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Electrical Conductance Conductivity ofMetal Semiconductor and Insulator |Band Theory
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This page is all about:What is Conductance?Definition of Electrical ConductanceEquation or Formula of Electrical ConductanceSpecific Conductance or ConductivityDefinition of Electrical ConductivityUnit of ConductanceUnit of ConductivityBand Theory for Electrical ConductivityValance BandConduction BandBand GapElectrical Conductivity of Metal
► Formula ► Insulator ► Steel Metal ► Metal Wire
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Table for Conductivity of Different MetalsElectrical Conductivity of SemiconductorTable for Conductivity of Different SemiconductorsElectrical Conductivity of InsulatorTable for Conductivity of Different Insulators
What is Conductance?
When we apply same potential difference across different conductors, we will see different currentsflow through them. Actually how much current will flow through a specific conductor for certainapplied potential difference across it, depends upon a specific property of the conductor, calledelectrical conductance . This property determines how easily a current can flow through a conductor.
As we know resistance is such a property of a conductor which resists the flow of current through it.That means, electrical conductance is reciprocal property of resistance. Generally conductance isdenoted as,
Definition of Electrical Conductance
Electrical conductance is defined as a special property of a conductor which determines how easilyan current can flow through it.
Equation or Formula of Electrical Conductance
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Let us take a piece of conductor of length l and cross sectional area A. If length of the conductor isincreased, the electrons have to drift more paths. Hence more chance of inter atomic collision. Thatmeans current gets much harder path to travel, means electrical conductance of the conductor isreduced.
Thus conductance is inversely proportional to length of the conductor.
If cross sectional area of conductor is increased then current gets more drift electrons. Hence,conductance of the conductor is increased.
From equation (1) & (2),
Where, σ = constant of proportional known as conductivity or specific conductance .
Specific Conductance or Conductivity
In the equation of the conductance we have already mentioned the term σ or Sigma as conductivity.Now in that equation if we put l = 1 m & A = 1 m then G = σ. That indicates σ is the conductance of aconductor whose length is 1 m & cross sectional area is 1 m . That mean specific conductance orconductivity is the conductance of a conductor whose volume is 1 m × 1 m = 1 m .
2
2
2 3
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Definition of Electrical Conductivity
Conductivity is the conductance of a material per unit volume.Electrical conductivity is a basic property of material. Due to this property one material can conductelectricity. Some materials are good conductor of electricity that means current can pass throughthem very easily; again some materials do not allow current to flow through them. The materialthrough which current passes easily, called good conductor of electricity in other words, theelectrical conductivity of these materials is high. On the other hand the materials do not allow thecurrent to flow through them are called electrical insulators. There are some materials whoseelectrical conductivity is not as high as conductor and also not as poor as insulator, they have anintermediate conductivity and these type of materials are known as semiconductors.
Unit of Conductance
As we mentioned earlier conductance is reciprocal of resistance of resistance. That is,
Unit of resistance is ohm & that is why unit of conductance is generally written as mho – the reversespelling of ohm. A modern electrical engineering, mho is named by Siemens.
Unit of Conductivity
The equation of conductivity, we have already deducted as,
Hence, unit of conductivity is,
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Here, S is Siemens.
Table of Resistivity and Conductivity of DifferentMaterials at 20°C
MATERIAL RESISTIVITY AT 20°C CONDUCTIVITY 20°C
Air 1.3 × 10 to 3.3 × 10 3 × 10 to 8 × 10
Aluminum 2.82 × 10 3.5 × 10
Annealed copper 1.72 × 10 5.80 × 10
Calcium 3.36 × 10 2.98 × 10
Carbon (amorphous) 5 × 10 to 8 × 10 1.25 to 2 × 10
Carbon (diamond) 1 × 10 ~10
Carbon (graphite) 2.5 × 10 to 5.0 × 10 //basal plane 2 to 3 × 10 //basal plane
Carbon steel -10 1.43 × 10-7
Constantan 4.9 × 10 2.04 × 10
Copper 1.68 × 10 5.96 × 10
Deionized water 1.8 × 10 5.5 × 10
Drinking water 2 × 10 to 2 × 10 5 × 10 to 5 × 10
Fused quartz 7.5 × 10 1.3 × 10
GaAs 5 × 10 to 10 × 10 5 × 10 to 10
Germanium 4.6 × 10 2.17
16 16 -15 -15
-8 7
-8 7
-8 7
-4 -4 3
12 -13
-6 -6 5
10
-7 6
-8 7
5 -6
1 3 -4 -2
17 -18
-7 -3 -8 3
-1
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Glass 10 × 10 to 10 × 10 10 to 10
Gold 2.44 × 10 4.10 × 10
Grain oriented electrical steel 4.60 × 10 2.17 × 10
Hard rubber 1 × 10 10
Iron 1.0 × 10 1.00 × 10
Lead 2.2 × 10 4.55 × 10
Lithium 9.28 × 10 1.08 × 10
Manganin 4.82 × 10 2.07 × 10
Mercury 9.8 × 10 1.02 × 10
Nichrome 1.10 × 10 9.09 × 10
Nickel 6.99 × 10 1.43 × 10
Paraffin wax 1 × 10 10
PET 10 × 10 10
Platinum 1.06 × 10 9.43 × 10
Sea water 2 × 10 4.8
Silicon 6.40 × 10 1.56 × 10
Silver 1.59 × 10 6.30 × 10
Stainless steel 6.9 × 10 1.45 × 10
Sulfur 1 × 10 10
Teflon 10 × 10 to 10 × 10 10 to 10
Tin 1.09 × 10 9.17 × 10
Titanium 4.20 × 10 2.38 × 10
10 14 -11 -15
-8 7
-7 6
13 -14
-7 7
-7 6
-8 7
-7 6
-7 6
-6 5
-8 7
17 -18
20 -21
-7 6
-1
2 -3
-8 7
-7 6
15 -16
22 24 -25 -23
-7 6
-7 6
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Tungsten 5.60 × 10 1.79 × 10
Wood (damp) 1 × 10 to 4 10 to 10
Wood (oven dry) 1 × 10 to 16 10 to 10
Zinc 5.90 × 10 1.69 × 10
Band Theory for Electrical Conductivity
The electrons in the outer most orbit of an atom experiences least attraction force. So the outermostatom can easily be detached from the parent atom. Let’s explain the details with band theory
When a number of atoms are brought together, the electrons of one atom experience forces of otheratoms. This effect is most pronounced in outer most orbits. Due to this force, the energy levels, whichwere sharply defined in an isolated atom, are now broadened into energy bands. Due to thisphenomenon generally two bands result, namely valance band and conduction band.
Valance Band
The outermost orbital of an atom, where electrons are so tightly bounded that; they cannot beremoved as free electron
Conduction Band
-8 7
3 -4 -3
14 -16 -14
-8 7
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This is the highest energy level or orbital in outer most shell, in which electrons are free enough tomove.
Band Gap
There is one energy gap that separates these two bands, the valance band and conduction band. Thisgap is called forbidden energy gap.
Electrical Conductivity of Metal
In metals, the atoms are so tightly packed that electron of one atom experience sufficientlysignificant force of other closed atoms. The result, the valance band and conduction band in metalscome very closer to each other and may even overlap. Consequently, by receiving very small amountof energy from external heat or electrical energy source, the electrons readily ascend to higher levelsin the metal. Such electrons are known as free electrons. These free electrons are responsible forcurrent that flows through a metal. When external electric source is connected to a piece of metal,these free electrons start flowing towards higher potential terminal of the source, causing current toflow in the metal. In metal, density of free electrons in conduction band is much higher than othermaterials, hence metal is referred as very good electrical conductor. In other words electricalconductivity of metal is very good.
Table for Conductivity of Different Metals
METALS CONDUCTIVITY IN SIEMENS/METER AT 20°C
Silver 6.30×10 7
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Copper 5.96X10
Aluminium 3.5X10
Annealed copper 5.80X10
Calcium 2.98X10
Carbon steel (1010) 6.99X10
Constantan 2.04X10
GaAs 5X10 to 10
Gold 4.10X10
Grain oriented electrical steel 2.17X10
Iron 1.00X10
Lead 4.55X10
Lithium 1.08X10
Manganin 2.07X10
Mercury 1.02X10
Nichrome 9.09X10
Nickel 1.43X10
Platinum 9.43X10
Stainless steel 1.45X10
Tin 9.17X10
Titanium 2.38X10
Tungsten 1.79X10
Zinc 1.69X10
7
7
7
7
6
6
−8 3
7
6
7
6
7
6
6
5
7
6
6
6
6
7
7
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Electrical Conductivity of Semiconductor
In semiconductor the valance band and conduction band are separated by a forbidden gap ofsufficient width. At low temperature, no electron possesses sufficient energy to occupy theconduction band and thus no movement of charge is possible. But at room temperature it is possiblefor some electrons to give sufficient energy and make the transitions in conduction band. The densityof electrons in conduction band at room temperature is not as high as in metals, thus cannot conductcurrent as good as metal. The electrical conductivity of semiconductor is not as high as metal butalso not as poor as electrical insulator. That is why, this type of material is called semiconductor –means half conductor.
Table for Conductivity of Different Semiconductors
SEMICONDUCTOR CONDUCTIVITY IN SIEMENS/METER AT 20°C
Germanium 2.17
Silicon 1.56X10
Electrical Conductivity of Insulator
Ideally electrical conductivity of an electrical insulator is nil. The atoms in the insulator molecules areelectrically stable enough. The outer most shells of these atoms are completely filled with electrons.In such material where forbidden gap is very large and as a result the energy required by the electronto cross over to the conduction band is practically large enough. Insulators do not conduct electricityeasily. That means the electrical conductivity of insulator is very poor.
Table for Conductivity of Different Insulators
INSULATOR CONDUCTIVITY IN SIEMENS PER METER AT 20°C
Air 3X10 to 8×10
Fused quartz 1.3X10
Glass 10 to 10
Hard rubber 10
Paraffin wax 10
− 3
−15 −15
−18
−11 −15
− 14
−18
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PET 10
Sulfur 10
Teflon 10 to 10
Wood 10 to 10
Objective Questions on Resistance (MCQs)
What is electrical conductance?What is electrical conductivity or specific conductance of a conductor?What is electric conductor?
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−21
−16
−25 −23
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