electrochemical and uf treatment: recycle oil & gas wastewater … · 2019. 3. 21. · – 0.28 kwh...

22
Electrochemical and UF Treatment: Recycle Oil & Gas Wastewater for Crop Irrigation

Upload: others

Post on 31-Jan-2021

0 views

Category:

Documents


0 download

TRANSCRIPT

  • Electrochemical and UF Treatment:

    Recycle Oil & Gas Wastewater for Crop Irrigation

  • 1

    • OriginClear Inc. founded in 2007: a pure technology company.

    • Went public in 2008 on OTC Bulletin Board.

    • Developed and proved a breakthrough high-speed water

    cleanup technology, Electro Water Separation™ with

    Advanced Oxidation (EWS:AOx™).

    • In 2015, began to…

    – Commercialize the technology: OriginClear Technologies

    – Consolidate water services companies: OriginClear Group

    OriginClear

    © 2016 OriginClear Technologies, Inc.

  • • EWS:AOx scaled and proven.

    • Expert team pursuing partnerships worldwide.

    • Active in Asia, Europe, US:

    • OriginClear Technologies Ltd., Asian subsidiary established,

    commercial status

    • Active opportunities in Europe

    • Malaysian JV now operational

    • Strategic discussions with majors in Bakersfield area.

    • “Sour well” remediation being proven in Texas

    2016: Technology Status

    2© 2016 OriginClear Technologies, Inc.

  • • EWS:AOx™ is a technology train for cleaning polluted water.

    – Originally designed for extracting algae from water

    – Then applied to recovering oil from produced water and

    • 2016: Advanced Oxidation (AOx) added as a final stage,

    addresses complex pollutants.

    • EWS is modular: It can be incorporated into an existing waste

    treatment system or designed as a stand alone equipment.

    What is EWS:AOx™

    3© 2016 OriginClear Technologies, Inc.

  • • Selected and specifically designed MMO anodes are a core specificity of EWS. Theyare used as Oxidizers both in the generation of H2O2 (ROS) as well as chlorinespecies in the Advanced Oxidation Process and in the generation of gas bubbles forElectro-Flotation.

    – HF Reactors (right) for gas separation and oxidation

    – ECR Reactors (below) for mixing and enhanced contact

    Key Elements in the EWS system

  • • Effective on:

    – Suspended Solids

    – Oil and Grease (petroleum

    hydrocarbons)

    – Ammonia

    – Dissolved Organics

    EWS:AOx™ Applications

    • Scalable technology: from table-top lab units to existing large

    infrastructure retrofits.

    5© 2016 OriginClear Technologies, Inc.

  • System diagram

    Gas Flotation removal of:• Suspended organics• TPHAeration1st stage ROS generation

    2nd stage ROS generation:• Heavy metals precipitation• Small-chain organicsMOS generation addresses:• Ammonia• Bacterial contamination• Color

    6© 2016 OriginClear Technologies, Inc.

  • © 2016 OriginClear Technologies, Inc. 7

    A standard implementation

    400 tons per day nominal treatment capacity – Two units fit in a 20’ container

  • Irrigation water standards

    8© 2016 OriginClear Technologies, Inc.

    Parameter Unit WHO US EPA

    Coliforms cfu/100 mL < 1,000 (food crops) < 2.2

    Turbidity NTU No recommendation < 2

    TSS mg/l - < 30 (processed food)

    BOD mg/l - < 10 (food crops)

    EC µs/cm

  • 380 370

    176

    28 2070.1 0.0 1.5

    0

    50

    100

    150

    200

    250

    300

    350

    400

    450

    500

    Turbidity (NTU) TSS (mg/l) Oil (mg/l)

    Turb

    idit

    y /

    TSS

    / O

    il in

    Wat

    er

    (NTU

    , mg/

    l, m

    g/l)

    Feed EWS EWS Prime

    9

    Niobrara Performance

    Feed water for testing: Produced & frac flowback

    from Colorado Western Slope disposal well facility

    Better than 99% removal of Turbidity, TSS and Oil observed

  • 10

    Permian Robustness

    Recovered Oil

    Water Samples

    Wide variations in feed from many different truckloads

    and tank mixing over two weeks of operation in the Permian

    0

    200

    400

    600

    800

    1000

    1200

    1400

    1600

    EWS

    Turb

    idit

    y (F

    NU

    )

    Operation Date

    Extended EWS Prime Performance

    Parsley Energy Raw SWD EWS Prime Effluent

  • 11

    Monterey Clarity

    Field operations to treat CSS produced water to

    steam boiler make-up and irrigation quality

    Beneficial Re-use

    Water Samples

    0

    200

    400

    600

    800

    1000

    1200

    0 100 200 300 400

    Turb

    isit

    y (N

    TU)

    Run Time (Hours)

    Vaquero FWKO Feed Turbidity EWS Prime Effluent Turbidity

  • 12

    High Energy Efficiency

    No observable membrane fouling even at high production

    capacity due to complete produced water pre-treatment

    0

    5

    10

    15

    20

    25

    30

    0

    5

    10

    15

    20

    25

    30

    35

    0 50 100 150 200 250 300 350

    Spec

    ific

    Flu

    x (g

    fd/p

    si)

    Mo

    du

    le F

    lux

    (gfd

    )

    Run Time (Hours)

    UF System Flux UF Specific Flux

    Vaquero Site in Monterey Formation

  • • Produced water treatment for irrigation

    Additional results

    13© 2016 OriginClear Technologies, Inc.

    All data generated by Zalco Laboratories

    Sampled 18 Feb 2015 at Hershey Tank Battery, Vaquero

    Energy (Bakersfield CA)

  • • Water from the flood inside the

    manufacturing site

    Prime Conduit – Oklahoma City

    14© 2016 OriginClear Technologies, Inc.

    Water quality components Load (ppm)

    Oil & Grease 173

    TSS 155

    COD 1750

    BOD 437

    Heavy metals such as Copper 2.43

  • • Mobile demo unit

    – EWS W25 Separator/Oxidizer

    – Media filter for polishing

    – 6 gallons per minute treatment

    Prime Conduit – Oklahoma City

    15© 2016 OriginClear Technologies, Inc.

  • • TSS, Oils and most COD removal

    Prime Conduit – Oklahoma City

    16© 2016 OriginClear Technologies, Inc.

    VIDEO

  • • Results after media polishing

    Prime Conduit – Oklahoma City

    17© 2016 OriginClear Technologies, Inc.

    Water quality components Load (ppm)

    Oil & Grease ND

    TSS ND

    COD 81

    BOD 45

    Heavy metals such as Copper 0.013

  • • As measured by 3d

    party lab.

    • Removal rates

    between 90% and

    100% except for

    two elements.

    Prime Conduit – Oklahoma City

    18© 2016 OriginClear Technologies, Inc.

  • 19

    • EWS PRIME Specific Energy Consumption (SEC)

    – 0.28 kWh per barrel or 1.7 kWh/m3 - including EWS & UF

    • EWS PRIME Operating Expense (w/o Labor, per m3)

    – Energy (at $0.15 per kWh) $0.26

    – Consumables (weekly partial anode replacement) $0.33

    – Typical Equipment maintenance $0.29

    • EWS PRIME Total Operating Expenses $0.88/m3

    $1,085/acre-foot

    • Current California Central valley water contract : $1,500/acre-foot

    Economics in 2015

  • 20

    Current Development

    BK 2016 PILOT VIDEO

  • Thank you for your attention

    www.originclear.com/tech

    21© 2016 OriginClear Technologies, Inc.

    http://www.originclear.com/contact