Download - The Chemistry of Acids and Bases
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Acids and Bases: TheoriesAcids and Bases: TheoriesAt the conclusion of our time At the conclusion of our time
together, you should be able to:together, you should be able to:
1. Explain the 3 different theories for an acid, Arrhenius, Bronsted-Lowry, Lewis
2. Explain the 3 different theories for a base, Arrhenius, Bronsted-Lowry, Lewis
3. Identify conjugate acids and bases
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Oh, that smarts!!Oh, that smarts!!
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Theory #1: Arrhenius (traditional) Theory #1: Arrhenius (traditional)
Acids – produce HAcids – produce H++ ions (or hydronium ions (or hydronium ions Hions H33OO++))
Bases – produce OHBases – produce OH-- ions ions
Simple look for an H at the beginning or Simple look for an H at the beginning or an OH at the end of a compoundan OH at the end of a compound
(problem: some bases don’t have (problem: some bases don’t have hydroxide ions!)hydroxide ions!)
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Arrhenius acid is a substance that produces H+ (H3O+) in water. Notice the H on the left.
Arrhenius base is a substance that produces OH- in water, but notice there is no OH- on the left!!
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AcidAcid
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BaseBase
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Theory #1: Arrhenius (traditional) Theory #1: Arrhenius (traditional)
Try #1 on your handout.Try #1 on your handout.
1.1. AA
2.2. SS
3.3. AA
4.4. BB
5.5. SS
6.6. BB
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Pinned!!!Pinned!!!
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Theory #2: Brønsted – LowryTheory #2: Brønsted – Lowry
Acids – proton donorAcids – proton donor
Bases – proton acceptorBases – proton acceptor
A “proton” is really just a A “proton” is really just a hydrogen atom that has lost hydrogen atom that has lost its electron!its electron!
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A Brønsted-Lowry acid is a proton donorA Brønsted-Lowry base is a proton acceptor
acid conjugate base
base conjugate acid
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The Brønsted definition means NHThe Brønsted definition means NH33 is a is a
BASEBASE in water — in water —
and water is itself an and water is itself an ACIDACID
BaseAcidAcidBaseNH4
+ + OH-NH3 + H2OBaseAcidAcidBase
NH4+ + OH-NH3 + H2O
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Label the acid, base, conjugate acid, and Label the acid, base, conjugate acid, and conjugate base in each reaction:conjugate base in each reaction:
CHCH33OH + NHOH + NH22-- CH CH33OO++ + NH + NH33 CHCH33OH + NHOH + NH22-- CH CH33OO++ + NH + NH33
acid conjugate acid
base conjugate base
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Label the acid, base, conjugate acid, and Label the acid, base, conjugate acid, and conjugate base in each reaction:conjugate base in each reaction:
HCN + SOHCN + SO44-2-2 HSO HSO44
-- + CN + CN-- HCN + SOHCN + SO44-2-2 HSO HSO44
-- + CN + CN--
acid conjugate base
base conjugate acid
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Theory #2: Brønsted – LowryTheory #2: Brønsted – Lowry Try Page 10 Top TableTry Page 10 Top Table
1b. OH1b. OH--
2b. H2b. H22OO
3a. HCO3a. HCO33--
4b. NO4b. NO33--
5a. NH5a. NH44++
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Theory #2: Brønsted – LowryTheory #2: Brønsted – Lowry Try Page 10 Bottom TableTry Page 10 Bottom Table
1b. H1b. H33OO++
2b. HCO2b. HCO33--
3b. H3b. H22COCO33
4a. SO4a. SO442-2-
5b. H5b. H33POPO44
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Label the acid, base, conjugate acid, and Label the acid, base, conjugate acid, and conjugate base in each reaction:conjugate base in each reaction:
HCl + POHCl + PO443-3- HPO HPO44
2- 2- + Cl + Cl--HCl + POHCl + PO443-3- HPO HPO44
2- 2- + Cl + Cl--
Acid Base Conjugate A Conjugate B
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Kid’s Kid’s Letters to Letters to
God:God:
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Lewis acid - a substance Lewis acid - a substance that accepts an that accepts an electron pairelectron pair
Lewis base - a Lewis base - a substance that donates substance that donates an electron pairan electron pair
Theory #3 – Lewis Theory #3 – Lewis
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Formation of Formation of hydroniumhydronium ion is an excellent ion is an excellent example of the Lewis definition.example of the Lewis definition.
•Electron pair of the new O-H bond originates Electron pair of the new O-H bond originates on the Lewis base.on the Lewis base.
HH
H
BASE
••••••
O—HO—H
H+
ACID
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•Left. Lewis acidLeft. Lewis acid•Right. Lewis baseRight. Lewis base
Do the Lewis Structures of Both!!
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Acids and Bases: TheoriesAcids and Bases: TheoriesLet’s see if you can:Let’s see if you can:
1. Explain the 3 different theories for an acid, Arrhenius, Bronsted-Lowry, Lewis
2. Explain the 3 different theories for a base, Arrhenius, Bronsted-Lowry, Lewis
3. Identify conjugate acids and bases
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Pass the Clicker!!!
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Which of the following definitions of an Which of the following definitions of an acid includes conjugate acids?acid includes conjugate acids?
1.1. ArrheniusArrhenius
2.2. Bronsted-LowryBronsted-Lowry
3.3. LewisLewis
4.4. KenzigKenzig
5.5. WoodsWoods
6.6. ToburenToburen
7.7. SabolSabol
8.8. SansonSanson
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Which of the following definitions of an Which of the following definitions of an acid defines an acid as a proton donor?acid defines an acid as a proton donor?
1.1. ArrheniusArrhenius
2.2. Bronsted-LowryBronsted-Lowry
3.3. LewisLewis
4.4. KenzigKenzig
5.5. WoodsWoods
6.6. ToburenToburen
7.7. SabolSabol
8.8. SansonSanson
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Which of the following definitions of an Which of the following definitions of an acid defines an acid as accepting an acid defines an acid as accepting an
electron pair?electron pair?
1.1. ArrheniusArrhenius
2.2. Bronsted-LowryBronsted-Lowry
3.3. LewisLewis
4.4. KenzigKenzig
5.5. WoodsWoods
6.6. ToburenToburen
7.7. SabolSabol
8.8. SansonSanson
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Oh my goodness!!!Oh my goodness!!!
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Which of the following definitions of an Which of the following definitions of an acid defines an acid as producing acid defines an acid as producing
hydrogen ions?hydrogen ions?
1.1. ArrheniusArrhenius
2.2. Bronsted-LowryBronsted-Lowry
3.3. LewisLewis
4.4. KenzigKenzig
5.5. WoodsWoods
6.6. ToburenToburen
7.7. SabolSabol
8.8. SansonSanson
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Identify the conjugate base in the Identify the conjugate base in the following equation.following equation.
1.1. NHNH33
2.2. HH22OO
3.3. NHNH44++
4.4. OH-OH-
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Hittite Innovations:Hittite Innovations:
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According to Arrehnius theory,Cu(OH)According to Arrehnius theory,Cu(OH)22 is is
a(n):a(n):
1.1. AcidAcid
2.2. BaseBase
3.3. SaltSalt
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According to Arrehnius theory,NaAccording to Arrehnius theory,Na22SOSO44 is is
a(n): a(n):
1.1. AcidAcid
2.2. BaseBase
3.3. SaltSalt
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Using the Bronsted Lowry theory, the Using the Bronsted Lowry theory, the conjugate base of Hconjugate base of H22SOSO44 would be: would be:
1.1. HSOHSO44++
2.2. HH33SOSO44--
3.3. HSOHSO44--
4.4. HH33SOSO44++
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HH22O + COO + CO332-2- OH OH-- + HCO + HCO33
According to Bronsted Lowry theory, in the According to Bronsted Lowry theory, in the above reaction, Habove reaction, H22O is a(n)O is a(n)
1.1. AcidAcid
2.2. BaseBase
3.3. Conjugate acidConjugate acid
4.4. Conjugate baseConjugate base
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According to Lewis theory,PClAccording to Lewis theory,PCl33 is a(n) is a(n)
1.1. AcidAcid
2.2. BaseBase
3.3. SaltSalt
4.4. Conjugate AcidConjugate Acid
5.5. Conjugate BaseConjugate Base
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HNO is calledHNO is called
1.1. Hydronitric acidHydronitric acid
2.2. Nitric acidNitric acid
3.3. Nitrous acidNitrous acid
4.4. Hyponitrous acidHyponitrous acid
5.5. Pernitric acidPernitric acid
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The pOH of a 0.0030M solution of HThe pOH of a 0.0030M solution of H22SOSO44 is: is:
1.1. 2.522.52
2.2. 11.4811.48
3.3. 2.222.22
4.4. 11.7811.78
5.5. 0.990.99
6.6. 13.0113.01
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Label the acid, base, conjugate acid, and Label the acid, base, conjugate acid, and conjugate base in each reaction:conjugate base in each reaction:
COCO33-2 -2 + H+ H33OO++ HCO HCO33
-- + H + H22OO COCO33-2 -2 + H+ H33OO++ HCO HCO33
-- + H + H22OO
HH22O + NHO + NH22-- NH NH33 + OH + OH-- HH22O + NHO + NH22-- NH NH33 + OH + OH--
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Label the acid, base, conjugate acid, and Label the acid, base, conjugate acid, and conjugate base in each reaction:conjugate base in each reaction:
HCl + OHHCl + OH-- Cl Cl-- + H + H22OO HCl + OHHCl + OH-- Cl Cl-- + H + H22OO
Acid Base Conjugate B Conjugate A