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DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE [email protected] 02.03.2008Codes: 10006, DPR 5055, document code: FDS10006 1/5

SAFETY DATA SHEET

1 - IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY

IDENTIFICATION OF THE PREPARATION

DECAPAGE or DEGREASER ST (code: 10006)

CLEANING & DEOXIDISING (code: DPR 5055)

MAIN USE OF THE PREPARATIONThis solution is used at ambient temperature with the selective brush plating process to degrease ferrous metals, nickeland alloys before plating. It is sometimes used for degreasing aluminium alloys but is not recommended on cuprousmetals.As the brush process is applied locally without immersion of the part, just where it is necessary, only small quantities ofsolution are stored or used.

COMPANY IDENTIFICATIONDALIC - ZI de Plagu - 41, rue des Eaux - B.P. 90139 - 35501 VITRE CEDEX, FRANCEManufacturer and Seller, tel.: (33) 2.99.75.36.99, fax: (33) 2.99.74.49.31.For information: [email protected], tel.: (33) 2.99.75.53.88.

RELEVANT OFFICIAL ADVISORY BODY (France): INRS / Orfila, tel. (33) 1.45.42.59.59.________________________________________________________________________________________________

2 - HAZARDS IDENTIFICATION

CHEMICAL NATUREAlkaline aqueous preparation containing in particular sodium hydroxide or soda.

PRODUCT CLASSIFICATION ACCORDING TO 1999/45/EC and 67/548/ECSymbolC, risk phrases:R34.

MAIN HAZARDS

Adverse physicochemical effects- Fire or explosion: this product is not classified as flammable or explosive.Adverse effects on healthCorrosive preparation, can cause burns: the skin can be damaged in its whole depth after 4 h of contact or less. Canproduce eyes lesions in case of contact if decontamination with water is not quickly achieved.

Effects on the environmentThis preparation does not present a special risk to environment providing that the recommendations of the section 13relative to disposal as well as the national or local provisions are followed. Refer also to the paragraphs 11, 13 and 15.________________________________________________________________________________________________

3 - COMPOSITION / INFORMATION ON INGREDIENTS

COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS (according to 1999/45/EC and 67/548/EC)Substances present in concentrations higher than the minimal level of danger: YES

Regulated substance

NaOH (19thadaptation)

Sodium hydroxideEC index N: 011-002-00-6

CAS N: 1310-73-2EINECS N: 215-185-5

Classification of thepure substance

C R35

S phrases (1/2)-26-36/39-45

Classification of thesubstance according toits concentration (in %)

5%2-5%

0.5-2%

C R35C R34Xi R36/38

Concentration range inthe preparation

2-5%

Substances with the R33 phrase (if 1%) or with the R64 phrase (if 1%) or classified as sensitizing (if 0.1%): NO.OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.OTHER INFORMATION: contains also not classified salts.________________________________________________________________________________________________

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DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE [email protected] 02.03.2008Codes: 10006, DPR 5055, Safety Data Sheet, document code: FDS10006 2/5

4 - FIRST AID MEASURES

CONTACT WITH SKINTake off contaminated clothing and shoes. Wash immediately with plenty of water, even without any burning sensation.Take a shower if necessary.

CONTACT WITH EYESRinse immediately with plenty of water for approximately 15 minutes, even without pain. Always seek medical advice.

INHALATIONTheoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualtyfrom the contaminated area, let him take a rest in a well-ventilated room and seek medical advice.

INGESTIONDo not give anything to drink. Do not induce vomiting. Call the medical service to transfer immediatelyinto hospital.

PROTECTION OF THE FIRST-AIDERSAccording to the situation, wear gloves, glasses, protective clothes and shoes, a mask ________________________________________________________________________________________________

5 - FIRE-FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIAWater spray, dry ice, powders

EXTINGUISHING MEDIA WHICH SHALL NOT BE USEDNo contraindication.

SPECIFIC HAZARDSDangerous decomposition products:Hydrogen evolution in small quantities in case of reaction with metals. Decomposition of some components begins at150C and gives notably polyacids, unsaturated anhydrides and carbon oxides. Formation of sodium oxide from 1250C.Prevent any material from entering drains or waterways or earth.

PROTECTION OF THE FIRE-FIGHTERSBecause of the substances produced during thermal decomposition, use approved self-contained breathing equipmentand protective clothing in case of intervention.________________________________________________________________________________________________

6 - ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS

Avoid contact with eyes, the skin, and clothes: wear at least glasses and gloves.ENVIRONMENTAL PRECAUTIONSDo not allow the product to be thrown away. Recover as much as possible for processing within the firm or by anapproved centre (pH correction necessary).

METHODS FOR CLEANING UPWith water to remove all non-recoverable product. Before throwing rinsing water, check the pH is between 5.5 and 8.5.________________________________________________________________________________________________

7 - HANDLING AND STORAGE

HANDLINGUse as supplied. Close containers (in PE) tightly after use with the original cap. Do not re-use containers with anotherproduct.

STORAGE

Store in a room away from strong acids, metals and organic products. Keep in original containers only, between 5 and30C. The maximum recommended shelf life is three years from the date of manufacture under normal conditions ofstorage.________________________________________________________________________________________________

8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS, TECHNICAL MEASURESNo drinking, eating or smoking on the workplace.Maintain the premises and the workstations in perfect state of cleanliness and clean them frequently.As the product is used at ambient temperature during a short time, the values below are generally not reached. Theydepend on the treatment time, the surface area treated and on the quality of the workshop air extraction.

EXPOSURE LIMIT VALUES IN AIR Sodium hydroxide

France : decisions of 26 October 2007, of30 June 2004, INRS file n ND 2098

Average value (8h)= 2 mg/m3

(INRS file n ND 2098)

Directives 2006/15/EC, 2000/39/EC and91/322/EC

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PERSONAL PROTECTIONProvide a shower, a powerful tap and sink unit, and an eye basin near the workplace.- Respiratory protection: during brush electrolysis, provide if possible an inhaling of the vapours / sprays where they

are created and extraction out of the premises, or at least work in a ventilated room and wear if necessary a filteringFFP3 mask according to EN 149:2001 standard.

- Hand protection: wear imperatively gloves (in latex or nitrile for example).- Eye protection: wear imperatively glasses with lateral protections or a facial screen. Do not wear contact lenses.- Skin protection: wear overalls and safety boots.________________________________________________________________________________________________

9 - PHYSICAL AND CHEMICAL PROPERTIES

- Appearance: colourless liquid- Odour: odourless.- pH: approximately 13.- Relative density: 1.05.- Solubility: miscible in water in all proportions.- Boiling point: approximately 100C.- Crystallisation / melting point: - 4C.- Flammability: no, but some reaction products, for example with metals, can be flammable (risk if formation of

hydrogen in a confined space).- Oxidising properties, risk of explosion or fire: no, or small risk, because the sodium hydroxide concentration is low.

- Other properties: no.________________________________________________________________________________________________

10 - STABILITY AND REACTIVITY

STABILITYGood at normal temperature with water evaporation for only risk.Good in humidity and light.

CONDITIONS TO AVOIDHigh temperatures: decomposition of some constituents from 150C.

MATERIALS TO AVOIDParticularly strong acids, unsaturated organic derivatives, nitroparaffins, chlorinated solvents like 1, 2- dichloroethyleneor trichloroethylene, chlorine, bromine and iodine. Some reactions may be strong, especially if the product has beenconcentrated or dehydrated.Weak action on metals: zinc, copper, lead, aluminium, tin, brass, bronze, because of the small concentration of soda.

HAZARDOUS DECOMPOSITION PRODUCTSLow evolution of hydrogen by action on some metals.Formation of polyacids from 150C and then of unsaturated anhydrides and carbon oxides. Formation of sodium oxidefrom 1250C.________________________________________________________________________________________________

11 - TOXICOLOGICAL INFORMATION

No data are available regarding the preparation. The evaluation of health hazards has been realised thanks todirectives 67/548/EC, 1999/45/EC and bibliographical data.

SKINCauses burns - the severity depends on the length of contact. Beware: the burning sensation is not immediate.

EYE MUCOSAProlonged contact may cause serious damage with possible aftereffects if rinsing is not immediately realized.

RESPIRATORY SYSTEMCauses burns (does not apply under normal conditions of use). Slightly irritant during electrolysis in case of a badinhaling of the vapours / sprays.

IN CASE OF INGESTIONCaustic damage to the digestive system with vomiting. According to the length of contact and to the swallowed quantity,complications may appear in the following days.

OCCUPATIONAL DISEASES: no (in France).________________________________________________________________________________________________

12 - ECOLOGICAL INFORMATION

There are no ecological data on the preparation.Prevent any material from entering drains or waterways or earth .Dangerous to the aquatic environment owing to the alkaline pH.

ECOTOXICITYBibliographic data concerning sodium hydroxide:- In solution (30 %): FISHES - LC50 (96 h) = 72 mg/L- Pure: FISHES - LC50 (96 h) = 125 mg/L, DAPHNIAS - EC50 (48 h) = 40 mg/L

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MOBILITY - PERSISTENCE AND DEGRADABILITY - BIOACCUMULATIVE POTENTIAL OTHER ADVERSEEFFECTSAccording to the available data, the raw materials contained in this preparation are easily biodegradable and are not bioaccumulative.

In line with the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE

ENVIRONMENTto this preparation.

________________________________________________________________________________________________13 - DISPOSAL CONSIDERATIONS

This product and water used for rinsing must not be thrown away in particular because of their pH. They must beprocessed within the firm or destroyed by an approved organization.Contaminated packaging if not re-used with the same product is also a special waste to be sent to an approvedorganization for recycling or disposal.Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (notably2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.

06 03 13*or 11 01 13*

Solid salts and solutions containing heavy metalsDegreasing wastes containing dangerous substances

11 01 11* Aqueous rinsing liquids containing dangerous substances

15 01 10* Packaging containing residues of or contaminated by dangerous substances

As the volume of rinsing water is small, it can be added to the waste solutions.

NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or localprovisions on this topic.________________________________________________________________________________________________

14 - TRANSPORT INFORMATION

A.D.R. (road transport)

Sodium hydroxide solution, class 8, classification code C5, packaging group III, hazard label model 8, restrictedquantities LQ7, hazard identification 80, material identification 1824.

I.M.D.G. (sea transport)

Sodium hydroxide solution, UN N 1824, class 8, packaging group III, subsidiary risk: not applicable, restrictedquantities 5 L, stowing and separation: category A, away from acids, safety sheets F-A, S-B.

I.A.T.A. (air transport)

Sodium hydroxide solution, UN N1824, class 8, subsidiary risk: not applicable, risk label: CORROSIVE, packaging

group: III, Passenger and Cargo aircraft: packaging instructions 819, maximum quantity per package: 5 L, Cargo aircraftonly: packaging instructions 821, maximum quantity per package: 60 L, instruction IDC 8L.________________________________________________________________________________________________

15 - REGULATORY INFORMATION

This safety data sheet has been established in accordance with the Corrigendum to Regulation (EC) n 1907/2006 of theEuropean Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007.The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29

th adaptation:

directive 2004/73/EC of April 29, 2004) and the directive 1999/45/EC reviewed in last in January 23, 2006 by thedirective 2006/8/EC.

EC LABELLING: CORROSIVEAlkaline aqueous preparation containing particularly sodium hydroxide.R34: causes bums.S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S28: after contact with skin, wash immediately with plenty of water.S36/37/39: wear suitable protective clothing, gloves and eye / face protection.S45: in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

HEALTH SURVEILLANCECouncil Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related tochemical agents at workAn appropriate health surveillance of workers must be carried out according to the risk.For each worker who undergoes this health surveillance, individual health and exposure records are to be made and keptup-to-date.

Other paragraphs in the French version of this safety data sheet summarize French rules regarding:

administrative declarations and rules,

environment laws regarding rinsing water treatment.

See specific legislative and administrative, national or local provisions on these topics.Additional information is provided in paragraphs 8, 11, 12, 13 and 14.________________________________________________________________________________________________

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16 - OTHER INFORMATION

RESTRICTION OF USEFor industrial use only.We remain available to bring you the training or advice you may need.

R PHRASES OF THE PURE COMPONENTS LISTED IN SECTION 3R35: causes severe burns.

R PHRASES OF THE PREPARATION ACCORDING TO THE SECTIONS 2 AND 15R34: causes burns.

BIBLIOGRAPHIC REFERENCESEuropean directives, INRS files, safety data sheets of the components established by their manufacturers or distributors,information of European Office of the chemical substances (ECB).

MODIFICATIONSUpdating in relation to directives 2006/8/EC, 2006/15/EC, corrigendum to regulation (EC) n 1907/2006 published in May29, 2007 and French decisions of October 26, 2007.Revised paragraphs: n2, 3, 8, 14, 15, 16.

OTHER INFORMATIONThis sheet is provided to complement, not replace, the user instructions.Information contained herein is bona fide and based on current knowledge relating to the product on the date ofpublication. Furthermore, the attention of the user is drawn to the risks which may be incurred when the product is usedfor purposes other than those for which it is designed.Information provided herein relates to this product only; it cannot take account of every situation which may arise at everywork place. This safety data sheet therefore represents only a part of the information required for establishing a safetyprogramme.Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulationsgoverning its activity, which are not all necessarily quoted herein in an exhaustive manner.________________________________________________________________________________________________

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