elleti group srl - benettongroup.com · tss -total suspended solid x cod ... any changes or...

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ATTACHED TO REPORTS 17.45097R1 – 17.45099R1 – 17.45100R2 Page 1 of 2 APPLICANT DATE: 24/10/2017 DATE REVISION (R1): 06/11/2017 BENETTON GROUP Srl DATE REVISION (R2): 08/11/2017 Via Villa Minelli, 1 PAGE: 3 31050 Ponzano Veneto (TV) Facility: ELLETI GROUP srl – Via del Lavoro 9, 37047 San Bonifacio (VR) Sample Description: INCOMING WATER Date and hour of sampling: 3/10/2017 Start: h 9:10 - End: h 12:10 Sampling location: Well Water Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: GITA03102017-01 Sample Description: RAW WASTEWATER Date and hour of sampling: 3/10/2017 Start: h 9:25 - End: h 12:25 Sampling location: Collection Tank Before Homogenization Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: GITA03102017-01 Sample Description: TREATED WATER Date and hour of sampling: 3/10/2017 Start: h 9:50 - End: h 12:50 Sampling location: Inspection Well (Dugaletta) Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: GITA03102017-01 NOTE: NOTE ON REVISED (R1): We revised this report in order to update the grid, as requested by the Client. NOTE ON REVISED (R2): We revised this report in order to correct the value of Total suspended solid (TSS) due to a typing mistake.

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Page 1: ELLETI GROUP SRL - benettongroup.com · TSS -Total suspended solid X COD ... any changes or modifications of this test report. ... Conclusion: See results

ATTACHED TO REPORTS 17.45097R1 – 17.45099R1 – 17.45100R2

Page 1 of 2

APPLICANT

DATE: 24/10/2017 DATE REVISION (R1): 06/11/2017

BENETTON GROUP Srl DATE REVISION (R2): 08/11/2017

Via Villa Minelli, 1 PAGE: 3

31050 Ponzano Veneto (TV)

Facility: ELLETI GROUP srl – Via del Lavoro 9, 37047 San Bonifacio (VR)

Sample Description:

INCOMING WATER Date and hour of sampling: 3/10/2017 Start: h 9:10 - End: h 12:10 Sampling location: Well Water Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: GITA03102017-01

Sample Description:

RAW WASTEWATER Date and hour of sampling: 3/10/2017 Start: h 9:25 - End: h 12:25 Sampling location: Collection Tank Before Homogenization Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: GITA03102017-01

Sample Description:

TREATED WATER Date and hour of sampling: 3/10/2017 Start: h 9:50 - End: h 12:50 Sampling location: Inspection Well (Dugaletta) Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: GITA03102017-01

NOTE: NOTE ON REVISED (R1): We revised this report in order to update the grid, as requested by the Client. NOTE ON REVISED (R2): We revised this report in order to correct the value of Total suspended solid (TSS) due to a typing mistake.

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Page 2 of 2

1A) CONVENTIONAL PARAMETERS (TREATED WATER 17.45100)

Foundational Progressive Aspirational

Temperature X TSS -Total suspended solid X

COD - Chemical oxygen demand X pH - Colour X BOD5 - Biological oxygen demand (5 days) Exceeded Total-P - Total phosphorus X Oil and Grease X Phenol X Metals X Cr (VI) - Hexavalent Chromium X Total-N - Total nitrogen X Ammonium-N - Ammonium nitrogen X Sulfide X Sulfite X Persistent Foam X Cyanide X AOX X Coliform X

ZDHC MRSL PARAMETERS INCOMING WATER (17.45097R1)

RAW WASTEWATER (17.45099R1)

TREATED WATER (17.45100R1)

2A) Alkylphenol and Alkylphenol ethoxylates N/R ! N/R 2B) Chlorinated Benzenes and Toluenes N/R ! N/R 2C) Chlorophenols N/R ! N/R 2D) Azo-dyes N/R ! N/R 2E) Colourants - Carcinogenic N/R ! N/R 2F) Colourants – Disperse N/R ! N/R 2G) Flame Retardants N/R ! N/R 2H) Glycols N/R ! N/R 2I) Halogenated solvents N/R ! N/R 2J) Organotin compounds ! " N/R 2K) Perfluorinated compounds (PFCs) N/R ! N/R 2L) Phthalates N/R ! N/R 2M) Polycyclic aromatic hydrocarbons N/R ! N/R 2N) Organic Volatile compounds ! " N/R Metals N/R ! ! Cr (VI) - Hexavalent Chromium ! " ! Cyanide N/R ! !

Note/Key:

" : Detected ! : Not Detected N/R : Not Requested N/A : Not Applicable

Chemical Laboratory Supervisor Claudio Sironi

REMARKS 1. It is prohibited the partial reproduction, any changes or modifications of this test report. The results are

exclusively referred to the samples tested.

Page 3: ELLETI GROUP SRL - benettongroup.com · TSS -Total suspended solid X COD ... any changes or modifications of this test report. ... Conclusion: See results

Issue date:05 Oct 2017201724 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45097R1a Rev. No.: 1 dated 6 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45097R1

17.45097R1a

This report cancels and replaces the previous one (17.45097) issued on 24/10/17.

Cr VIIdentification Parts

Incoming water - ELLETI GROUP srl, Via del Lavoro 9, 37047 San Bonifacio (VR)SAMPLE DESCRIPTION (no. 372627)

Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

Incoming Water < 0,001

The results expressed are in mg/L.

The symbol < followed by a number indicates that the concentration of the substance is lower than the limit of

quantification (LOQ)

Legend:

Requirements:

Conclusion: See results.

Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:

page 1 of 3MD Standard Report CH_v5/14

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Identification Parts Results

52008

TEST REPORT: 17.45097R1a Rev. No.: 1 dated 06 November 2017

Organotin Compounds

Method: According to ISO 17353

Instrument: Gas - Chromatograph with Mass Detector (GC-MSD)

T F A RD

This report cancels and replaces the previous one (17.45097) issued on 24/10/17.

MET

DMT

TMT

MBT

DBT

TBT

MPT

DPT

TPT

MOT

DOT

TOT

Multiple

Multiple

Multiple

Multiple

Multiple

Multiple

Multiple

Multiple

Multiple

Multiple

Multiple

Multiple

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

< 0,01

Incoming Water

The results expressed are in µg/L.

The symbol < followed by a number indicates that the concentration of the element is lower than the limit of

quantification (LOQ)

MET : Monomethyltin; - DMT: Dimethyltin; - TMT : Trimethyltin; MBT : Monobutyltin; - DBT : Dibutyltin; - TBT :

Tributyltin; - MPT : Monophenyltin; - DPT : Diphenyltin; - TPT : Triphenyltin; - MOT : Monooctyltin; - DOT : Dioctyltin; -

TOT : Trioctyltin.

Legend:

According to ISO 17353 Organotin CompoundsRequirements:

Conclusion: See results.

Reference:

Note:

page 2 of 3MD Standard Report CH_v5/14

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Identification Parts

52012

TEST REPORT: 17.45097R1a Rev. No.: 1 dated 06 November 2017

Volatile Organic Compounds

Method: According to ISO 11423-1

Instrument: GC-MS headspace

T F A RD

This report cancels and replaces the previous one (17.45097) issued on 24/10/17.

Benzene

Xylene

o-cresol

p-cresol

m-cresol

71-43-2

1330-20-7

95-48-7

106-44-5

108-39-4

< 1

< 1

< 1

< 1

< 1

Incoming Water

The results are expressed in µg/L.

The symbol < followed by a number indicates that the concentration of the substances is lower than the limit of

quantification (LOQ)

Legend:

According to ISO 11423-1 Volatile Organic Compounds (VOC)Requirements:

Conclusion: See results.

Reference:

Note:

page 3 of 3MD Standard Report CH_v5/14 ••• END OF REPORT •••

Page 6: ELLETI GROUP SRL - benettongroup.com · TSS -Total suspended solid X COD ... any changes or modifications of this test report. ... Conclusion: See results

Issue date:05 Oct 2017201724 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 6 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45099R1

17.45099R1a

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

Cr VIIdentification Parts

Raw wastewater - ELLETI GROUP srl, Via del Lavoro 9, 37047 San Bonifacio (VR)SAMPLE DESCRIPTION (no. 372628)

Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

Raw Wastewater 0,003

The results expressed are in mg/L.

The symbol < followed by a number indicates that the concentration of the substance is lower than the limit of

quantification (LOQ)

Legend:

Requirements:

Conclusion: See results.

Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:

page 1 of 16MD Standard Report CH_v5/14

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CyanideIdentification Parts

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 6 Nov 2017

Cyanide

Method: ISO 6703-1:1984

Instrument: UV-Visible Spectrophotometer

T F A RD

52040

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

Raw Wastewater < 0,05

The results expressed are in mg/L.

The symbol < followed by a number indicates that the concentration of the substance is less than the limit of

quantification (LOQ)

Legend:

Requirements:

Conclusion: .

Reference: According to ISO 6703-1:1984 Cyanide

Note:

page 2 of 16MD Standard Report CH_v5/14

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Identification Parts Result

52000

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Chlorobenzenes and Chlorotoluenes

Method: According to USEPA 8260B, 8270D

Instrument: Gaschromatograph with Mass detector

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

Monochlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,3,5-trichlorobenzene1,2,3,4-tetrachlorobenzene1,2,3,5-tetrachlorobenzene1,2,4,5-tetrachlorobenzenePentachlorobenzeneHexachlorobenzene2-chlorotoluene3-chlorotoluene4-chlorotoluene2,3-dichlorotoluene2,4-dichlorotoluene2,5-dichlorotoluene2,6-dichlorotoluene3,4-dichlorotoluene3,5-dichlorotoluene2,3,4-trichlorotoluene2,3,6-trichlorotoluene2,4,5-trichlorotoluene2,4,6-trichlorotoluene3,4,5-trichlorotoluene2,3,4,5-tetrachlorotoluene2,3,5,6-tetrachlorotoluene2,3,4,6-tetrachlorotoluenePentachlorotoluene

108-90-795-50-1541-73-1106-46-787-61-6120-82-1108-70-3634-66-2634-90-295-94-3608-93-5118-74-195-49-8108-41-8106-43-432768-54-095-73-819398-61-9118-69-495-75-025186-47-47359-72-02077-46-56639-30-123749-65-721472-86-676057-12-029733-70-8875-40-1877-11-2

< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8260B, 8270D Chlorobenzenes and ChlorotoluenesRequirements:

Conclusion: See results.Reference:

Note:

page 3 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52001

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Chlorophenols

Method: According to USEPA 8270D

Instrument: Gas Chromatograph with Mass Detector (MS)

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

2-Chlorophenol3-Chlorophenol4-Chlorophenol2,3-Dichlorophenol2,4-Dichlorophenol2,5-Dichlorophenol2,6-Dichlorophenol3,4-Dichlorophenol3,5-Dichlorophenol2,3,4-Trichlorophenol2,3,5-Trichlorophenol2,3,6-Trichlorophenol2,4,5-Trichlorophenol2,4,6-Trichlorophenol3,4,5-Trichlorophenol2,3,4,5-Tetrachlorophenol2,3,4,6-Tetrachlorophenol2,3,5,6-TetrachlorophenolPentachlorophenol

95-57-8108-43-0106-48-9576-24-9120-83-2583-78-887-65-095-77-2591-35-515950-66-0933-78-8933-75-595-95-488-06-2609-19-84901-51-358-90-2935-95-587-86-5

< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270D ChlorophenolsRequirements:

Conclusion: See results.Reference:

Note:

page 4 of 16MD Standard Report CH_v5/14

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Identification Parts

52002

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Dyes - Azo

Method: According to EN ISO 14362-1:2017 , EN ISO 14362-3:2017

Instrument: Liquid chromatograph with Mass selective detector (HPLC -MS); Gas chromatograph with Mas selective detector (GC -MS).

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

4,4’-methylene-bis-(2-chloro-aniline)4,4’-methylenedianiline4,4’-oxydianiline4-chloroaniline3,3’-dimethoxylbenzidine3,3’-dimethylbenzidine6-methoxy-m-toluidine2,4,5-trimethylaniline4,4’-thiodianiline4-aminoazobenzene4-methoxy-m-phenylenediamine4,4’-methylene-di-o-toluidine2,6-xylidineo-anisidine2-naphthylamine3,3’-dichlorobenzidine4-aminodiphenylBenzidineo-toluidine2,4-xylidine4-chloro-o-toluidine4-methyl-m-phenylenediamineo-aminoazotoluene5-nitro-o-toluidine

101-14-4101-77-9101-80-4106-47-8119-90-4119-93-7120-71-8137-17-7139-65-160-09-3615-05-4838-88-087-62-790-04-091-59-891-94-192-67-192-87-595-53-495-68-195-69-295-80-797-56-399-55-8

< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration for every Aromatic Amines detected (See listbelow) is lower than the limit of quantification (LOQ).

Legend:

According to EN ISO 14362-1:2017 , EN ISO 14362-3:2017 Dyes - AzoRequirements:

Conclusion: See results.Reference:

Note:

page 5 of 16MD Standard Report CH_v5/14

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Identification Parts

52003

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Alkylphenol and Alkylphenol Ethoxylates

Method: According to ISO 18857-2 and ISO 18254-1

Instrument: H.P.L.C.with DAD/MSD detectors and Gaschromatograph with mass detector (GC-MS)

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

Nonylphenol (NP)

Octylphenol (OP)

Octylphenol ethoxylates, (OPEO)

Nonylphenol ethoxylates(NPEO)

104-40-511066-49-225154-52-384852-15-3140-66-91806-26-427193-28-89002-93-19036-19-568987-90-69016-45-926027-38-337205-87-168412-54-4127087-87-0

< 5

< 5

< 5

< 5

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 18857-2 and ISO 18254-1 Alkylohenol and Alkylphenol EthoxylatesRequirements:

Conclusion: See results.Reference:

Note:

page 6 of 16MD Standard Report CH_v5/14

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Identification Parts Result

52004

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Dyes Carcinogenic and Disperse

Method: According to DIN 54231

Instrument: Liquid cromatograph with DAD and MS detector

T F A RD

Compound

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

Disperse DyesCarcinogenic Dyes

< 50< 500

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

According to DIN 54231 Dyes - Carcinogenic and DisperseRequirements:

Conclusion: See results.Reference:

List of Disperse Dyes detected (Which are classified to be allergenic) - CAS Number––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Disperse Yellow 1 119-15-3 11 Disperse Red 17 3179-89-32 Disperse Blue 102 12222-97-8 12 Disperse Blue 7 3179-90-63 Dipserse Blue 106 12223-01-7 13 Disperse Blue 26 3860-63-74 Disperse Yellow 39 12236-29-2 14 Disperse Yellow 49 54824-37-25 Disperse Orange 37/76/59 13301-61-6 15 Disperse Blue 35 12222-75-26 Disperse Brown 1 23355-64-8 16 Disperse Blue 124 61951-51-77 Disperse Orange 1 2581-69-3 17 Disperse Yellow 9 6373-73-58 Disperse Yellow 3 2832-40-8 18 Disperse Orange 3 730-40-59 Disperse Red 11 2872-48-2 19 Disperse Blue 35 56524-77-710 Disperse Red 1 2872-52-8

List of Dyes detected (Which are classified to be carcinogenic) - CAS Number–––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Acid Red 26 3761-53-3 9 Disperse Blue 3 2475-46-92 Basic Red 9 569-61-9 10 Basic Blue 26 2580-56-53 Basic Violet 14 632-99-5 11 Basic Green 4 569-64-2/2437-29-8/10309-95-24 Direct Black 38 1937-37-75 Direct Blue 6 2602-46-26 Direct Red 28 573-58-07 Disperse Blue 1 2475-45-88 Disperse Orange 11 82-28-0

Note:

page 7 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52005

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Flame Retardants

Method: According to ISO 22032:2006

Instrument: Gaschromatograph with mass detector (GC-MS)

T F A RD

Compound

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

TCEPdecaBDETRISpentaBDEoctaBDEBISTEPAPBBTBBPAHBCDDBBMPTDCPSCCP

115-96-81163-19-5126-72-732534-81-932536-52-05412-25-9545-55-159536-65-179-94-73194-55-63296-90-013674-87-885535-84-8

< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)The substances determined are:TCEP : Tris(2-chloroethyl)phosphate; - DecaBDE : Decabromodiphenyl ether; - TRIS : Tris(2,3-dibromopropyl)-phosphate; - PentaBDE : Pentabromodiphenyl ether; - OctaBDE : Octabromodiphenyl ether; - BIS : Bis(2,3-dibromopropyl)phosphate; - TEPA : Tris(1-aziridinyl)phosphine oxide; - PBB : Polybromobiphenyls; - TBBPA :Tetrabromobisphenol A; - HBCDD : Hexabromocyclododecane; - BBMP : 2,2-bis(bromomethyl)-1,3-propanediol ; -TDCP : Tris(1,3-dichloro-isopropyl)phosphate ; - SCCP : Short-chain chlorinated paraffins

Legend:

According to ISO 22032:2006 Flame RetardantsRequirements:

Conclusion: See results.Reference:

Note:

page 8 of 16MD Standard Report CH_v5/14

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Identification Parts

52006

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Glycols

Method: According to USEPA 8270

Instrument: Gaschromatograph with Mass Detector

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

Bis(2-methoxyethyl)-ether2-ethoxyethanol2-ethoxyethyl acetateEthylene glycol dimethyl ether2-methoxyethanol2-methoxyethylacetate2-methoxypropylacetateTriethylene glycol dimethyl ether

111-96-6110-80-5111-15-9110-71-4109-86-4110-49-670657-70-4112-49-2

< 50< 50< 50< 50< 50< 50< 50< 50

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270 GlycolsRequirements:

Conclusion: See results.Reference:

Note:

page 9 of 16MD Standard Report CH_v5/14

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Identification Parts

52007

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Halogenated Solvents

Method: According to USEPA 8260B

Instrument: Gaschromatograph with FID and Mass Detector

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

1,2-DichloroethaneMethylene chlorideTrichloroethyleneTetrachloroethylene

107-06-275-09-279-01-6127-18-4

< 1< 1< 1< 1

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8260B Halogenated SolventsRequirements:

Conclusion: See results.Reference:

Note:

page 10 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52008

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Organotin Compounds

Method: According to ISO 17353

Instrument: Gas - Chromatograph with Mass Detector (GC-MSD)

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

METDMTTMTMBTDBTTBTMPTDPTTPTMOTDOTTOT

MultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultiple

< 0,01< 0,01< 0,010,017

< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)MET : Monomethyltin; - DMT: Dimethyltin; - TMT : Trimethyltin; MBT : Monobutyltin; - DBT : Dibutyltin; - TBT :Tributyltin; - MPT : Monophenyltin; - DPT : Diphenyltin; - TPT : Triphenyltin; - MOT : Monooctyltin; - DOT : Dioctyltin; -TOT : Trioctyltin.

Legend:

According to ISO 17353 Organotin CompoundsRequirements:

Conclusion: See results.Reference:

Note:

page 11 of 16MD Standard Report CH_v5/14

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Identification Parts

52009

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Perfluorinated and Polyfluorinated Chemicals (PFCs)

Method: According to DIN 38407-42

Instrument: Liquid Chromatograph with Mass detector and Gas Chromatography with mass detector

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

PFOS

PFOAPFBS

PFHxA8:2 FTOH6:2 FTOH

355-46-4432-50-7335-67-129420-49-329420-43-3307-24-4678-39-7647-42-7

< 0,01

< 0,01< 0,01

< 0,01< 1< 1

Raw Wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to DIN 38407-42 Perfluorinated and Polyfluorinated Chemicals (PFCs)Requirements:

Conclusion: See results.Reference:

Note:

page 12 of 16MD Standard Report CH_v5/14

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Identification Parts

52010

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Phthalates

Method: According to USEPA 8270D

Instrument: Gascromatograph with Mass Detector - Liquid Cromatograph with DAD and Mass detector

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

DEHPBBPDBPDEPDNOPDINPDIDPDIBPDnHPDMEPDPRPDIOPDCHPDNPDHNUPDIHP

117-81-785-68-784-74-284-66-2117-84-028553-12-026761-40-084-69-584-75-3117-82-8131-16-827554-26-384-61-784-76-468515-42-471888-89-6

< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10

Raw Wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the analyte is lower than the limit ofquantification (LOQ)

The phthalates determined are:DEHP : Bis (2-ethylhexyl) phthalate ; - BBP : Butyl benzyl phthalate ; - DBP : Di-n-butyl phthalate ; - DEP : Diethylphthalate; - DNOP : Di-n-octyl phthalate; - DINP : Di-isononyl phthalate; - DIDP : Di-iso-decyl phthalate ; - DIBP : Di-isobutyl phthalate ; - DnHP : Di-n-hexyl phthalate; - DMEP : Dimethoxyethyl phthalate; - DPRP : Di-n-propyl phthalate;- DIOP : Di-iso-octyl phthalate; - DCHP : Di-cyclohexyl phthalate; - DNP : Dinonyl phthalate; - DIHP : Di-isoheptylphthalate; - DHNUP : 1,2-Benzene-di-carboxylic acid, di-C7-11-branched and linear alkyl esters.

Legend:

According to USEPA 8270D PhthalatesRequirements:

Conclusion: See results.Reference:

Note:

page 13 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52011

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Polycyclic Aromatic Hydrocarbons (PAH)

Method: According to USEPA 8270

Instrument: Gascromatograph with Mass Detector

T F A RD

Compound

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

Benzo(a)pyreneBenzo(e)pyreneBenzo(a)anthraceneBenzo(b)fluorantheneBenzo(j)fluorantheneBenzo(k)fluorantheneChryseneDibenzo(a,h)anthracene

AcenaphteneAcenaphthyleneAnthraceneBenzo(g,h,i)peryleneFluorantheneFluoreneIndeno(1,2,3-cd)pyreneNaphthalenePhenanthrenePyrene

50-32-8192-97-256-55-3205-99-2205-82-3207-08-9218-01-953-70-3

83-32-9208-96-8120-12-7191-24-2206-44-086-73-7193-39-591-20-385-01-8129-00-0

< 1< 1< 1< 1< 1< 1< 1< 1

< 1< 1< 1< 1< 1< 1< 1< 1< 1< 1

Raw Wastewater

The results are expressed in µg/L.The symbol < followed by a number inicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270 Polycyclic Aromatic Hydrocarbons (PAH)Requirements:

Conclusion: See results.Reference:

Note:

page 14 of 16MD Standard Report CH_v5/14

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Identification Parts

52012

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Volatile Organic Compounds

Method: According to ISO 11423-1

Instrument: GC-MS headspace

T F A RD

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

BenzeneXyleneo-cresolp-cresolm-cresol

71-43-21330-20-795-48-7106-44-5108-39-4

< 1< 15,66,43,3

Raw Wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 11423-1 Volatile Organic Compounds (VOC)Requirements:

Conclusion: See results.Reference:

Note:

page 15 of 16MD Standard Report CH_v5/14

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Identification Parts

52024

TEST REPORT: 17.45099R1a Rev. No.: 1 dated 06 November 2017

Metals

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

T F A RD

Compound

This report cancels and replaces the previous one (17.45099) issued on 24/10/17.

PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,001< 0,01

< 0,005< 0,01< 0,25< 0,05

< 0,5< 0,05

< 0,005

Raw Wastewater

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO17294-2 (2016) and ISO 11885 (2007) MetalsRequirements:

Conclusion: See results.Reference:

Note:

page 16 of 16MD Standard Report CH_v5/14 ••• END OF REPORT •••

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Issue date:05 Oct 2017201724 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45100R2

17.45100R2a

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

T°Identification Parts

Treated water - ELLETI GROUP srl, Via del Lavoro 9, 37047 San Bonifacio (VR)SAMPLE DESCRIPTION (no. 372629)

TemperatureMethod: According to US EPA 170.1

Instrument: Digital Thermometer

TREATED WATER 23,1

The results are expressed in °C.Legend:

Requirements:

Conclusion: See results.Reference: According to US EPA 170.1 Temperature

Note:

page 1 of 18MD Standard Report CH_v5/14

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Persistent FoamIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Persistent Foam

Method: N/A

Instrument: Laboratory equipment

T F A RD

52014

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER Not visible

//.Legend:

Requirements:

Conclusion: See results.Reference: N/A Persistent Foam

Note:

page 2 of 18MD Standard Report CH_v5/14

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TSSIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

TSS -Total suspended solid

Method: According to APAT CNR IRSA 2090B-MAN 29 2003

Instrument: Laboratory equipment

T F A RD

52015

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 5

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 2090B-MAN 29 2003 TSS- Total suspended solid

Note:

page 3 of 18MD Standard Report CH_v5/14

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CODIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

COD - Chemical oxygen demand

Method: According to APATCNR IRSA 5130

Instrument: Laboratory equipment

T F A RD

52016

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 40

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APATCNR IRSA 5130 COD - Chemical oxygen demand

Note:

page 4 of 18MD Standard Report CH_v5/14

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pHIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

pH

Method: According to APAT CNR IRSA 2060

Instrument: pH Meter

T F A RD

52017

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER 7,76

//.Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 2060 pH

Note:

page 5 of 18MD Standard Report CH_v5/14

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BOD5Identification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

BOD5 - Biological oxygen demand (5 days)

Method: According to USEPA 405.1 (5DAYS)

Instrument: Laboratory equipment

T F A RD

52019

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER 78

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is less than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.

Reference: According to USEPA 405.1 (5DAYS) BOD5 - Biological oxygen demand (5 days)

Note:

page 6 of 18MD Standard Report CH_v5/14

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Total-PIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Total-P - Total phosphorus

Method: According to ISO 15587:2002, ISO 11885:2007

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES)

T F A RD

52020

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER 1,13

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to ISO 15587:2002, ISO 11885:2007 Total-P - Total phosphorus

Note:

page 7 of 18MD Standard Report CH_v5/14

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Oil and GreeseIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Oil and Greese

Method: According to APAT CNR IRSA 5160A

Instrument: Laboratory equipment

T F A RD

52021

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER 0,9

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 5160A Oil and Greese

Note:

page 8 of 18MD Standard Report CH_v5/14

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Cr VIIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

T F A RD

52025

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 0,001

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:

page 9 of 18MD Standard Report CH_v5/14

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Total-NIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Total-N - Total nitrogen

Method: According to APAT CNR IRSA 4060 Man. 29 2003

Instrument: UV-Visible Spectrophotometer

T F A RD

52026

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 5

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4060 Man. 29 2003 Total-N - Total nitrogen

Note:

page 10 of 18MD Standard Report CH_v5/14

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Ammonium-NIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Ammonium-N - Ammonium nitrogen

Method: ISO 7150-1:1984

Instrument: UV-Visible Spectrophotometer

T F A RD

52027

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 0,5

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4030 Man. 29 2003 Ammonium-N - Ammonium nitrogen

Note:

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SulfideIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Sulfide

Method: According to APAT CNR IRSA 4160 MAN 29 2003

Instrument: Laboratory equipment

T F A RD

52028

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 0,01

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4160 MAN 29 2003 Sulfide

Note:

page 12 of 18MD Standard Report CH_v5/14

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SulfiteIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Sulfite

Method: According to APAT CNR IRSA 4150B MAN 29 2003

Instrument: Laboratory equipment

T F A RD

52029

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER 0,29

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4150B MAN 29 2003 Sulfite

Note:

page 13 of 18MD Standard Report CH_v5/14

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CyanideIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

Cyanide

Method: ISO 6703-1:1984

Instrument: UV-Visible Spectrophotometer

T F A RD

52040

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 0,05

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is less than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to ISO 6703-1:1984 Cyanide

Note:

page 14 of 18MD Standard Report CH_v5/14

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AOXIdentification Parts

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 8 Nov 2017

AOX

Method: According to EPA 5030+EPA8260

Instrument: Gaschromatograph with Mass Detector (GC-MSD)

T F A RD

52041

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

TREATED WATER < 0,1

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to EPA 5030+EPA8260 AOX

Note:

page 15 of 18MD Standard Report CH_v5/14

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Identification Parts

52018

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 08 November 2017

Colour

Method: According to ISO 7887-B:2011

Instrument: UV-Visible Spectrophotometer

T F A RD

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

Spectral absorption coefficient λ = 436 nmSpectral absorption coefficient λ = 525 nmSpectral absorption coefficient λ = 620 nmpH value after filtration

< 2 m-1< 1 m-1< 1 m-1

7,77

TREATED WATER

//.Legend:

According to ISO 7887-B:2011 Colour [Pt-Co]Requirements:

Conclusion: See results.Reference:

Note:

page 16 of 18MD Standard Report CH_v5/14

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Identification Parts

52022

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 08 November 2017

Phenol

Method: According to APAT CNR IRSA 5070 A1 Man 29 2003

Instrument: UV-Visible Spectrophotometer

T F A RD

Compound

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

Phenol < 0,001TREATED WATER

The results expressed are in mg/L.The symbol < followed by a number indicates that the concetration fo the substance is lower than the detection limitexpressed by that number.

Legend:

According to APAT CNR IRSA 5070 A1 Man 29 2003 PhenolRequirements:

Conclusion: See results.Reference:

Note:

page 17 of 18MD Standard Report CH_v5/14

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Identification Parts

52024

TEST REPORT: 17.45100R2a Rev. No.: 2 dated 08 November 2017

Metals

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

T F A RD

Compound

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,001< 0,01

< 0,005< 0,01< 0,25< 0,05

< 0,5< 0,05

< 0,005

TREATED WATER

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO17294-2 (2016) and ISO 11885 (2007) MetalsRequirements:

Conclusion: See results.Reference:

Note:

page 18 of 18MD Standard Report CH_v5/14

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Issue date:05 Oct 2017201724 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45100R2b Rev. No.: 2 dated 8 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45100R2

17.45100R2b

This report cancels and replaces the previous one (17.45100R1) issued on 06/11/17.

Coliform (UFC/100ml)Identification Parts

Treated water - ELLETI GROUP srl, Via del Lavoro 9, 37047 San Bonifacio (VR)SAMPLE DESCRIPTION (no. 372629)

Coliform (UFC/100ml)

Method: According to ISO 9308-1:2014

Instrument: Laboratory equipment

TREATED WATER 130.000

The results expressed are in UFC/100 ml.

The symbol < followed by a number indicates that the concetration fo the substance is lower than the detection limit

expressed by that number.

Results expressed according to ISO 8199:2005

Legend:

Requirements:

Conclusion: See results.

Reference: According to ISO 9308-1:12014 Coliform (UFC/100ml)

Note:

page 1 of 1MD Standard Report MB_v5/14 ••• END OF REPORT •••