electronic supporting information structures ...electronic supporting information 3d transition...
TRANSCRIPT
![Page 1: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/1.jpg)
Electronic Supporting Information
3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies and optical properties
Daniel J. Fanna,a Yingjie Zhang,*b Li Li,a Inna Karatchevtseva,b Nicholas Shepherd,a,b Abdul Azim,a Jason R. Price,c Janice Aldrich-Wright,a Jason K. Reynoldsa and Feng Li *a
a School of Science and Health, Western Sydney University , Locked Bag 1797, Penrith, NSW 2751, Australia. Email: [email protected] Australian Nuclear Science and Technology Organisation, Locked Bag 2001, Kirrawee DC, NSW 2232, Australia. Email: [email protected] Australian Synchrotron, 800 Blackburn Road, Clayton, VIC 3168, Australia
Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.This journal is © the Partner Organisations 2015
![Page 2: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/2.jpg)
List of Figures
Figure S1: 1H NMR 300 MHz spectrum of ligand HL in CDCl3.
Figure S2: High resolution ESI-Mass spectrum of HL in MeOH. The inset shows the isotope pattern for [H2L]+ in both experiment (bottom) and simulation (top).
Figure S3: High resolution ESI-Mass spectrum of complex 1 in MeOH.
Figure S4: The isotope patterns (bottom) with the simulated distribution (top) for [MnL2]+.
Figure S5: The isotope patterns (bottom) with the simulated distribution (top) for [MnL]+.
Figure S6: High resolution ESI-Mass spectrum of complex 2 in MeOH.
Figure S7: The isotope patterns (bottom) with the simulated distribution (top) for [CoL2]+.
Figure S8: The isotope patterns (bottom) with the simulated distribution (top) for [CoL]+.
Figure S9: High resolution ESI-Mass spectrum of complex 3 in MeOH.
Figure S10: The isotope patterns (bottom) with the simulated distribution (top) for [NiL]+.
Figure S11: The isotope patterns (bottom) with the simulated distribution (top) for [NiL2+H]+.
Figure S12: High resolution ESI-Mass spectrum of complex 4 in MeOH.
Figure S13: The isotope patterns (bottom) with the simulated distribution (top) for [CuL]+.
Figure S14: High resolution ESI-Mass spectrum of complex 5 in MeOH.
Figure S15: The isotope patterns (bottom) with the simulated distribution (top) for [ZnL]+.
Figure S16: A backscattered SEM image of complex 1 (left) and an EDS spectrum (right).
Figure S17: A backscattered SEM image of complex 2 (left) and an EDS spectrum (right).
Figure S18: A backscattered SEM image of complex 3 (left) and an EDS spectrum (right).
Figure S19: A backscattered SEM image of complex 4 (left) and an EDS spectrum (right).
Figure S20: A backscattered SEM image of complex 5 (left) and an EDS spectrum (right).
![Page 3: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/3.jpg)
Figure S1. 1H NMR 300 MHz spectrum of ligand L in CDCl3.
Figure S2. High resolution ESI-Mass spectrum of HL in MeOH. The inset shows the isotope pattern for [H2L]+ in both experiment (bottom) and simulation (top).
![Page 4: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/4.jpg)
Figure S3. High resolution ESI-Mass spectrum of complex 1 in MeOH.
Figure S4. The isotope patterns (bottom) with the simulated distribution (top) for [MnL2]+.
![Page 5: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/5.jpg)
Figure S5. The isotope patterns (bottom) with the simulated distribution (top) for [MnL]+.
Figure S6. High resolution ESI-Mass spectrum of complex 2 in MeOH.
![Page 6: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/6.jpg)
Figure S7. The isotope patterns (bottom) with the simulated distribution (top) for [CoL2]+.
Figure S8. The isotope patterns (bottom) with the simulated distribution (top) for [CoL]+.
![Page 7: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/7.jpg)
Figure S9. High resolution ESI-Mass spectrum of complex 3 in MeOH.
Figure S10. The isotope patterns (bottom) with the simulated distribution (top) for [NiL]+.
![Page 8: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/8.jpg)
Figure S11. The isotope patterns (bottom) with the simulated distribution (top) for [NiL2+H]+.
Figure S12. High resolution ESI-Mass spectrum of complex 4 in MeOH.
![Page 9: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/9.jpg)
Figure S13. The isotope patterns (bottom) with the simulated distribution (top) for [CuL]+.
Figure S14. High resolution ESI-Mass spectrum of complex 5 in MeOH.
![Page 10: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/10.jpg)
Figure S15. The isotope patterns (bottom) with the simulated distribution (top) for [ZnL]+.
Figure S16. A backscattered SEM image of complex 1 (left) and an EDS spectrum (right).
Figure S17. A backscattered SEM image of complex 2 (left) and an EDS spectrum (right).
![Page 11: Electronic Supporting Information structures ...Electronic Supporting Information 3d transition metal complexes with a julolidine‒quinoline based ligand: structures, spectroscopies](https://reader030.vdocuments.us/reader030/viewer/2022040402/5e849e8aa2ad8241d51aa228/html5/thumbnails/11.jpg)
Figure S18. A backscattered SEM image of complex 3 (left) and an EDS spectrum (right).
Figure S19. A backscattered SEM image of complex 4 (left) and an EDS spectrum (right).
Figure S20. A backscattered SEM image of complex 5 (left) and an EDS spectrum (right).