evaluation of relevant reflector properties
TRANSCRIPT
Aránzazu Fernández‐Garcí[email protected]
Florian Sutter (DLR)
4th SFERA Summer SchoolDLR
Hornberg, 15th May 2013
Evaluation of relevant reflector properties
4th SFERA Summer SchoolHornberg, 15th May 2013
Contents
1. Introduction2. Solar reflectors 3. Reflectance: soiling and
aging4. Shape
4th SFERA Summer SchoolHornberg, 15th May 2013
Introduction
• Classification
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Concentrator: reflector with the proper shape
4th SFERA Summer SchoolHornberg, 15th May 2013
• Efficiency
Introduction
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solar
lossthoverall P
PK ,
ρ
γτ
αPth,loss
Psolar
4th SFERA Summer SchoolHornberg, 15th May 2013
Macroscopic (concentrator shape)
γ
Microscopic (material scattering)
ρ
• Efficiency
Introduction
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solar
lossthoverall P
PK ,
4th SFERA Summer SchoolHornberg, 15th May 2013
Introduction
• The reflector is the first key component in the energy conversion process of concentrating solar technologies
• Any solar radiation that is not reflected by the mirror in the direction of the receiver is lost to the system
• The feasibility of these technologies strongly depends on the material and manufacturing process used to achieve a suitable solar reflector‒ Appropriate optical properties: reflectance‒ Suitable concetrator geometry: shape ‒ Cost effective component
7
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4th SFERA Summer SchoolHornberg, 15th May 2013
Contents
1. Introduction2. Solar reflectors 3. Reflectance: soiling and
aging4. Shape
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Reflective metals used in solar reflectors
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Silvered thick‐glass reflectors
Low-iron glass (<0.015 %). 4 mm thickness
Reflective layer : Silver (0.7-1.2 g/m2) ReflectanceDurabilityShapeCost
Back layer : Copper (> 0.3 g/m2)
Paint layer (20-2.5% Pb). Pb free: 0.15 %
Paint layer (10-1% Pb). Pb free: 0.15 %
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Silvered thick‐glass reflectors
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Silvered thick‐glass reflectors
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Silvered thin‐glass reflectors
Low-iron glass (<0.015 %). < 1 mm thickness
Reflective layer : Silver (0.8-1.2 g/m2)
Back layer : Cooper
Paint layer (20-2.5% Pb). Pb free: 0.15 %
Paint layer (10-1% Pb). Pb free: 0.15 %
ReflectanceDurabilityCostShape (back)Cost (back)
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Laminated silvered glass reflectors
ReflectanceDurabilityShapeCost
Low-iron glass (<0.015 %). 1.6 mm thickness
Low-iron glass (<0.015 %). 2.3 mm thickness
Reflective layer : Silver
Adhesive layer: Polyvinyl Buytral (PVB)
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Laminated silvered glass reflectors
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Aluminum reflectors
Sol-gel SiO2
SiO2
TiO2
Polished Al substrate
Anodization Al2O3
PVD Al (pure)
CostShapeShape (back) ReflectanceDurability
< 5 μm
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Aluminum reflectors with metal structure
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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• Aluminum reflectors with composite material structure
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Solar reflectors
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• Silvered polymer films
(Kennedy, 2010)
< 5 μm
Anti-soiling Layer
Adhesion Promoting LayerPMMA superstrate
Substrate
Metal back layer: Cu
Reflective layer: Silver
Pressure Sensitive Adhesive (PSA)
CostShapeShape (back) ReflectanceDurability
4th SFERA Summer SchoolHornberg, 15th May 2013
Solar reflectors
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Type of reflector Reflectance
Silvered Thin Glass 0.95Silvered Thick GlassLaminated silvered glass 0.93—0.94Silvered Polymer Film 0.90‐0.93Aluminum 0.83‐0.86
• Reflectance of different solar reflectors
4th SFERA Summer SchoolHornberg, 15th May 2013
Type of reflector Cost ($/m2)Silvered Thick Glass 43‐65Silvered Thin Glass 16‐43Silvered Polymer Film 20‐25Aluminum 20‐22
Solar reflectors
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• Cost of different solar reflectors
(Kennedy and Terwilliger, 2005)
4th SFERA Summer SchoolHornberg, 15th May 2013
Contents
1. Introduction2. Solar reflectors 3. Reflectance: soiling and
aging4. Shape
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance
• To enhance the feasibility of CSP systems, quality and lifetime guarantees of the components must be increased. Those guarantees can only be given with the appropriate testing methods and measurement tools
• The proper optical parameter to evaluate the quality of reflectors is the solar‐weighted specular reflectance
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Solar‐weighted reflectance:Whole solar spectrum
Specularity:Directed to the receiver
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance
• Scheme of specular reflectance
),,( SWs
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4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance
• Reflectance decrease mechanismsAbsorption Scattering/beam spread
• Both mechanisms are produced by these sources
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Soiling deposition:cleaning
Aging due to environmental stress: durability
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance: soiling/cleaning
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• Reflectance decrease due to soiling deposition• Cleaning is one of the main of aspect of maintenance tasks• Cleaning strategy depends on the reflector and the location
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance: soiling/cleaning
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• Cleaning methods typically used are mainly based on water ‒ Minimization of the water consumption by:
• Using some additives (mainly detergents)• Applying a brush, a foam, a tissue, etc.• Collect and reuse!!!!
‒ Optimization of the water treatment to reduce the cost‒ Combination of pressure and temperature of the water to
have a good compromise between efficiency and cost • Dry cleaning methods in some locations because in wet
ambients particles are strongly attached to the reflector surface
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance: soiling/cleaning
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• Anti‐soiling coatings to reduce soiling rate‒ Easy‐to‐clean effect‒ Dust repellent properties
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance: soiling/cleaning
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• Water based methods
(Abengoa)
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance: aging
• Typical guaranties requested involve the goal of 10‐30 years of real time in outdoor exposure with low degradation
• The materials evolve quickly and their competition in the market is strong accelerated conditions are necessary in service lifetime prediction
• Prediction of outdoor lifetime based on accelerated aging is not an easy task because it depends on:– The failure mechanisms, which is specific for each type of reflector– The real outdoor conditions, which depends on the location
• Commercial reflectors change composition and structure32
4th SFERA Summer SchoolHornberg, 15th May 2013
Reflectance: aging
• Degradation mechanisms:
• Factors:
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Top coating: degradation and transmittance loss
Back coating: degradationReflective layer: corrosion
TemperatureHumidity
Radiation (UV)
Chemicals:‐ NaCl
‐ SO2, NOX‐ Particles
Abrasion:‐ Part + wind‐ Cleaning
4th SFERA Summer SchoolHornberg, 15th May 2013
Contents
1. Introduction2. Solar reflectors 3. Reflectance: soiling and
aging4. Shape
4th SFERA Summer SchoolHornberg, 15th May 2013
Shape
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• Concentrator shape must be according to the design to focus the reflected radiation onto the receiver
Paraboloid Paraboloid/spherical/cylindrical
(large radius)
Parabola (cross section)
4th SFERA Summer SchoolHornberg, 15th May 2013
Shape
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• Shape measurement techniques:– Deflectometry (distortion of reflected patterns)– Close‐range photogrammetry (3D point probing)– Flux density measurements (as indirect measurement)– V‐Shot (laser)– Distant observer (inverse optical path)
(Fernández‐Reche and Fernández‐García, 2009)(Ulmer et al., 2008)
(Lüpfert et al., 2007)
4th SFERA Summer SchoolHornberg, 15th May 2013
Shape
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• Intercept factor is calculated by ray‐tracing, usingmeasured shape of the concentrator and considering:
• Results obtained are useful in:‒ Design process‒ Efficiency assessment‒ Quality control
‐ Sun shape‐ Reflector panel alignment
geometry‐ Receiver geometry‐ Receiver real position‐ Tracking accuracy‐ Other factors and loads
4th SFERA Summer SchoolHornberg, 15th May 2013
Thank you for your attention!!!!!
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