eurofillers 2003 (alicante) : 2003.09.08-11preparation and characterization of fillers and...

Universitat d'Alacant

f/—x Universidad de Alicantem

U»WPfiS*TV«r AUCAMTC

PROCEEDINGS

Edited by Jose Miguel Martin Martinez, editor

TIB/UB Hannover

128 602 511

89

CONTENTS

Monday - 8 September 2003 AULARIO II - Conference room

9:30h Plenary "Modified cellulosic fibres as reinforcing fillers for 27

lecture 1 macromolecular matrices". Prof. A. Gandini and N.M.

Belgacem. Ecole Franchise de Papeterie et des Industries

Graphiques. Institut National Polytechnique de Grenoble,S' Martin d'Heres (France).

Session 1. Preparation and characterization of fillers and

nanoparticles.

10:00h Al V. Collin. E. Peuvrel-Disdier. 33

Ecole des Mines de Paris, Centre de Mise en Forme des

Mat6riaux, Sophia-Antipolis, France.

Dispersion mechanisms of carbon black into elastomers

under shear conditions.

10:20h A2 M. Gerspacher.Sid Richardson Carbon Company, Fort Worth, United 37

States.

Carbon black micro-dispersion.

10:40h A3 L. Haurie, A.I. Fernandez, J.I. Velasco, J.M. Chimenos, 41

J.R. Tico Grau, F. Espiell.Unitat de Ciencia de Materials i Enginyeria Metal-liirgica,University of Barcelona, Barcelona, Spain.Synthetic hydromagnesite as flame retardant. A study ofstearic coating process.

ll:30h A4 D.S. Chaudharv, M, Jollands. 45

Rheology and Materials Processing Centre, School of

Civil and Chemical Engineering, Royal Melbourne

Institute of Technology, Melbourne, Australia.

An investigation into surface energetics of rice hull ash

particles using inverse gas chromatography (IGC).

ll:50h A5 K. Buku T. Jesionowski, J. Gutek. 49

Institute of Materials Technology, Polymer Processing

Laboratory, Poznan University of Technology, Poznan,Poland.

Novel silica from emulsion system ~ filler for

thermoplastic polyesters.

<S

12:10h A6 C. Calberg, F. Stassin, R. Jerome. 53

University of Liege, Liege, Belgium.

Surface modification of clays in supercritical carbon

dioxide.

12:30h A7 A. Jada.

Institut de Chimie des Surfaces et Interfaces, Mulhouse, 55

France.

Preparation and characterisation of calcium carbonate

particles in the presence of anionic polyelectrolyte-nonionic block copolymer mixture.

12:50h A8 L. Xinhai, S. Shangyue, L. Yibo, Y. Yousheng, L. Zhen. 59

China University of Geosciences, Wuhan, China.

Preparation and application ofwollastonite powder.

13:10h A9 C. Da Silva. B. Haidar, L. Vidal, J. Miehe-Brendte, R. Lc 63

Dred.

Institut de Chimie des Surfaces et Interfaces, Mulhouse,

France.

Preparation and properties of EPDM/synthetic claynanocomposites.

13:30h A10 V. Tokarev. S. Voronov, O. Bednarska, O. Shevchuk, S. 67

Trotsenko, N. Bukartyk.Institute of Chemistry and Chemical Technologies, Lviv

Polytechnic National University, Lviv, Ukraine.

Surface modification offillers with functional oligomers.

Session 2. Applications of fillers.

15:30h All P. Pen-in, L. Clerc. E. Leroy, A. Bergeret. J.M. Lripez- 71

Cuesta.

Centre des Materiaux de Grande Diffusion (CMGD),Ecole des Mines d'Ales, Ales eedex, France.

Incorporation of SMC recycled fractions as reinforcingfillers in polymers.

15:50h A12 U. Wagenknechl. S. Wiessncr. G. Mennig. 75

Institute of Polymer Research Dresden, Dresden,

Germany.Rubber powder- a perspectivefiller of thermoplastics.

16:10h A13 W.K. Wong.ExxonMobil Chemical Europe, Machelen, Belgium. 79

Reprocessable and easy processing silica filled P.wpro1IM

compound.

6

17:00h A14 A. Artola, J. Garcfa-Jaca. 83

CIDEMCO, Technological Research Centre, Azpeitia,Spain.

Conducting polymer core-shell systems for corrosion

protection.

17:20h A15 M. Bonet S. Mufioz, F. Cases.

Departamento de Ingenieria Textil y Papelera, Escuela 85

Politecnica de Valencia, Alcoy, Spain.Influence of the substituent in the reversibility ofcellulose ethers used as adhesive in artwork

conservation.

17:40h A16 J.L. Stanford, J. Halary, P. Cookson, P.A. Lovell, R.J. 89

Young.

Polymer Science and Technology Group, Materials

Science Centre, University of Manchester and UM1ST,Manchester, UK.

Carbon nanotube-filled polymers for use as remote

strain-sensor coatings.

18:00h A17 S. Kohjiya, Y. Ikeda. 93

Institute for Chemical Research, Kyoto University,

Kyoto, Japan.

Reinforcing effect of silica generated in situ on general-

purpose grade rubbers.

7

Tuesday - 9 September 2003

9:00h Plenary "Preparation, characterisation and properties of 97

lecture 2 nanocomposites based on epoxy resins". Dr. A.

Hartwig, M. Sebald, D. Piitz and L. Aberle. Fraunhofer-

Institut fur Fertigungstechnik und Angcwandte

Materialforschung - Bereich Klebtechnik und Polymere,Bremen (Germany).

Session 3. Characterization of filled materials.

9:30h A18 R. Wache, M.H. Klopffer. S. Gonzalez, P. Mederic. M. 101

Moan.

Applied Chemistry and Physical Chemistry Department,Institut Francais du Petrole, Rueil Malmaison, France.

Maleated polyethylene nanocomposites: influence of claycontent on barrier and melt rheological properties.

9:50h A19 K. Motha, J. Kunnari, R. Teimola. 105

Borealis Polymer Oy, Porvoo, Finland.

Polyolefin nanocomposites via melt-compounding - a

study of influencing variables.

10:1 Oh A20 Yu.A. Nikitin, L.S. Dzyubenko, S.I. Levytska, A.A. 109

Sopynenko, V.V. Brei.

Institute of Surface Chemistry, National Academy of

Sciences, Kiev, Ukraine.

Physico - mechanical properties of the modified

polypropylene of the containing high disperse alumina -

silica.

10:30h A21 L.P. Reuvekamp, J.W.M. Noordermeer. 113

Dept. of Rubber Technology, Twente University, The

Netherlands.

Influence of silica filler distribution on properties of tire

rubber treads, as related to silica characteristics.

U:30h A22 V.P. Privalko. S.M. Ponomarenko, E.G. Privalko, F. 117

Schon, W. Gronski.

Institute of Macromolecular Chemistry, National

Academy of Sciences, Kiev, Ukraine.

Structure and thermoelastic behavior of synthetic

rubber/organoclay nanocomposites.

8

:50h A23 F. Schon, W. Gronski. 121

Institut ftir Makromolekulare Chemie, Albert-Ludwigs-Universitat Freiburg, Freiburg, Germany.Characterization and properties of organoclay nanofillersin rubber composites.

12:10h A24 J. Ramier. M.N, Bouchereau, L. Chazeau, C. Gauthier, E. 125

Peuvrel-Disdier, C. Rochas, L. Stelandre.

Groupe d'Etudes de Metallurgie Physique et de Physiquedes Materiaux, Villeurbanne, France.

Influence of the surface treatment of silica on the

mechanical behaviour of filled elastomers: study by in

situ scattering techniques.

12:30h A25 MA. Rodriguez Perez. J.I. Velasco, D. Arencon, J.A. de 129

Saja.Dept. Ffsica de la Materia Condensada, Facultad de

Ciencias, University of Valladolid, Valladolid, Spain.

Dynamic mechanical behavior of PP/PET blends filledwith glass beads.

12:50h A26 O.I.H. Dimitrv. A.L.G. Saad, HA. Aziz. 133

Petrochemicals Dept., Egyptian Petroleum Research

Institute, Cairo, Egypt.Studies of electrical / mechanical properties and

activation energies of metal-filled polyvinyl chloride)

compositions.

13:10h A27 J. Ziegler. R.H. Schuster.

Deutsches Institut ftir Kautschuktechnologie e.V., 137

Hannover, Germany.

Influence of filler surface modifications on dynamic-

mechanical properties and the distribution of fillers in

rubber blends.

18:30h A28 L. Cabedo, E. Gimenez, J.M. Lagaron, R. Gavara, J.J. 141

Saura.

Dept. of Technology, University Jaume I, Castellon,

Spain.

Influence of kaolinite treatment on the morphology and

properties of EVOH nanocomposites prepared by melt

intercalation.

9

18:50h A29 CM. Liauw, G.C. Lees, R.N. Rothon, F. Wild, J.D. 145

Schofield, D. Thetford, P. Sunderland.

Centre for Materials Science Research, Department of

Chemistry and Materials, Manchester MetropolitanUniversity, Manchester, UK.

The effect of molecular structure of maleimide based

interfacial modifiers on the mechanical properties of

polyolefin/flame retardantfiller composites.

19:10h A30 SJCemg, 0. Shepelev. 149

Israel Plastics and Rubber Center, Polymers and Plastics

Engineering Dept., Shenkar College of Engineering and

Design, Israel.

Fire retardancy ofnano clay composites.

10

Wednesday -10 September 2003

9:00h Plenary "Complex adhesion effects of inorganic nanofillers vs 153

lecture 3 microfillers in polymer composites". Prof. V.

Kovacevic, Dr. M. Leskovac, Dr. S. Lucie Blagojevic and

Dr. D.Vrsaljko. University of Zagreb, Zagreb (Croatia).

Session 4. Adhesion between fillers and polymers.

9:30h A31 J. Vega-Baudrit, V. Navarro-Banon, J.M. Martin- 159

Martinez.

Adhesion and Adhesives Laboratory, University of

Alicante, Alicante, Spain.Nanosilica-polyurethane interactions evidenced by plate-plate rheology andDMTA.

9:50h A32 A. Martmez-Garcia, A. Sanchez-Reche, CM. Cepeda- 163

Jimenez, J.M. Martin-Martinez.

AIJU, Toy Research Institute, Alicante, Spain.

Improved adhesion ofEVA polymers filled with sepiolitetreated with corona discharge.

10:1 Oh A33 J. Magryta. 167

Rubber Research Institute, Piastow, Poland.

Models for the investigation of the vulcanizates structure.

Session 5. Fillers in formulations.

10:30h A34 S. Peeterbroeck, M. Alexandre, J. B. Nagy, C. Pirlot, A. 171

Fonseca, G. Philippin, J. Delnalle, Z. Mekhalif, R.

Sporken, G. Beyer, Ph. Dubois.

Service des Materiaux Polymeres et Composites,Universite de Mons-Hainaut, Mons, Belgium.EVA - layered silicate/carbon nanotubes nanocomposites.

10:50h A35 A. Jada, A. Aue, C. Ducroquetz. 175


France.

Effects of anionic and cationic polyelectrolytes on the

titanium dioxide particle surface charge.

11:50h A36 F. Benard, I. Campistron, A. Laguerre, F. Laval. 179

LCOM-Chimie des polymeres, Universite du Maine, Le

Mans, France.

Ageing ofsilica filled epoxy resins under irradiations.

11

lOh A37 B. Kandasubramanian. M. Gilbert. 183

Institute of Polymer Technology and Materials

Engineering, Loughborough University, Leicestershire,

UK.

Electroconductive fillerfor shielding plastics.

30h A38 G. Schmaucks, B. Friede, J.Q. Roszinski, A. Sorhuus, H. 187

Gesler, J. Hamann.

Elkem ASA, Materials, Kristiansand, Norway.

Surprising effect of a nano-size additive on the propertiesof elastomeric compounds.

50h A39 W. Schober. 191

Schoconsult GmbH, Graz, Austria.

Is submicron talc the future high cost performance nano-

mineralfor polypropylene compounds ?

lOh A40 P. Hornsbv, A. Ahmadnia. 195

Wolfson Centre for Materials Processing, Brunei

University, Uxbridge, UK.

Tailoring the fire retardant performance of filledpolymers using two-component processing technologies.

30h A41 O.G. Ersov, N. Nugav. 199

Chemistry Department and Polymer Research Center,

Bogazici University, Istanbul, Turkey.Selective filler effect on weld line strength of injectedmolded incompatible blend composites.

12

Thursday - 11 September 2003

10:00h Plenary "Concrete and mortars with the addition of mineral 203lecture 4 fillers and coupling agents". F. Sveg, J. Suput-Strupi,

Slovenian National

Building and Civil Engineering Institute, Ljubljana(Slovenia).

Session 6. General and miscellaneous aspects related to fillers.

10:30h A42 P. Brown, S. Marceau, P. Mele, N.D. Alberola. 209

Laboratoire Materiaux Organiques a ProprietesSpecifiques, University of Savoie, Le Bourget-du-Lac,France.

Molecular dynamics studies of model silica-polymernanocomposite systems.

10:50h A43 Al.V. Khavrvutchenko, V.D. Khavryutchenko. 213

Chemistry Dept., Kiev National Taras Shevchenko

University, Kiev, Ukraine.

Global stochastic optimization of nanoparticle structure -

new method for investigation of amorphous substances

thermal stability based on quantum chemistry simulation.

ll:10h A44 S. Abed. W. Knapp. V. Boschat, J.Y. Charmeau, P. 217

Laurens.

Ecole Superieure de Plasturgie, Oyonnax cedex, France.

Analysis of additional absorbers for laser welding ofcoloured thermoplastics.

12:00h A45 D.H. McQueen, K.M. Jager, M. Paligova. 221

Pepartment of Materials Science and Engineering,Chalmers University of Technology, Gdteborg, Sweden.

Multiple threshold percolation in polymer/fillercomposites.

12:20h A46 P. Mele, S. Marceau, D. Brown, N.D. Alberola. 225

Laboratoire Materiaux Organiques a ProprietesSpecifiques, University of Savoie, Le Bourget-du-Lac,France.

Reinforcement effects in nanocomposites enhanced by

aggregation and percolation phenomena.

13

12:40h A47 V. Collin. P. Navard. S. Patlazhan, E.Peuvrel-Disdier. 229

Ecole des Mines de Paris, Centre de Mise en Forme des

Materiaux, Sophia-Antipolis, France.

Infiltration of polymers into porous agglomerates: effect

ofexternaI forces.

13:00h A48 A.T. Ponomarenko, V.G. Shevchenko, V.V. Travkin. 233

Enikolopov Institute of Synthetic Polymeric Materials,

Moscow, Russia.

Anisotropy of physical properties in polymer composites

-fundamental and applied consequences.

15:00h A49 V.G. Shevchenko, A.T. Ponomarenko. 237

Enikolopov Institute of Synthetic Polymeric Materials,

Moscow, Russia.

Synthetic dielectrics from "conducting core-dielectric

shell"fibers: electromagnetic properties.

15:20h A50 A. Tracz, I. Kucinska, J.K. Jeszka. 241

Center of Molecular and Macromolecular Studies, Polish

Academy of Sciences, Lodz, Poland.

AFM studies of PE crystallization at polymer melt / solid

surface interface; model systems.

15:40h A51 P. Burgentzle, J. Duchet, J.F. Gerard, B. Fillon, A. Jupin. 245

Laboratoire des MateYiaux Macromole'culaires, Institut

National Des Sciences Applique'es de Lyon, Villeurbanne,France.

Study of clay/solvent interactions for varnish

formulations.

14

POSTER SESSION

1. Preparation and characterization of fillers and

nanoparticles.

Bl H. Angellier, S. Molina-Boisseau, A.Dufresne. 251

Equipe Structure et Proprietes des Glycomateriaux,Centre de Recherche sur les Macromolecules Vegetales,Grenoble cedex, France.

Starch nanocrystalsfillers.

B2 S.I. Levytska, A.G. Grebenyuk, V.V. Brei. 255

Institute of Surface Chemistry of the National Academyof Sciences, Kiev, Ukraine.

Vapour-phase oligomerization of some vinyl monomers

on the surface of high disperse aluminium - and titanium

- containing silicas.

B3 J. Zurawska, A. Krysztafkiewicz, T. Jesionowski, K. 259

Bula.

Institute of Materials Technology, Polymer ProcessingLaboratory, Poznan University of Technology, Poznan,Poland.

Silicas precipitated from solutions of sodium metasilicate

and of ammonium salts.

B4 J. Moczo, T. Frater, E. Fekete, B. Pukanszky. 263

Research Laboratory of Materials and Environmental

Chemistry, Chemical Research Center, HungarianAcademy of Sciences, Budapest, Hungary.Coating of CaCC>3 with a perfluoroctanoic acid: coatingconditions and surface characteristics.

B5 A. Jada, A. A. Chaou. 265


France.

Effect of silica surface characteristics on its adsorptive

properties.

B6 L. Kovarova, T. Peprnicek, A. Kalendova, J. Malac, J. 269

Simonik.

Faculty of Technology, Tomas Bata University in Zlin,

Nam, Czech Republic.Structure analysis ofPVC nanocomposites.

15

B7 T. Dobrilova, S. Nenkova, S. Vasileva, M. Natov. 273

University of Chemical Technology and Metallurgy,

Sofia, Bulgaria.

Modification of organic fillers from plant origin for

polymer composites.

B8 L.D. Ventura.

The Manchester Metropolitan University, Manchester, 275

United Kingdom.A fundamental study ofprotection and controlled release

oforganic additives using porous silicas.

2. Applications of fillers.

B9 M. Gajewski, Z. Czempinska-Switalska, J. Rudecka. 279

Private University of Environmental Protection, Radom,

Poland.

Application of microspheres wastes in rubber aftermodified with aide ofsilanes.

BIO M.LI. Maspoch, H.E. Ferrando, D. Vega, A. Gordillo, J.I. 281

Velasco, A.B. Martinez.

Centre Catala del Plastic, Universitat Politecnica de

Catalunya, Terrassa, Spain.The effect of glass fibre and phosphorus-containing

flame retardant on theflammability of recycled PET.

Bll L.R.M. Estevao, M. Le Bras, R. Delobel, R.S.V. 285

Nascimento.

Intituto de Quirnica, Universidade Federal do Rio de

Janeiro, Rio de Janeiro, Brazil.

Increasing flame retardancy of polyethylene intumescent

formulations by using waste refinery catalyst as a filler.

B12 R. Al Akoum, B. Haidar, H. Balard, A. Vidal. 289


France.

Effect of silica particle size on polymer adsorption.

Morphological, energetic and conformational

relationship.

3. Characterization of filled materials.

B13 T. Alekseeva, Y. Lipatov, N. Babkina, S. Grishchuk. 293

Institute of Macromolecular Chemistry of National


Peculiarities of kinetics formation of interpenetratingpolymer networks and their viscoelastic properties in the

presence ofmodified silica.

16

B14 R. Balart, F. Parres, J. Lopez, D. Garcia. 297

Dept. of Mechanical and Materials Engineering, HigherPolytechnic School of Alcoy- Polytechnic University of

Valencia, Alcoy, Spain.Predictive models of ethylene-vinyl acetate (EVA)copolymers with powdered Znfillers.

B15 K. Bula, J. Janik, T. Jesionowski, A. Krysztafkiewicz. 301Institute of Materials Technology, Polymer ProcessingLaboratory, Poznan University of Technology, Poznan,Poland.

Influence of low fraction nanosized silica content on

thermo-mechanical behaviour ofPET and PBT.

B16 F. Dalmas, J. Michelozzi, L. Chazeau, J. Cavaille, S. 305

Azizi, F. Alloin, A. Dufresne, M. Paillet.

Groupe d'Etudes de Metallurgie Physique et de Physiquedes Materiaux, Villeurbanne, France.

Influence of large aspect ratio nanofiller on the

mechanical behaviour of semi-crystalline polymer.

B17 A. Liszewska, B. Bednarek, M. Zaborski. 309

Institute of Polymers, Faculty of Chemistry, The

Technical University of Lodz, Lodz, Poland.

Properties ofelastomer - clay hybrid nanocomposites.

B18 J. Ldpez, A. Nadal, P. Stefani, D. Garcia. 311

Dept. of Mechanical and Materials Engineering, HigherPolytechnic School of Alcoy- Polytechnic University of

Valencia, Alcoy, Spain.Husk rice asfiller ofrecycling rubber.

B19 P. Mederic, I. Razafinimaro, T. Aubry, M. Moan, M.H. 315

Klopffer.Laboratoire de Rheologie, Universite de BretagneOccidentale, Brest, France.

Rheological and structural investigation of polymer/claynanocomposites: influence of processing conditions and

volume fraction effects.

B20 S. Mrkvickova, A. Blaha, R. Pavlica.

Faculty of Technology, Tomas Bata University in Zlin, 319

Nam, Czech Republic.Thermal conductivity of composite produced by

pultrusion process.

11

B21 T. Peprnicek, L. Kovarova, J. Malac, J. Simonik. 321

Faculty of Technology, Tomas Bata University in Zlin,

Nam, Czech Republic.The effect of conditions on nanocomposites PVC paste /

clay preparing.

B22 V.M. Karaman, V.P. Privalko, E.G. Privalko, B. 325

Lehmann, K. Friedrich.



Structure/property relationships for polyamided/organo-

clay nanocomposites in the melt and in the solid state.

B23 O. Ya. Uruypina, N.V. Serebryakova, V.I. Roldughin. 329

Institute of Physical Chemistry of RAS, Moscow, Russia.

The study of sedimentation stability of titanium phosphate

nano-particles in polymer solutions.

B24 N. Lopez, L. Sanchez, A. Jimenez, J.E. Crespo. 333

Dept. of Mechanical and Materials Engineering, Higher

Polytechnic School of Alcoy- Polytechnic University of

Valencia, Alcoy, Spain.Kinetic studies on the thermal degradation of reinforced

longfiber polypropylene.

B25 T.A. Shantalii. I.L. Karpova, K.S. Dragan, E.G. Privalko, 335

V.P. Privalko.



Synthesis and structure/property relationships forpolyimides reinforced with the sol-gel derived

nanoparticles.

B26 D.L. Starokadomskv.

Institute of Surface Chemistry, National Academy of 339


New about a SiOz nanofilled photopolymer acrylate

compositions: polymerisation, mechanisms, structure.

B27 I. Kucinska, A. Tracy.. J.P. Chapel, G. Boiteux, J.K. 341

Jeszka.



Why does the surface offreshly cleaved mica have a weak

influence on polyethylene crystallization from the melt?

18

B28 A. Tracz. I. Kucinska, J.K. Jeszka. 345



Crystallization of PE on model atomically flat surfaces in

the presence ofnano- and micro-particles ofgold.

B29 M.V. Tsebrenko. N.M. Rezanova, LA. Tsebrenko. 349

Kiev National University of Technologies and Design,Kiev, Ukraine.

Structure and properties of polymer composites filled byoriented microfibers.

B30 M. Tyburczv, M. Zaborski, W. Baryn. 353

Institute of Polymers, Technical University of Lodz,

Lodz, Poland.

The effect of surfactants on the properties of filledelastomer.

B31 J.I. Velasco, M. Ardanuy, L. Miralles, S. Ortiz, M.LI. 357

Maspoch, M. Sanchez-Soto, O.O. Santana.

Centre Catala del Plastic, Universitat Politecnica de

Catalunya, Terrassa, Spain.Polypropylene/undecyl ammonium montmorillonite

nanocomposites. Synthesis and characterization.

B32 J.L. Stanford. P. Navabpour, P.A. Lovell. 361

Polymer Science and Technology Group, Materials

Science Centre, University of Manchester and UMIST,

Manchester, UK.

Polymer-encapsulated carbon blacks as fillers in

thermoplastics.

B33 A. Leykin, M. Ioelovich, O. Figovsky. 363

The Israel Research Center, Polymate Ltd., Migdal

HaEmek, Israel.

Polymer composites containing nanofillers of various

types.

B34 V. Pascual-Sanchez. M.S. EsttSbanez-Rodnguez, J.M. 365

Martin-Martinez.

Adhesion and Adhesives Laboratory, Dept. of Inorganic

Chemistry, University of Alicante, Alicante, Spain.Addition of fumed silica to increase the mechanical

performance of epoxy resin coatings for "marron

imperial" marble.

19

B35 M.W. Backer, CA. Buesing, J.L. Dingman, J.M. 369

Gohndrone, S. Hu, W.C. Maki, B. Thomas, H.Yue, S.K.

Mealey.Dow Corning Ltd., South Glamorgan, Wales, UK.

Use of LC, NMR and MS for sulfidosilane material

characterization.

B36 L. Danyadi, J. Moczo, Z. Mezey, T. Czigany, B. 373

Pukanszky.

Dept. of Plastics and Rubber Technology, Budapest

University of Techonology and Economics, Budapest,

Hungary.Sisalfiber reinforced polypropylene composites.

4. Adhesion between fillers and polymers.

B37 A. Martinez-Garcia, A. Sanchez-Reche, CM. Cepeda- 375

Jimenez, J.M. Martin-Martinez.

AIJU, Toy Research Institute, Ibi, Spain.

Influence ofthe particle size ofCaCOj on the adhesion of

filled EVA materials.

5. Fillers in formulations.

B38 Ye.P. Mamunva, H. Zois, E.V. Lebedev, L. Apekis. 379



Electrical conductivity of metal fillers depending on the

applied pressure.

B39 VA. Tertvkh. Yu.N. Bolbukh, V.V. Yanishpolskii. 383

Institute of Surface Chemistry, National Academy of


Effect of initial and modified fumed silicas on polymerizaofof 2-hydroxyethylmethacrylate.

B40 A. Leuteritz, D. Pospiech, B. Kretzschmar, M. Willeke, 387

D. Jehnichen, U. Jentzsch, K. Grundke, A. Janke.

Institute of Polymer Research, Dresden, Germany.Polypropylene-clay nanocomposites: comparison of

different layered silicates.

B41 P. Liu, J. Tian, W. Liu, Q. Xue. 391

Chemistry Dept., Lanzhou University, Lanzhou, China.

Grafting of hyperbranched poly (amine esterj onto silica

nanoparticles.

20

B42 A.P. Duarte, S. Filipe, M.T. Cidade, J.C.M. Bordado. 395

ICTPOL, 1ST, Departamento de Quimica, Lisboa,

Portugal.In-situ reinforcement of PP with a liquid crystalline

polymer: synthesis of a compatibilizer and mechanical

properties of the compatibilized blends.

B43 M. S. Estebanez-Rodrfguez, V. Pascual-Sanchez, J.M. 399

Martin-Martinez.


Chemistry, University of Alicante, Alicante, Spain.Addition of marble wastes as filler of unsaturated

polyester resins.

B44 M.D. Landete-Ruiz, J.M. Martin-Martinez. 403


Chemistry, University of Alicante, Alicante, Spain.

Influence of the filler in the effectiveness of the UV

treatment ofEVA formulations.

B45 A. Martinez-Ruiz, P. Aran-Ais, A. Torro-Palau, A.C 407

Orgiles-Barcelo, J.M. Martin-Martinez.

INESCOP, Footwear Research Institute. Elda, Spain.

Influence of the particle size and shape of sepiolite as

filler in thermoplastic polyurethane adhesives.

B46 A.B. Munoz-Milan, MA. Perez-Liminana, F. Aran-Ais, 411

A.Torro-Palau, A.C. Orgiles-Barcelo.INESCOP, Footwear Research Institute. Elda, Spain.

Effect of the amount of calcium carbonate in the

rheological and adhesive properties of a water-based

polyurethane dispersion.

6. General and miscellaneous aspects related to fillers.

B47 LA. Golotina, L.L. Kozhevnikova. 415

Institute of Continuous Media Mechanics UB RAS, Perm,

Russia.

Continuum description of the mechanical behavior of

particulate composites using electronic spreadsheets.

B48 Al.V. Khavrvutchenko, V.D. Khavryutchenko. 419

Chemistry Dept., Kyiv National Taras Shevchenko

Univesity, Kiev, Ukraine.

Formation of fumed silica protoparticles in the

atmosphere ofrigid molecules: quantum chemistry study.

21

B49 V.D. Khavrvutchenko, Al.V. Khavryutchenko, Yu. A. 423

Tarasenko.

Institute for Sorption and Endoecology Problems,

National Academy of Science of Ukraine, Kiev, Ukraine.

Carbon nanoparticle - organic polymer matrix

interaction. Quantum chemistry point of view.

B50 Yu.V. Savelyev, L.P. Robota, T.V. Travinskaya, E.G. 427

Privalko.



Polyurethane-active carbon composite materials: model

systems.

B51 Yu.V. Savelyev, L.P. Robota, T.V. Travinskaya, V.V. 431

Shilov, S. Kripotou, P. Pissis.

Institute of Macromolecular Compounds, National


Polyurethane - layered silicate.

B52 Yu.V. Savelyev, O.A. Savelveva, N.T. Kartel. 435

Institute of Macromolecular Compounds, National


Polyurethane foam-active carbon sorbic compositesystems.

B53 V.V. Shilov, Yu.P. Gomza, V.I. Padalko. 439



Fine and fractal structure of nanodiamond as perspectivefiller of polymer nanocomposites.

B54 L. Alexandrescu, M. Leca.

INCDTP, Division Leather and Footwear Research 443

Institute, Bucharest, Romania.

Grafted polycloroprenic adhesive, used for cured rubber

protection footwear.

BS5 V. Rosculct, F. Harnagea. 447

INCDTP, Division Leather and Footwear Research

Institute, Bucharest, Romania.

Aspects regarding the use of water based adhesives in

footwear industry.

B56 M.D. Romero-Sanchez. J.M. Martin-Martinez, M.J. 451

Walzak.

Adhesion and Adhesives Laboratory, Dept. of InorganicChemistry, University of Alicante, Alicante, Spain.Improved adhesion of SBS rubber containing calcium

carbonatefiller by treatment with UV radiation.

22

B57 J. Vega-Baudrit, M. Moya-Portuguez, M. Duran- 455

Chavarria, Maria Sibaja.Laboratorio de Polimeros (POLIUNA), Universidad

Nacional, Heredia, Costa Rica.

Biodegradable polyurethanesfrom pineapple wastes.

23

eurofillers 2003 (alicante) : 2003.09.08-11preparation and characterization of fillers and...

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