emulso safety data sheet t - otter tail county, mn...emulso safety data sheet issue date:...

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T <r u* Road Repair & Maintenance emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product Name Other means of identification SDS# E-014 Recommended use of the chemical and restrictions on use Recommended Use Asphalt sealer. Details of the supplier of the safety data sheet Supplier Address Emulso Corporation 2750 Kenmore Avenue Tonawanda, NY 14150 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) Appearance Amber liquid Classification Phone:716-854-2889 Fax:716-854-2809 INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Physical State Liquid Version 1 Odor Characteristic Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard Statements Causes skin irritation Causes serious eye damage Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Page 1/7

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Page 1: emulso Safety Data Sheet T - Otter Tail County, MN...emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product

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Road Repair & Maintenance

emulso Safety Data Sheet

Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015

1. IDENTIFICATION

Glenzoil 20+

Product Identifier

Product Name

Other means of identification

SDS# E-014

Recommended use of the chemical and restrictions on use

Recommended Use Asphalt sealer.

Details of the supplier of the safety data sheet

Supplier AddressEmulso Corporation2750 Kenmore Avenue

Tonawanda, NY 14150

Emergency Telephone Number

Company Phone Number

Emergency Telephone (24 hr)

Appearance Amber liquid

Classification

Phone:716-854-2889

Fax:716-854-2809

INFOTRAC 1-352-323-3500 (International)1-800-535-5053 (North America)

2. HAZARDS IDENTIFICATION

Physical State Liquid

Version 1

Odor Characteristic

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 1

Signal Word

Danger

Hazard Statements

Causes skin irritation

Causes serious eye damage

Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handlingWear protective gloves/protective clothing/eye protection/face protection

Page 1/7

Page 2: emulso Safety Data Sheet T - Otter Tail County, MN...emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product

E-014- Glenzoil20+ Revision Date: 28-Aug-2015

Precautionary Statements - Response >^^IF IN EYES: Rinse cautiously withwater for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsingImmediately call a poison center or doctor/physicianIF ON SKIN: Wash with plenty of soap and waterIf skin irritation occurs: Get medical advice/attentionTake off contaminated clothing and wash it before reuse

Other Hazards

Toxicto aquatic lifewith long lasting effects

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%Tall oil 8002-26-4 10-15

Potassium hydroxide 1310-58-3 1-5

"If Chemical Name/CAS No is"proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentageof composition has been withheld as a trade secret.**

First Aid Measures

General Advice

Eye Contact

Skin Contact

Inhalation

Ingestion

4. FIRST-AID MEASURES

Provide this SDS to medical personnel for treatment.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy todo. Continue rinsing. Immediately call a poison center ordoctor/physician.

IF ON SKIN: Wash with plentyof soap and water. If skin irritation occurs: Get medicaladvice/attention. Takeoff contaminated clothing and wash itbefore reuse.

Remove to fresh air.

Clean mouth with water anddrink afterwards plenty ofwater.

Most important symptoms and effects

Symptoms Causes skin irritation. Causes serious eye damage.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media Not determined.

Specific Hazards Arising from the ChemicalNot determined.

Protective eguipment and precautions for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.

Page 2/7

Page 3: emulso Safety Data Sheet T - Otter Tail County, MN...emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product

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E-014- Glenzoil20+

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Use personal protectiveequipment as required.

Environmental Precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage ifsafe to do so.

Methods for Clean-Up Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Revision Date: 28-Aug-2015

Precautions for safe handling

Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands,and any exposed skin thoroughly after handling. Wear protective gloves/protective clothingand eye/face protection.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Materials None known based on information supplied.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical Name ACGIH TLV OSHAPEL NIOSH IDLH

Potassium hydroxide1310-58-3

Ceiling: 2 mg/m3 (vacated) Ceiling: 2 mg/m3 Ceiling: 2 mg/m3

Appropriate engineering controls

Engineering Controls Apply technical measures to comply with the occupational exposure limits.

Individual protection measures, such as personal protective eguipment

Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations.

Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection.

Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical StateAppearanceColor

LiquidAmber liquidAmber

Page 3/7

Odor

Odor Threshold

Characteristic

Not determined

Page 4: emulso Safety Data Sheet T - Otter Tail County, MN...emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product

E-014- Glenzoil20+

O Property

PHMelting Point/Freezing PointBoiling Point/Boiling RangeFlash Point

Evaporation RateFlammability (Solid, Gas)Upper Flammability LimitsLower Flammability LimitVapor PressureVapor DensitySpecific GravityWater SolubilitySolubility in other solventsPartition CoefficientAuto-ignition TemperatureDecomposition TemperatureKinematic ViscosityDynamic ViscosityExplosive PropertiesOxidizing Properties

Values

Not determined

Not determined

Not determined

Not determined

Not determined

Liquid- Not ApplicableNot determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Not determined

Remarks • Method

10. STABILITY AND REACTIVITY

Reactivity

Not reactive under normal conditions.

Chemical Stability

Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Conditions to Avoid

Keep out of reach of children.

Incompatible Materials

None known based on information supplied.

Hazardous Decomposition ProductsNone known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Eye Contact

Skin Contact

Inhalation

Ingestion

Causes serious eye damage.

Causes skin irritation.

Do not inhale.

Do not ingest.

Page 4 / 7

Revision Date: 28-Aug-2015

Page 5: emulso Safety Data Sheet T - Otter Tail County, MN...emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product

T

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E-014- Glenzoil20+ Revision Date: 28-Aug-2015

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50Tall oil

8002-26-4= 7600 mg/kg ( Rat)

--

Potassium hydroxide1310-58-3

= 284mg/kg (Rat)- -

Information on physical, chemical and toxicoloqical effects

Symptoms Please see section 4 ofthis SDSfor symptoms.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Carcinogenicity

Numerical measures of toxicity

Not determined

Based on the information provided, this product does not contain any carcinogens orpotential carcinogens as listed by OSHA, IARC or NTP.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Toxic to aquatic lifewith long lasting effects.

Component Information

Chemical Name Algae/aquatic plants Fish Toxicity tomicroorganisms

Crustacea

Tall oil

8002-26-4

0.87: 72 h

Pseudokirchneriella

subcapitata mg/L EC50

5.0 -10.0: 96 h Brachydaniorerio mg/L LC50 static

39.7: 48 h Daphnia magnamg/L EC50

Potassium hydroxide1310-58-3

80: 96 h Gambusia affinis

mg/L LC50 static

Persistence/Degradability

Not determined.

Bioaccumulation

Not determined.

Mobility

Chemical Name Partition Coefficient

Tall oil

8002-26-4

3.5-5.4

6.1-8.2

Potassium hydroxide1310-58-3

0.65

0.83

Other Adverse Effects

Not determined

Waste Treatment Methods

Disposal of Wastes

Contaminated Packaging

13. DISPOSAL CONSIDERATIONS

Disposal should be in accordance with applicable regional, national and local laws andregulations.

Disposal should be in accordance with applicable regional, national and local laws andregulations.

Page 5/7

Page 6: emulso Safety Data Sheet T - Otter Tail County, MN...emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product

u

E-014 - Glenzoil 20+ Revision Date: 28-Aug-2015

California Hazardous Waste Status

Chemical Name California Hazardous Waste Status

Potassium hydroxide1310-58-3

14. TRANSPORT INFORMATION

Toxic

Corrosive

Note

DOT

IATA

IMDG

Marine Pollutant

Please see current shipping paper formost up to date shipping information, includingexemptions and special circumstances.

Not regulated

Not regulated

This material may meet the definition of a marine pollutant

15. REGULATORY INFORMATION

International Inventories

Chemical Name

Tall oil

TSCA

Present

DSL

X

NDSL EINECS

Present

ELINCS ENCS

Present

IECSC

X

KECL

Present

PICCS

X

AICS

XPotassium hydroxide Present X Present Present X Present X X

Legend:TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

EINECS/EUNCS -European Inventory ofExisting Chemical Substances/European List ofNotified Chemical SubstancesENCS - Japan Existingand New ChemicalSubstances

IECSC - China Inventory of Existing Chemical Substances

KECL - KoreanExistingand EvaluatedChemicalSubstances

PICCS- Philippines Inventory of Chemicals and Chemical SubstancesAICS- Australian Inventory of Chemical Substances

US Federal Regulations

CERCLA

This material, as supplied, contains one or more substances regulated as ahazardous substance under the ComprehEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) ensive

Chemical Name

Potassium hydroxide1310-58-3

SARA 313

Hazardous Substances RQs10001b

CERCLA/SARA RQ Reportable Quantity (RQ)RQ 1000 lb final RQRQ 454 kg final RQ

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122 21and 40 CFR 122.42)

Chemical Name

Potassium hydroxide

US State Regulations

CWA - ReportableQuantities

1000 1b

CWA - Toxic Pollutants

Page 6/7

CWA - Priority Pollutants CWA - Hazardous

Substances

Page 7: emulso Safety Data Sheet T - Otter Tail County, MN...emulso Safety Data Sheet Issue Date: 25-Aug-2015 Revision Date: 28-Aug-2015 1. IDENTIFICATION Glenzoil 20+ Product Identifier Product

T

-

E-014- Glenzoil20+

California Proposition 65

This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Revision Date: 28-Aug-2015

Chemical Name New Jersey Massachusetts PennsylvaniaPotassium hydroxide

1310-58-3

X X X

16. OTHER INFORMATION

NFPA

HMIS

Issue Date:

Revision Date:

Revision Note:

Health Hazards

Not determined

Health Hazards

Not determined

FlammabilityNot determined

FlammabilityNot determined

25-Aug-201528-Aug-2015New format

InstabilityNot determined

Physical HazardsNot determined

Special HazardsNot determined

Personal Protection

Not determined

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.

End of Safety Data Sheet

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