~e..(.:j~ ~f~ {,f/(' ~~[.u.v pv pocfot j v ~'1leung.uwaterloo.ca/chem/254/ln/s3c...

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- 1/ II i {,f/(' PV c.J - - PoCfot" J V

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Page 1: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less

-1/ II

~ i ~ e..(.:J~ ~ f~ {,f/(' ~~[.u.v PV~ c.J - - PoCfot" J V ~'1

Page 2: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less

(. ) v v

~ a:. (., l~ d $<;:J S ~ w,·~ p V wok ~ ~ h~ (c:~. Y'lc e1f/...w ~,.t') r-----~~~----~~~~~k Jv = ....,. ~-r <:Lv =- 0

l'd,l/:..(6

F~ .J. -)dx +

1;f..t t! fA. ~ U. (17 V) f (" .)

~U ..... /?L() d V +- /dl1j .J I ~ l~v (CD l~T)v @

Grt" d4lv (AC r; v) U{r+d.T>Vt--6V)

G:> d..

f­V

T ucr~~~v)

till ==- U~ - l{ i :::: 4(r.r~r; Y+-tV) tA( T; V)

== U ( T+d, ~._v.~+~6~~T;7rn~;T----;-:~:\U Cr; tI

+

Page 3: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less

Ju == (?C(\ d v 7- C dT ~v ), v

~~ -= It~ c..~.::'r~ 4-T- ~fC v

tJh;f- 13 Cv ?

• '. c,v == -P6v

~= -P(~-Vt)

Page 4: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less
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--

~-;(d~ H(r; p )

@q JH =a: rdP + ~~~1"0r - W (l)~~id~ HCr;-p) :3 H(r~dr; F+dP)

/ I

C. ®~ i fJ,~ H(T+~ p..) d,T=

1

d H=- If (I+dr,p+dP~ - HCr;p)

etf+ == H(T+-J7" P-I-cl,P) - H(r+c!T: p) +- (-+(T+cLT: P .-14(7;1!

-

Page 6: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less
Page 7: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less

rf EE.. fA. +- PV drl:= 6((4+ PV.) :::: dL{-I- ~(~VJ

dH-= Sd-r.f~t~;; -4- ~cl~+ vctP dt-f =:: Cv6i +[p+ ~~ ]dV + vJP

cLH - c

{'dH df> = [P+~l ] JV + vd P .. \ CP r C? vk ) -;-J P

(~~+= [p~~~J&~) + V ~

T

~S~ 7... .r s<' b~c .:::;;.> ~ f- P ~ d F :::::'eJ -ct~ = C:vd -r- -+ if ~Jr] dV

d H- - C

Cpd\ ~ Cvdr -I- [~+d~0rJ d V

Cf" = Cv -+ -!!+fj~)r-] ~~)p J ~6\

Page 8: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less

p.,.s p<1.S' rJOf2;~ _ _ ~ tt. ~S'~1- ~f- of he..r,~/ ~ ~p44~ n.:s r:> less <e.r ~f,oesr~

..fIv- Q,r Uvtsf. vtJ/.u1"'V' -.* ~fa..~('l1;,( ~ ~ ~ 4+ ~~f )(~,£ (/,e.>s~_

C p ~ LV I

~~ f4y ~ J 'I'~l!!!!!!I-;> It~';(

> -(tC'

Page 9: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less
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Cp :::- C{/ of- T~~~~)p

v Cr; P.J 5-(:~" Ij) }

d,+­ T J P dh -t~c! r~1f

--~- ~

v - dr +

,­ v -

p v -~~)r

Cp .:= Cv _ -r l~~)"L (3P:),

d V­

/~_V)liT P

%v \J- ­I

Page 11: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less
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( 0

~/4~

\I E (}~)V

c... ~ C ~ ~ kNo == ~ Rl/ (;) == l/ ~ I 2.,.

I ~/~ 'l Q,~

-::-v =: J- 0 4- .J- r? +- ...L rc - S 0'-- l~ 2- "2..- -- _ I~ l -- z.

Page 13: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less

Df/l-T!;mlC

Page 14: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less

L:5N-S-)x 1<

POL Yh7CJMIc:. M~LcUL=S - • N~#(ftf~

,,;.~l"f N~ f( &!''101~tM/e

e5~ () ==c =0 H~ =. ~-H @1;rzwrs( 3~ ~ ::-t'i?

eJ /'e)"f- · zx;tR = Ir<

3Al -5" ,!ib ~~,J))

3tJ

tJt/NLIN~R

~s. ~~ ~,/ '-..

t+ H ~R:z..uJ

C t+r'J " ~ (~

lJi t:> . ~tv-/') fG

-

Page 15: ~e..(.:J~ ~f~ {,f/(' ~~[.u.v PV PoCfot J V ~'1leung.uwaterloo.ca/CHEM/254/ln/s3c Processes.pdf · p.,.s p less