequate general or local exhaust ventilation to keep

airborne concentrations below exposure limits.

RESPIRATORY: Use a NIOSH approved respirator when necessary.

SKIN: Use Viton or Nitrile gloves to avoid prolonged or repeated

skin contact.

EYE: Use splash goggles or face shield where splashing is expected

or can occur.

EXPOSURE LIMITS: The Threshold Limit Value (TLV) of 5 mg/m is suggested

For oil mist.


3


PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid

Boiling point Not Determined

Vapor Pressure Not Determined

Vapor Density (Air=1) Negligible

Evaporation Rate Not Determined

Solubility in Water Negligible

Specific Gravity (Water=1) 0.8686

Volatility (Volume) Negligible

VOC Unknown

pH Essentially Neutral

Coefficient of Water/Oil Distribution Not Determined

Odor Mild, Bland, Hydrocarbon Odor

Odor Threshold Not Determined

Appearance Amber Transparent Colored Liquid

Viscosity, cST @ 100ºC 10.70

Viscosity, cST @ 40ºC 62.30

Viscosity Index 161

Refractive Index 1.4664

Fire Point 250ºC

Pour Point -42ºC

STABILITY AND REACTIVITY

STABLILITY: Stable under moderately elevated temperatures and

Pressures.

INCOMPATABILITY: Avoid contact with strong oxidants.

HAZARDOUS POLYMERIZATION: Will not occur.

HAZARDOUS DECOMPOSITION: Toxic oxides of carbon, aldehydes and other products

Of PRODUCT of incomplete combustion.

TOXICOLOGICAL INFORMATION

EYE IRRITATION: Moderate to strong eye irritation. Based on data from components

or similar material.


4


TOXICOLOGICAL INFORMATION (CONT’D)

SKIN IRRITATION: Not expected to be a primary skin irritant. Based on data from

Components or similar material. Prolonged or repeated skin contact as

from clothing wet with material may cause dermatitis. Symptoms may

include redness, edema, drying, defatting, and cracking of the skin.

RESPIRATORY If material is misted or if vapors are generated from heating, exposure

IRRITATION: may cause irritation of mucous membranes and the upper respiratory

tract similar to that observed with mineral oil. Based on data from

components or similar materials. Under good industrial hygiene

practices where all exposure limits are observed, respiratory irritation

should not be a problem.

CHRONIC EXPOSURE

CHRONIC TOXICITY: No data available to indicate product present at greater than 1.0%

are chronic health hazards.

CARCINOGENICITY: No data available to indicate product present at greater than 1.0%

are a carcinogenic.

MUTAGENICITY: No data available to indicate product present at greater than 1.0%

present a mutagenic or genotoxic hazard.

REPRODUCTIVE No data available to indicate product present at greater than 1.0%

TOXICITY: present a reproductive hazard.

TERATOGENICITY: No data available to indicate product present at greater than 1.0%

Present a teratogenic hazards.

ADDITIONAL INFORMATION

EXPOSURE LIMITS: Under conditions which may generate mists, observe the OSHA PEL

mg 5 mg per cubic meter.

ECOLOGICAL INFORMATION

No data available on the adverse effects of this product on the environment.


5


DISPOSAL CONSIDERATIONS

If this product as supplied becomes a waste, it does not meet the criteria of a hazardous waste as

defined under the Resource Conservation and Recovery Act 9RCRA) 40 CFR 261.

TRANSPORT INFORMATION

This product is not classified as hazardous material for DOT shipping. For further information

relative to spills resulting from transportation incidents, refer to the latest DOT Emergency

Response Guidebook for Hazardous Materials.

REGULATORY INFORMATION

U.S. Federal Regulations

OSHA Table Z Synthetic Base Stock (mist)

TSCA Not Applicable

CERCLA 40 CFR 302.4 Zinc compounds @ 1.30 – 2.58% RQ 1 lb

SARA Title III

Section 311/312

Fire Hazard Yes

Reactive Hazard No

Release of Pressure No

Acute Health Hazard Yes

Chronic Health Hazard No

Section 313 Toxic Chemical Not Applicable

U.S. State Regulations

California (Prop 65)

Does not contain chemicals known to the state of California to cause cancer.

International Regulations

WHMIS All components listed

OTHER INFORMATION

The information contained herein is based on data considered accurate, to the best of BOSS

LUBRICANTS’S knowledge, however, no warranty is expressed or implied regarding the accuracy of

these data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury

or third person proximately caused by the material if reasonable safety procedures are not adhered to as

stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third

person proximatley caused by abnormal use of the material even if reasonable safety procedures are

followed. Furthermore, vendee assumes the risk in his use of the material.




Material name GASOLINE - ETHANOL BLENDED

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 2738

Product use Motor fuels.

Synonym(s) Unleaded Gasoline * Gasoline * Regular Gasoline * Premium Gasoline * Premium UnleadedGasoline * Mid Grade Gasoline * Gasoline (Export) * Petroleum Naphtha * Alkylate





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec



Appearance Amber liquid.

Emergency overview DANGER!Extremely flammable liquid and vapor - vapor may cause flash fire or explosion. Staticaccumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment.

Harmful if inhaled, absorbed through skin, or swallowed. Aspiration may cause lung damage.Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists arenarcotic and may cause headache, fatigue, dizziness and nausea. Cancer hazard. May causeheritable genetic damage. Toxic to aquatic organisms. May cause long-term adverse effects in theaquatic environment.

OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).


Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.

Eyes Contact may irritate or burn eyes. Eye contact may result in corneal injury.

Skin Harmful if absorbed through skin. Irritating to skin. Frequent or prolonged contact may defat anddry the skin, leading to discomfort and dermatitis.

Inhalation Harmful if inhaled. Irritating to respiratory system. In high concentrations, vapors and spray mistsare narcotic and may cause headache, fatigue, dizziness and nausea. May cause breathingdisorders and lung damage. May cause cancer by inhalation. Prolonged inhalation may beharmful.

Ingestion Harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungsmust be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth,throat, and stomach.

Target organs Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system.

CPH MSDS NA

1 / 9

GASOLINE - ETHANOL BLENDED CPH MSDS NA


Chronic effects Cancer hazard. Contains material which may have reproductive toxicity, teratogenetic ormutagenic effects. Liver injury may occur. Kidney injury may occur. May cause central nervoussystem disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mentalconfusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and drythe skin, leading to discomfort and dermatitis.

Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation.Unconsciousness. Corneal damage. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/orskin). Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice.Conjunctivitis. Proteinuria. Defatting of the skin. Rash.

Potential environmental effects Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.



86290-81-5 60-100Gasoline

64-17-5 5-10Ethanol

71-43-2 1-5Benzene




Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention.

Skin contact Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water.Get medical attention if irritation develops or persists. Wash clothing separately before reuse.Destroy or thoroughly clean contaminated shoes.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.Get medical attention if discomfort develops or persists.

Ingestion Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Ifvomiting occurs, keep head low so that stomach content does not get into the lungs. Get medicalattention immediately.

Notes to physician In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.Symptoms may be delayed.

General advice If exposed or concerned: get medical attention/advice. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance. Wash contaminated clothing before re-use.


Flammable properties Extremely flammable liquid and vapor - vapor may cause flash fire.

Extinguishing media


mediaWater. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).


mediaDo not use a solid water stream as it may scatter and spread fire.



from the chemicalVapor may cause flash fire. Vapors can flow along surfaces to distant ignition source and flashback. Sensitive to static discharge.

Protective equipment and

precautions for firefightersWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask.

Fire fighting

equipment/instructionsWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask. Withdraw immediately in case ofrising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire frommaximum distance or use unmanned hose holders or monitor nozzles. Move containers from firearea if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containersexposed to flames with water until well after the fire is out. For massive fire, use unmanned hoseholders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Vapors mayform explosive air mixtures even at room temperature. Prevent buildup of vapors or gases toexplosive concentrations. Some of these materials, if spilled, may evaporate leaving a flammableresidue. Water runoff can cause environmental damage.

CPH MSDS NA

2 / 9



Specific methods In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopenedcontainers.


productsCarbon monoxide. Carbon Dioxide. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons.


Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spillagescannot be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces beforeentering. Do not touch damaged containers or spilled material unless wearing appropriateprotective clothing. See Section 8 of the MSDS for Personal Protective Equipment.

Environmental precautions If facility or operation has an "oil or hazardous substance contingency plan", activate itsprocedures. Stay upwind and away from spill. Wear appropriate protective equipment includingrespiratory protection as conditions warrant. Do not enter or stay in area unless monitoringindicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew.Flammable. Review Firefighting Measures, Section 5, before proceeding with clean up. Keep allsources of ignition (flames , smoking, flares, etc.) and hot surfaces away from release. Containspill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stopleak if it can be done without risk. Use water spray to disperse vapors. Spilled material may beabsorbed by an appropriate absorbent, and then handled in accordance with environmentalregulations. Prevent spilled material from entering sewers, storm drains, other unauthorizedtreatment or drainage systems and natural waterways. Contact fire authorities and appropriatefederal, state and local agencies. If spill of any amount is made into or upon navigable waters, thecontiguous zone, or adjoining shorelines, contact the National Response Center at1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300.

Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leakif you can do so without risk. This material is a water pollutant and should be prevented fromcontaminating soil or from entering sewage and drainage systems and bodies of water. Dike thespilled material, where this is possible. Prevent entry into waterways, sewers, basements orconfined areas.

Methods for cleaning up Small Spills: Absorb spill with vermiculite or other inert material, then place in a container forchemical waste. Clean surface thoroughly to remove residual contamination. This material and itscontainer must be disposed of as hazardous waste.

Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the productand place into a container for later disposal. Prevent product from entering drains. Do not allowmaterial to contaminate ground water system. Should not be released into the environment.



Handling Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Avoidcontact with eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged exposure. Useonly with adequate ventilation. Wash thoroughly after handling. The product is flammable, andheating may generate vapors which may form explosive vapor/air mixtures. DO NOT handle, storeor open near an open flame, sources of heat or sources of ignition. Protect material from directsunlight. Take precautionary measures against static discharges. All equipment used whenhandling the product must be grounded. Use non-sparking tools and explosion-proof equipment.When using, do not eat, drink or smoke. Avoid release to the environment.

Storage Flammable liquid storage. Do not handle or store near an open flame, heat or other sources ofignition. This material can accumulate static charge which may cause spark and become anignition source. The pressure in sealed containers can increase under the influence of heat. Keepcontainer tightly closed in a cool, well-ventilated place. Keep away from food, drink and animalfeedingstuffs. Keep out of the reach of children.




ValueTypeComponents

STELBenzene (CAS 71-43-2) 2.5 ppm

TWA 0.5 ppm

STELEthanol (CAS 64-17-5) 1000 ppm

STELGasoline (CAS 86290-81-5) 500 ppm

TWA 300 ppm

CPH MSDS NA

3 / 9



US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

ValueTypeComponents

STELBenzene (CAS 71-43-2) 5 ppm

TWA 1 ppm


ValueTypeComponents

PELEthanol (CAS 64-17-5) 1900 mg/m3

1000 ppm

US. OSHA Table Z-2 (29 CFR 1910.1000)

ValueTypeComponents

CeilingBenzene (CAS 71-43-2) 25 ppm


ValueTypeComponents

STELBenzene (CAS 71-43-2) 8 mg/m3

2.5 ppm

TWA 1.6 mg/m3

0.5 ppm

TWAEthanol (CAS 64-17-5) 1880 mg/m3

1000 ppm


TWA 300 ppm



ValueTypeComponents


TWA 0.5 ppm



TWA 300 ppm


ValueTypeComponents


TWA 0.5 ppm



TWA 300 ppm


ValueTypeComponents

STELBenzene (CAS 71-43-2) 15.5 mg/m3

5 ppm

TWA 3 mg/m3

1 ppm


1000 ppm


ValueTypeComponents

STELBenzene (CAS 71-43-2) 16 mg/m3

5 ppm

TWA 3.2 mg/m3

1 ppm


1000 ppm

Engineering controls Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaustventilation, or other engineering controls to control airborne levels below recommended exposurelimits. Use explosion-proof equipment.


Eye / face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles.

Skin protection Wear chemical-resistant, impervious gloves. Full body suit and boots are recommended whenhandling large volumes or in emergency situations. Flame retardant protective clothing isrecommended.

CPH MSDS NA

4 / 9



Respiratory protection Wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressuremode with emergency escape provisions.

General hygiene

considerationsAvoid contact with skin. Keep away from food and drink. Provide eyewash station and safetyshower. Handle in accordance with good industrial hygiene and safety practice.


Appearance Amber liquid.


Form Liquid.

Color Amber.

Odor Gasoline-like.

Odor threshold < 0.25 ppm

pH Not available.

Vapor pressure > 1 (Air=1)

Vapor density 3 - 4 ( Air=1)

Boiling point 77 - 392 °F (25 - 200 °C)

Melting point/Freezing point Not available.

Solubility (water) Insoluble


Flash point < -40 °F (< -40 °C) Closed Cup


upper, % by volume

7.1 %


lower, % by volume

1.2 %

Auto-ignition temperature 842 °F (450 °C)

VOC 100 %

Evaporation rate 4 (Butyl acetate = 1)


Chemical stability Stable under normal temperature conditions and recommended use.

Conditions to avoid Heat, flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize,cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, staticelectricity, or other sources of ignition; they may explode and cause injury or death.



productsCarbon monoxide. Carbon dioxide. Sulfur oxides. Hydrocarbons.


reactionsHazardous polymerization does not occur.


Test Results

Toxicological data

Components Species

Ethanol (CAS 64-17-5)

LC50 Rat

Inhalation

Acute

20000 mg/l, 10 Hours

LD50 Rat

Oral

7060 mg/kg

Sensitization This substance may have a potential for sensitization which may provoke an allergic reactionamong sensitive individuals.

Acute effects Harmful if inhaled, absorbed through skin, or swallowed. Harmful: may cause lung damage ifswallowed. Irritating to eyes, respiratory system and skin. In high concentrations, vapors andspray mists are narcotic and may cause headache, fatigue, dizziness and nausea.

CPH MSDS NA

5 / 9



Local effects


Benzene (CAS 71-43-2) Can be absorbed through the skin.

Chronic effects Prolonged and repeated exposure to benzene may cause serious injury to blood forming organsand is associated with anemia and to the later development of acute myelogenous leukemia(AML). Danger of serious damage to health by prolonged exposure. Prolonged or repeatedoverexposure may cause central nervous system, kidney, liver, and lung damage.

Subchronic effects Subchronic inhalation of benzene by rats produced decreased white blood cell counts, decreasedbone marrow cell activity, increased red blood cell activity and cataracts. Blood disorders mayoccur after prolonged inhalation, prolonged skin contact and/or ingestion. Liver and kidneydamage may occur after prolonged and repeated exposure.

Carcinogenicity Cancer hazard. Contains benzene, a classified IARC 1 chemical (Known Human Carcinogen).

ACGIH Carcinogens

Benzene (CAS 71-43-2) A1 Confirmed human carcinogen.

Ethanol (CAS 64-17-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.

Gasoline (CAS 86290-81-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.


Benzene (CAS 71-43-2) 1 Carcinogenic to humans.

Gasoline (CAS 86290-81-5) 2B Possibly carcinogenic to humans.

US NTP Report on Carcinogens: Known carcinogen

Benzene (CAS 71-43-2) Known To Be Human Carcinogen.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Benzene (CAS 71-43-2) Cancer hazard.

Epidemiology Contains benzene. Human epidemiology studies indicate that prolonged and/or repeatedoverexposure to benzene may cause damage to the blood-producing system and serious blooddisorders, including leukemia. Animal tests suggest that prolonged and/or repeated overexposureto benzene may damage the embryo/fetus. The relevance of these animal studies to humans hasnot been fully established.

Mutagenicity May cause heritable genetic damage.

Neurological effects Central and/or peripheral nervous system damage. May cause central nervous system disorder(e.g., narcosis involving a loss of coordination, weakness, fatigue) and/or damage.

Reproductive effects Animal studies of benzene have shown testicular effects, alterations in reproductive cycles,chromosomal aberrations and embryo/fetotoxicity. May damage fertility or the unborn child. Cancause adverse reproductive effects - such as birth defects, miscarriages, or infertility. Avoidexposure to women during early pregnancy. Avoid contact during pregnancy/while nursing.

Further information Symptoms may be delayed.


Ecotoxicological data

Components Test ResultsSpecies

Benzene (CAS 71-43-2)

Aquatic

EC50Crustacea 8.76 - 15.6 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish 5.3 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)

Ethanol (CAS 64-17-5)

Aquatic

EC50Crustacea 7.7 - 11.2 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)

Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment.

Environmental effects The product contains a substance which is toxic to aquatic organisms and which may causelong-term adverse effects in the aquatic environment.

Aquatic toxicity Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Persistence and degradability Not available.

CPH MSDS NA

6 / 9



Bioaccumulation /


Partition coefficient

Ethanol -0.31

Benzene 2.13


Waste codes D001: Waste Flammable material with a flash point <140 °FD018: Waste Benzene

Disposal instructions Dispose in accordance with all applicable regulations. Dispose of this material and its container tohazardous or special waste collection point. Incinerate the material under controlled conditions inan approved incinerator. Do not allow this material to drain into sewers/water supplies. Do notcontaminate ponds, waterways or ditches with chemical or used container.


DOT

UN1203UN number


Gasoline, MARINE POLLUTANTProper shipping name

3Hazard class

IIPacking group

YesMarine pollutant


144, 177, B1, B33, IB2, T4, TP1 Special provisions




242Packaging bulk

IATA

UN1203UN number

GasolineUN proper shipping name


IIPacking group

YesEnvironmental hazards

3HERG code

IMDG

UN1203UN number

GASOLINE, MARINE POLLUTANTUN proper shipping name


IIPacking group

YesMarine pollutant


F-E, S-EEmS No.

TDG

GASOLINE, MARINE POLLUTANTProper shipping name

3Hazard class

UN1203UN number

IIPacking group

YesMarine pollutant

17, 82, 88Special provisions


US federal regulations


Not regulated.


Benzene (CAS 71-43-2)


Benzene (CAS 71-43-2) 0.1 %

CPH MSDS NA

7 / 9




Benzene (CAS 71-43-2) Listed.


Gasoline: 100Benzene: 10


Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No




No


370)Yes

Drug Enforcement


1308.11-15)

Not controlled


WHMIS classification B2 - Flammable LiquidsD1A - Immediate/Serious-VERY TOXICD2A - Other Toxic Effects-VERY TOXICD2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory status







YesEurope






YesPhilippines



State regulations



Ethanol (CAS 64-17-5) Listed.



US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Benzene (CAS 71-43-2) Listed: February 27, 1987 Carcinogenic.

US - California Proposition 65 - CRT: Listed date/Developmental toxin

Benzene (CAS 71-43-2) Listed: December 26, 1997 Developmental toxin.

CPH MSDS NA

8 / 9



US - California Proposition 65 - CRT: Listed date/Male reproductive toxin

Benzene (CAS 71-43-2) Listed: December 26, 1997 Male reproductive toxin.




US - Pennsylvania RTK - Hazardous Substances: Special hazard

Benzene (CAS 71-43-2) Special hazard.





Benzene (CAS 71-43-2) 500 LBS




Gasoline (CAS 86290-81-5) Listed.



HMIS® ratings Health: 2*Flammability: 4Physical hazard: 0



CPH MSDS NA

9 / 9




1. Product and Company IdentificationMaterial name KeroseneRevision date 10-25-2011Version # 01Product code 106Product use Heating and illuminating oil.Synonym(s) VARSOL 3139 SOLVENT

(613) 996-6666 - Canutec(306) 244-3447

Federated Co-operative Limited(416) 968-4415Toronto, ON M5W 1K3111 ST. Clair Avenue WestImperial Oil; Chemical Division

24 Hour EmergencyTelephone

Telephone

AddressSupplierTelephone

AddressManufacturer

P.O. Box 1050, 401 - 22nd StreetEast Saskatoon SK S7K 3M9 Canada

2. Hazards IdentificationPhysical state Liquid.Appearance Clear liquid.Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed or

vomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.

OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.Potential health effects

Routes of exposure Inhalation. Skin contact. Ingestion.Eyes Direct contact with eyes may cause temporary irritation.Skin Prolonged or repeated contact may dry skin and cause irritation.Inhalation Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and

respiratory tract irritation.Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.

Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms maybe delayed.

Signs and symptoms Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation.Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.




8052-41-3 60-100Stoddard solvent

64742-47-8 30-60Distillates, (petroleum), Hydrotreated Light

95-63-6 1-51,2,4-Trimethylbenze ne

100-41-4 0.1-1Ethylbenzene

91-20-3 0.1-1Naphthalene

1330-20-7 0.1-1Xylene


CPH MSDS NA

1 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-2011

07-12-2012

Contact supplier for current manufacturer.

07-12-201207-12-2012

4. First Aid MeasuresFirst aid procedures


Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully

conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.


5. Fire Fighting MeasuresFlammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containers

may explode when heated.Extinguishing media

Suitable extinguishingmedia


Unsuitable extinguishingmedia

None known.

Fire fightingequipment/instructions


Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.Hazardous combustionproducts

Carbon oxides.

6. Accidental Release MeasuresPersonal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for

Personal Protective Equipment.Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry into

waterways, sewer, basements or confined areas.Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible

material like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.




7. Handling and StorageHandling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrial

hygiene practices.Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container at

room temperature. Store away from incompatible materials.

8. Exposure Controls / Personal ProtectionOccupational exposure limits

US. ACGIH Threshold Limit ValuesValueTypeComponents

1,2,4-Trim ethyl benze ne (95-63-6)

TWA 25 ppm

Ethylbenze ne (100-41-4) TWA 20 ppmNaphthalen e (91-20-3) STEL 15 ppm

TWA 10 ppmStoddard solvent (8052-41-3)

TWA 100 ppm

CPH MSDS NA

2 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-2012 07-12-2012

US. ACGIH Threshold Limit ValuesValueTypeComponents

Xylene (1330-20-7) STEL 150 ppmTWA 100 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ValueTypeComponents

Ethylbenze ne (100-41-4) PEL 435 mg/m3100 ppm

Naphthalen e (91-20-3) PEL 50 mg/m310 ppm

Stoddard solvent (8052-41-3)

PEL 2900 mg/m3

500 ppmXylene (1330-20-7) PEL 435 mg/m3

100 ppmCanada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

FormValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

TWA 123 mg/m3

25 ppmDistillate s, (petroleum ),Hydrotreat ed Light (64742-47-8)

TWA 200 mg/m3 Vapor.

Ethylbenze ne (100-41-4) STEL 543 mg/m3125 ppm

TWA 434 mg/m3100 ppm

Naphthalen e (91-20-3) STEL 79 mg/m315 ppm

TWA 52 mg/m310 ppm


TWA 572 mg/m3

100 ppmCanada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health andSafety Regulation 296/97, as amended)

FormValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

TWA 25 ppm

Distillate s, (petroleum ),Hydrotreat ed Light (64742-47-8)

TWA 200 mg/m3 Non-aerosol.

Ethylbenze ne (100-41-4) STEL 125 ppmTWA 100 ppm

Naphthalen e (91-20-3) STEL 15 ppmTWA 10 ppm


STEL 580 mg/m3

TWA 290 mg/m3Xylene (1330-20-7) STEL 150 ppm

TWA 100 ppmCanada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)

ValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

TWA 123 mg/m3

25 ppmEthylbenze ne (100-41-4) STEL 540 mg/m3

125 ppmTWA 435 mg/m3

100 ppm

CPH MSDS NA


Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)ValueTypeComponents

Naphthalen e (91-20-3) STEL 78 mg/m315 ppm

TWA 52 mg/m310 ppm


TWA 525 mg/m3

Xylene (1330-20-7) STEL 650 mg/m3150 ppm

TWA 435 mg/m3100 ppm

Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)ValueTypeComponents

1,2,4-Trim ethyl benze ne (95-63-6)

TWA 123 mg/m3



100 ppmNaphthalen e (91-20-3) STEL 79 mg/m3

15 ppmTWA 52 mg/m3

10 ppmStoddard solvent (8052-41-3)

TWA 525 mg/m3

100 ppmXylene (1330-20-7) STEL 651 mg/m3


100 ppmMexico. Occupational Exposure Limit Values

ValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

STEL 170 mg/m3

35 ppmTWA 125 mg/m3



100 ppmNaphthalen e (91-20-3) STEL 75 mg/m3

15 ppmTWA 50 mg/m3

10 ppmStoddard solvent (8052-41-3)

STEL 1050 mg/m3


100 ppmXylene (1330-20-7) STEL 655 mg/m3


100 ppmEngineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of

inhalation of vapors.Personal protective equipment

Eye / face protection Use approved safety goggles or face shield.Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.Respiratory protection In case of inadequate ventilation, use respiratory protection.

CPH MSDS NA


General hygieneconsiderations


9. Physical & Chemical PropertiesAppearance Clear liquid.

Color Clear, colorless.

Odor Mild. Petroleum.



Form Liquid.

pH Not applicable.

Melting point < -65.2 °F (< -54 °C)

Freezing point < -65.2 °F (< -54 °C)

Boiling point 327.2 - 397.4 °F (164 - 203 °C)

Flash point 116.6 °F (47 °C) Closed Cup

Evaporation rate 0.01 (Butyl acetate = 1)

Flammability limits in air, upper,% by volume

6 %

Flammability limits in air, lower,% by volume

1.1 %

Vapor pressure 0.03 kPa

Vapor density 5

Specific gravity 0.8 (15.5°C)

Solubility (water) Very slightly soluble in the following materials: cold water and hot water.

Partition coefficient(n-octanol/water)

Not available.


Decomposition temperature Not available.

VOC 0.81 % w/w

Percent volatile 100 % w/w

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts


Possibility of hazardousreactions

Will not occur.

Toxicological data


Product Test Results

Acute Dermal LD50 Rabbit: 471.476 g/kg estimatedKerosene

Acute Dermal LD50 Rat: 4714.7574 g/kg estimatedAcute Inhalation LC50 Rat: 86434.1588 ppm estimatedAcute Inhalation LC50 Rat: 86434.1588 mg/l estimatedAcute Other LD50 Mouse: 22579.9501 mg/kg estimated

Components Test Results

Acute Dermal LD50 Rabbit: > 5000 mg/kgEthylbenzene (100-41-4)

Acute Oral LD50 Rat: 5.46 g/kg

CPH MSDS NA

5 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-201207-12-2012

Components Test Results

Acute Oral LD50 Rat: 4300 mg/kgXylene (1330-20-7)

Acute Dermal LD50 Rabbit: > 2 g/kgNaphthalene (91-20-3)

Acute Oral LD50 Rat: 490 mg/kgAcute Dermal LD50 Rabbit: > 3160 mg/kg1,2,4-Trimethylbenzene (95-63-6)

Acute Inhalation LC50 Rat: 18000 mg/m3 4 hoursAcute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contact

may dry skin and cause irritation. Overexposure to mists/vapours of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.

Local effectsUS ACGIH Threshold Limit Values: Skin designation

Naphthalene (CAS 91-20-3) Can be absorbed through the skin.Sensitization None known.Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

ACGIH CarcinogensEthylbenzene (CAS 100-41-4) A3 Confirmed animal carcinogen with unknown relevance to

humans.Naphthalene (CAS 91-20-3) A4 Not classifiable as a human carcinogen.Xylene (CAS 1330-20-7) A4 Not classifiable as a human carcinogen.

IARC Monographs. Overall Evaluation of CarcinogenicityEthylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.Naphthalene (CAS 91-20-3) 2B Possibly carcinogenic to humans.Stoddard solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

US NTP Report on Carcinogens: Anticipated carcinogenNaphthalene (CAS 91-20-3) Anticipated carcinogen.

Ecotoxicological data


Product Test Results

EC50 Daphnia: 267.4925 mg/l 48 hours estimatedKeroseneComponents Test Results

EC50 Water flea (Daphnia magna): 1 - 4 mg/l 48 hoursEthylbenzene (100-41-4)LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 4mg/l 96 hoursLC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 8mg/l 96 Hours

Xylene (1330-20-7)

EC50 Water flea (Daphnia magna): 1.09 - 3.4 mg/l 48 hoursNaphthalene (91-20-3)LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss):0.91 - 2.82 mg/l 96 hoursLC50 Fathead minnow (Pimephales promelas): 7.19 - 8.28 mg/l96 hours

1,2,4-Trimethylbenzene (95-63-6)

Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Persistence anddegradability

No data available.

Bioaccumulation /Accumulation

No data available.


Not available.

Mobility in environmentalmedia

No data available.

CPH MSDS NA


13. Disposal ConsiderationsWaste codes D001: Waste Flammable material with a flash point <140 °FDisposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competent

authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.

Waste from residues / unusedproducts



14. Transport InformationDOT

Basic shipping requirements:UN1268UN numberPetroleum distillates, n.o.s.Proper shipping nameCombustible LiquidHazard classIIIPacking group3Labels required

Additional information:144, T11, TP1, TP8Special provisions150Packaging exceptions201Packaging non bulk243Packaging bulk128ERG number

IATABasic shipping requirements:

1268UN numberPetroleum distillates, n.o.s. (Stoddard solvent)Proper shipping name3Hazard classIIIPacking group

Additional information:3HERG code

IMDGBasic shipping requirements:

1268UN numberPETROLEUM DISTILLATES, N.O.S. (Stoddard solvent)Proper shipping name3Hazard classIIIPacking groupF-E, S-EEmS No.

TDGBasic shipping requirements:

PETROLEUM DISTILLATES, N.O.S. (Stoddard solvent)Proper shipping name3Hazard classUN1268UN numberIIIPacking group·Marine pollutant

15. Regulatory InformationUS federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.

All components are on the U.S. EPA TSCA Inventory List.TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)

Not regulated.US CAA Section 112 Hazardous Air Pollutants (HAPs) List

ETHYLBENZENE (CAS 100-41-4)M-XYLENES (CAS 1330-20-7)NAPHTHALENE (CAS 91-20-3)

CPH MSDS NA


US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration1,2,4-Trimethylbenzene (CAS 95-63-6) 1.0 %Ethylbenzene (CAS 100-41-4) 0.1 %Naphthalene (CAS 91-20-3) 0.1 %Xylene (CAS 1330-20-7) 1.0 %

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Xylene (CAS 1330-20-7) Listed.

CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)Ethylbenze ne: 1000Naph thalene: 100Xylen e: 100

Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes

Delayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

Section 302 extremelyhazardous substance (40CRF 355, Appendix A)

No

Section 311/312 (40 CFR370)

No

Drug EnforcementAdministration (DEA) (21 CFR1308.11-15)

Not controlled


WHMIS status ControlledWHMIS classification B3 - Flammable/Combustible

D2A - Other Toxic Effects-VERY TOXICD2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory statusCountry(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical

Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

State regulations WARNING: This product contains chemicals known to the State of California to cause cancer.

CPH MSDS NA


US - California Hazardous Substances (Director's): Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceEthylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substanceEthylbenzene (CAS 100-41-4) Listed: June 11, 2004 Carcinogenic.Naphthalene (CAS 91-20-3) Listed: April 19, 2002 Carcinogenic.

US - Massachusetts RTK - Substance: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Distillates, (petroleum), Hydrotreated Light (CAS64742-47-8)

Listed.

Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.

US - New Jersey Community RTK (EHS Survey): Reportable threshold1,2,4-Trimethylbenzene (CAS 95-63-6) 500 LBSDistillates, (petroleum), Hydrotreated Light (CAS64742-47-8)

10000 LBS

Ethylbenzene (CAS 100-41-4) 500 LBSNaphthalene (CAS 91-20-3) 500 LBSXylene (CAS 1330-20-7) 500 LBS

US - New Jersey RTK - Substances: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.

US - Pennsylvania RTK - Hazardous Substances: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Distillates, (petroleum), Hydrotreated Light (CAS64742-47-8)

Listed.

Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.

16. Other InformationHMIS® ratings Health: 2

Flammability: 2Physical hazard: 0




CPH MSDS NA


07-12-2012


1. Product and Company IdentificationMaterial name SOLVENTRevision date 09-16-2011Version # 01CAS # 8052-41-3Product code 2183Product use Solvent. Fuel. Diluter Feedstock.Synonym(s) VARSOL 3139 SOLVENT

(613) 996-6666 - Canutec(306) 244-3447

Federated Co-operative Limited-Richmond, BC V6X 1W5 Canada9800 Van Home WayUnivar Canada Ltd.

24 Hour EmergencyTelephone

Telephone

AddressSupplierTelephone

AddressManufacturer

P.O. Box 1050, 401 - 22nd StreetEast Saskatoon SK S7K 3M9 Canada

2. Hazards IdentificationPhysical state Liquid.Appearance Clear liquid.Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed or

vomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.

OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.Potential health effects

Routes of exposure Inhalation. Skin contact. Ingestion.Eyes Direct contact with eyes may cause temporary irritation.Skin Prolonged or repeated contact may dry skin and cause irritation.Inhalation Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and

respiratory tract irritation.Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.

Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms maybe delayed.

Signs and symptoms Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation.Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.




8052-41-3 60-100Stoddart solvent


4. First Aid MeasuresFirst aid procedures


CPH MSDS NA

1 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-2011

Contact supplier for current manufacturer.

07-12-2012

07-12-2012 07-12-2012

Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully

conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.


5. Fire Fighting MeasuresFlammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containers

may explode when heated.Extinguishing media

Suitable extinguishingmedia


Unsuitable extinguishingmedia

None known.

Fire fightingequipment/instructions


Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.Hazardous combustionproducts

Carbon oxides.

6. Accidental Release MeasuresPersonal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for

Personal Protective Equipment.Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry into

waterways, sewer, basements or confined areas.Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible

material like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.




7. Handling and StorageHandling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrial

hygiene practices.Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container at

room temperature. Store away from incompatible materials.

8. Exposure Controls / Personal ProtectionOccupational exposure limits

US. ACGIH Threshold Limit ValuesValueTypeMaterial

Stoddart solvent (8052-41-3)

TWA 100 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ValueTypeMaterial


PEL 2900 mg/m3

500 ppmCanada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

ValueTypeMaterialStoddart solvent (8052-41-3)

TWA 100 ppm

CPH MSDS NA

2 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-2012 07-12-2012

Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)ValueTypeMaterial572 mg/m3

Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health andSafety Regulation 296/97, as amended)


TWA 290 mg/m3

STEL 580 mg/m3Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)


TWA 525 mg/m3

Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)ValueTypeMaterial


TWA 100 ppm

525 mg/m3Mexico. Occupational Exposure Limit Values


TWA 100 ppm

STEL 1050 mg/m3200 ppm

TWA 523 mg/m3Engineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of

inhalation of vapors.Personal protective equipment

Eye / face protection Use approved safety goggles or face shield.Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.Respiratory protection In case of inadequate ventilation, use respiratory protection.General hygieneconsiderations


9. Physical & Chemical PropertiesAppearance Clear liquid.

Color Clear, colorless.

Odor Mild. Petroleum.



Form Liquid.

pH Not applicable.

Melting point -72.4 °F (-58 °C)

Freezing point Not available.

Boiling point 316.4 - 383 °F (158 - 195 °C)

Flash point 109.4 °F (43 °C) Closed Cup

Evaporation rate 0.1 (Butyl acetate = 1)

Flammability limits in air, upper,% by volume

13.3 %

Flammability limits in air, lower,% by volume

1 %

Vapor pressure 0.04 kPa

Vapor density 5

Specific gravity 0.79 (15.5°C)

CPH MSDS NA

3 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-201207-12-2012

Solubility (water) Not available.


Not available.


Decomposition temperature Not available.

VOC 100 %

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts


Possibility of hazardousreactions

Will not occur.

11. Toxicological InformationAcute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contact

may dry skin and cause irritation. Overexposure to mists/vapours of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.

Sensitization None known.Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of CarcinogenicityStoddart solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.

12. Ecological InformationEcotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Persistence anddegradability

No data available.

Bioaccumulation /Accumulation

No data available.


Not available.

Mobility in environmentalmedia

No data available.

13. Disposal ConsiderationsWaste codes D001: Waste Flammable material with a flash point <140 °FDisposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competent

authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.

Waste from residues / unusedproducts



14. Transport InformationProduct Specific Note: This product meets the limited quantities exception as follows:

IMDG: Limited quantities up to 5 liters.Otherwise, the above descriptions apply.

DOTBasic shipping requirements:

UN1268UN numberPetroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking group

CPH MSDS NA


3Labels requiredAdditional information:

144, B1, IB3, T4, TP1, TP29Special provisions150Packaging exceptions203Packaging non bulk242Packaging bulk128ERG number

IATABasic shipping requirements:

UN1268UN numberPetroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking group3Labels required

Additional information:150Packaging exceptions203Packaging non bulk242Packaging bulk

IMDGBasic shipping requirements:

1268UN numberPETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking groupF-E, S-EEmS No.

TDGBasic shipping requirements:

Petroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classUN1268UN numberIIIPacking group

Additional information:144, B1, IB3, T4, TP1, TP29Special provisions

Basic shipping requirements:3Labels required

Additional information:150Packaging exceptions203Packaging non bulk242Packaging bulk

15. Regulatory InformationUS federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.

All components are on the U.S. EPA TSCA Inventory List.TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)

Not regulated.CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)

NoneSuperfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

Section 302 extremelyhazardous substance (40CRF 355, Appendix A)

No

Section 311/312 (40 CFR370)

No

CPH MSDS NA


Drug EnforcementAdministration (DEA) (21 CFR1308.11-15)

Not controlled


WHMIS status ControlledWHMIS classification B3 - Flammable/Combustible

D2B - Other Toxic Effects-TOXICWHMIS labeling

Inventory statusCountry(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical

Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)


US - California Hazardous Substances (Director's): Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

US - Massachusetts RTK - Substance: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

US - New Jersey RTK - Substances: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

US - Pennsylvania RTK - Hazardous Substances: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

16. Other InformationHMIS® ratings Health: 2

Flammability: 2Physical hazard: 0




CPH MSDS NA


07-12-2012

*Trademarks of Imperial Oil Limited. Imperial Oil, Licensee. Lubricants and Specialties, Marketing Technical Services ™Trademark of Exxon Corporation. Imperial Oil, Licensee. Helplines: 1-800-268-3183

Esso Gear Oil GX Extra is an API GL-6 quality oil specifically designed for severe service with shock loading ♦ Esso Gear Oil GX Extra is a premium

multi-service, extreme pressure, sulphur-phosphorus type gear oil recommended for the high performance requirements of API service classification GL-5 and GL-6.

♦ A synthetic blended product available in 75W-90, and 80W-140 grades

Primary Applications Esso Gear Oil GX Extra is a multi-service, non-corrosive type hypoid gear lubricant recommended for API service GL-5 and the more severe API service GL-6 (now obsolete). GL-6 is defined by the American Petroleum Institute as designating those lubricants suitable for the lubrication of gears, particularly hypoid gears, in passenger cars, trucks and other equipment operating under high speed, severe shock loaded; high speed, low torque; and low speed, high torque conditions. Esso Gear Oil GX Extra is recommended for most manual transmissions, reducers, differentials, and final drives used in passenger cars, trucks, construction and mining equipment, farm tractors and industrial equipment requiring API GL-5 orGL-6 performance levels. Esso Gear Oil GX Extra 75W-90 is suitable as an all-season lubricant for manual transmissions and differentials in most passenger car and light duty vehicles - including Ford high off-set hypoid gears. The exceptions include those differentials which require limited slip performance for which Esso Gear Oil LS 80W-90 is recommended and manual transmissions and transaxles for which specific OEM or API service GL-4 lubricants are specified. Esso Gear Oil GX Extra is recommended for most equipment in severe service, particularly in the differentials and planetary gears in mining and woodland trucks, where maximum protection is required.

ESSO GEAR OIL GX EXTRA

AUTOMOTIVE GEAR OILS

April 2009

ESSO GEAR OIL GX EXTRA

AUTOMOTIVE GEAR OILS

April 2009

*Trademarks of Imperial Oil Limited. Imperial Oil, Licensee. Lubricants and Specialties, Marketing Technical Services ™Trademark of Exxon Corporation. Imperial Oil, Licensee. Helplines: 1-800-268-3183

Esso Gear Oil GX Extra is recommended for Mack GO-F specification. For Mack Trucks specifying GO-H or GO-J oils, use Esso Gear Oil GX 80W-90 or 85W-140. Esso Gear Oil GX Extra is also suitable for worm gear drives and axles. Performance Features Anti-Score Protection Esso Gear Oil GX Extra meets API service level GL-6 score levels. This provides excellent gear tooth wear protection in high off-set hypoid and shock loaded conditions. Multi-Temperature Service Esso Gear Oil GX Extra 80W-140 offers both good low temperature performance and protection at high operating temperatures. For extreme low temperature operating conditions, Esso Gear Oil GX Extra 75W-90 is recommended. This high quality synthetic blend offers improved low temperature flow characteristics without sacrificing performance at high operating temperatures. Under low temperature start-up conditions, the channel point and viscosity are important, since lubricants should flow readily between contacting surfaces. The temperature at which the lubricant reaches a viscosity of 1500 Poise is used to define low temperature properties, and is

based on a series of tests in a specific rear axle design. These tests have shown that pinion bearing failure has occurred at Brookfield viscosity higher than 1500 Poise. Other axle designs may tolerate higher viscosities, and the typical properties of Esso Gear Oil GX Extra should be used only as a guide. Corrosion Protection, Filterability, Foam Protection, Seal Compatibility, Oil Compatibility and Storage Stability properties are similar to those of Esso Gear Oil GX. Precautions Esso Gear Oil GX Extra is manufactured from quality petroleum base stocks, blended with selected additives. As with all petroleum products, good personal hygiene and careful handling should always be practiced. Avoid prolonged contact with the skin, splashing into the eyes, ingestion, or vapour inhalation. Please refer to the Esso Material Safety Data Sheet for further information. Note: This product is NOT controlled under the Canadian WHMIS legislation.

Typical Properties Esso Gear Oil GX Extra 75W-90 80W-140 Density @ 15 °C 903 894 Flash, COC, °C 150 160 Kinematic Viscosity cSt @ 40 °C 93 268 cSt @ 100 °C 15.9 27.4 Viscosity Index 182 134 Brookfield Viscosity, cP @ -40°C 90,000 @ -26°C 130,000 Pour Point, °C -48 -33 Channel Point, °C <-45 <-36 Colour 1.0 1.0 The values shown above are representative of current production. Some are controlled by manufacturing and performance specifications while others are not. All may vary within modest ranges.

SECTION 1 - PRODUCT INFORMATION

Product Identifier: 06-134 Q.D. SHOP PRIMER - RED

Product Use: Protective Coating

Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.

Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave

City: Vancouver Province: BC City: Vancouver Province: BC

Postal Code: V6A 3L5

Emergency Phone: (604) 253-4022



SECTION 2 - HAZARDOUS INGREDIENTS

Hazardous Ingredients(Specific)

% CAS Number

LD 50 of Ingredient(Specify

species,route)

LC 50 of Ingredient(Specify

species)

ETHYLBENZENE 0.27 - 0.73 100-41-4 3500 MG/KG(ORAL, RAT)

4000 PPM(VAPOR, RAT)

TOLUENE 12 - 13 108-88-3 2600 MG/KG(ORAL, RAT)


IRON OXIDE FUME 7 1309-37-1 NOT AVAILABLE NOT AVAILABLE

XYLENE (MIXED ISOMERS)

14 - 15 1330-20-7 5400 MG/KG(ORAL, RAT)


LOW FLASH NAPTHA ALIPHATIC

7 - 11 64742-89-8 NOT AVAILABLE NOT AVAILABLE

SECTION 3 - PHYSICAL DATA


Odour and Appearance: liquid with a solvent smell

Coating VOC(gm/l): 498

Odour Threshold(ppm): Not Available

Specific Gravity: 1.25

Vapor Density(air=1): Not Available

Vapor Pressure(mmHg): Not Available

Evaporation Rate: Not Available

Boiling Point(º C ): Not Available

Freezing Point(º C ): Not Available

pH: Not Applicable

Coefficient of Water/Oil Distribution:

Not Available

SECTION 4 - FIRE AND EXPLOSION DATA

Flammability:Yes If yes, Under which Conditions?Flammable Liquid

Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam

Flashpoint and Method: 9 °C Closed Cup

Upper Flammable Lt (% by Volume):Not Available

Lower Flammable Lt (% by Volume):Not Available

Autoignition Temperature: Not Available

Explosion Data - Sensitivity to Impact: No

Explosion Data - Sensitivity to Static discharges: No

Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, calcium oxide, aldehydes, magnesium oxide, formaldehyde, nitrogen oxides

SECTION 5 - REACTIVITY DATA

Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable

Incompatibility with other substances:Yes

If yes, which ones? Strong Acids Strong Oxidizing agents

Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfur dichloride, tetranitromethane, dichlorohydrantion, heat, sparks, or other ignition sources, generation of dust

Hazardous Decomposition Products:carbon dioxide

SECTION 6 - TOXICOLOGICAL PROPERTIES

Route of Entry

Skin Contact: Yes Absorption: Yes

Eye Contact: Yes

Inhalation: Yes Ingestion: Yes

Effects to Acute exposure to Product: ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and DERMATITIS. TOLUENE has been known to cause FATIGE, WEAKNESS, INCOORDINATION, HEADACHE and DIZZINESS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION and SKIN AND EYE IRRITATION. LOW FLASH NAPTHA ALIPHATIC has been known to cause NAUSEA, HEADACHE, VOMITING and EUPHORIA.

Effects to Chronic exposure to Product: ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. TOLUENE has been known to cause IMPARED MEMORY, IMPARED SPEECH, IMPARED VISION, IMPARED HEARING, DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. LOW FLASH NAPTHA ALIPHATIC has been known to cause DERMATITIS, LIVER DAMAGE, KIDNEY DAMAGE, SNS, CENTRAL NERVOUS SYSTEM DAMAGE.

Exposure Limits (Value,Units,By) ETHYLBENZENE: 100 ppm ACGIH TOLUENE: 150 ppm OSHA IRON OXIDE FUME: 5 mg/m3 ACGIH XYLENE (MIXED ISOMERS): 100 ppm ACGIH LOW FLASH NAPTHA ALIPHATIC: N/A

Irritancy (if yes, explain) ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) TOLUENE is a skin and eye irritant. (MODERATE SKIN IRRITANT) XYLENE (MIXED ISOMERS) is a skin and eye irritant.

Sensitization (if yes, explain) Carcinogenicity (if yes, explain) ETHYLBENZENE is considered to be a Animal carcinogen. The agent is not likely to cause cancer

in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI. ETHYLBENZENE is possibly carcinogenic to humans(2B) by IARC.

Reproductive Toxicity (if yes, explain) LOW FLASH NAPTHA ALIPHATIC may damage the reproductive system.

Teratogenicity (if yes, explain) TOLUENE may cause birth defects. (REDUCED FETAL WEIGHT AND BEHAVIOURAL EFFECTS) XYLENE (MIXED ISOMERS) may cause birth defects.

Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)

SECTION 7 - PREVENTIVE MEASURES

Personal Protective Equipment

Gloves: Yes

Respirator: Yes

Eye: Yes Footwear: No

Clothing: No

Other: No

If checked, specify type: Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT

Engineering controls (specify such as ventilation, enclosed process): Use mechanical ventilation to reduce exposure.

Leak and Spill Procedure: Wear adequate protective equipment and eliminate all ignition sources. Contain spill with absorbant material and place in a suitable covered and labeled container for disposal.

Waste Disposal: Check with Federal, Provincial and local government regulations and requirements for disposal.

Handling Procedures and Equipment: Use in a well ventilated area. Do not use with incompatible substances.

Storage Requirements: Store in a cool, well ventilated area out of direct sunlight.

Special Shipping Information: TDG Shipping Name: PAINT Classification: 3.2 Packing Group: II Identification Number: UN1263

SECTION 8 - FIRST AID MEASURES

Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.

Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert, give two glasses of water. Seek medical attention immediately.

Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse. Flush with large amounts of soap and water. If irritation persists, seek medical attention.

Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, while holding eyelids open or until irritation subsides. If irritation persist, get medical attention.

SECTION 9 - PREPARATION INFORMATION

Prepared by: General Paint Technical Dept

Phone: (604) 253-3131

Preparation Date: Feb 27, 2012


Product Identifier: 06-154 ANTI-CORROSIVE PRIMER - RED











% CAS Number


species,route)


species)

ETHYLBENZENE 1 - 5 100-41-4 3500 MG/KG(ORAL, RAT)


TOLUENE 6 108-88-3 2600 MG/KG(ORAL, RAT)


IRON OXIDE FUME 7 1309-37-1 NOT AVAILABLE NOT AVAILABLE

XYLENE (MIXED ISOMERS)

18 - 21 1330-20-7 5400 MG/KG(ORAL, RAT)


LOW FLASH NAPTHA ALIPHATIC

2.22 - 3.7 64742-89-8 NOT AVAILABLE NOT AVAILABLE

NAPHTHA, VM & P 3.16 - 3.49 8032-32-4 NOT AVAILABLE 3400 PPM(VAPOR, RAT)

N-DIBUTYL PHTHALATE 1.17 84-74-2 8000 MG/KG(ORAL, RAT)

25 PPM(VAPOR, MOUSE)












pH: Not Applicable


Not Available










Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, calcium oxide, aldehydes, magnesium oxide, formaldehyde, phthalic anhydride, nitrogen oxides




If yes, which ones? Strong Acids Strong Oxidizing agents Strong Bases

Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfur dichloride, tetranitromethane, dichlorohydrantion, heat, sparks, or other ignition sources, generation of dust, igniton sources



Route of Entry


Eye Contact: Yes


Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and DERMATITIS. TOLUENE has been known to cause FATIGE, WEAKNESS, INCOORDINATION, HEADACHE and DIZZINESS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION and SKIN AND EYE IRRITATION. LOW FLASH NAPTHA ALIPHATIC has been known to cause NAUSEA, HEADACHE, VOMITING and EUPHORIA. N-DIBUTYL PHTHALATE has been known to cause EYE IRRITATION, STOMACH IRRITATION and UPPER RESPITORY TRACT IRRITATION.

Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DEPRESSION. TOLUENE has been known to cause IMPARED MEMORY, IMPARED SPEECH, IMPARED VISION, IMPARED HEARING, DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. LOW FLASH NAPTHA ALIPHATIC has been known to cause DERMATITIS, LIVER DAMAGE, KIDNEY DAMAGE, SNS, CENTRAL NERVOUS SYSTEM DAMAGE. NAPHTHA, VM & P has been known to cause DERMATITIS.

Exposure Limits (Value,Units,By) ETHYLBENZENE: 100 ppm ACGIH TOLUENE: 150 ppm OSHA IRON OXIDE FUME: 5 mg/m3 ACGIH XYLENE (MIXED ISOMERS): 100 ppm ACGIH LOW FLASH NAPTHA ALIPHATIC: N/A NAPHTHA, VM & P: 300 ppm ACGIH N-DIBUTYL PHTHALATE: 5 mg/m3 ACGIH

Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) TOLUENE is a skin and eye irritant. (MODERATE SKIN IRRITANT) XYLENE (MIXED ISOMERS) is a skin and eye irritant. NAPHTHA, VM & P is a skin and eye irritant.

Sensitization (if yes, explain) Carcinogenicity (if yes, explain) ETHYLBENZENE is considered to be a Animal carcinogen. The agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI. ETHYLBENZENE is possibly carcinogenic to humans(2B) by IARC. NAPHTHA, VM & P is considered to be a Animal carcinogen. The agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI.

Reproductive Toxicity (if yes, explain) LOW FLASH NAPTHA ALIPHATIC may damage the reproductive system. N-DIBUTYL PHTHALATE may damage the reproductive system.

Teratogenicity (if yes, explain) TOLUENE may cause birth defects. (REDUCED FETAL WEIGHT AND BEHAVIOURAL EFFECTS) XYLENE (MIXED ISOMERS) may cause birth defects. N-DIBUTYL PHTHALATE may cause birth defects.




Gloves: Yes

Respirator: Yes

Eye: Yes Footwear: No

Clothing: No

Other: No







Special Shipping Information: TDG Shipping Name: PAINT Classification: 3.2 Packing Group: II Identification Number: UN1263








Phone: (604) 253-3131

Preparation Date: Feb 27, 2012



Product Identifier:10-010 LOW ODOR ALKYD INT GLO





Postal Code:V6A 3L5

Emergency Phone:(604) 253-4022

Postal Code:V6A 3L5

EmergencyPhone:(604) 253-4022


HazardousIngredients(Specific)

% CASNumber

LD 50 ofIngredient(Specify

species,route)

LC 50 ofIngredient(Specify

species)

TITANIUM DIOXIDE 19 - 23 13463-67-7 NOT AVAILABLE NOT AVAILABLE

HEAVY NAPTHA(HYDROTREATED)

13 64742-48-9 NOT AVAILABLE NOT AVAILABLE

MINERAL SPIRITS 24 - 25 8052-41-3 5000 MG/KG(ORAL,RAT)

5500 PPM(VAPOR,RAT)


PhysicalState:Liquid

Odour andAppearance:liquid with a solventsmell

Coating VOC(gm/l):417

OdourThreshold(ppm):Not Available

SpecificGravity:1.1

VaporDensity(air=1):Not Available

VaporPressure(mmHg):Not Available

Evaporation Rate:Not Available

Boiling Point(C ):Not Available

Freezing Point( C ):Not Available

pH:Not Applicable

Coefficient ofWater/OilDistribution:

Not Available


Flammability:YesIf yes, Under which Conditions?Flammable Liquid


Flashpoint and Method:45 C Closed Cup

Upper Flammable Lt (%by Volume):Not Available

Lower Flammable Lt (%by Volume):Not Available

Autoignition Temperature:Not Available

Explosion Data -Sensitivity to Impact: No

Explosion Data -Sensitivity to Staticdischarges: No

Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, sulfuroxides



Incompatibility with othersubstances:Yes

If yes, which ones?Strong AcidsStrong Oxidizing agents

Reactivity, and under what conditions?heat, ignition sources, generation of dust, flame,sparks, other ignition sources, nitric acid, dichlorohydrantion, heat, sparks, or other ignition sources

Hazardous Decomposition Products:


Route ofEntry

Skin Contact:Yes

Absorption:Yes

Eye Contact:Yes

Inhalation:Yes

Ingestion:Yes

Effects to Acute exposure to Product:HEAVY NAPTHA (HYDROTREATED) has been known to cause HEADACHE, DIZZINESS andOTHER CENTRAL NERVOUS SYSTEM EFFECTS. MINERAL SPIRITS has been known to causeEYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT, DIZZINESS and DERMATITIS.

Effects to Chronic exposure to Product:MINERAL SPIRITS has been known to cause NARCOSIS, CENTRAL NERVOUS SYSTEMDEPRESSION.

Exposure Limits (Value,Units,By)TITANIUM DIOXIDE: 10 mg/m3 ACGIH

HEAVY NAPTHA (HYDROTREATED): 1200 mg/m3 Manufacturer (ESSO)MINERAL SPIRITS: 100 PPM ACGIH

Irritancy (if yes, explain)MINERAL SPIRITS is a skin and eye irritant. (MILD)

Sensitization (if yes, explain) Carcinogenicity (if yes, explain)TITANIUM DIOXIDE is possibly carcinogenic tohumans(2B) by IARC.

Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)



PersonalProtectiveEquipment

Gloves:Yes

Respirator:Yes

Eye: Yes Footwear:No

Clothing:No

Other: No

If checked, specify type:Respirator: NIOSH APPROVED Gloves: BUTYL RUBBER Eye: SPLASH RESISTANT

Engineering controls (specify such as ventilation, enclosed process):Use mechanical ventilation to reduce exposure.

Leak and Spill Procedure:Wear adequate protective equipment and eliminate all ignition sources. Contain spill withabsorbant material and place in a suitable covered and labeled container for disposal.

Waste Disposal:Check with Federal, Provincial and local government regulations and requirements fordisposal.

Handling Procedures and Equipment:Use in a well ventilated area. Do not use with incompatible substances.

Storage Requirements:Store in a cool, well ventilated area out of direct sunlight.

Special Shipping Information:TDG Shipping Name: PAINT Classification: 3.3 Packing Group: III Identification Number:UN1263



Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert,give two glasses of water. Seek medical attention immediately.

Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse.Flush with large amounts of soap and water. If irritation persists, seek medical attention.

Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, whileholding eyelids open or until irritation subsides. If irritation persist, get medical attention.


Prepared by:General Paint Technical Dept

Phone:(604) 253-3131

Preparation Date:Jun 17, 2010



Product Identifier:10-122 CO-OP RUST - GLOSS WHI





Postal Code:V6A 3L5


Postal Code:V6A 3L5




% CASNumber


species,route)


species)

ETHYLBENZENE 0.11 -0.22

100-41-4 3500 MG/KG(ORAL,RAT)

4000 PPM(VAPOR,RAT)

XYLENE (MIXEDISOMERS)

0.55 -1.1

1330-20-7 5400 MG/KG(ORAL,RAT)

6350 PPM(VAPOR,RAT)


MINERAL SPIRITS 17 64742-88-7 5000 MG/KG(ORAL,RAT)

5500 PPM(VAPOR,RAT)


5500 PPM(VAPOR,RAT)


Physical Odour and Coating VOC(gm/l): Odour

State:Liquid

Appearance:liquid with a solventsmell

440 Threshold(ppm):Not Available

SpecificGravity:1.12






pH:Not Applicable


Not Available














If yes, which ones?Strong AcidsStrong Oxidizing agentsStrong Bases

Reactivity, and under what conditions?heat, ignition sources, potassium t-butoxide, nitric acid,sulfuric acid, sulfur dichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks,or other ignition sources



Route ofEntry

Skin Contact:Yes

Absorption:Yes

Eye Contact:Yes

Inhalation:Yes

Ingestion:Yes

Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and

DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUSSYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION andSKIN AND EYE IRRITATION. MINERAL SPIRITS has been known to cause CONJUNCTIVITIS,CORNEAL DAMAGE, NAUSEA, VOMITING, DIARRHEA, HEADACHE and DIZZINESS. MINERALSPIRITS has been known to cause EYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT,DIZZINESS and DERMATITIS.

Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. XYLENE(MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS.MINERAL SPIRITS has been known to cause DERMATITIS. MINERAL SPIRITS has been knownto cause NARCOSIS, CENTRAL NERVOUS SYSTEM DEPRESSION.

Exposure Limits (Value,Units,By)ETHYLBENZENE: 100 ppm ACGIHXYLENE (MIXED ISOMERS): 100 ppm ACGIHTITANIUM DIOXIDE: 10 mg/m3 ACGIHMINERAL SPIRITS: 100 mg/m3 ACGIHMINERAL SPIRITS: 100 PPM ACGIH

Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) XYLENE(MIXED ISOMERS) is a skin and eye irritant. MINERAL SPIRITS is a skin and eye irritant.(MILD)

Sensitization (if yes, explain) Carcinogenicity (if yes, explain)ETHYLBENZENE is considered to be a Animalcarcinogen. The agent is not likely to causecancer in humans except under uncommon orunlikely routes or levels of exposure(A3) byACGHI. ETHYLBENZENE is possiblycarcinogenic to humans(2B) by IARC.TITANIUM DIOXIDE is possibly carcinogenic tohumans(2B) by IARC.

Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)XYLENE (MIXED ISOMERS) may cause birthdefects.




Gloves:Yes

Respirator:Yes


Clothing:No

Other: No

If checked, specify type:Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT














Phone:(604) 253-3131



Product Identifier: 10-134 MARINE RUST MID BLUE










Hazardous Ingredients(Specific) % CAS Number LD 50 of Ingredient(Specify

species,route)

LC 50 of Ingredient(Specify species)

ETHYLBENZENE 0.18 - 0.33 100-41-4 3500 MG/KG(ORAL, RAT) 4000 PPM(VAPOR, RAT)

XYLENE (MIXED ISOMERS) 0.5 - 1.5 1330-20-7 5400 MG/KG(ORAL, RAT) 6350 PPM(VAPOR, RAT)

TITANIUM DIOXIDE 2.79 - 3.49 13463-67-7 NOT AVAILABLE NOT AVAILABLE

MINERAL SPIRITS 18 - 19 64742-88-7 5000 MG/KG(ORAL, RAT) 5500 PPM(VAPOR, RAT)

MINERAL SPIRITS 29 - 31 8052-41-3 5000 MG/KG(ORAL, RAT) 5500 PPM(VAPOR, RAT)












pH: Not Applicable


Not Available








Explosion Data - Sensitivity to Impact: No Explosion Data - Sensitivity to Static discharges: No

Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, sulfur oxides, isobutylene



Incompatibility with other substances:Yes If yes, which ones? Strong Acids Strong Oxidizing agents Strong Bases

Reactivity, and under what conditions?heat, ignition sources, potassium t-butoxide, nitric acid, sulfuric acid, sulfur dichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks, or other ignition sources, heat (temperatures above 194°c)



Route of Entry Skin Contact: Yes Absorption: Yes Eye Contact: Yes Inhalation: Yes Ingestion: Yes

Effects to Acute exposure to Product: ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION and SKIN AND EYE IRRITATION. MINERAL SPIRITS has been known to cause CONJUNCTIVITIS, CORNEAL DAMAGE, NAUSEA, VOMITING, DIARRHEA, HEADACHE and DIZZINESS. MINERAL SPIRITS has been known to cause EYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT, DIZZINESS and DERMATITIS.

Effects to Chronic exposure to Product: ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. XYLENE (MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. MINERAL SPIRITS has been known to cause DERMATITIS. MINERAL SPIRITS has been known to cause NARCOSIS, CENTRAL NERVOUS SYSTEM DEPRESSION.

Exposure Limits (Value,Units,By) ETHYLBENZENE: 100 ppm ACGIH XYLENE (MIXED ISOMERS): 100 ppm ACGIH TITANIUM DIOXIDE: 10 mg/m3 ACGIH MINERAL SPIRITS: 100 mg/m3 ACGIH MINERAL SPIRITS: 100 PPM ACGIH

Irritancy (if yes, explain) ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) XYLENE (MIXED ISOMERS) is a skin and eye irritant. MINERAL SPIRITS is a skin and eye irritant. (MILD)

Sensitization (if yes, explain) Carcinogenicity (if yes, explain) ETHYLBENZENE is considered to be a Animal carcinogen. The agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI. ETHYLBENZENE is possibly carcinogenic to humans(2B) by IARC. TITANIUM DIOXIDE is possibly carcinogenic to humans(2B) by IARC.

Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain) XYLENE (MIXED ISOMERS) may cause birth defects.




Gloves: Yes Respirator: Yes Eye: Yes Footwear: No Clothing: No Other: No







Special Shipping Information: TDG Shipping Name: PAINT Classification: 3.3 Packing Group: III Identification Number: UN1263








Phone: (604) 253-3131

Preparation Date: Oct 06, 2010



Product Identifier:11-890 LOW SHEEN NON-SLIP EN.-Q.D.GREY





Postal Code:V6A 3L5


Postal Code:V6A 3L5




% CASNumber


species,route)


species)

ETHYLBENZENE 2.11 -2.81

100-41-4 3500 MG/KG(ORAL,RAT)

4000 PPM(VAPOR,RAT)

TOLUENE 8 108-88-3 2600 MG/KG(ORAL,RAT)

8800 PPM(VAPOR,RAT)


8 1330-20-7 5400 MG/KG(ORAL,RAT)

6350 PPM(VAPOR,RAT)

TITANIUM DIOXIDE 2.92 -3.64

13463-67-7 NOT AVAILABLE NOT AVAILABLE

LOW FLASH NAPTHAALIPHATIC

2.28 -3.09

64742-89-8 NOT AVAILABLE NOT AVAILABLE












pH:Not Applicable


Not Available















Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfurdichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks, or other ignitionsources



Route ofEntry

Skin Contact:Yes

Absorption:Yes

Eye Contact:Yes

Inhalation:Yes

Ingestion:Yes

Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE andDERMATITIS. TOLUENE has been known to cause FATIGE, WEAKNESS, INCOORDINATION,HEADACHE and DIZZINESS. XYLENE (MIXED ISOMERS) has been known to cause CENTRALNERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS,INCOORDINATION and SKIN AND EYE IRRITATION. LOW FLASH NAPTHA ALIPHATIC has beenknown to cause NAUSEA, HEADACHE, VOMITING and EUPHORIA.

Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION.TOLUENE has been known to cause IMPARED MEMORY, IMPARED SPEECH, IMPARED VISION,IMPARED HEARING, DERMATITIS. XYLENE (MIXED ISOMERS) has been known to causeLIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. LOW FLASH NAPTHA ALIPHATIC has beenknown to cause DERMATITIS, LIVER DAMAGE, KIDNEY DAMAGE, SNS, CENTRAL NERVOUSSYSTEM DAMAGE.

Exposure Limits (Value,Units,By)ETHYLBENZENE: 100 ppm ACGIHTOLUENE: 150 ppm OSHAXYLENE (MIXED ISOMERS): 100 ppm ACGIHTITANIUM DIOXIDE: 10 mg/m3 ACGIHLOW FLASH NAPTHA ALIPHATIC: N/A

Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) TOLUENE isa skin and eye irritant. (MODERATE SKIN IRRITANT) XYLENE (MIXED ISOMERS) is a skin andeye irritant.


Reproductive Toxicity (if yes, explain)LOW FLASH NAPTHA ALIPHATIC may damagethe reproductive system.

Teratogenicity (if yes, explain)TOLUENE may cause birth defects. (REDUCEDFETAL WEIGHT AND BEHAVIOURAL EFFECTS)XYLENE (MIXED ISOMERS) may cause birthdefects.




Gloves:Yes

Respirator:Yes


Clothing:No

Other: No















Phone:(604) 253-3131




Product Identifier:32-001 EXTERIOR ALKYD PRIMER





Postal Code:V6A 3L5


Postal Code:V6A 3L5




% CASNumber


species,route)


species)

ETHYLBENZENE 0.1 - 1 100-41-4 3500 MG/KG(ORAL,RAT)

4000 PPM(VAPOR,RAT)


0.33 -0.66

1330-20-7 5400 MG/KG(ORAL,RAT)

6350 PPM(VAPOR,RAT)


NAPTHA PETROLIUM,LIGHT ALKYLATE

6 64741-66-8 NOT AVAILABLE NOT AVAILABLE

MINERAL SPIRITS 13 64742-88-7 5000 MG/KG(ORAL,RAT)

5500 PPM(VAPOR,RAT)


5500 PPM(VAPOR,RAT)












pH:Not Applicable


Not Available










Hazardous Combustion Pdts:oxides of sulfur, aluminum oxide, carbon monoxide, carbon dioxide,calcium oxide, aldehydes, nitrogen oxides, sulfur oxides, magnesium oxide





Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfurdichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks, or other ignitionsources



Route ofEntry

Skin Contact:Yes

Absorption:Yes

Eye Contact:Yes

Inhalation:Yes

Ingestion:Yes

Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE andDERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUSSYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION andSKIN AND EYE IRRITATION. MINERAL SPIRITS has been known to cause CONJUNCTIVITIS,CORNEAL DAMAGE, NAUSEA, VOMITING, DIARRHEA, HEADACHE and DIZZINESS. MINERALSPIRITS has been known to cause EYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT,DIZZINESS and DERMATITIS.

Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. XYLENE(MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS.MINERAL SPIRITS has been known to cause DERMATITIS. MINERAL SPIRITS has been knownto cause NARCOSIS, CENTRAL NERVOUS SYSTEM DEPRESSION.

Exposure Limits (Value,Units,By)ETHYLBENZENE: 100 ppm ACGIHXYLENE (MIXED ISOMERS): 100 ppm ACGIHTITANIUM DIOXIDE: 10 mg/m3 ACGIHNAPTHA PETROLIUM, LIGHT ALKYLATE: 1400 mg/m3 Imperial Oil (manufacturer)MINERAL SPIRITS: 100 mg/m3 ACGIHMINERAL SPIRITS: 100 PPM ACGIH

Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) XYLENE(MIXED ISOMERS) is a skin and eye irritant. MINERAL SPIRITS is a skin and eye irritant.(MILD)


Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)XYLENE (MIXED ISOMERS) may cause birthdefects.




Gloves:Yes

Respirator:Yes


Clothing:No

Other: No















Phone:(604) 253-3131


Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX

Revision Date: 18 May 2012 Page 1 of 10

______________________________________________________________________________________________________________________

MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT

Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX Product Description: Glycol MSDS Number: 8514 Product Code: 35101010A0H7 Intended Use: Antifreeze/coolant

COMPANY IDENTIFICATION

Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada

24 Hour Environmental / Health Emergency Telephone

1-866-232-9563

Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ETHYLENE GLYCOL 107-21-1 55 - 65% Dermal Lethality: LD50 9.53

g/kg (Rabbit); Inhalation Lethality: LC50 4300 ppm (Rat); Oral Lethality: LD50 4.70 g/kg (Rat)

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

HEALTH EFFECTS

May cause harm to the unborn child. Ingestion may cause serious adverse effects and may be fatal. May cause kidney failure and central nervous system effects. Prolonged exposure to elevated concentrations of mist or liquid may cause irritation of the skin, eyes, and respiratory tract. High-pressure injection under skin may cause serious damage.

NFPA Hazard ID: Health: 1 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 2* Flammability: 1 Reactivity: 0



______________________________________________________________________________________________________________________

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION

Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT

Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

EYE CONTACT

Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION

Seek immediate medical attention. NOTE TO PHYSICIAN

This product contains ethylene glycol and/or diethylene glycol which, if ingested, are metabolized to toxic metabolites by the enzyme alcohol dehydrogenase, for which ethanol and 4-methylpyrazole {U.S. drug name Fomepizole, trade name Antizol} are antagonists. Administration of oral or intravenous ethanol or intravenous 4-methylpyrazole may arrest further metabolism of this material and thereby ameliorate the toxicity. Use of ethanol or 4-methylpyrazole does not affect toxic metabolites that are already present and is not a substitute for hemodialysis.

SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA

Appropriate Extinguishing Media: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water or standard foam

FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in Section 8.



______________________________________________________________________________________________________________________

Hazardous Combustion Products: Smoke, Fume, Aldehydes, Incomplete combustion products, Oxides of carbon

FLAMMABILITY PROPERTIES

Flash Point [Method]: 116°C (240°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 3.2 UEL: 15.3 Autoignition Temperature: 40°C (104°F)

SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.

PROTECTIVE MEASURES

Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.

SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Do not touch or walk through spilled material. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Consult an expert. Warn other shipping. Material will sink. Remove material, as much as possible, using mechanical equipment. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS

Remove debris in path of spill and remove contaminated debris from shoreline and water surface. Dispose of according to local regulations. Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE HANDLING

Avoid breathing mists or vapour. Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.

STORAGE

Do not store in open or unlabelled containers. Keep away from incompatible materials.



______________________________________________________________________________________________________________________

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source ETHYLENE GLYCOL Aerosol. Ceiling 100 mg/m3 ACGIH

NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:

No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:

No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves.

Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.



______________________________________________________________________________________________________________________

ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION

Physical State: Liquid Colour: Violet Odour: Characteristic Odour Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density: > 1 Flash Point [Method]: 116°C (240°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 3.2 UEL: 15.3 Autoignition Temperature: 40°C (104°F) Boiling Point / Range: N/D Vapour Density (Air = 1): 2.1 at 101 kPa Vapour Pressure: 0.008 kPa (0.06 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): 0.01 pH: 9 - 11 Log Pow (n-Octanol/Water Partition Coefficient): < 2 Solubility in Water: Complete Viscosity: [N/D at 40°C] Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/D Pour Point: -52°C (-62°F)

SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers, Acids, Alkalies HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks



______________________________________________________________________________________________________________________

Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar

materials. Irritation: Data available. Negligible hazard at ambient/normal handling temperatures.

Based on test data for structurally similar materials.

Ingestion Toxicity (Rat): LDLo 100 ml Moderately toxic. Based on test data for structurally similar

materials.

Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar

materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test

data for structurally similar materials.

Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test

data for structurally similar materials. CHRONIC/OTHER EFFECTS

Contains: ETHYLENE GLYCOL (EG): Repeated high oral exposure has caused kidney damage, neurological effects, degeneration of the liver and changes in blood chemistry and circulating blood cells in laboratory animals. Repeated overexposure has the potential to cause similar toxic effects in humans. EG causes developmental and reproductive effects at high dose levels in laboratory animals. The relevance of these findings to humans is uncertain. However, as a precaution, avoid exposure during pregnancy.

Additional information is available by request. CMR Status: None. Chemical Name CAS Number List Citations ETHYLENE GLYCOL 107-21-1 4

--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Material -- Expected to remain in water or migrate through soil. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be readily biodegradable.



______________________________________________________________________________________________________________________

Atmospheric Oxidation: Material -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Material -- Potential to bioaccumulate is low.

SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS

Even though this product is readily biodegradable, it must not be indiscriminately discarded into the environment. Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport

LAND (DOT)

Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethylene Glycol ) Hazard Class & Division: 9 ID Number: 3082 Packing Group: III Product RQ: 7692.31 LBS - ETHYLENE GLYCOL ERG Number: 171 Label(s): 9 Transport Document Name: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethylene Glycol), 9, PG III, RQ

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA): Not Regulated for Air Transport



______________________________________________________________________________________________________________________

SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class D, Division 2, Subdivision A: Very Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, EINECS, ENCS, IECSC, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: None. Chemical Name CAS Number List Citations ETHYLENE GLYCOL 107-21-1 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Eye - Header was modified. Section 04: First Aid Ingestion - Header was modified. Section 06: Protective Measures was modified. Section 06: Notification Procedures - Header was modified. Section 11: Acute Toxicity Table Header was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Colour was modified. Section 11: Inhalation - Header was modified. Section 09: Evaporation Rate - Header was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapour Pressure - Header was modified. Section 09: Vapour Pressure was modified. Hazard Identification: Health Hazards was modified. Section 11: Inhalation Lethality Test Data was modified. Section 06: Accidental Release-Spill Management-Land was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Flash Point C(F) was modified.



______________________________________________________________________________________________________________________

Section 14: Sea (IMDG) - Header was modified. Section 14: Air (IATA) - Header was modified. Section 14: LAND (TDG) - Header was modified. Section 14: LAND (TDG) Default was modified. Section 14: Sea (IMDG) - Default was modified. Section 14: Air (IATA) - Default was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Hazard Identification: Hazards Note was modified. Composition: Component table was modified. Section 16: Health Hazards was modified. Section 16: Health Hazards - Header was modified. Section 16: CA Prepared by - Header was modified. Section 08: Exposure Limits Table was modified. Section 16: Land Spill was modified. Section 16: First Aid Inhalation - Header was modified. Section 16: Precautionary Label Text - Header was modified. Section 09: Oxidizing Properties was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. Section 13: Regulatory Disposal Information - Header was modified. Section 14: Product RQ - Header was added. Section 14: Product RQ was added. Section 15: Canadian List Citations Table was added. Section 15: Chemical Name - Header was added. Section 15: CAS Number - Header was added. Section 15: List Citations -Header was added. Section 01: Product Code was added. Section 01: Product Code - Header was added. ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class D, Division 2, Subdivision A: Very Toxic Material HEALTH HAZARDS May cause harm to the unborn child. PRECAUTIONS Avoid breathing mists or vapour. Avoid contact with skin. FIRST AID Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Skin: Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.



______________________________________________________________________________________________________________________

FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Stop leak if you can do so without risk. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Recover by pumping or with suitable absorbent. Do not touch or walk through spilled material. Water Spill: Stop leak if you can do so without risk. Report spills as required to appropriate authorities. Material will sink. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007472 (1011905) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety

Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30

Revision Date: 03 Mar 2011 Page 1 of 9

______________________________________________________________________________________________________________________


Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30 Product Description: Base Oil and Additives MSDS Number: 15932 Intended Use: Engine oil




519-339-2145

Transportation Emergency Phone Number 519-339-2145 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15.

HEALTH EFFECTS

Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION

Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek



______________________________________________________________________________________________________________________ immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT


EYE CONTACT


First aid is normally not required. Seek medical attention if discomfort occurs.


Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water

FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon


Flash Point [Method]: 230C (446F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F)



PROTECTIVE MEASURES

Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending



______________________________________________________________________________________________________________________ on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.


Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.


Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator.

STORAGE

The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL.



______________________________________________________________________________________________________________________ NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS




No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.

ENVIRONMENTAL CONTROLS

See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data.



______________________________________________________________________________________________________________________ GENERAL INFORMATION

Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D


Relative Density (at 15 C): 0.863 Flash Point [Method]: 230C (446F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F) Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: [N/D at 20°C] | < 1 kPa (7.5 mm Hg) at 38C Evaporation Rate (n-butyl acetate = 1): < 0.1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: [N/D at 40°C] | 12 cSt (12 mm2/sec) at 100C Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/A Pour Point: -30°C (-22°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation

Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials.

Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.

Ingestion

Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.

Skin



______________________________________________________________________________________________________________________ Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar

materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test



data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself:

Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.

Additional information is available by request. CMR Status: None.

--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to

partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may

reduce the bioconcentration or limit bioavailability.



______________________________________________________________________________________________________________________ SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants.



LAND (DOT): Not Regulated for Land Transport



SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, TSCA, DSL, PICCS, IECSC, KECI Special Cases:

Inventory Status ELINCS Restrictions Apply ENCS Restrictions Apply



______________________________________________________________________________________________________________________ The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Eye - Header was modified. Section 04: First Aid Ingestion - Header was modified. Section 06: Notification Procedures - Header was modified. Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 11: Acute Toxicity Table Header was modified. Section 09: Colour was modified. Section 11: Inhalation - Header was modified. Section 09: Evaporation Rate - Header was modified. Section 09: Vapour Pressure - Header was modified. Section 07: Handling and Storage-Handling was modified. Section 07: Handling and Storage-Storage Phrases was modified. Section 11: Inhalation Lethality Test Data was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 14: Sea (IMDG) - Header was modified. Section 14: Air (IATA) - Header was modified. Section 14: LAND (TDG) - Header was modified. Section 14: LAND (DOT) - Header was modified. Section 14: LAND (DOT) - Default was modified. Section 14: LAND (TDG) Default was modified. Section 14: Sea (IMDG) - Default was modified. Section 14: Air (IATA) - Default was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Hazard Identification: Hazards Note was modified. Section 16: CA Prepared by - Header was modified. Section 09: Oxidizing Properties was modified. Section 15: List Citation Table - Header was modified.



______________________________________________________________________________________________________________________

Section 13: Regulatory Disposal Information - Header was modified. Section 06: Protective Measures was added. Section 06: Accidental Release - Protective Measures - Header was added. Section 15: Canadian List Citations Table was added. Section 15: Chemical Name - Header was added. Section 15: CAS Number - Header was added. Section 15: List Citations -Header was added. ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5014229 (543611) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety


==================================================

SECTION I - PRODUCT IDENTIFICATION ==================================================

==================================================

SECTION II – HAZARDOUS INGREDIENTS ==================================================

Ingredients CAS# Wt% ACGIH-TLV LC50 LD50 Alcohols, C9-11, ethoxylated 68439-46-3 1 - 5 Not available Not available 1200 mg/kg oral, rat Hydrogen chloride 7647-01-0 1 - 5 5 ppm Ceiling 935 ppm 4 h, mouse 900 mg/kg oral, rabbit

==================================================

SECTION III - PHYSICAL DATA ==================================================

Boiling Point (°C): Not available Specific Gravity (H2O = 1): 1.05

Vapour Pressure (mm Hg): Not available Evaporation Rate (Ether = 1): Not available

Vapour Density (Air = 1): Not available pH (100%): 0.5

Solubility in Water: Emulsifiable Viscosity: Water thin


Appearance; Odour: Opaque green; floral

==================================================

SECTION IV - FIRE AND EXPLOSION DATA ==================================================

Flammability: Not flammable by WHMIS criteria.

Flash Point (oC, TCC): None LEL: Not applicable UEL: Not applicable

Hazardous Combustion Products: May include and are not limited to oxides of carbon, hydrogen chloride, oxides of nitrogen, ammonia, chlorine.

Autoignition Temperature (oC): Not applicable

Means of Extinction: Treat for surrounding material.

Special Fire Hazards: Firefighters should wear self-contained breathing apparatus. ==================================================

SECTION V - REACTIVITY DATA ==================================================

Conditions for Chemical Instability: Stable.

Incompatible Materials: Oxidizers, aluminum, caustics, reducers.

Reactivity, and Under What Conditions: Reacts vigorously with alkaline material or metals. Reacts with soft metals producing flammable hydrogen gas.

Hazardous Decomposition Products: May include and are not limited to oxides of carbon, hydrogen chloride, oxides of nitrogen, ammonia, chlorine when heated to decomposition.

Product Name:

SAN-I-CAN PORCELAIN CLEANER (1L)

Product Use:

Bathroom Care

WHMIS Class:

Class E - Corrosive Material

TDG Classification: HYDROCHLORIC ACID, SOLUTION; Class 8; UN1789; PG II

Manufacturer/Supplier: Kemsol Products Ltd.

Address:

1120 McDonald St. Regina, SK S4N 4X3

Telephone: (306) 569-0636

HEALTH

3

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

PROTECTION

B

SAN-I-CAN POPRCELAIN CLEANER (1L)

==================================================

SECTION VI - TOXICOLOGICAL PROPERTIES ==================================================

Route of Entry: Eye, Skin contact, Inhalation, Ingestion.

EFFECTS OF ACUTE EXPOSURE:

Eye: May cause chemical burns. May cause blindness.

Skin: May cause chemical burns.

Inhalation (mists): Harmful. May cause respiratory tract irritation or chemical burns.

Ingestion: Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.

EFFECTS OF CHRONIC EXPOSURE:

Skin: May cause chemical burns.

Irritancy: Corrosive by WHMIS criteria.

Respiratory Tract Sensitization: No data available.

Carcinogenicity: Non-hazardous by WHMIS criteria.

Teratogenicity, Mutagenicity, Reproductive Effects: No data available.

==================================================

SECTION VII- PREVENTATIVE MEASURES ==================================================

Gloves: Rubber gloves. Confirm with a reputable supplier first.

Eye Protection: Chemical splash goggles.

Respiratory Protection: Not normally required if good ventilation is maintained.

Other Protective Equipment: As required by employer code.

Engineering Controls: General ventilation normally adequate.

Leak and Spill Procedure: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice.

Waste Disposal: Review federal, provincial, and local government requirements prior to disposal.

Storage and Handling Requirements: Keep out of reach of children. Store in a closed container away from incompatible materials.

==================================================

SECTION VIII - FIRST AID ==================================================

Eye: Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately.

Skin: Immediately flush with cool water for 15 minutes while removing contaminated clothing and shoes. Discard or wash well before reuse. Obtain medical attention if irritation persists.

Inhalation: Move victim to fresh air. If symptoms persist, obtain medical attention.

Ingestion: Do not induce vomiting. Rinse mouth with water then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing.

=================================================

SECTION IX - PREPARATION INFORMATION =================================================

Date: 06/01/12 MSDS Prepared by: Kemsol Products Ltd.

Telephone: (306) 569-0636 ================================================== Disclaimer

Information for this material safety data sheet was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the mandatory requirements of WHMIS. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this form. If user requires independent information on ingredients in this or any other material, we recommend contact with the Canadian Centre for Occupational Health and Safety (CCOHS) in Hamilton, Ontario (1-905-572-4400) or CSST in Montreal, Quebec (514-873-3990).

2

Material Safety Data SheetVersion: 1.5

05/13/2008

RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A

Page 1/7


Manufactured By: Waterford Plant 260 Hudson River Rd Waterford NY 12188

Revised: 05/13/2008 Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS CHEMTREC 1-800-424-9300 Chemical Family/Use: Silicone Elastomer Formula: Mixture HMIS Flammability: 1 Reactivity: 0 Health: 0 NFPA Flammability: 1 Reactivity: 0 Health: 1

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION! May cause skin, eye, and respiratory tract irritation. May generate formaldehyde at temperatures greater than 150 C (300 F). See Section 10 of MSDS for details. Attention: Not for injection into humans.

Form: Liquid Color: beige Odor: Slight POTENTIAL HEALTH EFFECTS INGESTION

None known. Not an anticipated route of exposure. SKIN

Skin contact may cause irritation. INHALATION

Inhalation of vapors may cause irritation of the respiratory tract. EYES

May cause eye irritation. MEDICAL CONDITIONS AGGRAVATED

None known. SUBCHRONIC (TARGET ORGAN )

None known. CHRONIC EFFECTS / CARCINOGENICITY

No data available


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ROUTES OF EXPOSURE

Inhalation

3. COMPOSITION / INFORMATION ON INGREDIENTS

PRODUCT COMPOSITION CAS REG NO. WGT. %

A. HAZARDOUS B. NON-HAZARDOUS polyvinylsiloxane 68083-19-2 30 - 60 %

Polyalkylalkenylsiloxane 68584-83-8 10 - 30 %

Limestone 471-34-1 1 - 5 %

4. FIRST AID MEASURES INGESTION

Do not induce vomiting. If victim is conscious, give 1-3 glasses of water to drink. Never give anything by mouth to an unconscious person. Get medical attention if irritation persists.

SKIN

Wash with soap and water. Get medical attention if irritation or symptoms from Section 3 develop.

INHALATION

If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If breathing is difficult give oxygen. Get medical attention.

EYES

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.

NOTE TO PHYSICIAN

Treatment is symptomatic and supportive.

5. FIRE-FIGHTING MEASURES FLASH POINT: > 100 °C; 212 °F


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IGNITION TEMPERATURE: Not applicable FLAMMABLE LIMITS IN AIR - LOWER (%): No data available FLAMMABLE LIMITS IN AIR - UPPER (%): No data available SENSITIVITY TO MECHANICAL IMPACT: No SENSITIVITY TO STATIC DISCHARGE

Sensitivity to static discharge is not expected. EXTINGUISHING MEDIA

All standard extinguishing agents are suitable. SPECIAL FIRE FIGHTING PROCEDURES

Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus with full face mask and full protective clothing.

FURTHER INFORMATION

Standard procedure for chemical fires.

6. ACCIDENTAL RELEASE MEASURES ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as specified in the protective equipment section.

7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

Keep container closed when not in use. Avoid contact with skin, eyes and clothing. Keep away from children.

STORAGE

Keep container closed. Store away from heat, sources of ignition, and incompatibles.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS

Eyewash stations; Showers; Exhaust ventilation RESPIRATORY PROTECTION

If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved


05/13/2008


Page 4/7

respiratory protection should be worn. Supplied air respirators may be required for non-routine or emergency situations. Respiratory protection must be provided in accordance with OSHA regulations (see 29CFR 1910.134).

PROTECTIVE GLOVES

Rubber gloves EYE AND FACE PROTECTION

Safety glasses with side-shields OTHER PROTECTIVE EQUIPMENT

Wear suitable protective clothing and eye/face protection. Exposure Guidelines

Component CAS RN Source Value

Absence of values indicates none found PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal Recommended Exposure Limit OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA) effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).

9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT - C & F: >260 °C; 500 °F VAPOR PRESSURE (20 C) (MM HG): Negligible VAPOR DENSITY (AIR=1): 1.0 FREEZING POINT: Not applicable MELTING POINT: Not applicable PHYSICAL STATE: Liquid ODOR: Slight COLOR: beige EVAPORATION RATE (BUTYL ACETATE=1): < 1 SPECIFIC GRAVITY (WATER=1): ca. 1.28 DENSITY: ca. 1.28 g/cm3 ACID / ALKALINITY (MEQ/G): Unknown pH: No data available VOLATILE ORGANIC CONTENT (VOL): No data available SOLUBILITY IN WATER (20 C): Insoluble SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT):

Toluene

VOC EXCL. H2O & EXEMPTS (G/L): ca. 1


05/13/2008


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10. STABILITY AND REACTIVITY STABILITY

Stable HAZARDOUS POLYMERIZATION

Will not occur HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS

Carbon monoxide; Carbon dioxide (CO2); Silicon dioxide.; Formaldehyde; This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A MSDS for formaldehyde is available from Momentive.

INCOMPATIBILITY (MATERIALS TO AVOID)

None known. CONDITIONS TO AVOID

None known.

11. TOXICOLOGICAL INFORMATION ACUTE ORAL

Remarks: Unknown ACUTE DERMAL

Remarks: Unknown ACUTE INHALATION

Remarks: Unknown OTHER

None. SENSITIZATION

No data available SKIN IRRITATION

No data available EYE IRRITATION

No data available MUTAGENICITY

Unknown


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Page 6/7

12. ECOLOGICAL INFORMATION ECOTOXICITY

No data available

DISTRIBUTION

No data available CHEMICAL FATE

No data available

13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD

Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION

Further Information: This product is not regarded as dangerous goods according to the

national and international regulations on the transport of dangerous goods.

15. REGULATORY INFORMATION

Inventories

Canada DSL Inventory y (Positive listing) Japan Inventory of Existing & New Chemical Substances (ENCS)

y (Positive listing)

Korea Existing Chemicals Inventory (KECI)


China Inventory of Existing Chemical Substances


Australia Inventory of Chemical Substances (AICS)


Philippines Inventory of Chemicals and Chemical Substances (PICCS)


TSCA list y (Positive listing) On TSCA Inventory


05/13/2008


Page 7/7

EU list of existing chemical substances


For inventories that are marked as quantity restricted or special cases, please contact Momentive.

US Regulatory Information SARA (311,312) HAZARD CLASS

No SARA HazardsAcute Health Hazard; Chronic Health Hazard SARA (313) CHEMICALS

CALIFORNIA PROPOSITION 65

WARNING! This product contains a chemical known in the State of California to cause cancer. 100-41-4, Ethylbenzene. 71-43-2, Benzene. 108-88-3, Toluene.

Canadian Regulatory Information WHMIS HAZARD CLASS

Non-controlled. Other SCHDLE B/HTSUS: 3910.00 Silicones in Primary Form ECCN: EAR99

16. OTHER INFORMATION OTHER

These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not applicable UNKN = unknown NE = none established REC = recommended ND = none determined V = recommended by vendor SKN = skin TS = trade secret R = recommended MST = mist NT = not tested STEL = short term exposure limit ppm = parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status not required under 40 CFR part 720.30(h-2).


05/13/2008

RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B

Page 1/7


Manufactured By: Waterford Plant 260 Hudson River Rd Waterford NY 12188

Revised: 05/13/2008 Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS CHEMTREC 1-800-424-9300 Chemical Family/Use: Silicone Rubber Formula: Mixture HMIS Flammability: 1 Reactivity: 1 Health: 0 NFPA Flammability: 1 Reactivity: 1 Health: 1

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION! Product generates flammable gas on contact with acids, bases or oxidizing substances. May cause irritation of skin and eyes.

Form: Liquid Color: Blue Odor: Slight POTENTIAL HEALTH EFFECTS INGESTION

None known. SKIN

May cause mild skin irritation. INHALATION

None known. EYES

May cause mild eye irritation. MEDICAL CONDITIONS AGGRAVATED

None known. SUBCHRONIC (TARGET ORGAN )

None known. CHRONIC EFFECTS / CARCINOGENICITY

This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, or OSHA.


05/13/2008


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ROUTES OF EXPOSURE

None known.


PRODUCT COMPOSITION CAS REG NO. WGT. %

A. HAZARDOUS B. NON-HAZARDOUS METHYLHYDROGENPOLYSILOXANE

68988-57-8 30 - 60 %

polyvinylsiloxane 68083-19-2 30 - 60 %

Polyalkylalkenylsiloxane 68584-83-8 10 - 30 %

4. FIRST AID MEASURES INGESTION

Rinse mouth with water several times. Obtain medical attention. SKIN

After contact with skin, remove product mechanically. Wash off with soap and water. INHALATION

None known. EYES

Immediately flush eye(s) with plenty of water. If eye irritation persists, consult a specialist. NOTE TO PHYSICIAN

None known.

5. FIRE-FIGHTING MEASURES FLASH POINT: > 100 °C; 212 °F FLAMMABLE LIMITS IN AIR - LOWER (%): Not applicable FLAMMABLE LIMITS IN AIR - UPPER (%): Not applicable SENSITIVITY TO MECHANICAL IMPACT: No


05/13/2008


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EXTINGUISHING MEDIA

Carbon dioxide (CO2), Foam, Water spray, Dry powder SPECIAL FIRE FIGHTING PROCEDURES

Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus with full face mask and full protective clothing.

FURTHER INFORMATION

Standard procedure for chemical fires.

6. ACCIDENTAL RELEASE MEASURES ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED

Wipe, scrape or soak up in an inert material and put in a container for disposal. Wear proper protective equipment as specified in the protective equipment section.

7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

Use personal protective equipment. Avoid contact with skin, eyes and clothing. Keep container closed when not in use to prevent contact with acidic, basic, or oxidizing materials, and metallic catalysts like tin soaps and noble metals (Pt, Rh, etc.).

STORAGE

Store away from heat, sources of ignition, and incompatibles.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS

Eyewash stations RESPIRATORY PROTECTION

If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Supplied air respirators may be required for non-routine or emergency situations. Respiratory protection must be provided in accordance with OSHA regulations (see 29CFR 1910.134).

PROTECTIVE GLOVES

Protective gloves


05/13/2008


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EYE AND FACE PROTECTION Safety glasses with side-shields

OTHER PROTECTIVE EQUIPMENT

Lightweight protective clothing Exposure Guidelines

Component CAS RN Source Value

Absence of values indicates none found PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal Recommended Exposure Limit OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA) effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).

9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT - C & F: >300 °C; 572 °F VAPOR PRESSURE (20 C) (MM HG): No data available VAPOR DENSITY (AIR=1): No data available FREEZING POINT: No data available MELTING POINT: No data available PHYSICAL STATE: Liquid ODOR: Slight COLOR: Blue EVAPORATION RATE (BUTYL ACETATE=1): Unknown SPECIFIC GRAVITY (WATER=1): ca. 1.02 DENSITY: ca. 1.02 g/cm3 ACID / ALKALINITY (MEQ/G): No data available pH: N/A VOLATILE ORGANIC CONTENT (VOL): No data available SOLUBILITY IN WATER (20 C): Insoluble SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT):

Soluble in toluene

VOC EXCL. H2O & EXEMPTS (G/L): ca. 5

10. STABILITY AND REACTIVITY STABILITY

Stable HAZARDOUS POLYMERIZATION

Will not occur


05/13/2008


Page 5/7

HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS Flammable hydrogen gas.; Carbon dioxide (CO2); Carbon monoxide; Formaldehyde; Silicon dioxide.; This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A MSDS for formaldehyde is available from Momentive.


Avoid contact with acidic, basic, or oxidizing agents, and metallic catalysts like tin soaps and noble metals (Pt, Rh, etc.).

CONDITIONS TO AVOID

Avoid contact with acids, bases, or oxidizing agents. Product generates flammable gas on contact with acids, bases or oxidizing substances.

11. TOXICOLOGICAL INFORMATION ACUTE ORAL

Remarks: None known. ACUTE DERMAL

Remarks: None known. ACUTE INHALATION

Remarks: Unknown OTHER

None. MUTAGENICITY

Unknown

12. ECOLOGICAL INFORMATION CHEMICAL FATE

No data available

13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD

Disposal should be made in accordance with federal, state and local regulations.


05/13/2008


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Further Information: This product is not regarded as dangerous goods according to the

national and international regulations on the transport of dangerous goods.


Inventories

Canada DSL Inventory y (Positive listing) Japan Inventory of Existing & New Chemical Substances (ENCS)


Korea Existing Chemicals Inventory (KECI)


China Inventory of Existing Chemical Substances


Australia Inventory of Chemical Substances (AICS)


Philippines Inventory of Chemicals and Chemical Substances (PICCS)


TSCA list y (Positive listing) On TSCA Inventory EU list of existing chemical substances


Canada NDSL Inventory n (Negative listing) For inventories that are marked as quantity restricted or special cases, please contact Momentive.

US Regulatory Information SARA (311,312) HAZARD CLASS

No SARA Hazards SARA (313) CHEMICALS

CALIFORNIA PROPOSITION 65

Warning! This product contains a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. 71-43-2, Benzene. 108-88-3, Toluene.

Canadian Regulatory Information


05/13/2008


Page 7/7

WHMIS HAZARD CLASS

D2A VERY TOXIC MATERIALS

Other SCHDLE B/HTSUS: 3910.00 Silicones in Primary Form ECCN: EAR99

16. OTHER INFORMATION OTHER

These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not applicable UNKN = unknown NE = none established REC = recommended ND = none determined V = recommended by vendor SKN = skin TS = trade secret R = recommended MST = mist NT = not tested STEL = short term exposure limit ppm = parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status not required under 40 CFR part 720.30(h-2).

Canadian Workplace Hazardous Materials Information SystemMaterial Safety Data Sheet

I. PRODUCT IDENTIFICATIONProduct Name: PC FAST ORANGE PUMICE CREAM 400GRItem No: 20864Product Type: Waterless hand cleaner

II. COMPOSITION/INFORMATION ON INGREDIENTSComponent Weight% LD50/oral/rat LC50/inhalation/rat ACGIH; TLV-TWA

WATER7732-18-5

70-80 not available not available

PUMICE1332-09-8

5-15 not available not available 10 mg/m3 (inhal); 3 mg/m3

(resp) ACGIHD-LIMONENE5989-27-5

5-15 4400 mg/kg not available

ETHOXYLATED C11-C16 ALCOHOL127036-24-2

<3 oral rat: >500 mg/kg not available

CASTOR OIL8001-79-4

<3 not available not available

PROPYLENE GLYCOL57-55-6

<3 20 g/kg not available

III. PHYSICAL DATAPhysical State/Appearance: White cream with pumiceOdour & Odour Threshold: Citrus odourSpecific Gravity: 1.02Evaporation Rate: <1 (butyl acetate = 1)Vapour Pressure: Not determinedVapour Density: Heavier than airFreezing Point: Not determinedpH: 6.5-7.5Octanol/Water Coefficient: Not determinedBoiling Point: Not determined

IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Water, Dry chemical, Carbon dioxide, FoamHazardous Combustion Products: None knownSensitivity to Static Discharge: Sensitivity to static discharge is not expected.Conditions of Flammability: None anticipated.Flash Point/Range: >95°C COCAutoignition Temperature: Not determinedUpper Explosive Limit: Not determinedLower Explosive Limit: Not determined

V. REACTIVITY DATAConditions Causing Chemical Instability: NoneMaterials to avoid: None reasonably foreseeableConditions of Reactivity: NoneHazardous Decomposition Products: None anticipated

VI. HAZARDS IDENTIFICATIONPrimary Routes of Exposure: Eye and skin contact, ingestion, inhalationToxicity Information: (See Effects of Acute Exposure to Product)Effects of Acute Exposure: None under normal conditions of use.

1 of 2

Permatex Canada, Inc.8450 Lawson Road, Unit 1Milton, ON Canada L9T 0A4Telephone: 1-87-Permatex(877) 376-2839Urgence: 800-255-3924 (ChemTel)

VI. HAZARDS IDENTIFICATIONEffects of Chronic Exposure: Estimated oral LD50 is greater than 5000 mg/kg. Primary irritation tests show that this product is not a

primary irritant..Irritancy of Product: None under normal conditions of use.Sensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)Reproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None knownWHMIS Hazard Class: Non-controlled

VII. PREVENTATIVE MEASURESPersonal ProtectionEyes: Not required.Skin: Not necessary.Ventilation: None needed.Engineering Controls: No special precautions requiredSpill Procedures: Rinse away with water or wipe up with a towel.Protection of Man and Environment: Follow Canadian and local regulations for disposal.Handling Procedures and Equipment:No special precautions required.Special Handling Information: Hand cleaners should be stored at temperatures between 5 degrees C. and 37 degrees C.

VIII. FIRST AID MEASURESIngestion: If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention.Inhalation: None reasonably foreseeable.Skin Contact: Flush with water.Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical

attention if irritation persists.

IX. SHIPPING INFORMATIONCanadian Transportation of Dangerous Goods

Proper Shipping Name: Not regulatedHazard Class: NoneUN/ID No: None

IATAProper Shipping Name: Not regulatedClass or Division: NoneUN/ID Number: None

IMDGProper Shipping: Not regulatedHazard Class: NoneUN Number: None

X. PREPARATION INFORMATIONEstimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0HMIS is a registered trademark of the National Paint and Coatings Assn.

Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0NFPA is a registered trademark of the National Fire Protection Assn.

Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: October 28, 2010

Company:Permatex Canada, Inc. 8450 Lawson Rd. Unit 1, Milton, ON L9T 0A4

Revision Number: 6Telephone No.: 1-87-Permatex (877) 376-2839

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Product Name: Item No: 20864PC FAST ORANGE PUMICE CREAM400GR

R.B. Howes & Co., Inc., 60 Ocean State Drive, North Kingstown, RI 02852, Tel: 1-800-438-9080 or 1-401-294-5500

U.S. SAFETY DATA SHEET

Howes Lubricator Diesel Treat Page 1 of 6

Section 1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Howes Lubricator Diesel Treat Part Number(s): 103060, 103061, 103062, 103064,

103065, 103066, 103068, 103070 Company Identification: R.B. Howes & Co., Inc. 60 Ocean State Drive North Kingstown, RI 02852 Tel: 800-438-9080 or 401-294-5500 Emergency Telephone Number: Chemtrec 1-800-424-9300 or 703-527-3887 (24 hours)

Section 2. HAZARDS IDENTIFICATION

Emergency Overview Combustible. Light amber oil-like liquid with distinctive odor. Prolonged or repeated skin contact may cause skin irritation. Ingestion harmful or fatal if not treated. Prolonged exposure to heavy concentrations of vapors may cause irritation to mucus membranes and airway. Respiratory diseases such as asthma and skin conditions such as rashes, cuts or similar skin diseases are generally aggravated by exposure. Do not handle near excessive heat, sparks, flame or strong oxidants. Incompatible with (material to avoid) strong oxidants like liquid chlorine or concentrated oxygen. This material could be a slipping hazard if spilled. OSHA Regulatory Status This product contains components that are considered to be hazardous under OSHA’s Hazard Communication Standard (29 CFR 1900.1200). Potential Health Effects Eye Contact: May cause redness and mild irritation. Skin Contact: Prolonged contact may cause mild irritation. Ingestion: Can cause cramps and nausea. Inhalation: Prolonged exposure may irritate the respiratory tract. Carcinogen: OSHA: no IARC: Ethylbenzene & Vinyl Acetate, Group 2B, possible human carcinogenic NTP: no




Section 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS # % by Volume Petroleum Distillates 64742-46-7 1.00 – 70.0 Aliphatic Hydrocarbon 8052-41-3 1.00 – 50.0 1,2,4 Trimethylbenzene 95-63-6 0.50 – 1.50 1,3,5 Trimethylbenzene 108-67-8 0.01 – 0.60 Trimethylbenzene 25551-13-7 0.01 – 0.30 Ethylbenzene 100-41-4 0.01 – 0.05 Vinyl Acetate 108-05-4 0.01 – 0.05

Section 4. FIRST AID MEASURES

Eye contact: Flush eyes with plenty of water for several minutes. Get medical attention if irritation persists. Skin contact: Wash skin with plenty of soap and water for several minutes. Get medical attention if irritation persists. Ingestion: Do not induce vomiting. Water may be given slowly. Contact physician immediately. Inhalation: If irritation or headache occurs, remove to fresh air. If signs/symptoms continue, get medical attention. Additionally: In all cases, if symptoms persist, contact physician.

Section 5. FIRE FIGHTING MEASURES

Flash point: 150°F / 65.5°C (Rapid Flash Point Closed-Cup, ASTM D3243) Autoignition temperature: Data not available. Upper flammable limit: Data not available. Lower flammable limit: Data not available. Extinguishing media: Foam, CO2, water fog or spray.




Fire fighting equipment: Recommend wearing self contained breathing apparatus. Avoid breathing vapors or fumes. Cool exposed containers with water spray. Unusual fire and explosion hazard: Combustible liquid. May form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld or expose containers to flame or other sources of ignition. National Fire Protection Association (NFPA) Flammability (red): 2 Health (blue): 1 Reactivity (yellow): 0 Special (white):

Section 6. ACCIDENTAL RELEASE MEASURES

Use appropriate personal protective equipment (PPE). (see section 8) Soak up the spill with oil absorbents, sand or other non-combustible material. Place residue in suitable, covered and properly labeled container. Dispose in accordance with federal, state and local laws.

Section 7. HANDLING AND STORAGE

Keep away from sources of ignition. Keep container closed when not in use.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

OSHA Permissible Exposure Limits (PEL’s); 8-hour Time Weighted Averages (TWA) Petroleum Distillates TWA: 2000 ppm Aliphatic Hydrocarbon TWA: 500 ppm

1,2,4 Trimethylbenzene TWA: 25 ppm 1,3,5 Trimethylbenzene TWA: 25 ppm Trimethylbenzene TWA: 25 ppm Ethylbenzene TWA: 100 ppm Vinyl Acetate TWA: 10 ppm

Engineering Controls Good general ventilation should be sufficient to control airborne levels.




Respiratory Protection Respirator use is not expected to be necessary under normal conditions of use. If application creates mist, wear a NIOSH approved respirator. Skin Protection For brief contact, no precautions other than wearing long sleeves should be needed. Use chemical resistant gloves such as neoprene. Eye/Face Protection Safety glasses with side shield, anti-splash goggles or face shield. Hygiene Recommendations Avoid breathing mist or vapor. Avoid contact with skin and eyes. Keep an eyewash kit available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Light amber Odor: Distinctive Physical State: Liquid Flash: 150°F / 65.5°C (Rapid Flash Point Closed-Cup, ASTM D3243) VOC: 823 (g/l) pH: Not determined Vapor Pressure: <.1mm Hg Vapor Density: >1 (air = 1) Boiling Point: 327°F / 164°C Freezing Point: Not determined Solubility in Water: Insoluble Specific Gravity: <.9 (H2O = 1)

Section 10. STABILITY AND REACTIVITY

Chemical Stability: Stable under normal ambient temperature (70°F / 21°C) and pressure

(14.7 psi / 760 mmHg). Conditions to Avoid: Combustible when exposed to excessive heat, sparks, flames or strong

oxidants. Incompatible Materials: Contact with strong oxidizers like chlorine or concentrated oxygen. Hazardous Decomposition Products: Under fire conditions: Carbon oxides (CO, CO2) Hazardous Polymerization: Hazardous polymerization will not occur.




Section 11. TOXICOLOGICAL INFORMATION

Oral (rat) LD50 Dermal (rabbit) LD50 Inhalation (rat) LC50 Petroleum Distillates 5,000 mg/kg 3,000 mg/kg Aliphatic Hydrocarbon 5,000 mg/kg 3,000 mg/kg 5,500 mg/m3 1,2,4 Trimethylbenzene 5,000 mg/kg 3160 mg/kg 18,000 mg/m3 1,3,5 Trimethylbenzene 23,000 mg/kg 24,000 mg/m3 Trimethylbenzene 8,970 mg/kg Ethylbenzene 3,500 mg/kg 17,800 mg/kg 55,000 mg/m3 Vinyl Acetate 2,900 mg/kg 2,335 mg/kg 11,400 mg/m3

Section 12. ECOLOGICAL INFORMATION

No ecotoxicological studies have been conducted on this product.

Section 13. DISPOSAL CONSIDERATIONS

Waste management should be in compliance with federal, state and local laws.

Section 14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties and mode of transportation. 49 CFR §173.150(f) Exceptions for Class 3 flammable and combustible liquids. Howes part number(s): 103060, 103061, 103062, 103064, 103065, 103066, 103068, 103070 Non-bulk packaging (≤ 119 gal. liquid; ≤ 882 lbs. solid):

This product is non hazardous when packaged in non-bulk packaging. Howes part number(s): N/A

Bulk packaging (> 119 gal. liquid; > 882 lbs. solid): This product is hazardous when packaged in bulk packaging and the Proper Shipping Name would be:

Proper Shipping Name: Petroleum distillates, n.o.s. UN Identification Number: UN1268 Hazard Class – Primary: 3 Packing Group: III Flash Point: 150°F / 65.5°C




49 CFR §172.101 (Appendix B) List of Marine Pollutants This product is not a marine pollutant as defined in 49 CFR §171.8.

Section 15. REGULATORY INFORMATION

U.S. Regulations: Clean Air Act (CAA) 112(r) Accidental Release Prevention Substances: Vinyl Acetate. Clean Water Act (CWA) 307 Priority Pollutants: Ethylbenzene. Clean Water Act (CWA) 311 Hazardous Substances: Ethylbenzene, Vinyl Acetate. CERCLA 302 Hazardous Substances: Ethylbenzene RQ 1,000 lbs. Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986: (Known to cause cancer) Ethylbenzene. SARA 302/304 Emergency Planning and Notification Substances: No products were found. SARA 313 Toxic Chemical Notification: Ethylbenzene, 1,2,4 Trimethylbenzene, Vinyl Acetate. TSCA Inventory Status: All components are included or are exempted from listing on the US Toxic Substances Control Act Inventory.

Section 16. OTHER INFORMATION

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Health (Blue) 1 Flammability (Red) 2 Reactivity (Yellow) 0 Personal Protection (White) B SDS PREPARATION Prepared By: VP of Logistics Issue Date: July 5, 2012 Supersedes Date: August 26, 2011 The recommendations and data presented herein are based on sources considered to be reliable. Any use inconsistent with our recommendations may affect the risk characterization. However, no warranty is expressed or implied regarding the accuracy of the data or the results obtained from the use of this information or the use of the product. R.B. Howes & Co., Inc. expressly disclaims all liability for loss or damage, including consequential loss, or injury to persons (including death) arising directly or indirectly from reliance upon the information or misuse of the material.



24 Hour Assistance:

1-847-367-7700

Rust-Oleum Corp.

www.rustoleum.com

1. Identification

4/2/2012Product Name: ENAMEL 5-GL FLAT BLACK Revision Date:








EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea.



EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs.

EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.

Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula.




ACGIH TLV-TWA

ACGIH TLV-STEL

OSHA PEL-TWAOSHA PEL-CEILING

Limestone 1317-65-3 50.03 mg/m3(Respirable)

N.E.5 mg/m3(Respirable)

N.E.

Stoddard Solvents 8052-41-3 20.0 100 ppm N.E. 500 ppm N.E.Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Carbon Black 1333-86-4 5.0 3.5 mg/m3 N.E. 3.5 mg/m3 N.E.Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.

Page 1 / 4





FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.

FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention.





SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance.


STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.

STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use.





SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.


OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.


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Vapor Density HEAVIER THAN AIR Odor: Solvent Like









HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes.





Limestone N.E. N.E.



Carbon Black >8000 mg/kg (Rat, Oral) N.E.





DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems.







Limited Quantity: No No No


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Fire Hazard, Chronic Health Hazard

SARA SECTION 313:







CANADIAN WHMIS:


Canadian WHMIS Class: B3 D2A


HMIS Ratings:


NFPA Ratings:






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Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)

Version 1.1 Print Date 10/17/2011

Revision Date 09/01/2011 MSDS Number 350000004239 SITE_FORM Number 30000000000000003564.001

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1. PRODUCT AND COMPANY IDENTIFICATION

Product information

Trade name : RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)

Use of the Substance/Mixture

: Insect Repellent

Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1

Emergency telephone number

: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666


Emergency Overview Appearance / Odor : blue / solid / mild pleasant

Immediate Concerns

:

Potential Health Effects


This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA 29 CFR 1910.1200 or Canadian Controlled Products Regulations. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES

5. FIREFIGHTING MEASURES

Flash point : Note: no data available





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Lower explosion limit : Note: no data available

Upper explosion limit : Note: no data available





Form : solid

Color : blue

Odor : mild pleasant

pH : not applicable

Boiling point : not applicable

Freezing point : not applicable

Flash point : no data available

Evaporation rate : not applicable

Autoignition temperature : not applicable

Lower explosion limit : no data available

Upper explosion limit : no data available

Vapour pressure : not applicable

Density : no data available Water solubility : not applicable

Partition coefficient: n-octanol/water

: not applicable





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Volatile Organic Compounds Total VOC (wt. %)*

: 0 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations



Acute oral toxicity : LD50 > 5,000 mg/kg

Acute inhalation toxicity : LC50 > 1.1 mg/l

Acute dermal toxicity : LD50 > 2,000 mg/kg

Chronic effects Carcinogenicity : no data available

Mutagenicity : None Anticipated Reproductive effects : no data available

Teratogenicity : no data available

Sensitisation : no data available


Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS


Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.





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Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).

: This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

16. OTHER INFORMATION

HMIS Ratings Health 1

Flammability 1

Reactivity 0

NFPA Ratings Health 1

Fire 1

Reactivity 0

Special -

Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment &

Regulatory Affairs (GSARA)





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MSDS: CALCIUM LIME AND RUST REMOVER Page 1 of 2 Revision Date: 3/06/12

MATERIAL SAFETY DATA SHEET from STEARNS PACKAGING CORPORATION

SECTION I—PRODUCT/MANUFACTURER’S IDENTITY

HAZARD RATING 4 = Extreme

0 Flammability 3 = High

2 Health 2 = Moderate

0 Reactivity 1 = Slight

None Special Hazard 0 = Insignificant

IDENTITY (As Used On Label and List): Calcium, Lime & Rust Remover SYNONYMS: ST-1257 FORMULA ID NUMBER: AM10 EPA REG #: None NSF CERTIFIED: None

COMPANY: STEARNS PACKAGING CORPORATION ADDRESS: 4200 Sycamore Ave. (53714), PO Box 3216 Madison, Wisconsin (WI) 53704-0216 PHONE: 1 (608) 246–5150 FAX: 1 (608) 246–5149 INTERNET: www.stearnspkg.com EMAIL: [email protected]

For Transportation Emergency Involving Hazardous Materials Contact: CHEM-TEL 1 (800) 255–3924 Shipping Information: DOT SHIPPING NAME: NA1760, Compounds, cleaning liquid, (containing phosphoric acid), 8, PG III, Ltd Qty. Item 48580, Sub 3, Class 55 DOT SHIPPING NUMBER: NA1760 HAZARD LABEL: NA1760, Compounds, cleaning liquid, (containing phosphoric acid), 8, PG III, Ltd Qty. No diamond required for PG III, Ltd Qty HAZARD CLASS: 8, Corrosive

SECTION II—HAZARDOUS INGREDIENTS OR IDENTITY INFORMATION HAZARDOUS CHEMICAL IDENTITY &

CAS# HAZARD OSHA PEL ACGIH TLV OTHER LIMITS % (OPTIONAL)

▶ Phosphoric acid 7664-38-2

Corrosive 1 mg/cu m 1 mg/cu m 3 mg/cu m (STEL) 42.25

SARA SECTION 313 TITLE III NOTIFICATION REQUIRED: No; CHEMICAL IN PRODUCT: N/A; CAS#: N/A; WEIGHT % OF CHEM: N/A

SECTION III—PHYSICAL/CHEMICAL CHARACTERISTICS

BOILING POINT: 111ºC VAPOR PRESSURE (mm Hg): 0.03 mm Hg @20ºC SPECIFIC GRAVITY (WATER=1): 1.279 VAPOR DENSITY (AIR=1): Not Determined MELTING POINT: Not Applicable EVAPORATION RATE: Not Determined

SOLUBILITY IN WATER: Infinite pH (CONCENTRATE): 0.5 APPEARANCE AND ODOR: Light orange, clear liquid,

Slight acid odor pH (1% SOLUTION): 1.65 – 1.74

SECTION IV—FIRE AND EXPLOSION HAZARD DATA

FLASH POINT (METHOD USED): Non-combustible, >200ºF

EXTINGUISHING MEDIA: CO2, water, dry chemical

FLAMMABLE LIMITS: LEL: Not Applicable UEL: Not Applicable

SPECIAL FIRE FIGHTING PROCEDURES:

Use full protective clothing and self-contained breathing apparatus. Thermal decomposition emits toxic fumes of oxides of phosphorous.

FIRE & EXPLOSION HAZARDS: None

SECTION V—REACTIVITY DATA

STABILITY: Stable INCOMPATIBILITY (MATERIALS TO AVOID):

None known

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: None known CONDITIONS TO AVOID: Freezing and extremes of heat HAZARDOUS POLYMERIZATION: Will not occur

MSDS: CALCIUM LIME AND RUST REMOVER Page 2 of 2 Revision Date: 3/06/12

SECTION VI—HEALTH HAZARD DATA/FIRST AID PROCEDURES

HEALTH HAZARDS (ACUTE AND CHRONIC): Irritation or corrosion may occur to exposed tissues, especially eyes, skin, throat, nasal cavities and other mucous membranes from contact with the product, its use solutions, or mists and vapors generated by the product. Eye contact may cause blindness. Ingestion may be harmful or fatal.

CARCINOGENICITY: NTP: No IARC Monographs: No OSHA Regulated: No SIGNS AND SYMPTOMS OF OVEREXPOSURE: Irritation of exposed tissues. Chronic exposure causes burns. Eyes, skin and mucous membranes may

be simultaneously irritated or burned if exposed to mists of phosphoric acid solutions. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: No data available. EMERGENCY AND FIRST AID PROCEDURES: Eyes: If contact with eyes occurs, flush with plenty of cool water for 15 minutes. Consult a physician. Skin: May be irritating to skin. If contact occurs, flush with water and wear gloves in the future to minimize exposure. Wash hands

thoroughly after handling. Discontinue use if irritation persists and consult a physician. Inhalation: Remove from exposure. Obtain medical attention immediately. Ingestion: May be harmful if swallowed. If ingested, drink large amounts of water or milk. DO NOT induce vomiting. Get medical attention

immediately. Avoid contamination of foods. Note to Physician: Extremely corrosive agent which will burn any exposed tissues upon other than very brief contact. Eyes, skin, and mucous

membranes should be flushed thoroughly with water, and ophthalmologic consultation should be obtained for any corneal burns. In case of ingestion, immediate dilution with water, milk or demulcent liquids is worthwhile, but attempts to neutralize with a base should be avoided because of excessive base and heat formation, which may increase the threat of esophagogastric perforation. Vomiting and diarrhea (laxative effect of phosphates) are to be expected with large doses. Parenteral fluid administration may be needed if losses therefrom are severe, or if shock ensues. Supportive care may be needed for such other complications as glottal edema, hematemesis and perforation (unlikely). Induced vomiting should be avoided because local tissue injury may be aggravated, but the patient should be watched hyperphospatemia and hypocalcemia. Milk or other demulcent liquids may be worthwhile for gastric irritation.

SECTION VII—PRECAUTIONS FOR SAFE HANDLING AND USE

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear acid-resistant suit and complete protective equipment including rubber gloves, boots, chemical goggles and faceshield. Small spills: mop up and dispose of in DOT-approved waste containers. Large spills: Contain by diking with soil or other absorbent material and carefully neutralize with soda ash or lime. If soda ash is used, provide adequate ventilation to dissipate carbon dioxide gas. Keep unneutralized material out of sewers, storm drains, surface waters, and soil.

WASTE DISPOSAL METHOD: Waste disposal must be done in accordance with all local, city or municipality, county, state, and federal regulations. Consult your state department of natural resources or the EPA for specific questions not answerable through other sources. Wastewater should never enter a fresh water body without treatment. If material cannot be salvaged, an acceptable method of disposal is neutralization followed by discharge into treatment system with large amounts of water..

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a dry, well-ventilated place above 50ºF. Store away from all other chemicals and potential sources of contamination. Do not use pressure to empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

OTHER PRECAUTIONS: Empty containers may have residues, gases, and mists, and are subject to proper waste disposal, as above. Always obey hazard warnings and handle empty containers as if they were full. Always keep product out of the reach of children.

SECTION VIII—OTHER REGULATORY INFORMATION

California Safe Drinking Water and Toxic Enforcement Act of 1986: Ethylene oxide 75-21-8 1,4 Dioxane 123-91-1 TSCA Inventory Status: All ingredients used in Calcium, Lime and Rust Remover are listed on the TSCA inventory.

SECTION IX—CONTROL MEASURES

RESPIRATORY PROTECTION: In general, respirators are not needed if the product is used in a well-ventilated area. However, use of a NIOSH/MSHA respirator may be a good common sense approach to working with products where dusts and mists are known to cause irritation of the eyes and/or mucous membranes.

VENTILATION: Local Exhaust: Recommended to control below TLV of 1 ppm for phosphoric acid.

Mechanical (General): Recommended to control below TLV of 1 ppm for phosphoric acid.

SKIN PROTECTION: Neoprene, rubber, or other chemical resistant gloves. Wear protective clothing to prevent repeated or prolonged contact.

EYE PROTECTION: Splash goggles, or safety glasses if splashing is not a concern. WORK/HYGIENIC PRACTICES: As good hygiene dictates.

Stearns Packaging Corporation makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Stearns Packaging Corporation as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Stearns Packaging Corporation assume any liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Stearns Packaging Corporation does not recommend blending this product with any other chemicals. All information, recommendations and data contained herein concerning this product are based upon information available at the time of writing from recognized technical sources.

The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000


I Product: ORIGINAL PINE-SOL BRAND CLEANER

Description: CLEAR AMBER LIQUID WITH CHARACTERISTIC PINE ODOR

Other Designations Distributor Emergency Telephone Nos.

EPA Reg. No. 5813-54 Clorox Sales Company

1221 Broadway Oakland, CA 94612

For Medical Emergencies, call 1-800-446-1014

For Transportation Emergencies, call

Chemtrec 1-800-424-9300

II Health Hazard Data III Hazardous Ingredients Eye irritant. May cause skin irritation. Avoid contact with food. No medical conditions are known to be aggravated by exposure to this product. FIRST AID: EYE CONTACT: Immediately flush eyes with plenty of water. If irritation persists, call a physician. INGESTION: Do not induce vomiting. Promptly drink a large amount of milk or water. Call a physician. SKIN CONTACT: Wash skin with water. If irritation persists, call a physician. INHALATION: Remove to fresh air. If breathing problems develop, call a physician.

Ingredient Concentration Worker Exposure Limit Pine oil 10 - 20% Not established. CAS # 8002-09-3

Isopropyl alcohol 4 - 7% 400 ppm - TLV-TWAa CAS #67-63-0 400 ppm - PELb 500 ppm - TLV-STELc Alkyl alcohol ethoxylates 2 - 6% Not established. CAS # 66455-15-0

aTLV-TWA = ACGIH Threshold Limit Value - Time Weighted Average bPEL = OSHA Permissible Exposure Limit - Time Weighted Average cTLV-STEL = ACGIH Threshold Limit Value - Short Term Exposure Limit None of the materials in this product are on the IARC, OSHA, or NTP carcinogen lists.

IV Special Protection and Precautions V Transportation and Regulatory Data Hygienic Practices: Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use local exhaust to minimize exposure to product mist. Personal Protective Equipment: Wear safety glasses. Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact.

DOT: Not restricted per 49 CFR 173.120(a)(3) and Appendix H.

IMDG: Not restricted per IMDG Code Page 0016 Paragraph 5.1.3.1.1.

IATA: Not restricted per IATA D.G.R. Sections 3.3.1.2 and 3.3.5.

EPA - SARA Title III/CERCLA: This product is regulated under Sections 311/312. This product contains no chemicals which are regulated under Section 313 and contains sodium dodecylbenzenesulfonate (CAS #25155-30-0, <4%), ammonium hydroxide (CAS #1336-21-6, <1%), benzoic acid (CAS #65-85-0, <1%) and glycol ethers (<1%) which are regulated under Section 304/CERCLA.

VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations.

Stable under normal use and storage conditions.

VIII Fire and Explosion Data IX Physical Data Flash Point: 105° F (Setaflash closed cup).

Fire Extinguishing Agents: Dry chemical, carbon dioxide (CO2), foam, or water spray.

pH...................................................................................................... 3.0 - 4.0

Specific gravity......................................................................................... ~1.0

Solubility in water .................................................................................Soluble

1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 4/01

Safety Data Sheet

Propane

Synonyms: Dimethylmethane, Liquefied Petroleum Gas (LPG), Sales Propane, Commercial Propane, Refinery Propane, Product Propane (non-odorized)

____________________________________________________________

GHS Classification:

Signal Word

Danger Hazard Statements

Precautionary Statements

Chemical Name:

Section 1 - Chemical Product and Company Identification

Section 2 - Hazards Identification

Company Information Product Information Product: Propane (odorized)Chemical Name: Propane Chemical Family: Liquified Petroleum Gas (Paraffinic Hydrocarbons) Chemical Formula: C3H8

GHS LABEL ELEMENTS Pictogram(s)

H220 - Extremely flammable gas. H280 - Contains gas under pressure, may explode if heated.

Prevention P210 - Keep away from heat/sparks/open flames/hot surfaces. No smokingResponseP376 - Stop leak if safe to do so.P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely.P381 - Eliminate all ignition sources if safe to do so.Storage P403 - Store in a well-ventilated place.P405 - Store locked up.P410 - Protect from sunlight.Disposal P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.

Flammable Gas - Category 1 Gases Under Pressure - Liquefied Gas

Ferrellgas (Blue Rhino) One Liberty Plaza Liberty, MO 64068 Emergency # 800-424-9300 (CHEMTREC)General SDS assistance # 855-738-9178 (Ferrellgas Safety Department)

Page 1 of 8 Revision Date 11/2014

http://www.hess.com/

Safety Data Sheet

Material Name: Propane

____________________________________________________________

First Aid: Eyes

First Aid: Skin

Remove contaminated clothing. In case of blistering, frostbite or freeze burns seek immediate medical attention. First Aid: Ingestion

Risk of ingestion is extremely low. However, if oral exposure occurs, seek immediate medical assistance. First Aid: Inhalation

Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.

General Fire Hazards See Section 9 for Flammability Properties. Liquid releases flammable vapors at well below ambient temperatures and readily forms a flammable mixture with air. Dangerous fire and explosion hazard when exposed to heat, sparks or flame. Vapors are heavier than air and may travel long distances to a point of ignition and flash back.

Hazardous Combustion Products Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).

Extinguishing Media Use extinguishing media suitable for the surrounding material, preferably or, any extinguisher suitable for Class B fires, dry chemical, fire fighting foam, CO2, and other gaseous agents. However, fire should not be extinguished unless flow of gas can be immediately stopped.

Unsuitable Extinguishing Media None

Section 3 - Composition / Information on Ingredients

Section 4 - First Aid Measures

Direct contact with liquid propane can result in eye burns.

Cover eyes to protect from light. Seek immediate medical attention. In case of contact with eyes, hold eyelids open to allow liquid to evaporate and gently flush with lukewarm water.

Direct contact with liquid propane can result in skin burns (frostbite).

This product is classified as a simple asphyxiant. High vapor concentrations may produce a reversiblecentral nervous system depression (anesthesia) and asphyxiation.

Section 5 - Fire Fighting Measures


CAS # Component Percent74-98-6 Propane 85 - 100 106-97-8 Butane and heavier 0 - 2.5 74-84-0 Ethane 0 - 5 115-07-1 Propylene 0 - 10 75-08-1 Ethyl Mercaptan 0 - 0.0025

Safety Data Sheet

Material Name: Propane Fire Fighting Equipment/Instructions

Gas fires should not be extinguished unless flow of gas can be immediately stopped. Shut off gas source and allow gas to burn out. If spill or leak has not ignited, determine if water spray may assist in dispersing gas or vapor to protect personnel attempting to stop leak. Use water to cool equipment, surfaces and containers exposed to fire and excessive heat. For large fire the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Isolate area, particularly around ends of storage vessels. Let vessel, tank car or container burn unless leak can be stopped. Withdraw immediately in the event of a rising sound from a venting safety device. Large fires typically require specially trained personnel and equipment to isolate and extinguish the fire. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH- approved pressure-demand self-contained breathing apparatus with full facepiece and full protective clothing.

Recovery and Neutralization Stop the source of the release, if safe to do so.

Materials and Methods for Clean-Up Do not flush down sewer or drainage systems. Do not touch spilled liquid (frostbite/freeze burn hazard!). Consider the use of water spray to disperse vapors. Isolate the area until gas has dispersed. Ventilate and gas test area before entering.

Emergency Measures Evacuate nonessential personnel and secure all ignition sources. No road flares, smoking or flames in hazard area. Consider wind direction, stay upwind and uphill, if possible. Evaluate the direction of product travel. Vapor cloud may be white, but color will dissipate as cloud disperses - fire and explosion hazard is still present!

Personal Precautions and Protective Equipment Do not touch spilled liquid (frostbite/freeze burn hazard!).

Environmental Precautions Do not flush down sewer or drainage systems.

Prevention of Secondary Hazards None

Handling Procedures

Storage Procedures

Incompatibilities Keep away from strong oxidizers, ignition sources and heat. Explosion hazard when exposed to chlorine dioxide. Heating barium peroxide with propane causes violent exothermic reaction. Heated chlorine-propane mixtures are explosive under some conditions.

Section 6 - Accidental Release Measures

Section 7 - Handling and Storage

Keep away from flame, sparks, ingnition sources and excessive temperatures. Use only in well ventilated areas.

Store only in approved containers. Keep away from flame, sparks, excessive temperatures and open flame. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition.

____________________________________________________________ Page 3 of 8 Revision Date 11/2014

Safety Data Sheet


____________________________________________________________

Component Exposure Limits Propane (74-98-6)

ACGIH: 1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C1-4) OSHA: 1000 ppm TWA; 1800 mg/m3 TWA

NIOSH: 1000 ppm TWA; 1800 mg/m3 TWA Ethane (74-84-0)

ACGIH: 1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C1-4) Propylene (115-07-1)

ACGIH: 500 ppm TWA

Engineering Measures Use adequate ventilation to keep gas and vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Use explosion-proof equipment and lighting in classified/controlled areas.

Personal Protective Equipment: Respiratory Use a NIOSH approved positive-pressure, supplied air respirator with escape bottle or self-contained breathing apparatus (SCBA) for gas concentrations above occupational exposure limits, for potential for uncontrolled release, if exposure levels are not known, or in an oxygen-deficient atmosphere. CAUTION: Flammability limits (i.e., explosion hazard) should be considered when assessing the need to expose personnel to concentrations requiring respiratory protection.

Personal Protective Equipment: Hands Use cold-impervious, insulating gloves where contact with liquid may occur.

Personal Protective Equipment: Eyes

Personal Protective Equipment: Skin and Body Where contact with liquid may occur, wear apron and faceshield.

Appearance: Colorless Odor: Odorless

Physical State: Gas pH: ND

Solubility (H2O): Specific Gravity:

Section 8 - Exposure Controls / Personal Protection

Section 9 - Physical & Chemical Properties

1.52 (Air = 1) -43.8°F (-42.1°C) Molecular Weight:Boiling Point: 44.096slight (0.1 to 1.0%)

Expansion Ratio: 1 to 270 (from liquid to gas @ 14.7 psia)

Where there is a possibility of liquid contact, wear splash-proof safety glasses and faceshield.

208 psig @ 100 °F (37.8 °C) 1.56 @ 32°F (0°C) Max Vapor Pressure: Vapor Density:

Burning Rate: ND Evaporation Rate: ND VOC: ND

Octanol/H2O Coeff.: ND Flash Point: -156°F (-104 °C) Flash Point Method: PMCC Auto Ignition: 842°F (450°C)

Upper Flammability Limit (UFL): 9.6%Lower Flammability Limit (LFL): 2.15%


Safety Data Sheet


Chemical Stability This is a stable material.

Will not occur. Conditions to Avoid

Keep away from strong oxidizers, ignition sources and heat. Incompatible Products

Explosion hazard when exposed to chlorine dioxide. Heating barium peroxide with propane causes violent exothermic reaction. Heated chlorine-propane mixtures are explosive under some conditions.

Hazardous Decomposition Products

Acute Toxicity A: General Product Information

Propane exhibits some degree of anesthetic action and is mildly irritating to the mucous membranes. At high concentrations propane acts as a simple asphyxiant without other significant physiological effects. High concentrations may cause death due to oxygen depletion.

Potential Health Effects: Skin Corrosion Property/Stimulativeness Vapors are not irritating. Direct contact to skin or mucous membranes with liquefied product or cold vapor may cause freeze burns and frostbite. Contact to mucous membranes with liquefied product may cause frostbite and freeze burns. Signs of frostbite include a change in the color of the skin to gray or white, possibly followed by blistering. Skin may become inflamed and painful.

Potential Health Effects: Eye Critical Damage/ Stimulativeness Vapors are not irritating. However, contact with liquid or cold vapor may cause frostbite, freeze burns, and permanent eye damage.

Potential Health Effects: Ingestion Ingestion is unlikely. Contact with mucous membranes with liquefied product may cause frostbite and freeze burns.

Section 10 - Chemical Stability & Reactivity Information

Section 11 - Toxicological InformationCarbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke) may be formed during combustion.

Hazardous Polymerization

Potential Health Effects: Inhalation This product is considered to be non-toxic by inhalation. Inhalation of high concentrations may cause central nervous system depression such as dizziness, drowsiness, headache, and similar narcotic symptoms, but no long-term effects. Numbness, a "chilly" feeling, and vomiting have been reported from accidental exposures to high concentrations. This product is a simple asphyxiant. In high concentrations it will displace oxygen from the breathing atmosphere, particularly in confined spaces. Signs of asphyxiation will be noticed when oxygen is reduced to below 16%, and may occur in several stages. Symptoms may include rapid breathing and pulse rate, headache, dizziness, visual disturbances, mental confusion, incoordination, mood changes, muscular weakness, tremors, cyanosis, narcosis and numbness of the extremities. Unconsciousness leading to central nervous system injury and possibly death will occur when the atmospheric oxygen concentration is reduced to about 6% to 8% or less. WARNING: The burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, and death.


Safety Data Sheet

Material Name: Propane Respiratory Organs Sensitization/Skin Sensitization

This product is not reported to have any skin sensitization effects. Generative Cell Mutagenicity

This product is not reported to have any mutagenic effects. Carcinogenicity A: General Product Information

This product is not reported to have any carcinogenic effects.

Reproductive Toxicity This product is not reported to have any reproductive toxicity effects.

Specified Target Organ General Toxicity: Repeated Exposure This product is not reported to have any specific target organ repeat effects.

Aspiration Respiratory Organs Hazard This product is not reported to have any aspiration hazard effects.

Ecotoxicity A: General Product Information

Liquid release is only expected to cause localized, non-persistent environmental damage, such as freezing. Biodegradation of this product may occur in soil and water. Volatilization is expected to be the most important removal process in soil and water. This product is expected to exist entirely in the vapor phase in ambient air.

B: Component Analysis - Ecotoxicity - Aquatic Toxicity

Section 12 - Ecological Information

No ecotoxicity data is available for this product's components.

Persistence/Degradability No information available.

Bioaccumulation No information available.

Mobility in Soil No information available.

Waste Disposal Instructions See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.

Disposal of Contaminated Containers or Packaging Dispose of contents/container in accordance with local/regional/national/international regulations.

____________________________________________________________

Section 13 - Disposal Considerations

DOT Information

Section 14 - Transportation Information

UN #: 1075 or 1978 Hazard Class: 2.1 Shipping Name: Petroleum Gases, Liquefied Placard:


Safety Data Sheet

Regulatory Information

Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Propylene (115-07-1)

SARA 313: 1.0 % de minimis concentration SARA Section 311/312 – Hazard Classes

Acute Health Chronic Health Fire Sudden Release of Pressure Reactive -- -- X X --

SARA SECTION 313 - SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:

INGREDIENT NAME (CAS NUMBER) CONCENTRATION PERCENT BY VOLUME Propylene (115-07-1) 30 max

State Regulations

Propylene 115-07-1 Yes DSL EINECS Ethane 74-84-0 Yes DSL

Yes DSL

Component Analysis - Inventory

Additional Regulatory Information No components are listed in the WHMIS IDL.

Component Analysis - WHMIS IDL

The following components appear on one or more of the following state hazardous substances lists:

Component Analysis - State


Section 15 - Regulatory Information

Component CAS CA MA MN NJ PA RI


Component CAS # TSCA CAN EUEINECS

Propane 74-98-6 EINECS

Propane 74-98-6 No Yes Yes Yes Yes YesEthane 74-84-0 No Yes Yes Yes Yes YesPropylene 115-07-1 Yes Yes Yes Yes Yes Yes

Safety Data Sheet


____________________________________________________________

* * * Section 16 - Other Information * * * NFPA® Hazard Rating Health 2

Fire 4 Reactivity 0

HMIS® Hazard Rating Health 2 Moderate Fire

hysical 4

Severe P 0 Minimal

4

Key/Legend

Literature References None

Other Information Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our

ritten contract of sale or acknowledgment. wVendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if

Issue Information

reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material.

FerrellgasOne Liberty PlazaLiberty, MO 64068

This Safety Data Sheet supersedes all previous editions.

2 0


Issued: November, 2014Issued by: Ferrellgas Safety Department

EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., NJTSR = New Jersey Trade Secret Registry; TSCA = Toxic Substance Control Act; EU = European Union; CAN = Canada


Product Identifier: 70-052 BREEZE EXTERIOR FLAT-ACCENT BASE











% CAS Number


species,route)


species)

TITANIUM DIOXIDE 1.63 - 1.86 13463-67-7 NOT AVAILABLE NOT AVAILABLE

PROPYLENE GLYCOL 1.68 - 1.7 57-55-6 20000 MG/KG(ORAL, RAT)

NOT AVAILABLE



Odour and Appearance: liquid with a slight ammonia smell







Boiling Point(º C ): Greater than 100°C

Freezing Point(º C ): Less than 0°C

pH: 8.5-9.5

Coefficient of Water/Oil Distribution: Not Available


Flammability:No If yes, Under which Conditions?Not Applicable


Flashpoint and Method: "Not Applicable

Upper Flammable Lt (% by Volume):Not Applicable

Lower Flammable Lt (% by Volume):Not Applicable

Autoignition Temperature: Not Applicable



Hazardous Combustion Pdts:nitrogen oxides, carbon dioxide, carbon monoxide




If yes, which ones? Strong Acids Strong Oxidizing agents Strong Bases

Reactivity, and under what conditions?heat, generation of dust, temperatures above 320°c

Hazardous Decomposition Products:oxides of nitrogen, ammonia, aldehydes


Route of Entry


Eye Contact: Yes


Effects to Acute exposure to Product: Insufficient Data

Effects to Chronic exposure to Product: PROPYLENE GLYCOL has been known to cause LACTIC ACIDOSIS.

Exposure Limits (Value,Units,By) TITANIUM DIOXIDE: 10 mg/m3 ACGIH PROPYLENE GLYCOL: 10 mg/m3 AIHA

Irritancy (if yes, explain)

Sensitization (if yes, explain) Carcinogenicity (if yes, explain) TITANIUM DIOXIDE is possibly carcinogenic to humans(2B) by IARC.

Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)




Gloves: No Respirator: Yes

Eye: No Footwear: No

Clothing: No

Other: No

If checked, specify type: Respirator: NIOSH APPROVED

Engineering controls (specify such as ventilation, enclosed process): Use mechanical ventilation to reduce exposure, ground all equipment and avoid exposure to open flames or sparks.



Handling Procedures and Equipment: Use in a well ventilated area. Do not use with incompatible substances and keep away from heat and all ignition sources. Use grounded and non-sparking equipment only.

Storage Requirements: Store in a cool, well ventilated area out of direct sunlight. Store away from heat and all ignition sources. Storage facility should be manufactured out of fire resistant materials.

Special Shipping Information: None Required








Phone: (604) 253-3131

Preparation Date: Oct 03, 2012

Date: 29 April 2013 Supercedes: 4 May 2010


IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300

1. PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION:

Product Name: PURELL® INSTANT HAND SANITIZER

Company Name & Address:

GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron, OH 44311

Emergency Phone: 1-800-424-9300 CHEMTREC

Non-Emergency Phone: (330) 255-6000 MSDS Request Phone: (330) 255-6000 x8804

2. INFORMATION ON INGREDIENTS:

HAZARDOUS INGREDIENTS CAS NUMBER OSHA PEL ACGIH TLV % RANGE

Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm 62 Isopropanol 67-63-0 400 ppm 200 ppm <5

Other ingredient(s) with notification requirements: CAS NUMBER List

Ethyl Alcohol 64-17-5 MA 1; NJ 1S; PA 1; CN 2 Isopropanol 67-63-0 MA 1; NJ 1S; PA; CN 1

3. HAZARDS IDENTIFICATION:

EMERGENCY OVERVIEW When used according to instructions, the product applicable to this MSDS is safe and presents no immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may require immediate medical attention.

Potential Health Effects:

HMIS: Health 2 Flammability 3 Reactivity 0 Personal Protection None

Eye Contact: May cause eye irritation. Skin Contact: No irritation or reaction expected. Inhalation: Not applicable. Ingestion: May cause upset stomach, nausea (Abnormal entry route). Carcinogenicity: Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH.

4. FIRST AID MEASURES:

Eye Contact: Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition worsens or irritation persists, contact physician.

Skin Contact: Not applicable. Inhalation: Not applicable. Ingestion: Do not induce vomiting. Contact a physician or Poison Control Center.

PURELL® INSTANT HAND SANITIZER Page 2 of 2

Document#: 9652-521

5. FIRE FIGHTING MEASURES:

NFPA: Health 2 Fire 3 Reactivity 0 Flashpoint °F/°C (PMCC method): 77°F/25°C Unusual Fire and Explosion Hazards: Product is flammable due to alcohol content. Special Fire Fighting Procedures: None known. Extinguishing Media: X Water Fog X Alcohol Foam X CO2 X Dry Chemical Other

6. ACCIDENTAL RELEASE MEASURES:

Avoid contact with ignition sources since product is flammable. Absorb onto inert material and dispose in appropriate manner. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES.

7. HANDLING AND STORAGE:

Keep away from fire or flame. Store at normal room temperature away from reach of small children. Keep containers sealed. Use older containers first. Avoid freezing conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION:

Eye Protection: None required under normal conditions. Skin Protection: None required under normal conditions. Respiratory Protection: None required under normal conditions. Ventilation: None required under normal conditions. Protective Equipment or Clothing: None required under normal conditions.

9. PHYSICAL AND CHEMICAL PROPERTIES:

Appearance and Odor Clear liquid, citrus fragrance pH (undiluted): 6.0 – 9.2 VOC , %: 65

10. STABILITY AND REACTIVITY:

Stable/Non reactive product. Avoid ignition sources. 11. TOXICOLOGICAL INFORMATION:

No acute or chronic toxic effects expected when used according to directions. 12. ECOLOGICAL CONSIDERATIONS:

No ecological or special considerations when used according to directions. Not considered environmentally harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment plants.

13. DISPOSAL CONSIDERATIONS:

Characteristic hazardous waste-flammable liquid. Dispose according to local, state and Federal regulations. 14. TRANSPORT INFORMATION:

Hazardous by transport regulations. When transported by ground modes in the U.S., this product typically is typically shipped as Consumer Commodity ORM-D. When transported by water, this product is typically shipped as a UN1170 in Limited Quantities. Refer to all current transport regulations for exact requirements.

15. REGULATORY AND OTHER INFORMATION:

TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(vi).

Complies with current FDA regulations for cosmetic and/or over-the-counter drug products.

This formula meets the FDA Food Code Hand Antiseptics (Sanitizers) criteria (Section 2-301.16).

WHMIS: Exempt under the Food and Drug Act Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product.

GRIME EATER PRODUCTS LIMITED Date : 2014-01-01

4140 B Sladeview Crescent Units # 1 & 2

Mississauga, Ontario, Canada, L5L 6A1

1-905-820-2255


1 PRODUCT IDENTIFICATION

Product Name : GRIME EATER ™ GEL WITH PUMICE HAND CLEANSER

Product Type : HAND CLEANSER - WATERLESS

2 INFORMATION ON INGREDIENTS

INGREDIENTS WITH REPORTING REQUIREMENTS

CAS # % RANGE OSHA PEL ACGIH TLV LD50 / LC50

112-80-1 3% - 7%

102-71-6 1% - 5% 5mg/m3 TWA

Products are notified cosmetics under the Food & Drug Act

3 HAZARDS IDENTIFICATION

These products when used as instructed are safe and pose no short or long term health hazards.

Incorrect or abnormal use ie : ingestion may require medical attention.

HAZARD RATING

Eye contact May cause eye irritation HEALTH 0

Skin contact No irritation under normal conditions FLAMMABILITY 0

Inhalation Not applicable REACTIVITY 0

Ingestion May cause upset stomach PERSONAL PROTECTION 0

0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH 4 = EXTREME

4 FIRST AID MEASURES

Eye contact Flush eyes thoroughly with potable water for 15 minutes. DO NOT RUB EYES UNDER ANY CIRCUMSTANCES.

Skin contact Not applicable

Inhalation Not applicable

Ingestion DO NOT induce vomiting. Drink plenty of water. Get medical attention.

OLEIC ACID

TRIETHANOLAMINE

Page 1 of 3

GRIME EATER ™ GEL WITH PUMICE HAND CLEANSER

5 FIRE FIGHTING MEASURES

Flash Point N/E

Recommended extinguishing media Carbon Dioxide, Dry Chemical

Special Fire Fighting Procedures None

Unusual Fire Explosion Hazards None

Hazardous Products Formed by Fire None anticipated

6 ACCIDENTAL RELEASE MEASURES

No special requirements. Rinse with water, mop up or wipe up with towel.

May cause slippery surfaces - exercise caution.

7 HANDLING AND STORAGE

Store at room temperature. Keep from extreme heat and freezing.

Keep out of reach of Children.

8 EXPOSURE CONTROL / PERSONAL PROTECTION

Eyes Not required

Skin Not required

Respiratory Not required

Ventilation Not required

Protective equipment Not required

9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance Green

Odor honey almond ( synthetic - allergy safe )

pH 8.0 - 9.0

Specific Gravity 0.985

VOC Content N/E

Viscosity N/E

Solubility in water yes

Page 2 of 3

GRIME EATER ™ GEL WITH PUMICE HAND CLEANSER

10 STABILITY AND REACTIVITY

Stable / Non reactive product

Avoid strong oxidizing agents

11 TOXICOLOGICAL INFORMATION

No acute or chronic toxic effects when used as directed.

12 ECOLOGICAL CONSIDERATIONS

No ecological / environmental issues with this product, when used in normal dilutions ( with water )

No concerns for typical usage / drainage to sewers, septic systems and treatment plants.

13 DISPOSAL CONSIDERATIONS

Dispose through a sanitary sewer in accordance with local, state / provincial and federal regulations.

14 TRANSPORT INFORMATION

Non Hazardous / Non flammable - No shipping restrictions

15 REGULATORY INFORMATION

Canada - These products have been classified in accordance with the hazard criteria of the CPR / IDL and the MSDS contains all

of the information required by the CPR. All ingredients listed on the DSL.

California Proposition 65 No California Prop 65 chemicals are known to exist at or above the No Significant Risk Level.

TSCA inventory status All ingredients listed

16 OTHER INFORMATION

Products are notified cosmetics under the Food & Drug Act

This MSDS is registered with Canadian Centre for Occupational Health & Safety ( CCOHS ) www.ccohs.ca PH 905-572-2981

DISCLAIMER

The information contained on this MSDS is based on available testing and data as supplied to Grime Eater Products Limited and is

believed to be correct and reliable, however no guarantee for it's accuracy or completeness is offered by Grime Eater.

Grime Eater assumes no responsibility or liability from loss or damage due to improper use, incompatibility of these products with

other products and failure to follow directions on the product label and MSDS.

Prepared By : Chemical Department

Company : Grime Eater Products Limited N/E = NOT ESTABLISHED

Telephone : 1-888-424-2976 / 905-820-2255 DNA = DOES NOT APPLY

Revision Date : 2014-01-01

Supercedes Date: 2012-11-01

Page 3 of 3

JACK OIL J132C

Page 1 of 6 MSDS Revision Date (mm/dd/yyyy): 07/11/2013


: JACK OIL Product identifier

SECTION 1: IDENTIFICATION

Hydraulic oil : Product Use

: Mixture. Chemical Family

J132C : Manufacturer part no.

Refer to Supplier

Manufacturer’s name and address: Supplier’s name and address:

Radiator Specialty Co., of Canada 1711 Aimco Blvd. Mississauga, ON, Canada L4W 1H7

(905) 625-9117 (Monday - Friday, 8 AM - 4 PM) : Information Telephone #

613-996-6666 (CANUTEC) : 24 Hr. Emergency Tel #

SECTION 2 - HAZARDS IDENTIFICATION

Classification : WHMIS information: This product is not a WHMIS controlled product in Canada. It does not meet any of the criteria for a controlled product provided in Part IV of the Controlled Products Regulations (CPR).

Emergency Overview Clear amber liquid. Petroleum odour. Fumes from heated product or mists may irritate respiratory tract. May cause mild eye irritation. Prolonged or repeated skin contact may cause drying and irritation.

:

POTENTIAL HEALTH EFFECTS:

:

Signs and symptoms of short-term (acute) exposure

If product is heated or mists are formed, inhalation may cause irritation to the nose, throat and respiratory tract.

Inhalation

: Skin Direct skin contact may result in little or no irritation.

: Eyes May cause mild transient irritation.

May cause irritation of mouth, throat, and stomach. May cause nausea, vomiting, and diarrhea. Ingestion :

Prolonged skin contact may cause dermatitis (rash), characterized by red, dry, itching skin.

Effects of long-term (chronic) exposure

:

See TOXICOLOGICAL INFORMATION, Section 11. : Carcinogenic status

Additional health hazards : See TOXICOLOGICAL INFORMATION, Section 11.

See ECOLOGICAL INFORMATION, Section 12. :

Potential environmental effects

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients CAS # Wt.%

64742-52-5 Distillates (petroleum), hydrotreated heavy naphthenic

60.00 - 100.00

*N/Av Zinc compounds < 0.3

*Note:: The specific identity of this component is considered proprietary information.

If inhaled, move to fresh air. If breathing has stopped, give artificial respiration. Consult a physician.

: Inhalation


JACK OIL J132C


Remove contaminated clothing. Wash off with soap and plenty of water. If irritation persists, seek prompt medical attention.

Skin contact :

Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists, seek prompt medical attention.

Eye contact :

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention.

:

Treat symptomatically. : Notes For Physician

Fire hazards/conditions of flammability


Not flammable under normal conditions of use. However, may ignite if exposed to extreme heat and flame. Product may float, and be re-ignited at the water's surface. Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Vapours are heavier than air and collect in confined and low-lying areas.

:

None known. : Oxidizing properties

: Not expected to be sensitive to mechanical impact or static discharge.

Explosion data: Sensitivity to mechanical impact / static discharge

Dry chemical, foam, carbon dioxide and water fog. Do not use water jet, as this may spread burning material.

: Suitable extinguishing media

Special fire-fighting procedures/equipment

Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. Move containers from fire area if safe to do so. Water spray may be useful in cooling equipment exposed to heat and flame.

:

Hazardous combustion products

: Carbon oxides; Phosphorus compounds; Nitrogen oxides (NOx); Polycyclic aromatic hydrocarbons; Sulphur oxides; Other unidentified organic compounds.

All persons dealing with the clean-up should wear the appropriate chemically protective equipment. Keep all other personnel upwind and away from the spill/release. Restrict access to area until completion of clean-up. Refer to protective measures listed in sections 7 and 8.



Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike the area to prevent spreading.

Environmental precautions :

Spill response/cleanup Ventilate area of release. Remove all sources of ignition. Contain and absorb spilled liquid with non-combustible, inert absorbent material (e.g. sand), then place absorbent material into a container for later disposal (see Section 13). Notify the appropriate authorities as required.

:

: Prohibited materials Do not use combustible absorbents, such as sawdust.

Use with adequate ventilation. Wear suitable protective equipment during handling. Avoid breathing vapours. Avoid contact with skin, eyes and clothing. Keep away from extreme heat and flame. Avoid contact with incompatible materials. Wash thoroughly after handling. Keep container tightly closed when not in use.

Safe Handling procedures :


Store in a cool, dry, well-ventilated area. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Inspect periodically for damage or leaks.

Storage requirements :

Incompatible materials : Strong oxidizing agents.

Special packaging materials : Always keep in containers made of the same materials as the supply container.

Exposure Limits

ACGIH TLV OSHA PEL

STEL TWA STEL PEL Ingredients

5 mg/m³ (As 'Oil

mist, mineral') N/Av 5 mg/m³ (As 'Oil mist,

mineral') N/Av Distillates (petroleum), hydrotreated

heavy naphthenic

N/Av N/Av N/Av N/Av Zinc compounds

SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION

JACK OIL J132C


Ventilation and engineering measures

Use in a well-ventilated area. Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits.

:

Respiratory protection : If the TLV is exceeded, a NIOSH/MSHA-approved respirator is advised. Advice should be sought from respiratory protection specialists.

Skin protection : Gloves impervious to the material are recommended. Advice should be sought from glove suppliers. Depending on conditions of use, an impervious apron should be worn.

Eye / face protection : Safety glasses with side-shields or chemical splash goggles.

An eyewash station and safety shower should be made available in the immediate working area.

: Other protective equipment

General hygiene considerations

: Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink, smoke or use cosmetics while working with this product. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid : Appearance Light amber liquid. :

Odour Petroleum odour. : Odour threshold N/Av :

pH N/Av :

Boiling point 0.895 @ 20°C : Specific gravity : 240.5°C

Melting/Freezing point N/Av :

N/Av :

Coefficient of water/oil distribution

Vapour pressure (mmHg @ 20° C / 68° F)

0.008 :

Solubility in water Insoluble. :

Vapour density (Air = 1) 4.3 : Evaporation rate (n-Butyl acetate = 1)

: < 1

Volatile organic Compounds (VOC's)

N/Av :

Volatiles (% by weight) : N/Av

Flash point 160°C :

Flash point Method Not available. : Auto-ignition temperature Cleveland Open Cup :

Lower flammable limit (% by vol.) Upper flammable limit (% by vol.)

: : N/Av N/Av

Flame Projection Length Flashback observed : : N/Ap N/Ap

Absolute pressure of container

: N/Ap

Viscosity : N/Av

No additional information. : General Informatioln

Section 10: STABILITY AND REACTIVITY

Stability and reactivity Stable under the recommended storage and handling conditions prescribed. :

Hazardous polymerization Hazardous polymerization does not occur. :

Conditions to avoid : Avoid heat and open flame.

Materials To Avoid And Incompatibility

: See Section 7 (Handling and Storage) for further details.

Hazardous decomposition products None known, refer to hazardous combustion products in Section 5. :

Eyes, skin, respiratory system and digestive system. Target organs :

SECTION 11 - TOXICOLOGICAL INFORMATION

Routes of exposure Inhalation: Skin Absorption: Skin & Eyes: Ingestion: YES YES NO YES :

: May be mildly irritating to eyes and skin. Irritancy

There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data.

: Toxicological data

LD50 LC50(4hr)

inh, rat Ingredients (Rabbit, dermal) (Oral, rat)

Distillates (petroleum),

hydrotreated heavy naphthenic

> 5 mg/L (mist) > 5000 mg/kg > 2000 mg/kg

JACK OIL J132C


Zinc compounds N/Av N/Av N/Av

Carcinogenic status No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP. Use caution when pouring this material. This product can generate a complex mixture of airbourne material during heating or in a fire. This combustion material can include carcinogenic polycyclic aromatic hydrocarbons.

:

: Not expected to have other reproductive effects. Reproductive effects

: Teratogenicity Not expected to be a teratogen.

: Mutagenicity Not expected to be mutagenic in humans.

: Epidemiology None known or reported by the manufacturer.

Sensitization to material : Not expected to be a skin or respiratory sensitizer.

: Synergistic materials None known or reported by the manufacturer.

None known or reported by the manufacturer. other important hazards :

Conditions aggravated by overexposure

Pre-existing skin and respiratory disorders. :

Ecotoxicity : The ecological characteristics of this product have not been fully investigated. The product should not be allowed to enter drains or water courses, or be deposited where it can affect ground or surface waters. See the following tables for individual ingredient ecotoxicity data.

SECTION 12 - ECOLOGICAL INFORMATION

Ecotoxicity data:

NOEC / 21 day LC50 / 96h M Factor

Toxicity to Fish CAS No Ingredients



> 5000 mg/L (Rainbow

trout)

64742-52-5 N/Av None.

Zinc compounds N/Av *N/Av N/Av None.

CAS No Ingredients Toxicity to Daphnia

EC50 / 48h NOEC / 21 day M Factor

64742-52-5 None. N/Av > 1000 mg/L [Daphnia magna (Water flea)]



*N/Av None. N/Av N/Av Zinc compounds

CAS No Ingredients Toxicity to Algae

EC50 / 96h or 72h NOEC / 96h or 72h M Factor

64742-52-5 Distillates (petroleum),


> 1000 mg/L/96hr (Green

algae) N/Av None.

*N/Av Zinc compounds N/Av N/Av None.

Mobility No data is available on the product itself. :

Persistence No data is available on the product itself. Contains: Distillates (petroleum), hydrotreated heavy naphthenic. Distillates (petroleum), hydrotreated heavy naphthenic is not considered readily biodegradable and is insoluble in water. The substance may persist in the environment.

:

Bioaccumulation potential No data is available on the product itself. :

Other Adverse Environmental effects

No data is available on the product itself. :

JACK OIL J132C


Handle waste according to recommendations in Section 7. : Handling for Disposal

SECTION 13 - DISPOSAL CONSIDERATIONS

Dispose of in accordance with federal, provincial and local hazardous waste laws. : Methods of Disposal

SECTION 14: TRANPORT INFORMATION

Regulatory Information UN Number Shipping Name Class

Packing Group Label

Not regulated. not regulated TDG None none

None.

Additional information

TDG


Labelling:

This product is not a WHMIS controlled product in Canada. As such, this product does not require a WHMIS Supplier label.

Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL). WHMIS information: Refer to Section 2 for a WHMIS Classification for this product.

Canadian Information:

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the

information required by the CPR.

TSCA: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory.

US Federal Information:


: ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Services HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer Inh: Inhalation LC: Lethal Concentration LD: Lethal Dose MSHA: Mine Safety and Health Administration N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health NOEC: No observable effect concentration NTP: National Toxicology Program OECD: Organisation for Economic Co-operation and Development OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit RTECS: Registry of Toxic Effects of Chemical Substances STEL: Short Term Exposure Limit TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System .

Legend

JACK OIL J132C


1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2013. 2. International Agency for Research on Cancer Monographs, searched 2013. 3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2013 (Chempendium, HSDB and RTECs). 4. Material Safety Data Sheets from manufacturer. 5. OECD - The Global Portal to Information on Chemical Substances - eChemPortal, 2013

References :

Prepared for:

Radiator Specialty Co. of Canada 1711 Aimco Blvd. Mississauga, ON, Canada, L4W 1H7 Telephone: 905-625-9117 (Mon. - Fri., 8 AM - 4 PM) Please direct all enquiries to Radiator Specialty.

Prepared by:

ICC The Compliance Center Inc. http://www.thecompliancecenter.com

DISCLAIMER OF LIABILITY

This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by Radiator Specialty Co. of Canada and CCOHS’ Web Information Service. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and Radiator Specialty Co. of Canada expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and Radiator Specialty Co. of Canada.

:

MSDS Preparation Date (mm/dd/yyyy)

07/26/2007

MSDS Revision Date (mm/dd/yyyy)

: 07/11/2013

Revision No. 3 :

(M)SDS sections updated: 12. ECOLOGICAL INFORMATION.

: Revision Information

END OF DOCUMENT

Safety Data Sheet

Revision Number: 004.0 Issue date: 08/29/2014

IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 1 of 7

1. PRODUCT AND COMPANY IDENTIFICATION Product name: PST® 592 Pipe Sealant With PTFE IDH number: 88567 Product type: Anaerobic Sealant Item number: 59214 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067

Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com


EMERGENCY OVERVIEW

WARNING: CAUSES SKIN AND EYE IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.

HAZARD CLASS HAZARD CATEGORY

SKIN IRRITATION 2

EYE IRRITATION 2B

SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing dust or fumes. Wash thoroughly after handling. Contaminated work clothing

should not be allowed out of the workplace. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing.

Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local

governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.


Hazardous Component(s) CAS Number Percentage*

Mica 12001-26-2 10 - 30

Polyglycol dimethacrylate Proprietary 10 - 30


Polyglycoldioctanoate Proprietary 10 - 30

Octan-1-ol 111-87-5 10 - 30

Ethene, tetrafluoro-, homopolymer 9002-84-0 5 - 10

Silica, amorphous, treated 68909-20-6 1 - 5

Titanium dioxide 13463-67-7 1 - 5

Propane-1,2-diol 57-55-6 1 - 5

Cumene hydroperoxide 80-15-9 0.1 - 1

Benzaldehyde 100-52-7 0.1 - 1

Cumene 98-82-8 0.1 - 1

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.


Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove

contaminated clothing and footwear. Wash clothing before reuse. Get medical attention.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.

Symptoms: See Section 11.


Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray.

Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in

explosions or rupture of storage containers.

Hazardous combustion products: Oxides of carbon. Toxic fluorine compounds. Irritating organic vapours.

6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to

prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.



Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8.

Storage: For safe storage, store at or below 38 °C (100.4 °F)

Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

Mica 3 mg/m3 TWA

Respirable fraction. 20 MPPCF TWA None None

Polyglycol dimethacrylate None None None None

Polyglycoldioctanoate None None None None

Octan-1-ol None None 50 ppm (265 mg/m3)

TWA None

Ethene, tetrafluoro-, homopolymer None None None

10 mg/m3 TWA Total dust.

5 mg/m3 TWA Respirable fraction.

Silica, amorphous, treated 10 mg/m3 TWA Inhalable dust.

6 mg/m3 TWA None None

Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total

dust. None None

Propane-1,2-diol None None 10 mg/m3 TWA

Aerosol. None

Cumene hydroperoxide None None 1 ppm (6 mg/m3)

TWA (SKIN)

None

Benzaldehyde None None

4 ppm (17.4 mg/m3) STEL

2 ppm (8.7 mg/m3) TWA (Skin sensitizer)

None

Cumene 50 ppm TWA 50 ppm (245 mg/m3)

PEL (SKIN)

None None

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below

exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should

be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an

apron or body suit to prevent skin contact. Neoprene, Butyl-rubber, or nitrile-rubber gloves.



Physical state: Paste Color: White Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 10 mm hg (27 °C (80.6 °F)) Boiling point/range: > 149 °C (> 300.2 °F) Melting point/ range: Not available. Specific gravity: 1.21 Vapor density: Not available. Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 0.72 %; 6.86 g/l Viscosity: Not available. Decomposition temperature: Not available.


Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials.

Hazardous decomposition products:

Oxides of carbon. Toxic fluorine compounds. Irritating organic vapours.

Incompatible materials: Strong oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from

incompatible materials.


Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion


Potential Health Effects/Symptoms

Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Vapors may cause headaches, nausea, dizziness and respiratory tract irritation.

Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes eye irritation. Ingestion: May cause gastrointestinal tract irritation if swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects

Mica None Lung Polyglycol dimethacrylate None Allergen, Irritant Polyglycoldioctanoate None Irritant

Octan-1-ol Oral LD50 (RAT) = > 5 g/kg

Dermal LD50 (RABBIT) = > 5 g/kg Central nervous system, Irritant

Ethene, tetrafluoro-, homopolymer None No Target Organs Silica, amorphous, treated None No Target Organs

Titanium dioxide None Irritant, Respiratory, Some evidence of

carcinogenicity

Propane-1,2-diol Oral LD50 (RABBIT) = 18 g/kg

Oral LD50 (RAT) = 30 g/kg Irritant

Cumene hydroperoxide None Allergen, Central nervous system, Corrosive,

Irritant, Mutagen

Benzaldehyde Oral LD50 (RAT) = 1,300 mg/kg

Dermal LD50 (RABBIT) = > 1,250 mg/kg Allergen, Central nervous system, Irritant

Cumene Oral LD50 (RAT) = 2.91 g/kg

Oral LD50 (RAT) = 1,400 mg/kg Inhalation LC50 (RAT, 4 h) = 8000 ppm

Central nervous system, Irritant, Lung

Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen

(Specifically Regulated)

Mica No No No

Polyglycol dimethacrylate No No No

Polyglycoldioctanoate No No No

Octan-1-ol No No No

Ethene, tetrafluoro-, homopolymer No No No

Silica, amorphous, treated No No No

Titanium dioxide No Group 2B No

Propane-1,2-diol No No No

Cumene hydroperoxide No No No

Benzaldehyde No No No

Cumene No Group 2B No


Ecological information: Not available.



Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: D018: Benzene.

14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

International Air Transportation (ICAO/IATA)


Water Transportation (IMO/IMDG)


15. REGULATORY INFORMATION United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.

TSCA 12 (b) Export Notification: Ethene, tetrafluoro-, homopolymer (CAS# 9002-84-0).

CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This

product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List.


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

Prepared by: Sheila Gines, Regulatory Affairs Specialist

Issue date: 08/29/2014


DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

Product Name: MOBIL HYDRAUL 56

Revision Date: 28 Aug 2014 Page 1 of 9

______________________________________________________________________________________________________________________


Product Name: MOBIL HYDRAUL 56 Product Description: Base Oil and Additives MSDS Number: 20777 Product Code: 20152050B510 Intended Use: Hydraulic fluid


Supplier: Imperial Oil Downstream 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada


1-866-232-9563



HEALTH EFFECTS

Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.


Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use



______________________________________________________________________________________________________________________

adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT


EYE CONTACT





FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Smoke, Fume, Oxides of carbon, Sulphur oxides


Flash Point [Method]: >198°C (389°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D



PROTECTIVE MEASURES



______________________________________________________________________________________________________________________

Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.




Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator.

STORAGE

The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION



______________________________________________________________________________________________________________________

Substance Name Form Limit/Standard Note Source HYDROTREATED MIDDLE DISTILLATE (PETROLEUM)

Inhalable fraction.

TWA 5 mg/m3 ACGIH

Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following is recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction). NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS





No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.




______________________________________________________________________________________________________________________

ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.


Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D


Relative Density (at 15 °C): 0.884 Flash Point [Method]: >198°C (389°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Vapour Density (Air = 1): > 2 at 101 kPa [Estimated] Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20ºC [Estimated] Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 55 cSt (55 mm2/sec) at 40ºC | 9.6 cSt (9.6 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/A Pour Point: -36°C (-33°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt Decomposition Temperature: N/D

SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION



______________________________________________________________________________________________________________________

ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation

Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.

Ingestion Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.

Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on

assessment of the components.

Eye Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on

assessment of the components. CHRONIC/OTHER EFFECTS

Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. MIDDLE DISTILLATES: Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitising in test animals.

CMR Status: None. Chemical Name CAS Number List Citations HYDROTREATED MIDDLE DISTILLATE (PETROLEUM)

64742-46-7 4

--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land.



______________________________________________________________________________________________________________________

Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may



Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants.






SECTION 15 REGULATORY INFORMATION



______________________________________________________________________________________________________________________

WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements AICS, DSL, ENCS, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC ALKYLDITHIOPHOSPHATE 68649-42-3 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Disposal Considerations - Disposal Recommendations information was modified. Section 09: Boiling Point C(F) information was modified. Section 09: Pour Point C(F) information was modified. Section 09: Flash Point C(F) information was modified. Section 09: n-Octanol/Water Partition Coefficient information was modified. Section 05: Hazardous Combustion Products information was modified. Section 09: Flash Point C(F) information was modified. Section 09: Autoignition Temperature information was modified. Section 09 Viscosity information was modified. Section 09 Viscosity information was modified. Section 15: National Chemical Inventory Listing information was modified. Section 09: Relative Density information was modified. Section 16: MSN,MAT ID information was modified. Section 11: Chronic Tox - Component - WHMIS information was modified. Section 08: Exposure Limits Table information was added. Section 11: Chemical Name - Header information was added. Section 11: CAS Number - Header information was added. Section 11: List Citation - Header information was added. Section 11: Tox List Cited Table information was added. Section 08: OEL Table - Substance Name Column - Header information was added.



______________________________________________________________________________________________________________________

Section 08: OEL Table - Form Column - Header information was added. Section 08: OEL Table - Limit Column - Header information was added. Section 08: OEL Table - Notation Column - Header information was added. Section 08: OEL Table - Source Column - Header information was added. Section 09: Vapour Pressure information was added. Section 15: Special Cases - Header information was deleted. Section 15: Special Cases Table information was deleted. Section 15: Inventory - Header information was deleted. Section 15: Status - Header information was deleted. Section 09: Vapour Pressure information was deleted. ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 7105047 (538859) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety

Product Name: LIGHT DISTILLATE

Revision Date: 09 Apr 2013 Page 1 of 12

______________________________________________________________________________________________________________________


Product Name: (see Section 16 for Synonyms) LIGHT DISTILLATE Product Description: Petroleum Distillates MSDS Number: 8529 Product Code: 10102015 Intended Use: Fuel/solvent/blend stock




1-866-232-9563


SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity KEROSENE, STRAIGHT RUN 8008-20-6 0 - 100% None LIGHT ATMOSPHERIC GAS OIL 64741-44-2 0 - 100% None LIGHT HYDROCRACKED DISTILLATE (PETROLEUM) 64741-77-1 0 - 100% None Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity NAPHTHALENE 91-20-3 < 1% Dermal Lethality: LD50 >

2500 mg/kg (Rat); Inhalation Lethality: LC50 > 0.4 mg/l (Rat); Oral Lethality: LD50 622 mg/kg (Mouse)

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS

Combustible. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.

HEALTH EFFECTS

Irritating to skin. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. Breathing of high vapour concentrations may cause dizziness, light-headedness, headache,



______________________________________________________________________________________________________________________

nausea and loss of co-ordination. Continued inhalation may result in unconsciousness. High-pressure injection under skin may cause serious damage. Target Organs: Skin |

NFPA Hazard ID: Health: 2 Flammability: 2 Reactivity: 0 HMIS Hazard ID: Health: 2* Flammability: 2 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION


SKIN CONTACT

Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

EYE CONTACT


Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN

If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE

Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis.



FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to



______________________________________________________________________________________________________________________

protect personnel. Unusual Fire Hazards: Combustible. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon


Flash Point [Method]: 40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D



PROTECTIVE MEASURES


SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.





______________________________________________________________________________________________________________________


Avoid all personal contact. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Loading/Unloading Temperature: ND Transport Temperature: N/D Transport Pressure: N/D Static Accumulator: This material is a static accumulator.

STORAGE

The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge. Storage Temperature: N/D Storage Pressure: N/D

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source KEROSENE, STRAIGHT RUN Stable

Aerosol. TWA 5 mg/m3 Supplier

KEROSENE, STRAIGHT RUN Vapour. TWA 200 mg/m3 Supplier KEROSENE, STRAIGHT RUN [as total hydrocarbon vapor]

Non-Aerosol TWA 200 mg/m3 Skin ACGIH

LIGHT ATMOSPHERIC GAS OIL Stable Aerosol.

TWA 5 mg/m3 Supplier

LIGHT ATMOSPHERIC GAS OIL Vapour. TWA 200 mg/m3 Supplier LIGHT HYDROCRACKED DISTILLATE (PETROLEUM)

Stable Aerosol.

TWA 5 mg/m3 Supplier

LIGHT HYDROCRACKED DISTILLATE (PETROLEUM)

Vapour. TWA 200 mg/m3 Supplier

NAPHTHALENE STEL 15 ppm Skin ACGIH NAPHTHALENE TWA 10 ppm Skin ACGIH




______________________________________________________________________________________________________________________


Use explosion-proof ventilation equipment to stay below exposure limits.



Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.


Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.


Physical State: Liquid Colour: Pale Yellow Odour: Petroleum/Solvent



______________________________________________________________________________________________________________________

Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 °C): 0.85 Flash Point [Method]: 40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: 180°C (356°F) - 320°C (608°F) [Estimated] Vapour Density (Air = 1): N/D Vapour Pressure: [N/D at 20 °C] | < 1 kPa (7.5 mm Hg) at 38°C Evaporation Rate (n-butyl acetate = 1): < 1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 1.7 cSt (1.7 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/A Pour Point: -39°C (-38°F) Decomposition Temperature: N/D

SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation


Irritation: No end point data for material. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on assessment of the components.

Ingestion


Skin

Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.



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Irritation (Rabbit): Data available. Moderately irritating to skin with prolonged exposure. Based on test data for structurally similar materials.

Eye

Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.

CHRONIC/OTHER EFFECTS For the product itself:

Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Contains: KEROSENE: Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in animal tests. MIDDLE DISTILLATES WITH CRACKED STOCKS: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung function. NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain.

CMR Status: Chemical Name CAS Number List Citations KEROSENE, STRAIGHT RUN 8008-20-6 4 NAPHTHALENE 91-20-3 3, 4

--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic

environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and

wastewater solids.



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High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY Biodegradation: Majority of components -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties may



Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.


SECTION 14 TRANSPORT INFORMATION LAND (TDG)

Proper Shipping Name: FUEL OIL (Kerosene) Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Marine Pollutant: Yes Footnote: Marine Pollutant designation is applicable only if shipped over water.

LAND (DOT)

Proper Shipping Name: DIESEL FUEL Hazard Class & Division: 3 ID Number: 1993



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Packing Group: III ERG Number: 128 Label(s): None Transport Document Name: UN1993, DIESEL FUEL, 3, PG III Footnote: The flash point of this material is greater than 38ºC/100ºF. Regulatory classification of this material varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable liquid. This material is not regulated under 49 CFR in a container of 450 litre/119 gallon capacity or less when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance.

SEA (IMDG)

Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 EMS Number: F-E, S-E UN Number: 1202 Packing Group: III Marine Pollutant: Yes Label(s): 3 Transport Document Name: UN1202, HEATING OIL, LIGHT, 3, PG III, (40°C c.c.), MARINE POLLUTANT

AIR (IATA)

Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name: UN1202, HEATING OIL, LIGHT, 3, PG III

SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements DSL, TSCA Special Cases:

Inventory Status AICS Not determined ENCS Not determined IECSC Not determined KECI Not determined PICCS Not determined



______________________________________________________________________________________________________________________

The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations NAPHTHALENE 91-20-3 5

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Protective Measures was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 09: Pour Point C(F) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: VAPOUR PRESSURE was modified. Section 09: Vapour Pressure was modified. Section 11: Inhalation Irritation Test Data was modified. Section 06: Accidental Release-Spill Management-Land was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 04: First Aid Pre-existing Medical Conditions was modified. Section 08: Respiratory Protection was modified. Section 14: Transport Document Name was modified. Section 14: Label(s) was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 11: Additional Health Information was modified. Section 14: DOT Footnote was modified. Section 15: Special Cases Table was modified. Composition: Component table was modified. Composition: Component table was modified. Section 08: Exposure Limits Table was modified. Section 16: Land Spill was modified. Section 16: Water Spill was modified. Section 15: Canadian List Citations Table was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. Section 09: Decomposition Temperature was added. Section 09: Decomposition Temp - Header was added. Section 01: Product Code was added. Section 01: Product Code - Header was added. SYNONYMS: AUTOMOTIVE (ON-ROAD) DIESEL FUEL, DIESEL ARCTIC, DIESEL FUEL, DIESEL LOW SULPHUR



______________________________________________________________________________________________________________________

LIGHT, DIESEL LOW SULPHUR LIGHT DYED, DIESEL LOW SULPHUR LIGHT RAIL, DIESEL REGULAR SULPHUR LIGHT DYED, FURNACE FUEL LIGHT, FURNACE FUEL LIGHT DYED, MC SOLVENT, STOVE OIL, STOVE OIL DYED ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS Irritating to skin. If swallowed, may be aspirated and cause lung damage. Target Organs: Skin | PHYSICAL HAZARDS Combustible. In use, may form flammable/explosive vapour-air mixture. Material can accumulate static charges which may cause an ignition. PRECAUTIONS Avoid all personal contact. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. Report spills as required to appropriate authorities. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy



______________________________________________________________________________________________________________________

itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007490 (552455) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety

Product Name: MIDDLE DISTILLATE

Revision Date: 26 Nov 2014 Page 1 of 11

______________________________________________________________________________________________________________________


Product Name: (see Section 16 for Synonyms) MIDDLE DISTILLATE Product Description: Hydrocarbons and Additives MSDS Number: 826 Intended Use: Fuel




1-866-232-9563


SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity FUEL OIL NO. 2 68476-30-2 > 99 % None Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity NAPHTHALENE 91-20-3 < 1% Inhalation Lethality: LC50 >

0.4 mg/l (Rat); Oral Lethality: LD50 710 mg/kg (Mouse); Oral Lethality: LD50 533 mg/kg (Mouse)

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS

Combustible. In use, may form flammable/explosive vapour-air mixture. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.

HEALTH EFFECTS

Irritating to skin. If swallowed, may be aspirated and cause lung damage. Under conditions of poor personal hygiene and prolonged repeated contact, some polycyclic aromatic compounds (PACs) have been suspected as a cause of skin cancer in humans. May be irritating to the eyes, nose, throat, and lungs. High-pressure



______________________________________________________________________________________________________________________

injection under skin may cause serious damage. Target Organs: Skin |



SKIN CONTACT

Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

EYE CONTACT



If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE

Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis.



FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering



______________________________________________________________________________________________________________________

streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Combustible. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Static discharge: material can accumulate static charges which may cause an incendiary electrical discharge. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Sulphur oxides, Smoke, Fume, Aldehydes, Oxides of carbon, Incomplete combustion products


Flash Point [Method]: >40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.7 UEL: 6.5 Autoignition Temperature: N/D



PROTECTIVE MEASURES


SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Eliminate sources of ignition. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.





______________________________________________________________________________________________________________________


Avoid breathing mists or vapour. Avoid contact with skin. Do not siphon by mouth. It is dangerous and/or unlawful to put petrol into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.

STORAGE

The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source FUEL OIL NO. 2 Stable

Aerosol. TWA 5 mg/m3 Supplier

FUEL OIL NO. 2 Vapour. TWA 200 mg/m3 Supplier FUEL OIL NO. 2 [total hydrocarb, vapor&aerosol]

Inhalable fraction and vapour

TWA 100 mg/m3 Skin ACGIH

NAPHTHALENE TWA 10 ppm Skin ACGIH NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS


Adequate ventilation should be provided so that exposure limits are not exceeded.

PERSONAL PROTECTION



______________________________________________________________________________________________________________________

Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:


If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves.

Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.




Physical State: Liquid Colour: Clear (May Be Dyed) Odour: Petroleum/Solvent Odour Threshold: N/D


Relative Density (at 15.5 °C): 0.82 - 0.9



______________________________________________________________________________________________________________________

Flash Point [Method]: >40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.7 UEL: 6.5 Autoignition Temperature: N/D Boiling Point / Range: 150°C (302°F) - 370°C (698°F) Vapour Density (Air = 1): 4 at 101 kPa Vapour Pressure: [N/D at 20°C] | 4 kPa (30 mm Hg) at 38°C Evaporation Rate (n-butyl acetate = 1): < 1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 1.3 cSt (1.3 mm2/sec) at 40ºC - 11 cSt (11 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/A Pour Point: -4°C (25°F) - -39°C (-38°F) Decomposition Temperature: N/D


Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.

Based on assessment of the components.

Ingestion Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar

materials.

Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar

materials. Irritation: Data available. Moderately irritating to skin with prolonged exposure.

Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on




______________________________________________________________________________________________________________________


Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Diesel exhaust fumes: Carcinogenic in animal tests. Inhalation exposures to exhaust for 2 years in test animals resulted in lung tumours and lymphoma. Extract of particulate produced skin tumours in test animals. Caused mutations in-vitro. Diesel fuel: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung function. Contains: NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain.

CMR Status: Chemical Name CAS Number List Citations FUEL OIL NO. 2 68476-30-2 4 NAPHTHALENE 91-20-3 3, 4


environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment

and wastewater solids. High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the

land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Hydrocarbon component -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL



______________________________________________________________________________________________________________________

Hydrocarbon component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.





Proper Shipping Name: FUEL OIL Hazard Class & Division: 3 UN Number: 1202 Packing Group: III

LAND (DOT)

Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 ID Number: 1202 Packing Group: III ERG Number: 128 Label(s): 3 Transport Document Name: UN1202, HEATING OIL, LIGHT, 3, PG III Footnote: The flash point of this material is greater than 38ºC/100ºF. Regulatory classification of this material varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable liquid.

SEA (IMDG)

Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 EMS Number: F-E, S-E



______________________________________________________________________________________________________________________

UN Number: 1202 Packing Group: III Label(s): 3 Transport Document Name:

AIR (IATA)

Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name:

SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Listed or exempt from listing/notification on the following chemical inventories: DSL, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations NAPHTHALENE 91-20-3 5

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 05: Hazardous Combustion Products information was modified. Section 15: National Chemical Inventory Listing - Header information was modified. Section 08: Exposure Limits Table information was modified. SYNONYMS: DIESEL REGULAR SULPHUR RAIL #3, ULTRA LOW SULPHUR DIESEL, DIESEL MARINE,



______________________________________________________________________________________________________________________

DIESEL LOW SULPHUR RAIL, DIESEL LOW SULPHUR, DIESEL LOW SULPHUR DYED, DIESEL MARINE GAS OIL, DIESEL REGULAR SULPHUR, DIESEL REGULAR SULPHUR RAIL, DIESEL REGULAR SULPHUR DYED, ESSO DIESEL FUEL, DIESEL REGULAR SULPHUR RAIL DYED, ESSO HEATING OIL, FURNACE FUEL DYED, FURNACE FUEL, ISO 8217 DMA, ISO 8217 DMB, NO. 2 FUEL OIL, REGULAR SULPHUR DIESEL FUEL, DIESEL MARINE DYED, DIESEL MARINE GAS OIL INTERNATIONAL, DIESEL MARINE GAS OIL DYED, DIESEL FUEL, AUTOMOTIVE (ON-ROAD) DIESEL FUEL, FURNACE LOW S DYED, FURNACE LOW S, DIESEL MARINE - NLA DYED, DIESEL LOW SULPHUR RAIL DYED, DIESEL MARINE CGSB-3.11, DIESEL MARINE CGSB DYED, NAVAL DISTILLATE FUEL ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS Irritating to skin. If swallowed, may be aspirated and cause lung damage. Target Organs: Skin | PHYSICAL HAZARDS In use, may form flammable/explosive vapour-air mixture. Combustible. Material can accumulate static charges which may cause an ignition. PRECAUTIONS Avoid contact with skin. Do not siphon by mouth. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Eliminate sources of ignition. Remove from the surface by skimming or with suitable absorbents. Report spills as required to appropriate authorities. Seek the advice of a specialist before using dispersants.



______________________________________________________________________________________________________________________

----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5000908 (1004214) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety

Product Name: UNIREX EP 0


______________________________________________________________________________________________________________________


Product Name: UNIREX EP 0 Product Description: Base Oil and Additives MSDS Number: 8386 Product Code: 2015A020W020 Intended Use: Grease




1-866-232-9563



HEALTH EFFECTS



Under normal conditions of intended use, this material is not expected to be an inhalation hazard.



______________________________________________________________________________________________________________________

SKIN CONTACT


EYE CONTACT





FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Oxides of carbon, Smoke, Fume, Sulphur oxides, Incomplete combustion products


Flash Point [Method]: 174°C (345°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: >260°C (500°F)



PROTECTIVE MEASURES

Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.



______________________________________________________________________________________________________________________

For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.


Prevent entry into waterways, sewers, basements or confined areas.


Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.

STORAGE

Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS



PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use



______________________________________________________________________________________________________________________

with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:







Physical State: Solid Form: Semi-fluid Colour: Dark Green Odour: Characteristic Odour Threshold: N/D


Relative Density: 0.93 Flash Point [Method]: 174°C (345°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: >260°C (500°F)



______________________________________________________________________________________________________________________

Boiling Point / Range: 293°C (559°F) Vapour Density (Air = 1): > 5 at 101 kPa Vapour Pressure: < 0.01 kPa (0.08 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): < 0.01 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: >20 cSt (20 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt Decomposition Temperature: N/D NOTE: Most physical properties above are for the oil component in the material.


Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.





assessment of the components. CHRONIC/OTHER EFFECTS For the product itself:



______________________________________________________________________________________________________________________

An ingredient or ingredients that are classified as a skin sensitizer. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.

CMR Status: None.


Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may



Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate recycling methods in accordance with applicable regulations and material characteristics at the time of disposal .



______________________________________________________________________________________________________________________






SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION



______________________________________________________________________________________________________________________

N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 16: Not determined, Not applicable information was modified. Section 09: Vapour Pressure information was modified. Hazard Identification: NFPA Health information was modified. Hazard Identification: HMIS Health information was modified. Section 05: Hazardous Combustion Products information was modified. Section 15: National Chemical Inventory Listing - Header information was modified. Section 15: National Chemical Inventory Listing information was modified. Section 12: Ecological Information - Acute Aquatic Toxicity information was added. Section 12: Ecological Information - Acute Aquatic Toxicity information was added. Section 12: Ecological Information - Acute Aquatic Toxicity information was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity information was deleted. ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007339 (1011757) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety



______________________________________________________________________________________________________________________


Product Name: (see Section 16 for Synonyms) UNIREX EP 2 Product Description: Base Oil and Additives MSDS Number: 20444 Product Code: 2015A0207210 Intended Use: Grease




1-866-232-9563



HEALTH EFFECTS



Under normal conditions of intended use, this material is not expected to be an inhalation hazard.



______________________________________________________________________________________________________________________

SKIN CONTACT


EYE CONTACT





FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon


Flash Point [Method]: >200°C (392°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D



PROTECTIVE MEASURES

Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.



______________________________________________________________________________________________________________________

For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT Land Spill: Allow spilled material to solidify and shovel it up into a suitable container for recycle or disposal. Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.




Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.

STORAGE

Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS



PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications,



______________________________________________________________________________________________________________________

handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:







Physical State: Solid Form: Semi-fluid Colour: Green Odour: Characteristic Odour Threshold: N/D


Relative Density: 0.89 Flash Point [Method]: >200°C (392°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D



______________________________________________________________________________________________________________________

Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: < 0.01 kPa (0.08 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 220 cSt (220 mm2/sec) at 40ºC | 18.5 cSt (18.5 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: >260°C (500°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material.


Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Not determined. Based on assessment of the components.








______________________________________________________________________________________________________________________

An ingredient or ingredients that are classified as a skin sensitizer. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.

Additional information is available by request. CMR Status: None.

--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to

partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may




REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain



______________________________________________________________________________________________________________________

residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.





SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, IECSC, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable



______________________________________________________________________________________________________________________

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 09: Vapour Pressure was modified. Section 15: Canadian List Citations Table was modified. Section 04: First Aid Skin was modified. Section 11: Other Health Effects Header was modified. Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 06: Accidental Release - Protective Measures - Header was added. Hazard Identification: Health Hazards was modified. Section 11: Dermal Lethality Test Data was modified. Section 11: Dermal Lethality Test Comment was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Inhalation Lethality Test Data was modified. Section 11: Dermal Irritation Test Data was modified. Section 11: Eye Irritation Test Data was modified. Section 11: Oral Lethality Test Comment was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 09 Viscosity was modified. Section 08: Hand Protection was modified. Section 08: Skin and Body Protection was modified. Section 11: Skin Irritation Conclusion was modified. Section 09: Melting Point C(F) was modified. Section 11: Other Health Effects was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted. Section 01: Company Contact Methods Sorted by Priority was modified. Section 06: Protective Measures was modified. SYNONYMS: Unirex EP 2 Electroluber ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 7091356 (1015501) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety



______________________________________________________________________________________________________________________

Product Name: UNLEADED GASOLINE

Revision Date: 23 Feb 2015 Page 1 of 13

______________________________________________________________________________________________________________________


Product Name: (see Section 16 for Synonyms) UNLEADED GASOLINE Product Description: Hydrocarbons and Additives MSDS Number: 8522 Intended Use: Fuel




1-866-232-9563


SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ETHYL ALCOHOL 64-17-5 0 - 1% None GASOLINE 86290-81-5 > 99 % None METHYL-TERT-BUTYL ETHER 1634-04-4 0 - 1% Oral Lethality: LD50 4000

mg/kg (Rat) Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity BENZENE 71-43-2 0 - 1.5% None CUMENE 98-82-8 0 - 1% None CYCLOHEXANE 110-82-7 0 - 1.5% None ETHYL BENZENE 100-41-4 0 - 3.5% Inhalation Lethality: LC50

17.8 mg/l (Rat); Oral Lethality: LD50 3.5 g/kg (Rat)

n-Hexane 110-54-3 0 - 5% None NAPHTHALENE 91-20-3 0 - 1% Inhalation Lethality: LC50 >

0.4 mg/l (Rat); Oral Lethality: LD50 710 mg/kg (Mouse); Oral Lethality: LD50 533 mg/kg (Mouse)

TOLUENE 108-88-3 0 - 20% None XYLENES 1330-20-7 0 - 20% None * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.



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NOTE: The concentration of the components shown above may vary substantially. In certain countries, benzene content may be limited to lower levels. Oxygenates such as tertiary-amyl-methyl ether, ethanol, di-isopropyl ether, and ethyl-tertiary-butyl ether may be present. Because of volatility considerations, gasoline vapor may have concentrations of components very different from those of liquid gasoline. The major components of gasoline vapor are: butane, isobutane, pentane, and isopentane. The reportable component percentages, shown in the composition/information on ingredients section, are based on API's evaluation of a typical gasoline mixture. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS

FLAMMABLE. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.

HEALTH EFFECTS

May cause cancer. Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. May cause central nervous system depression. High-pressure injection under skin may cause serious damage. Exposure to benzene is associated with cancer (acute myeloid leukaemia and myelodysplastic syndrome), damage to the blood-producing system, and serious blood disorders (see Section 11).

NFPA Hazard ID: Health: 1 Flammability: 3 Reactivity: 0 HMIS Hazard ID: Health: 1* Flammability: 3 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION


SKIN CONTACT


EYE CONTACT



If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.



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This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.



FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Extremely Flammable. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous Combustion Products: Sulphur oxides, Aldehydes, Oxides of carbon, Incomplete combustion products, Smoke, Fume


Flash Point [Method]: -40°C (-40°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 1.4 UEL: 7.6 Autoignition Temperature: >250°C (482°F)



PROTECTIVE MEASURES

Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills:



______________________________________________________________________________________________________________________

full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas of fire and explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.




Avoid breathing mists or vapour. Avoid all personal contact. Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Do not siphon by mouth. Use only with adequate ventilation. Do not use as a cleaning solvent or other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful to put petrol into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container. Do not use electronic devices (including but not limited to cellular phones, computers, calculators, pagers or other electronic devices etc) in or around any fuelling operation or storage area unless the devices are certified intrinsically safe by an approved national testing agency and to the safety standards required by national and/or local laws and regulations. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.

STORAGE

Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container



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choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source BENZENE STEL 1 ppm Supplier BENZENE TWA 0.5 ppm Supplier BENZENE STEL 2.5 ppm Skin ACGIH BENZENE TWA 0.5 ppm Skin ACGIH CUMENE TWA 50 ppm ACGIH CYCLOHEXANE TWA 100 ppm ACGIH ETHYL ALCOHOL STEL 1000 ppm ACGIH ETHYL BENZENE TWA 20 ppm ACGIH GASOLINE STEL 200 ppm Supplier GASOLINE TWA 100 ppm Supplier GASOLINE Vapour. TWA 300 mg/m3 100 ppm Supplier GASOLINE STEL 500 ppm ACGIH GASOLINE TWA 300 ppm ACGIH METHYL-TERT-BUTYL ETHER TWA 50 ppm ACGIH n-Hexane TWA 50 ppm Skin ACGIH NAPHTHALENE TWA 10 ppm Skin ACGIH TOLUENE TWA 20 ppm ACGIH XYLENES STEL 150 ppm ACGIH XYLENES TWA 100 ppm ACGIH





No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.



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Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:






Physical State: Liquid Colour: Clear (May Be Dyed) Odour: Petroleum/Solvent Odour Threshold: N/D


Relative Density (at 15 °C): 0.74 Flash Point [Method]: -40°C (-40°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 1.4 UEL: 7.6 Autoignition Temperature: >250°C (482°F) Boiling Point / Range: > 20°C (68°F) - 225°C (437°F) Vapour Density (Air = 1): 3.2 at 101 kPa Vapour Pressure: > 26.6 kPa (200 mm Hg) at 20ºC | 76 kPa (570 mm Hg) at 38 °C - 103 kPa (772.5 mm Hg) at 38°C Evaporation Rate (n-butyl acetate = 1): > 10 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3 Solubility in Water: Negligible Viscosity: <1 cSt (1 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.



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OTHER INFORMATION

Freezing Point: N/D Melting Point: N/A Decomposition Temperature: N/D

SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Halogens, Strong Acids, Alkalies, Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation

Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Elevated temperatures or mechanical action may form vapours,

mist, or fumes which may be irritating to the eyes, nose, throat, or lungs.

Ingestion

Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.

Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Mildly irritating to skin with prolonged exposure. Based on




Laboratory animal studies have shown that prolonged and repeated inhalation exposure to light hydrocarbon vapours in the same boiling range as this product can produce adverse kidney effects in male rats. However, these effects were not observed in similar studies with female rats, male and female mice, or in limited studies with other animal species. Additionally, in a number of human studies, there was no clinical evidence of such effects at normal occupational levels. In 1991, The U.S. EPA determined that the male rat kidney is not useful for assessing human risk. Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits), and to



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heart-stimulating substances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may initiate arrhythmias. Contains: BENZENE: Caused cancer (acute myeloid leukemia and myelodysplastic syndrome), damage to the blood-producing system, and serious blood disorders in human studies. Caused genetic effects and effects on the immune system in laboratory animal and some human studies. Caused toxicity to the fetus and cancer in laboratory animal studies. CUMENE: Repeated inhalation exposure of cumene vapour produced damage in the kidney of male rats only. These effects are believed to be species specific and are not relevant to humans. ETHANOL: Prolonged or repeated exposure to high concentrations of ethanol vapour or overexposure by ingestion may produce adverse effects to brain, kidney, liver, and reproductive organs, birth defects in offspring, and developmental toxicity in offspring. GASOLINE UNLEADED: Carcinogenic in animal tests. Chronic inhalation studies resulted in liver tumours in female mice and kidney tumours in male rats. Neither result considered significant for human health risk assessment by the United States EPA and others. Did not cause mutations in-vitro or in-vivo. Negative in inhalation developmental studies and reproductive tox studies. Inhalation of high concentrations in animals resulted in reversible central nervous system depression, but no persistent toxic effect on the nervous system. Non-sensitizing in test animals. Caused nerve damage in humans from abusive use (sniffing). METHYL TERTIARY BUTYL ETHER (MTBE): Carcinogenic in animal tests. Inhalation exposure to high concentrations resulted in higher than expected mortality in male mice due to urinary tract obstructions and female mice displayed benign liver tumours. Inhalation exposure to high concentrations resulted in higher than expected mortality in male rats due to progressive kidney damage as well as increased benign and malignant kidney tumours, and benign testicular tumours. Did not cause mutations in-vitro or in-vivo. Rabbits exposed to high vapour concentrations did not have any offspring with adverse developmental effects. Mice exposed to high vapour concentrations (maternally toxic) had offspring with embryo/fetal toxicity and birth defects. Rats exposed to high vapour concentrations did not display any treatment-related effects in a two generation reproduction study.The significance of the animal findings at high exposures are not believed to be directly related to potential human health hazards in the workplace. NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain. N-HEXANE: Prolonged and/or repeated exposures to n-Hexane can cause progressive and potentially irreversible damage to the peripheral nervous system (e.g. fingers, feet, arms, legs, etc.). Simultaneous exposure to Methyl Ethyl Ketone (MEK) or Methyl Isobutyl Ketone (MIBK) and n-Hexane can potentiate the risk of adverse effects from n-Hexane on the peripheral nervous system. n-Hexane has been shown to cause testicular damage at high doses in male rats. The relevance of this effect for humans is unknown. TOLUENE : Concentrated, prolonged or deliberate inhalation may cause brain and nervous system damage. Prolonged and repeated exposure of pregnant animals (> 1500 ppm) have been reported to cause adverse fetal developmental effects. ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is uncertain. XYLENES: High exposures to xylenes in some animal studies have been reported to cause health effects on the developing embryo/fetus. These effects were often at levels toxic to the mother. The significance of these findings to humans has not been determined.

CMR Status: Chemical Name CAS Number List Citations BENZENE 71-43-2 1, 4, 5 CUMENE 98-82-8 3, 4 CYCLOHEXANE 110-82-7 4 ETHYL ALCOHOL 64-17-5 4 ETHYL BENZENE 100-41-4 3, 4 GASOLINE 86290-81-5 3, 4



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METHYL-TERT-BUTYL ETHER 1634-04-4 4 n-Hexane 110-54-3 4 NAPHTHALENE 91-20-3 3, 4 TOLUENE 108-88-3 4 XYLENES 1330-20-7 4


environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment

and wastewater solids. Less volatile component -- Low solubility and floats and is expected to migrate from water to the land.

Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Majority of components -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties

may reduce the bioconcentration or limit bioavailability.





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Proper Shipping Name: GASOLINE Hazard Class & Division: 3 UN Number: 1203 Packing Group: II Marine Pollutant: Yes Special Provisions: 17 Footnote: Marine Pollutant designation is applicable only if shipped over water.

LAND (DOT)

Proper Shipping Name: GASOLINE Hazard Class & Division: 3 ID Number: 1203 Packing Group: II ERG Number: 128 Label(s): 3 Transport Document Name: UN1203, GASOLINE, 3, PG II

SEA (IMDG)

Proper Shipping Name: MOTOR SPIRIT or GASOLINE or PETROL Hazard Class & Division: 3 EMS Number: F-E, S-E UN Number: 1203 Packing Group: II Label(s): 3 Transport Document Name: UN1203, MOTOR SPIRIT or GASOLINE or PETROL, 3, PG II, (-40°C c.c.)

AIR (IATA)

Proper Shipping Name: MOTOR SPIRIT or GASOLINE or PETROL Hazard Class & Division: 3 UN Number: 1203 Packing Group: II Label(s) / Mark(s): 3 Transport Document Name: UN1203, GASOLINE, 3, PG II

SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material



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This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations BENZENE 71-43-2 6 CUMENE 98-82-8 6 CYCLOHEXANE 110-82-7 6 ETHYL BENZENE 100-41-4 6 METHYL-TERT-BUTYL ETHER 1634-04-4 6 n-Hexane 110-54-3 6 NAPHTHALENE 91-20-3 6 TOLUENE 108-88-3 6 XYLENES 1330-20-7 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 05: Hazardous Combustion Products information was modified. Section 15: National Chemical Inventory Listing - Header information was modified. Composition: Component table information was modified. Composition: Component table information was modified. Section 08: Exposure Limits Table information was modified. SYNONYMS: GASOLINE REGULAR UNLEADED RUL87 DCA DYED, GASOLINE PREMIUM UNLEADED PUL91 DCA, GASOLINE PREMIUM UNLEADED PUL91 LDCA, GASOLINE PREMIUM UNLEADED PUL91 LDCA DYED, ISOOCTANE, AUTOMOTIVE GASOLINE, ESSO SUPREME GASOLINE, GASOLINE REGULAR UNLEADED RUL87 LDCA DYED, ESSO EXTRA GASOLINE, GASOLINE REGULAR UNLEADED RUL87 LDCA, EXXON MIDGRADE GASOLINE, ESSO PREMIUM GASOLINE, ESSO MIDGRADE GASOLINE, ESSO REGULAR GASOLINE, GASOLINE MIDGRADE UNLEADED MUL89 DCA, EXXON REGULAR GASOLINE, GASOLINE MIDGRADE UNLEADED MUL89, EXXON PREMIUM GASOLINE, GASOLINE REGULAR UNLEADED RUL87 DYED, GASOLINE MIDGRADE



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UNLEADED MUL89 DCA DYED, GASOLINE REGULAR UNLEADED RUL87, GASOLINE PREMIUM UNLEADED PUL91, GASOLINE RBOB BLENDSTOCK P91, GASOLINE RBOB BLENDSTOCK R87, GASOLINE MIDGRADE UNLEADED MUL89 LDCA, GASOLINE MIDGRADE UNLEADED MUL89 LDCA DYED, GASOLINE REGULAR UNLEADED RUL87 DCA, GASOLINE PREMIUM UNLEADED PUL91 DCA DYED ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material HEALTH HAZARDS May cause cancer. Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. May cause central nervous system depression. PHYSICAL HAZARDS FLAMMABLE. Material can accumulate static charges which may cause an ignition. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. PRECAUTIONS Avoid breathing mists or vapour. Avoid all personal contact. Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Do not siphon by mouth. Use only with adequate ventilation. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas of fire and explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the advice of a specialist before using dispersants.



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Product Name: BLOCK GREASE S-100

Revision Date: 10 Sep 2012 Page 1 of 9

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Product Name: BLOCK GREASE S-100 Product Description: Base Oil and Additives MSDS Number: 8363 Product Code: 2015A020R010 Intended Use: Grease




1-866-232-9563


SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ASPHALT (PETROLEUM) 8052-42-4 5 - 15% None ROSIN (PINE ROSIN, COLOPHONY) 8050-09-7 5 - 15% None SODIUM STEARATE 822-16-2 10 - 20% None * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

HEALTH EFFECTS

May cause sensitisation by skin contact. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.

NFPA Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary



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from person to person. SECTION 4 FIRST AID MEASURES INHALATION

Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT

Wash contact areas with soap and water. Remove contaminated clothing. Wash carefully behind ears, under nails and in skin folds. Get medical assistance. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

EYE CONTACT





FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon


Flash Point [Method]: 182°C (360°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: 204°C (400°F)

SECTION 6 ACCIDENTAL RELEASE MEASURES



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NOTIFICATION PROCEDURES


PROTECTIVE MEASURES

Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.




Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.

STORAGE

Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source ASPHALT (PETROLEUM) [benzene solubles]

Inhalable fraction.

TWA 0.5 mg/m3 ACGIH

SODIUM STEARATE TWA 10 mg/m3 ACGIH



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Chemical / oil resistant clothing if contact with material is likely. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.



SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES



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Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION

Physical State: Solid Form: Semi-fluid Colour: Brown Odour: Characteristic Odour Threshold: N/D


Relative Density (at 15 °C): 0.9 Flash Point [Method]: 182°C (360°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: 204°C (400°F) Boiling Point / Range: 371°C (700°F) [Estimated] Vapour Density (Air = 1): > 2 at 101 kPa [Estimated] Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20ºC [Estimated] Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: [N/D at 40°C] | 10.3 cSt (10.3 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt Decomposition Temperature: N/D



Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.



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Ingestion


Skin

Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.

Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.

Eye

Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.


Sensitisation: Allergic dermatitis in humans. The study was conducted on structurally similar material. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.

Additional information is available by request. CMR Status: None. Chemical Name CAS Number List Citations ASPHALT (PETROLEUM) 8052-42-4 4 SODIUM STEARATE 822-16-2 4


Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable



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BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may



If Regulated, dispose of waste in a secure hazardous waste landfill. If not regulated, dispose of as normal refuse.






SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or



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have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: None.

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 11: Inhalation Irritation Test Data was modified. Section 14: LAND (TDG) - Header was modified. Section 15: National Chemical Inventory Listing was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS May cause sensitisation by skin contact. PRECAUTIONS Avoid contact with skin. FIRST AID Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Wash carefully behind ears, under nails and in skin folds. Get medical assistance. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal.



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Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Report spills as required to appropriate authorities. Skim from surface Use Not intended or suitable for use in or around a household or dwelling. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007315 (1017155) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety

Product Name: COMMERCIAL PROPANE (ODORIZED)

Revision Date: 07 Jun 2013 Page 1 of 11

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Product Name: COMMERCIAL PROPANE (ODORIZED) Product Description: Liquefied Hydrocarbon Gas, Gas or Liquefied Gas MSDS Number: 8515 Intended Use: Fuel gas




1-866-232-9563


SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ALKANES, C4 68513-65-5 0 - 2.5% None ETHANE 74-84-0 0 - 5% None ISOBUTANE 75-28-5 0 - 2.5% Inhalation Lethality: LC50 >

13000 ppm (Rat) PROPANE 74-98-6 90 - 99% None PROPYLENE 115-07-1 1 - 10% None * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS

Flammable Gas. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Frostbite hazard - rapidly expanding gas or liquid may cause frostbite. Material can accumulate static charges which may cause an ignition.

HEALTH EFFECTS

Continued exposure to odorised gas may reduce or eliminate ability to smell the odorant. People with impaired ability to detect odour due to colds, allergies, injuries etc must be especially cautious. Odour must not be used exclusively as a safety measure. Proper respiratory protection and fire/explosion precautions should be utilised when odour is first detected. Inert gas and/or simple asphyxiant. Reduces oxygen available for breathing. Exposure to concentrations above 10% of the LEL may cause a general central nervous system



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(CNS) depression typical of anesthetic gases or intoxicants. Aliphatic hydrocarbon gases may build up in confined spaces and may cause dizziness, light-headedness, headache, nausea and loss of co-ordination. Continued inhalation may result in narcosis, unconsciousness, and possibly lead to death. High-pressure injection under skin may cause serious damage.


Immediately remove from further exposure. Get immediate medical assistance. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device.

SKIN CONTACT

If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. If frostbite occurs, immerse involved area in water at body temperature. Keep immersed for 20 to 40 minutes. Seek medical assistance.

EYE CONTACT

Flush thoroughly with water for at least 15 minutes. Get medical assistance. INGESTION

Not Applicable NOTE TO PHYSICIAN

This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.


Appropriate Extinguishing Media: Use water fog, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water

FIRE FIGHTING

Fire Fighting Instructions: Allow the fire to burn under controlled conditions. Stop leak if you can do so without risk. Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from entering streams,



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sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Flammable Gas. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Incomplete combustion products, Oxides of carbon


Flash Point [Method]: -103°C (-153°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 2.4 UEL: 9.5 Autoignition Temperature: 432°C (810°F)



PROTECTIVE MEASURES

Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of the spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that provide chemical resistance and, when necessary, heat-resistance and/or thermal insulation are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Small spills: normal work clothes are usually adequate. Large spills: full body suit of chemical and thermal resistant material is recommended. Chemical goggles and face shield are recommended if contact with liquefied gas is possible.

SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. Allow liquid to evaporate from the surface. All equipment used when handling the product must be grounded. Do not direct water at spill or source of leak. Do not touch or walk through spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Isolate area until gas has dispersed. Prevent spreading of vapour through sewers, ventilation systems and confined areas. Use water spray to reduce vapour or divert vapour cloud drift. Avoid allowing water run-off to contact spilled material. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Allow liquid to evaporate from the surface. See Land Spill section of the SDS for advice on gases. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction



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and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.




Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Ethyl mercaptan is added to gas as an odorant to aid in the detection of the gas in case of leak or accidental discharge. Since ethyl mercaptan is reactive, a reduction in its effectiveness may occur during transport and storage of the odorised gas. Therefore, odour must not be used exclusively as a safety measure. Handle gas with strict adherence to established safety procedures. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. Material can accumulate static charges which may cause an electrical spark (ignition source). Static Accumulator: This material is a static accumulator.

STORAGE

Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source ISOBUTANE STEL 1000 ppm ACGIH PROPYLENE TWA 500 ppm ACGIH




PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator



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selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:


If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves. Thermally protective, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves.

Eye Protection: If contact is likely, safety glasses with side shields are recommended. Face shield is recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Thermally protective and chemical resistant apron and long sleeves are recommended when volume of material is significant.





Physical State: Gas Form: Liquefied Colour: Colourless Odour: Mercaptan Odour Threshold: N/D


Relative Density (at 15 °C): 0.51 Flash Point [Method]: -103°C (-153°F) [ASTM D-92]



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Flammable Limits (Approximate volume % in air): LEL: 2.4 UEL: 9.5 Autoignition Temperature: 432°C (810°F) Boiling Point / Range: -42°C (-44°F) Vapour Density (Air = 1): 1.5 at 101 kPa Vapour Pressure: 850 kPa (6375 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): > 1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/A Solubility in Water: Negligible Viscosity: [N/D at 40 °C] | 0.5 cSt (0.5 mm2/sec) at 15°C Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: N/D Melting Point: >-187°C (-305°F)



Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.

Ingestion

Toxicity: No end point data for material. Not applicable.

Skin Toxicity: No end point data for material. Not applicable. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test



data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself:

May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue,



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mental confusion and blurred vision) and/or damage. Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite (cold burn). Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits), and to heart-stimulating substances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may initiate arrhythmias. Simple asphyxiant: Acts by displacing oxygen in the lungs thereby diminishing the supply of oxygen available to the blood and tissues. Symptoms include shortness of breath, rapid heart rate, incoordination, lethargy, headaches, nausea, vomiting, and disorientation. Continued lack of oxygen may result in convulsions, loss of consciousness and death. Since exercise increases the tissue need for oxygen, symptoms will occur more quickly during exertion in an oxygen-deficient environment. Oxygen in enclosed spaces should be maintained at 21 percent by volume.

CMR Status: None. Chemical Name CAS Number List Citations ISOBUTANE 75-28-5 4 PROPYLENE 115-07-1 4

--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Material -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater

solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be inherently biodegradable Atmospheric Oxidation: Material -- Expected to degrade at a moderate rate in air BIOACCUMULATION POTENTIAL Material -- Potential to bioaccumulate is low.

SECTION 13 DISPOSAL CONSIDERATIONS



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Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS




Proper Shipping Name: LIQUEFIED PETROLEUM GASES Hazard Class & Division: 2.1 UN Number: 1075 Packing Group: (N/A)

LAND (DOT)

Proper Shipping Name: PETROLEUM GASES, LIQUEFIED Hazard Class & Division: 2.1 ID Number: 1075 Packing Group: (N/A) ERG Number: 115 Label(s): 2.1 Transport Document Name: UN1075, PETROLEUM GASES, LIQUEFIED, 2.1

SEA (IMDG)

Proper Shipping Name: PETROLEUM GASES, LIQUEFIED Hazard Class & Division: 2.1 EMS Number: F-D, S-U UN Number: 1075 Packing Group: (N/A) Label(s): 2.1 Transport Document Name: UN1075, PETROLEUM GASES, LIQUEFIED, 2.1 (-103°C c.c.)

AIR (IATA)

Proper Shipping Name: PETROLEUM GASES, LIQUEFIED Hazard Class & Division: 2.1 UN Number: 1075 Packing Group: (N/A) Label(s) / Mark(s): 2.1 Transportation Limitations: CARGO AIRCRAFT ONLY Transport Document Name: UN1075, PETROLEUM GASES, LIQUEFIED, 2.1



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SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class A: Compressed Gas Class B, Division 1: Flammable Gases This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations PROPYLENE 115-07-1 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATIONN/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Protective Measures was modified. Section 09: Boiling Point C(F) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapour Pressure was modified. Section 11: Dermal Lethality Test Data was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Inhalation Irritation Test Data was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Autoignition Temperature was modified. Section 09 Viscosity was modified. Section 09 Viscosity was modified. Section 14: Transport Document Name was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Section 11: Additional Health Information was modified. Section 16: MSN,MAT ID was modified.



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Section 09: Melting Point C(F) was modified. Composition: Component table was modified. Section 16: CA Contains was modified. Section 08: Exposure Limits Table was modified. Section 15: Canadian List Citations Table was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: Contains: ALKANES, C4; ISOBUTANE; PROPYLENE; ETHANE; PROPANE WHMIS Classification: Class A: Compressed Gas Class B, Division 1: Flammable Gases HEALTH HAZARDS May cause central nervous system depression. PHYSICAL HAZARDS Flammable Gas. In use, may form flammable/explosive vapour-air mixture. Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygen below safe breathing levels. Frostbite hazard - rapidly expanding gas or liquid may cause frostbite. Material can accumulate static charges which may cause an ignition. PRECAUTIONS Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Inhalation: Immediately remove from further exposure. Get immediate medical assistance. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device. Eye: Flush thoroughly with water for at least 15 minutes. Get medical assistance. Skin: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. If frostbite occurs, immerse involved area in water at body temperature. Keep immersed for 20 to 40 minutes. Seek medical assistance. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. Allow liquid to evaporate from the surface. Do not direct water at spill or source of leak. If possible, turn leaking containers so that gas escapes rather than liquid. Isolate area until gas has dispersed. Prevent spreading of vapour through sewers, ventilation systems and confined areas. Use water spray to reduce vapour or divert vapour cloud drift. Avoid allowing water run-off to contact spilled material. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Allow liquid to evaporate from the surface. Report spills as required to appropriate authorities. See Land Spill section of the SDS for advice on gases.



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CLR CALCIUM, LIME & RUST REMOVER

521012 Page 1 of 6 Date issued 01-October-2012

1 - PRODUCT AND COMPANY IDENTIFICATION SDS ID: 521012 Product Name CLR Calcium, Lime & Rust Remover Product Use Aqueous Acidic Cleaner for Removal of Calcium, Lime, and Rust from Hard

Surfaces Retail Package: [28 fl. oz., 42 fl. oz., and 128 fl. oz. (one gallon)} CAS# Proprietary Mixture Restrictions on Use Incompatible with strong oxidizing agents, metals (except stainless steel, chrome), acids, bases, and bleach. Manufacturer: Jelmar, LLC Emergency Phone Number: 1(800) 323-5497 (USA) Address: 5550 W. Touhy Ave. Monday – Friday 8:30 A.M. – 4:30 P.M. CST Skokie, IL 60077 Emergency 24 hour Contact: Chemtrec 1(800) 424-9300

2 – HAZARDS IDENTIFICATION Emergency Overview: WARNING: EYE IRRITATANT. GHS Toxicity Category 2A Causes eye irritation

and possible SKIN IRRITATANT GHS Category 3 – on sensitive skin.DO NOT get in eyes, on skin or clothing. DO NOT mix with bleach or other household chemicals as harmful fumes may result. DO NOT ingest. DO NOT breathe vapor or mist. Use in well ventilated areas. Keep container closed when not in use.

KEEP OUT OF REACH OF CHILDREN

Potential Short Term Health Effects Routes of Exposure Eyes, Skin, Inhalation, Ingestion. Eyes Irritant

Avoid eye contact Effects may vary depending on length of exposure, solution concentration

Skin Irritant. Prolonged contact may cause dermatitis, and itching. Inhalation No adverse effects expected under typical use conditions. Ingestion Oral burns, vomiting, and gastrointestinal disturbance. Target organs Eyes. Skin.

SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS Component CAS# OSHA HAZARD % by Weight 1. Lactic Acid 79-33-4 YES 12.00-18.00 2. Gluconic Acid 526-95-4 YES 2.50-3.75 3. Lauramine Oxide 1643-20-5 YES 1.50-3.25




SECTION 4 – FIRST AID MEASURES EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. If irritation persists, get medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse. If irritation persists get medical attention. INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A PHYSCIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest.

SECTION 5 – FIRE FIGHTING MEASURES FLAMMABILTY: Not flammable FLASH POINT: None; Method: ASTM D-56 EXPLOSIVE LIMITS IN AIR: Not available EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Use water spray, dry chemical, alcohol foam or carbon dioxide. FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies. HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to irritating gases and vapors. FIRE AND EXPLOSION HAZARDS: None known.

SECTION 6 – ACCIDENTAL RELEASES MEASURES Steps to be taken in Case Material is Released or Spilled: Avoid contact with skin and eyes Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves. Large Spill: Use personal protection recommended in Section 8. Isolate area, and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters.

SECTION 7- HANDLING AND STORAGE STORAGE: Store in cool, well-ventilated area, away from heat. Keep containers tightly closed. Avoid contact with combustible materials, wood, and organic materials. Store in original container in a secure area away from children and pets. HANDLING: Avoid contact with eyes, skin or clothing. May be harmful or if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hand thoroughly after use. Consumer size containers (28, and 42 fluid ounces and gallon containers), should be rinsed and recycled. DO NOT PRESSURIZE, CUT OR EXPOSE THESE CONTAINERS TO HEAT, FLAME,




SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: None required during normal household use. EYE PROTECTION: Not required during normal household usage. Do not wear contact lenses. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves. OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective clothing and footwear where direct contact with chemicals in this product is possible. WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling. EXPOSURE GUIDELINES: OSHA ACGIH COMPONENT PEL STEL/C TWA STEL/C 1. Lactic Acid N.E N.E. N.E. N.E. 2. Gluconic Acid N.E. N.E. N.E. N.E. 3. Lauramine Oxide N.E. N.E. N.E. N.E.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Boiling point: 99ºC / 210º F Specific Gravity @20ºC: 1.04 – 1.06 Vapor Pressure: N.D. Percent Volatiles: ~77.2% (Calculated) Freezing Point: N.D. Evaporation Rate: N.D. (nBuAc=1) Melting Point: N.D. Total VOC (wt. %): 0% - does not include any Vapor Density (mm Hg): N.D. (Volatile Organic Compounds/ CARB applicable pH: @20ºC 2.10-2.30 California Air Resource Board) exemptions Solubility in Water: 100%

SECTION 10 – STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Avoid elevated temperatures. INCOMPATIBLE MATERIALS: Strong oxidizing agents, metals (except stainless steel and chrome), acids, and bases. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating gases, vapors and carbon oxides. POSSIBILITY OF HAZARDOUS REACTIONS: No data.

SECTION 11 – TOXICOLOGICAL INFORMATION LD50 ACUTE EYE IRRITATION: OPPTS 8740.2400 Toxicity - Irritant; GHS Toxicity Category 2A - Irritant LD50 ACUTE DERMAL IRRATION - RABBITS: OPPTS 870.2500 Toxicity Category IV – Mild or Slight Skin Irritation; GHS Category 3 – Mild Skin Irritation. LD50ACUTE ORAL TOXICITY – RATS: OPPTS 870.1100 Toxicity Category IV >5,000 mg/kg; GHS Category 5 >5,000 mg/kg - Not Toxic




LD50ACUTE DERMAL TOXICITY - RABBITTS: OPPTS 870-1200 Toxicity Category IV >5 g/kg; GHS Category 5 >5,000 mg/kg – Not Toxic LD50 ACUTE INHALATION TOXICITY – RATS: OPPTS 870.1300 Toxicity Category IV - Not toxic by inhalation; GHS Category 5 - Not toxic by inhalation

SECTION 12- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: LACTIC ACID: Persistence / degradability

Readily biodegradable, according to appropriate OECD test. Biochemical oxygen demand (BOD)5 = 0.45 mg O2 /mg Biochemical oxygen demand (BOD)20= 0.60 mg O2/mg Chemical oxygen demand (COD) =0.90 mg O2 /mg

Bioaccumulation None.

Ecotoxicity EC50/48h/Daphnia = 240mg/l LC50/48h/Fish = 320 mg/l EC50/Algae = 3500 mg/l(neutral) No data available.

GLUCONIC ACID: Fish 96-h LC50 > 1000.0 mg/L Daphnid 48-h LC50 > 1000.0 mg/L Green algal 96-h EC50 > 1000.0 mg/L Fish Chronic Value (ChV) > 100.0 mg/L Daphnid ChV > 100.0 mg/L Algal ChV > 100.0 mg/L Biological Fate: No bioconcentration in aquatic organisms and rapid biodegradation/disappearance in the environment, i.e. 40% in 5 days.

LAURAMINE OXIDE: Acute Aquatic Toxicity Reviewed Category ≤1 mg/L Algae IC50 0.01 mg/L Invertebrate EC50 1.01 mg/L Fish LC50 2.6 mg/L Biodegradation: % degraded in 28 days ≥60% ThOD/ThCO2 (≥70% DOC) DOWANOL DPNB: Movement & Partitioning

Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for mobility in soil is very high (Koc between 0 and 50).




Henry’s Law Constant (H): 3.78E-07 atm*m3/mole; 25 °C Estimated. Partition coefficient, n-octanol/water (log Pow): 1.13 Estimated. Partition coefficient, soil organic carbon/water (Koc): 10 - 21 Estimated. Persistence and Degradability Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method

4.97E-11 cm3/s 2.6 h Estimated. OECD Biodegradation Tests: Biodegradation Exposure Time Method 91 % 28 d OECD 301E Test 96 % 28 d OECD 302B Test Theoretical Oxygen Demand: 2.35 mg/mg ECOTOXICITY Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, guppy (Poecilia reticulata), static, 96 h: 841 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, static, 48 h, immobilization: > 1,000 mg/l

CLR CHEMICAL FATE INFORMATION: 28-day biodegradation. The matter is readily biodegradable. OECD 301D

SECTION 13 – DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Rinse empty bottles and recycle. Dispose of unused product in a permitted hazardous waste management facility following all local, state, and federal regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. Follow label warnings, since containers may retain some reside of the product. Processing, use or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations.

SECTION 14 - TRANSPORTATION INFORMATION DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT. Identification Number: N.A. Packaging Group: N.A.




UN Number: N.A. TDG Classification: Not Regulated IMDG Classification: Not Regulated IATA Classification: Passenger – Not Regulated WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR.

SECTION 15 – REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventory requirements. SARA TITTLE III SECTION 311/312 CATEGORY: IMMEDIATE (ACUTE) HEALTH HAZARARD: YES DELAYED (CHRONIC) HEALTH HAZARD: NO FIRE HAZARD: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE HAZARD: NO SARA SECTIONS 302/304/313/HAP: NO INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES AUSTRALIA (ACIS) YES KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL) NO PHILIPPINES YES STATES RIGHT TO KNOW: California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and Wisconsin. Complies with listed States Right to Know Act. The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm.

SECTION 16 – OTHER INFORMATION Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent from freezing. Other Precautions: None required. MSDS ABBREVIATIONS: N. A.: Not Applicable HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound N. D.: Not Determined N.E.: Not Established




C: Ceiling Limit HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound Revision: New Formula, GHS Format October 2012 R. A. Gaudreault Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR be responsible for damages of any nature whatsoever resulting from use of or reliance upon said information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS.

KIK

CUSTOM PRODUCTS Page 1 of 2


Section 1. Chemical Product and Company Identification

Product Name/Trade Name Glass Cleaner

Ref# 40000263

Manufacturer: KIK CUSTOM PRODUCTS

2921 Corder Street

Houston, TX USA 77054

Contact Number:

24 Hour Emergency Contact:

Prepared By:

Date Last Revised:

Replaces Date:

Tel: 905-660-0444

Tel: 1-800-255-3924

KIK CUSTOM PRODUCTS

October 7, 2014

October 18, 2011

Section 2. Hazardous Ingredients Name % CAS# LD50/LC50

Aqua Ammonia ≤1.0 7664-41-7 43 mg/kg (oral) /30,000 ppm (1hr)

Section 3. Physical Data

State Liquid pH 10.5 – 12.5

Appearance Blue % Volatile 99.9 %

Odour Ammonia Boiling Point N Av.

Specific Gravity 1.000-1.010 Vapour Pressure N Av.

Solubility 100% in water Freezing Point Approx. 0°C

Section 4. Fire & Explosion

Flammable: YES NO X

Means of Extinction: As per surrounding fire

Special Procedures: As per surrounding fire.

Flash Point: & Method: > 200°F TCC

Hazardous Combustion Products: N. Av.

Section 5. Reactivity Data

Chemical Stability: YES X NO

Conditions: N App.

Incompatibility: YES NO X

What Substances:

Reactivity / Conditions: None reactive

Hazardous Decomposition Products: N Av.

KIK

CUSTOM PRODUCTS Page 2 of 2

Section 6. Toxicological Properties Route of Entry

Skin Contact X Skin Absorption Eye Contact X

Inhalation Acute X Inhalation Chronic Ingestion X

Effects of Acute Exposure: Inhalation of vapours will irritate breathing passages. Contact with eyes may

cause mild irritation. Ingestion may cause very mild sensation in mouth, throat and stomach.

Effects of chronic exposure: Prolonged and repeated exposure to skin will cause irritation, drying and

dermatitis

Carcinogenicity, Reproductive Effects, Teratogenicity, Mutagenicity: No known effects

Section 7. Preventative Measures

Protective Equipment

Gloves: Recommended for prolonged exposure. Eyes: Not normally required

Respiratory: Not normally required. Footwear: Not Applicable

Leak & Spill Procedure: Rinse with water mop up dispose of in accordance with local,

state/provincial and federal regulations

Section 8. First Aid Measures

Skin: Wash with soap and water

Eyes: Flush eyes with cool running water holding eyelids apart to ensure thorough rinsing for 15 minutes.

Remove contact lenses.

Inhalation: Move to fresh air and restore breathing, if required.

Ingestion: DO NOT INDUCE VOMITING! Drink large amounts of water. Do not give anything by mouth

to a convulsing or unconscious person. See a doctor immediately.

General Advice: If irritation occurs, see a doctor immediately.

Section 9. Regulatory Information

TRANSPORTATION: Not Restricted

WHIMIS Controlled Product: No

Health 1

Flammability 0

Reactivity 0

As the handling and use of products under user's conditions are beyond our control, no warranty, expressed or implied, is made concerning this product. The information contained herein is offered only as a guide to the handling of this specific material and is not intended to be all-inclusive in the manner and conditions of use and handling. The user assumes all risks of use or handling, whether or not in accordance with any directions or suggestions of the manufacturer. Manufacturer shall not be liable to purchaser or any other person for loss or damages directly or indirectly arising from the use of our product.

KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1

SECTION I-MATERIAL IDENTIFICATION AND USE

Material Name/Identifier: Silicone Gasket Maker (Clear) Stock No. 472

Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.

City: Brampton Province: Ontario

Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)

Chemical Name: N. Ap (mixture) Chemical Family: Silicone rubber sealant

Chemical Formula: N. Ap (mixture) Trade Names & Synonyms: None

Material Use: Sealer Molecular Weight: N/Ap.

SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL

Hazardous Approximate LD50 LC50

Ingredients C.A.S. Concentration Species & Route Species & Route

Amorphous silica 7631-86-9 7 - 13 % 3160 mg/kg rat-oral >0.139mg/L(4hr) rat-inhal

Methyltriacetoxysilane 4253-34-3 1 - 5% 1600 mg/kg rat-oral N/Av.

Ethyl Triacetoxysilane 17689-77-9 1 - 5 % 1460mg/kg rat-oral N/Av.

Octamethylcyclotetrasiloxane 556-67-2 0.1 - 1% 1540mg/kg rat-oral 36mg/L(4hr) rat - inhal

SECTION III-PHYSICAL DATA FOR MATERIAL

Physical State: Paste Odour/Appearance: Acetic acid odour/ thixotropic sealant

Specific Gravity: 1.01 Odour Threshold(p.p.m.): N/Av.

Boiling Point: N/Av. Evaporation Rate: N/Av.

Freezing Point: N/Av. Solubility in Water: insoluble

% Volatile(by volume): N/Av. Vapour Pressure(mm)Hg: N/Av.

Vapour Density(Air=1): N/Av. Coefficient of Water/Oil Distribut: N/Av.

pH N/Ap.

SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL

Flammability Yes/No No If yes under which conditions?: N.Ap.

Auto Ignition Temperature: N/Av. Means of Extinction: Dry chemical, foam, waterspray, carbon dioxide

carbon dioxide, carbon monoxide, formaldehyde

Upper Flammable limit (%vol) None Lower Flammable Limit(% by volume): None

Explosion Data: Sensitivity to Mech. Impact: N. Ap Sensitivity to Static Discharge: N.Ap.

SECTION V-REACTIVITY DATA

Chemical Stability Yes/No: Yes If NO under which conditions? N.Ap.

Incompatibility to Other Substances Yes/No: yes If so which ones? : Strong oxidizers or electrophiles

(e.g Ferric chloride) strong Acid and Base

Reactivity and under what conditions? Heat, open flames, fire. Moisture and incompatible material

Hazardous Decomposition Products: Carbon oxides, Carbon monoxide, formaldehyde, silicon dioxide, metal oxide.

N/E: not established N.Ap.: not applicable N/Av.: not available

Material Name/Identifier: Silicone Gasket Maker (Clear) Stock No. 472 PAGE 2

SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT

Route of Entry: ALL Routes --SKIN CONTACT --SKIN ABSORPTION --EYE CONTACT --INHALATION --INGESTION

Effects of Acute Exposure: Uncured product contact will irritate skin, lips, gums and tongue. May cause mild respiratory irritation.

Effects of Chronic Exposure: No known chronic health effects, but should avoid unnecessary exposure to product

LD 50 of Product: N/Av. LC 50 of Product: N/Av.

Irritancy of Product: Skin, eye irritant Exposure Limits of Product: N/Av.

Sensitization of Product: Allergic skin sensitization possible through repeated direct contact with the ketoxime in uncured product.

--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY None known

SECTION VII-PREVENTIVE MEASURES

Personal Protective Equipment to be used:

Gloves(specify): Nitril, neoprene, Eye(specify): Safety glasses

Respiratory(specify): Mask with filter for free acidic vapour Clothing: Not required

Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved cartridge type respirator is recommended

Engineering Controls: Local and mechanical ventilation required.

Leak and Spill Procedure: Wipe, scrape or soak up in an inert mateiral and put in a container for disposal

Surface may become slippery, cleaning may required steam, solvent or detergent.

Waste Disposal: Standard methods approved in your region.

Storage Requirements: Store at room temperature between 10 and 25ºC. keep in well ventilated area. Keep lid closed when not in use.

Handling Procedures and Acetic acid is released during application and curing. Provide adequate ventilation to control

Equipment: exposures within guidelines of OSHA.

TDG Classification: non-regulated.

WHMIS Classification: Consumer commodity/ CCCR label Complies with CCCR 2001

SECTION VIII-FIRST AID MEASURES

Eye: Rinse thoroughly with water for 10-15 minutes. Consult a physician immediately.

Skin: Remove contaminated clothing. Wash with soap and water. Consult doctor if irritation, rashes persist.

Inhalation: Move patient to fresh air and restore breathing if requiredseek medical help if discomfort persist.

Ingestion: DO NOT INDUCE VOMITING. Call a physician immediately.

SECTION IX-PREPARATION DATE OF M.S.D.S.

Additional Info/Comments: Sources Used: Supplier's data

Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory

Date Prepared: January 2, 2015 Kleen-Flo Tumbler Industries Limited

THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED

N/Av.: not available N/Ap.: not applicable N/E: not established



Material Name/Identifier: ACE-Start Starting Fluid Stock No. 735




Chemical Name: N.Ap. (Mixture) Chemical Family: N/Av. (Mixture)

Chemical Formula: N.Ap. (Mixture) Trade Names & Synonyms: Kleen-Start

Material Use: Engine Starting Fluid Molecular Weight: N/Av. (Mixture)



Ingredients C.A.S. % Concentration Species & Route Species & Route

Diethyl ether 60-29-7 40-70 1215mg/kg rat-oral 73000 ppm(150 min.) rat-inhal.

Heptane 142-82-5 30-60 4420-5840mg/kg rat-oral 14000 ppm (4 hr) rat-inhl.

Carbon dioxide 124-38-9 5-10 N/Ap. N/Av.


Physical State: Aerosol Odour/Appearance: ether-like odour/ colorless liquid


Boiling Point: 35.5ºC Evaporation Rate: >1 (Butyl-acetate=1)

Freezing Point: N/E Solubility in Water: Negligible

% Volatile(by volume): 100 Vapour Pressure, psig 80 -90

Vapour Density(Air=1): >1 Coefficient of Water/Oil Distribut: N/Av.

pH N/Ap.


Flammability Yes/No: Yes, extremely If yes under which conditions?: Excessive heat, open flame or sparksAuto Ignition Temperature: N/Av. Means of Extinction: carbon dioxide, dry chemical, foam

Flashpoint and Method: -45ºC Hazardous Combustion Products: Hydrocarbon fumes, smoke,

Carbon dioxide, carbon monoxide.

Flame Extension: >45 cm but <100 cm Flashback yes.

Upper Flammable limit (%vol) 36 Lower Flammable Limit(% by volume): 1

Explosion Data: Sensitivity to Mechanical Impact: N.Ap Sensitivity to Static Discharge: N.Ap.


Chemical Stability Yes/No: No If NO under which conditions? above 35.5ºC

Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents, Nitric acid

Reactivity and under what conditions? N/Av. Sulfuric acid, Amines.

Hazardous Decomposition Products: Carbon monoxide & carbon dioxides.


Material Name/Identifier: ACE-Start Starting Fluid Stock No. 735 PAGE 2



Effects of Acute Exposure: May cause defatting and drying of skin and eye irritation. May irritate mucous membranes of respiratory tract.

Overexposure may cause central nervous system depression. Headache or nausea.

Effects of Chronic Exposure: Continuous inhalation of spray may harmful or fatal.


Irritancy of Product: Skin & Eye Irritant Exposure Limits of Product: N/Av.

Sensitization of Product: N/Av. Toxicologically Synergistic Materials: N/Av.

--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY

Diethyl ether has caused birth defects and toxicity to the fetus in animal tests.



Gloves(specify): Solvent resistant gloves Eye(specify): Safety Glasses

Respiratory(specify): NOISH approved organic vapor mask Clothing: Not required

Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved respirator is recommended

Engineering Controls: Local or mechanical ventilation required to keep exposure limit below 400 ppm (diethyl ether).Leak and Spill Procedure: Absorb with inert non reactive absorbant. Use non sparking tool. Remove all ignition sources.

Waste Disposal: Do not puncture or incinerate, even when can is empty. Dispose as per local, provincial regulation.

Storage Requirements: Store in cool, well ventilayed area at room temperature. Do not expose under direct sunlight for prolonged period.

Handling Procedure & Keep away from open flame and spark excessive heat. Do not store above 30ºC for a long period of time.

Equipment: Keep away from reach of children. Do not inhale or ingest.

NFPA30B/CNFC3.3.5 Level 3

IATA (air transport) Prohibited. (Passanger Aircraft)

Marine (IMDG) Limited Quantity, Aerosol, UN1950, Class 2.1

DSL listing: All components are listed in the inventory.

TDG Classification: Consumer Commodity

WHMIS Classification: Consumer Commodity - exempt from WHMIS labeling requirement. Complies with CCCR 2001


Eye: Flush with plenty of water for at least 15 minutes. If irritation persists, seek medical help immediately.

Skin: Remove contaminated clothing. Wash with soap and water. If rash, irritation persists contact a physician.

Inhalation: Move patient to fresh air and restore breathing if required. If discomfort persist see a doctor.

Ingestion: DO NOT INDUCE VOMITING. Seek medical help immedaitely.




Date Prepared: Janaury 2, 2015. Kleen-Flo Tumbler Industries Limited





Material Name/Identifier: Brake & Parts Kleen(Non Chlorinated) Stock No. 313




Chemical Name: N.Ap. Chemical Family: N/Ap. ( mixture)

Chemical Formula: N.Ap. ( mixture) Trade Names & Synonyms: none

Material Use: Cleaner Molecular Weight: N.Ap. ( mixture)



Ingredients C.A.S. Conc. %wt. Species & Route Species & Route

Heptane 142-82-5 60-100 >15000 mg/kg rat-oral 103g/m3 (4hr) rat-inhal

Isopropyl alcohol 67-63-0 10 -30 >4720 mg/kg rat-oral 12000 ppm rat- (8 hr) inhl.

Carbon dioxide 124-38-9 3 -7 N/Ap N/Av.


Physical State: aerosol Odour/Appearance: Solvent-like, clear, colorless

Specific Gravity: 0.7 Odour Threshold(p.p.m.): N/E

Boiling Point: (on conc.) 80 -100 °C Evaporation Rate: > 1 (water=1)

Freezing Point: N/Av. Solubility in Water: partial soluble

% Volatile(by volume): 100% Vapour Pressure(mm)Hg: N/E

Vapour Density(Air=1): >1 Coefficient of Water/Oil Distribut: N/E

pH N.Ap.


Flammability Yes/No Yes, Highly flammable If yes under which conditions?: Open flame, Spark, Excessive heat

Auto Ignition Temperature: 204-399 °C Means of Extinction: Water fog, Dry Chemical, Foam

Flashpoint (Concentrate): Lowest known Heptane -7 ºC, T.C.C. Hazardous Combustion Products: hydrocarbon fumes and

Flame extension >45 cm smoke, carbon monoxide where combustio stion is incomplete.

Upper Flammable limit (%vol) 12 Lower Flammable Limit(% by volume): 1.2

Explosion Data: Sensitivity to Mechanical Impact: N.Av. Sensitivity to Static Discharge: N/E


Chemical Stability Yes/No: Yes If NO under which conditions? N.Ap.

Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents

Reactivity and under what conditions? Excessive heat, open flame, spark

Hazardous Decomposition Products: Hydrocarbon fumes and smoke, carbon monoxide where combustion is incomplete


Material Name/Identifier: Brake & Parts Kleen(Non Chlorinated) Stock No. 313 PAGE 2



Effects of Acute Exposure: May cause Dizziness, nausea, vomiting, weekness, eye and skin irritation.

Effects of Chronic Exposure: Solvents may cause defatting dermatitis.

LD 50 of Product: N/E LC 50 of Product: N/E

Irritancy of Product: Skin and eye irritant Exposure Limits of Product: N/E

Sensitization of Product: N/E Toxicologically Synergistic Materials: N/E

--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY none known



Gloves(specify): Nitrile, vinyl or chemical resistant gloves Eye(specify): Wear eye/face protection

Respiratory(specify): Wear cartridge type respirator Clothing: Not required

Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved cartridge type respirator is recommended

Engineering Controls: Use adequate ventilation.

Leak and Spill Procedure: Use inert absorbent material, non sparking tools to contain spills. Ventilate area.

Prevent from entering sewage or waterways.


Storage Requirements: Store in a cool, well ventilated area where temperature not to exceed 50ºC

Handling Procedures and Use with adequate ventilation. Contents under pressure. Keep away from heat, sparks, flame and other

Equipment: sources of ignition. Keep away from children. Do not inhale or ingest.

DSL All ingredients are in the Domestic substance listing.

NFPA 30B/CNFC 3.3.5 Level 3


WHMIS Classification: A, B5, D2-B


Eye: Flush immediately with fresh water for at least 15 minutes. See a doctor immediately.

Skin: Wash with soap and water, consult a doctor if irritation or rashes persist.

Inhalation: Move patient to fresh air and restore breathing if required. Call a physician if discomfort persist.

Ingestion: DO NOT INDUCE VOMITING. Get medical attention immediately.


Additional Info/Comments: Source used: Supplier's data


Date Prepared: January 2, 2015 Kleen-Flo Tumbler Industries Limited


N/Av.: not available N/Ap: not applicable N/E: not established



Material Name/Identifier: Kleen-Start Starting Fluid Stock No. 730




Chemical Name: N.Ap. (Mixture) Chemical Family: N/Av. (Mixture)

Chemical Formula: N.Ap. (Mixture) Trade Names & Synonyms: Kleen-Start

Material Use: Engine Starting Fluid Molecular Weight: N/Av. (Mixture)



Ingredients C.A.S. % Concentration Species & Route Species & Route

Diethyl ether 60-29-7 40-70 1215mg/kg rat-oral 73000 ppm(150 min.) rat-inhal.

Heptane 142-82-5 30-60 4420-5840mg/kg rat-oral 14000 ppm (4 hr) rat-inhl.

Carbon dioxide 124-38-9 5-10 N/Ap. N/Av.


Physical State: Aerosol Odour/Appearance: ether-like odour/ colorless liquid


Boiling Point: 35.5ºC Evaporation Rate: >1 (Butyl-acetate=1)

Freezing Point: N/E Solubility in Water: Negligible

% Volatile(by volume): 100 Vapour Pressure, psig 80 -90

Vapour Density(Air=1): >1 Coefficient of Water/Oil Distribut: N/Av.

pH N/Ap.


Flammability Yes/No: Yes, extremely If yes under which conditions?: Excessive heat, open flame or sparksAuto Ignition Temperature: N/Av. Means of Extinction: carbon dioxide, dry chemical, foam

Flashpoint and Method: -45ºC Hazardous Combustion Products: Hydrocarbon fumes, smoke,

Carbon dioxide, carbon monoxide.

Flame Extension: >45 cm but <100 cm Flashback yes.

Upper Flammable limit (%vol) 36 Lower Flammable Limit(% by volume): 1

Explosion Data: Sensitivity to Mechanical Impact: N.Ap Sensitivity to Static Discharge: N.Ap.


Chemical Stability Yes/No: No If NO under which conditions? above 35.5ºC

Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents, Nitric acid

Reactivity and under what conditions? N/Av. Sulfuric acid, Amines.

Hazardous Decomposition Products: Carbon monoxide & carbon dioxides.


Material Name/Identifier: Kleen-Start Starting Fluid Stock No. 730 PAGE 2



Effects of Acute Exposure: May cause defatting and drying of skin and eye irritation. May irritate mucous membranes of respiratory tract.

Overexposure may cause central nervous system depression. Headache or nausea.

Effects of Chronic Exposure: Continuous inhalation of spray may harmful or fatal.


Irritancy of Product: Skin & Eye Irritant Exposure Limits of Product: N/Av.

Sensitization of Product: N/Av. Toxicologically Synergistic Materials: N/Av.

--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY

Diethyl ether has caused birth defects and toxicity to the fetus in animal tests.



Gloves(specify): Solvent resistant gloves Eye(specify): Safety Glasses

Respiratory(specify): NOISH approved organic vapor mask Clothing: Not required

Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved respirator is recommended

Engineering Controls: Local or mechanical ventilation required to keep exposure limit below 400 ppm (diethyl ether).Leak and Spill Procedure: Absorb with inert non reactive absorbant. Use non sparking tool. Remove all ignition sources.


Storage Requirements: Store in cool, well ventilayed area at room temperature. Do not expose under direct sunlight for prolonged period.

Handling Procedure & Keep away from open flame and spark excessive heat. Do not store above 30ºC for a long period of time.

Equipment: Keep away from reach of children. Do not inhale or ingest.

NFPA30B/CNFC3.3.5 Level 3

IATA (air transport) Prohibited. (Passanger Aircraft)

Marine (IMDG) Limited Quantity, Aerosol, UN1950, Class 2.1

DSL listing: All components are listed in the inventory.


WHMIS Classification: Consumer Commodity - exempt from WHMIS labeling requirement. Complies with CCCR 2001


Eye: Flush with plenty of water for at least 15 minutes. If irritation persists, seek medical help immediately.

Skin: Remove contaminated clothing. Wash with soap and water. If rash, irritation persists contact a physician.

Inhalation: Move patient to fresh air and restore breathing if required. If discomfort persist see a doctor.

Ingestion: DO NOT INDUCE VOMITING. Seek medical help immedaitely.




Date Prepared: Janaury 2, 2015. Kleen-Flo Tumbler Industries Limited



Material Safety Data Sheet_______________________________________________

Revision Date 01-May-2013

1. CHEMICAL PRODUCT AND COMPANYINFORMATION

Product code 92964

Product name Moly Coat

Recommended Use Lubricant

Supplier Lawson Products, Inc.8770 W.Bryn Mawr Ave.- Suite 900Chicago, IL 606311-866-529-7664

Emergency telephone number (888) 426-4851


Aggravated Medical ConditionsNone Known

Principal Routes of ExposureEyes. Skin contact. Inhalation. Ingestion.


Eyes May cause the following effects:. Irritation. Pain.Tearing. Reddening. Swelling. Stinging sensation.Feeling like that of fine dust in the eye.

Skin Repeated or prolonged exposure may cause:. SkinIrritation. Defatting. Dermatitis. Chronic exposurecauses drying effect on the skin .

Inhalation Harmful by inhalation. Avoid breathing vapors ormists. Repeated or prolonged exposure may causethe following effects:. Headaches. Dizziness.Nausea. Decreased blood pressure. Changes inheart rate. Cyanosis. Central nervous systemdamage. Lung damage. Kidney damage. Liverdamage.

Ingestion No hazard under normal industrial and institutionaluse. Harmful or fatal if swallowed. Can burn mouth,throat, and stomach.


Chemical Name CAS-No Weight %

Propane/Isobutane/N-Butane

68476-86-8 40-50

2-Propanone 67-64-1 20-30

Dimethylbenzene 1330-20-7 10-20

Isopropyl Alcohol 67-63-0 1-10

Ethylbenzene 100-41-4 1-10

Molybdenum sulfide 1317-33-5 1-10


Eye contact Flush eyes immediately with large amounts ofwater. Seek medical attention if irritation persists.

Skin contact Wash off immediately with soap and plenty ofwater. Seek medical attention if irritation persists.

Ingestion Seek medical attention immediately. Do not inducevomiting. Give victim a glass of water or milk.Contact physician or poison control centerimmediately. Do not give anything by mouth to anunconscious person.

Inhalation Move to fresh air. If not breathing, give artificialrespiration. If breathing is difficult, give oxygen.Immediate medical attention is required.


Flash point °C -96.11

Flash point °F -141

Method Pensky-Martens C.C.

Autoignition temperature °C No data available

Autoignition temperature °F No data available

Flammability Limits (% in Air)Upper 12.8

Lower 0.8

Specific Information for Aerosol Products

Flame extension Unknown

Flashback Unknown

Suitable extinguishing mediaAlcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Waterfog.

Special protective equipment for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand,MSHA/NIOSH (approved or equivalent) and full protective gear.

Fire and Explosion HazardsContainers may vent or burst under extreme or prolonged fire conditions.Vapors are heavier than air and may travel along the ground to an ignitionsource distant from material handling area. Possible ignition sourcesinclude pilot lights, flames, lighted cigarettes, heating elements, electricmotors, sparks from electrical switches. Empty containers contain residueand/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, orexpose such containers to heat, sparks, flame, static electricity, or othersources of ignition. They may explode and cause injury or death.

Sensitivity to shockNo information available.

_______________________________________________

Page 1 / 4

Emergency OverviewVapors may be irritating to eyes, nose, throat, and lungs. Vapors may

cause flash fire or explosion.

_______________________________________________

Sensitivity to static dischargeNo information available.


Methods for cleaning upSoak up with noncombustible inert absorbent material. Place in suitablecontainer for disposal as hazardous waste.


HandlingThoroughly wash hands and exposed skin after handling. Wash handswith soap and water before eating, drinking, smoking, or using toiletfacilities. Control airborne concentration below exposure level. Use onlyaccording to label directions. Handle empty containers as if they were full.Avoid breathing vapors. Do not get on skin or in eyes.

StorageKeep away from heat. Keep away from open flames, hot surfaces andsources of ignition. Do not freeze.

NFPA Storage CodeStore as Level 3 Aerosol (NFPA 30B)

8. EXPOSURE CONTROLS / PERSONALPROTECTION

ChemicalName

OSHA PEL(TWA)

OSHA PEL(Ceiling)

ACGIH OEL(TWA)

ACGIH OEL(STEL)


- - - -

2-Propanone 1000 ppm2400 mg/m3

- 500 ppm 750 ppm

Dimethylbenzene

100 ppm435 mg/m3

- 100 ppm 150 ppm

IsopropylAlcohol

400 ppm980 mg/m3

- 200 ppm 400 ppm

Ethylbenzene 100 ppm435 mg/m3

- 20 ppm -

Molybdenumsulfide

- - - -

Ventilation and Environmental ControlsUse enough ventilation, local exhaust at the work area, general, or both,to keep below the TLV's in the worker's breathing zone and the generalarea.

Hygiene measuresHandle in accordance with good industrial hygiene and safety practice.

Other precautionsAvoid contact with skin, eyes and clothing.

Respiratory protectionIf the exposure limits are exceeded, a NIOSH/MSHA approved respiratoris recommended. Protection provided by air purifying respirators islimited. Use a positive pressure supplied air respirator. if there is anypotential for an uncontrolled release:. where exposure levels are notknown. or other circumstances where an air purifying respirator (P100)may not provide adequate protection . Seek professional advise prior torespirator selection and use.

Hand ProtectionChemical resistant gloves. Consult glove manufacturer to determine theproper type for a specific operation.

Eye protectionWear safety glasses with side shields.

Skin and body protectionWear appropriate clothing to minimize skin contact.


Form Aerosol

Color Black - Green

Odor Solvent

Odor Threshold No information available

pH Not Applicable

Specific Gravity 0.6752

Vapor pressure No data available

Vapor density heavier than air

Evaporation Rate Is faster than Butyl Acetate

Water solubility Negligible

VOC Content 68.6%; 369 gm/liter; 3.08 lbs/gal

Partition Coefficient (n-octanol/water)

No data available

Boiling point/range °C -30.6 - 175

Boiling point/range °F -23 - 284

Melting point/range °C No data available

Melting point/range °F No data available

Flash point °C -96.11

Flash point °F -141


StabilityStable under normal conditions.

Conditions to avoidContact with ignition sources, hot-glowing surfaces, electrical arcs,sparks, and open flame. Do not use near welding arcs.

IncompatabilityStrong acids. Alkalies. Oxidizers.

_______________________________________________

Page 2 / 4

Product code 92964 Product name Moly Coat

_______________________________________________

Hazardous Decomposition ProductsCarbon oxides.

PolymerizationWill not occur.


Component Information

Chemical Name LD50(oral,rat

)

LD50(dermal,rat/rab

bit)

LC50 (inhalation,rat)

Propane/Isobutane/N-Butane68476-86-8

- - -

2-Propanone67-64-1

5800mg/kg

- -

Dimethylbenzene1330-20-7

4300mg/kg

1700mg/kg

47635 mg/L5000 ppm

Isopropyl Alcohol67-63-0

4396mg/kg

12800mg/kg12870mg/kg

72.6 mg/L

Ethylbenzene100-41-4

3500mg/kg

15354mg/kg

17.2 mg/L

Molybdenumsulfide1317-33-5

- - 2820 mg/m3

Synergistic Products None known


Sensitization None known

Chronic toxicity Possible risks of irreversible effects .Prolonged exposure may causechronic effects .

Mutagenic effects None known

Teratogenic effects None known

Reproductive toxicity None known

Target Organ Effects Long term exposure to vapor maycause lung damage. Long termexposure to vapor may cause kidneydamage. Central nervous system.

Carcinogenic effects See table below

ChemicalName

ACGIHOEL -

Carcinogens

IARC NTP -Known

Carcinogens

NTP -Suspected

HumanCarcinoge

ns

OSHARTK

Carcinogens


Not Listed Not Listed Not Listed Not Listed Not Listed

2-Propanone A4 Not Listed Not Listed Not Listed Not Listed

Dimethylbenzene

A4 Not Listed Not Listed Not Listed Not Listed

IsopropylAlcohol

A4 Not Listed Not Listed Not Listed Not Listed

Ethylbenzene A3 Group 2B Not Listed Not Listed Listed

Molybdenumsulfide

Not Listed Not Listed Not Listed Not Listed Not Listed



Disposal InformationDispose in accordance with federal, state, and local regulations.

14. TRANSPORTATION INFORMATION

DOTConsumer commodity, ORM-D

TDGConsumer commodity, ORM-D


Chemical Name US EPA SARA 313 Emission Reporting

Dimethylbenzene Listed

Isopropyl Alcohol Listed

Ethylbenzene Listed

State Regulations

_______________________________________________

Page 3 / 4

Microtox DataPhotobacterium phosphoreum EC50=9.68 mg/L (30 min)Nitrosomonas EC50=96 mg/L (24 h)

Product name Moly Coat

Water Flea DataDaphnia magna EC501.8 - 2.4 mg/L (48 h)

Microtox DataPhotobacterium phosphoreum EC50=0.0084 mg/L (24 h)

Microtox DataPhotobacterium phosphoreum EC50=14500 mg/L (15 min)

Water Flea Datawater flea hEC50 48 (3.82 mg/L)Gammarus lacustris hLC50 48 (0.6 mg/L)water flea hEC50 48 (3.82 mg/L)

Isopropyl Alcohol

Product code 92964

Microtox DataPhotobacterium phosphoreum EC50=35390 mg/L (5 min)

Water Flea DataDaphnia magna EC5010294 - 17704 mg/L (48 h)Daphnia magna EC5012600 - 12700 mg/L (48 h)

Water Flea DataDaphnia magna EC50=13299 mg/L (48 h)

2-Propanone

Ethylbenzene

Dimethylbenzene

_______________________________________________

Chemical Name New Jersey -RTK

Pennsylvania- RTK

CaliforniaProp. 65


Not Listed Not Listed Not Listed

2-Propanone Not Listed Listed Not Listed

Dimethylbenzene Not Listed Listed Not Listed

Isopropyl Alcohol Not Listed Listed Not Listed

Ethylbenzene Not Listed Listed Carcinogen

Molybdenum sulfide Not Listed Not Listed Not Listed

WARNING: This product contains a chemical(s) known to the state ofCalifornia to cause cancer and birth defects or other reproductive harm

International Inventories

Chemical Name EINECS DSL NDSL TSCA


X X - X

2-Propanone X X - X

Dimethylbenzene X X - X

Isopropyl Alcohol X X - X

Ethylbenzene X X - X

Molybdenum sulfide X X - X

CPRThis product has been classified in accordance with the hazard criteria ofthe Controlled Product Regulations and the MSDS contains all of theinformation required by the Controlled Product Regulations.


HMIS

Health - 2Flammability - 4Physical Hazard - 0

Prepared By V. Shargorodsky, Regulatory AffairsEngineer

The information accumulated herein is believed to be accurate, but is notwarranted to be, whether originating with the company or not. Recipientsare advised to confirm in advance of need that the information is current,applicable, and suitable to their circumstances.

_______________________________________________

Page 4 / 4

Product code 92964 Product name Moly Coat

MSD Consumer Care, Inc.3535 Trans-CanadaPointe Claire, QuebecCanada H9R 1B4


MSD Consumer Care, Inc. urges each user or recipient of this MSDS to read the entire data sheet to become aware of the hazards associated with thismaterial.

SECTION 1. IDENTIFICATION OF SUBSTANCE AND CONTACT INFORMATION

MSDS NAME: Muskol Aerosol, 23.5% DEET

SYNONYM(S): Muskol Insect Repellent Aerosol

MSDS NUMBER: SP001588

EMERGENCY NUMBER(S): (908) 423-6000 (24/7/36) English Only

Transportation Emergencies - CANUTEC: (613) 996-6666 (Canada)

INFORMATION: Merck Consumer Care Products CanadaCustomer Service (English): 1-800-361-6550Service à la clientèle (French): 1-800-361-2431

MERCK MSDS HELPLINE: (908) 473-3371 (Worldwide)Monday to Friday, 9am to 5pm (US Eastern Time)

SECTION 2. HAZARDS IDENTIFICATION

Consumers: Refer to the package insert or product label for appropriate consumer-specific information about this product when used according tomanufacturer's directions.


The following summary is based upon available information about the individual ingredients of the mixture, or of the expected properties of the mixture.

May be harmful to fish and aquatic organisms.

Alcohol odor

Aerosol

Flammable.

EMERGENCY OVERVIEW

May be severely irritating to the eyes.May be harmful by inhalation.Absorbed through the skin.Harmful if swallowed or absorbed through the skin in large amounts.

May cause effects to:nervous systemcardiovascular systemliverkidney

Clear, Light yellow

DEET is a common insect repellent which is applied directly to the skin. DEET may cause stinging and slight to moderate eye and mucous membraneirritation. DEET may cause contact dermatitis or excerbation of pre-existing skin disease in sensitive individuals. DEET is efficiently absorbed from theskin or gut. If large amounts of DEET are inhaled, ingested, or applied dermally (especially areas of skin that are occluded), the potential for severetoxicity exists. However, compared to the widespread use of the product, there are relatively few cases of toxicity. Reported acute or chronic effectsfrom overexposure to DEET were restlessness, drowsiness, irritability, weakness, headaches, incoordination, slurred speech, confusion, insomnia,tremor, flexing or extending of extremities, decreases in blood pressure, decreased heartbeat, skin effects (rashes, bullous eruptions and necrosis),pyschosis, seizures, prolonged disability, coma, or anaphylactic reaction. Death has been reported when large amounts of DEET were ingested.

Ethanol (ethyl alcohol) is an eye, nose, and mucous membrane irritant. It may cause skin irritation or sensitization after prolonged exposure. Acuteeffects of ethanol may include headache, dizziness, nausea, sensations of warmth and cold, numbness, fatigue, breathing difficulty, cough, tearing,vision impairment, incoordination, decreased reaction time, alteration of mood and personality, slurred speech, coma and respiratory depression.Chronic effects may include concentration difficulty, sleepiness, kidney and liver damage, and cardiac effects. Chronic ingestion of ethanol may causecancer of the oral cavity, pharynx, larynx, esophagus, and liver. Oral ingestion of alcohol during pregnancy may cause Fetal Alcohol Syndrome (FAS)including joint, limb, and cardiac abnormalities and behavioral and learning impairment. There have been no reports of FAS as a result of occupationalhandling of ethanol.

Isobutane and propane are simple asphixiant gases (displaces oxygen from the breathing atmosphere), anesthetics, and central nervous systemdepressants. Inhalation exposure to high concentrations may cause fatigue, vomiting, nausea dizziness, decreased vision, mood disturbances,numbness of extremities (e.g. fingers), headache, confusion, decreased coordination and judgment, breathing difficulties, irregular heartbeat, cyanosis,convulsions, or coma. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Direct contact with liquefiedisobutane or propane may cause frostbite or burns to the eyes or following prolonged skin contact.

LISTED CARCINOGENS

INGREDIENT CAS NUMBER OSHA IARC NTP ACGIH

Ethyl Alcohol 64-17-5 K A3

Ethanol (ethyl alcohol): IARC (International Agency for Research on Cancer) has classified Alcoholic Beverages as Group 1 (indicating in theirevaluation that the agent is carcinogenic to humans). However, occupational handling or manufacturer's specified use of this product is not expected toresult in relevant exposures. K (NTP): NTP - Known Human Carcinogen A3 (ACGIH): ACGIH A3 - Confirmed Animal Carcinogen with UnknownRelevance to Humans

SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS

PRODUCT USE: Consumer product

CHEMICAL FORMULA: Mixture.

The formulation for this product is proprietary information. Only hazardous ingredients in concentrations of 1% or greater and/or carcinogenic ingredientsin concentrations of 0.1% or greater are listed in the Chemical Composition table. Active ingredients in any concentration are listed.

CHEMICAL COMPOSITION

INGREDIENT CAS NUMBER PERCENT

Isobutane 75-28-5 1-5

Ethyl Alcohol 64-17-5 30-60

Diethyltoluamide (DEET) 134-62-3 23.5

Propane 74-98-6 10-30

ADDITIONAL INFORMATION: This MSDS is written to provide health and safety information for individuals who will be handling the finalproduct formulation during research, manufacturing, and distribution. For health and safety information forindividual ingredients used during manufacturing, refer to the appropriate MSDS for each ingredient. Referto the package insert or product label for handling guidance for the consumer.

SECTION 4. FIRST AID MEASURES

INHALATION: Remove to fresh air. If any trouble breathing, get immediate medical attention. Administer artificialrespiration if breathing has ceased. If irritation or symptoms occur or persist, consult a physician.

SKIN CONTACT: In case of skin contact, while wearing protective gloves, carefully remove any contaminated clothing,including shoes, and wash skin thoroughly with soap and water. If irritation or symptoms occur or persist,consult a physician.

MSDS NUMBER: SP001588MSDS NAME: Muskol Aerosol, 23.5% DEET

Latest Revision Date: 11-Mar-2014 Page 2 of 8

SECTION 4. FIRST AID MEASURESEYE CONTACT: In case of eye contact, IMMEDIATELY rinse eyes thoroughly with plenty of water. If wearing contact

lenses, remove only after initial rinse, and continue rinsing eyes for at least 15 minutes. Get IMMEDIATEmedical attention.

INGESTION: Rinse mouth and drink a glass of water. Do not induce vomiting unless under the direction of a qualifiedmedical professional or Poison Control Center. If symptoms persist, consult a physician.

SECTION 5. FIRE FIGHTING MEASURES

FLAMMABILITY DATA:

Flash Point: Concentrate (Similar Product Formulation): 13 deg C (55.4 deg F) Method: Tagliabue closed cup (TCC)Ethanol (50%): 24 deg C ( 79 deg F) Method: Close cupPropellant:: -84.4 deg C (-120 deg F)

Classification: Flammable (US OSHA Criteria)Flammable (Canada WHMIS Criteria)

Autoignition Temperature: Concentrate: 422 deg C ( 791.6 deg F )

SPECIAL FIRE FIGHTING PROCEDURES:Wear full protective clothing and self-contained breathing apparatus (SCBA).

SUITABLE EXTINGUISHING MEDIA:Carbon dioxide (CO2), extinguishing powder or water spray.

See Section 9 for Physical and Chemical Properties.

SECTION 6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS:Wear appropriate personal protective equipment as specified in Section 8. Keep personnel away from the clean-up area.

SPILL RESPONSE / CLEANUP:All spills should be handled according to site requirements and based on precautions cited in the MSDS. In the case of liquids, use proper absorbentmaterials. For laboratories and small-scale operations, incidental spills within a hood or enclosure should be cleaned by using a HEPA filtered vacuum orwet cleaning methods as appropriate. For large dry or liquid spills or those spills outside enclosure or hood, appropriate emergency response personnelshould be notified. In manufacturing and large-scale operations, HEPA vacuuming prior to wet mopping or cleaning is required.

See Sections 9 and 10 for additional physical, chemical, and hazard information.

SECTION 7. HANDLING AND STORAGE

HANDLING:Keep containers adequately sealed during material transfer, transport, or when not in use. Wash face, hands, and any exposed skin after handling. Donot eat, drink, or smoke when using this substance or mixture.

Appropriate handling of this material is dependent on many factors, including physical form, duration and frequency of process or task, and effectivenessof engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness of all exposure controlmeasures. See Section 8 (Exposure Controls) for additional guidance.

STORAGE:Store in a cool, dry, well ventilated area. Keep away from heat, sparks, open flames, and direct sunlight.

See Section 8 for exposure controls and additional safe handling information.



SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLSThe health hazard risks of handling this material are dependent on many factors, including physical form, duration and frequency of process or task, andeffectiveness of engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness of allexposure control measures. Exposure controls for normal operating or routine procedures follow a tiered strategy. Engineering controls are thepreferred means of long-term or permanent exposure control. If engineering controls are not feasible, appropriate use of personal protective equipment(PPE) may be considered as alternative control measures. Exposure controls for non-routine operations must be evaluated and addressed as part ofthe site-specific risk assessment.

RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):

Respiratory Protection: None required for consumer use of this product.

Respiratory protective equipment (RPE) may be required for certain laboratory and large-scalemanufacturing tasks if potential airborne breathing zone concentrations of substances exceed the relevantexposure limit(s). Workplace risk assessment should be completed before specifying and implementingRPE usage. Potential exposure points and pathways, task duration and frequency, potential employeecontact with the substance, and the ability of the substance to be rendered airborne during specific tasksshould be evaluated. Initial and ongoing strategies of quantitative exposure measurement should beobtained as required by the workplace risk assessment. All RPE must conform to local and regionalspecifications for efficacy and performance. Consult your site or corporate health and safety professionalfor additional guidance.

Skin Protection: None required for consumer use of this product.

Gloves that provide an appropriate barrier to the skin are recommended if there is potential for contact withthis material. Consult your site safety staff for guidance.

Eye Protection: None required for consumer use of this product.

Safety glasses with side shields. Use of goggles or full face protection is required if there is potential forcontact with this material. Consult your site safety staff for guidance.

Body Protection: None required for consumer use of this product.

In small-scale or laboratory operations, lab coats or equivalent protection is required. Disposable Tyvek orother dust impermeable suit should be considered based on procedure or level of exposure. Use ofadditional PPE such as shoe coverings, gauntlets, hood, or head covering may be necessary. Consultyour site safety staff for guidance.

In large-scale or manufacturing operations, disposable Tyvek or other dust impermeable suit isrecommended and based on level of exposure. Use of additional PPE such as shoe coverings, gauntlets,hood, or head covering may be necessary. Consult your site safety staff for guidance.

EXPOSURE LIMIT VALUES

INGREDIENT CAS NUMBER ACGIH TLV (TWA) OSHA PEL (TWA)

Isobutane 75-28-5 1000 ppm

Ethyl Alcohol 64-17-5 1000 ppm1900 mg/m3

Propane 74-98-6 1000 ppm 1000 ppm1800 mg/m3

INGREDIENT CAS NUMBER ACGIH TLV (STEL/ SKIN)

ACGIH TLV(CEIL)

OSHA PEL(STEL / SKIN)

OSHA PEL(CEIL)

Ethyl Alcohol 64-17-5 1000 ppm

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

FORM: Aerosol

COLOR: Clear, Light yellow

ODOR: Alcohol odor

BOILING POINT / RANGE: 79-100 deg C

VAPOR PRESSURE: 45-55 psi @ 20 deg C

VAPOR DENSITY: >1



SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESSPECIFIC GRAVITY: Aerosol: 0.75-0.79

Concentrate: 0.85-0.89

SOLUBILITY:

Water: Not determined

EVAPORATION RATE: >1

See Section 5 for flammability/explosivity information.

SECTION 10. STABILITY AND REACTIVITY

STABILITY/ REACTIVITY:Stable under normal conditions.

INCOMPATIBLE MATERIALS / CONDITIONS TO AVOID:Oxidizers.

HAZARDOUS DECOMPOSITION PRODUCTS / REACTIONS:No dangerous decomposition is expected if used according to manufacturer's specifications.

SECTION 11. TOXICOLOGICAL INFORMATION

There are no data available specifically for this formulation. The data shown below pertains to the following individual ingredients in the formulation, orare from studies conducted using similar formulas containing the same active and/or hazardous ingredients found in this product.

ACUTE TOXICITY DATA

INHALATION:Deet: LC50: 5.95 mg/L

Ethanol: Inhalation LC50 (10hr): 20,000ppmEthanol caused dose dependent effects following inhalation exposure in rats on the central nervous system including drowsiness, incoordination,narcosis and excitation.

Propane caused irregular breathing, tremors, stupor, and CNS depression in guinea pigs exposed to 2.2 to 5.5% (24,000 to 55,000 ppm). Effects wererapidly reversible upon cessation of exposure. In cats, 89% propane caused a decrease in blood pressure, and in dogs, 1% to 3.3% causedhemodynamic changes, decreases in mean arotic pressure, stroke volume, and cardiac output, increase in pulmonary vascular resistance, anddecreases in the contractility of the heart muscle. Weak cardiac sensitization was observed in mice and dogs exposed to 10 to 15% propane.Respiratory depression was observed in non-human primates exposed to 20% propane.

Isobutane caused CNS depression, rapid and shallow respiration, and apnea in mice exposed to high concentrations. In dogs, 45% isobutane causedanesthetic effects.

SKIN:Similiar product formulations were shown to be slightly irritating to animals.

DEET caused minimal to moderate transient dermal irritation in animals, which cleared by day 7.

Ethanol was mildly to moderately irritating to the skin of rabbits.

Propane is a moderate irritant.

EYE:Similar product formulations were shown to be moderate to severe eye irritants to animals.

Ethanol (95%) was irritating to the eyes of rabbits.

ORAL:Clinical signs of toxicity noted in animals treated with DEET at 50 to 500 mg/kg included piloerection, increased vocalization and decreased activity. Atlethal doses, animals showed signs of lacrimation, depression, prostration, tremors, asphyxial convulsions or respiratory failure usually preceding cardiacfailure.

Ethanol: Oral LD50: 6.2 to 17.8 g/kg (rat); 5.5 to 6.6 g/kg (dog)

DERMAL AND RESPIRATORY SENSITIZATION:Ethanol has been shown to be a weak sensitizer in a human patch test. Ethanol was negative in the mouse ear sensitization assay.



REPEAT DOSE TOXICITY DATA

SUBCHRONIC / CHRONIC TOXICITY:Subchronic (56 to 90 days) to chronic (2-year) oral studies with DEET were conducted in animals. Effects noted at dosages ranging from 8.4 to 10,000mg/kg/day included decreases in food consumption and weight, salivation, tremors, elevated liver and kidney weights and cholesterol, and death (highdose groups only). Microscopic findings were observed in the kidneys, testis, epidiymides, and uterus. NOELs ranged from 61 to 100 mg/kg/day acrossspecies.

Repeated oral and inhalation exposure to high concentrations of ethanol has caused kidney and liver damage in animals.

REPRODUCTIVE / DEVELOPMENTAL TOXICITY:DEET caused no effects on reproduction or development in animals administered oral doses up to 1,000 mg/kg/day. Maternal toxicity was observed atthe higher dosages and was consisted with that seen in acute, subchronic and chronic studies. The reproductive and developmental NOEL was 250mg/kg/day.

Ethanol: Exposure to large doses during gestation is reported to cause effects on reproduction, including fetotoxicity and growth retardation in mice,rats, and rabbits. However, no teratogenic effects were reported.

MUTAGENICITY / GENOTOXICITY:DEET was negative in a bacterial mutagenicity study (Ames), a chromosome aberration study, a dominant lethal test, and in an unscheduled DNAsynthesis assay. DEET was negative in a mouse lymphoma assay without metabolic activation but positive with metabolic activation.

Ethanol was positive in a bacterial mutagenicity study (Ames) and negative in a mammalian mutagenicity study (mouse lymphoma).

Propane was negative in a bacterial mutagenicity study.

Isobutane was negative in a bacterial mutagenicity study (Ames).

CARCINOGENICITY:This material or product has not been evaluated for carcinogenicity.

There was no evidence of carcinogenicity in mice or rats treated with DEET at dosages up to 1000 mg/kg/day for 78 weeks and 2 years, respectively.

Rats given 25 to 50% ethanol by oral gavage or in the drinking water for one to two years did not show a significant increase in tumors compared to thecontrol groups. Mice given 43% ethanol in drinking water for three years showed an increase in papillomas of the forestomach, malignant lymphomasand lung adenomas. Ethanol was an effective promoter of liver tumors in rats given a single intraperitoneal dose of diethylnitrosamine followed bytreatment of ethanol in the drinking water for 12 to 18 months.

SECTION 12. ECOLOGICAL INFORMATION

There are no data for the final product or its formulation(s). The information presented below pertains to the following ingredient(s).

ECOTOXICITY DATA

INGREDIENT ECOTOXICITY Deet: 96-hr LC50 (rainbow trout): 75 mg/LDeet: 48-hr EC50 (daphnid): 75 mg/LDeet: Avian Oral LD50 (quail): 1375 mg/kg

Ethanol: 96-hr (static) LC50 (rainbow trout): 13 g/LEthanol: 96-hr (flow-through) LC50 (fathead minnow): 12.9-15.3 g/L

ENVIRONMENTAL DATA

OTHER INGREDIENT ENVIRONMENTAL DATA: DEET: n-Octanol/Water Partition Coefficient (log Pow): 2.02DEET will be stable to hydrolysis at pH levels 5 to 9.

SECTION 13. DISPOSAL CONSIDERATIONS

MATERIAL WASTE:Disposal must be in accordance with applicable federal, state/provincial, and/or local regulations. Incineration is not the preferred method of disposal.Operations that involve the crushing or shredding of waste materials or returned goods must be handled to meet the recommended exposure limit(s).

PACKAGING AND CONTAINERS:Disposal must be in accordance with applicable federal, state/provincial, and/or local regulations.



SECTION 14. TRANSPORT INFORMATION

Refer to site-specific procedures and requirements for additional guidance.

DOT CLASSIFICATION:

Proper Shipping Name: AerosolsHazard Class: 2.1UN Number: UN 1950Packing Group: None

IATA/ICAO CLASSIFICATION:

Proper Shipping Name: Aerosols, flammableHazard Class: 2.1UN Number: UN 1950Packing Group: None

ADR CLASSIFICATION:

Proper Shipping Name: AerosolsHazard Class: 2.1UN Number: UN 1950Packing Group: None

IMDG/IMO CLASSIFICATION:

Proper Shipping Name: AerosolsHazard Class: 2UN Number: UN 1950Packing Group: None

SECTION 15. REGULATORY INFORMATION

WHMIS CLASSIFICATIONS:

This product has been classified in accordance with the hazard criteria on the Controlled Products Regulations and the MSDS contains all theinformation required by the Controlled Products Regulations. The final packaged product is not subject to WHMIS classification. The followingclassification applies to the bulk formulation handled in the workplace.

Controlled Product Class: B5: Flammable AerosolD1B: ToxicD2B: Toxic

TSCA LISTING

INGREDIENT TSCA

Isobutane X

Ethyl Alcohol X

Diethyltoluamide (DEET) X

Propane X

SECTION 16. OTHER INFORMATION

Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracyor completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intendedpurposes or for the consequence of its use. Each individual should make a determination as to the suitability of the information for their particularpurpose(s).

MSDS NUMBER: SP001588


MSDS NAME: Muskol Aerosol, 23.5% DEET

DEPARTMENT ISSUING MSDS: Global Safety & the EnvironmentMerck & Co., Inc.One Merck DriveWhitehouse Station, NJ 08889

MERCK MSDS HELPLINE: (800) 770-8878 (US and Canada)(908) 473-3371 (Worldwide)Monday to Friday, 9am to 5pm (US Eastern Time)

MSDS CREATION DATE: 24-Oct-2002

SUPERSEDES DATE: 03-Mar-2011

SECTIONS CHANGED (CAN SUBFORMAT): 1, 16

SIGNIFICANT CHANGES (CAN SUBFORMAT): Phone Number(s)



NEMCO RESOURCES LTD. Page 1 of 13 SR-1 Antifreeze & Coolant Pure

Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666


1. Product and company identification

PRODUCT NAME : SR-1 Antifreeze & Coolant Pure

PRODUCT CODE : 0696

SUPPLIER : NEMCO RESOURCES LTD.

25 Midland Street

Winnipeg, Manitoba

R3E 3J6 Canada

Date Issued : October, 2013

Emergency (call collect) : 204-788-1030

CANUTEC : 613-996-6666


EMERGENCY OVERVIEW

Slight odor.

May be fatal if swallowed.

Vapors can cause eye irritation.

Lowest Known LD50 (Oral) 107-21-1 >5000 mg/kg (Rats)

Lowest Known LD50 (Skin) 107-21-1 >8000 mg/kg (Rabbits)

HAZARD RATING SYSTEM

NFPA: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0

HMIS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0

KEY: 0 – Minimal 1 – Slight 2 - Moderate 3 - Serious 4 - Severe

POTENTIAL ACUTE HEALTH EFFECTS

Inhalation : At room temperature, exposures to vapors are minimal due to physical properties; higher temperatures may generate vapor levels sufficient to cause adverse effects.

Ingestion : Single dose oral toxicity is considered to be moderate. Excessive exposure may cause central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Small amounts swallowed incidental to normal handling operations are not likely to cause injury; however, swallowing amounts larger than that may cause serious injury, even death



Eye : May cause slight transient (temporary) eye irritation. Corneal injury is unlikely. Vapors or mists may cause eye irritation.


Skin : Prolonged or repeated exposure not likely to cause significant skin irritation. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. Repeated skin exposure may result in absorption of harmful amounts. Massive contact with damaged skin or of material sufficiently hot to burn skin may result in absorption of potential lethal amounts.

Systemic (Other Target Organ) Effects

: The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, central nervous system depression and kidney injury. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. Treatment with ethanol to inhibit the metabolism of glycol to oxalate.Early administration of ethanol may counter the toxic effects of ethylene glycol (cardiopulmonary effects attributed to metabolic acidosis and renal damage). Hemodialysis or peritoneal dialysis have been of benefit. Pre-existing respiratory and skin disorders may be aggravated by over-exposure to this product. Treat symptomatically and supportively.

Cancer Information : Based on data from long-term animal studies, ethylene glycol is not believed to pose a carcinogenic risk to man.

Teratology (Birth Defects) : Exposure to ethylene glycol has caused birth defects in laboratory animals only at doses toxic to the mother.

Reproductive Effects : Ethylene glycol has not interfered with reproduction in animal studies except at very high doses.

CHRONIC, PROLONGED OR REPEATED OVEREXPOSURE

Effects of Repeated Overexposure

: Repeated inhalation of ethylene glycol mist may produce signs of central nervous system involvement, particularly dizziness and nystagmus.

Other Effects of Overexposure : repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material.

3. COMPOSITION/INFORMATION ON INGREDIENTS Material CAS# % by Wt PEL (OSHA) TLV (ACGIH) Ethylene Glycol 107-21-1 >95 50 ppm 50 ppm


EYE CONTACT : Immediately flush eyes with large amounts of water for 15 minutes, lifting lower and upper lids. Get medical attention as soon as possible. Contact lenses should never be worn when working with this chemical.

SKIN CONTACT : Flush area of skin contact immediately with large amounts of water for at least 15 minutes while removing contaminated clothing. If irritation persists after flushing, get medical attention promptly. Wash clothing before re-use.

INHALATION : If inhaled, immediately remove victim to fresh air and call emergency medical care. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

INGESTION : Obtain medical attention immediately. If patient is fully conscious, give two glasses of water. Do not induce vomiting. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whisky. For children, give proportionally less liquor, according to weight.



4. FIRST AID MEASURES Notes to physician : It is estimated that the lethal oral dose to adults is of the order of 1.0 ml/kg. Ethylene glycol is

metabolized by alcohol dehydrogenate to various metabolites including glyceraldehydes, glycolic acid and oxalic acid which cause an elevated anion-gap metabolic acidosis and renal tubular injury. The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, CNS depression, and kidney injury. Urinalysis may show albuminuria, hematuria and oxaluria. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. The currently recommended medical management of ethylene glycol poisoning includes elimination of ethylene glycol and metabolites, correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and follow up urinalysis and clinical chemistry. There should be particular emphasis on acid-base balance and renal function tests. A continuous infusion of 5% sodium bicarbonate with frequent monitoring of electrolytes and fluid balance is used to achieve correction of metabolic acidosis and forced diuresis. As a competitive substrate for alcohol dehydrogenase, ethanol is antidotal. Given in the early stages of intoxication, it blocks the formulation of nephrotoxic metabolites. A therapeutically effective blood concentration of ethanol is in the range 100-150 mg/dl, and should be achieved by a rapid loading dose and maintained by intravenous infusion. For severe and/or deteriorating cases, hemodialysis may be required. Dialysis should be considered for patients who are symptomatic, have severe metabolic acidosis, a blood ethylene glycol concentration greater than 25 md/dl, or compromise of renal functions. A more effective intravenous antidote for physician use is 4-methylpyrazole, a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occurred. A generally recommended protocol is a loading dose of 15 mg/kg followed by 10 mg/kg every 12 hours for 4 doses and then 15 mg/kg every 12 hours until ethylene glycol concentrations are below 20 mg/100 ml. Slow intravenous infusion is required. Since 4-methyplyrozole is dialyzable, increased dosage may be necessary during hemodialysis. Additional therapeutic measures may include the administration of cofactors involved in the metabolism of ethylene glycol. Thiamine (100 mg) and pyridoxine (50 mg) should be given every six hours. Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. The mechanism of production has not been elucidated, but it appears to be non-cardiogenic in origin in several cases. Respiratory support with mechanical ventilation and positive end expiratory pressure may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and dysphasia..




Flammable Properties : Flash Point: None, since % of water is over 20. Autoignition Temperature: Autoignition temperature for 100% ethylene glycol is 398C (748F).

Flammability Limits : % of vapor concentration at which product can ignite in presence of spark. Lower Flammability Limit: Not determined Upper Flammability Limit: Not determined

Flammability limits are not determined on this product because the solution consists of 50% water. If and when the water evaporates and 100% glycol is left, the upper and lower flammability limits would be 3.2% and 15.3% (the same as concentrated Ethylene glycol).

HAZARDOUS PRODUCTS OF COMBUSTION

: Hazardous combustion products may include and are not limited to carbon monoxide, carbon dioxide and trace amounts of aldehydes and organic acids. When available oxygen is limited, as in a fire or when heated to very high temperatures by a hot wire or plate, carbon monoxide and other hazardous compounds such as aldehydes might be generated.

EXTINGUISH MEDIA : Water fog or fine spray. Alcohol resistant foams (ATC type) are preferred if available. General purpose synthetic foams (including AFFF) or protein foams may function, but much less effectively. Carbon dioxide. Dry chemical. Do not use direct water stream. May spread fire.

FIRE FIGHTING INSTRUCTIONS : No fire and explosion hazards expected under normal storage and handling conditions (i.e. ambient temperatures). However, ethylene glycol or solutions of ethylene glycol and water can form flammable vapors with air if heated sufficiently. Keep people away. Isolate fire area and deny unnecessary entry.

PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS

: Wear positive-pressure, self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves).


PROTECT PEOPLE : Material is moderately toxic when ingested. Take adequate precautions to keep people, especially children away from spill site. PVC-coated rubber gloves and monogoggles or face shield can be used during cleanup of spill site. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -18oC (0oF). Do not store near food, foodstuffs, drugs or potable water supplies.

PROTECT ENVIRONMENT : Do not dump used product or diluted material into sewers, on the ground, or into any body of water. .

CLEANUP : Small spills: Soak up with absorbent material. Large spills: Dike and pump into suitable containers for disposal. Ensure compliance with all applicable statues that require notification of appropriate government officials



7. HANDLING AND STORAGE HANDLING : Put on appropriate personal protective equipment (see section 8). Eating,

drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

STORAGE : Keep container closed when not in use. Store away from heat or open flame. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -37oC (-34oF). Do not store near food, foodstuffs, drugs or potable water supplies.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS : Use general or local exhaust ventilation to meet TLV requirements.

RESPIRATORY PROTECTION : Respiratory protection is required if airborne concentration exceeds TLV. At any detectable concentration any self-contained breathing apparatus with a full face piece and operated in a pressure-demand or other positive pressure mode or any supplied-air respirator with a full face piece and operated in a pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode..

EYE PROTECTION : Safety goggles and face shield. Emergency eyewash should be available. Contact lenses should not be worn when working with this chemical.

SKIN PROTECTION : Protective gloves recommended when prolonged skin contact cannot be avoided. Polyethylene; Neoprene; Nitrile; Polyvinyl alcohol; Natural Rubber, Butyl Rubber. Safety shower should be available.

HAND PROTECTION : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hours (breakthrough time): nitrile rubber

EXPOSURE LIMITS Component Exposure Limits Skin Form Ethylene glycol 100 mg/m3 CEILING ACGIH Aerosol Ethylene glycol 125 mg/m3 CEILING OSHA-vacated 50 ppm CEILING OSHA – vacated 100 mg/m3 CEILING UCC Aerosol and Vapor Diethylene glycol 50 ppm TWA8 AIHA WEEL Aerosol and Vapor Diethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol In the Exposure Limits Chart above, if there is no specific qualifier (i.e., Aerosol) listed in the Form Column for a particular limit, the listed limit includes all airborne forms of the substance that can be inhaled. A “blank” in the Skin column indicates that exposure by the cutaneous (skin) route is not a potential significant contributor to overall exposure.



9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE : Clear viscous liquid

ODOR THRESHOLD-ppm : Odorless.

pH : 7.5-11

BOILING POINT C (F) : 107°C (226°F)

FREEDZING POINT C (F) : -37°C (-34°F)

FLASH POINT C (F) : Not Established

FLAMMABILITY : Not Established

WATER SOLUBILITY : Complete Soluble in water

VOC CONTENT : Not Established

VAPOR PRESSURE -mmHg 20 C

: <0.1

VAPOR DENSITY: : Not Established

EVAPORATION RATE : Nil

FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING EPRESENTATIVE

10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.)

: Stable

CONDITION OF INSTABILITY : Keep away from flame


: Strong acid or oxidizing agents

HAZARDOUS DECOMPOSITION PRODUCTS

: Incomplete combustion may produce CO gas.

HAZARDOUS POLYMERIZATION

: Will not occur



11. TOXICOLOGICAL DATA Skin: The dermal LD50 has not been determined. Ingestion: The lethal dose in humans is estimated to be 100 ml (3 ozs.). The oral LD50 for rats is in the 6000-13,000-mg/kg range. Hydrated Inorganic Acid Sodium Salt: The lowest dose of a similar compound reported to produce death in humans was estimated to be 709 mg/kg body weight for a person weighing 150 pounds, this would be equivalent to swallowing about one-tenth (.1) of a pound of the dry material in a short period of time. Acute oral LD50s for a similar compound = 2,650 mg/kg (rats) 2,000 mg/kg (mice) Mutagenicity (The Effects on Genetic Material): In vitro mutagenicity studies were negative. Animal mutagenicity studies were negative. Significant Data with Possible Relevance to Humans: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to asses the effects of exposure of pregnant rats and made to aerosis at concentrations of 150, 1000 and 25000 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol percutaneous absorption of ethylene glycol from contaminated skin, or swallowing ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 25000 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity. The major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. A chronic dietary feeding study of diethylene glycol with rats showed mild kidney injury at 1%, while concentrations of 2% and 4% caused more marked kidney injury. In addition, at 2% and 4% of diethylene glycol in the diet, some rats developed benign papillary tumors in the urinary bladder. These have been attributed to the presence of urinary bladder calcium oxalate stones. No evidence for carcinogenicity was found with a chronic skin-painting study with diethylene glycol in mice. The absence of a direct chemical carcinogenic effect addords with the results in vitro genotoxicity studies that show that it does not produce mutagenic or clastogenic effects. A feeding study employing up to 5.0% diethylene glycol in the diet failed to produce any teratogenic effects. In a mouse continuous breeding study with large doses of diethylene glycol in drinking water, there was evidence for reproductive toxicity at 3.5% (equivalent to 6.1 g/kg/day) as reduced number of litter, live pups per litter and live pup weight. No such effects were seen at 1.75% (approximately 3.05 g/kg/day). The relevance of these very high dosages to human health is uncertain. Pregnant rats receiving undiluted diethylene glycol by gavage over the period of organogenesis had toxic effects at 4.0 and 8.0 ml/kg/day as mortality, decreased body weight, decreased food consumption increased water consumption and increased liver and kidney weights. Fetotoxicity was seen only at these maternally toxic dosages. Decreased fetal body weight occurred at 8.0 ml/kg/day, and increased skeletal variants at 4.0 and 8.0 ml/kg/day. No embryotixic or teratogenic effects were seen. Neither maternal toxicity nor fetotoxicity occurred at 1.0 ml/kg/day. In a study with mice also receiving undiluted diethylene glycol over the period of organogenesis, maternal toxicity occurred at 2.5 and 10.0 ml/kg/day, but not at 0.5 ml/kg/day. Definitive developmental toxicity was not seen in this species. ACUTE TOXICITY Peroral: The lethal dose in humans is estimated to be 3 oz. or 100 ml. Rat: LD50 (6000 – 13000) mg/kg



Percutaneous: Rabbit: LD50 = >22270 mg/kg; 24 h occluded Inhalation: Rat: 8-hour exposure, substantially saturated vapor studies, dynamic generation method Mortality: 0/6 Inhalation: Mist/vapor study, rat, at 170C, 8-hour exposure = 2.2 mg/l Mortality: 0/6 Inhalation: Rat: 8-hour exposure, fog = 10000 ppm; 65 - 70C Mortality: 0/6 IRRITATION Skin: Rabbit: 24-hour occluded contact, 0.5 ml Results: Minor erythema and edema Skin: Human: Primary irritation patch test, 48-hour occluded, 0.2 ml Results: Evidence of irritation Eye: Rabbit: 0.1 ml Results: Minor transient iritis, conjunctival irritation with discharge REPEATED EXPOSURE In a 7-day dietary study with rats, a significant increase in kidney weights in females was observed at 5.0 gm/kg. The NOEL was 2.5 gm/kg. In a 24-month dietary study with rats, increased mortality in males was observed at the highest dose, 1.0 gm/kg/day. There were multiple signs: mineralization of several organs, including the cardiac vessels, cardiac muscle, vas deferens, stomach and pulmonary vessels; cellular hyperplasia of the parathyroids, hemosiderosis of the spleen, myocardial fibrosis, portal fibrosis of the liver, bile duct hyperplasia and hydronephrosis and oxylate nephrosis of the kidneys. Ethylene glycol was not oncogenic. In a 90-day dietary study with dogs, repeated exposures to 2.5 gm/kg resulted in acute renal failure and deaths. The NOAEL was 1.0 gm/kg. SENSITIZATION (ANIMAL AND HUMAN STUDIES) Repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material. REPRODUCTIVE TOXICITY A three-generation study indicated that ethylene glycol did not affect reproductive parameters at dietary concentrations up to 1.0 gm/kg/day in any generation. CHRONIC TOXICITY AND CARCINOGENICITY Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in



tumor incidence or a different pattern of tumors compared with untreated controls. The absence of a carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. GENETIC TOXICOLOGY In Vitro: Ethylene glycol was devoid of genotoxic activity in an Ames test, forward gene mutation and sister chromatid exchange (SCE) studies in Chinese Hamster Ovary (CHO) cells and an in vitro cytogenetics study. In Vivo: Ethylene glycol by three different routes (intravenous, peroral and percutaneous) demonstrates apparent first-order pharmacokinetic behavior for the disposition in and the elimination from the plasma. Dose-dependent changes occur for the elimination of metabolites in the urine and as 14CO2 after single doses for the intravenous and peroral, but not the percutaneous route. The hypothesis from literature sources exists that developmental toxicity is caused by a metabolite of ethylene glycol, called glycolic acid, and not parent ethylene glycol. Under most conditions of ethylene glycol exposure, the glycolic acid metabolite is present in the blood in very low levels. However, it can become the major metabolite following large doses of ethylene glycol due to saturation of glycolic acid oxidation and/or elimination. When levels of this acidic metabolite exceed the capacity of maternal blood buffers to neutralize it, a maternal metabolic acidosis ensues, which has been hypothesized to be the true agent responsible for ethylene glycol induced developmental toxicity. Research suggests that ethylene glycol developmental toxicity is due to a dose-rate dependent toxicokinetic shift leading to glycolate accumulation and metabolic acidosis. ADDITIONAL STUDIES Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations of 150, 1000 and 2500 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 2500 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity.



12. ECOLOGICAL INFORMATION (Concentrated Ethylene Glycol)

13. DISPOSAL CONSIDERATIONS DO NOT discharge to sewer. Wear appropriate personal protection. Take up with sand, vermiculite, or similar inert material. Dispose in accordance with federal, state and local regulations.



14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION Non-Bulk Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package) Bulk Proper Shipping Name: Environmentally Hazardous Substance, LIQUID N.O.S. (ETHYLENE GLYCOL) Technical Name: ETHYLENE GLYCOL ID Number: UN 3082 Hazard Class: 9 Packing Group: PG III Reportable Quantity: 5,000 lb. IATA Non-Bulk Not Regulated by IATA IMDG Non-Bulk Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package)


THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS.

Chemical Name Cas Number Ethylene Glycol 107-21-1

United States - TSCA Inventory: Listed Water Standards: No data available Atmospheric Standards: Clean Air Act (1990) - List of Hazardous Air Contaminants: listed CERCLA: Reportable Quantity (RQ): 5,000 pounds (532 gallons) OSHA Hazard Communication Standard: This product is a “hazardous chemical” as defined by the OSHA

Hazard Communication Standard, 29 CFR 1910.1200.



15. REGULATORY INFORMATION SARA Title III: Section 311/312 - Categories: Acute hazard; chronic hazard

Section 312 - Inventory Reporting: Ethylene glycol is subject to Tier I and/or Tier II annual inventory reporting. Section 313 - Emission Reporting: Ethylene glycol is subject to Form R reporting requirements. Section 302 - Extremely Hazardous Substances: Ethylene glycol is not listed.

State Right-To-Know:

California - Exposure Limits - Ceilings: vapor-50 ppm ceiling; 125 mg/m3 ceiling Director's List of Hazardous Substances: listed Florida - Hazardous Substances List: listed Massachusetts - Right-to-Know List: listed Minnesota - Haz. Subs. List: listed (particulate and vapor) New Jersey - Right-to-Know List (Total): Present greater than 1.0% Pennsylvania Right-to-Know List: environmental hazard

Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required. WHMIS Information: D2A - material has potential toxic effects. Refer elsewhere in the MSDS for specific warnings and safe handling information. Refer to the employer's workplace education program. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986): The normal consumer use of this product does not result in exposure to chemicals known to the state of California to cause Cancer and/or reproductive harm above the significant risk level for carcinogens or the maximum allowable dose levels for reproductive toxins. Warnings are not required for consumer packaging. However, industrial or other occupational use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding these levels and are labeled accordingly. California SCAQMD Rule 443.1 (South Coast Air Quality Management District Rule 443.1, Labeling of Materials Containing Organic Solvents): VOC: Vapor pressure 0.06 mmHg at 20°C 1113.38 g/l



16. OTHER INFORMATION ********************************************************************** Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses, which infringe valid patents, or as extending license under valid patents. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Nemco assumes no responsibility for accuracy of information unless the document is the most current available from an official Nemco distribution system. Nemco neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any country except Canada. ********************************************************************** FOR FURTHER INFORMATION, CONTACT: Date of printing : October, 2013

Date of issue : October, 2013

Supplier : Nemco Resources Ltd

Address : 25 Midland Street Winnipeg, Manitoba R3E 3J6 CANADA

Telephone : 204-788-1030

Fax : 204-788-1593

NeoChem Div. of ENERCON WATER TREATMENT LTD. 3606 – 6 Avenue North, Lethbridge, AB T1H 5C4

Phone: (403) 328-9730 * Toll Free: 1-800-248-1195 * Fax: (403) 327-4375 Website: www.neochem.ca * Email: [email protected]

EMERGENCY PHONE NUMBER (CANUTEC): (613) 906-6666

ChemTronic (Aerosol)

Section 01: Identification Product Name: ChemTronic Recommended Use: Demoisturing Lubricant (See Technical Data Sheet) Section 02: Hazards Identification/Emergency Overview Physical State: Aerosol WHMIS Classification: A, D1 Colour: Brown Odour: Solvent Hazard Statement: Do not puncture or incinerate container, even when empty.

Section 03: Composition/Information on Ingredients Ingredient % Conc. C.A.S. # Ingredient % Conc. C.A.S. # Methylene Chloride 30 - 60 75-09-2 Perchloroethylene (Tetrachloroethylene) 30 - 60 127-18-4 Diethylene Glycol Monobutyl Ether 1 - 5 112-34-5 Sodium Sulfonate 3 - 7 Not Available Carbon Dioxide 1 – 5 124-38-9 Section 04: First Aid Measures Skin: Flush skin thoroughly for at least 15 minutes. Remove contaminated clothing if necessary. Seek medical attention if irritation occurs or persists. Eyes: Flush eyes with running water for at least 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek medical attention immediately. Inhalation: Assist difficult breathing by removing casualty to fresh air. Administer oxygen to casualty experiencing breathing difficulty. Perform artificial respiration if breathing stops. Seek medical attention if irritation or breathing difficulties persist. Ingestion: If swallowed, DO NOT induce vomiting. Never give anything by mouth to an unconscious person. Seek medical attention immediately. Section 05: Fire Fighting Measures Flammable: Non-Flammable. If yes, under what conditions: Not Applicable Means of extinction: Standard procedure for chemical fires. Cool containers / tanks with water spray. Hazardous combustion products: Possible phosgene over 250° C, chlorine gas, hydrochloric acid. Hydrocarbon fumes and smoke. Carbon monoxide (where combustion is incomplete). Special protective equipment and precautions for firefighters: Standard equipment for chemical fires. Section 06: Accidental Release Measures Personal precautions, protective equipment and emergency procedures: See Section 8. Environment precautions: Avoid entry of product into the sewage system or water streams. Methods and materials for containment and disposal: Do not puncture or incinerate containers, even when empty. Dispose of in accordance with local, provincial and federal regulations. Section 07: Handling and Storage Precautions for safe handling: Open and handle container with care, ensure the spray nozzle will direct the spray toward the intended target rather than the user. Do not eat, drink or smoke in the presence of open container. Follow routine safe-handling procedures. Storage requirements: When not in use, keep container tightly closed in a dry, cool, well-ventilated area. Avoid contact with incompatible materials listed in Section 10. Product should be stored away from food, drink and ignition sources. Empty containers can retain product residue and may be hazardous. Section 08: Exposure Controls/Personal Protection Note: These recommendations provide general guidelines for handling this product. Personal protective equipment should be selected according to individual application of the material, safe handling practices to consider include: exposure potential, chemical concentration and ventilation. Methylene Chloride vapours can readily accumulate in poorly ventilated areas and can cause unconsciousness. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local, provincial and federal authorities. Recommended Personal Protective Equipment: Gloves: PVC or Nitrile Rubber Respiratory: NIOSH approved respirator (when fumes are present) Eye: Chemical goggles or face shield Footwear: Chemical resistant footwear

Clothing: Cover exposed skin Engineering controls: Local mechanical exhaust ventilation Other: Eyewash station and safety shower are proximal to workstation

Section 09: Physical and Chemical Properties Physical State: Aerosol Appearance: Brown Liquid Odour: Solvent Odour threshold: Not Available pH: Not Applicable Melting point / Freezing point (°C): Not Available Initial boiling point and boiling range (°C): >260° C Flash point (°C): Not Available Evaporation rate: >1 Flammability: Non-Flammable

Upper / Lower flammability or explosive limits: Not Available Vapour pressure (psig): 70 – 80 @ 20° C Vapour density (Air=1): >1 Relative density: Not Available Solubility in Water: Negligible Partition coefficient: n-octanol/water: Not Available Auto-ignition temperature (°C): 556° C Decomposition temperature: Not Available Specific Gravity (Liquid): 0.84 – 0.88

ChemTronic (Aerosol) Section 10: Stability and Reactivity Chemical stability under normal conditions: Stable. If no, under what conditions: Avoid moisture and elevated temperatures. Possibility of hazardous reactions: Normally stable. Incompatible materials: Avoid contact with strong oxidizing agents. Reactivity and under what conditions: Normally stable. Hazardous decomposition products: Possible phosgene over 250° C, chlorine gas, hydrochloric acid. Hydrocarbon fumes and smoke. Carbon monoxide (where combustion is incomplete). Section 11: Toxicological Information Hazardous Ingredients (Section 3): LD50, (Oral) LD50, (Dermal) LC50, (Inhalation) Methylene Chloride 2100 mg/kg (Rat) Not Available 88000 mg/m3 (1/2h) (Rat) Perchloroethylene (Tetrachloroethylene) 2629 mg/kg (Rat) Not Available 5200 ppm (4h) (Mouse) Diethylene Glycol Monobutyl Ether 6560 mg/kg (Rat) Not Available Not Available Sodium Sulfonate Not Available Not Available Not Available Carbon Dioxide Not Applicable Not Available Not Available Effects of acute exposure Skin Contact: Irritant. Skin Absorption: Not Applicable Eye: Irritant. Inhalation: Irritation (where mist or fumes are accumulated). Propellant is simple asphyxiant. Ingestion: Moderately Toxic. Effects of chronic exposure Chronic Exposure Overview: Chronic effects include allergic reactions (headaches, difficulty breathing, rapid heart rate and anaphylaxis) in susceptible individuals. Prolonged and repeated exposure can cause pneumonitis. Solvents may cause defatting dermatitis. Methylene Chloride has moderate toxicity if ingested. If aspirated, Methylene Chloride may be rapidly absorbed through the lungs and result in injury to other body systems. Skin Contact: Irritant. Methylene Chloride overexposure may have central nervous system effects. Solvents may cause defatting dermatitis. Skin Absorption: Not Applicable Eye: Irritation. Inhalation: Methylene Chloride overexposure may lead to central nervous system depression and cardiac sensitization and may cause headache, vomiting, nausea and weakness. Ingestion: Irritation. Methylene Chloride has moderate toxicity if ingested. Teratogenicity: Not Available Reproductive toxicity: Not Available Mutagenicity: Not Available Carcinogenicity: Methylene Chloride and Perchloroethylene have been listed as potential carcinogens by the International Agency for Research on Cancer (IARC). Section 12: Ecological Consideration Ecotoxicity (aquatic and terrestrial): Not Available Persistence and degradability: Not Available Bioaccummulative potential: Not Available

Mobility in soil: Not Available Other adverse effects: Not Available

Section 13: Disposal Considerations Waste Disposal: Dispose of this material and its container in accordance with local, provincial and federal regulations. Section 14: Transport Information UN Number: Not Applicable Shipping Name: Consumer Commodity

Packing Group: Not Applicable Special Shipping Information: Not Applicable

Section 15: Regulatory Information This safety data sheet has been prepared in accordance with the WHMIS standards. All materials used appear on the Canadian DSL. Materials not listed are either non-hazardous or in concentrations of less than 0.1%. Section 16: Other Information Responsibility Statement The information contained herein is provided as a guide to the handling of this product. It is our belief that the information provided in this safety data sheet is reliable. This product should not be used by any person who is not familiar with the contents of this safety data sheet, the recommendation found on the label or technical data sheet. No warranty of any kind is given or implied and Enercon Water Treatment Ltd. assumes no responsibility for damages, losses, injuries or events resulting from damages incurred from its use. The information on this material safety data sheet relates only to the specific material designated herein and does not relate to material use in combination with any other material or in any process. Prepared By: Technical Services Preparation Date: March 1, 2013 Expiry Date: March 1, 2016

Page: 1 of 5


MSDS Number: 1106C

Section 1 PRODUCT AND COMPANY IDENTIFICATION

Trade Name: OATEY CANADIAN ALL PURPOSE CEMENT

Product Nos.: Milky - 31575, 31576, 31577, 31578, 31579

Product Use: Cement for PVC, CPVC and ABS pipe

Formula: PVC and CPVC Resin in Solvent Solution

Synonyms: None

Firm Name &

Address:

Oatey Company 4700 West 160th Street, Cleveland, Ohio 44135

www.oatey.com

Firm Phone No: (216) 267-7100

Emergency Phone

Nos.:

For Emergency First Aid call 1-877-740-5015. For chemical transportation

emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the U.S. 1-

703-527-3887.

Prepared by: Technical Department

Preparation Date: 09/11/2012

Section 2 HAZARDS IDENTIFICATION

Emergency Overview:

Milky

liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors may cause flash

fire. May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory

irritation and central nervous system effects. Swallowing may cause irritation, nausea,

vomiting, diarrhea and kidney or liver disorders. Aspiration hazard. May be fatal if

swallowed. Symptoms may be delayed.

Section 3 COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENTS: %wt/wt : CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA OTHER:

Tetrahydrofuran 30 - 45% 109-99-9 50 ppm(skin) 200 ppm 25 ppm (Mfg)

100 ppm STEL

Methyl Ethyl Ketone 7 - 13% 78-93-3 200 ppm 200 ppm None

300 ppm STEL

Acetone 10 – 20% 67-64-1 500 ppm 1000 ppm None

750 ppm STEL

PVC Resin 7 – 13% 9002-86-2 10 mg/m3 15 mg/m3 None

(Non-hazardous)

CPVC Resin 3 – 7% 68648-82-8 10 mg/m3 None None

(Non-hazardous) Established

Cyclohexanone 10 – 20% 108-94-1 20 ppm(skin) 50 ppm None

50 ppm STEL

Amorphous Fumed Silica 1 - 5% 112945-52-5 10 mg/m3 None None

(Non-hazardous) Established a

OSHA Hazard Classification: Flammable, irritant, organ effects

Section 4 FIRST AID MEASURES

Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and

water. Get medical attention if irritation develops. Remove dried cement with

Oatey Plumber's Hand Cleaner or baby oil.

Eyes: If material gets into eyes or if fumes cause irritation, immediately flush eyes

with plenty of water until chemical is removed. If irritation persists, get

Page: 2 of 5

medical attention immediately.

Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes

difficult, administer oxygen. Administer artificial respiration if breathing

has stopped. Seek immediate medical attention.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to

a person who is unconscious or drowsy. Get immediate medical attention by

calling a Poison Control Center, or hospital emergency room. If medical advice

cannot be obtained, then take the person and product to the nearest medical

emergency treatment center or hospital.

Section 5 FIRE FIGHTING MEASURES

Flashpoint /

Method:

14 - 23 Degrees F. (-10 to -5 Degrees C) / CCCFP

Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume

Extinguishing

Media:

Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container

with water. Water may be ineffective as an extinguishing agent.

Special Fire

Fighting

Procedure:

Firefighters should wear positive pressure self-contained breathing apparatus

and full protective clothing for fires in areas where chemicals are used or

stored

Unusual Fire

And Explosion

Hazards:

Extremely flammable liquid. Keep away from heat and all sources of ignition

including sparks, flames, lighted cigarettes and pilot lights. Containers may

rupture or explode in the heat of a fire. Vapors are heavier than air and may

travel to a remote ignition source and flash back. This product contains

tetrahydrofuran that may form explosive organic peroxide when exposed to air or

light or with age.

Hazardous

Decomposition

Products:

Combustion will produce toxic and irritating vapors including carbon monoxide,

carbon dioxide and hydrogen chloride.

Section 6 ACCIDENTAL RELEASE MEASURES

Spill or Leak

Procedures:

Remove all sources of ignition and ventilate area. Stop leak if it can be done

without risk. Personnel cleaning up the spill should wear appropriate personal

protective equipment, including respirators if vapor concentrations are high.

Soak up spill with an inert absorbent such as sand, earth or other non-

combusting material. Put absorbent material in covered, labeled metal

containers. Prevent liquid from entering watercourses, sewers and natural

waterways. Report releases to authorities as required. See Section 13 for

disposal information.

Section 7 HANDLING AND STORAGE

Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists.

Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after

handling. Do not eat, drink or smoke in the work area. Keep product away from

heat, sparks, flames and all other sources of ignition. No smoking in storage

or use areas. Keep containers closed when not in use.

Storage: Store in a cool, dry, well-ventilated area away from incompatible materials.

Keep containers closed when not in use.

Other: "Empty" containers retain product residue and can be hazardous. Follow all MSDS

precautions in handling empty containers. Do not cut or weld on or near empty

or full containers.

Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at

the point of use below recommended exposure limits. If used in enclosed area,

use exhaust fans. Exhaust fans should be explosion-proof or set up in a way

that flammable concentrations of solvent vapors are not exposed to electrical

fixtures or hot surfaces.

Respiratory

Protection:

For operations where the exposure limit may be exceeded, a NIOSH approved

organic vapor respirator or supplied air respirator is recommended. Equipment

selection depends on contaminant type and concentration, select in accordance

with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting,

use self-contained breathing apparatus.

Skin Rubber gloves are suitable for normal use of the product. For long exposures

Page: 3 of 5

Protection: chemical resistant gloves may be required such as 4H(tm) or Silver Shield(tm)

to avoid prolonged skin contact.

Eye

Protection:

Safety glasses with side shields or safety goggles.

Section 9 PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: 151 Degrees F / 66 Degrees C

Melting Point: Not applicable

Vapor Pressure: 145 mmHg @ 20 Degrees C

Vapor Density: (Air = 1) 2.5

Volatile Components: 80-84%

Solubility In Water: Negligible

pH: Not applicable

Specific Gravity: 0.94 +/- 0.02 @ 20 Degrees C

Evaporation Rate: (BUAC = 1) = 5.5 - 8.0

Appearance: Milky Liquid

Odor: Ether-Like

Will Dissolve In: Tetrahydrofuran

Material Is: Liquid

Section 10 STABILITY AND REACTIVITY

Stability: Stable.

Conditions To

Avoid:

Avoid heat, sparks, flames and other sources of ignition.

Hazardous

Decomposition

Products:

Combustion will produce toxic and irritating vapors including carbon

monoxide, carbon dioxide and hydrogen chloride.

Incompatibility/

Materials To

Avoid:

Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds,

chlorinated inorganics (potassium, calcium and sodium hypochlorite) and

hydrogen peroxides. May attack plastic, resins and rubber.

Hazardous

Polymerization:

Will not occur.

Section 11 TOXICOLOGICAL INFORMATION

Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation,

coughing, headache, dizziness, dullness, nausea, shortness of breath and

vomiting. High concentrations may cause central nervous system depression,

narcosis and unconsciousness. May cause kidney, liver and lung damage.

Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone and

cyclohexanone may be absorbed through the skin causing effects similar to

those listed under inhalation.

Eye: Vapors may cause irritation. Direct contact may cause irritation with

redness, stinging and tearing of the eyes. May cause eye damage.

Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea.

Aspiration during swallowing or vomiting can cause chemical pneumonia and

lung damage. May cause kidney and liver damage.

Chronic

Toxicity:

Prolonged or repeated overexposure cause dermatitis and damage to the

kidney, liver, lungs and central nervous system.

Toxicity Data: Acetone: Oral rat LD50: 5,800 mg/kg

Inhalation rat LC50: 50,100 mg/m3/8 hours

Cyclohexanone: Oral rat LD50: 1,620 mg/kg

Inhalation rat LC50: 8,000 ppm/4 hours

Skin rabbit LD50: 1 mL/kg

Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg

Inhalation rat LC50: 21,000 ppm/3 hours

Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg

Inhalation rat LC50: 23,500 mg/m3/8 hours

Skin rabbit LD50: 6,480 mg/kg

Sensitization: None of the components are known to cause sensitization.

Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by

Page: 4 of 5

NTP, IARC or OSHA. The National Toxicology Program has reported that

exposure of mice and rats to tetrahydrofuran (THF) vapor levels up to 1800

ppm 6 hr/day, 5 days/week for their lifetime caused an increased incidence

of kidney tumors in male rats and liver tumors in female mice. The

significance of these findings for human health is unclear at this time, and

may be related to "species specific" effects. Elevated incidences of tumors

in humans have not been reported for THF. ACGIH has classified

cyclohexanone (CYH) and tetrahydrofuran as “A3,” Confirmed Animal

Carcinogens with Unknown Relevance to Humans.

Mutagenicity: Cyclohexanone has been positive in bacterial and mammalian assays. Acetone,

methyl ethyl ketone and tetrahydrofuran are generally thought not to be

mutagenic.

Reproductive

Toxicity:

Methyl ethyl ketone and cyclohexanone have been shown to cause embryofetal

toxicity and birth defects in laboratory animals. Acetone and

tetrahydrofuran has been found to cause adverse developmental effects only

when exposure levels cause other toxic effects to the mother.

Medical

Conditions

Aggravated By

Exposure:

Persons with pre-existing skin, lung, kidney or liver disorders may be at

increased risk from exposure to this product.

Section 12 ECOLOGICAL INFORMATION

This product is not expected to be toxic to aquatic organisms.

Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.

Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L.

Acetone: 96 hour LC50 for fish is greater than 100 mg/L.

Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.

VOC

Information:

This product emits VOC’s (volatile organic compounds) in its use. Make sure

that use of this product complies with local VOC emission regulations, where

they exist.

VOC Level: Maximum 510 g/L per SCAQMD Test Method 316A.

Section 13 DISPOSAL CONSIDERATIONS

Waste Disposal: Dispose in accordance with current local, state and federal

regulations.

RCRA Hazardous Waste

Number:

U002, U057, U159, U213

EPA Hazardous Waste

ID Number:

D001, D035, F003, F0005

EPA Hazard Waste

Number:

Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)

Section 14 TRANSPORT INFORMATION

DOT Less than 1 Liter (0.3

gal)

Greater than 1 Liter (0.3

gal)

UN/NA Number: None UN1133

Proper Shipping Name: Consumer Commodity Adhesives

Hazard Class: ORM-D 3

Packing Group: None PGII

Hazard Labels: None Flammable Liquid

IMDG

UN Number: UN1133 UN1133

Proper Shipping Name: Adhesives Adhesives

Hazard Class: 3 3

Packing Group: II II

Label: None (Limited Quantities

are expected from

labeling)

Class 3 (Flammable Liquid)

Flashpoint (deg C) -10 to -5 Degrees C -10 to -5 Degrees C

Page: 5 of 5

2008 North American Emercency Response Guidebook Number: 127

Section 15 REGULATORY INFORMATION

Hazard Category for

Section 311/312:

Acute Health, Chronic Health, Flammable

Section 302

Extremely Hazardous

Substances (TPQ):

This product does not contain chemicals regulated under SARA Section 302.

Section 313 Toxic

Chemicals:

This product does not contain chemicals subject to SARA Title III Section

313 Reporting requirements.

CERCLA 103

Reportable

Quantity:

Spills of this product over the RQ (reportable quantity) must be reported

to the National Response Center. The RQ for the product, based on the RQ

for Tetrahydrofuran (45% maximum) of 1,000 lbs, is 2,222 lbs.

Many states have more stringent release reporting requirements. Report

spills required under federal, state and local regulations.

California

Proposition 65:

This product contains trace amounts of chemicals known to the State of

California to cause cancer. Under normal use conditions, exposure to

these chemicals at levels above the State of California “No Significant

Risk Level” (NSRL) are unlikely. The use of proper personal protective

equipment (PPE) and ventilation guidelines noted in Section 8 will

minimize exposure to these chemicals.

TSCA Inventory All of the components of this product are listed on the TSCA inventory.

Canadian WHIMS

Classification:

Class B, Division 2; Class D, Division 2, Subdivision B; Class D,

Division 2, Subdivision A. This product has been classified in accordance

with the hazard criteria of the Controlled Products Regulations (CPR) and

the MSDS contains all the information required by the CPR.

Section 16 OTHER INFORMATION

NFPA and HMIS:

NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None

HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G

Disclaimer:

The information herein has been compiled from sources believed to be reliable, up-to-date, and

is accurate to the best of our knowledge. However, we cannot give any guarantees regarding

information from other sources, and expressly do not make warranties, nor assume any liability

for its use.

Template: tmpl-cn-e1


I. PRODUCT IDENTIFICATIONProduct Name: PC FAST ORANGE LOTION WITH PUMICE 443 MLItem No: 25117Product Type: Waterless hand cleaner

II. COMPOSITION/INFORMATION ON INGREDIENTSComponent: Weight% LD50/oral/rat LC50/inhalation/rat ACGIH; TLV-TWA

WATER7732-18-5

>75 not available not available

PUMICE1332-09-8

<10 not available not available 10 mg/m3 (inhal); 3 mg/m3

(resp) ACGIH



D-LIMONENE5989-27-5

0.1-1.0 4400 mg/kg not available

III. PHYSICAL DATAPhysical State/Appearance: White lotion with pumice

Odour & Odour Threshold: Orange odour


Evaporation Rate: <1 (Butyl acetate = 1)

Vapour Pressure: Not determined

Vapour Density: Heavier than air

Freezing Point: Not determined

pH: 6.0-8.0

Octanol/Water Coefficient: Not determined

Boiling Point: 100°C (212°F)

IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Carbon dioxide, Water, dry chemical

Hazardous Combustion Products: Not applicable

Sensitivity to Static Discharge: Sensitivity to static discharge is not expected.

Conditions of Flammability: None anticipated.

Flash Point/Range: >100°C.

Autoignition Temperature: Not determined

Upper Explosive Limit: Not determined

Lower Explosive Limit: Not determined

V. REACTIVITY DATAConditions Causing Chemical Instability: None

Materials to avoid: None reasonably foreseeable

Conditions of Reactivity: None.

Hazardous Decomposition Products: None anticipated

VI. HAZARDS IDENTIFICATIONPrimary Routes of Exposure: Eye and skin contact, ingestion, inhalation

Existing Conditions Aggravated byExposure:

None known

Toxicity Information: (See Effects of Acute Exposure to Product)

Effects of Acute Exposure: None under normal conditions of use.

Effects of Chronic Exposure: May cause an allergic skin reaction.

Irritancy of Product: Possible eye irritation.

Sensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)

1 of 2

ITW Permatex Canada35 Brownridge Road, Unit 1Halton Hills, ON Canada L7G 0C6Telephone: (800) 924-6994Urgence: 800-255-3924 (ChemTel)

VI. HAZARDS IDENTIFICATIONReproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None known

WHMIS Hazard Class: Non-controlled

VII. PREVENTATIVE MEASURESPersonal ProtectionEyes: Not required.

Skin: Not required.

Ventilation: Not required under normal use.

Engineering Controls: No special provisions are required under normal conditions.

Spill Procedures: Rinse away with water or wipe up with a towel.

Protection of Man and Environment: Follow Canadian and local regulations for disposal.

Handling Procedures and Equipment:Protect from freezing.

Special Handling Information: Avoid contact with eyes.

VIII. FIRST AID MEASURESIngestion: If swallowed, do not induce vomiting - seek medical advice.

Inhalation: Immediate medical attention is not required.

Skin Contact: Flush with water.

Eye Contact: Flush with water. If eye irritation persists, get medical attention.


Proper Shipping Name: Not regulated

Hazard Class: None

UN/ID No: None

IATA (Air)Proper Shipping Name: Not regulated

Class or Division: None

UN/ID Number: None

IMDG (Vessel)Proper Shipping Name: Not regulated

Hazard Class: None

UN Number: None

X. PREPARATION INFORMATIONEstimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0

(HMIS is a registered trademark of the National Paint and Coatings Association)

Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0

(NFPA is a registered trademark of the National Fire Protection Association)

Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: March 31, 2015

Company: ITW Permatex Canada. 35 Brownridge Rd. Unit 1, Halton Hills, ON L76 0C6Revision Number: 3

Telephone No.: 1-800-924-6994

2 of 2


I. PRODUCT IDENTIFICATIONProduct Name: FAST ORANGE PUMICE LOTION 1 GALItem No: 25218Product Type: Waterless hand cleaner


WATER7732-18-5


PUMICE1332-09-8

<10 not available not available 10 mg/m3 (inhal); 3 mg/m3

(resp) ACGIH



D-LIMONENE5989-27-5


III. PHYSICAL DATAPhysical State/Appearance: White lotion with pumice







pH: 6.0-8.0



IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Carbon dioxide, Water, dry chemical

Hazardous Combustion Products: Not applicable.



Flash Point/Range: >95°C COC










None known




Irritancy of Product: Possible eye irritation.

1 of 2


VI. HAZARDS IDENTIFICATIONSensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)Reproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None known



Skin: Not required.













Hazard Class: None

UN/ID No: None



UN/ID Number: None


Hazard Class: None

UN Number: None





Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: May 17, 2013


Telephone No.: 1-800-924-6994

2 of 2


I. PRODUCT IDENTIFICATIONProduct Name: PC FAST ORANGE SMOOTH LOTION 1.89 LItem No: 25520Product Type: Waterless hand cleaner


WATER7732-18-5


POLYMER EMULSION(PROPRIETARY)_

<3 not available not available



D-LIMONENE5989-27-5


III. PHYSICAL DATAPhysical State/Appearance: White lotion







pH: 6.0-8.0



IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Water, Carbon dioxide, Dry chemical, Foam

Hazardous Combustion Products: Not applicable.



Flash Point/Range: >95°C COC










None known




1 of 2


VI. HAZARDS IDENTIFICATIONIrritancy of Product: Possible eye irritation.

Sensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)Reproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None known



Skin: Not required.













Hazard Class: None

UN/ID No: None



UN/ID Number: None


Hazard Class: None

UN Number: None





Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: May 16, 2013


Telephone No.: 1-800-924-6994

2 of 2


1. PRODUCT IDENTIFICATIONProduct Name: Spray Nine® 32 fl.oz

Item No: 26832Product Type: Multi-Purpose Cleaner

2. COMPOSITION/INFORMATION ON INGREDIENTSComponent: Weight% ACGIH; TLV-TWA OSHA PEL

WATER7732-18-5

>80 Not listed Not listed

ETHOXYLATED C9-C11 ALCOHOLS68439-46-3

1-5 Not listed Not listed

DIPROPYLENE GLYCOLMONONBUTYL ETHER29911-28-2

1-5 Not listed Not listed

3. HAZARDS IDENTIFICATIONToxicity: Product may cause reversible eye and skin irritation.. May irritate respiratory system upon frequent or

prolonged use. Oral LD50 greater than 5000 mg/kg.

Primary Routes of Entry: Eye and skin contact, ingestion, inhalation

Signs and Symptoms of Exposure: Overexposure may cause eye and skin redness. May cause inflammation of mucous membranes andirritation. Ingestion may cause nausea and vomiting.

Aggravated Medical Condition: Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product.


4. FIRST AID MEASURESIngestion: If swallowed, do not induce vomiting - seek medical advice. Never give anything by mouth to an

unconscious person.

Inhalation: Move to fresh air in case of accidental inhalation of vapours. If symptoms persist, call a physician.

Skin Contact: Wash off with soap and water. If skin irritation persists, call a physician.

Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medicalattention if irritation persists.

5. FIRE FIGHTING MEASURESFlash Point °F(C°): 182°F/83°C TCC

Recommended Extinguishing Media: Carbon dioxide, Dry chemical, Foam

Special Fire-Fighting Procedures: Wear suitable protective equipment. Use water spray to cool exposedcontainers.

Hazardous Products of Combustion: Oxides of carbon, Oxides of nitrogen

Unusual Fire/Explosion Hazards: Does not sustain combustion (ASTM D4206).



6. ACCIDENTAL RELEASE MEASURESSpill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal.

Clean up spills thoroughly as residue is slippery.

1 of 3


ITW PermatexSpray Nine Brands10 Columbus Blvd.Hartford, CT 06106 USATelephone: 1-87-Permatex(877) 376-2839Emergency: 800-255-3924 (ChemTel)International Emergency: +01-813-248-0585

7. HANDLING AND STORAGEStorage: Keep containers tightly closed in a cool, well-ventilated place. Store below 100°F. Do not allow freezing.

Handling: Use in a well ventilated area. Avoid contact with skin and eyes. Wash thoroughly after handling. Productmay cause surfaces to become slippery.

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEyes: Safety glasses.

Skin: Neoprene or nitrile gloves recommended.

Ventilation: Where reasonably practicable this should be achieved by the use of local exhaust ventilation and goodgeneral extraction.

Respiratory Protection: Not required under normal use.

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Clear liquid

Odor: Citrus

Boiling Point: ~212°F (100°C)

pH: ~12.4

Solubility in Water: Soluble

Specific Gravity: 1.02 g/ml

VOC(Wt.%): 0

Vapor Pressure: 18 mm Hg

Vapor Density (Air=1): >1

Evaporation Rate: <1 (butyl acetate=1)

10. STABILITY AND REACTIVITYChemical Stability: Stable

Hazardous Polymerization: Will not occur

Incompatabilities: Strong oxidizers

Conditions to Avoid: Freezing

Hazardous Products of Combustion: Oxides of carbon, Oxides of nitrogen

11. TOXICOLOGICAL INFORMATIONOral LD50 (rat) >5,000 mg/kgDermal LD50 (rabbit) >5,000 mg/kgInhalation LD50 (rat) >200 g/LEye irritation: Draize = 27.3 of 110 (reversible in 10 days)Skin irritation: Draize 2.5 of 10 (reversible in 14 days)


No data available

13. DISPOSAL CONSIDERATIONSRecommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations

US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material

14. TRANSPORTATION INFORMATIONDOT (49CFR 172)U.S. Department of Transportation - DOT - 49 CFR (Ground)

DOT Shipping Name: Not regulated

Hazard Class: None

UN/ID Number: None



UN/ID Number: None


Hazard Class: None

UN Number: None

Item No. 26832Spray Nine® 32 fl.ozProduct Name:

Marine Pollutant: None

SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.

None

California Proposition 65: No California Prop 65 chemicals are known to be present.

TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.

16. OTHER INFORMATIONEstimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0.

Estimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0

(NFPA is a registered trademark of the National Fire Protection Association)(HMIS is a registered trademark of the National Paint and Coatings Association)

Item No. 26832

Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106

Spray Nine® 32 fl.oz

Revision Number: 3

Telephone No.: 1-87-Permatex (877) 376-2839

Prepared By: Denise Boyd, Manager-Environmental, Health & Safety

Product Name:

Revision Date: March 25, 2014

MOTOR FLUSH MF2C, MF12C, MF2/6C



: MOTOR FLUSH Product identifier

SECTION 1: IDENTIFICATION

Internal Engine Cleaner. : Product Use

: Mixture. Chemical Family

MF2C, MF12C, MF2/6C : Manufacturer part no.

Refer to Supplier

Manufacturer’s name and address: Supplier’s name and address:

Radiator Specialty Co., of Canada 1711 Aimco Blvd. Mississauga, ON, Canada L4W 1H7

(905) 625-9117 (Monday - Friday, 8 AM - 4 PM) : Information Telephone #

613-996-6666 (CANUTEC) : 24 Hr. Emergency Tel #

SECTION 2 - HAZARDS IDENTIFICATION

Classification : WHMIS information: This product is a WHMIS Controlled Product. It meets one or more of the criteria for a controlled product provided in Part IV of the Canadian Controlled Products Regulations (CPR). WHMIS classification: Class B3 (Combustible Liquids); Class D2A (Materials Causing Other Toxic Effects, Very Toxic Material); Class D2B (Materials Causing Other Toxic Effects, Toxic Material). Labelling: Phrases recommended to appear on a supplier label, can be found in Section 15. WHMIS symbols required on a supplier label:

Emergency Overview Light amber liquid. Petroleum odour. WARNING! Combustible liquid and vapour. Harmful if inhaled. May cause respiratory irritation. May cause nausea, vomiting, headache and other central nervous system effects. Harmful or fatal if swallowed. May be an aspiration hazard. Can enter the lungs and cause damage. May cause eye irritation. Prolonged or repeated skin contact may cause drying and irritation. Contains material which

may cause cancer, based on animal data.

:


:

Signs and symptoms of short-term (acute) exposure

May cause irritation to the nose, throat and upper respiratory tract. Symptoms may include pain, headache, nausea, vomiting, dizziness, drowsiness and other central nervous system effects.

Inhalation

: Skin May cause mild skin irritation. May cause redness and itching or burning sensation. Prolonged contact, such as when trapped against the skin under clothing or jewelry, may be more irritating. May be absorbed and cause symptoms similar to those for inhalation.

: Eyes May cause mild to moderate irritation.

May cause irritation of mouth, throat, and stomach. Symptoms may include pain, headache, nausea, vomiting, dizziness, drowsiness and other central nervous system effects. May be an aspiration hazard. Aspiration into the lungs during swallowing or subsequent vomiting may cause chemical pneumonitis, which can be fatal.

Ingestion :

Prolonged skin contact may cause dermatitis (rash), characterized by red, dry, itching skin.

Effects of long-term (chronic) exposure

:

Possible cancer hazard. See TOXICOLOGICAL INFORMATION, Section 11. : Carcinogenic status

Additional health hazards : See TOXICOLOGICAL INFORMATION, Section 11.

See ECOLOGICAL INFORMATION, Section 12. :

Potential environmental effects



SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients CAS # Wt.%

68476-34-6 Petroleum distillates 60.00 - 100.00 64742-52-5 Distillates (petroleum), hydrotreated heavy

naphthenic 7.00 - 13.00

78330-12-8 Petroleum sulfonate 0.10 - 1.00

If inhaled, move to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen by qualified medical personnel only. Get medical attention.

: Inhalation


Remove/Take off immediately all contaminated clothing. Wash exposed area thoroughly with soap and water for at least 15 minutes. If irritation persists, seek prompt medical attention.

Skin contact :

Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists, seek prompt medical attention.

Eye contact :

Ingestion Seek immediate medical attention/advice. Do not induce vomiting. Never give anything by mouth to an unconscious person.

:

Treat symptomatically. : Notes For Physician

Fire hazards/conditions of flammability


Combustible liquid and vapour. Will ignite when exposed to heat, flame and other sources of ignition. Product may float, and be re-ignited at the water's surface. Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Vapours may be heavier than air and may collect in confined and low-lying areas.

:

None known. : Oxidizing properties

: Not expected to be sensitive to mechanical impact. May be sensitive to static discharge.

Explosion data: Sensitivity to mechanical impact / static discharge

Dry chemical, foam, carbon dioxide and water fog. Do not use water jet, as this may spread burning material.

: Suitable extinguishing media

Special fire-fighting procedures/equipment

Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. Move containers from fire area if safe to do so. Water spray may be useful in cooling equipment exposed to heat and flame.

:

Hazardous combustion products

: Carbon oxides; Sulphur oxides; Phosphorus compounds; Nitrogen oxides (NOx); Polycyclic aromatic hydrocarbons; Other unidentified organic compounds.

All persons dealing with the clean-up should wear the appropriate personal protective equipment. Keep all other personnel upwind and away from the spill/release. Restrict access to area until completion of clean-up.



Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike the area to prevent spreading.

Environmental precautions :

Spill response/cleanup Ventilate area of release. Remove all sources of ignition. Use only non-sparking tools and equipment in the clean-up process. Contain and absorb spilled liquid with non-combustible, inert absorbent material (e.g. sand), then place absorbent material into a container for later disposal (see Section 13). Notify the appropriate authorities as required.

:

: Prohibited materials Do not use combustible absorbents, such as sawdust.



Use in a well-ventilated area. Wear suitable protective equipment during handling. Avoid breathing vapours. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks, and open flames. No sparking tools should be used. Avoid contact with incompatible materials. Wash thoroughly after handling.

Safe Handling procedures :


Store in a cool, dry, well-ventilated area. Keep away from direct sunlight. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Inspect periodically for damage or leaks. No smoking in the area.

Storage requirements :

Incompatible materials : Strong oxidizing agents; Acids.

Special packaging materials : Always keep in containers made of the same materials as the supply container.

Exposure Limits

ACGIH TLV OSHA PEL

STEL TWA STEL PEL Ingredients

N/Av N/Av 100 mg/m³ (vapor and aerosol, as total

hydrocarbons) (skin)

N/Av Petroleum distillates

5 mg/m³ (As 'Oil

mist, mineral') N/Av 5 mg/m³ (As 'Oil mist,

mineral') N/Av Distillates (petroleum), hydrotreated

heavy naphthenic

N/Av N/Av N/Av N/Av Petroleum sulfonate

SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION

Ventilation and engineering measures

Use in a well-ventilated area. Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits.

:

Respiratory protection : If the TLV is exceeded, a NIOSH/MSHA-approved respirator is advised. Advice should be sought from respiratory protection specialists.

Skin protection : Impervious gloves must be worn when using this product. Advice should be sought from glove suppliers. Depending on conditions of use, an impervious apron should be worn.

Eye / face protection : Chemical splash goggles are recommended.

An eyewash station and safety shower should be made available in the immediate working area.

: Other protective equipment

General hygiene considerations

: Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink, smoke or use cosmetics while working with this product. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid : Appearance Light amber liquid. :

Odour Petroleum odour. : Odour threshold N/Av :

pH N/Av :

Boiling point 0.86 @ 20°C : Specific gravity : 79.4°C

Melting/Freezing point N/Av :

N/Av :

Coefficient of water/oil distribution

Vapour pressure (mmHg @ 20° C / 68° F)

N/Av :

Solubility in water Insoluble. :

Vapour density (Air = 1) N/Av : Evaporation rate (n-Butyl acetate = 1)

: N/Av

Volatile organic Compounds (VOC's)

N/Av :

Volatiles (% by weight) : N/Av

Flash point 71.1°C :

Flash point Method N/Av : Auto-ignition temperature TCC :

Lower flammable limit (% by vol.) Upper flammable limit (% by vol.)

: : N/Av N/Av

Flame Projection Length Flashback observed : : N/Ap N/Ap



Absolute pressure of container

: N/Ap

Viscosity : < 10 cSt @ 40°C

No additional information. : General Informatioln

Section 10: STABILITY AND REACTIVITY

Stability and reactivity Stable under the recommended storage and handling conditions prescribed. :

Hazardous polymerization Hazardous polymerization does not occur. :

Conditions to avoid : Avoid heat and open flame. Keep away from direct sunlight. Do not use in areas without adequate ventilation. Avoid contact with incompatible materials.

Materials To Avoid And Incompatibility

: Strong oxidizing agents; Acids.

Hazardous decomposition products None known, refer to hazardous combustion products in Section 5. :

Eyes, skin, respiratory system, digestive system, central nervous system. Target organs :

SECTION 11 - TOXICOLOGICAL INFORMATION

Routes of exposure Inhalation: Skin Absorption: Skin & Eyes: Ingestion: YES YES YES YES :

: Mild to moderate eye irritant. Mild skin irritant.. Irritancy

There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data.

: Toxicological data

LD50 LC50(4hr)

inh, rat Ingredients (Rabbit, dermal) (Oral, rat)

Petroleum distillates N/Av N/Av N/Av



> 5 mg/L (mist) > 5000 mg/kg > 2000 mg/kg

Petroleum sulfonate N/Av > 2000 mg/kg > 2000 mg/kg

Carcinogenic status Contains the following chemicals listed as confirmed animal carcinogens (A3) by ACGIH: Petroleum distillates.

:

: Not expected to have other reproductive effects. Reproductive effects

: Teratogenicity Not expected to be a teratogen.

: Mutagenicity Not expected to be mutagenic in humans.

: Epidemiology None known or reported by the manufacturer.

Sensitization to material : Not expected to be a skin or respiratory sensitizer.

: Synergistic materials None known or reported by the manufacturer.

CNS depression may result from extreme exposures. other important hazards :

Conditions aggravated by overexposure

None known or reported by the manufacturer. :

Ecotoxicity : The ecological characteristics of this product have not been fully investigated. The product should not be allowed to enter drains or water courses, or be deposited where it can affect ground or surface waters. See the following tables for individual ingredient ecotoxicity data.

SECTION 12 - ECOLOGICAL INFORMATION

Ecotoxicity data:

NOEC / 21 day LC50 / 96h M Factor

Toxicity to Fish CAS No Ingredients

Petroleum distillates 21 mg/L (Rainbow trout) 68476-34-6 N/Av None.

Distillates (petroleum), hydrotreated heavy naphthenic

> 5000 mg/L (Rainbow trout)

64742-52-5 N/Av None.

Petroleum sulfonate N/Av 78330-12-8 N/Av None.



CAS No Ingredients Toxicity to Daphnia

EC50 / 48h NOEC / 21 day M Factor

68476-34-6 None. N/Av 49 - 94 mg/L (Daphnia

magna) Petroleum distillates

64742-52-5 None. N/Av > 1000 mg/L [Daphnia

magna (Water flea)] Distillates (petroleum),


78330-12-8 None. N/Av N/Av Petroleum sulfonate

CAS No Ingredients Toxicity to Algae

EC50 / 96h or 72h NOEC / 96h or 72h M Factor

68476-34-6 Petroleum distillates 10 mg/L/72hr (Green algae) 3 mg/L (NOEL) None.

64742-52-5 Distillates (petroleum),


> 1000 mg/L/96hr (Green

algae) N/Av None.

78330-12-8 Petroleum sulfonate N/Av N/Av None.

Mobility No data is available on the product itself. :

Persistence No data is available on the product itself. Contains: Petroleum distillates. Petroleum distillates are not considered to be readily biodegradable.

:

Bioaccumulation potential No data is available on the product itself. :

Other Adverse Environmental effects

No data is available on the product itself. :

Handle waste according to recommendations in Section 7. Empty containers retain residue (liquid and/or vapour) and can be dangerous.

: Handling for Disposal

SECTION 13 - DISPOSAL CONSIDERATIONS

Dispose of in accordance with federal, provincial and local hazardous waste laws. : Methods of Disposal

SECTION 14: TRANPORT INFORMATION

Regulatory Information UN Number Shipping Name Class

Packing

Group Label

Not regulated. not regulated TDG None none

None.


TDG


Labelling:

WARNING! Combustible liquid and vapour. Harmful if inhaled. May cause respiratory irritation. May cause nausea, vomiting, headache and other central nervous system effects. Harmful or fatal if swallowed. May be an aspiration hazard. Can enter the lungs and cause damage. May cause eye irritation. Prolonged or repeated skin contact may cause drying and irritation. Contains material which may cause cancer, based on animal data.

Precautions: Use in a well-ventilated area. Wear suitable protective equipment during handling. Avoid breathing vapours. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks, and open flames. No sparking tools should be used. Avoid contact with incompatible materials. Wash thoroughly after handling. Store in a cool, dry, well ventilated area, away from heat and ignition sources.



FIRST AID: If inhaled, move to fresh air. If breathing stopped, begin artificial respiration. If breathing is difficult, give oxygen by qualified medical personnel only. Get medical attention. For skin contact, immediately remove contaminated clothing then wash thoroughly with soap and water for at least 15 minutes. If irritation persists, seek prompt medical attention. For eye contact, flush with running water for at least 15 minutes. If irritation persists, seek prompt medical attention. If ingested, do not induce vomiting. Never give anything by mouth to an unconscious person. Seek immediate medical attention/advice. Refer To Material Safety Data Sheet for further information.

Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL). WHMIS information: Refer to Section 2 for a WHMIS Classification for this product.

Canadian Information:

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR.

TSCA: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory.

US Federal Information:


: ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Services HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer Inh: Inhalation LC: Lethal Concentration LD: Lethal Dose MSHA: Mine Safety and Health Administration N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health NOEC: No observable effect concentration NTP: National Toxicology Program OECD: Organisation for Economic Co-operation and Development OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit RTECS: Registry of Toxic Effects of Chemical Substances STEL: Short Term Exposure Limit TCC: Tagliabue Closed Cup TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System

Legend

1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2013. 2. International Agency for Research on Cancer Monographs, searched 2013. 3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2013 (Chempendium, HSDB and RTECs). 4. Material Safety Data Sheets from manufacturer. 5. OECD - The Global Portal to Information on Chemical Substances - eChemPortal, 2013

References :



Prepared for:

Radiator Specialty Co. of Canada 1711 Aimco Blvd. Mississauga, ON, Canada, L4W 1H7 Telephone: 905-625-9117 (Mon. - Fri., 8 AM - 4 PM) Please direct all enquiries to Radiator Specialty.

Prepared by:

ICC The Compliance Center Inc. http://www.thecompliancecenter.com

DISCLAIMER OF LIABILITY

This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by Radiator Specialty Co. of Canada and CCOHS’ Web Information Service. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and Radiator Specialty Co. of Canada expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and Radiator Specialty Co. of Canada.

:

MSDS Preparation Date (mm/dd/yyyy)

07/26/2007

MSDS Revision Date (mm/dd/yyyy)

: 07/18/2013

Revision No. 3 :

(M)SDS sections updated: 9. PHYSICAL AND CHEMICAL PROPERTIES (Viscosity); 12. ECOLOGICAL INFORMATION.

: Revision Information

END OF DOCUMENT

Methanol Products

Not available.

CH3OH

Alcohol. (Solvent.)

67-56-1

Not available.

Not available.

Recochem Inc.Communications and Regulatory AffairsDepartment(905) 878-5544

Recochem Inc.850 Montee de LiesseMontreal, Quebec514-341-3550

Class B-2: Flammable liquidClass D-1B: Material causing immediate and serious toxic effects (Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

Material Safety Data SheetWHMIS (Pictograms) WHMIS (Classification) Personal protective equipment

Section 1. Product and Company IdentificationProduct name/ Trade name

Synonym

Chemical family

Chemical formula

Manufacturer/Supplier

Material uses

AssociatedProduct’s ItemCode

CAS #

In case ofemergency

Print date

Validation date 2013-04-02.

2013-04-04.

Extremely hazardous by the following route of exposure: of ingestion. Hazardous by the following route of exposure: ofinhalation. Slightly hazardous by the following route of exposure: of skin contact (irritant, permeator), of eye contact(irritant). Non-sensitizer to skin. Severe over-exposure can result in death.

Acute exposure to methanol, either through ingestion or breathing high airborne concentrations can result in symptomsappearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited to CNS, eyes andgastrointestinal tract. Because of the initial CNS’s effects of headache, vertigo, lethargy and confusion, there may be animpression of ethanol intoxication. Blurred vision, decreased acuity and photophobia are common complaints.Treatment with ipecac or lavage is indicated in any patient presenting within two hours of ingestion. A profoundmetabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more accurate measure of severitythan serum methanol levels. Treatment protocols are available from most major hospitals and early collaboration withappropriate hospitals is recommended.

Section 2. Hazards identification

Potential Acute HealthEffects

Note to Physician

Emergency Overview

Flammable liquid. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contact with skin andclothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use.

WARNING!FLAMMABLE LIQUID AND VAPOR. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

See section 11 for more detailed information on health effects and symptoms.

Section 3. Composition, information on ingredients

Canada

Name CAS number Conc. (% w/w)

Methanol 67-56-1 100

Continued on next page

Methanol ProductsPage: 2/8Validated on 2013-04-02.

There are no other ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence requirereporting in this section.

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anythingby mouth to an unconscious person. Get medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 30 minutes,occasionally lifting the upper and lower eyelids. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 30 minutes while removing contaminatedclothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attentionimmediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medicalattention immediately.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Use dry chemical, CO2, water spray (fog) or foam.

Explosive in the form of vapor when exposed to heat or flame. Vapor may travel a considerable distance to source ofignition and flash back. Emits acrid smoke and irritating fumes when heated to decomposition.

Highly flammable liquid and vapor.

Section 5. Fire-fighting measures

Products of combustion

Fire-fighting media andinstructions

Fire Hazards

Explosion Hazards

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, orif water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceousearth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools andexplosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent materialmay pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section13 for waste disposal.

Section 6. Accidental release measures

Small spill and leak

Large spill and leak



Store in accordance with local regulations. Store in a segregated and approved area. Store in original containerprotected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10)and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed andsealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to preventleakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited inareas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Useonly with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areasand confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any otherignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparkingtools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate staticelectricity during transfer by grounding and bonding containers and equipment before transferring material. Emptycontainers retain product residue and can be hazardous. Do not reuse container.

Section 7. Handling and Storage

Handling

Storage

Section 8. Exposure controls/personal protection

Engineering controls

Personal protectionEyes

Body

Respiratory

Hands

Product name Exposure limits

United States

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash gogglesPossible: face shield

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.Possible: safety apron coveralls boots.

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this inecessary. >8 hours (breakthrough time): nitrile rubber



Canada

Methanol ACGIH TLV (United States, 1/2008). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 262 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 328 mg/m³ 15 minute(s).OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s).NIOSH REL (United States, 6/2008). Absorbed through skin. TWA: 200 ppm 10 hour(s). TWA: 260 mg/m³ 10 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s).OSHA PEL (United States, 11/2006). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s).OSHA (United States, 2003). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s).

[1]Absorbed through skin.

Methanol US ACGIH 1/2008 200 262 - 250 328 - - - - [1]AB 6/2008 200 262 - 250 328 - - - - [1]BC 6/2008 200 - - 250 - - - - - [1]ON 6/2008 200 260 - 250 325 - - - - [1]QC 6/2008 200 262 - 250 328 - - - - [1]

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations

CeilingSTEL (15 mins)TWA (8 hours)Occupational exposure limits

64.5°C (148.1°F)Boiling/condensation point

Liquid.

100% (v/v)

7

-98°C (-144°F)

0.79

1.11 [Air = 1]

12.8 kPa (96 mm Hg)

Easily soluble in the following materials: cold water, hotwater and diethyl ether.

2000 ppm

32.04 g/mole

Alcohol. [Slight]

Not available.

Colorless.

5.9 (Butyl acetate. = 1)

Not available.

Section 9. Physical and chemical properties

Physical State andAppearance

Molecular weight

pH

Odour

Taste

Colour

Relative density

Vapor pressure

Vapour Density

Volatility

OdourThreshold

Viscosity

Solubility

Evaporationrate




Lower: 6%Upper: 36%

CLOSED CUP: 11°C (51.8°F). (Tagliabue.)

385°C (725°F)

Flammable.

Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge andheat.Non-flammable in the presence of the following materials or conditions: shocks and mechanical impacts.Explosive in the form of vapor when exposed to heat or flame. Vapor may travel a considerable distance to source ofignition and flash back. Emits acrid smoke and irritating fumes when heated to decomposition.

The product is:

Auto-ignition temperature

Flash point

Flammable limits

Fire hazards in thepresence of varioussubstances

VOC content OtherProperties

Not available.100 % (w/w)


Slightly reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.

Not available.

Section 10. Stability and reactivity

Stability

Conditions of instability

Incompatibility withvarious substancesHazardous decompositionproducts


Acute toxicity

Chronic toxicity

Carcinogenicity

Classification

Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA

Section 11. Toxicological Information

Canada

Methanol LC50 Inhalation Gas. Rat 64000 ppm 4 hoursLD50 Dermal Rabbit 15800 mg/kg -LD50 Dermal Rabbit 15840 mg/kg -LD50 Oral Rat 5600 mg/kg -LD50 Oral Rat 5600 mg/kg -

Methanol A5 4 - - - None.

Conclusion/Summary Not available.


Conclusion/Summary May be fatal or cause blindness if swallowed.Chronic Exposure Effects can include one or all of the following: Acute poisoning,headaches, nausea, vomiting, unconsciousness, kidney and liver damage.Exposure can cause dermatitis.



Mutagenicity

Conclusion/Summary :

Teratogenicity


Reproductive Toxicity


Not available.

Not available.

Not available.

Section 12. Ecological informationFor accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggestedinstructions.

Canada

:

Aquatic ecotoxicity


Biodegradability

Conclusion/Summary : No additional remark.

Product/ingredient name Result Species ExposureMethanol Acute LC50 2500000 ug/L Marine water Crustaceans - Crangon crangon -

Adult48 hours

Acute LC50 3289 to 4395 mg/L Freshwater

Daphnia - Daphnia magna -Neonate - <24 hours

48 hours

Acute LC50 >100000 ug/L Fresh water Fish - Pimephales promelas -Juvenile (Fledgling, Hatchling,Weanling) - 0.2 to 0.5 g

96 hours

Not available.

Ecotoxicity Readily biodegradable

The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-productsshould at all times comply with the requirements of environmental protection and waste disposal legislation and anyregional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers.

Waste information

Section 13. Disposal considerations




In containers of 1 L (1Kg) capacity or less this product is classifiedas a "Limited Quantities""Consumer Commodity" under TDGregulations.

Class

Not a pollutant.

Section 14. Transport information

Proper Shipping Name(Canada) TDG

Special provisions

Class 3: Flammable liquid.

Special provisions In containers of 1 L (1Kg) this product is qualified as a "consumercommodity" ORM-D under DOT

Proper Shipping Name(United States) DOT

Methanol


Methanol

Marine pollutant

Proper Shipping NameIMDG

No placard (handling and hazard label) requi red.

Special provisions RemarksIn containers of 1 L (1Kg) capacity or less this product is classifiedas a "Limited Quantity" under IMDG regulations

Class 6.1: Toxic substance.Subsidiary class

Class 6.1: Toxic substance.Subsidiary class

International AirTransport Association(IATA)


Class 6.1: Toxic substance.ClassSubsidiary class

For air shipment classification and associated regulations, please refer to the latest edition ofIATA Dangerous Goods Regulations.

Class

United States DOT (Classification)

IMDG Classification

Canada TDG Classification

Methanol

UN 1230II

UN numberPacking Group

IIUN 1230UN number

Packing Group

UN 1230

II




130B

03

1

Flammable liquidTarget organ effects

U.S.A. Regulatory Lists

Section 15. Regulatory information

HCS Classification(U.S.A.)

Hazardous MaterialInformation System(U.S.A.)

National FireProtectionAssociation(U.S.A.)

Health

Specific hazard

Reactivity

FlammabilityHealth

Flammability

Reactivity

Personal protection

Class B-2: Flammable liquidClass D-1B: Material causing immediate and serious toxic effects(Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

WHMIS Classification(Canada)

This product and/ or all of its components are on the TSCA inventory list.

This product and/ or all of its components are on the DSL.Canada DomesticSubstances List (DSL)Status

Section 16. Other information

Validated and verified by Compliance and Technical Information Manager on 2013-04-02 ph.#905-878-5544.

Printed 2013-04-04.

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever forthe accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certainhazards are described herein, we cannot guarantee that these are the only hazards that exist.

MSDS are available at www.recochem.com

Universal Fully Formulated Antifreeze/Coolant Premix 60/40

Not available.

CH2OHCH2OH

Not available.

Not available.

WIP-15240-60

Industrial applications: Coolant and antifreeze formulations.


Recochem Inc.850 Montee de LiesseMontreal, QuebecH4T 1P4(514) 341-3550www.recochem.com

Class D-1B: Material causing immediate and serious toxic effects(Toxic).Class D-2A: Material causing other toxic effects (Very toxic).



Synonym

Chemical family

Chemical formula


Material uses


CAS #

In case ofemergency

Print date


2013-05-01.

Toxic by ingestion. May cause abdominal discomfort or pain, nausea, vomiting, dizziness, central nervous system effectsand coma. Cardiac failure, pulmonary edema and severe kidney damage may develop. May cause mild eye irritation.May cause mild skin irritation. Unlikely to be inhaled because of physical characteristics, however, heated material mayproduce vapours, which may cause irritation to lungs if inhaled excessively. Inhalation, particularly of mist, may causeirritation of the nose and throat with headache. High vapour concentrations may produce nausea, vomiting, headache,dizziness and irregular eye movement..

The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, central nervous systemdepression and kidney injury. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. Treatment withethanol to inhibit the metabolism of glycol to oxalate.Early administration of ethanol may counter the toxic effects ofethylene glycol (cardiopulmonary effects attributed to metabolic acidosis and renal damage).Hemodialysis or peritoneal dialysis have been of benefit.Pre-existing respiratory and skin disorders may be aggravated by over-exposure to this product.Treat symptomatically and supportively.



Note to Physician

Emergency Overview

Harmful by inhalation. Do not breathe vapor or mist. Avoid contact with eyes, skin and clothing. May cause target organdamage, based on animal data. Use only with adequate ventilation. Keep container tightly closed and sealed until readyfor use.

WARNING!MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.



Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40

Page: 2/8Validated on 2013-04-23.



Canada


Ethylene glyco 107-21-1 60






Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician See section 2 Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.


Use an extinguishing agent suitable for the surrounding fire.

Emits acrid smoke and irritating fumes when heated to decomposition.May be combustible at high temperature.

Not a product presenting risks of explosion.




Fire Hazards

Explosion Hazards




Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, orif water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of viaa licensed waste disposal contractor.

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceousearth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensedwaste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note:see section 1 for emergency contact information and section 13 for waste disposal.




Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool andwell-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to preventleakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited inareas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep inthe original container or an approved alternative made from a compatible material, kept tightly closed when not in use.Empty containers retain product residue and can be hazardous. Do not reuse container.


Handling

Storage




Body

Respiratory

Hands

United States

No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product contains ingredientswith exposure limits, use process enclosures, local exhaust ventilation or otheengineering controls to keep worker exposure below any recommended or statutorylimits.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash goggles

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.







Canada

Ethylene glycol OSHA PEL 1989 (United States, 3/1989). CEIL: 50 ppm CEIL: 125 mg/m³ACGIH TLV (United States, 1/2008). C: 100 mg/m³ Form: Aerosol

Form: [a]Aerosol [b]aerosol [c]Particulate [d]Vapour [e]vapour and mist

Ethylene glycol US ACGIH 1/2008 - - - - - - - 100 - [a]AB 6/2008 - - - - - - - 100 - [b]BC 6/2008 - - - - 100 - - - - [a]

- 10 - - 20 - - - - [c]- - - 50 - - - - - [d]

ON 6/2008 - - - - - - - 100 -QC 6/2008 - - - 50 127 - - - - [e]

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations

CeilingSTEL (15 mins)TWA (8 hours)Occupational exposure limits

132°C (269.6°F)Boiling/condensation point

Clear viscous liquid.

Not available.

7

-52°C (-61.6°F)

1.08 to 1.12

2.1 [Air = 1]

0.008 kPa (0.06 mm Hg)

Soluble in water, methanol, diethyl ether.

25 ppm

Not available.

Odorless.

Sweet.

Green.

Not available.

Not applicable.

Not available.

May be combustible at high temperature.

Non-flammable in the presence of the following materials or conditions: open flames, sparks and static discharge, heatand shocks and mechanical impacts


Dynamic: 21 mPa·s (21 cP)



Molecular weight

pH

Odour

Taste

Colour

Relative density

Vapor pressure

Vapour Density

Volatility

OdourThreshold

Viscosity

Solubility

The product is:


Flash point

Flammable limits


Evaporationrate



Not available.101.4 % (w/w) [ISO 11890-1]





Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.Avoid contamination with reactive substances.

Not available.


Stability




Acute toxicity


Chronic toxicity

Carcinogenicity

Classification

Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA


Canada

Ethylene glycol LC50 Inhalation Dusts andmists

Rat 2725 mg/m³ 4 hours

LD50 Dermal Rabbit 9500 mg/kg -LD50 Dermal Rabbit 9500 mg/kg -LD50 Dermal Rabbit 9530 uL/kg -LD50 Intraperitoneal Mouse 5614 mg/kg -LD50 Intraperitoneal Rat 5010 mg/kg -LD50 Intravenous Rat 3260 mg/kg -LD50 Oral Cat 1650 mg/kg -LD50 Oral Dog 5500 mg/kg -LD50 Oral Mouse 5500 mg/kg -LD50 Oral Rat 4000 mg/kg -LD50 Oral Rat 4700 mg/kg -LD50 Oral Rat 5000 mg/kg -LD50 Subcutaneous Rat 2800 mg/kg -LD50 Unreported Mouse 8050 mg/kg -LD50 Unreported Rabbit 5017 mg/kg -LD50 Unreported Rat 13 g/kg -

Ethylene glycol A4 - - - - -

Conclusion/Summary (Ethylene glycol) The most common effects seen from ingestion of ethylene glycol arecentral nervous system (CNS) depression (muscular incoordination, lethargy, coma) andharmful effects on the kidneys including inflammation, degeneration, tissue death(necrosis), tubule dilation and oxalate crystal or stone deposition.


Conclusion/Summary Exposure can cause dermatitis.




Mutagenicity


Teratogenicity




Not available.

(Ethylene Glycol) Embryotoxicity (late resorptions), fetotoxicity (reduced fetal bodyweight) and teratogenicity (external, soft tissue and skeletal defects) have been observedin rats and mice exposed to at high oral doses that caused no or minimal maternaltoxicity. The US National Toxicology Program-Center for the Evaluation of Risks toHuman Reproduction (NTP-CERHR) has also concluded that oral exposure to high dosesof ethylene glycol causes developmental toxicity in rats and mice.

Not available.

Section 12. Ecological information

For accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggestedinstructions.

Canada

:

Aquatic ecotoxicity


Biodegradability


Product/ingredient name Result Species ExposureEthylene glycol Acute EC50 >100 mg/L Daphnia 4 hours

Acute EC50 >100 mg/L Daphnia 4 hoursAcute IC50 >100 mg/L Algae 1 hoursAcute IC50 >100 mg/L Algae 1 hoursAcute LC50 >100000 ug/L Marine water Crustaceans - Crangon crangon -

Adult48 hours

Acute LC50 6900000 to 8800000 ug/LFresh water

Daphnia - Ceriodaphnia dubia -Neonate

48 hours

Acute LC50 >100 mg/L Fish 24 hoursAcute LC50 >100 mg/L Fish 24 hoursAcute LC50 8050000 ug/L Fresh water Fish - Pimephales promelas - <=7

days96 hours

Chronic NOEC 11610000 ug/L Freshwater

Daphnia - Ceriodaphnia dubia -<=24 hours

48 hours

Chronic NOEC 6090000 ug/L Freshwater

Fish - Pimephales promelas - <=7days

96 hours

Not available.

Ecotoxicity This product shows a low bioaccumulation potential.




The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-productsshould at all times comply with the requirements of environmental protection and waste disposal legislation and anyregional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers.

Waste information



Not applicable.

Class

Not a pollutant.




Special provisions

Class 9: Miscellaneous hazardous material.


Environmentally hazardous substance, liquid, n.o.s. (Ethylene glycol)

Not controlled under IMDG.

Not applicable.

Marine pollutant




Special provisions Not applicable.

Not applicable.Subsidiary class

-Subsidiary class

Not a TDG-controlled material.

-ClassSubsidiary class

Class


IMDG Classification


Not applicable.

Not applicable.Not applicable.


Not applicable.Not applicable.UN number

Packing Group

UN 3082

IIIUN numberPacking Group




Special provisions In single containers of 5000 lbs capacity or less this product isexempt from DOT regulations (not regulated). Does not requirelabel or placards.Reportable Quantity (RQ)= 5000 lbs (2268 kg) (as ethylene glycolFor bulk shipments equal to or greater than Reportable Quantity(RQ), please adhere to classification as outlined in DOTClassification section.



200B

00

2

Target organ effects






Health

Specific hazard

Reactivity

FlammabilityHealth

Flammability

Reactivity

Personal protection

Class D-1B: Material causing immediate and serious toxic effects(Toxic).Class D-2A: Material causing other toxic effects (Very toxic).






Printed 2013-05-01.



Solvent 3139 (Petroleum Distillat)

dry cleaning safety solvent; mineral spirits; varnoline; naphtha safetysolvent; white spirits

C9~C11 paraffin(85%) + aromatics(15%)

Solvent.

8052-41-3

SOLVENT 3139

Consumer products: Various.Other non-specified industry: DRY CLEANING; SPOT AND STAINREMOVAL.


Recochem Inc.850 Montee de LiesseMontreal, QuebecH4T 1P4(514) 341-3550www.recochem.com

Class B-3: Combustible liquid with a flash point between 37.8°C(100°F) and 93.3°C (200°F).Class D-2B: Material causing other toxic effects (Toxic).



Synonym

Chemical family

Chemical formula


Material uses


CAS #

In case ofemergency

Print date


2014-11-24.

This product may cause mild irritatation to eyes and skin upon contact.Prolonged and repeated contact with skin can cause drying of the skin resulting in irritation and dermatitis.Inflammation of the eye is characterized by mild redness, watering, and itching.Skin inflammation is characterized by mild itching, scaling, reddening.Ingestion can cause burning sensation, vomiting, drowsiness and in severe cases pulmonary edema.Inhalation of excessive amounts may result in impairment, such as drowsiness, lack of coordination, headache andnausea.

Aspiration hazard if swallowed. Can enter lungs and cause damage. Small amounts of liquid aspirated into therespiratory system during ingestion or from vomiting may cause mild to severe pulmonary injury and possible death.



Note to Physician

Emergency Overview

Combustible liquid and vapor. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contactwith skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use.

WARNING!COMBUSTIBLE LIQUID AND VAPOR.



Solvent 3139 (Petroleum Distillat)Page: 2/7Validated on 2014-11-20.



Canada


Stoddard solvent 8052-41-3 100






Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.


Use dry chemical, CO2, water spray (fog) or foam.

Container explosion may occur under fire conditions or when heated. Vapor may travel a considerable distance tosource of ignition and flash back. Vigorously supports combustion. Combustible when exposed to heat or flame.

Vapor may travel a considerable distance to source of ignition and flash back.




Fire Hazards

Explosion Hazards

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, orif water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.





Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceousearth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools andexplosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent materialmay pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section13 for waste disposal.


Do not store above the following temperature: 43°C (109.4°F). Store in accordance with local regulations. Store in asegregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources.Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that havebeen opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited inareas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Useonly with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areasand confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any otherignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparkingtools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate staticelectricity during transfer by grounding and bonding containers and equipment before transferring material. Emptycontainers retain product residue and can be hazardous. Do not reuse container.


Handling

Storage




Body

Respiratory

Hands

United States

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash goggles

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.






Canada

Stoddard solvent ACGIH TLV (United States, 1/2008). TWA: 100 ppm 8 hour(s). TWA: 525 mg/m³ 8 hour(s).OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 525 mg/m³ 8 hour(s).NIOSH REL (United States, 6/2008). TWA: 350 mg/m³ 10 hour(s). CEIL: 1800 mg/m³ 15 minute(s).OSHA PEL (United States, 11/2006). TWA: 500 ppm 8 hour(s). TWA: 2900 mg/m³ 8 hour(s).

No exposure limit value known.


153.9 to 202.2°C (309 to 396°F)Boiling/condensation point

Liquid.

100% (v/v), 100% (w/w)

Not available.

-58°C (-72.4°F)

0.78

5 [Air = 1]

0.29 kPa (2.2 mm Hg)

Easily soluble in the following materials: diethyl ether, n-octanol.Insoluble in the following materials: water.

Not available.

Not available.

KEROSENE-LIKE [Slight]

Not available.

Colorless.

Lower: 1%Upper: 13.3%

Closed cup: 38.85 to 42.85°C (101.9 to 109.1°F) [Tagliabue. (ASTM D56)]

232.22°C (450°F)

Combustible.


Kinematic: 0.0114 cm2/s (1.14 cSt)



Molecular weight

pH

Odour

Taste

Colour

Relative density

Vapor pressure

Vapour Density

Volatility

OdourThreshold

Viscosity

Solubility

The product is:


Flash point

Flammable limits

Evaporationrate



Not available.101.3 % (w/w) [ISO 11890-1]



Flammable in the presence of open flames, sparks and static discharge. This product is combustible if exposed to heator when in involved in a fire and in contact with combustible materials which may act as a wick.



Reactive with oxidizing agents.

Not available.


Stability




Acute toxicity


Chronic toxicity

Carcinogenicity

Mutagenicity


Teratogenicity




IDLH :


Canada

Not available.

Not available.

Not available.

20000 mg/m³




Section 12. Ecological information

For accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggestedinstructions.

Canada

:

Aquatic ecotoxicity

Ecotoxicity No known significant effects or critical hazards.




Biodegradability


Not available.

The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retainsome product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-productsshould at all times comply with the requirements of environmental protection and waste disposal legislation and anyregional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers.

Waste information



In containers of 450L or less this product is not classified as aDangerous Goods according to TDG exemption 1.33

Class

Not a pollutant.



Special provisions


PETROLEUM DISTILLATES, N.O.S.

Marine pollutant



Special provisions In containers of 5 L (5Kg) capacity or less this product is classifiedas a "Consumer Commodity" under IMDG regulations.

-Subsidiary class


-ClassSubsidiary class


IMDG Classification



UN 1268III


IIIUN 1268UN number

Packing Group



Combustible liquid.

Special provisions In containers of 450 L capacity or less this product is exempt fromDOT regulations (non regulated).



-Subsidiary class



Class

UN 1268

III


120G

02

1

Combustible liquidTarget organ effects






Health

Specific hazard

Reactivity

FlammabilityHealth

Flammability

Reactivity

Personal protection

Class B-3: Combustible liquid with a flash point between 37.8°C(100°F) and 93.3°C (200°F).Class D-2B: Material causing other toxic effects (Toxic).






Printed 2014-11-24.




Synonyms

Chemical Name

Chemical Formula

Chemical Family

Material Uses

Rust Inhibitor Aerosol (1043)

Rust Inhibitor (1043)

Not applicable.

Chemical mixture.

Hydrocarbons.

Multi-purpose rust inhibitor and lubricant.

WHMIS Protective Clothing TDG Road / Rail

Section I. Product Identification and Uses

Not available.

Not available.

Not applicable.

1043

Molecular Weight Not applicable.

Supplier Emergency Number CANUTEC ( 24 HR )(613)996-6666

Rust Check Corporation6175 Danville Road, Mississauga, Ontario L5T 2H7(905) 670-5411

CI#

DSL

CAS #

Code

Product Name

Section 2. Hazardous Ingredients

1) Petroleum Distillates, Light 8052-41-3 1-5 INHALE (LD50) ppm/kg: Acute: >1400 (Rat).2) Petroleum Distillates, Heavy 8008-20-6

64742-81-03-7 ORAL (LD50) mg/kg: Acute: >5000 (Rat).

3) Petroleum Distillates, Heavy 64742-54-764742-52-5

3-7 Not available.

4) Petroleum Distillates, Light 64742-53-6 3-7 Not available.5) Propane 74-98-6 5-15 Not available.6) Isobutane 75-28-5 5-10 GAS (LC50): Acute: 142500 ppm 4 hour(s) [Rat].

Name CAS # % by Weight LC50/LD50


Volatility

pH (1% Soln/Water)

Odor

Color

Melting Point

Boiling Point

Taste

Vapor Pressure

Odor Threshold

Density

Vapor Density

LogKow

Ionicity (Surface ActiveAgent)

Liquid (Aerosol Concentrate).

Not available.

Aerosol Portion: Not applicable.Liquid Portion: Not available.

Red.

Not available.

Aerosol Portion: -42.1 to -0.5°C.Liquid Portion: Not available.

0.850 - 0.875 @ 20°C (Water = 1).

Greater than1.0 (Air = 1.0)

The highest known value is 7 mm of Hg (@ 20°C) (Petroleum distillate).

Not available.

Not available.

Characteristic.

Not available.

Propane: 22,000 mg/m3

Critical Temperature Not available.

Instability Temperature Not available.

Section 3. Physical Data

Evaporation Rate Aerosol Portion: faster than butyl acetate;Immediate at temperatures above -35°C.Liquid Portion: slower than butyl acetate.

Continued on Next Page

Rust Inhibitor (1043) Page Number: 2


A B-5 D-2B CONSUMER COMMODITY.

Dispersion Properties

Solubility

Not available.

Not available.

Conditions of Instability No additional remark.

The Product is:

Auto-ignitionTemperature

Products of Combustion

Flash Points

Extinguishing Media

Flammable Limits

Flammability

Not available.

Extremely Flammable Aerosol

These products are carbon oxides (CO, CO2), sulfur and other irritating gases.

Not available.

Not available.

SMALL FIRE: Use DRY chemicals, carbon dioxide or foam.LARGE FIRE: Use foam or water fog.Cool containing vessels with water spray in order to prevent pressure build-up, autoignition or explosion. Avoidspreading burning liquid with water used to cool containers.Self-contained respiratory protection should be provided for firefighters.

The flammability of an aerosol by WHMIS definition is determined by its flame-extension or its flashback. Theflame-extension of this product is greater than 45 cm. FIRE CODE: Level 3 Aerosol (as per NFPA 30B).Do not use in the presence of open flame or spark.Do not place in hot water or near radiators, stoves or other sources of heat.

Risks of Explosion Risk of explosion of the product in presence of mechanical impact: Do not subject aerosol cans to impact.Risk of explosion of the product in the presence of static discharge: Aerosol spray may be sensitive to staticdischarge due to flammable concentrate and flammable propellant. Vapours of this product may form aflammable/explosive mixture with air in enclosed areas and come into contact with open flames, sparks or staticdischarge.Do NOT expose aerosol containers to open flames, heat or ignition sources.Container may explode if heated.

Section 4. Fire and Explosion Data

Hazardous DecompositionProducts

Stability

Corrosivity

Products of Degradation

Reactivity

Degradability


These products are carbon oxides (CO, CO2), sulfur and other irritating gases.

Not available.

Not available.

No specific information is available in our database regarding the corrosivity of this product in presence of variousmaterials.

Avoid contact with strong oxidizing agents, strong acids and strong alkalies.Keep away from heat, sparks, open flame and all possible ignition sources.

Section 5. Reactivity

Not available.

No additional remark.Conditions of Instability

Not available.Instability Temperature





Toxicity to Animals

Acute Effects onHumans

Routes of Entry

Chronic Effects onHumans

Ingestion. Inhalation. Skin contact. Eye contact.

WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE.Acute oral toxicity (LD50): >8000 mg/kg [Rat]. (Petroleum distillate).Acute toxicity of the gas (LC50): 142500 ppm 4 hour(s) [Rat]. (Isobutane).Acute toxicity of the vapor (LC50): >5900 ppm 4 hour(s) [Rat]. (Petroleum distillate).

EYE CONTACT: May cause redness.SKIN CONTACT: Prolonged or repeated contact may cause irritation.INHALATION: May cause chemical pneumonitis if sprayed and mist is inhaled into lungs.INGESTION: May cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into thelungs may cause chemical pneumonitis, which can be fatal.Can be fatal if inhaled or ingested. This product may irritate eyes and skin upon contact.

Prolonged or repeated skin contact may lead to dermatitis.

TLV Petroleum distillateTWA: 300 (ppm) from ACGIH (TLV)

PropaneSimple asphyxiant.

Consult local authorities for acceptable exposure limits.

Section 6. Toxicological Properties

Synergetic Products(Toxicologically)

Not available.

Irritation/Corrosivity Not available.

Sensitization None known.

Carcinogenic Effects No ingredients listed as carcinogens by IARC OR ACGIH.

Toxic Effects onReproduction

DEVELOPMENTAL TOXICITY: Not available.

Teratogenic Effects TERATOGENIC EFFECTS: Not available.

Mutagenic Effects MUTAGENIC EFFECTS: Not available.

Storage

Precautions

Small Spill and Leak

Large Spill and Leak

Protective Clothing

Store in a cool, dry place. Do not place in hot water or near radiators, stoves or other sources of heat. Do notpuncture or incinerate container or store at temperatures over 50°C or in direct sunlight.

Ventilate area and eliminate all sources of ignition. Keep away from heat. Absorb with an inert DRY material andplace in an appropriate waste disposal container.

Not applicable for aerosol containers.

Not applicable for aerosol containers.

Contents under pressure. Container may explode if heated. Direct inhalation of spray may be harmful. Keep out ofreach of children.

Section 7. Preventive Measures

Recommend Safety glasses, chemical resistant gloves and NIOSHApproved respirator for organic mists and vapours.

Engineering Controls Use under well-ventilated conditions.

Personal ProtectiveEquipment





Waste Disposal Recycle to process, if possible. Consult your local or regional authorities. Do not dispose in sewers. When containeris empty, press button to release all pressure, then dispose of in garbage can.

Handling Do not use in the presence of open flame, sparks or ignition sources. Keep away from heat. Avoid breathing vapoursor spray mists. If ingested, seek medical advice immediately and show the container or the label. Avoid contact withskin and eyes. After handling, always wash hands thoroughly with soap and water.

Not available.Special ShippingInformation

No additional information.


Flush eyes with plenty of running water for at least 15 minutes, lifting upper and lower lids, occasionally. Get medicalattention.

Remove affected person to fresh air. If breathing is difficult, administer oxygen. If breathing stops give artificialrespiration. Get medical attention.


If swallowed, call physician or poison control centre immediately. DO NOT induce vomiting. Rinse mouth with water.Aspiration of material into lungs due to vomiting may cause chemical pneumonitis which can be fatal.

Eye Contact

Skin Contact

Hazardous Inhalation

Slight Inhalation

Slight Ingestion

Hazardous Ingestion

Wash thoroughly with soap and water. If irritation persists, get medical attention. Remove contaminated clothing andwash before reuse.

Section 8. First Aid

Hazardous SkinContact

Section 9. MSDS PreparationReferences Not available.

Validated by Regulatory Affairs Dept. on April 10, 2015

Emergency Phone: (905) 670-5411 , (613)996-6666 , 1-800-265-0790

No additional remark.

CONSUMER COMMODITY.

WHMIS WHMIS CLASS A: Compressed gas.WHMIS CLASS B-5: Flammable aerosol.WHMIS CLASS D-2B: Material causing other toxic effects (TOXIC).

Not applicable.

TDG Road /Rail

Classification

ResponsableName/Telephone No.





To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any ofits subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Finaldetermination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards andshould be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazardsthat exist.


Safety Data Sheet* Trusted Quality Since 1921 *

www.rustoleum.com

1. Identification

Product Name: ENAMEL 1-GL 2PK FLAT WHITE Revision Date: 8/14/2014

Product Identifier: 2764402 Supercedes Date: 8/13/2014


Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA

Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA


24 Hour Hotline: 847-367-7700Emergency Telephone:


EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.

Classification

Symbol(s) of Product

Signal Word

Danger

GHS HAZARD STATEMENTSFlammable liquid, category 4 H227 Combustible liquid

Organic Peroxide, categories C, D H242 Heating may cause a fire.

Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.

Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.

Skin Irritation, category 2 H315 Causes skin irritation.

Eye Irritation, category 2B H320 Causes eye irritation.

Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.

STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.

STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.

GHS PRECAUTIONARY STATEMENTSP102 Keep out of reach of children.

P103 Read label before use.

P202 Do not handle until all safety precautions have been read and understood.

P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

P220 Keep/Store away from clothing/…/combustible materials.

P234 Keep only in original container.

Page 1 / 6


P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P262 Do not get in eyes, on skin, or on clothing.

P264 Wash … thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

P285 In case of inadequate ventilation wear respiratory protection.

P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see … on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P351 Rinse cautiously with water for several minutes.

P352 Wash with plenty of soap and water.

P362 Take off contaminated clothing and wash before reuse.

P374 Fight fire with normal precautions from a reasonable distance.

P402 Store in a dry place.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.

P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.

P420 Store away from other materials.

P501 Dispose of contents/container to …


HAZARDOUS SUBSTANCES

Chemical Name CAS-No. Wt.%Range

GHS Symbols GHS Statements

Limestone 10-251317-65-3

Stoddard Solvents 10-25 GHS02 H2248052-41-3

Titanium Dioxide 10-2513463-67-7

Mineral Spirits 10-25 GHS06 H33164742-88-7

The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.



FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: If swallowed, get medical attention.


EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Combustible liquid and vapor. No unusual fire or explosion hazards noted.

Page 2 / 6


SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.


STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing. Avoid contact with eyes.

STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Avoid excess heat.



ACGIH TLV-TWA

ACGIH TLV-STEL

OSHA PEL-TWAOSHA PEL-

CEILING

Limestone 1317-65-3 20.0 N.E. N.E.15 mg/m3 [Total

Dust]N.E.

Stoddard Solvents 8052-41-3 20.0 100 ppm N.E. 500 ppm N.E.

Titanium Dioxide 13463-67-7 15.0 10 mg/m3 N.E.15 mg/m3 [Total

Dust]N.E.

Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.

PERSONAL PROTECTION




SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.


OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.

Page 3 / 6



Appearance: Liquid Physical State: Liquid

Odor: Solvent Like Odor Threshold: N.E.

Relative Density: 1.359 pH: N.A.

Freeze Point, °C: N.D. Viscosity: N.D.

Solubility in Water: Negligible Partition Coefficient, n-octanol/water: No Information

Decompostion Temp., °C: No Information

Boiling Range, °C: 212 - 400 Explosive Limits, vol%: 0.7 - 8.9

Flammability: Supports Combustion Flash Point, °C: 40

Evaporation Rate: Slower than Ether Auto-ignition Temp., °C: No Information

Vapor Density: Heavier than Air Vapor Pressure: N.D.

(See "Other information" Section for abbreviation legend)


CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition.


HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.



11. Toxicological information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. Substance causes moderate eye irritation.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.

EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to the nose, throat and respiratory tract. Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)


ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat

N.I. - No Information


ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.


DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.

Page 4 / 6



Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. 1263 1263 N.A.

Proper Shipping Name: Not Regulated Paint Paint Not Regulated

Hazard Class: N.A. 3 3 N.A.

Packing Group: N.A. III III N.A.

Limited Quantity: No Yes, >5L No Yes, >5L No No






Sara Section 313:



Toxic Substances Control Act:


No TSCA components exist in this product.

Inventory Information

Country ValueUSA (TSCA) No InformationCanada (DSL) No InformationMexico(INSQ) No InformationEurope (EINECS) No InformationJapan (ENCS) No InformationPhilippines (PICCS) No InformationChina (IECSC) No InformationAustralia (AICS) No InformationKorea (KECI) No InformationNew Zealand (NZIOC) No Information

No Information

CALIFORNIA PROPOSITION 65:

Warning: This products contains a substance known to the State of California to cause cancer.

Chemical Name CAS-No.

Titanium Dioxide 13463-67-7

Page 5 / 6


CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS

Warning: This product contains a substance known to the State of California to cause birth defects or other reproductiveharm.

No Proposition 65 Reproductive Toxins exist in this product.


CANADIAN WHMIS:

This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.


HMIS RATINGS


CANADIAN WHMIS CLASS: B3 D2A

NFPA RATINGS



MSDS REVISION DATE: 8/14/2014

REASON FOR REVISION: No Information


Text for GHS Hazard Statements shown in Section 3 describing each ingredient:

H224 Extremely flammable liquid and vapour.H331 Toxic if inhaled.

Icons for GHS Pictograms shown in Section 3 describing each ingredient:

GHS02

GHS06

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

Page 6 / 6



www.rustoleum.com

1. Identification

Product Name: ENAMEL 1-GL 2PK HIGH GLOSS WHITE Revision Date: 8/15/2014








EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Use ventilation necessary to keep exposures below recommended exposure limits, if any.

Classification


Signal Word

Danger
















Page 1 / 7



































Ethylbenzene 0.1-1.0 GHS02-GHS07 H225-332100-41-4









UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted. Closed containers may explode when exposed to extreme heat due to buildup of steam. Combustible liquid and vapor.

Page 2 / 7




STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.

STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Avoid excess heat.



ACGIH TLV-TWA

ACGIH TLV-STEL


CEILING



Dust]N.E.

Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.

PERSONAL PROTECTION




SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.


OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.


Page 3 / 7





Relative Density: 1.066 pH: N.D.


Solubility in Water: Slight Partition Coefficient, n-octanol/water: No Information



Flammability: Does not Support Combustion Flash Point, °C: 40





CONDITIONS TO AVOID: Avoid all possible sources of ignition. Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases.







EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Substance may cause slight skin irritation.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.

EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Irritating to the nose, throat and respiratory tract. Harmful if swallowed.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)




13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat






Page 4 / 7














Sara Section 313:



Ethylbenzene 100-41-4






No Information




Titanium Dioxide 13463-67-7Ethylbenzene 100-41-4

Page 5 / 7






CANADIAN WHMIS:



HMIS RATINGS



NFPA RATINGS







H224 Extremely flammable liquid and vapour.H225 Highly flammable liquid and vapour.H331 Toxic if inhaled.H332 Harmful if inhaled.


GHS02

GHS06

GHS07

Page 6 / 7



Page 7 / 7


Safety Data Sheetwww.toughandeasyfloors.com

1. Identification

Product Name: ENAMEL 1-GL 2PK SEMIGL WHITESEMIGLOSS

Revision Date: 9/17/2014



Supplier: Rust-Oleum Industrial Flooring11 Hawthorn ParkwayVernon Hills, IL 60061USA

Manufacturer: Rust-Oleum Industrial Flooring11 Hawthorn ParkwayVernon Hills, IL 60061USA




EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Flammable liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation.

Classification


Signal Word

Danger

GHS HAZARD STATEMENTSFlammable Liquid, category 2 H225 Highly flammable liquid and vapour.

Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.



Eye Irritation, category 2 H319 Causes serious eye irritation.










Page 1 / 7


















P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skinwith water/shower.

P370+P378 In case of fire: Use … for extinction.

P403+P235 Store in a well-ventilated place. Keep cool.






P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.





P410 Protect from sunlight.








Stoddard Solvent 25-50 GHS02 H2248052-41-3


Limestone 10-251317-65-3


Talc 2.5-1014807-96-6



Page 2 / 7






FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.



UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted. Closed containers may explode when exposed to extreme heat due to buildup of steam. Isolate from heat, electrical equipment, sparks and open flame.



STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.

STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Avoid excess heat. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids.



ACGIH TLV-TWA

ACGIH TLV-STEL


CEILING

Stoddard Solvent 8052-41-3 30.0 100 ppm N.E. 500 ppm N.E.


Dust]N.E.

Limestone 1317-65-3 15.05 mg/m3(NIOSH,

Respirable Dust)N.E.

15 mg/m3 [TotalDust]

N.E.


Talc 14807-96-6 5.0 2 mg/m3 N.E.0.1 mg/m3

[Respirable]N.E.

Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.

PERSONAL PROTECTION


Page 3 / 7




SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.


OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.












Vapor Density: Heavier than air Vapor Pressure: N.D.



CONDITIONS TO AVOID: Avoid all possible sources of ignition. Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases.






EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Causes skin irritation. Allergic reactions are possible.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.

EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if swallowed.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.


Page 4 / 7













Proper Shipping Name:Paint Products inLimited Quantities

Paint PaintPaint Products inLimited Quantities



Limited Quantity: Yes Yes Yes Yes






Sara Section 313:







Page 5 / 7




No Information









CANADIAN WHMIS:



HMIS RATINGS



NFPA RATINGS






Page 6 / 7





GHS02

GHS06

GHS07

Rust-Oleum Industrial Flooring believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Industrial Flooring makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

Page 7 / 7



www.rustoleum.com

1. Identification

Product Name: ENAMEL 5-GL HIGH GLOSS BLACK Revision Date: 8/13/2014

Product Identifier: 634300 Supercedes Date: New SDS







EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Flammable liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.

Classification


Signal Word

Danger

GHS HAZARD STATEMENTSFlammable Liquid, category 2 H225 Highly flammable liquid and vapour.


Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.




Eye Irritation, category 2 H319 Causes serious eye irritation.








Page 1 / 7





P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.












P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skinwith water/shower.


P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing.




P337+P313 If eye irritation persists: Get medical advice/attention.




P370+P378 In case of fire: Use … for extinction.




P403+P235 Store in a well-ventilated place. Keep cool.


P410 Protect from sunlight.










Carbon Black 1.0-2.5 GHS02 H2511333-86-4





Page 2 / 7




FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.


EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. No unusual fire or explosion hazards noted.



STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.



STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.



ACGIH TLV-TWA

ACGIH TLV-STEL


CEILING

Stoddard Solvents 8052-41-3 40.0 100 ppm N.E. 500 ppm N.E.Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Carbon Black 1333-86-4 5.0 3 mg/m3 N.E. 3.5 mg/m3 N.E.Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.

PERSONAL PROTECTION






Page 3 / 7























EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Causes skin irritation. Allergic reactions are possible.


EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.

Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula. IARC lists Ethylbenzene as a possible human carcinogen (group 2B).




64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat

Page 4 / 7









UN Number: 1263 1263 1263 1263

Proper Shipping Name: Paint Paint Paint Paint

Hazard Class: 3 3 3 3

Packing Group: III III III III

Limited Quantity: No No No No






Sara Section 313:







Page 5 / 7




No Information




Carbon Black 1333-86-4Ethylbenzene 100-41-4





CANADIAN WHMIS:



HMIS RATINGS



NFPA RATINGS






Page 6 / 7



H224 Extremely flammable liquid and vapour.H225 Highly flammable liquid and vapour.H251 Self-heating: may catch fire.H331 Toxic if inhaled.H332 Harmful if inhaled.


GHS02

GHS06

GHS07


Page 7 / 7



www.rustoleum.com

1. Identification

Product Name: ENAMEL 5-GL HIGH GLOSS WHITE Revision Date: 8/14/2014

Product Identifier: 2766300 Supercedes Date: New SDS







EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.

Classification


Signal Word

Danger
















Page 1 / 7











































EXTINGUISHING MEDIA: Dry Chemical, Dry Sand, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Combustible liquid and vapor. No unusual fire or explosion hazards noted.

Page 2 / 7




STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.



STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Avoid excess heat.



ACGIH TLV-TWA

ACGIH TLV-STEL


CEILING



Dust]N.E.

Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.

PERSONAL PROTECTION








Page 3 / 7






















EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation.


EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to the nose, throat and respiratory tract. Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)










Page 4 / 7














Sara Section 313:









No Information





Page 5 / 7






CANADIAN WHMIS:



HMIS RATINGS



NFPA RATINGS









GHS02

GHS06

GHS07

Page 6 / 7



Page 7 / 7



24 Hour Assistance:

1-847-367-7700

Rust-Oleum Corp.

www.rustoleum.com

1. Identification

8/7/2012Product Name: ENAMEL QT 4PK GLOSS WHITE Revision Date:



Rust-Oleum Corporation

11 Hawthorn Parkway

Vernon Hills, IL 60061

USA


11 Hawthorn Parkway


USA




EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract.

Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea.



EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor

concentrations are irritating to the eyes, nose, throat and lungs.

EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can

enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational

overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has

been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in

humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists

Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group

2B-"Possibly carcinogenic to humans" by IARC. Significant exposure is not anticipated during brush application or drying. Risk of

overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual

concentration of Titanium Dioxide in the formula.



Chemical Name CAS-No.Weight %

Less Than

ACGIH TLV-

TWA

ACGIH TLV-

STELOSHA PEL-TWA

OSHA PEL-

CEILING



Dust]N.E.

Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.


Amorphous Silica 7631-86-9 1.0 N.E. N.E. 0.8 mg/m3 N.E.

Page 1 / 4



FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical

attention. Do NOT allow rubbing of eyes or keeping eyes closed.


FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

immediate medical attention. Do NOT use mouth-to-mouth resuscitation.

FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the

lungs and cause severe lung damage. Get immediate medical attention.





SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible

autoignition or explosion. Evacuate area and fight fire from a safe distance.


STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use

combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate

closed containers.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is

emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.

STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat,

sparks, flame and sources of ignition. Keep container closed when not in use.


ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne

levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must

be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an

organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to

exceed exposure limits.

Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an

uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide

adequate protection.

SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or

Neoprene gloves may afford adequate skin protection.


OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal

protective equipment and its application.

Page 2 / 4




Vapor Density Heavier than Air Odor: Solvent Like



Specific Gravity: 1.071 pH: N.D.






HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits

acrid smoke and irritating fumes.






Titanium Dioxide >7500 mg/kg (Rat, Oral) N.E.



Amorphous Silica >7500 mg/kg (Rat) >250 mg/m3 (Rat, 6Hr)




DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow

to enter storm drains or sewer systems.



Proper Shipping Name: Paint Paint Paint

Hazard Class: 3 3 3

UN Number: UN1263 UN1263 UN1263

Packing Group: III III III

Limited Quantity: No Yes Yes


Page 3 / 4




This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the

Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to

meet the following categories:

Fire Hazard, Acute Health Hazard

SARA SECTION 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund

Amendment and Reauthorization Act of 1986 and 40 CFR part 372:



This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from

the United States:



CANADIAN WHMIS:


Canadian WHMIS Class: B3 D2A D2B


HMIS Ratings:


NFPA Ratings:






Page 4 / 4



24 Hour Assistance:

1-847-367-7700

Rust-Oleum Corp.

www.rustoleum.com

1. Identification

8/7/2012Product Name: ENAMEL QT 4PK GLOSS SAFETY ORANGE Revision Date:




11 Hawthorn Parkway


USA


11 Hawthorn Parkway


USA




EMERGENCY OVERVIEW: Suspect cancer hazard. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and

respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness,

headache or nausea.



EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor

concentrations are irritating to the eyes, nose, throat and lungs.

EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can

enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational

overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has

been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in

humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists

Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group

2B-"Possibly carcinogenic to humans" by IARC. Significant exposure is not anticipated during brush application or drying. Risk of

overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual

concentration of Titanium Dioxide in the formula. Suspect cancer hazard--contains material which may cause cancer.



Chemical Name CAS-No.Weight %

Less Than

ACGIH TLV-

TWA

ACGIH TLV-

STELOSHA PEL-TWA

OSHA PEL-

CEILING



Pigment Orange 5 3468-63-1 5.0 N.E. N.E.5 mg/m3

(Respirable Dust)N.E.

Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.



Dust]N.E.

Page 1 / 4



FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical

attention. Do NOT allow rubbing of eyes or keeping eyes closed.


FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

immediate medical attention. Do NOT use mouth-to-mouth resuscitation.

FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the

lungs and cause severe lung damage. Get immediate medical attention.





SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible

autoignition or explosion. Evacuate area and fight fire from a safe distance.


STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use

combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate

closed containers.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is

emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.

STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat,

sparks, flame and sources of ignition. Keep container closed when not in use.


ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne

levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must

be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an

organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to

exceed exposure limits.

Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an

uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide

adequate protection.

SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or

Neoprene gloves may afford adequate skin protection.


OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal

protective equipment and its application.

Page 2 / 4




Vapor Density Heavier than Air Odor: Solvent Like









HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits

acrid smoke and irritating fumes.







Pigment Orange 5 >10,000 mg/kg (Rat, Oral) N.E.



Titanium Dioxide >7500 mg/kg (Rat, Oral) N.E.




DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow

to enter storm drains or sewer systems.







Limited Quantity: No Yes Yes

Page 3 / 4





This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the

Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to

meet the following categories:


SARA SECTION 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund

Amendment and Reauthorization Act of 1986 and 40 CFR part 372:



This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from

the United States:



CANADIAN WHMIS:


Canadian WHMIS Class: B3 D2B


HMIS Ratings:


NFPA Ratings:






Page 4 / 4


according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)



1/9


Product information

Trade name : OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)


: Insect Repellent





Emergency Overview Appearance / Odor : yellow / liquid / pleasant

Immediate Concerns

: Caution FLAMMABLE: CAUSES EYE IRRITATION. Keep away from heat, sparks and flame. Avoid contact with eyes and lips.

Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.

Eyes : Causes:

Moderate eye irritation

Skin : May cause skin reactions in rare cases. Prolonged or repeated contact may dry skin and cause irritation.

Inhalation : May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects.

Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Causes headache, drowsiness or other effects to the central






2/9

nervous system.

Aggravated Medical Condition

: Persons with pre-existing skin disorders may be more susceptible to irritating effects. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects Do not apply to cuts or irritated skin.


Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:

Chemical Name CAS-No. Weight percent

Ethyl alcohol 64-17-5 30.00 - 60.00

N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00

For additional information on product ingredients, see www.whatsinsidescjohnson.com.


Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists.

Skin contact : Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. If you suspect a reaction to this product, discontinue use and remove contaminated clothing.

Inhalation : Remove to fresh air.

Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.


Suitable extinguishing media

: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.






3/9

Specific hazards during firefighting

: Flammable liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Burns with colourless flame. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses.

Further information : Fight fire from maximum distance or protected area. Cool and

use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

Flash point : 25 °C

77 °F Method: Tag Closed Cup (TCC)




Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment.

Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment.

Methods for cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site.


Handling






4/9

Advice on safe handling : Avoid contact with eyes and lips. Avoid breathing vapors, mist or gas. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection against fire and explosion

: Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.

Storage

Requirements for storage areas and containers

: Keep away from food, drink and animal feedingstuffs. Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.


Occupational Exposure Limits

Components CAS-No. mg/m3

ppm

Non-standard

units

Basis

Ethyl alcohol 64-17-5 -

1,000 ppm

-

ACGIH STEL


Respiratory protection

Use only with adequate ventilation. Do not spray in enclosed areas.

Hand protection

: No special requirements.

Eye protection

Safety glasses with side-shields

Skin and body protection


Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.


Form : liquid






5/9

Color : yellow

Odor : pleasant

pH : 7.5

Boiling point : 75 °C

Boiling point : 167 °F

Freezing point : no data available

Flash point : 25 °C 77 °F Method: Tag Closed Cup (TCC)

Evaporation rate : no data available

Autoignition temperature : no data available



Vapour pressure : no data available

Density : 0.930 g/cm3 at 21 °C

Water solubility : dispersible


: no data available


Conditions to avoid : Heat, flames and sparks.

Materials to avoid : Do not mix with oxidizing agents. Avoid contact with: Oxidizing agents Natural Rubber Plastic Aluminium


: Thermal decomposition can lead to release of irritating gases and vapours.






6/9

Hazardous reactions : Stable under recommended storage conditions.


Acute oral toxicity : LD50 estimated > 2,000 mg/kg

Acute inhalation toxicity : LC50

estimated > 2.07 mg/l

Acute dermal toxicity : LD50

estimated > 5,000 mg/kg


Mutagenicity : no data available

Reproductive effects : no data available


Sensitisation : Substances is not a sensitizer.


Ecotoxicity effects : no data available






7/9


PESTICIDAL WASTE: Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.

RCRA waste class : D001 (Ignitable Waste)


Land transport

U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1993 Flammable liquids, n.o.s.

Class: 3

UN number 1993 Packaging group: II Note: Limited quantities derogation may be applicable to this product,

please check transport documents.

Sea transport

IMDG: Proper shipping name UN 1993 Flammable liquids, n.o.s. Class: 3 UN number: 1993 Packaging group: II EmS: F-E, S-E Note: Limited quantities derogation may be applicable to this product,


Air transport

ICAO/IATA:

Proper shipping name UN 1993 Flammable liquids, n.o.s. Class: 3 UN/ID No.: UN 1993 Packaging group: II Note: SC Johnson typically does not ship products via air. Refer to

IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air.






8/9



California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.

Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.


HMIS Ratings

Health 2

Flammability 3

Reactivity 0

NFPA Ratings

Health 2

Fire 3

Reactivity 0

Special -

Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)






9/9


OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)



1/10


Product information

Trade name : OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)


: Insect Repellent





Emergency Overview Appearance / Odor : clear / aerosol / Alcohol Odor

Immediate Concerns

: Caution FLAMMABLE: CAUSES EYE IRRITATION. Harmful if swallowed. Keep away from heat, sparks and flame. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Avoid contact with eyes and lips. Contents under pressure.


Eyes : Causes: Moderate eye irritation

Skin : May cause skin reactions in rare cases.

Inhalation : May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects.





2/10

Ingestion : Harmful if swallowed.

Causes headache, drowsiness or other effects to the central nervous system.


: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects Do not apply to cuts or irritated skin.



Chemical Name CAS-No. Weight percent

Ethyl alcohol 64-17-5 30.00 - 60.00

N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00

Butane 106-97-8 1.00 - 5.00

Propane 74-98-6 1.00 - 5.00

Isobutane 75-28-5 1.00 - 5.00



Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists.

Skin contact : Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. If you suspect a reaction to this product, discontinue use and remove contaminated clothing.

Inhalation : Remove to fresh air. If breathing is affected, get medical attention.






3/10





: Burns with colourless flame. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses.


use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

Flash point : -7 °C

19.4 °F



NFPA Classification : NFPA Level 2 Aerosol


Personal precautions : Remove all sources of ignition. Wear personal protective equipment.


Methods for cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site.





4/10


Handling

Advice on safe handling : Do not puncture or incinerate. Avoid contact with eyes and lips. Avoid breathing vapors, mist or gas. For personal protection see section 8. Do not spray toward face. Do not use in areas without adequate ventilation. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Smoking, eating and drinking should be prohibited in the application area.


: Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.

Storage


: Keep away from food, drink and animal feedingstuffs. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Keep in a dry, cool and well-ventilated place.

Other data : Stable under recommended storage conditions.





5/10




ppm

Non-standard

units

Basis


1,000 ppm

-

ACGIH STEL

Butane 106-97-8 -

1,000 ppm

-

ACGIH TWA

Propane 74-98-6 -

1,000 ppm

-

ACGIH TWA

Isobutane 75-28-5 -

1,000 ppm

-

ACGIH TWA



Use only with adequate ventilation. Do not spray in enclosed areas.

Hand protection


Eye protection

Safety glasses with side-shields



Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area.


Form : aerosol

Color : clear

Odor : Alcohol Odor

pH : no data available





6/10

Boiling point : no data available


Flash point : -7 °C

19.4 °F


Flammability (solid, gas) : no data available

Auto-ignition temperature : no data available




Density : no data available

Water solubility : slightly soluble


: no data available

Viscosity, dynamic : no data available

Viscosity, kinematic : no data available

Relative vapor density : no data available


: 64.2 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations



Materials to avoid : Strong oxidizing agents







7/10

Thermal decomposition : Note: no data available



Acute oral toxicity : LD50 Measured 3,735 mg/kg


Measured > 2.18 mg/l


Measured > 2,000 mg/kg


Mutagenicity : None Anticipated Reproductive effects : no data available


Sensitisation : Substances is not a sensitizer.







8/10




Land transport

U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1

Class: 2.1

UN number 1950 Packaging group: None. Note: Limited quantities derogation may be applicable to this product,


Sea transport

IMDG: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: Limited quantities derogation may be applicable to this product,


Air transport

ICAO/IATA: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN/ID No.: UN 1950 Packaging group: None. Note: SC Johnson typically does not ship products via air. Refer to






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Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.





HMIS Ratings

Health 2

Flammability 4

Reactivity 0

NFPA Ratings

Health 2

Fire 4

Reactivity 0

Special -







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RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)


Revision Date 10/07/2014 MSDS Number 350000004124


Product information

Trade name : RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)


: Insecticide





Emergency OverviewAppearance / Odor : off-white / aerosol / characteristic

Immediate Concerns

: Warning Avoid contact with skin, eyes and clothing. Avoid breathing vapours, mist or gas. Keep away from heat, sparks and flame. Harmful if absorbed through skin. Toxic by inhalation. Contents under pressure. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. May be harmful if swallowed.


Eyes : May cause:

Mild eye irritation

Skin : May cause skin reactions in rare cases. Harmful if absorbed through skin. May cause systemic effects.

Inhalation : Excessive exposures may affect human health, as follows:

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Harmful if inhaled. May cause systemic effects. Inhalation may cause central nervous system effects.

Ingestion : Aspiration hazard if swallowed - can enter lungs and cause damage. Causes headache, drowsiness or other effects to the central nervous system.


: None known.



Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 10.00 - 30.00 Isobutane 75-28-5 5.00 - 10.00 Propane 74-98-6 5.00 - 10.00 n-Octyl bicycloheptene dicarboximide

113-48-4 0.10 - 1.00

Permethrin 52645-53-1 0.10 - 1.00 d-(Cis/Trans) Allethrin 584-79-2 0.0001 - 0.10

For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES

Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.

Skin contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention immediately. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Inhalation : Remove to fresh air. If breathing is affected, get medical attention. If not breathing, give artificial respiration. Get medical attention immediately.


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: Aerosol Product - Containers may rocket or explode in heat of fire. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Burns with colourless flame.


use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

Flash point : < -7 °C

< 19.4 °F Method: Tag Closed Cup (TCC) Note: Propellant

Lower explosion limit : Note: No data available

Upper explosion limit : Note: No data available

NFPA Classification : NFPA Level 1 Aerosol 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove all sources of ignition. Wear personal protective equipment.


Methods for cleaning up : Soak up with inert absorbent material. If damage occurs to aerosol can: Sweep up and shovel into suitable containers for disposal. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site.

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Handling

Advice on safe handling : Do not puncture or incinerate. Do not enter places where used or stored until adequately ventilated. Avoid breathing vapours, mist or gas. Do not spray toward face. Do not use in areas without adequate ventilation. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Smoking, eating and drinking should be prohibited in the application area.


: Keep away from heat and sources of ignition.

Storage


: Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place.




ppm

Non-standard

units

Basis


1,000 ppm

-

ACGIH STEL

Isobutane 75-28-5 -

1,000 ppm

-

ACGIH STEL

Propane 74-98-6 -

1,000 ppm

-

ACGIH TWA



Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection. Do not spray in enclosed areas.

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Hand protection

: Rubber gloves

Eye protection

No special requirements.



Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area.


Form : aerosol

Color : off-white

Odor : characteristic

pH : 8.6 - 9.5

Melting point : No data available

Boiling point : 78 - 100 °C

Freezing point : No data available

Flash point : < -7 °C < 19.4 °F Method: Tag Closed Cup (TCC) Propellant

Evaporation rate : No data available

Auto-ignition temperature : No data available

Lower explosion limit : No data available

Upper explosion limit : No data available

Vapour pressure : estimated86.66 hPa

Density : 0.88 - 0.92 g/cm3

Water solubility : negligible


: No data available

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Materials to avoid : Strong acids Do not mix with oxidizing agents.

Materials to avoid : Strong oxidizing agents Do not mix with bleach or any other household cleaners. Strong bases




Hazardous reactions : If accidental mixing occurs and toxic gas is formed, exit area

immediately. Do not return until well ventilated.


Acute oral toxicity : LD50 estimated 500 - 5,000 mg/kg

Acute inhalation toxicity : No data available

Acute dermal toxicity : No data available

Chronic effects Carcinogenicity : None Anticipated Mutagenicity : None Anticipated Reproductive effects : None Anticipated

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Teratogenicity : None Anticipated

Sensitisation : No data available


Ecotoxicity effects : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.




Land transport

U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name AEROSOLS, Flammable, 2.1 Class: 2.1 UN number 1950 Packaging group: None. Note: SC Johnson ships this product as "Limited Quantity" when the

container quantity value is 1 Liter or less.

Sea transport

IMDG: Proper shipping name AEROSOLS, Flammable, 2.1 Class: 2 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: SC Johnson ships this product as "Limited Quantity" when the

container quantity value is 1 Liter or less.

Air transport

ICAO/IATA:

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Proper shipping name AEROSOLS, Flammable, 2.1 Class: 2.1 UN/ID No.: UN 1950 Packaging group: None. Note: SC Johnson typically does not ship products via air. Refer to







HMIS Ratings Health 2

Flammability 4

Reactivity 0

NFPA Ratings Health 2

Fire 4

Reactivity 0

Special -

This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information

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This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment &

Regulatory Affairs (GSARA)

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WINDEX® ORIGINAL GLASS CLEANER



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Product information

Trade name : WINDEX® ORIGINAL GLASS CLEANER


: Hard Surface Cleaner





Emergency Overview Appearance / Odor : blue / liquid / pleasant

Immediate Concerns

: Avoid contact with skin, eyes and clothing.


Eyes : May cause:

Mild eye irritation

Skin : Prolonged or repeated contact may dry skin and cause irritation.

Inhalation : No adverse effects expected when used as directed.

Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort.


: Persons with pre-existing skin disorders may be more susceptible to irritating effects.


This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA 29 CFR 1910.1200 or Canadian Controlled Products Regulations.






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Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.

Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.

Inhalation : No special requirements

Ingestion : Rinse mouth with water.





: Container may melt and leak in heat of fire.

Further information : Although this product has a flash point below 200 Deg F, it is

an aqueous solution containing an alcohol and does not sustain combustion. Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

Flash point : 85 °C

185 °F Method: ASTM D 56




Personal precautions : No special precautions required.

Environmental precautions : Outside of normal use, avoid release to the environment.

Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills.






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Clean residue from spill site.


Handling

Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.


: Normal measures for preventive fire protection.

Storage


: Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.

Other data : Stable under normal conditions.



ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above.



No personal respiratory protective equipment normally required.

Hand protection


Eye protection

No special requirements.



Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.


Form : liquid

Color : blue

Odor : pleasant






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pH : 10.7

Boiling point : no data available


Flash point : 85 °C 185 °F Method: ASTM D 56


Flammability (solid, gas) : Does not sustain combustion.

Auto-ignition temperature : no data available




Density : 0.997 g/cm3 at 20 °C

Water solubility : soluble

Viscosity, dynamic : no data available

Viscosity, kinematic : no data available




Conditions to avoid : Direct sources of heat.

Materials to avoid : Strong oxidizing agents





Acute oral toxicity : LD50






5/7



estimated > 2.58 mg/l




Mutagenicity : no data available

Reproductive effects : no data available


Sensitisation : Not known to be a sensitizer.




Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.


Land transport






6/7

U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport

IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport

ICAO/IATA:

Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None.


Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.


California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.



HMIS Ratings

Health 1

Flammability 2

Reactivity 0

NFPA Ratings






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Health 1

Fire 2

Reactivity 0

Special -



3306

SAFETY DATA SHEET

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Power Cleanse PRODUCT IDENTIFIER CODE(S): 3306/3307 PRODUCT RECOMMENDED/INTENDED USE: Industrial-Grade Hand Cleaner MANUFACTURER/SUPPLIER: TEXAS REFINERY CORP. ADDRESS: 840 N. MAIN STREET FORT WORTH, TX 76164 GENERAL INFORMATION: 817-332-1161 24 HR. EMERGENCY PHONE NUMBER: CHEMTREC 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (See Section 15.)

SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS Number Weight %

Petroleum Distillate 64742-15-0 35-50

Amyl Acetate 628-63-7 < 2.0

Isopropanol 67-63-0 < 2.0

Triethanolamine 102-71-6 < 1.0

Nonylphenol ethoxylate 26027-38-3 < 3.0

Petroleum Hydrocarbon Oil 64741-89-5 10-20

(See Section 8 for Exposure Limits)

SECTION 4 FIRST AID MEASURES PRINCIPAL ROUTES OF EXPOSURE: Eyes and Ingestion EFFECTS OF OVEREXPOSURE: May cause mild, transient irritation to eyes. If ingested may cause abdominal pain, nausea, vomiting and/or diarrhea. EYE: Rinse cautiously with water for several minutes. If irritation persists get medical attention. SKIN: N/A. This product is an industrial-grade hand cleaner. INGESTION: Do NOT induce vomiting. Get medical attention. INHALATION: N/A. No inhalation hazards expected from this product under normal conditions of use and storage. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Unknown. NOTES TO PHYSICIAN: None.

SECTION 5 FIRE FIGHTING MEASURES FIRE CLASSIFICATION: GHS Non-flammable. Non-Combustible. NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 FLASH POINT (°F/C): > 212/100 LOWER EXPLOSION LIMIT/UPPER EXPLOSION LIMIT: Not established. OSHA FLAMMABILITY CLASSIFICATION: Non-flammable. Non-combustible. SUITABLE EXTINGUISHING MEDIA: If a fire occurs in which this product is involved or is in the vicinity, use an NFPA Class B extinguisher (carbon dioxide or foam) for Class III B Liquid Fires for extinction.

3306

FIREFIGHTING PROCEDURES: Water spray may be used to cool exposed containers. Use fog nozzles and self-contained breathing apparatus (SCBA). PROTECTION OF FIRE FIGHTERS: Chemical fire- wear self-contained breathing apparatus (SCBA). UNUSUAL FIRE AND EXPLOSION HAZARDS: None. COMBUSTION PRODUCTS: Oxides of carbon and nitrogen.

SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION: Wear appropriate personal protective equipment when cleaning up spills (See Section 8). Keep unnecessary people away; isolate hazard area and deny entry. PROCEDURES: Mop up with absorbent material and dispose of in approved containers in accordance with local, State and Federal pollution control regulations.

SECTION 7 HANDLING AND STORAGE HANDLING: Avoid contact with eyes. For industrial use only. STORAGE: Store away from strong oxidizers and at temperatures not exceeding 120°F (49°C). Keep out of reach of children. Do not flame cut, weld or braze on or around open containers.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Not required under normal conditions of use. PERSONAL PROTECTIVE EQUIPMENT: Not required under normal conditions of use. EYE/FACE PROTECTION: Not required under normal conditions of use. SKIN PROTECTION: Not required under normal conditions of use. RESPIRATORY PROTECTION: Not required under normal conditions of use. OCCUPATIONAL EXPOSURE LIMITS:

Component PEL TLV

Petroleum Distillate 400 ppm 300 ppm

Amyl Acetate 100 ppm 100 ppm

Isopropanol 400 ppm 400 ppm

Triethanolamine Not established 100 ppm

Nonylphenol ethoxylate Not established Not established

Petroleum hydrocarbon oil 5 mg/m3 5 mg/m3

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE (Color and physical state): Thick creamy pink liquid ODOR: Banana odor. pH: Not determined. MELTING POINT/FREEZING POINT: Not determined. BOILING POINT (OF/C): 212/100 FLASH POINT (OF/C): > 212/100 EVAPORATION RATE (Butyl Acetate =1): < 1.0 FLAMMABILITY: Non-flammable. Non-combustible. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: Not established. VAPOR PRESSURE (mm Hg): 15.8 VAPOR DENSITY (Air=1): 5.0 SOLUBILITY (ies) in water: Dispersable.

3306

SPECIFIC GRAVITY (H2O=1): 0.871 PERCENT VOLATILE BY VOLUME: Not established.

SECTION 10 STABILITY AND REACTIVITY CHEMICAL STABILITY: This material is considered stable under specified conditions of storage, shipment and/or use. INCOMPATIBILITY WITH OTHER MATERIALS: Strong oxidizers. CONDITIONS TO AVOID: None known. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and nitrogen. HAZARDOUS REACTION/ POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY VALUES: Petroleum Distillates: Oral LD50 (Rat) = > 5000 mg/kg Dermal LD50 (Rabbit) = > 2000 mg/kg Inhalation LC50 (Rat) = 5000 ppm/4 H Amyl Acetate: Oral LD50 (Rat) = 6500 mg/kg Dermal LD50 (Rabbit) = No data available. Inhalation LC50 (Rat) = No data available. Isopropanol: Oral LD50 (Rat) = 3600 mg/kg Dermal LD50 (Rabbit) = 12,800 mg/kg Inhalation LC50 (Rat) = 16,000 ppm/8 H Triethanolamine: Oral LD50 (Rabbit) = 2200 mg/kg Dermal LD50 (Rabbit) = No data available. Inhalation LC50 (Rat) = No data available. Nonylphenol ethoxylate: Oral LD50 (Rat) = 4000 mg/kg Dermal LD50 (Rabbit) = No data available. Inhalation LC50 (Rat) = No data available. Petroleum Hydrocarbon oil: Oral LD50 (Rat) = > 5000 mg/kg Dermal LD50 (Rabbit) = > 2000 mg/kg Inhalation LC50 (Rat) = 5000 ppm/4 H IRRITANT EFFECT ON THE SKIN: None. IRRITANT EFFECT ON THE EYES: None. SENSITIZATION: None. MUTAGENICITY: No specific data available. CARCINOGENICITY: None known. REPROTOXICITY/TERATOGENICITY: None known. FURTHER INFORMATION ON TOXICOLOGY: None.

SECTION 12 ECOLOGICAL INFORMATION This product is not expected to be harmful to aquatic organisms based on data for the components. INFORMATION ON ELIMINATION (PERSISTENCE AND DEGRADABILITY) BIOACCUMULATION: No specific data available ECOTOXICOLOGICAL EFFECTS: No specific data available FURTHER INFORMATION ON ECOLOGY: Do not allow to contaminate the soil, waterways or waste water.

3306

SECTION 13 DISPOSAL CONSIDERATIONS PROCEDURES: Federal, State and/or Local approved disposal. CONTAINER CLEANING AND DISPOSAL: Federal, State and/or Local approved disposal for alkaline cleaning compounds.

SECTION 14 TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING DESCRIPTION: N/A INTERNATIONAL MARITIME ORGANIZATION (IMDG) SHIPPING DESCRIPTION: N/A FREIGHT CLASSIFICATION: Cleaning, Scouring or Washing Compound, NOI (NMFC48580 SUB 3 CLASS 55)

SECTION 15 REGULATORY INFORMATION TOXIC SUBSTANCES CONTROL ACT (TSCA): All hazardous components of this product are listed on the TSCA inventory. CLEAN WATER ACT (CWA): If spilled into waters of the U.S., this product may be reportable under the Clean Water Act. CLEAN AIR ACT (CAA): This product is not considered a hazardous substance under the Clean Air Act. EPCRA 311/312 CATEGORIES: 1. IMMEDIATE (ACUTE) HEALTH EFFECTS 2. DELAYED (CHRONIC) HEALTH EFFECTS 3. FIRE HAZARD 4. SUDDEN RELEASE OF PRESSURE HAZARD 5. REACTIVITY HAZARD THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(S) SUBJECT TO REPORTING REQUIREMENTS OF SARA SECTION 313 (40 CRF 372): N/A THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR REPRODUCTIVE HARM: N/A OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS): N/A. This product is not regulated by WHMIS (Canada). EUROPEAN INVENTORY OF EXISTING CHEMICALS (EINECS): N/A. This product is not regulated under EU.

SECTION 16 OTHER INFORMATION REVISION INDICATOR: New SDS compliant with GHS AND OSHA. DATE OF REVISION: 11/15/2013 SUPERSEDES: 03/05/2013

DISCLAIMER: THIS INFORMATION IS BEING SUPPLIED TO YOU UNDER OSHA "RIGHT TO KNOW" REGULATION 29 CFR 1910.1200 AND IS OFFERED IN GOOD FAITH. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA

AVAILABLE TO US AND IS BELIEVED TO BE TRUE AND ACCURATE TO THE BEST OF OUR KNOWLEDGE. TEXAS

REFINERY CORP. MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THIS DATE, THE

HAZARDS CONNECTED WITH THE USE OF THE MATERIAL, OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

TEXAS REFINERY CORP. MAKES NO WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, CONCERNING THE SAFE USE OF

THIS MATERIAL IN YOUR PROCESS OR IN COMBINATION WITH OTHER SUBSTANCES. TEXAS REFINERY CORP. ASSUMES

NO RESPONSIBILITY FOR DAMAGE OR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.

The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087


MSDS #: RQ1000484 Issue Date: March 11, 2013 Supersedes: N/A Issue Date: March 4, 2010

SECTION I - PRODUCT IDENTIFICATION Identity: Disinfecting Multi-Purpose Liquid Hard Surface Cleaner Finished Product Brands: Mr. Clean Antibacterial Multi-Surfaces and Mr. Clean Disinfectant Multi-

Surfaces Liquid (Summer Citrus scent) P&G Telephone Number: 1-800-867-2532 or call Local Poison Control Center or your physician.

SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: May be harmful if swallowed. Eye Contact: Mild eye irritant. Skin Contact: Mild skin irritant. Inhalation: N/A Signs and Symptoms of Exposure: Ingestion: Oral ingestion may result in transient system effects (ataxia and muscle weakness) and/or gastrointestinal irritation with nausea, vomiting or diarrhea. This product contains alcohol ethoxylates. Large ingestions (>2 ml/kg) may also cause symptoms of alcohol-like intoxication, lack of coordination, drowsiness, inarticulateness, headache or ataxia. Alcohol ethoxylates may contribute to central nervous system symptoms. Eye Contact: Instillation into the eye may result in transient superficial effects similar to those produced by mild toilet soaps and detergents. Skin Contact: Use on irritated or extremely dry skin may aggravate the existing condition. Inhalation: N/A Medical Conditions Generally Known to be Aggravated by Exposure: N/A Potential Environmental Effects: (See Section 12 for more information)

SECTION III - COMPOSITION AND INGREDIENTS Active ingredient listed on the product label is the following: Sodium hydroxide .......................................................................................................... 0.34% Other Ingredients (includes grease cutting agents) ...................................................... 99.66% Total ............................................................................................................................ 100.00% Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA:

Chemical Name Common Name CAS No. Composition Range

TLV/LD50/LC50

Alcohol ethoxylates Nonionic surfactants

Confidential 3-7% LD50 (rat, oral) = 200-2000 mg/kg

SECTION IV – FIRST AID INFORMATION

First Aid Procedures: Ingestion: Drink 1-2 glasses of water and call a physician or poison control center (product contains alcohol ethoxylates) – do not induce vomiting unless they tell you to do so. Eye Contact: Hold eyes open and rinse gently with water for 15-20 min. If wearing contacts, remove lenses after first 5 min., and continue rinsing. If irritation persists, call a physician. Skin: Thoroughly wash exposed area with soap and water and discontinue use. Remove contaminated clothing. If irritation persists, call a physician. Inhalation: Remove to fresh air. Note to Physician: (if applicable): N/A Other: Consumer product package has the following precautionary statement: “KEEP OUT OF REACH OF CHILDREN. CAUTION: Eye Irritant. Avoid contact with eyes.

SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): >200°F / >93.3°C (ASTM D-93 Pensky-Martens Closed Cup). Flammable Properties: Upper Flammable Limit: N/A Lower Flammable Limit: N/A Explosive Limits: UEL: N/A LEL: N/A Auto-ignition Temperature: N/A Hazardous Combustion Products: None known. Explosion Data (Sensitivity to Mechanical Impact): N/A Explosion Data (Sensitivity to Static Discharge): N/A Extinguishing Media: Suitable: CO2, water, dry chemical or “alcohol” foam. Use water to keep fire-exposed container cool. Unsuitable: N/A Protection of Firefighters: Specific Hazards Arising from the Material: None Protective Equipment and Precautions for Firefighters: No unusual precautions necessary.

SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: See Section VIII below. Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS. Do not landfill. Small (household) quantities may be disposed of via sewer with large quantities of water. Incineration is preferred where permitted. Methods for Containment: Prevent spills from reaching a waterway. Methods for Cleanup: Use water spray to dilute and/or wash away spills to avoid exposure and to protect persons working to stop/repair leak. Absorb spilled product onto absorbent material. Other Information: (if applicable) N/A

SECTION VII – HANDLING AND STORAGE

Precautions To Be Taken in Handling: Handle in a well ventilated, cool and dry area. Precautions To Be Taken in Storage: Storage must be in a well ventilated, cool and dry area.

SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines: N/A Engineering Controls: Ventilation Mechanical (General): Normal/general dilution ventilation is acceptable. Personal Protective Equipment (PPE): Eye/Face Protection: None required with normal consumer use. Occupational Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable. Skin Protection: None required with normal consumer use. Occupational Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Respiratory Protection: None required with normal use.

SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Colored liquid (orange). Packaged in a pourable plastic bottle.

Flash Point (Method Used): >200F / >93.3°C (ASTM D-93 Pensky-Martens Closed Cup.)

Odor: Product is perfumed. Reserve Alkalinity: N/A Odor Threshold: N/A Solubility in Water: Completely Physical State: Liquid. Decomposition Temperature: N/A Vapor Pressure (mm Hg): N/A Evaporation Rate (nBuOAc=1): Unknown Vapor Density (Air=1): N/A Specific Gravity/Density: 1.019 g/cm3 Boiling Point: N/A Melting/Freezing Point: N/A Partition Coefficient (n-octanol/water): N/A pH (10% solution): 10.3 Volatile Organic Compound (VOC): Product complies with US State and Federal regulations for VOC content.

SECTION X – STABILITY AND REACTIVITY

Chemical Stability: Stable Conditions to Avoid: None Incompatible Materials: None Hazardous Decomposition Products: None known Possibility of Hazardous Reactions: None known

SECTION XI - TOXICOLOGICAL INFORMATION Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: This finished consumer product is not carcinogenic. NTP: No IARC: No All product ingredients were checked for NTP and IARC carcinogen listings relevant to this product formulation.

SECTION XII - ECOLOGICAL INFORMATION

No concerns at relevant environmental concentrations.

SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with federal, state/provincial and local regulations. Non-Household Setting (US Federal): Industrial disposal of product in finished, consumer-ready packaging must be disposed of as an organic pesticide. Records must be kept of the disposal that documents the method of disposal, the date of disposal, the location of the disposal site, the type of pesticide disposed of (organic pesticide), and the amount of pesticide disposed of. Disposal records must be retained for 20 years. Incineration is preferred where permitted. Product removed from finished, consumer-ready packaging may be disposed of as non-pesticidal, liquid waste which is non-hazardous waste according to Federal RCRA regulations (40 CFR 261). California Hazardous Waste: Yes Household Use: Consumers may dispose of small (household) quantities down the drain with large quantities of water. Discard empty container in trash or thoroughly rinse and recycle container where facilities exist.

SECTION XIV - TRANSPORT INFORMATION

Ground Transport (US DOT): Not regulated. Air Transport (IATA): Not regulated. Marine/Water Transport (IMDG): Not regulated.

SECTION XV - REGULATORY INFORMATION United States All intentionally-added components of this product are listed on the US TSCA Inventory. EPA Registration Number: 3573-63 SARA 313/302/304/311/312 chemicals: None. California: This product has been evaluated and does not require warning labeling under California Proposition 65. State Right-to-Know and CERCLA: The following ingredients present in the finished product at >1% (or >0.1% for carcinogens) are listed on state right-to-know lists or state worker exposure lists

Ingredient CAS # Max Level

CERCLA RQ

State IL MA NJ PA RI

None

Canada All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations.

SECTION XVI - OTHER INFORMATION

Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. P&G Hazard Rating: Health: 1 4=EXTREME Flammability: 0 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumes no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product.


LA9776SULPHURIC ACID 98%

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct Id: LA9776Product Name: SULPHURIC ACID 98%Synonyms: Sulphuric Acid, Hydrogen Sulphate, Oil of Vitriol, Battery Acid.Chemical Family: Inorganic acid.Application: Water treatment. Metal pickling. Petroleum processing. Manufacture of fertilizers, explosives and otheracids.

Distributed By:Univar Canada Ltd.9800 Van Horne WayRichmond, BCV6X 1W5

Prepared By: The Environment, Health and Safety Department of Univar Canada Ltd.Preparation date of MSDS: 13/Jan/2014Telephone number of preparer: 1-866-686-4827

24-Hour Emergency Telephone Number (CANUTEC): (613) 996-6666


Ingredients Percentage(W/W)

LD50s and LC50s Route & Species:

Sulphuric Acid7664-93-9

70-100 Oral LD50 (Rat) 2140 mg/kgInhalation LC50 (Rat) 510 mg/m3 (2-hour exposure)

LC50 (Rat): 255 mg/m3 (equivalent 4-hour exposure)LC50 (Mouse): 160 mg/m3 (equivalent 4-hour exposure).

Note: No additional remark.

3. HAZARDS IDENTIFICATIONPotential Acute Health Effects:Eye Contact: Corrosive to eye tissue and may cause severe damage and blindness. Inflammation of the eye ischaracterized by redness, watering, and itching.Skin Contact: Corrosive! Effects on the skin may be delayed and damage may occur without the onset of pain. Causesburns, and brownish or yellow stains. Concentrated solutions may cause second or third degree burns with severenecrosis and may cause permanent scarring. Prolonged and repeated exposure to dilute solutions often causes irritation,redness, pain and drying and cracking of the skin.Inhalation: Inhalation of the mist may produce severe irritation of respiratory tract, characterized by coughing, choking,or shortness of breath. May be fatal if inhaled.


Page 1 of 6

3. HAZARDS IDENTIFICATIONIngestion: Harmful if swallowed. Causes burns to the mouth, throat and stomach.

4. FIRST AID MEASURESEye Contact: Immediately flush eyes with copious quantities of water for at least 20 minutes holding lids apart to ensureflushing of the entire surface. Seek immediate medical attention. Do not transport victim until the recommended flushingperiod is completed, unless flushing can be continued during transport.Skin Contact: Flush affected skin with gently flowing water for 20-60 minutes and remove contaminated clothing whilerinsing. Obtain medical attention immediately. Do not transport victim until the recommended flushing period iscompleted, unless flushing can be continued during transport. Remove contaminated clothing and discard. Removecontaminated shoes and discard.Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. If symptomspersist, get medical attention. If the affected person is not breathing, apply artificial respiration. If breathing is difficult,give oxygen. In situations where administering oxygen is appropriate, first aiders must be trained in the safe use andhandling of oxygen. It is preferable to administer oxygen under a doctor's supervision or advice. If the heart has stopped,trained personnel should begin cardiopulmonary resuscitation (CPR) immediately. Immediate medical assistance isrequired.Ingestion: If conscious, wash out mouth with water. Seek immediate medical attention. Do NOT induce vomiting. Nevergive anything by mouth to an unconscious or convulsing person. If vomiting occurs spontaneously, keep head below hipsto prevent aspiration of liquid into the lungs. Administer artificial respiration if breathing has stopped. If the heart hasstopped, trained personnel should begin cardiopulmonary resuscitation (CPR) immediately.Notes to Physician: Aspiration may cause severe lung damage. Evacuate stomach in a way which avoids aspiration. Ifingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, toprevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation andappropriate chemotherapy if respiration is depressed. Following exposure the patient should be kept under medicalreview for at least 48 hours as delayed pneumonitis may occur. DO NOT attempt to neutralize the acid with weak basessince the reaction will produce heat that may extend the corrosive injury.

5. FIRE FIGHTING MEASURESFlash Point: None.Flash Point Method: Not applicable.Autoignition Temperature: Not available.Flammable Limits in Air (%): Not Available.Extinguishing Media: Use extinguishing media appropriate for surrounding fire. If water is used, care should be taken,since it can generate heat and cause spattering if applied directly to sulphuric acid.Special Exposure Hazards: Strong dehydrating agent, which may cause ignition of finely divided combustible materialson contact. Reacts violently with water with the evolution of heat. It can react explosively with organic materials. Reactswith metals to generate flammable hydrogen gas. Reacts violently with water with the evolution of heat. It can reactexplosively with organic materials. Reacts with many metals to liberate hydrogen gas that can form explosive mixtureswith air. Hydrogen, a highly flammable gas, can accumulate to explosive concentrations inside drums, or any types ofsteel containers or tanks upon storage.Hazardous Decomposition/Combustion Materials (under fire conditions): Oxides of sulphur.Special Protective Equipment: Fire fighters must wear full face, positive pressure, self-contained breathing apparatusand appropriate protective clothing.NFPA RATINGS FOR THIS PRODUCT ARE: HEALTH 3, FLAMMABILITY 0, INSTABILITY 2HMIS RATINGS FOR THIS PRODUCT ARE: HEALTH 3, FLAMMABILITY 0, REACTIVITY 2

6. ACCIDENTAL RELEASE MEASURESPersonal Precautionary Measures: Restrict access to unprotected personnel. Wear appropriate protective equipment.Environmental Precautionary Measures: Prevent entry into sewers or streams, dike if needed. Consult localauthorities.Procedure for Clean Up: Isolate hazard area and restrict access. Stop leak only if safe to do so. Eliminate all ignitionsources. Handling equipment must be grounded. Ventilate area. Contain spill with sand or other inert materials.Neutralize with lime slurry, limestone, or soda ash. Absorb with an inert dry material and place in an appropriate wastedisposal container.


Page 2 of 6

7. HANDLING AND STORAGEHandling: For industrial use only. Handle and open containers with care. Avoid contact with eyes, skin and clothing. Donot ingest. Avoid inhalation of chemical. Empty containers may contain hazardous product residues. Keep the containersclosed when not in use. Protect against physical damage. Use appropriate personnel protective equipment. Use extremecare when diluting with water. ALWAYS ADD ACID TO WATER. Use with adequate ventilation. CAUTION: Hydrogen, ahighly flammable gas, can accumulate to explosive concentrations inside drums, or any type of steel containers or tanksupon storage. Carbon steel storage tanks must be vented. Use corrosion-resistant transfer equipment when transferringacid.Storage: Store above freezing point. Elevated temperatures will increase the corrosion rate of most metals as well ascause build-up of pressure due to sulfur dioxide generation. Store packaged acid in a dry, well-ventilated location. Avoidstorage with incompatible materials. Storage tanks should be protected from water getting in, be well ventilated, andmaintained structurally in a safe and reliable condition. Sulfuric acid will attack some forms of plastics and coatings.Always add acid to water - not water to acid. If kept in upper floors of building, floors should be acid proof with drains to arecovery tank.

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering Controls:

Use process enclosure, local exhaust ventilation, or other engineering controls to keep airborne levels belowrecommended exposure limits. Electrical installations should be protected against the corrosive action of acid vapors.Respiratory Protection: A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mistcartridges for concentrations up to 10 mg/m3. An air-supplied respirator if concentrations are higher or unknown.Gloves:

Neoprene gloves. PVC gloves.Skin Protection: Impervious boots. Butyl rubber acid suit.Eyes: Chemical safety goggles and/or full face shield to protect eyes and face, if product is handled such that it could besplashed into eyes.Other Personal Protection Data: Ensure that eyewash stations and safety showers are proximal to the work-stationlocation.

Ingredients Exposure Limit - ACGIH Exposure Limit - OSHA Immediately Dangerousto Life or Health - IDLH

Sulphuric Acid 0.2 mg/m3 TLV-TWA 1 mg/m3 TWA 15 mg/m3

9. PHYSICAL AND CHEMICAL PROPERTIESPhysical State: Liquid. (Oily).Color: Clear to amber.Odor: Odorless A pungent odor may exist if certain impurities are present in the acid.pH <1Specific Gravity: 1.835Boiling Point: 279°C /535°FFreezing/Melting Point: -35°C / -31°FVapor Pressure: <0.3 mm Hg @ 25°CVapor Density: 3.4% Volatile by Volume: Not Available.Evaporation Rate: Not Available.Solubility: Soluble in water.VOCs: Not Available.Viscosity: Not Available.Molecular Weight: 98.08 g/moleOther: Not Available.

10. STABILITY AND REACTIVITYChemical Stability: Stable.Hazardous Polymerization: Will not occur.Conditions to Avoid: Avoid excessive heat, open flames and all ignition sources. Water.


Page 3 of 6

10. STABILITY AND REACTIVITYMaterials to Avoid: Contact with organic materials (such as alcohol, acrylonitrile, chlorates, carbides, epichlorohydrin,fulminates, isoprene, nitrates and picrates) may cause fire and explosions. Contact with metals may produce flammablehydrogen gas. Reducing agents. Alkalis. Moisture.Hazardous Decomposition Products: Toxic fumes. Sulfuric acid. Oxides of sulphur. Sulfuric acid vapors may bereleased upon heating and sulfur dioxide and sulfur trioxide may be released upon decomposition.Additional Information:

When diluting, add acid to water. DO NOT add water to the acid. Sulfuric acid can be corrosive to most metals,depending on such factors as acid concentration, temperature and impurities. Concentrated sulfuric acid (containingmore than 90% H2SO4) can be safely handled using carbon steel, cast iron, and certain stainless steel alloys. Theresistance of alloys to sulfuric acid corrosion generally increases with increasing chromium, molydbenum, copper andsilicon content.

11. TOXICOLOGICAL INFORMATIONPrinciple Routes of Exposure

Ingestion: Harmful if swallowed. Causes burns to the mouth, throat and stomach.Skin Contact: Corrosive! Effects on the skin may be delayed and damage may occur without the onset of pain. Causesburns, and brownish or yellow stains. Concentrated solutions may cause second or third degree burns with severenecrosis and may cause permanent scarring. Prolonged and repeated exposure to dilute solutions often causes irritation,redness, pain and drying and cracking of the skin.Inhalation: Inhalation of the mist may produce severe irritation of respiratory tract, characterized by coughing, choking,or shortness of breath. May be fatal if inhaled.Eye Contact: Corrosive to eye tissue and may cause severe damage and blindness. Inflammation of the eye ischaracterized by redness, watering, and itching.

Additional Information: Repeated exposure may produce erosion and discoloration of teeth.Acute Test of Product:Acute Oral LD50: 2140 mg/kg (Rat)Acute Dermal LD50: Not Available.Acute Inhalation LC50: 510 mg/m3 (2-hour exposure) (Rat)255 mg/m3 (equivalent 4-hour exposure) (Rat)160 mg/m3 (equivalent 4-hour exposure) (Mouse)

Carcinogenicity:

Ingredients IARC - Carcinogens ACGIH - Carcinogens

Sulphuric Acid Group 1 A2

Carcinogenicity Comment: WHO and IARC have concluded that occupation exposure to strong inorganic acid mistscontaining sulfuric acid is carcinogenic to man, (Group 1) causing cancer of the larynx and, to a lesser extent, the lung.Exposure to any mist or aerosol during the use of this product should be avoided and, in any case, keep exposure belowthe occupational exposure limit for sulfuric acid. IARC's classification is for inorganic acid mists containing sulfuric acidonly and does not apply to sulfuric acid or sulfuric acid solutions.

Reproductive Toxicity/ Teratogenicity/ Embryotoxicity/ Mutagenicity: Not Available.


Page 4 of 6

12. ECOLOGICAL INFORMATIONEcotoxicological Information:

Ingredients Ecotoxicity - Fish SpeciesData

Acute CrustaceansToxicity:

Ecotoxicity - FreshwaterAlgae Data

Sulphuric Acid LC50 (Brachydanio rerio) 500mg/L

LC50 (Oncorhynchus mykiss)2.8 ug/L (96hr)

Not Available. Not Available.

Other Information:Harmful to aquatic life at low concentrations.

13. DISPOSAL CONSIDERATIONSDisposal of Waste Method: Disposal of all wastes must be done in accordance with municipal, provincial and federalregulations.Contaminated Packaging: Empty containers should be recycled or disposed of through an approved wastemanagement facility.

14. TRANSPORT INFORMATIONDOT (U.S.):DOT Shipping Name: SULFURIC ACIDDOT Hazardous Class 8DOT UN Number: UN1830DOT Packing Group: IIDOT Reportable Quantity (lbs): Not Available.Note: No additional remark.Marine Pollutant: No.

TDG (Canada):TDG Shipping Name: SULPHURIC ACIDHazard Class: 8UN Number: UN1830Packing Group: IINote: No additional remark.Marine Pollutant: No.


Page 5 of 6

15. REGULATORY INFORMATIONU.S. TSCA Inventory Status: All components of this product are either on the Toxic Substances Control Act (TSCA)Inventory List or exempt.

Canadian DSL Inventory Status: All components of this product are either on the Domestic Substances List (DSL), theNon-Domestic Substances List (NDSL) or exempt.

Note: Not available.

U.S. Regulatory Rules

Ingredients CERCLA/SARA - Section302:

SARA (311, 312) HazardClass:

CERCLA/SARA - Section313:

Sulphuric Acid Listed Listed Listed

California Proposition 65: Not Listed.MA Right to Know List: Listed.New Jersey Right-to-Know List: Listed.Pennsylvania Right to Know List: Listed.

WHMIS Hazardous Class:D1A VERY TOXIC MATERIALSE CORROSIVE MATERIAL

16. OTHER INFORMATIONAdditional Information: This product has been classified in accordance with the hazard criteria of the

Canadian Controlled Products Regulations (CPR) and the MSDS contains all theinformation required by the CPR.

Disclaimer: NOTICE TO READER:Univar, expressly disclaims all express or implied warranties of merchantability andfitness for a particular purpose, with respect to the product or information providedherein, and shall under no circumstances be liable for incidental or consequentialdamages.

Do not use ingredient information and/or ingredient percentages in this MSDS as aproduct specification. For product specification information refer to a ProductSpecification Sheet and/or a Certificate of Analysis. These can be obtained fromyour local Univar Sales Office.

All information appearing herein is based upon data obtained from the manufacturerand/or recognized technical sources. While the information is believed to beaccurate, Univar makes no representations as to its accuracy or sufficiency.Conditions of use are beyond Univar's control and therefore users are responsible toverify this data under their own operating conditions to determine whether theproduct is suitable for their particular purposes and they assume all risks of their use,handling, and disposal of the product, or from the publication or use of, or relianceupon, information contained herein. This information relates only to the productdesignated herein, and does not relate to its use in combination with any othermaterial or in any other process.

***END OF MSDS***


Page 6 of 6

WD-40

Page 1 of 4


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

MANUFACTURER/SUPPLIER: US Office: WD-40 Company 1061 Cudahy Place San Diego, CA 92110 Information Phone #: (619) 275-1400 Emergency Phone # 24 hr: Chemtrec: (800) 424-9300 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals.

Canadian Office: WD-40 Products [Canada] Ltd. P.O. Box 220 Toronto, Ontario M9C 4V3 Information Phone #: (416) 622-9881 Emergency Phone # 24 hr: Canutec: (613) 996-6666 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals

PRODUCT NAME: WD-40 Aerosol PRODUCT USE: Cleaner, lubricant. MSDS DATE OF PREPARATION: March 27, 2014

SECTION 2 HAZARDS IDENTIFICATION DANGER! Harmful or fatal if swallowed. Flammable aerosol. Contents under pressure. Avoid eye contact. Use with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. POTENTIAL HEALTH EFFECTS: PRIMARY ROUTES OF ENTRY: Inhalation, skin and eye contact. ACUTE EFFECTS: INGESTION: This product has low oral toxicity. Swallowing of the liquid contents may cause irritation, nausea, vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis. EYES: Contact may be mildly irritating to eyes. May cause redness and tearing. SKIN: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. INHALATION: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. May aggravate existing respiratory conditions such as asthma. Intentional abuse may be harmful or fatal. CHRONIC EFFECTS: None expected.

SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS

Ingredient CAS Number Percent Aliphatic Petroleum Distillates 64742-47-8

64742-88-7 50-70%

Petroleum Base Oil 64742-58-1 64742-53-6 64742-56-9 64742-65-0

30-35%

Non-Hazardous Ingredients Proprietary <10% Carbon Dioxide 124-38-9 2-3%

WD-40 Aerosol 03/27/14

Page 2 of 4

SECTION 4 FIRST AID MEASURES

For Medical Emergencies Call 1-888-324-7596 (24 hours/day) INGESTION: Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. EYE CONTACT: Flush thoroughly with water. Get medical attention if irritation persists. SKIN CONTACT: Wash with soap and water. If irritation develops and persists, get medical attention. INHALATION: If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. UNUSUAL FIRE/EXPLOSION HAZARDS: Contents under pressure. Aerosol containers may burst under fire conditions. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back.

SECTION 6 ACCIDENTAL RELEASE MEASURES

SPILL RESPONSE: Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required.

SECTION 7 HANDLING AND STORAGE

HANDLING: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use with adequate ventilation. Keep away from heat, sparks and open flames. Wash thoroughly with soap and water after handling. Do not puncture or incinerate containers. Keep can away from electrical current or battery terminals. Electrical arcing can cause burn-through (puncture) which may result in flash fire, causing serious injury. Keep out of the reach of children. STORAGE: Do not store above 120F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol.

SECTION 8 EXPOSURE CONTROLE/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS: Aliphatic Petroleum Distillates 1200 mg/m3 TWA Manufacturer Recommended Petroleum Base Oil 5 mg/m3 TWA ACGIH TLV

10 mg/m3 STEL ACGIH TLV Non-Hazardous Ingredients None Established Carbon Dioxide 5000 ppm TWA, 30,000 ppm STEL ACGIH TLV

The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Safety glasses or goggles recommended. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation.


Page 3 of 4

For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits. Personal Protection: Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and concentration. Follow applicable regulations and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling.

SECTION 9 PHYSICAL DATA APPEARANCE AND ODOR: Light amber liquid with a mild odor.

Freezing Point: Not Applicable Odor Threshold: Not Determined Boiling Point: 361 - 369F (183 - 187°C) Specific Gravity: 0.78 – 0.82 @ 60F Solubility in Water: Insoluble pH: Not Applicable Vapor Pressure: 95-115 PSI @ 70F Vapor Density: Greater than 1 Percent Volatile: 70-75% VOC: 533 grams/liter (65%) Coefficient of Water/Oil Distribution:

Not Determined Kinematic Viscosity:

2.79-2.96cSt @ 100F

Flash Point: 122F (49°C) Tag Open Cup (concentrate)

Flammable Limits: (Solvent Portion)

LEL: 0.6% UEL: 8.0%

Pour Point: -63C (-81.4F ) ASTM D-97 Explosion Impact: None

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable INCOMPATIBILITY: Strong oxidizing agents. Avoid heat and open flames. Do not puncture or incinerate containers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide.

SECTION 11 TOXICOLOGICAL INFORMATION The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard.

SECTION 12 ECOLOGICAL INFORMATION No data is currently available.

SECTION 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: If this product becomes a waste, it would be expected to meet the criteria of a hazardous waste based on flammability. However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local regulations.

SECTION 14 TRANSPORT INFORMATION DOT Surface Shipping Description: Consumer Commodity, ORM-D After 1/1/2014 UN1950, Aerosols, 2.1 Ltd. Qty (Note: Shipping Papers are not required for Limited


Page 4 of 4

Quantities unless transported by air or vessel – each package must be marked with the Limited Quantity Mark) Canadian TDG Classification: Limited Quantity IMDG Code Hazard Classification: UN1950, Aerosols, 2.1.

SECTION 15 REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills as required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. CANADIAN REGULATIONS: Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List or exempt from notification Canadian WHMIS Classification: Class B-5 (Flammable Aerosol). This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR.

SECTION 16 OTHER INFORMATION HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Physical Hazard – 0 (minimal hazard) Revision Date: 03/27/14 Supersedes: 03/10/13 Prepared By: Industrial Health & Safety Consultants, Inc. 1-203-929-3473 This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS regulations. The foregoing information has been compiled from sources believed to be accurate but is not warranted to be. Recipients are advised to confirm in advance of need that data is correct. Standards change without notice. It is the responsibility of the recipient to insure that their personnel have been notified of any changes which may affect them. The data provided on this MSDS are not meant to be used as specifications, only as guideline information as to the safe use of this product. User should refer to applicable laws before use. N/D = Not Determined N/E = Not Established N/A = Not Applicable 1014100/No.0084102


Date of issue 02/12/14

Product name REACH NPE FREE

Product code M600Supersedes 04/13/11

Product use Hand Cleaner

Emergency Telephone Numbers

For MSDS Information: Technical Services Group Telephone (780) 453-8100 (Business Hours 8:00am - 5:00pm)

For Medical or Transportation EmergencyCANUTEC (24 Hours) (613) 996-6666 - Call Collect

Prepared By Technical Services Group 11627 178th Street Edmonton, Alberta T5S 1N6

ZEP Inc.11627 178th StreetEdmonton, Alberta T5S 1N61-877-I-BUY-ZEP (428-9937)www.zep.com

Section 1. Chemical Product and Company Identification

Emergency overviewCAUTION !HARMFUL IF SWALLOWED.Do not ingest. Do not get in eyes. Avoid breathing vapor or mist.

Acute Effects

Eyes

Skin

Inhalation

Ingestion

Routes of Entry Eye contact.Irritating to eyes. Inflammation of the eye is characterized by redness, watering and itching.This product is formulated for use on skin but should be rinsed off when possible.Inhalation not likely under normal use conditions. Inhalation of high concentrations of vapor may affect the central nervous system. Symptoms and signs include headache, dizziness, fatigue,muscular weakness, drowsiness and, in extreme cases, loss of consciousness.

Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.

NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment.

Chronic effects Skin which is repeatedly defatted by contact with this product may be more susceptible to irritation, infection or dermititis.

Additional Information: See Toxicological Information (Section 11)

Section 2. Hazards Identification

Name of Hazardous Ingredients CAS number % by Weight

Section 3. Composition/Information on Ingredients

LIGHT ALIPHATIC NAPHTHA; solvent naphtha (petroleum), medium aliphatics 64742-88-7 15 - 40C12-C14 ETHOXYLATED ALCOHOLS 68551-12-2 1 - 5MONOETHANOLAMINE; 2-aminoethanol; MEA 141-43-5 1 - 5

Eye Contact

Skin Contact

Inhalation

Ingestion

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.This product is formulated for use on the skin, but should always be immediately rinsed off with plenty of water.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if symptoms appear.If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.Never give anything by mouth to an unconscious person. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately.

Section 4. First Aid Measures

Page: 1/3

Material Safety Data Sheet Product Name REACH NPE FREEProduct code M600

Closed cup: 71°C (159.8°F)[Tagliabue.]

Flash Point

Not available.Flammable Limits

Flammability

Fire hazard Gel structure inhibits combustibility of solvent.

Gel structure inhibits combustibility of solvent.

Fire-Fighting Procedures Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. In case of fire, use water spray (fog), foam, dry chemical or CO₂.

Section 5. Fire Fighting Measures

Auto-ignition Temperature

Products of Combustion None known.

Explosion hazard Not available.

Spill Clean up Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Section 6. Accidental Release Measures

Handling

Storage

Put on appropriate personal protective equipment (see Section 8). Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Do not reuse container. Wash thoroughly after handling. Avoid contact with eyes.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store between the following temperatures: 40°F - 120°F (4.4°C - 49°C). Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Keep out of the reach of children.


Personal Protective Equipment (PPE)

Eyes

Hands and BodyRespiratory

Product name Exposure limitsNo exposure limit value known.

Recommended: No special protection is required.Recommended: No special protective clothing is required.

A respirator is not needed under normal and intended conditions of product use.

Section 8. Exposure Controls/Personal Protection

Physical StatepHBoiling Point

Specific GravitySolubility

Liquid. [Gel]8Not available.0.95

ColorOdor

Vapor Pressure

Vapor DensityEvaporation Rate

VOC (Consumer)

Green. [Light]Almond-like.Not available.Not available.Not available.

338 (g/l). 35.7%

Very slightly soluble in the following materials:cold water and hot water. Emulsifies in water.

Section 9. Physical and Chemical Properties

Freezing Point


Will not occur.

Stability and Reactivity

Hazardous Decomposition Products

Hazardous PolymerizationReactive or incompatible with the following materials: oxidizing materials.Incompatibility

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 10. Stability and Reactivity

Page: 2/3

Material Safety Data Sheet Product Name REACH NPE FREEProduct code M600


Carcinogenicity

Reproductive toxicity

Conclusion/Summary : No results available.

Teratogenicity

No results available.

Mutagenicity

Conclusion/Summary : No results available.

:Conclusion/Summary

Acute toxicity


Not available.

Environmental Effects No known significant effects or critical hazards. Aquatic Ecotoxicity

Not available.

Section 12. Ecological Information

Waste Information

Waste Stream Not available.

Section 13. Disposal Considerations

Waste must be disposed of in accordance with applicable regulations. Consult your local or regional authorities for additional information.

PG* : Packing group

Regulatory information UN number Proper shipping name Classes PG* Label

Not available. Not available. Not available. -

Section 14. Transport Information

IMDG Class

TDG Classification Not regulated. - - -

NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. Limited Quantity: Small quantities of controlled goods are not regulated as Dangerous Goods according to TDG regulations.


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Section 15. Regulatory Information

Canada

WHMIS (Canada) Not controlled under WHMIS (Canada).This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Section 16. Other Information

ferries - mhisafety msds book 2015...safety data sheet (sds) date prepared/revised: 1/9/2015 version...

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