Transcript
Page 1: V.G. Kirichenko physical series , issue 2 /54/ Diffusion ...nuclear.univer.kharkov.ua/lib/1001_2(54)_12_p114-120.pdf · V.G. Kirichenko 1, O.V. Kovalenko , M.G. Kompaniiets2, V.N

548.1:533.9

-Fe

. . 1, . . 1, . . 2, . . 1

1 . . .

61108, . , . , 31 2Goethe-Universität Frankfurt

Senckenberganlage 31, 60325, Frankfurt am Main E-mail: [email protected]

Received 20 March 2012, accepted 14 May 2012

.

. DAl, DY

. , (Y, Al, Ti) , .

: , , , , , , .

DIFFUSION IN THE SURFACE LAYERS OF OXIDE INCLUSIONS IN DISPERSE STRENGTHENING -Fe V.G. Kirichenko1, O.V. Kovalenko1, M.G. Kompaniiets2, V.N. Leonov1

1Kharkov Karazin National University 31 Kurchatov St., Kharkov, 61108

2Goethe-Universität Frankfurt

Senckenberganlage 31, 60325, Frankfurt am Main The results of the concentration dependence analyzing of the inclusions elemental composition and the matrix to determine the comparative values of diffusion coefficients in disperse strengthening -iron. Numerical simulation of two-dimensional data is allowed to obtain the three-dimensional forms of oxide inclusions. The values for DAl, DY in the iron, involving published data on the diffusion of iron in different temperature ranges. According to our data, the diffusion coefficients of the elements included (Y, Al, Ti) in the case of the model system is higher than the self-diffusion coefficient of iron. KEY WORDS: iron, nanoparticles, oxide, yttrium, structure, phase composition, diffusion.

-Fe

. . 1, . . 1, . . 2, .M. 1

1 . . . 61108, . , . , 31

2 Goethe-Universität Frankfurt Senckenberganlage 31, 60325, Frankfurt am Main

- .

. DAl, DY . ,

(Y, Al, Ti) , . : , , , , , , .

-

, , , [1, 2]. .

– - - ,

( ).

[3-7]. , ,

. « - ».

( ) - .

114

© Kirichenko V.G., Kovalenko O.V., Kompaniiets M.G., Leonov V.N., 2012

«Journal of Kharkiv University», ¹1001, 2012 V.G. Kirichenko...physical series «Nuclei, Particles, Fields», issue 2 /54/ Diffusion in the surface...

Page 2: V.G. Kirichenko physical series , issue 2 /54/ Diffusion ...nuclear.univer.kharkov.ua/lib/1001_2(54)_12_p114-120.pdf · V.G. Kirichenko 1, O.V. Kovalenko , M.G. Kompaniiets2, V.N

, , ( 50-100 )

. FEI Nova NanoLab 600. -

Quanta 3D. . 1 , .

. 1. 0,1 % ( ) 1 .% ( ). 100

. 2 - 10 .

: Y2O2,73, « – ». ( . 3)

3D ( . 2) «Harvard Chart XL».

Fe

Y

Al . 2.

. 3. 3D -

,

115physical series «Nuclei, Particles, Fields», issue 2 /54/ Diffusion in the surface...

Page 3: V.G. Kirichenko physical series , issue 2 /54/ Diffusion ...nuclear.univer.kharkov.ua/lib/1001_2(54)_12_p114-120.pdf · V.G. Kirichenko 1, O.V. Kovalenko , M.G. Kompaniiets2, V.N

. , .

, . ( . 4).

: i j

i j

c cdcdx x x

−=

. 1. ( .

4) .

– ,

,

. , , , –

,

[8]. .

½(VA+VB)( A- B)2>2RT (VA, VB – , A, B –

, = /H VΔ , .

, – – ,

– , . ,

, ,

.

, , , ,

. : 1)

2)

,

.

[8], ,

. ,

( , , . .).

Al

Fe

Y . 4. ,

116«Journal of Kharkiv University», ¹ 1001, 2012 V.G. Kirichenko...

Page 4: V.G. Kirichenko physical series , issue 2 /54/ Diffusion ...nuclear.univer.kharkov.ua/lib/1001_2(54)_12_p114-120.pdf · V.G. Kirichenko 1, O.V. Kovalenko , M.G. Kompaniiets2, V.N

( . 2,3,4)

. , , ,

, [9]. -

« – ». [10]

« – » D:

−=DtDt

CtxC o

4exp

2),(

2ππ

.

(t) ( ) , J = -∇

, [11]. « –

» ( . 2) . (

). . , DAl, DY , DTi, DCr, DY

. ,

:

i ii i i

iFe i Al i Y

Fe Al Y

dc dc dcD x D y Ddx dx dx

= + , (1)

xi, yi – , ,

. 1500-1550 °C.

1150 ° . 1500-1550 ° – 10-4 3/ [12] ( . 5), 1150 ° – 5,7·10-9 3/ [12].

. 5.

: 1 – , 2 – , 3 – ,

4 – [13]

. 6. Fe-Y

- - ( . 6). (1)

, 1500-1550 ° ( . 7, 8) 1150 ° ( . 9, 10).

117physical series «Nuclei, Particles, Fields», issue 2 /54/ Diffusion in the surface...

Page 5: V.G. Kirichenko physical series , issue 2 /54/ Diffusion ...nuclear.univer.kharkov.ua/lib/1001_2(54)_12_p114-120.pdf · V.G. Kirichenko 1, O.V. Kovalenko , M.G. Kompaniiets2, V.N

. 7. ,

=1500-1550 °

. 8.

, =1500-1550 °

.9. , = 1150 ° [13]

. 10. ,

= 1150 ° [13]

. 11.

, = 1150 ° .

. 12. ,

= 1150 ° .

118«Journal of Kharkiv University», ¹ 1001, 2012 V.G. Kirichenko...

Page 6: V.G. Kirichenko physical series , issue 2 /54/ Diffusion ...nuclear.univer.kharkov.ua/lib/1001_2(54)_12_p114-120.pdf · V.G. Kirichenko 1, O.V. Kovalenko , M.G. Kompaniiets2, V.N

. 13. ,

= 1150 ° .

. 14. ,

= 1150 ° .

( . 11-14, ) : – DY = 2,26·10-4 3/ , DAl = 20,5·10-4 3/ ;

– DCr = 2,95·10-9 3/ , DTi = 4,29·10-8 3/ , DY = 6.21·10-10 3/ . , , ,

.

,

° DFe, 3/ DY, 3/ DAl, 3/ DCr, 3/ DTi, 3/

1540 10-4 2,26·10-4 20,51·10-4

1150 5,7·10-9 6,21·10-10 2,95·10-9 4,29·10-8

.

. DAl, DY

. , , ,

.

1. Azarenkov N.A., Voevodin V.N., Kirichenko V.G., Kovtun G.P. Perspektivy primeneniya nanostrukturnykh materialov v

atomnoy energetike // The Journal of Kharkiv National University, physical series “Nuclei, Particles, Fields”. -2010- 887– Iss.1(45). - S.4-24.

2. Hsiung L., Fluss M., Tumey S., Marian J., Kimura A., Willaime F., Serruys Y. Materials Modeling in Nuclear Energy Environment: State of Art and Beyond // SMoRE CRP, PARIS. May 31 to June 4, 2010.

3. 3. Putilov A.V. Razrabotki FGUP VNIINM v oblasti nanotekhnologiy i nanomaterialov dlya atomnoy otrasli // Rossiyskie nanotekhnologii. - 2007. - T.2, 9-10. - S. 6-11.

4. Ivanova I.I., Demidik A.N. Ferritnye dispersno-uprochnennye stali dlya goryachey zony reaktorov na bystrykh neytronakh // Voprosy atomnoy nauki i tekhniki. Seriya: Fizika radiatsionnykh povrezhdeniy i radiatsionnoe materialovedenie. - 2001. -

4(80). - S. 65-68. 5. Ageev V.S., Nikitina A.A., Sagaradze V.V., Safronov B.V., Chukanov A.P., Tsvelev V.V. Ispol'zovanie metodov metallurgii

raspylennykh i bystrozakalennykh poroshkov dlya izgotovleniya obolochek TVELov iz dispersno-uprochnennykh oksidami (DUO) zharoprochnykh ferritno-martensitnykh staley // Voprosy atomnoy nauki i tekhniki. Seriya: Fizika radiatsionnykh povrezhdeniy i radiatsionnoe materialovedenie. - 2007. - . 2(90). - S. 134-141.

119physical series «Nuclei, Particles, Fields», issue 2 /54/ Diffusion in the surface...

Page 7: V.G. Kirichenko physical series , issue 2 /54/ Diffusion ...nuclear.univer.kharkov.ua/lib/1001_2(54)_12_p114-120.pdf · V.G. Kirichenko 1, O.V. Kovalenko , M.G. Kompaniiets2, V.N

6. Okuda T., Fujiwara M. Dispersion behaviour of oxide particles in mechanically alloyed ODS steel // Journal of Materials Science Letters. – 1995. – Vol.14. - P. 1600-1603.

7. Mukhopadhyay D.K.H. Roes F.F., Gelles D.S. Development of oxide dispersion strengthened ferritic steel for fusion // J. Nucl. Mater. - 1998. - Vol. 258-263. - P. 1209-1215.

8. Grigorovich V.K. Elektronnoe stroenie i termodinamika splavov zheleza. – M.: Nauka, 1970. 9. Bokshteyn S.Z. Diffuziya i struktura metallov. - M.: Metallurgiya, 1973. –206 s. 10. Dekhtyar I.Ya., Mikhalenkov V.S., Pilipenko V.V., Silant'ev V.I. Izuchenie diffuzii ksenona v serebre // Sb. «Diffuzionnye

protsessy v metallakh». – Kiev: Naukova Dumka. –1968. –S. 54–60. 11. Kaur I., Gust V. Diffuziya po granitsam zeren i faz. - M.: Mashinostroenie, 1991. – 446 s. 12. Larikov L.N., Mazanko V.F., Nosar' A.I., Fal'chenko V.M. Diffuziya v tverdom tele s uchetom izmeneniya ego razmerov

// Ukrainskiy fizicheskiy zhurnal. - 1977. – T. 22, 9. - S. 1518-1522. 13. 1st International Workshop on Dispersion Strengthened Steels for Advanced Nuclear Applications. DIANA I. Centre CNRS

Paul Langevin, Aussois, France, April 4-8, 2011.-403 p.

120«Journal of Kharkiv University», ¹ 1001, 2012 V.G. Kirichenko...


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