1
Soils and Groundwater Baseline Screening Assessment
& Baseline Report
ESB West Offaly Power Station
Document No.: QS-000139-01-R460-018
Date: 05/04/2019
Engineering and Major Projects, One Dublin Airport Central, Dublin Airport, Cloghran, Co. Dublin,
K67 XF72, Ireland.
Phone +353 (0)1 703 8000
www.esb.ie
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File Reference:
Client/Recipient: ESB West Offaly Power Station
Project Title: IE Licence Review
Report Type: Soils and Groundwater Baseline Report
Report No. QS-000139-01-R460-018
Revision No. 0
Prepared by: Oonagh Duffy Date: 04/12/2018
Title: Senior Environmental Consultant
Verified by: Anne Marie Casey Date: 08/01/2019
Title: Senior Environmental Specialist
Approved by: Paddy Kavanagh Date: 28/04/2019
Title: Planning and Environmental
Team Manager
File
Copyright © ESB
All rights reserved. No part of this work may be modified, reproduced or copied in any form or by any means - graphic, electronic or mechanical, including photocopying, recording, taping or used for any purpose other than its designated purpose, without the written permission of ESB.
Template Used: T-020-017-Engineering and Major Projects Report Template
Change History of Report:
Date New revision Author Summary of Change
Table of Contents
1. Introduction .................................................................................................................... 6
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2. Methodology .................................................................................................................. 6
3. Previous Reports ........................................................................................................... 7
4. Preparing the Report ...................................................................................................... 9
5. Stage 1: Identifying the hazardous substances that are currently used, produced or
released at the installation .................................................................................................. 12
5.1 Guidance Requirements ....................................................................................... 12
5.2 Facility Details ....................................................................................................... 12
5.3 Substances used and generated at the Station & ADF ......................................... 12
6. Stage 2: Identifying the relevant hazardous substances............................................... 15
6.1 Guidance Requirements ....................................................................................... 15
6.2 Identified Hazardous Substances .......................................................................... 15
7. Stage 3: Assessment of Potential Pollution Risk .......................................................... 16
7.1 Guidance Requirements ....................................................................................... 16
7.2 Chemical Storage, Handling & Management......................................................... 16
The following storage and handling condition is stipulated under the IE Licence: ............ 16
7.3 Leachate from the ADF ......................................................................................... 17
7.4 Operational Discharges ........................................................................................ 18
7.5 Stage 3 Summary ................................................................................................. 21
8. Stage 4: Site History .................................................................................................... 22
8.1 Guidance Requirements ....................................................................................... 22
8.2 Site History and Overview ..................................................................................... 22
8.2.1 Ash Disposal Facility ......................................................................................... 23
8.3 Exit Audit of the former ESB Power Station at Shannonbridge .............................. 24
8.4 WOP EIS 2001 ..................................................................................................... 24
8.5 Site Infrastructure.................................................................................................. 26
8.6 Incident History ..................................................................................................... 26
9. Stage 5: Environmental Setting .................................................................................... 27
9.1 Guidance Requirements ....................................................................................... 27
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9.2 Topography........................................................................................................... 27
9.3 Geology and Hydrogeology ................................................................................... 27
9.4 Hydrology ............................................................................................................. 29
9.5 Surrounding land use ............................................................................................ 29
9.6 Natural Habitats .................................................................................................... 30
9.7 Conceptual Site Model .......................................................................................... 30
10. Stage 6: Site Characterisation ...................................................................................... 32
10.1 Guidance Requirements ....................................................................................... 32
10.2 Summary of Groundwater Quality, AECOM Risk Screening and Technical
Assessment, 2015 ........................................................................................................... 32
10.3 ESB 2017 Site Investigation Soil Analytical Results .............................................. 36
10.3.1 ESB 2017 SI Groundwater Monitoring Results .................................................. 38
10.4 Groundwater Monitoring Result 2014 -2017- AER Review .................................... 41
10.4.1 Station – PS - GW1 ........................................................................................... 43
10.4.2 Station – PS - GW2 ........................................................................................... 46
10.4.3 ADF - GW3 ........................................................................................................ 50
10.4.4 ADF- GW4 ......................................................................................................... 53
10.4.5 ADF - GW5 ........................................................................................................ 56
10.4.6 ADF - GW6 ........................................................................................................ 59
10.5 Summary of Soil Site Characteristics .................................................................... 62
10.6 Summary of Ground Water Site Characteristics .................................................... 62
11. Stage 7: Site investigation ............................................................................................ 67
11.1 Guidance Requirements ....................................................................................... 67
11.2 Requirement for Site investigation ........................................................................ 67
12. Stage 8- Baseline Report ............................................................................................. 68
References ......................................................................................................................... 69
Appendix 1: Total Petroleum Hydrocarbons (TPH) Breakdown ........................................... 71
Appendix 2: CSM graphical Representation ........................................................................ 77
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Appendix 3 Soil Analytical Results ...................................................................................... 80
Appendix 4.Soil Laboratory Results .................................................................................... 92
Appendix 5 Groundwater Analytical Results ...................................................................... 181
Appendix 6.Groundwater Laboratory Results .................................................................... 185
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1. Introduction
West Offaly Power (WOP) station is an ESB peat fired station which has been commercially
operational since 2004. The WOP station has one unit, consisting of a boiler, turbine and
auxiliary plant, with an electricity generating capacity of 150MWe. The boiler operates on
peat with gas oil used for start-up. It is scheduled to burn approximately 1,250,000 energy
tonnes of peat each year.
The WOP station is applying to the Environmental Protection Agency (EPA) for a review of
its existing Industrial Emissions (IE) Licence (Licence no. P0611-02), see Attachment-1-1-
Reason for Licence Review. As part of the IE Licence review application, it is necessary to
prepare a Baseline Assessment and Report detailing the findings for submission to the EPA.
The objective of this report is to present the findings of this Baseline Assessment in relation
to soils and groundwater at the WOP site including its associated Ash Disposal Facility
(ADF).
2. Methodology
This report complies with the requirements of Article 22(2) of Directive 2010/75/EU, the
Industrial emissions Directive (IED), which states:
‘Where the activity involves the use, production or release of relevant hazardous
substances and having regard to the possibility of soil and groundwater
contamination at the site of the installation, the operator shall prepare and submit to
the competent authority a baseline report before starting operation of an installation
or before a permit for an installation is updated for the first time after 7 January 2013.
The baseline report shall contain the information necessary to determine the state of
soil and groundwater contamination so as to make a quantified comparison with the
state upon definitive cessation of activities provided for under paragraph 3.’
In addition, Article 22(2) of the IED specifies that a baseline report should contain the
following:
‘information on the present use and, where available, on past uses of the site; and
where available, existing information on soil and groundwater measurements that
reflect the state at the time the report is drawn up or, alternatively, new soil and
groundwater measurements having regard to the possibility of soil and groundwater
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contamination by those hazardous substances to be used, produced or released by
the installation concerned.’
Consideration has also been given to the communication from the European Commission
(EC) namely the EC Guidance Concerning Baseline Reports1 under Article 22(2) of Directive
2010/75/EU on Industrial Emissions during the Compilation of this report.
In line with the commission guidance, there are 8 stages required in determining if a baseline
report is required and to produce the baseline report itself. These stages are as follows:
Stages 1-3: Screening Stages to decide whether a baseline report is required;
Stages 4-7: To determine how a baseline report has to be prepared; and
Stages 8: To determine the content of the report.
3. Previous Reports
A number of historical reports were reviewed during the compilation of this baseline soil and
groundwater assessment as follows:
1. West Offaly Power Industrial Emissions Licence (Licence P0611-02), Annual
Environmental Reports 2014, 2015, 2016 and 2017.
2. Shannonbridge New Peat Power Station Project Environmental Impact Statement
(EIS), Volume 1(ESB, February 2001).
3. West Offaly Power Environmental Liabilities Risk Assessment (ESB, 2016).
4. West Offaly Power Decommissioning Management Plan (DMP) and Closure,
Restoration and Aftercare Management Plan (CRAMP) (ESB, 2016)
5. ESB West Offaly Power Risk Screening and Technical Assessment (AECOM, August,
2015).
6. ESB West Offaly Power Further Environmental Assessment 2015 (AECOM,
November, 2015).
7. SEW Proposal for Permanent Capping Works for Cell No.1, No.2, No.3 and No. 4 at
West Offaly Power Ash Disposal Facility, completed by Bord Na Mona (2014-2016)
1 COMMUNICATION FROM THE COMMISSION; European Commission Guidance concerning
baseline reports under Article 22(2) of Directive 2010/75/EU on industrial emissions 2014/C
136/03
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8. SEW Proposal for Construction of Cell No.5 at West Offaly Power Ash Disposal
Facility, completed by Bord Na Mona (April, 2016)
9. Operational Plan for West Offaly Ash Disposal Facility, prepared by Bord Na Mona
(April, 2015)
10. Shannonbridge Generating Station Environmental Site Investigation: Site
Characterisation Report, prepared by ESBI (September, 1995)
11. ESB Shannonbridge Environmental Exit Audit – Ash Ponds (related to the former ESB
Power Generating Station, Shannonbridge, Co. Offaly) (ESB, 2010).
12. West Offaly Power Station and the Ash Disposal Facility – Site Investigation: Factual
Report and Interpretative Report (Causeway Geotech, 2017)
13. ESB Site Drainage Testing Completion Report 2017 Project at ESB West Offaly
Power, Shannonbridge, Co. Offaly & ESB Lough Ree Power, Lanesborough, Co.
Longford (ESB, 2017).
In 2015, as required under IE Licence Condition 6.14.3, a Risk Screening and Technical
Assessment report of groundwater quality beneath the generating site and associated Ash
Disposal Facility (ADF) was undertaken (report 5 and 6 listed above). These reports are
included as environmental reports to this IE Licence review application as the following
attachments:
Attachment-7-1-3-3-Rec Env Report_ Hydrogeo Report
Attachment-7-1-3-3-Rec Env Report_Hydrogeo Report_2
The WOP station undertakes a groundwater monitoring programme which samples a
number of boreholes across the site in compliance with the requirements of the EPA IE
Licence P0611-02. Groundwater monitoring data for 2014 to 2017 has been compiled and
reviewed and presented in these AER reports (report 1 listed above) and monitoring results
are available within the Annual Environmental Reports (AER), see the following attachments:
Attachment-7-1-3-1_AER 2014;
Attachment-7-1-3-1_AER 2015;
Attachment-7-1-3-1_AER 2016; and
Attachment -7-1-3-1_AER 2017.
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4. Preparing the Report
Table 4-1 presents the main stages when preparing a screening assessment and it
corresponding section in this report.
Table 4-1: Stages in the preparation of a Baseline Assessment
Stage Activity Objective Section
1.
Sc
ree
nin
g S
tag
es
Identify which hazardous substances
are used, produced or released at the
installation and produce a list of these
hazardous substances.
Determine whether or not
hazardous substances are
used, produced or released in
view of deciding on the need to
prepare and submit a baseline
report.
Section 5
2. Identify which of the hazardous
substances from Stage 1 are relevant
hazardous substances. Discard those
hazardous substances that are
incapable of contaminating soil or
groundwater. Justify and record the
decisions taken to exclude certain
hazardous substances.
To restrict further
consideration to only the
relevant hazardous
substances in view of deciding
on the need to prepare and
submit a baseline report.
Section 6
3. For each relevant hazardous
substance brought forward from Stage
2, identify the actual possibility for soil
or groundwater contamination at the
site of the installation, including the
probability of releases and their
consequences, and taking particular
account of:
the quantities of each hazardous
substance or groups of similar
hazardous substances concerned;
how and where hazardous
substances are stored, used and
to be transported around the
installation;
where they pose a risk to be
released;
In case of existing installations
also the measures that have been
To identify which of the
relevant hazardous
substances represent a
potential pollution risk at the
site based on the likelihood of
releases of such substances
occurring. For these
substances, information must
be included in the baseline
report. Section 7
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Stage Activity Objective Section
adopted to ensure that it is
impossible in practice that
contamination of soil or
groundwater takes place.
4.
Bas
eli
ne
Re
po
rt P
rep
ara
tio
n
Provide a site history. Consider
available data and information:
In relation to the present use of the
site, and on emissions of
hazardous substances which have
occurred and which may give rise
to pollution. In particular, consider
accidents or incidents, drips or
spills from routine operations,
changes in operational practice,
site surfacing, changes in the
hazardous substances used.
Previous uses of the site that may
have resulted in the release of
hazardous substances, be they the
same as those used, produced or
released by the existing
installation, or different ones.
Identify potential sources
which may have resulted in the
hazardous substances
identified in Stage 3 being
already present on the site of
the installation.
Section 8
5 Identify the site’s environmental setting
including:
Topography;
Geology;
Direction of groundwater flow;
Other potential migration pathways
such as drains and service
channels;
Environmental aspects (e.g.
particular habitats, species,
protected areas etc.); and
Surrounding land use.
Determine where hazardous
substances may go if released
and where to look for them.
Also identify the environmental
media and receptors that are
potentially at risk and where
there are other activities in the
area which release the same
hazardous substances and
may cause them to migrate
onto the site.
Section 9
6 Use the results of Stages 3 to 5 to
describe the site, in particular
demonstrating the location, type,
extent and quantity of historic pollution
Identify the location, nature
and extent of existing pollution
on the site and to determine
which strata and groundwater
Section
10
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Stage Activity Objective Section
and potential future emissions sources
noting the strata and groundwater
likely to be affected by those emissions
– making links between sources of
emissions, the pathways by which
pollution may move and the receptors
likely to be affected.
might be affected by such
pollution. Compare with
potential future emissions to
see if areas are coincident.
7 If there is sufficient information to
quantify the state of soil and
groundwater pollution by relevant
hazardous substances on the basis of
Stages (1) to (6) then go directly to
Stage 8. If insufficient information
exists then intrusive investigation of
the site will be required in order to
gather such information. The details of
such investigation should be clarified
with the competent authority.
Collect additional information
as necessary to allow a
quantified assessment of soil
and groundwater pollution by
relevant hazardous
substances. Section
11
8
Bas
eli
ne
Re
po
rt
Co
nte
nt
Produce a baseline report for the
installation that quantifies the state of
soil and groundwater pollution by
relevant hazardous substances.
Provide a baseline report in
line with the IED.
Section 9
– 12
represent
s the
Baseline
Report
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5. Stage 1: Identifying the hazardous substances that are currently
used, produced or released at the installation
5.1 Guidance Requirements
Further to the objectives for Stage 1 detailed in Table 4.1 the following is required
under the Commission guidance:
Produce a list of all hazardous substances dealt with inside the installation
boundary (either as raw materials, products, intermediaries, by-products,
emissions or wastes). This should include all hazardous substances associated
with both the IED Annex I activities and directly associated activities which have
a technical connection to the activities carried out and which could have an effect
on soil or groundwater pollution.
Where hazardous substances are listed under trade names the chemical
constituents should also be identified. For mixtures or compounds the relative
proportion of the largest constituent chemicals should be identified.
5.2 Facility Details
The ESB WOP Station is a 150 MWe combustion plant with the ability to fire on peat.
Gas oil is also used to commence firing at start-up phase. Electricity from the facility is
exported into the National Grid. The primary bulk raw materials includes the fuel to be
combusted. There are also a variety of wastes arising from the peat combustion and
environmental control operations on the site. Ash from the combustion process is
disposed of at the dedicated Ash Disposal Facility (ADF). The sites activities are
controlled under the IE Licence for the Site (Licence P611-02) issued by the EPA and
an AER is prepared and submitted for the site. A list of all substances and mixtures
used and produced at the WOP station has been provided as Attachment-4-6-2-Raw-
Material-Interm-Products to the IE Licence review application.
5.3 Substances used and generated at the Station & ADF
The main substances used or produced in the generation of electricity at WOP include:
Peat which is delivered by train and truck to WOP, enters the station through
the Intermediate Peat Storage area (IPS) which is capable of storing 8400
tonnes of peat; and is transferred by conveyor belt system to the day silos. Peat
is a flammable material.
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Gas oil (Diesel) is delivered by road tanker and stored in a 200 m3 bunded
tank. Diesel is a flammable material.
Pulverised Fly Ash (PFA) and Bottom Fly Ash (BFA) which arises from the peat
combustion process are deposited in the stations ADF.
Potentially leachate is generated at the ADF site as a result of the disposal of
ash from the WOP station.
Water from the River Shannon for use as Cooling water and process water.
Cooling water is abstracted and used in a once-through cooling water cycle and
discharged back into the Shannon. Process water is also abstracted and
treated for use in the boiler and subsequently discharge back into the River
Shannon.
A number of other chemical substances are used at WOP to support the water
treatment process (e.g. Ammonia), the wastewater (foul water) treatment
system, the onsite station laboratory and general maintenance works
throughout the station and the ADF. Table 5-1 presents the chemicals stored in
significant volumes on site.
There are a number of surface water discharges from the station and the ADF
which are licensed under the existing IE licence. This includes the discharge of
the cooling water, boiler blowdown, water treatment effluent, treated foul water
from the onsite sewage treatment system and storm water, see further details in
Attachment-4-8-1-Operational Report to this IEL review application
Table 5-1: Major chemicals stored on site
Chemical Container Volume
Caustic Soda (NaOH) 30m3
Sulphuric Acid (H2SO4) 30m3
Caustic Brine 30m3
Ammonia (NH3) 1m3
Diesel (gas oil) 200m3 (auxiliary diesel generator)
1m3 (Diesel tank fire ware pump)
1.3m3 (emergency diesel generator tank)
25 m3 (locomotive fuel)
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Chemical Container Volume
2 x 2.3 m3 (other use)
Lubricating Oil 8 m3
Gear Oil 2.3 m3
Antifreeze 1 m3
Waste Oil 1 m3
Further details of the substances and mixtures used and produced at the WOP station
have been provided as Attachment-4-6-2-Raw-Material-Interm-Products to the IE
Licence review application.
.
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6. Stage 2: Identifying the relevant hazardous substances
6.1 Guidance Requirements
Stage 2 as outlined in the commission guidance requires the following:
From the list produced in Stage 1, determine the potential pollution risk of each
hazardous substance by considering its chemical and physical properties such as:
composition, physical state (solid, liquid, and gas), solubility, toxicity, mobility,
persistence, etc. This information should be used to determine whether or not the
substance has the potential to cause pollution of soil and groundwater. The data,
together with the rationale used to interpret it, should be presented so it is clear in
the baseline report why substances have been excluded or included.
6.2 Identified Hazardous Substances
Based on the materials detailed in Attachment-4-6-2-Raw-Material-Interm-Products and
their quantities stored or produced, the substances considered relevant for this
assessment therefore include:
1. Major chemical stored onsite;
o Caustic Soda (NaOH);
o Sulphuric Acid (H2SO4);
o Caustic Brine;
o Ammonia (NH3);
o Diesel (gas oil);
o Lubricating Oil
o Gear Oil,
o Antifreeze; and
o Waste Oil
2. ADF Leachate (if and when generated); and
3. Operational Discharges such as process and wastewater and the associated site
drainage infrastructure.
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7. Stage 3: Assessment of Potential Pollution Risk
7.1 Guidance Requirements
Stage 3 as outlined in the commission guidance requires the following:
Each substance brought forward from Stage 2 should be considered in the context
of the site to determine whether circumstances exist which may result in the release
of the substance in sufficient quantities to represent a pollution risk, either as a
result of a single emission or as a result of accumulation from multiple emissions.
7.2 Chemical Storage, Handling & Management
The following storage and handling condition is stipulated under the IE Licence:
3.6 Tank, Container and Drum Storage Areas
3.6.1 All tank, container and drum storage areas shall be rendered
impervious to the materials stored therein. Bunds shall be designed having
regard to Agency guidelines ‘Storage and Transfer of Materials for
Scheduled Activities’ (2004).
3.6.2 All tank and drum storage areas shall, as a minimum, be bunded,
either locally or remotely, to a volume not less than the greater of the
following:
(i) 110% of the capacity of the largest tank or drum within the
bunded area; or
(ii) 25% of the total volume of substance that could be stored within
the bunded area.
3.6.3 All drainage from bunded areas shall be treated as contaminated
unless it can be demonstrated to be otherwise. All drainage from bunded
areas shall be diverted for collection and safe disposal, unless it can be
deemed uncontaminated and does not exceed the trigger levels set for
storm water emissions under Condition 6.13 of this licence.
3.6.4 Within six months of the date of grant of this licence, all inlets, outlets,
vent pipes, valves and gauges must be within a bunded area.
3.6.5 All tanks, containers and drums shall be labelled to clearly indicate
their contents.
In addition, Condition 6.9 of the IEL Licence requires the following:
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The integrity and water tightness of all underground pipes, tanks, bunding
structures and containers and their resistance to penetration by water or other
materials carried or stored therein shall be tested and demonstrated by the
licensee within twelve months from date of grant of licence. This testing shall be
carried out by the licensee at least once every three years thereafter and reported
to the Agency on each occasion. This testing shall be carried out in accordance
with any guidance published by the Agency. A written record of all integrity tests
and any maintenance or remedial work arising from them shall be maintained by
the licensee. A report on such tests shall be included in the AER. the site is
required to complete.
The adherence to the above conditions forms part of ongoing environmental monitoring
and management at the site. The most recent bund integrity testing was completed during
2017. All bund are currently compliant , 2017 was the last suite of testing and any failures
were repaired and retested and it is detailed in the AER on an annual basis
The WOP station and ADF is certified to ISO14001. There is an appointed environmental
committee for the site which sits biannually. This committee is responsible for the
implementation of the following good environmental practices aimed at reducing risks
from potential spills and leaks;
All chemicals listed in 6.2 are bunded and/or stored in double skinned containers;
In-house environmental audits are completed regularly ;
All bunds are alarmed;
Bunds are inspected monthly and alarms tested biannually;
Oil tanks are filled to maximum of 75% of their total capacity.
Chemical tanks are filled to maximum of 90% of their total capacity.
7.3 Leachate from the ADF
The ADF is an engineered landfill currently comprising five cells complete with a geo-
synthetic clay liner (GCL) at the base of each cell. Cells 1-3 are already closed and
capped. Cell 4 and 5 are currently in operation. The GCL consists of sodium bentonite
clay, supported by geotextiles, which forms another hydraulic barrier, to prevent leachate
migration to groundwater. The landfill is subdivided into cells which are filled sequentially.
The GCL is overlain with a composite drainage layer (CDL), which collects any leachate
generated. The CDL drains to a leachate collection drainage system at one end of each
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cell, which transfers leachate to a leachate monitoring manhole and from there to a
temporary storage lagoon where it is allowed to settle. Leachate when produced in the
cells is managed through both recirculation and discharge. Once the leachate complies
with the ELVs set out in Section B of License P0611-02, it is discharged to the Gowlan
River north of the ADF. Surface water emissions limits for Ash Disposal Lagoon Outfall
(AL-SW1) are included in Schedule B.2 Emissions to Water of the Existing Licence and
are detailed in Table 7-3.
Table 7-1: Leachate Emission Limits
Source Parameter Emission Limit Value
Ash Disposal Lagoon Outfall (AL-SW1)
pH 6 - 9
Suspended Solids 35 mg/m3
Toxicity 5
In addition to AL-SW1 monitoring point, there are four groundwater monitoring locations
(ADF-GW3 to ADF-GW6) at the ADF site, see Site plan QS-000139-01-D460-020. These
locations are monitored and reported in the AER with regards to Groundwater Threshold
Values (GTVs) (where available) set out in the European Communities Environmental
Objectives (Groundwater) Regulations, 2010 as amended.
7.4 Operational Discharges
There are five sources of operational discharges to surface water within the station and
one within the ADF. These discharges are include;
1. Cooling water;
2. Screen wash water (surface water intake screen);
3. Boiler blowdown;
4. Water treatment effluent;
5. Treated foul water from the onsite sewage treatment system; and
6. Leachate from the ADF cells.
In addition, there are also discharges from the surface water drainage system i.e. storm
water (SW6 and SW7). Surface water from the station is discharged from emission points
SW1, SW2, SW3, SW4 and SW5 and the emission limits are included in Schedule B.2 of
the IE Licence.
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In accordance with EMS 9.1-05, site drainage (including storm water, process and foul)
testing was carried out in 2014, 2017 and 2018. All drainage on site, including drains,
manholes were tested and any defects identified in the 2014 surveys have been repaired.
In 2017 the septic tank, anoxic tank and foul effluent pump sump were emptied and
internal inspections carried out on the septic and anoxic tanks. Internal inspections show
no structural issues in either tank. However, following concerns relating to ground or river
water entering the foul effluent system, inspections and surveys were carried out to
determine the source. The potential area was narrowed down to an estimated 6m gravity
drain from the septic tank to the anoxic tank. The 2017 survey and report recommended
that drains on site should be cleared and washed out, and a drain survey carried out to
determine if ground or river water is entering the drainage system. The surveys including
hydrostatic testing were completed in October 2018. The station is commencing a repair
programme in 2019 in relation to any failed drains from the previous clean and test
programme conducted in 2018
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Table 7-2: Surface Water Discharge Emission Limits
Source Parameter Emission Limit Value
Cooling and
Screen Wash
Water
(PS-SW1 &
PS-SW2)
Thermal load 186 MWth
Residual Chorine
0.1 mg/l2
pH 6 - 8.5
Sewage Treatment Effluent
(PS-SW3)
pH 6 - 9
Temperature 25OC
BOD 20 mg/l
Suspended Solids
30 mg/l
Boiler Blowdown
(PS-SW4)
Temperature Condition 5.5 - Discharges from the installation shall not artificially increase the ambient temperature of the receiving water by more than 1.5oC outside the mixing zone. In relation to temperature, the mixing zone shall not exceed 25% of the cross sectional area of the river at any point.
pH 6-9
Ammonia (as N) 1 mg/l & 0.07 kg/day
Sulphate (as SO4)3
0.5 mg/l
Water Treatment Effluent
(PS-SW5)
Temperature 25oC
pH 6-8.5
Toxicity 10 TU
BOD 20 mg/l
Suspended Solids
30 mg/l
Total Dissolved Solids
30,000 mg/l
Ammonia (as N) 1.5 mg/l & 21.9kg/annum
The ELV is 50mg/l during condensate polisher plant regeneration only
2 Agreed with the EPA on the 20/12/2013- submission LR006046, “not to conduct residual chlorine monitoring on PS-SW1 and SW-2 3 Agreed with the EPA on the 23/06/2017- submission LR029247 not to conduct sulphate monitoring on PS-SW4.
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7.5 Stage 3 Summary
The relevant hazardous substances at WOP Station and the ADF identified in Stage 2
include the following:
Major chemical stored onsite;
Leachate; and
Operational Discharges.
The potential for chemicals, ash leachate and process discharges to pose an
environmental risk is low with the current controls, i.e. storage and drainage infrastructure,
the landfill cell design and surface water management systems and monitoring. However,
due to the sensitive nature of the receiving environment namely the River Shannon and
its associated ecological designations4, a Baseline Report has been compiled for this IE
Licence Review application.
4 The station site is adjacent to the River Shannon and is adjacent to the River Shannon Callows Special Area of Conservation (SAC -Site Code 002160) and the Middle Shannon Callows Special Protection Area (SPA – Site Code 004096). The ADF site is over 3.5 km from the Callows SAC/SPA, is 2.5 km from the Mongan Bog SPA/SAC and 1 km from the Fin Lough SAC.
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8. Stage 4: Site History
8.1 Guidance Requirements
Stage 4 as outlined in the commission guidance requires the following:
The purpose of this section is to determine which of the relevant hazardous
substances identified by Stage 3 have the potential to be present on site in the soil
and groundwater already as a result of activities to date and to determine whether
they are coincident with potential future emission points.
8.2 Site History and Overview
Construction of the original Shannonbridge Generating Station began in the late 1950’s
and there has been continuous production of electricity at the site since 1965 when a 40
MW unit was first commissioned. That station was extended in 1977 and again in 1982
when at which point it had an installed electrical capacity of 125 MW. The EPA issued an
Integrated Pollution Prevention and Control (IPPC) licence (Reg. No. P0626-01) for the
site in April 2003.That station was decommissioned in 2003 and the site was remediated
to the satisfaction of the EPA. The established character and use of the WOP site is
industrial – reflecting its long established use for electricity generation activity.
An environmental exit audit for the original Shannonbridge Generating Station was carried
out in 2009 which assessed soil and groundwater quality beneath the former ash ponds
within the former ESB Power Station at Shannonbridge. Power generating activities
ceased in 2004 and the demolition of the former station buildings was completed in 2009
prior to the exit audit.
The existing station (a 150MW unit) was commissioned by ESB in 2005 as required by
the Electricity Regulation Act 1999 (Public Service Obligations) Order 2002 (SI
No.217/2002). It is a peat-fuelled generation station with an installed capacity of 150 MW
electric. It operates under an IE Licence (P0611-02) issued by the EPA. The footprint of
the previous Shannonbridge units and the former, now decommissioned, ash disposal
facility lie outside the site IE Licenced boundary of WOP generating station.
The site accommodates structures and activities typical of a generating station, including
fuel (principally peat with relatively small volumes of oil used for start-up and combustion
support), storage and handling areas and associated plant; the generation station itself;
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and a range of ancillary services including water treatment and management systems,
offices and administration area.
8.2.1 Ash Disposal Facility
The station’s off-site ADF is located on remote Bord na Móna cutaway bogland at
Clonfinlough, Co. Offaly, approximately 8 km from the power station. The ADF site area
extends to approximately 35 ha. The deposited ash comprises bottom ash and fly ash. Of
the total ash arising, approximately 5% is bottom ash and the remainder is fly ash. The
facility is operated by Bord na Móna on the station’s behalf. The ADF operates under the
same IE licence as the station – Licence P0611-02.
Fly ash and bottom ash are transported to the ADF on Bord na Móna’s narrow gauge rail
system in specially designed saddleback wagons. One train (rake), each containing up to
12 wagons, is used daily, Monday – Saturday. Each wagon comprises two covered ash
buckets with combined capacity of approximately 7-9 m³ of ash. The ash is tipped from
the wagons and is placed in the cells using low bearing pressure tracked earthmoving
plant. The ash is placed semi-dry and is wetted to control potential dust emissions. It is
graded to fall during the filling of the cells to ensure that ponding, resulting in leachate
generation, does not occur. A tractor drawn spray tanker or fixed spray system is used in
wetting the ash to aid compaction and further prevent dust nuisance. Leachate produced
in the cells is managed through both recirculation and discharge. Discharge to the Gowlan
River north of the ADF is undertaken in compliance with the ELVs set out in Section B of
License P0611-02. Three cells (Cells 1, 2 and 3) are already closed and capped, and Cell
4 is operational and partially capped. It is proposed to cap the remaining area of Cell 4
during this year and will be completed next year and Cell 5 is also operational.
Cover and capping that is already in place for completed cells comprises a 1 m layer of
peat / subsoil, which was added in a concave mound design. It is revegetated to blend
with the natural landscape. Cells 1-4 have a basal and capping liner (permanent low
permeability Geosynthetic Clay Liner). From Cell 5 all cells will be entirely lined. The
material to be used for the restoration layer will be a mixture of peat and soil and shall be
sourced on site from existing uprisings stockpiles and cutaway bog within the site
boundary. It is anticipated that Cell 6 will be used from late 2019 / early 2020 and will be
actively in-use when the WOP Station enters its co-firing phase transitioning from peat to
biomass. That cell will be required for acceptance of ash up until end of 2020.
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It is proposed that a further five engineered landfill cells will be developed (Cells 7, 8, 9,
10 and 11). This will extend the ADF footprint by c.173,130 sq.m. This will accommodate
the disposal of an additional c. 929,200 cubic metres of ash (approximately equivalent to
880,000 tonnes). As noted above, this facility will have no defined date of closure but it is
expected it can accommodate ash arisings for a period in the range of 25 years.
To facilitate the extended operation of the ADF, peat soil within the ADF site area and
adjacent to the landfill footprint itself will also be excavated to a depth of circa one metre
to provide material for the final landfill capping layer.
Cells will continue to be capped as they are filled.
8.3 Exit Audit of the former ESB Power Station at Shannonbridge
The environmental exit audit which was as carried out in 2009 assessed soil and
groundwater quality beneath the former ash ponds within the former ESB Power Station
at Shannonbridge. The audit concluded the following:
Soil and water quality in the subject area is not considered to pose a risk to future
site users in a continued industrial/commercial landuse scenario assuming
groundwater and surface water (north and south drains) within the subject area
will not be used as drinking water.
The subject area is considered to be “asbestos safe” as per the ESB brownfield
policy.
The risk to controlled waters from shallow soil, shallow groundwater and surface
water quality in the subject area is considered to be low.
8.4 WOP EIS 2001
An Environmental Impact Statement (ESB, 2001) for the WOP station detailed that:
“Ammoniacal nitrogen was found to exceed the EU Drinking Water Limit for
ammonia of 0.3 mg/l in all eight groundwater samples. Concentrations were
between 3.5 mg/l and 11.4 mg/l. Ammoniacal nitrogen may be naturally present in
groundwater as it is formed by the microbial reduction of other nitrogen
compounds. However, it can also be sourced from foul and industrial wastes that
may be released to the groundwater by septic tanks, agricultural slurry pits, etc.
The widespread occurrence and relative close range of concentrations would
suggest that the ammoniacal nitrogen levels in the groundwater at the site
represent the background concentration range.
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Elevated concentrations were recorded for nitrite (0.05 mg/l, 0.12 mg/l and 0.14
mg/l, which exceed the EU Drinking Water Limit of 0.03 mg/l), Chemical Oxygen
Demand (44 mg/l to 241mg/l, which exceed the EU Surface Water (A3) Limit of 40
mg/l,), faecal coliforms (between 1 cfu/100 ml and 23 cfu/100 ml) and total
coliforms (all >180 cfu/100 ml). These determinands, in a similar manner to
ammoniacal nitrogen, may be associated with foul water discharges.
However, foul water discharge seems unlikely as a source of groundwater
contamination given the location of the site. The elevated Chemical Oxygen
Demand may be due to the presence of significant levels of Organic Carbon in the
water. The organic material in the water would provide a substrate for bacterial
metabolism and this may expand the presence of the coliforms. Where elevated
levels of these four determinants were recorded, they are considered to be
representative of the higher end of the natural background range.
A zinc concentration of 2,810 μg/l, exceeding the EU Drinking Water Limit (1,000
μg/l), was reported in one groundwater sample. This concentration is well above
the other groundwater samples where the highest concentration was 136 μg/l.
Calcium and Iron were found to exceed their respective EU Drinking Water Limits
in two samples. Potassium exceeded the EU Drinking Water Limit (12 mg/l) in two
samples with concentrations of 29 mg/l and 33 mg/l. Elevated concentrations of
calcium, Iron and potassium are thought to be associated with the overburden and
bedrock chemistry and are thus representative of the higher end of the natural
background range. Five of the seven groundwater samples had manganese
concentrations above the EU Drinking Water Limit (50 μg/l) with concentrations
ranging from 81 μg/l in to 699 μg/l. Elevated manganese concentrations are also
thought to relate to bedrock and groundwater geochemistry and are considered to
represent natural background concentrations.
Elevated concentrations of DRO, mineral oil, total phenol and total PAH were
reported in one to two groundwater samples. These elevated hydrocarbon
concentrations are generally not significantly above the concentrations
encountered in the other groundwater samples and may be due to the introduction
of hydrocarbons during fieldwork. It is also possible that the hydrocarbons
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encountered are related to the natural levels and are at the upper end of the
natural range.
Hydrocarbons can be derived from the natural breakdown of larger naturally
occurring organic molecules and the soil samples may, therefore, be more organic
rich than the other samples tested.
In general, while some analytes were at the higher end of their naturally occurring
ranges, the groundwater did not show significant contamination.”
8.5 WOP EIAR 2017
An EIAR was prepared in 2018 to support a planning application to transition WOP from
peat to biomass. As part of this EIAR, environmental soil and groundwater samples were
collected from existing and new boreholes and trial pits in 2017. Samples were analysed
by a UKAS ISO 17025 accredited lab. Results are discussed and incorporated in Section
6 below.
8.6 Site Infrastructure
A certified EMS is in place with procedures for inspection and maintenance of storage
equipment, bunds and drains. The following are the relevant EMS procedures followed on
site;
EMS 11.2-04 Procedure for Testing Bunds Safety Shower Checks.
EMS 11.2-12 Procedure for Inspection and Cleaning of Interceptor.
EMS 9.1-05 Procedure for Maintenance of Drains, Sewers and Pipelines.
8.7 Incident History
The site has a long history of industrial use. However no major incidents, with the
potential to negatively impact soil or water quality, have occurred on site since the
commissioning of WOP station in 2004. Minor incidents have been reported to the EPA as
they occurred within the AERs.
It is noted that a non-compliance in relation to a breach of a quarterly ELV for ammonia
occurred as sampling was undertaken after a condensate polisher regeneration (ammonia
ELV is 50mg/l for a CPP regen) in 2017. WOP station subsequently undertook and
submitted to the EPA additional analysis on this sampling point for approximately two
months to demonstrate compliance with the required ELV. No further action was required.
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9. Stage 5: Environmental Setting
9.1 Guidance Requirements
Stage 5 as outlined in the commission guidance, requires the following:
As a result of Stages 1-4 the locations on the site are identified where future
emissions could occur and where emissions may already have occurred. Stage 5
aims to determine the fate of any such emissions, the strata and groundwater
which may be affected and to establish the extent and depth to which the land
needs to be characterised. This requires an understanding of the characteristics of
the ground and groundwater at the site as well as the surrounding areas that may
influence the site of the installation itself.
Where available, site specific data should be used. When not available use
reference data, qualitative/subjective assessment, inferred or extrapolated data. In
each case the source of the data should be identified, and where this is not site
specific justification for the use of the selected data and include details of any
margins of error which apply.
9.2 Topography
Power Station: West Offaly Power is located approximately 25 km south of Athlone and
approximately 15 km east of Ballinasloe. Immediately south of the site, the River Suck
flows into the River Shannon. The River Shannon is the dominant feature of the
landscape, with all other water bodies in the area flowing into it. The power station site is
at an elevation of 35m – 45m above OD.
Ash Disposal Facility Site: The station’s off-site ADF is located on remote Bord na
Móna cutaway bogland near Derrylahan, Co. Offaly, approximately 8 km from the power
station. The ADF site area extends to approximately 35 ha. The ADF consists of full cells
(which have been filled to capacity and are now capped) and active ash cells (cells still in
use). The area surrounding the ADF site is used by Bord Na Mona for the production and
storage of milled peat. The ground level in the disposal area lies between 35 – 40 m OD
(ESB, 2001). As part of the proposed planning to transition of WOP from peat to biomass
fuel, the ADF will be expanded and will extend over an additional circa 17.3 ha.
9.3 Geology and Hydrogeology
Power Station: The Teagasc soils layers indicates that the site is underlain to the west
and northwest by mineral Alluvium soils and Made ground (at the site of the former
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Shannonbridge Power Station). Part of the site to the northwest sits on Peat Gleys Basic
parent materials with the reminder of the site comprising Grey Brown Podzolics and
surface water and Ground water Gleys derived chiefly from limestone. The main WOP
station site is indicated as being underlain by Alluvium undifferentiated gravelly subsoil to
the west, with Basic esker sands and gravels to the east. The central area of the site
comprises Made ground.
Information from GSI indicates the underlying bedrock is Dinantian Upper Impure
Limestone. Teagasc have identified the subsoil beneath the west of the site as being
Alluvium. The eastern portion of the site is underlain by Till derived chiefly from limestone.
Shallow groundwater is present in the soils above the bedrock. Due to the nature and
extent of this groundwater, this water is not classified as an aquifer by the GSI. The
bedrock aquifer beneath the site is classed as Locally Important (Ll) which is moderately
productive only in local zones. The bedrock below the site is karstic meaning that high
groundwater flows and yields may be encountered in discrete zones. GSI mapping
indicates that the station site is located on two main vulnerability classes, Moderate
vulnerability to the west and High vulnerability to the east. Overall, the flow direction is
likely to be towards the Shannon River to the west and southwest of the groundwater
body.
The GSI database indicates that the nearest two groundwater abstraction wells are
located between 1 - 1.5 km to the north of the site (Raghra Townland adjacent to
Shannonbridge).
Ash Disposal Facility: The ADF is located on Cut-raised Bog cutaway/cutover soils. The
Subsoils beneath the ADF site are Cutover peat.
The GSI website indicates the site is underlain partially to the northwest by the Navan
Beds (Diantian Courcetyan dark Limestone, Mudstone and Sandstone) and mainly to the
southwest by the Ballystein Formation comprising Dark Muddy limestones and Shale. The
GSI Sheet No. 15 indicates that the site is underlain by Carboniferous Argillaceous
Bioclastic limestones (ABL) of Courceyan age. The ABL consists of dark grey
fossiliferous, argillaceous calcarenites interbedded with thin calcareous shales. The Sheet
indicates the presence of a north-east south-west trending fault approximately 1km to the
north of the site.
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The underlying bedrock aquifer is classified by the GSI as a locally important aquifer
(bedrock which is moderately productive only in local zones) with ‘low’ groundwater
vulnerability. There are no Source Protection Zones within 5 km radius of the site. Based
on groundwater elevation data collected in November 2000, groundwater flow direction is
towards the Gowan River northwest of the site.
The WOP station site and the WOP ADF site are located on the Clara groundwater body
(IE_SH_G_240) and is categorised as having a Good status
9.4 Hydrology
Power Station: Both the power station and the ADF are within the Shannon System
catchment and surface drainage ultimately enters this system. Both the Suck and the
Shannon Upper waterbodies are located upstream of WOP station and its discharges.
Process and drainage water from the station site is discharged directly to the River
Shannon.
The Water Framework Directive (WFD) status of the Shannon (Shannon (Lower) 010) is
unassigned. There are seven discharges from the site to the (Shannon (Shannon (Lower)
_010 under the existing IE licence and all are monitored in accordance with IE Licence
No. P0611-02.
Ash Disposal Facility: The ADF is located within an area of cutaway Bord na Móna
commercial peatland located at Derrylahan. There is one surface water discharge point
under the IE licence from the ADF. This discharge point is located on the Blackwater
(Shannonbridge) _020 (known also as the Gowlan River), a tributary of the River
Blackwater, and north of the ADF. The WFD status of the Blackwater (Shannonbridge)
_020 is good.
Any leachate discharged from the ADF to the Blackwater (Shannonbridge) _020 is done
under the existing IE licence and is monitored in accordance with IE Licence No. P0611-
02.
9.5 Surrounding land use
Power Station: The site is situated south of the village of Shannonbridge and is not
adjacent to or affected by other industries which have the potential to cause pollution to
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migrate onto the site. The site is bound to the east by the river Shannon, agricultural fields
to west and north and commercial and residential to the to the south and north.
Ash Disposal Facility: The ADF site is located at Derrylahan, 6.5 km north east of the
WOP site. It occupies an area of 36 ha located within 800 ha of commercial Bord na
Móna peat harvesting land.
9.6 Natural Habitats
The station site is adjacent to the River Shannon and there are several designated sites
located within 15km of WOP Station and the ADF. This includes the River Shannon
Callows SAC and several SAC and SPA sites in the surrounding bogland area. More
details of the Biodiversity in relation to the station and ADF sites is contained within the
following attachments:
Attachment-7-1-3-3-Rec Env Report_AA Screening
9.7 Conceptual Site Model
The Conceptual Site Model (CSM) describes the potential sources of contamination at the
site, the potential migration pathways along which it could migrate and the sensitive
receptors it could impact upon. Figure 9-1 and Figure 9-2 below presents the CSM
identifying the Source-Pathway-Receptor linkages for the station and the ADF compiled
by AECOMin their Risk Screening and Technical Assessment report. A CSM graphical
representation produced by AECOM is presented in Appendix 2 for the station and the
ADF.
Figure 9-1: Station CSM
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Figure 9-2: ADF CSM
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10. Stage 6: Site Characterisation
10.1 Guidance Requirements
Stage 6 as outlined in the Commission guidance requires the following:
A description of the site should in particular demonstrate the location, type, extent
and quantity of historic pollution and potential future emissions sources noting the
strata and groundwater likely to be affected by those emissions.
10.2 Summary of Groundwater Quality, AECOM Risk Screening and Technical
Assessment, 2015
A comprehensive risk based screening assessment of groundwater quality beneath the
site was undertaken by AECOM in 2015 to address Condition 6.14.3 of the IE License. All
available reports and data were considered up to 2015 as part of this assessment.
AECOM produced the following two reports as part of this assessment and in consultation
with the EPA. The reports were completed in accordance with the EPA Guidance on the
Authorisation of Discharges to Groundwater (2011);
AECOM, Risk Screening and Technical Assessment, IEL P0611-02,
Ref:47092932, 20 August 2015 (Attachment-7-1-3-3-Rec Env Report_ Hydrogeo
Report);
AECOM WOP Further Environmental Assessment 2015, Ref 47093108, 13
November 2015 (Attachment-7-1-3-3-Rec Env Report_Hydrogeo Report_2).
The AECOM reports assessed available analytical groundwater data against screening
criteria generated from the following hierarchy;
European Communities Environmental Objectives (Groundwater) Regulations
(GTV), 2011 (Statutory Instrument No. 389 of 2011); and
Environmental Protective Agency’s draft Interim Guideline Values (IGVs) for the
Protection of Groundwater, 2003.
Elevated concentrations of Arsenic, Nickel, Sulphate, Potassium and Manganese were
reported above the screening criteria at the Station and the ADF. Table 10-1 presents the
exceedances identified by AECOM of 2014 analytical results (the most recent available
data set).
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Table 10-1: Elevated Concentrations 2015 Report
Parameter Screening
Criteria
(ug/l)
Reported
Concentrations Range
of Exceedances (ug/l)
Exceeding Wells
- ADF
Exceeding
Wells -
Station
Arsenic 7.5 (GTV) 18 ADF – GW5 -
Nickel 15 (GTV) 15.3 ADF – GW5 -
Potassium 5000 (IGV) 24900 - 26700 ADF-GW4 PS-GW2
Sulphate 187.5 (GTV) 273 - PS-GW2
Manganese 50 (IGV) 58.3 - 550 ADF-GW3, ADF-
GW4, ADF-GW5
and ADF-GW6
PS-GW2
Table 10-2: 2015 Potential Risk Status
Parameter ADF
Exceeding
Wells
Station
Exceeding
Wells
Potential Source Identified Potential Risk
to Groundwater
Status*
Arsenic ADF –
GW5
- Sampling Methodology and
Background geology and
hydrogeology
Low
Nickel ADF –
GW5
- Sampling Methodology and
Background geology and
hydrogeology
Low
Potassium ADF-GW4
and ADF-
GW6
PS-GW2 Either background geology
and hydrogeology or Former
Ash disposal area located at
the station and leachate from
the ADF.
Low
Sulphate - PS-GW2 Former Ash disposal area
located at the station
Low
Manganese ADF-GW3,
ADF-GW4,
ADF-GW5
PS-GW2 Background geology and
hydrogeology
Low
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Parameter ADF
Exceeding
Wells
Station
Exceeding
Wells
Potential Source Identified Potential Risk
to Groundwater
Status*
and ADF-
GW6
Chloride ADF-GW4 - Leachate levels generated
were above the lined section
(1.0 m height) of the cell and
therefore leachate reportedly
seeped out over the lined
portion of the cell. The
Operational plan was revised
in 2014 and new agreement
was reached with the EPA in
2014 regarding the liner and
capping requirements.
Low
*2015 AECOM reports
Since 2011, Total Petroleum Hydrocarbons (TPH) have not been detected at
concentrations exceeding the LOD (1 mg/l). However, it should be noted that the LOD is
greater than the GAC of 0.01 mg/l.
The following are the main conclusions detailed in the AECOM2015 reports:
Potential risks to groundwater were identified from elevated concentrations of
arsenic, nickel, potassium and sulphate. Further monitoring is recommended to
identify any significant upward trends and to confirm or otherwise the potential
risks and to demonstrate compliance with the Groundwater Regulations.
Given that the elevated concentrations of arsenic, nickel, potassium and sulphate
were less than100 times the GAC, the risk to the overall status of the groundwater
body is considered to be low.
An area to the south of the site (the station) is identified as a potential risk to
controlled waters, as it contains landfilled waste materials from the former power
station. It is recommended that a groundwater sample is collected down hydraulic
gradient of this area to assess possible impact to the groundwater body and to
demonstrate compliance with the Groundwater Regulations.
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Bunds were observed to be in a good condition. Bund integrity testing was
completed in 2014 and it was reported to AECOM that all bunds passed the
respective integrity tests. Good environmental management practices are in place
to reduce the risk of spills to the environment.
As each cell within the landfill reaches capacity, it is capped with a permanent low
permeability GCL and as a result, leachate production at the ADF will eventually
cease.
It is recommended that alternative analysis for hydrocarbons is used with an LOD
<10ug/L to screen for potential hydrocarbons.
The EPA requested further information and this was furnished through a second report
issued (AECOMWOP Further Environmental Assessment 2015, Ref 47093108) in
November 2015. To address the EPA queries, additional testing and assessment was
completed as part of this report.
AECOM reported that the sampling methodology undertaken to collect groundwater
samples likely contributed to the elevated concentrations detected. Their additional
assessment of the ADF leachate determined that Arsenic and Nickel concentrations were
below their respective GAC. Consequently the potential risk from the ADF leachate to the
underlying groundwater was considered to be low.
Elevated potassium concentrations were reported at the ADF and the station indicating a
potential risk to the underlying groundwater. The risk is determined as low given that the
elevated concentrations are 100 less than the GAC for potassium and associated with
natural background levels (EIS 2001).
The following conclusions were drawn by AECOM following their additional sampling,
testing and assessment undertaken in “the Former Dump Area” of the former station:
Asbestos Containing Material (ACMs) were present in eleven of the seventeen
test pits excavated. All ACM observed was beneath the surface and mostly in a
bound form. Lose fibrous material was also encountered at depths of between
1.0m and 2.1meters below ground level. No ACM was observed on the surface.
Given that the observed ACM was in all cased buried, that no ACM was observed
on the ground surface and that the area has since been overlain by Bord na Mona
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railway tracks, the generation of airborne asbestos fibres from the subject area
was considered unlikely.
A management system was recommended to be put in place to manage the risks
posed by the identified ACM, particularly in relation to any future excavation works
in the vicinity of the subject area.
10.3 ESB 2017 Site Investigation Soil Analytical Results
A geotechnical site investigation was undertaken in 2017 to support the Environmental
Impact Assessment (EIA) process in relation to the proposed transition to a full biomass
generating station and increasing the capacity of the ADF.
The extent of the investigation included boreholes by cable percussion boring and rotary
drilling, temporary groundwater well installations, trial pits, slit trenches, soil and
groundwater sampling, in-situ and laboratory testing, and the preparation of a factual and
geotechnical interpretative report on the findings.
Six temporary5 groundwater monitoring wells (WOP BH2/17, WOP BH4/17, WOP BH5/17,
WOP BH6/17, WOP BH9/17 and WOP BH11/17) were installed at the station. Three
temporary groundwater monitoring wells were installed at the ADF (WOP_ADF BH01/17,
WOP_ADF BH02/17, WOP-ADF BH03/17) and four IE Licence groundwater monitoring
wells (WOP ADF GW3, WOP ADF GW4, WOP ADF GW5, WOP ADF GW6).
As part of the Site Investigation, soil samples were collected from boreholes and trial pits
excavated across both the station and the ADF. Samples were transported under
standard Chain of Custody and analysed by a UKAS ISO17015 accredited laboratory.
Soil samples were collected from shallow soil at the Station and the ADF and compared
against risk based Generic Assessment Criteria (GAC) to assess the potential risk to
future site users. No significant visual or olfactory signs of contamination were identified
during the course of the site investigation. Soil analytical results are presented in
Appendix 3 and laboratory results presented in Appendix 4.
The GACs used are UK industry standard screening values produced by LQM/CIEH
(Land Quality Management Limited and Chartered Institute of Environmental Health)
5 It is planned that these wells will be decommissioned prior to the commencement of future construction works
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Suitable 4 Use Levels (S4UL6) developed for a range of significant contaminant
parameters and generic land use settings including; in this case, the continued end-use
as a commercial land use and based on 1% Soil Organic Matter. The S4UL GACs are
generic toxicology based health criteria and represent an estimated contaminant
concentration, below which would likely pose a minimal potential risk to Human Health. If
detected concentrations are below the GAC, then the potential risks are not considered
significant. Concentrations above the GAC do not mean a significant risk is present, but
that further consideration is required in order to assess the potential residual risk to
Human Health.
This risk based approach is considered consistent with the Irish EPA guidance on
assessment of contaminated land at EPA Licenced facilities and a best practice approach
in Ireland for the assessment of residual risks associated with ground contamination.
Soil samples were tested for a range of the following parameters;
Metals including Aluminium, Arsenic, Barium, Cadmium, Chromium, Copper, Iron,
Lead, Mercury, Molybdenum, Nickel, Selenium and Zinc
Polycyclic Aromatic Hydrocarbons (PAHS)
Methyl Tertiary Butyl Ether
Benzene, Toluene, Xylene, Ethylbenzene
Total Petroleum Hydrocarbon (TPH)
Ammonicial Nitrogen,
Chloride,
Orthophosphate
Sulphate
Semi Volatile Organic Matter (SVOC)
Volatile Organic Matter (VOC)
Analytical results for all 17 samples collected and analysis at the Station and 16 samples
collected at the ADF, were below their respective GAC or the laboratory LOD. This,
together with the absence of any significant visual or olfactory signs of contamination,
indicate the potential risk to Human Health is low.
6 GACs generated using the UKEA Contaminated Land Exposure Assessment (CLEA)8 model
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10.3.1 ESB 2017 SI Groundwater Monitoring Results
Following the completion of the 2017 Site Investigation, ESB undertook a groundwater
monitoring round sampling all groundwater wells present at the Station and the ADF.
An analysis of the groundwater monitoring data undertaken as part of the groundwater
monitoring round at the WOP station compared to the Groundwater Threshold Values
(GTVs) in the European Communities Environmental Objectives (Groundwater)
Regulations, 2010, (S.I. No. 9 of 2010) and surface EQS. The following parameters were
tested;
Dissolved Metals
PAHs
TPH CWG
BTEX
VOC and SVOC
Organochlorine & Organophosphorus Pesticides
Phenols
Ammoniacal Nitrogen
Chloride
Nitrate
Nitrite
Orthophosphate
Sulphide
Total Coliforms
Groundwater samples were collected at 7 locations across the Station site. The following
table presents the exceedances at the Station wells when compared to their respective
screening criteria. All other parameters were either not detected above the laboratory
lower limit of detection (LOD) or their respective screening criteria and are therefore not
considered further. Analytical results are presented in Appendix 5 and laboratory results
presented in Appendix 6.
Table 10-3: 2017 Station Groundwater Monitoring Results
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Sample ID GW Regulations Screening
Criteria
WOP
BH02/17
WOP BH04/1
7
WOP BH05/1
7
WOP BH06/1
7
WOP BH09/1
7
WOP-PS-
GW1
WOP-PS-
GW2
Sample Date 11/05/2017
11/05/2017
11/05/2017
11/05/2017
11/05/2017
11/05/2017
10/05/2017
GTV IGV
Dissolved Aluminium #
150 (ug/l) 291 20 661 1083 20 20 20
Total Dissolved Iron #
200 (ug/l)
20 7588 21 69 20 242 1800
Dissolved Manganese #
50 (ug/l)
2 928 2 2 239 823 203
Dissolved Sodium #
150 mg/l 160.8
96.1 105 193.6 37.2 11 80.4
Sulphate as SO4 #
187.5 mg/l
120.9
191 310.9 108.3 162.8 41.3 248.6
Ammoniacal Nitrogen as N #
0.175 mg/l
3.69 2.44 6.72 21.29 1.78 0.04 9.81
Elevated dissolved aluminium concentrations (291 ug/l -1083 ug/l) were detected above
the GTV screening criteria (150ug/l) in 3 wells (BH02, BH05 and BH06) sampled at the
former ash landfill at the station. The concentrations detected indicate a potential risk to
the underlying groundwater. However the potential risk to the underlying groundwater is
low given the environmental site setting and that the elevated concentrations are 100 less
than the screening criteria for Aluminium.
Iron concentrations were found to be elevated in 3 wells (BH04, PSGW1 and PSGW2). It
has been previously assessed and reported by AECOM that elevated levels of Iron are
associated with overburden and bedrock chemistry in the area, see Section 9.4 above.
Consequently, the potential risk to the underlying groundwater is considered low given the
environmental site setting and the naturally elevated background concentrations.
Four of the seven groundwater samples had manganese concentrations above the
screening criteria (50 μg/l) with concentrations ranging from 203 μg/l in to 928 μg/l.
Elevated manganese concentrations are also thought to relate to bedrock and
groundwater geochemistry as previously reported by AECOM and are considered to
represent natural background concentrations, see Section 9.4 for further detail.
Dissolved sodium concentrations were detected above the screening criteria at three well
locations (WOP BH02/17, WOP BH06/17). Concentrations are only slightly elevated and
the potential risk to groundwater is therefore considered low.
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Sulphate was detected above the screening criteria (187.5ug/l) in 3 wells (WOP BH04/17,
WOP BH05/17, WOP-PS-GW2) with concentrations ranging between 191ug/l and
310.9ug/l. Sulphate concentrations are only slightly elevated above the screening criteria
and therefore the potential risk to groundwater is low.
Ammoniacal Nitrogen (N) concentrations range 0.04mg/l and 21.29mg/l above the
screening criteria (0.175mg/l) in all 7 samples tested at the station. Similar concentrations
were recorded at the ADF as well as at Lanesborough Power Station and associated ADF
also sent in peat environment. Given the general ranges detected across in similar peat
locations, this indicates natural background levels (associated with decaying peat
material) are elevated in this environment.
Table 10-4: 2017 ADF Groundwater Monitoring Results
Sample ID GW Regulations Screening Criteria
WOP_ADF
BH01/17
WOP_ADF
BH02/17
WOP-ADF
BH03/17
WOP ADF GW3
WOP ADF GW4
WOP ADF GW5
WOP ADF GW6
Sample Date 10/05/2017
10/05/2017
10/05/2017
10/05/2017
10/05/2017
10/05/2017
10/05/2017
Parameters GTV IGV
Dissolved Arsenic
7.5 ug/l 3 19.8 19.1 2.5 2.5 49.5 14.1
Total Dissolved Iron #
200 ug/l 2602 3615 2803 1203 2691 9159 5720
Dissolved Manganese #
50 ug/l 3672 877 168 86 95 56 110
Dissolved Nickel 15 mg/l 2 15 6 2 2 20 2
Ammoniacal Nitrogen as N #
0.175 mg/l
2.07 9.22 7.52 2.03 3.17 7.95 4.71
Similar to groundwater monitoring results reported by AECOM in 2015, Arsenic
concentrations in groundwater at the ADF were detected above the GTV screening
criteria (7.5ug/l) in 4 of the 7 samples analysed. Concentrations ranged between 35ug/l
and 49.5ug/l. AECOM reported in their The Risk Screening and Technical Assessment
Report that the source of the elevated arsenic concentration is unclear but it may be
associated with elevated background concentrations often associated with the regional
geology in the area (impure limestones); or the ash landfilled at the site. Further testing of
ash leachate, undertaken by AECOM and reported in their ESB WOP Further
Assessment report, 2015, determined that arsenic was not a significant leachate from the
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ash material. Consequently, the source of the arsenic is considered to be natural and the
potential environmental risk to groundwater is low.
Iron concentrations were found to be elevated in all 7 wells with concentrations ranging
between 1203ug/l and 9159ug/l. It has been previously been assessed and reported by
AECOM that there are elevated natural background levels of Iron associated with
overburden and bedrock chemistry in the area, see Section 9.4 above. Consequently, the
potential risk to the underlying groundwater is considered low given the environmental site
setting and the naturally elevated background concentrations.
All seven groundwater samples had manganese concentrations above the screening
criteria (50μg/l) with concentrations ranging from 56μg/l to 3672μg/l. Elevated manganese
concentrations are also thought to relate to bedrock and groundwater geochemistry as
previously reported by AECOM and are considered to represent natural background
concentrations.
Dissolved Nickel concentrations (20mg/l) were detected above the screening criteria
(15mg/l) at one well location (WOP ADF GW5). Concentrations are only slightly elevated
and the potential risk to groundwater is therefore considered low.
Ammoniacal Nitrogen (N) concentrations range 2.03mg/l and 9.22mg/l above the GTV of
0.175ug/l in all 7 samples tested at the station. Similar concentrations were recorded at
the ADF as well as at Lanesborough Power Station and associated ADF also set in peat
environment. Given the general ranges detected across in similar peat locations, this
indicates natural background levels are elevated in this environment.
10.4 Groundwater Monitoring Result 2014 -2017- AER Review
A review of the most recent groundwater monitoring data collected as part of the annual
monitoring program, has been undertaken for the purpose of this Baseline Report. Annual
sampling results are collated for the period 2014 to 2017. Monthly and/or quarterly
monitoring are collated for the most recent available results i.e. 2017.
All results for the period 2014 -2017 are contained within the AERs in the following
attachments to this IE Licence review:
Attachment-7-1-3-1_AER 2014
Attachment-7-1-3-1_AER 2015
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Attachment-7-1-3-1_AER 2016
Attachment-7-1-3-1_AER 2017
The IE Licence monitoring requirements in relation to the two monitoring boreholes at the
WOP station site are detailed below.
Table 10-5: Licence requirements: GW1 – GW6 inclusive
Parameter Requirements Frequency Analysis Method/Technique
Visual inspection/odour Quarterly NA
Groundwater Levels Quarterly NA
Total Ammonia Annually Standard Method
Total Nitrogen Annually Standard Method
COD Annually Standard Method
Hydrocarbons Quarterly Standard Method
Chloride Quarterly Standard Method
Sulphate Quarterly Standard Method
Metals/non-metals Annually Standard Method
Nitrate Annually Standard Method
Otho-Phosphate (as P) Annually Standard Method
Mercury Annually Standard Method
Electrical Conductivity Monthly Standard Method
pH Monthly pH electrode and recorder
A summary of the components discussed in the following chapters is seen in Table 10-6:.
Table 10-6:Components and their abbreviations
bbreviation Component Abbreviation Component
Al Aluminium Mn Manganese
As Arsenic Mo Molybdenum
B Boron N Nitrogen
BOD Biological Oxygen Demand Na Sodium
Ca Calcium NH4 Ammonium
Cd Cadmium Ni Nickel
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bbreviation Component Abbreviation Component
COD Chemical Oxygen Demand Pb Lead
Cr Chromium PO4 Phosphate
Cu Copper Se Selenium
Fe Iron SO4 Sulphate
Hg Mercury TPH Total Petroleum
Hydrocarbons
K Potassium Zn Zinc
Mg Magnesium
10.4.1 Station – PS - GW1
Table 10-7 outlines the monitoring result in relation to PS-GW1 for the period 2014-2017
(Annual Sampling) for Total Nitrogen, Ammonia, COD and Phosphorus and Nitrates. The
majority of the annual results are generally below their respective GTVs where these
screening criteria are available. Nitrate concentrations were slightly elevated in 2015,
however concentrations were below the lower limit of detections in subsequent years.
Table 10-7: PS-GW1_ 2014-2017 (Annual Sampling Results)
Year Total Nitrogen
(mg/l)
Ammoniacal Nitrogen
as NH4 (mg/l)
COD (mg/l)
P04 (mg/l)
Nitrates (mg/l)
GTV 0.175 0.375
2014 1 <0.2 13.9 0.05 0.343
2015 <1 <0.2 18.4 0.06 0.45
2016 <1 <0.2 <7 0.02 <0.3
2017 <1 <0.2 <7 0.05 <0.3
Table 10-8 and Table 10-9 outline the monitoring results in relation to PS-GW1 for the
monthly and quarterly 2017 sampling. In 2017 for PS-GW1, the conductivity, pH
monitoring, chloride, Total Petroleum Hydrocarbons (TPH) and Sulphate (SO4) results
are consistently below the either their respective screening criteria or the lowest
laboratory limit of detection (LOD) where available.
Table 10-8: PS-GW1_ 2017 (Monthly Sampling)
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Month pH Conductivity
GTV 1875 (µs/cm)
January 7.3 793
February 7.27 771
March 7.5 877
April 7.4 829
May 7.6 899
June 7.4 749
July 7.4 706
August 7.3 784
September 7.59 728
October 7.2 736
November 7.3 724
December 7.65 759
Table 10-9: PS-GW1_ 2017 (Quarterly Sampling)
Chloride TPH SO4
Units mg/l mg/l mg/l
GTV 187.5 0.075 187.5
Q1 31.4 <1 61.4
Q2 14.2 <1 41.2
Q3 14.1 <1 45.1
Q4 12.9 <1 44.5
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Table 10-10: PS-GW1_ 2014-2017 (Annual Sampling) Metals
Where GTVs or IGV are available for metals, the results are consistently below their respective screening criteria (GTV/IGV) indicating the
potential risk to groundwater is low.
Ca K Na Mg Fe Al As Cd Cu Mo Ni Se Zn B Cr Pb Mn Hg
Units (mg/l) (µg/l)
GTV 150 150 7.5 3.75 1500 15 750 37.5 18.75 0.75
IGV 200 5 50 0.2 100 50
2014 133 1.28 19.4 11.7 <0.019
<2.9 0.615
<0.1 2.54 0.757 <0.15 0.39 2.1 9.4 6.89 0.105 0.483 <0.01
2015 124 <1 14.4 11.9 <0.019
<2.9 0.537
<0.1 <0.85 0.757 2.17 2.04 3.25 16.5 0.719 <0.02 6.06 <0.01
2016 142 <1 16.9 13.7 <0.019
<2.9 0.193
0.1 1.06 0.978 2.41 0.39 3.73 15 2.29 <0.02 8.16 <0.01
2017 163 <1 10 15 0.019 <2 0.815
<0.08 <0.3 3.34 3.37 <0.5 <1 26.4 <1 <0.2 7.56 <0.01
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10.4.2 Station – PS - GW2
PSGW-2 is located outside the boundary of the station in the old Shannonbridge ash
pond and operated under the surrendered IPC Licence 626- outside the IEL boundary of
P0611-02. An exit audit for the ash pond was submitted and accepted by the EPA.
Table 10-11 outlines the annual monitoring result in relation to PS-GW2 for the period
2014-2017 for Total Nitrogen, Ammonia, COD and Phosphorus and Nitrates.
Table 10-11: PS-GW2_ 2014-2017 (Annual Sampling Results)
Year Total Nitrogen
(mg/l)
Ammoniacal Nitrogen
as NH4 (mg/l)
COD (mg/l) P04 (mg/l)
Nitrates (mg/l)
GTV 0.175 0.375
2014 6.42 6.3 14.6 0.314 < 0.3
2015 8.58 1.79 19.1 1.11 0.0842
2016 6.38 4.83 12.7 0.02 0.3
2017 6.79 6.28 17.2 0.35 0.3
Ammoniacal Nitrogen as is elevated in all samples reported between 2014 and 2017
ranging between 1.79mg/l and 6.28mg/l. As detailed in Section 11.3, similar
concentrations were recorded at the Station as well as at Lanesborough Power Station
and associated ADF also set in peat environment. Given the general ranges detected
across in similar peat locations, this indicates natural background levels are elevated in
this environment.
Table 10-12 and Table 10-13 outline the 2017 monthly and quarterly sampling monitoring
results in relation to PS-GW2. During the 2017 groundwater monitoring undertaken at PS-
GW2 the conductivity, pH monitoring, chloride, Total Petroleum Hydrocarbons analytical
results are consistently below the GTV, consequently the potential environmental risk to
groundwater is low.
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Table 10-12: PS-GW2_ 2017 (Monthly Sampling)
Month pH Conductivity (µs/cm)
GTV 1875
January 7.6 1193
February 7.42 1140
March 7.5 1152
April 7.4 1095
May 7.4 1015
June 7.6 1011
July 7.5 926
August 7.3 1136
September 7.75 946
October 7.5 945
November 7.5 930
December 7.78 961
Table 10-13: PS-GW2_ 2017 (Quarterly Sampling)
Chloride (mg/l)
TPH (mg/l) SO4 (mg/l)
GTV 187.5 0.075 187.5
Q1 52.4 <1 205
Q2 52.9 <1 240
Q3 53.8 <1 161
Q4 51.4 <1 166
Sulphate has exceeded the GTV on two occasions in 2017, see Table 10-13. The
concentrations are only slightly exceeding the screening criteria and consequently the
potential risk to groundwater is low. Where GTVs/IGV screening criteria are available for
metals, the results are consistently below with the exception of potassium and
Manganese.
Similar too concentrations recorded at the station, manganese concentrations were
reported above the screening criteria (50μg/l) at PS-GW2. Elevated concentrations range
from 314μg/l to 550μg/l. Elevated manganese concentrations are related to bedrock and
groundwater geochemistry as previously reported by AECOM and are considered to
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represent natural background concentrations. Consequently the potential risk to
groundwater is low.
Potassium concentrations ranging between 24.9ug/l and 27.6ug/l were reported between
2014 and 2017 at PS-GW2. Although the reported concentrations are above the
screening criteria (5mg/l) they are associated with natural background levels (WOP EIS
2001). Consequently they are not considered significant and the potential risk to
groundwater is low.
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Table 10-14: PS-GW2_ 2014-2017 (Annual Sampling) Metals
Ca K Na Mg Fe Al As Cd Cu Mo Ni Se Zn B Cr Pb Mn Hg
Units (mg/l) (µg/l)
GTV 150 150 7.5 3.75 1500 15 750 37.5 0.75
IGV 200 5 50 0.2 100 50
2014 92 24.9 127 27.4 <0.019
<2.9 2.27 <0.1 1.83 0.777 0.15 3.4 3.48 13.3 5.71 0.047 550 <0.01
2015 105 27.6 100 22.1 0.0282
5.3 1.18 <0.1 0.886 <0.24 1.25 5.03 2.48 70 2.21 0.075 324 <0.01
2016 144 <1 17.3 13.6 <0.019
8.07 0.553 <0.1 1.04 1.3 2.6 1.41 5.08 20.6 3.43 0.02 3.99 <0.01
2017 98.9 20.4 80.7 23.8 0.05 3.03 0.5 0.08 0.3 0.88 0.4 0.5 <1 71.5 <1 0.2 314 0.01
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10.4.3 ADF - GW3
Table 10-15 outlines the monitoring result in relation to ADF-GW3 for the period 2014-
2017 (Annual Sampling) for Total Nitrogen, Ammonia, COD and Phosphorus and Nitrates.
Total Nitrogen and Phosphorus.
Table 10-15: ADF-GW3_ 2014-2017 (Annual Sampling Results)
Year Total Nitrogen
(mg/l)
Ammoniacal Nitrogen as NH4 (mg/l)
COD (mg/l)
P04 (mg/l)
Nitrates (mg/l)
GTV 0.175 0.375
2014 1.03 0.262 67.4 <0.05 <0.3
2015 1.28 0.239 67.4 <0.05 0.213
2016 <1 0.745 61.5 <0.02*7 <0.3
2017 <1 <0.2 58.9 <0.05 <0.3
*Limited of detection changed in 2016 from <0.05 to <0.02 mg/l
Ammoniacal Nitrogen concentrations for all samples are above the GTV (0.175mg/l),
albeit marginal in exceedance. Concentrations range between 0.2mg/l and 0.745mg/l.
Ammoniacal Nitrogen concentrations are attributed to elevated natural background levels
and the potential risk to underlying groundwater is considered low as a result.
Table 10-16 and
Table 10-17 outlines the 2017 monthly and quarterly sampling monitoring results in
relation to ADF-GW3. The 2017 PS-GW3 analytical results for electrical conductivity, pH,
chloride, TPH and Sulphate are consistently below the GTVs.
Table 10-16: ADF-GW3_ 2017 (Monthly Sampling)
Month pH Conductivity (µs/cm)
GTV 1875
January 7.1 422
February 7.41 388
March 7.3 482
April 7.3 451
May 7.3 456
June 7.1 520
July 7.3 398
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Month pH Conductivity (µs/cm)
August 7 338
September 7.64 289
October 7.1 382
November 7 383
December 7.6 382
Table 10-17: ADF-GW3_ 2017 (Quarterly Sampling)
Chloride (mg/l)
TPH (mg/l) SO4 (mg/l)
GTV 187.5 0.075 187.5
Q1 13.3 <1 2
Q2 14.4 <1 2
Q3 8.1 <1 2
Q4 9.7 <1 2
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Table 10-18: PS-GW3_ 2014-2017 (Annual Sampling) Metals
Where GTVs/IGV are available for metals, the results are consistently below the GTV with the exception of iron and manganese when
compared to the IGVs.
Iron concentrations exceeding its screening criteria (IGV) of 0.2mg/l range between 0.14mg/l and 0.702mg/l. Manganese concentrations
exceeding its screening criteria (50ug/l) range between 58.3ug/l and 83.5ug/l. Elevated Iron and Manganese concentrations are attributed to
natural background levels and are considered to pose a low potential risk to groundwater.
8 LOD for Selenium in 2017 was <0.5 ug/l 9 LOD for Boron in 2017 was <5 ug/l
Ca K Na Mg Fe Al As Cd Cu Mo Ni Se Zn B Cr Pb Mn Hg
Units (mg/l) (µg/l)
GTV 150 150 7.5 3.75 1500 15 750 37.5 18.75 0.75
IGV 200 5 50 0.2 100 50
2014 71 1.84 10.3 5.35 0.345
9.82 1.44 0.109 2.51 0.284 0.493 <0.39 16.2
9.4 4.41 0.593 58.3 <0.01
2015 49.4 <1 8.23 4.97 0.146
14.9 0.225 0.1 0.954 0.24 0.941 <0.39 23 <9.4 1.16 0.11 2.43 <0.01
2016 83.9 <1 7.2 4.97 0.702
9.72 0.396 0.1 0.85 0.77 1.7 <0.39 3.28
<9.4 1.64 0.021 83.5 <0.01
2017 84.2 <1 6.02 5.36 0.34 16.5 1.28 <0.08 0.35 <0.5 0.817 <0.58 12 <59 <1 <0.2 60.4 <0.01
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10.4.4 ADF- GW4
The 2014-2017 annual groundwater monitoring results for ADF-GW4 are presented in
Table 10-19 for Total Nitrogen, Ammoniacal Nitrogen, COD and Phosphorus and Nitrates.
Table 10-19: ADF-GW4_ 2014-2017 (Annual Sampling Results)
Year Total Nitrogen
(mg/l)
Ammoniacal Nitrogen
as NH4 (mg/l)
COD (mg/l) P04 (mg/l)
Nitrates (mg/l)
GTV 0.175 0.375
2014 3.31 2.83 76.3 <0.05 0.3
2015 2.63 2.46 67.6 <0.05 <0.067710
2016 2.09 1.45 60.2 <0.0211 0.3
2017 3.23 2.67 76.8 <0.05 0.3
Consistent with other monitored locations across the site, Ammonia exceeded its GTV
each year. Concentrations range between 1.45mg/l and 2.83mg/l. Ammoniacal Nitrogen
concentrations are attributed to elevated natural background levels linked to decaying
peat.
Table 10-20 and Table 10-21 outlines the 2017 monthly and quarterly monitoring results
in relation to ADF-GW4. For PS-GW4 for 2017 the conductivity, pH monitoring, Total
Petroleum Hydrocarbons (TPH) and Sulphate (SO4) results are consistently below the
GTV.
Table 10-20: ADF-GW4_ 2017 (Monthly Sampling)
Month pH Conductivity (µs/cm)
GTV 1875
January 7.1 640
February 7.37 594
March 7.2 533
April 7.1 545
May 7.3 538
June 7.2 547
July 7.0 535
August 7.1 673
September 7.37 622
10 LOD for nitrates in 2015 was <0.0677mg/l 11 LOD for PO4 in 2016 was <0.02mg/l
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Month pH Conductivity (µs/cm)
GTV 1875
October 7.0 444
November 7.1 528
December 7.47 519
Table 10-21: ADF-GW4_ 2017 (Quarterly Sampling)
Chloride (mg/l)
TPH (mg/l)
SO4 (mg/l)
GTV 187.5 0.075 187.5
Q1 25 <1 2
Q2 35 <1 2
Q3 12 <1 <2
Q4 33 <1 <2
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Table 10-22: ADF-GW4_ 2014-2017 (Annual Sampling) Metals
Month Ca K Na Mg Fe Al As Cd Cu Mo Ni Se Zn B Cr Pb Mn Hg
Units (mg/l) (µg/l)
GTV 150 150 7.5 3.75 1500 15 750 37.5 18.75 0.75
IGV 200 5 50 0.2 100 50
2014 104 26.7 50.7 3.5 0.181
2.9 5.09 <0.1 2 0.393 0.289
6.46 0.951
<9.4 6.17 0.354 96.9 <0.01
2015 93.8 11.1 32.3 3.86 0.902
8.09 1.6 <0.1 0.85 <0.24 2.39 1.23 0.99 <9.4 1.64 0.651 115 0.0103
2016 81.6 4.27 19 3.74 1.78 7.88 0.55 <0.1 0.85 <0.24 1.63 <0.39
1.44 <9.4 1.98 0.046 88.6 <0.01
2017 95.7 9.69 26.6 2.37 2.19 9.48 0.75 <0.08
<0.3 <0.5 0.664
<0.5 3.24 <5 <1 0.249 99 <0.01
Where GTVs/IGV are available for metals, the results are consistently below the GTV with the exception of potassium, iron and manganese
when compared to the IGVs
Potassium, Iron and Manganese concentrations were reported in the AER above their respective screening criteria between 2014 and 2017.
Potassium concentrations above the screening criteria (5 mg/l) range between 9.69mg/l and 26.7mg/l. Manganese concentrations above the
screening criteria (50ug/l) range between 96.9ug/l and 115ug/l. Elevated Iron concentrations above its screening criteria (0.2mg/l) range
between 0.902mg/l and 2.19mg/l. Elevated concentrations for all three parameters are attributed to natural background levels and are
considered to pose a low potential risk to groundwater.
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10.4.5 ADF - GW5
Table 10-23 outlines the monitoring result in relation to ADF-GW5 for the period 2014-
2017 (Annual Sampling) for Total Nitrogen, Ammonia, COD and Phosphorus and Nitrates.
Table 10-23: ADF-GW5_ 2014-2017 (Annual Sampling Results)
Year Total Nitrogen
(mg/l)
Ammoniacal Nitrogen as NH4 (mg/l)
COD (mg/l)
P04 (mg/l)
Nitrates (mg/l)
GTV 0.175 0.375
2014 7.71 7.42 29.8 <0.05 0.461
2015 7.78 5.59 29.1 <0.05 0.329
2016 9.18 8.74 20.8 <0.0212 <0.3
2017 8.48 8.03 31.1 <0.5 <0.3
Similar to other locations, Ammoniacal Nitrogen exceeds GTV (0.175mg/l) in 2014, 2015,
2016 and 2017 with concentrations ranging between 5.59mg/l and 8.74mg/l. Nitrates
slightly exceeded its GTV (0.375ug/l) in 2014 with a reported concentration of 0.461ug/l.
Subsequent years were below the screening criteria. All other results remain below their
GTV where available.
Table 10-24 and Table 10-25 outlines the monitoring results in relation to ADF-GW5 for
the period 2017 (monthly and quarterly sampling). For all PS-GW5 results for the
conductivity, chloride, Total Petroleum Hydrocarbons (TPH) and Sulphate (SO4) results
are consistently below the GTV.
Table 10-24: ADF-GW5_ 2017 (Monthly Sampling)
Month pH Conductivity (µs/cm)
GTV 1875
January 7.1 686
February 7.05 705
March 7.6 683
April 7 703
May 7.1 639
June 7 658
July 7 638
12 LOD for PO4 in 2016 was <0.02 mg/l
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Month pH Conductivity (µs/cm)
August 7.1 667
September 7.5 525
October 7.0 574
November 7.1 646
December 7.56 648
Table 10-25: ADF-GW5_ 2017 (Quarterly Sampling)
Chloride (mg/l) TPH (mg/l) SO4 (mg/l)
GTV 187.5 0.075 187.5
Q1 12.5 <1 2
Q2 11.6 <1 2
Q3 34 <1 2
Q4 12 <1 2
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Table 10-26: ADF-GW5_ 2014-2017 (Annual Sampling) Metals
Ca K Na Mg Fe Al As Cd Cu Mo Ni Se Zn B Cr Pb Mn Hg
Units (mg/L) (µg/l)
GTV 150 150 7.5 3.75 1500 15 750 37.5 18.75 0.75
IGV 200 5 50 0.2 100 50
2014 138 2.01 10 1.84 0.019 <2.913 18.1 <0.114
1.81 5.73 15.3 <0.315
2.55 <9.4 6.87 0.076 95.1 <0.01
2015 127 1.66 9.12 1.63 <0.019
<2.9 <9.4 <2.9 <0.85 4.34 15.6 5.77 1.91 <9.4 2.25 0.09 51.8 <0.01
2016 138 2.07 9.81 1.95 <0.019
<2.9 13.3 <0.1 <0.85 3.87 21.9 <0.39
6.97 15.1 3.31 <0.02 56 <0.01
2017 138 1.83 9.43 1.98 0.59 <2 13.9 <0.08
<0.3 5.76 19.4 <0.5 1 5.86 1 0.2 53.1 <0.01
Where GTVs/IGV are available for metals, the results are consistently below the GTV with the exception of iron, arsenic, nickel and manganese
when compared to the GTVs/ IGVs.
Iron, Arsenic, Nickle and Manganese concentrations were detected above their respective screening criteria. Iron concentrations were detected
at 0.59mg/l exceeding its IGV (0.2mg/l). Arsenic concentrations ranged between 9.4mg/l and 18.1mg/l exceeding the GTV (7.5mg/l). Nickel
concentrations reported between 2014 and 2017 ranged between 15.3ug/l and 21.9ug/l exceeding its screening criteria (15ug/l). Manganese
concentrations exceed its screening criteria (50ug/l) with concentrations ranging between 51.8ug/l and 95.1ug/l. In all cases, concentrations
were only slightly exceeding their respective screening criteria. Consequently, the potential risk to groundwater is low.
13 LOD for Aluminium in 2014 was <2.9 ug/l 14 LOD for Cadmium in 2014 was <0.1 ug/l 15 LOD for Selenium in 2014 was <0.3 ug/l
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10.4.6 ADF - GW6
Table 10-27 outlines the monitoring result in relation to ADF-GW6 for the period 2014-
2017 (Annual Sampling).
Table 10-27: ADF-GW6_ 2014-2017 (Annual Sampling Results)
Year Total Nitrogen
(mg/l)
Ammoniacal Nitrogen as NH4 (mg/l)
COD (mg/l) P04 (mg/l)
Nitrates (mg/l)
GTV 0.175 0.375
2014 4.48 3.87 49.2 <0.05 <0.3
2015 5.22 4.36 35.1 <0.05 <0.06
2016 4.72 4.32 25.2 <0.02 <0.3
2017 4.5 4.25 33.5 <0.05 <0.3
Nitrates were below its GTV. Ammoniacal Nitrogen concentrations exceed the GTV
(0.175mg/l) with concentrations ranging between 3.87mg/l and 4.36mg/l. are above the
GTV. Ammoniacal nitrogen concentrations are attributed to natural background levels and
therefore pose a low potential risk to groundwater.
Table 10-28 and Table 10-29 outlines the monitoring results in relation to ADF-GW6 for
the period 2017 (monthly and quarterly sampling). For PS-GW3 for 2017 the conductivity,
pH, chloride, Total Petroleum Hydrocarbons (TPH) and Sulphate (SO4) results are
consistently below the GTV.
Table 10-28: ADF-GW6_ 2017 (Monthly Sampling)
Month pH Conductivity (µs/cm)
GTV 1875
January 7 629
February 7.14 639
March 7.2 597
April 7.2 632
May 7.2 603
June 7.2 593
July 7.1 665
August 7.3 673
September 7.49 537
October 7.1 505
November 7.1 562
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Month pH Conductivity (µs/cm)
December 7.1 482
Table 10-29: ADF-GW6_ 2017 (Quarterly Sampling)
Chloride (mg/l)
TPH (mg/l)
SO4 (mg/l)
GTV 187.5 0.075 187.5
Q1 11.2 <1 2
Q2 10.6 <1 2
Q3 10.6 <1 2
Q4 11 <1 2
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Table 10-30: ADF-GW6_ 2014-2017 (Annual Sampling) Metals
Year Ca K Na Mg Fe Al As Cd Cu Mo Ni Se Zn B Cr Pb Mn Hg
Units (mg/L) (µg/l)
GTV 150 150 7.5 3.75 1500 15 N/A 750 37.5 18.75 0.75
IGV 200 5 50 0.2 100 50
2014 110 2.99 11.3 6.83 0.168 <2.9 1.93 <0.1 0.85 1.05 1.62 0.498 2.43 <9.4 4.19 0.183 242 <0.01
2015 118 2.29 9.42 5.01 0.0492
<2.9 1.26 <0.1 <0.85 3.39 1.75 <0.39 5.11 <9.4 2.52 0.16 253 0.0133
2016 110 2.49 9.51 6.42 2.89 3.12 5.03 <0.1 <0.85 2.37 2.46 <0.39 34.2 13 0.632 <0.02 242 <0.01
2017 125 1.78 8 5.39 0.199 <2 4.13 <0.08 <0.3 2.25 0.76 <0.5 1.19 7.31 <1 <0.2 128 <0.01
Where GTVs/IGV are available for metals, the results are consistently below the GTV with the exception of iron and manganese when
compared to the IGVs.
Iron concentrations (2.89mg/l) slightly exceeded its IGV screening criteria (0.2mg/l) in 2016, however subsequent monitoring results were
below the IGV. Manganese concentrations exceed its screening criteria (50ug/l) with concentrations ranging between 128ug/l and 253ug/l. In all
cases, concentrations were only slightly exceeding their respective screening criteria. Manganese concentrations are associated with elevated
natural background levels. Consequently, the potential risk to groundwater is low.
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10.5 Summary of Soil Site Characteristics
No major spills and/or leaks of any chemicals or oils have been reported since
development of the site. Minor events have been reported to the EPA and addressed in
agreement with them.
An area to the south of the site (the station) was identified by AECOM as a potential risk
to controlled waters, as it contains landfilled waste materials from the former power
station. As part of this additional assessment, AECOM reported the following in relation to
soil;
Asbestos Containing Material (ACMs) were present in eleven of the seventeen
test pits excavated. All ACM observed was beneath the surface and mostly in a
bound form. Lose fibrous material was also encountered at depths of between
1.0m and 2.1meters below ground level. No ACM was observed on the surface.
Given that the observed ACM was in all cased buried, that no ACM was observed
on the ground surface and that the area has since been overlain by Bord na Mona
railway tracks, the generation of airborne asbestos fibres from the subject area
was considered unlikely.
Soil samples collected during the 2017 Site Investigation at the Station and the ADF were
below their respective GAC or the laboratory LOD. This, together with the absence of any
significant visual or olfactory signs of contamination, indicate the potential risk to Human
Health is low.
10.6 Summary of Ground Water Site Characteristics
The Risk Screening and Technical Assessment Report prepared by AECOM, in 2015 and
reviewed by the EPA, identified elevated concentrations of Arsenic, Nickel, Sulphate,
Potassium and Manganese above their respective screening criteria at the Station and
the ADF.
Elevated concentrations of Sulphate, Potassium and Manganese were attributed to
elevated natural background levels with an overall low risk identified to the underlying
groundwater bodies at the Station and the ADF.
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AECOM reported that the sampling methodology undertaken to collect groundwater
samples may have contributed to the elevated Arsenic and Nickel concentrations
detected. Additional assessment of the ADF leachate determined that Arsenic and Nickel
concentrations were below their respective screening criteria. Overall, AECOM concluded
that elevated Arsenic and Nickel concentrations were less than 100 times the GAC and
the risk to the groundwater body is reported as low.
Further groundwater monitoring was undertaken in 2017 by ESB at the Station and the
ADF.
Elevated aluminium concentrations were detected at the Station, however the potential
risk to the underlying groundwater is low given the environmental site setting and that the
elevated concentrations are 100 less than the screening criteria for Aluminium.
Iron concentrations were found to be elevated. It has been previously been assessed and
reported by AECOM that there are elevated natural background levels of Iron associated
with overburden and bedrock chemistry in the area, see Section 9.4 above.
Consequently, the potential risk to the underlying groundwater is considered low given the
environmental site setting and the naturally elevated background concentrations.
Groundwater samples collected at the Station had manganese concentrations above the
screening criteria. Elevated manganese concentrations are also thought to relate to
bedrock and groundwater geochemistry as previously reported by AECOM and are
considered to represent natural background concentrations. The potential risk to the
underlying groundwater is therefore considered low.
Dissolved sodium concentrations at the station were detected above the screening criteria
at three well locations at the station. Concentrations are only slightly elevated and the
potential risk to groundwater is therefore considered low.
Sulphate concentrations are only slightly elevated above the screening criteria and
therefore the potential risk to groundwater is low at the station.
Ammoniacal Nitrogen concentrations were reported above the screening criteria in all
samples tested at the station. Similar concentrations were recorded at the ADF as well as
at Lanesborough Power Station and associated ADF also sent in peat environment. Given
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the general ranges detected across in similar peat locations, this indicates natural
background levels (associated with decaying peat material) are elevated in this
environment.
Similar to groundwater monitoring results reported by AECOM in 2015, Arsenic
concentrations at the ADF in groundwater were detected above the screening criteria.
AECOM reported in their The Risk Screening and Technical Assessment Report that the
source of the elevated arsenic concentration is unclear but it may be associated with
elevated background concentrations often associated with the regional geology in the
area (impure limestones); or the ash landfilled at the site. Further testing of ash leachate,
undertaken by AECOM and reported in their ESB WOP Further Assessment report, 2015,
determined that arsenic was not a significant leachate from the ash material.
Consequently, the source of the arsenic is considered to be natural background levels
and the potential environmental risk to groundwater is low.
As with Iron concentrations at the Station, Iron at the ADF was found to be elevated. It
has been previously been assessed and reported by AECOM that there are elevated
natural background levels of Iron associated with overburden and bedrock chemistry in
the area. Consequently, the potential risk to the underlying groundwater is considered low
given the environmental site setting and the naturally elevated background
concentrations.
Manganese concentrations were reported above the screening criteria at the ADF.
Elevated manganese concentrations are also thought to relate to bedrock and
groundwater geochemistry as previously reported by AECOM and are considered to
represent natural background concentrations. The potential risk to groundwater is
therefore considered to be low.
Dissolved Nickel concentrations at the ADF were detected above the screening criteria at
one well location. Concentrations are only slightly elevated and the potential risk to
groundwater is therefore considered low.
Ammoniacal Nitrogen concentrations detected at the ADF were above the screening
criteria. Similar concentrations were recorded at the Station as well as at Lanesborough
Power Station and associated ADF also set in peat environment. Given the general
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ranges detected across in similar peat locations, this indicates natural background levels
are elevated in this environment.
Annual groundwater results collected at the Station and reported in the AER are generally
below their respective GTVs where these screening criteria are available.
No significant groundwater quality issues were identified at PS-GW1. Nitrate
concentrations were slightly elevated in 2015, however concentrations were below the
lower limit of detections in subsequent years.
PSGW-2 is located outside the boundary of the station in the old Shannonbridge ash
pond and operated under the surrendered IPC Licence 626- outside the IEL boundary of
P0611-02. An exit audit for the ash pond was submitted and accepted by the EPA.
Ammoniacal Nitrogen as is elevated in all samples reported between 2014 and 2017
ranging between 1.79mg/l and 6.28mg/l. Similar concentrations were recorded at the
Station as well as at Lanesborough Power Station and its associated ADF which is also
set in peat environment. Given the general ranges detected across in similar peat
locations, this indicates natural background levels are elevated in this environment.
Sulphate has exceeded the screening criteria at PSGW-2 on two occasions in 2017. The
concentrations are only slightly exceeding the screening criteria and consequently the
potential risk to groundwater is low.
Manganese concentrations were reported above the screening criteria at PS-GW2.
Elevated manganese concentrations are related to bedrock and groundwater
geochemistry as previously reported by AECOM and are considered to represent natural
background concentrations. Consequently the potential risk to groundwater is low.
Elevated potassium concentrations were reported between 2014 and 2017 at PS-GW2.
Although the reported concentrations are above the screening criteria they are associated
with natural background levels. Consequently they are not considered significant and the
potential risk to groundwater is low.
At the ADF, Ammoniacal Nitrogen concentrations for all samples are above the screening
criteria. Iron and Manganese and Potassium concentrations also exceed their respective
screening criteria. Ammoniacal Nitrogen, Iron and Manganese concentrations are
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attributed to elevated natural background levels and the potential risk to underlying
groundwater is considered low as a result.
At ADF-GW5, Arsenic and Nickle concentrations were detected above their respective
screening criteria. Concentrations were only slightly exceeding their respective screening
criteria. Consequently, the potential risk to groundwater is low.
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11. Stage 7: Site investigation
11.1 Guidance Requirements
Stage 7 as outlined in the Commission guidance requires the following:
If there is sufficient information from Stages 1-6 to characterise the site both laterally
and vertically and to allow the baseline status in terms of quantified levels of
pollution of soil and groundwater by relevant hazardous substances to be defined,
then go directly to Stage 8. When choosing to use existing information the operator,
in providing it, and competent authority, in assessing it, need to be aware of the
uncertainty and risk associated with using such data.
11.2 Requirement for Site investigation
Baseline information is available from existing data sources, existing reports, site
investigation reports related to construction projects and the comprehensive network of
borehole monitoring locations across the site to provide an assessment of the state of the
soils and groundwater within the site. It is considered that sufficient data is available.
Therefore no further site investigation and assessment is proposed.
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12. Stage 8- Baseline Report
Section 9 to Section 12 of this report represents the baseline report in line with Article
22(1) of Directive 2010/75/EU for the IE licence (no.P611-02) review application for the
WOP station.
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References
ESB West Offaly Power Further Environmental Assessment 2015, completed by
AECOM (November, 2015).
ESB, West Offaly Power Hydrogeological Assessment, completed by AECOM
(June, 2015).
ESB, Shannonbridge New Peat Power Station Project Environmental Impact
Statement (EIS), Volume 1, (February 2001).
ESB West Offaly Power Risk Screening and Technical Assessment (AECOM,
August, 2015).
ESB West Offaly Power Further Environmental Assessment 2015 (AECOM,
November, 2015).
SEW Proposal for Permanent Capping Works for Cell No.1, No.2, No.3 and No. 4
at West Offaly Power Ash Disposal Facility, completed by Bord Na Mona (2014-
2016)
SEW Proposal for Construction of Cell No.5 at West Offaly Power Ash Disposal
Facility, completed by Bord Na Mona (April, 2016)
Operational Plan for West Offaly Ash Disposal Facility, prepared by Bord Na Mona
(April, 2015)
Shannonbridge Generating Station Environmental Site Investigation: Site
Characterisation Report, prepared by ESBI (September, 1995)
ESB Shannonbridge Environmental Exit Audit – Ash Ponds (related to the former
ESB Power Generating Station, Shannonbridge, Co. Offaly) (ESB, 2010).
West Offaly Power Station and the Ash Disposal Facility – Site Investigation:
Factual Report and Interpretative Report (Causeway Geotech, 2017)
ESB, West Offaly Power Industrial Emissions Licence (Licence P611-02), Annual
Environmental Report (2014).
ESB, West Offaly Power Industrial Emissions Licence (Licence P611-02), Annual
Environmental Report (2015).
ESB, West Offaly Power Industrial Emissions Licence (Licence P611-02), Annual
Environmental Report (2016).
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ESB, West Offaly Power Industrial Emissions Licence (Licence P611-02), Annual
Environmental Report (2017).
European Commission(EC), Directive 2010/75/EU of the European Parliament
and of the Council of 24 November 2010 on Industrial Emissions (Integrated
Pollution Prevention and Control) (EC, 2010).
European Commission, Guidance Concerning Baseline Reports under Article
22(2) of Directive 2010/75/EU (EC, 2010).
West Offaly Power Environmental Liabilities Risk Assessment (ESB, 2016).
West Offaly Power Decommissioning Management Plan (DMP) and Closure,
Restoration and Aftercare Management Plan (CRAMP) (ESB, 2016).
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71
Appendix 1: Total Petroleum Hydrocarbons (TPH) Breakdown
GW1 EPH C10-C40
T EPH (C6-C40)
MTBE Benzene Toluene Ethylbenzene mp Xylene O-Xylene BTEX GRO EPH (C6-C10)
Units ug/l
LOD <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q3 2015 <46 <100 3 <7 <4 <5 <8 <3 <28 <10 <100
Q4 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q1 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q2 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q3 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q4 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q1 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q2 2017 <100 <100 <3 <7 <4 <5 <8 6 <28 16 <100
Q3 2017 <100 <100 <3 <7 <4 <5 <8 <3 <29 <10 <100
Q4 2017 <100 <100 <3 <7 <4 <5 <8 <3 <29 <10 <100
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GW2 EPH C10-C40
T EPH (C6-C40)
MTBE Benzene Toluene Ethylbenzene mp Xylene O-Xylene BTEX GRO EPH (C6-C10) GRO C5-C12
Units ug/l
LOD <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q2 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q3 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q2 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q4 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
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GW3 EPH C10-C40
T EPH (C6-C40)
MTBE Benzene Toluene Ethylbenzene mp Xylene O-Xylene BTEX GRO EPH (C6-C10) GRO C5-C12
Units ug/l
LOD <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q2 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q3 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q2 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q4 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
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GW4 EPH C10-C40
T EPH (C6-C40)
MTBE Benzene Toluene Ethylbenzene mp Xylene O-Xylene BTEX GRO EPH (C6-C10) GRO C5-C12
Units ug/l
LOD <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2015 163 163 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q2 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q3 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q2 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 12 <100 <50
Q4 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 12 <100 <50
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GW5 EPH C10-C40
T EPH (C6-C40)
MTBE Benzene Toluene Ethylbenzene mp Xylene O-Xylene BTEX GRO EPH (C6-C10) GRO C5-C12
Units ug/l
LOD <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q2 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q3 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q2 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100
Q3 2017 <100 <100 <3 <7 19 <5 12 8 39 50 <100 59
Q4 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
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GW6 EPH C10-C40
T EPH (C6-C40)
MTBE Benzene Toluene Ethylbenzene mp Xylene O-Xylene BTEX GRO EPH (C6-C10) GRO C5-C12
Units ug/l
LOD <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2015 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q2 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q3 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q4 2016 <46 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 -
Q1 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q2 2017 <100 <100 <3 <7 <4 <5 <8 <3 <28 <10 <100 <50
Q3 2017 <100 <100 <3 <7 19 <5 12 8 39 50 <100 59
Q4 2017 <100 <100 <3 <7 <4 <5 <8 5 <28 13 <100 <50
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Appendix 2: CSM graphical Representation
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80
Appendix 3 Soil Analytical Results
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DescriptionWOP ADF
Boreholes
WOP ADF
Boreholes
JE Job No. 17/4799 17/4799
J E Sample No. 1-4 5-8
Sample IDWOP-ADF
BH01/17
WOP-ADF
BH03/17
Sampled Date Time 22/02/2017 22/02/2017
Sample Type Soil Soil
Depth 2.20 4.00
Chem Group Chem Name Unit LOD Commercial #3
Aluminium mg/kg <50 No S4UL 7939 7472
Arsenic # mg/kg <0.5 640 3.9 7.3
Barium # mg/kg <1 No S4UL 51 43
Cadmium # mg/kg <0.1 190 1.2 1.2
Chromium # mg/kg <0.5 8600 24.4 33.7
Copper # mg/kg <1 68000 19 17
Iron mg/kg <20 No S4UL 12480 12070
Lead # mg/kg <5 No S4UL 15 13
Mercury #mg/kg <0.1
1100 *
58vap
(25.8) **<0.1 <0.1
Molybdenum # mg/kg <0.1 No S4UL 1.1 2
Nickel # mg/kg <0.7 980 39.3 38.5
Selenium # mg/kg <1 12000 <1 <1
Zinc # mg/kg <5 730000 86 75
Natural Moisture Content % <0.1 No S4UL 26.2 26.3
Ammoniacal Nitrogen as N mg/kg <0.6 No S4UL 10.6 -
Chloride # mg/kg <2 No S4UL 18 -
Hexavalent Chromium # mg/kg <0.3 33 <0.3 <0.3
Ortho Phosphate as PO4 mg/kg <0.3 No S4UL <0.3 -
Sulphate as SO4 (2:1 Ext) # g/l <0.0015 No S4UL 0.0248 -
Chromium III mg/kg <0.5 8600 24.4 33.7
Organic Matter % <0.2 No S4UL 1.1 -
Notes
# ISO17025 (UKAS) accredited - UK.
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter
*inorganic mercury
**elemental mercury
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
Produced: Keelin Timoney
Checked: Patrick Sweeney
Approved: Anne Marie Casey
Metals
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Description WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
WOP ADF
Trial Pits
JE Job No. 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272
J E Sample No. 1-2 3-4 5-6 7-8 11-12 15-16 17-18 21-22 23-24 25-26 27-28 31-32 33-34 35-36
Sample IDWOP-ADF
TP02/17
WOP-ADF
TP02/17
WOP-ADF
TP03/17
WOP-ADF
TP03/17
WOP-ADF
TP04/17
WOP-ADF
TP05/17
WOP-ADF
TP06/17
WOP-ADF
TP07/17
WOP-ADF
TP08/17
WOP-ADF
TP08/17
WOP-ADF
TP09/17
WOP-ADF
TP10/17
WOP-ADF
TP01/17
WOP-ADF
TP01/17
Sampled Date Time 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Depth 1.50 2.50 0.50 1.50 2.50 2.00 1.00 1.50 0.50 2.50 1.00 1.00 1.50 3.00
Chem Group Chem Name Unit LOD Commercial #2
Aluminium mg/kg <50 No S4UL 212 7575 23690 9008 6804 4400 974 1352 - 1559 1393 7952 511 4662
Arsenic # mg/kg <0.5 640 #3 0.5 7.5 5.2 2.0 11.1 2.9 2.5 1.1 - 1.4 1.0 3.3 0.7 5.9
Barium # mg/kg <1 No S4UL 34 47 120 28 88 19 29 8 - 9 9 31 9 25
Cadmium # mg/kg <0.1 190 #3 <0.1 1.0 0.7 0.2 1.0 0.8 0.2 0.7 - 0.6 0.9 0.5 <0.1 0.9
Chromium # mg/kg <0.5 8600 #3 19.0 27.7 58.9 27.5 30.9 29.6 33.9 17.1 - 15.2 17.4 48.6 16.5 32.2
Copper # mg/kg <1 68000 #3 2 15 34 11 16 11 5 5 - 6 5 15 3 11
Iron mg/kg <20 No S4UL 4812 10640 16960 13320 14140 6663 6474 3045 - 5475 2574 8603 1168 8860
Lead # mg/kg <5 No S4UL <5 13 31 12 13 9 <5 5 - <5 7 11 <5 10
Mercury # mg/kg <0.11100 *#3
58vap
(25.8) **#3<0.1 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 - <0.1 <0.1 <0.1 <0.1 <0.1
Molybdenum # mg/kg <0.1 No S4UL 2.1 1.6 1.0 0.6 2.4 2.2 3.1 0.6 - 0.6 0.8 3.1 1.3 2.2
Nickel # mg/kg <0.7 980 #3 3.8 37.7 75.0 31.1 34.1 24.5 10.3 9.9 - 12.5 9.2 37.9 2.9 28.7
Selenium # mg/kg <1 12000 #3 2 <1 1 <1 2 <1 2 <1 - <1 <1 1 <1 <1
Zinc # mg/kg <5 730000 #3 <5 69 121 62 64 36 9 23 - 26 18 58 <5 48
Naphthalene # mg/kg <0.04 190 (76.4) sol - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
Acenaphthylene mg/kg <0.03 83000 (86.1) sol - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 - <0.03 <0.03
Acenaphthene # mg/kg <0.05 84000 (57) sol - <0.05 <0.05 <0.05 - - <0.05 <0.05 - - <0.05 - <0.05 <0.05
Fluorene # mg/kg <0.04 63000 (30.9) - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
Phenanthrene # mg/kg <0.03 22000 - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 - <0.03 <0.03
Anthracene # mg/kg <0.04 520000 - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
Fluoranthene # mg/kg <0.03 23000 - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 - <0.03 <0.03
Pyrene # mg/kg <0.03 54000 - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 - <0.03 <0.03
Benzo(a)anthracene # mg/kg <0.06 170 - <0.06 <0.06 <0.06 - - <0.06 <0.06 - - <0.06 - <0.06 <0.06
Chrysene # mg/kg <0.02 350 - <0.02 <0.02 <0.02 - - <0.02 <0.02 - - <0.02 - <0.02 <0.02
Benzo(bk)fluoranthene # mg/kg <0.07 No S4UL - <0.07 <0.07 <0.07 - - <0.07 <0.07 - - <0.07 - <0.07 <0.07
Benzo(a)pyrene # mg/kg <0.04 35 - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
Indeno(123cd)pyrene # mg/kg <0.04 500 - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
Dibenzo(ah)anthracene # mg/kg <0.04 3.5 - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
Benzo(ghi)perylene # mg/kg <0.04 3900 - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
Coronene mg/kg <0.04 No S4UL - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 - <0.04 <0.04
PAH 17 Total mg/kg <0.64 No S4UL - <0.64 <0.64 <0.64 - - <0.64 <0.64 - - <0.64 - <0.64 <0.64
Benzo(b)fluoranthene mg/kg <0.05 44 - <0.05 <0.05 <0.05 - - <0.05 <0.05 - - <0.05 - <0.05 <0.05
Benzo(k)fluoranthene mg/kg <0.02 1200 - <0.02 <0.02 <0.02 - - <0.02 <0.02 - - <0.02 - <0.02 <0.02
Methyl Tertiary Butyl Ether # ug/kg <2 No S4UL - - <2 <2 - - - <2 - - <2 - <2 <2
Benzene # ug/kg <3 27000 - - <3 <3 - - - <3 - - <3 - <3 <3
Toluene # ug/kg <3 56000000vap (869000) - - <3 <3 - - - <3 - - <3 - <3 <3
Ethylbenzene # ug/kg <3 5700000vap (518000) - - <3 <3 - - - <3 - - <3 - <3 <3
p/m-Xylene # ug/kg <55900000sol (576000)
/ 6200000vap (625000)- - <5 <5 - - - <5 - - <5 - <5 <5
o-Xylene # ug/kg <3 6600000sol (478000) - - <3 <3 - - - <3 - - <3 - <3 <3
Notes
# ISO17025 (UKAS) accredited - UK. Produced: Keelin Timoney
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter Checked: Patrick Sweeney
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter Approved: Anne Marie Casey
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
*inorganic mercury
**elemental mercury
a S4UL for >C16-C35
b S4UL for >EC21-EC35
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
Metals
PAH MS
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EPA Export 28-05-2019:04:59:37
Description
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
JE Job No. 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272 17/3272
J E Sample No. 1-2 3-4 5-6 7-8 11-12 15-16 17-18 21-22 23-24 25-26 27-28 31-32 33-34 35-36
Sample IDWOP-ADF
TP02/17
WOP-ADF
TP02/17
WOP-ADF
TP03/17
WOP-ADF
TP03/17
WOP-ADF
TP04/17
WOP-ADF
TP05/17
WOP-ADF
TP06/17
WOP-ADF
TP07/17
WOP-ADF
TP08/17
WOP-ADF
TP08/17
WOP-ADF
TP09/17
WOP-ADF
TP10/17
WOP-ADF
TP01/17
WOP-ADF
TP01/17
Sampled Date Time 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Depth 1.50 2.50 0.50 1.50 2.50 2.00 1.00 1.50 0.50 2.50 1.00 1.00 1.50 3.00
Chem Group Chem Name Unit LOD Commercial #2
>C5-C6 # mg/kg <0.1 3200 (304) sol - - - <0.1 - - - <0.1 - - <0.1 - - <0.1
>C6-C8 # mg/kg <0.1 7800 (144) sol - - - <0.1 - - - <0.1 - - <0.1 - - <0.1
>C8-C10 mg/kg <0.1 2000 (78) sol - - - <0.1 - - - <0.1 - - <0.1 - - <0.1
>C10-C12 # mg/kg <0.2 9700 (48) sol - - - <0.2 - - - <0.2 - - <0.2 - - <0.2
>C12-C16 # mg/kg <4 59000 (24) sol - - - <4 - - - <4 - - <4 - - <4
>C16-C21 # mg/kg <7 160000 a - - - <7 - - - <7 - - <7 - - <7
>C21-C35 # mg/kg <7 160000 a - - - <7 - - - <7 - - <7 - - <7
Total aliphatics C5-35 mg/kg <19 160000 a - - - <19 - - - <19 - - <19 - - <19
>C5-EC7 # mg/kg <0.1 26000 (1220) sol - - - <0.1 - - - <0.1 - - <0.1 - - <0.1
>EC7-EC8 # mg/kg <0.1 56000vap (869) - - - <0.1 - - - <0.1 - - <0.1 - - <0.1
>EC8-EC10 # mg/kg <0.1 3500 (613) vap - - - <0.1 - - - <0.1 - - <0.1 - - <0.1
>EC10-EC12 # mg/kg <0.2 16000 (364) sol - - - <0.2 - - - <0.2 - - <0.2 - - <0.2
>EC12-EC16 # mg/kg <4 36000 (169) sol - - - <4 - - - <4 - - <4 - - <4
>EC16-EC21 # mg/kg <7 28000 - - - <7 - - - <7 - - <7 - - <7
>EC21-EC35 # mg/kg <7 28000 - - - <7 - - - <7 - - <7 - - <7
Total aromatics C5-35 # mg/kg <19 28000 b - - - <19 - - - <19 - - <19 - - <19
Total aliphatics and aromatics(C5-35) mg/kg <38 160000 a - - - <38 - - - <38 - - <38 - - <38
Natural Moisture Content % <0.1 No S4UL 472.4 28.1 38.7 14.7 50.3 14.0 780.0 12.5 878.3 9.3 11.5 17.7 670.0 15.6
Organic Matter % <0.2 No S4UL - - - 0.5 - - - 0.2 - - - - - 1.0
Ammoniacal Nitrogen as N mg/kg <0.6 No S4UL 17.2 - - <0.6 - - - <0.6 28.4 - - - - 4.9
Chloride # mg/kg <2 No S4UL 148 - - 24 - - - 22 121 - - - - 29
Hexavalent Chromium # mg/kg <0.3 33 #3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 - <0.3 <0.3 <0.3 <0.3 <0.3
Ortho Phosphate as PO4 mg/kg <0.3 No S4UL <0.3 - - <0.3 - - - <0.3 5.6 - - - - <0.3
Sulphate as SO4 (2:1 Ext) # g/l <0.0015 No S4UL 0.0820 - - 0.0243 - - - 0.0038 0.0115 - - - - 0.0111
Chromium III mg/kg <0.5 8600 #3 19.0 27.7 58.9 27.5 30.9 29.6 33.9 17.1 - 15.2 17.4 48.6 16.5 32.2
SVOC MS 2-Chlorophenol # ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
2-Methylphenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
2-Nitrophenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
2,4-Dichlorophenol # ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
2,4-Dimethylphenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
2,4,5-Trichlorophenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
2,4,6-Trichlorophenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
4-Chloro-3-methylphenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
4-Methylphenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
4-Nitrophenol ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
Pentachlorophenol ug/kg <10 400000 - - - <10 - - - - - - - - - <10
Phenol # ug/kg <10 760000dir (31000000) - - - <10 - - - - - - - - - <10
2-Chloronaphthalene # ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
2-Methylnaphthalene # ug/kg <10 No S4UL - - - <10 - - - - - - - - - <10
Bis(2-ethylhexyl) phthalate ug/kg <100 No S4UL - - - <100 - - - - - - - - - <100
Butylbenzyl phthalate ug/kg <100 No S4UL - - - <100 - - - - - - - - - <100
Di-n-butyl phthalate ug/kg <100 No S4UL - - - <100 - - - - - - - - - <100
Di-n-Octyl phthalate ug/kg <100 No S4UL - - - <100 - - - - - - - - - <100
Diethyl phthalate ug/kg <100 No S4UL - - - <100 - - - - - - - - - <100
Dimethyl phthalate # ug/kg <100 No S4UL - - - <100 - - - - - - - - - <100
Notes
# ISO17025 (UKAS) accredited - UK. Produced: Keelin Timoney
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter Checked: Patrick Sweeney
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter Approved: Anne Marie Casey
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
*inorganic mercury
**elemental mercury
a S4UL for >C16-C35
b S4UL for >EC21-EC35
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
Phthalates
TPH CWG
Aliphatics
Aromatics
Phenols
PAHS
For
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ectio
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se.
EPA Export 28-05-2019:04:59:37
Description WOP ADF
Trial Pits
WOP ADF
Trial Pits
JE Job No. 17/3272 17/3272
J E Sample No. 7-8 35-36
Sample IDWOP-ADF
TP03/17
WOP-ADF
TP01/17
Sampled Date Time 30/01/2017 30/01/2017
Sample Type Soil Soil
Depth 1.50 3.00
Chem Group Chem Name Unit LOD Commercial #2
1,2-Dichlorobenzene ug/kg <10 2000000 (571000) sol <10 <10
1,2,4-Trichlorobenzene # ug/kg <10 220000 <10 <10
1,3-Dichlorobenzene ug/kg <10 30000 <10 <10
1,4-Dichlorobenzene ug/kg <10 4400000 (224000) vap <10 <10
2-Nitroaniline ug/kg <10 No S4UL <10 <10
2,4-Dinitrotoluene ug/kg <10 No S4UL <10 <10
2,6-Dinitrotoluene ug/kg <10 No S4UL <10 <10
3-Nitroaniline ug/kg <10 No S4UL <10 <10
4-Bromophenylphenylether # ug/kg <10 No S4UL <10 <10
4-Chloroaniline ug/kg <10 No S4UL <10 <10
4-Chlorophenylphenylether ug/kg <10 No S4UL <10 <10
4-Nitroaniline ug/kg <10 No S4UL <10 <10
Azobenzene ug/kg <10 No S4UL <10 <10
Bis(2-chloroethoxy)methane ug/kg <10 No S4UL <10 <10
Bis(2-chloroethyl)ether ug/kg <10 No S4UL <10 <10
Carbazole ug/kg <10 No S4UL <10 <10
Dibenzofuran # ug/kg <10 No S4UL <10 <10
Hexachlorobenzene ug/kg <10 110000 (200) vap <10 <10
Hexachlorobutadiene # ug/kg <10 31000 <10 <10
Hexachlorocyclopentadiene ug/kg <10 No S4UL <10 <10
Hexachloroethane ug/kg <10 No S4UL <10 <10
Isophorone # ug/kg <10 No S4UL <10 <10
N-nitrosodi-n-propylamine # ug/kg <10 No S4UL <10 <10
Nitrobenzene # ug/kg <10 No S4UL <10 <10
VOC MS Dichlorodifluoromethane ug/kg <2 No S4UL <2 <2
Methyl Tertiary Butyl Ether # ug/kg <2 No S4UL <2 <2
Chloromethane # ug/kg <3 No S4UL <3 <3
Vinyl Chloride ug/kg <2 59 <2 <2
Bromomethane ug/kg <1 No S4UL <1 <1
Chloroethane # ug/kg <2 No S4UL <2 <2
Trichlorofluoromethane # ug/kg <2 No S4UL <2 <2
1,1-Dichloroethene (1,1 DCE) # ug/kg <6 No S4UL <6 <6
Dichloromethane (DCM) # ug/kg <30 No S4UL <30 <30
Notes
# ISO17025 (UKAS) accredited - UK.
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
*inorganic mercury
**elemental mercury
a S4UL for >C16-C35
b S4UL for >EC21-EC35
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
Produced: Keelin Timoney
Checked: Patrick Sweeney
Approved: Anne Marie Casey
Other SVOCs
For
insp
ectio
n pur
pose
s only
.
Conse
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EPA Export 28-05-2019:04:59:37
Description
WOP
ADF Trial
Pits
WOP
ADF Trial
Pits
JE Job No. 17/3272 17/3272
J E Sample No. 7-8 35-36
Sample IDWOP-ADF
TP03/17
WOP-ADF
TP01/17
Sampled Date Time 30/01/2017 30/01/2017
Sample Type Soil Soil
Depth 1.50 3.00
Chem Group Chem Name Unit LOD Commercial #2
VOC MS
continuedtrans-1-2-Dichloroethene
# ug/kg <3 No S4UL <3 <3
1,1-Dichloroethane # ug/kg <3 No S4UL <3 <3
cis-1-2-Dichloroethene # ug/kg <3 No S4UL <3 <3
2,2-Dichloropropane ug/kg <4 No S4UL <4 <4
Bromochloromethane # ug/kg <3 No S4UL <3 <3
Chloroform # ug/kg <3 No S4UL <3 <3
1,1,1-Trichloroethane # ug/kg <3 660000 <3 <3
1,1-Dichloropropene # ug/kg <3 No S4UL <3 <3
Carbon tetrachloride # ug/kg <4 2900 <4 <4
1,2-Dichloroethane # ug/kg <4 670 <4 <4
Benzene # ug/kg <3 27000 <3 <3
Trichloroethene (TCE) # ug/kg <3 1200 <3 <3
1,2-Dichloropropane # ug/kg <6 No S4UL <6 <6
Dibromomethane # ug/kg <3 No S4UL <3 <3
Bromodichloromethane # ug/kg <3 No S4UL <3 <3
cis-1-3-Dichloropropene ug/kg <4 No S4UL <4 <4
Toluene # ug/kg <3 56000000
vap (869000) <3 <3
trans-1-3-Dichloropropene ug/kg <3 No S4UL <3 <3
1,1,2-Trichloroethane # ug/kg <3 No S4UL <3 <3
Tetrachloroethene (PCE) # ug/kg <3 No S4UL <3 <3
1,3-Dichloropropane # ug/kg <3 No S4UL <3 <3
Dibromochloromethane # ug/kg <3 No S4UL <3 <3
1,2-Dibromoethane # ug/kg <3 No S4UL <3 <3
Chlorobenzene # ug/kg <3 56000 <3 <3
1,1,1,2-Tetrachloroethane ug/kg <3 110000 <3 <3
Ethylbenzene # ug/kg <3 5700000v
ap (518000) <3 <3
p/m-Xylene # ug/kg <5
5900000sol (576000)
/ 6200000vap (625000)<5 <5
o-Xylene # ug/kg <3 6600000sol (478000) <3 <3
Styrene ug/kg <3 No S4UL <3 <3
Bromoform ug/kg <3 No S4UL <3 <3
Isopropylbenzene # ug/kg <3 No S4UL <3 <3
1,1,2,2-Tetrachloroethane # ug/kg <3 270000 <3 <3
Bromobenzene ug/kg <2 No S4UL <2 <2
1,2,3-Trichloropropane # ug/kg <4 No S4UL <4 <4
Propylbenzene # ug/kg <4 No S4UL <4 <4
2-Chlorotoluene ug/kg <3 No S4UL <3 <3
1,3,5-Trimethylbenzene # ug/kg <3 No S4UL <3 <3
4-Chlorotoluene ug/kg <3 No S4UL <3 <3
tert-Butylbenzene # ug/kg <5 No S4UL <5 <5
1,2,4-Trimethylbenzene # ug/kg <6 No S4UL <6 <6
sec-Butylbenzene # ug/kg <4 No S4UL <4 <4
4-Isopropyltoluene # ug/kg <4 No S4UL <4 <4
1,3-Dichlorobenzene # ug/kg <4 30000 <4 <4
1,4-Dichlorobenzene # ug/kg <4 4400000 (224000)
vap <4 <4
n-Butylbenzene # ug/kg <4 No S4UL <4 <4
1,2-Dichlorobenzene # ug/kg <4 2000000 (571000)
sol <4 <4
1,2-Dibromo-3-chloropropane # ug/kg <4 No S4UL <4 <4
1,2,4-Trichlorobenzene # ug/kg <7 220000 <7 <7
Hexachlorobutadiene ug/kg <4 31000 <4 <4
Naphthalene ug/kg <27 190000 (76400) sol <27 <27
1,2,3-Trichlorobenzene # ug/kg <7 102000 <7 <7
Notes
# ISO17025 (UKAS) accredited - UK.
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
*inorganic mercury
**elemental mercury
a S4UL for >C16-C35
b S4UL for >EC21-EC35
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
Produced: Keelin Timoney
Checked: Patrick Sweeney
Approved: Anne Marie Casey
For
insp
ectio
n pur
pose
s only
.
Conse
nt of
copy
right
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r req
uired
for a
ny ot
her u
se.
EPA Export 28-05-2019:04:59:37
DescriptionWOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
JE Job No. 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/3119 17/3119 17/3119 17/3119 17/3119
J E Sample No. 1-4 5-8 9-10 11-12 15-16 17-18 19-20 21-22 23-24 25-26 13-14 27-28 1-2 3-4 5-6 7-8 9-10
Sample ID WOP TP05/17 WOP TP05/17 WOP TP04/17 WOP TP04/17 WOP TP03/17 WOP TP03/17 WOP TP02/17 WOP TP02/17 WOP TP01/17 WOP TP01/17 WOP TP04/17 WOP TP01/17 WOP TP06/17 WOP TP06/17 WOP TP07/17 WOP TP08/17 WOP TP06/17
Sampled Date Time 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 27/01/2017 27/01/2017 27/01/2017 27/01/2017 27/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Depth 1.00 4.00 2.00 3.50 0.50 2.50 1.00 2.00 0.50 3.00 0.50-2.00 0.50-1.50 0.75 1.50 0.50 1.00 0.50-1.50
Chem Group Chem Name Unit LOD Commercial #3
Aluminium mg/kg <50 No S4UL 8159 11190 3302 7675 9979 10130 7435 8023 11300 5995 - - 8293 2604 2899 2334 -
Antimony mg/kg <1 No S4UL - - - - - - - - - - <1 <1 - - - - <1
Arsenic # mg/kg <0.5 640 27.2 34.2 3.5 12.8 29.3 36.9 28.1 36.2 26.5 3.9 12.9 20.8 40.2 6.2 6.7 4.3 5.9
Barium # mg/kg <1 No S4UL 196 199 163 273 184 225 203 176 192 73 169 200 55 17 16 15 15
Cadmium # mg/kg <0.1 190 0.5 0.7 <0.1 1.3 0.8 0.8 0.7 0.9 0.7 0.3 0.5 0.6 0.2 0.3 0.4 0.4 0.3
Chromium # mg/kg <0.5 8600 13.7 16.0 8.5 18.1 17.7 14.9 17.6 21.0 22.3 14.4 25.8 15.0 22.8 18.5 22.2 22.7 88.5
Copper # mg/kg <1 68000 20 17 5 22 17 18 18 26 22 25 14 18 10 4 8 7 5
Iron mg/kg <20 No S4UL 30370 36380 7620 20370 31510 37640 31880 33190 42000 12710 - - 23900 7366 7143 5925 -
Lead # mg/kg <5 No S4UL 20 14 <5 13 17 21 13 25 11 11 14 11 71 13 13 9 11
Mercury # mg/kg <0.11100 a
58vap
(25.8) b<0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Molybdenum # mg/kg <0.1 No S4UL 7.0 7.4 1.3 6.8 5.3 6.7 4.9 8.6 7.3 3.9 3.0 6.4 0.8 1.5 1.3 1.9 6.1
Nickel # mg/kg <0.7 980 32.6 36.3 10.1 42.1 34.6 33.7 35.3 42.1 54.0 25.0 26.3 34.3 36.6 10.6 16.0 14.8 13.0
Selenium # mg/kg <1 12000 7 10 2 10 10 11 10 11 8 4 5 8 <1 <1 <1 <1 <1
Zinc # mg/kg <5 730000 57 57 8 46 55 59 48 89 65 18 40 41 641 159 72 74 87
Naphthalene # mg/kg <0.04 1100 (432) sol <0.04 <0.04 <0.04 <0.04 <0.04 0.14 <0.04 <0.04 <0.04 <0.04 <0.04 0.32 <0.04 <0.04 <0.04 <0.04 <0.04
Acenaphthylene mg/kg <0.03 100000 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03
Acenaphthene # mg/kg <0.05 100000 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Fluorene # mg/kg <0.04 71000 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04
Phenanthrene # mg/kg <0.03 23000 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03
Anthracene # mg/kg <0.04 540000 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04
Fluoranthene # mg/kg <0.03 23000 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03
Pyrene # mg/kg <0.03 54000 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03
Benzo(a)anthracene # mg/kg <0.06 180 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06
Chrysene # mg/kg <0.02 350 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
Benzo(bk)fluoranthene # mg/kg <0.07 45* <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07
Benzo(a)pyrene # mg/kg <0.04 36 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04
Indeno(123cd)pyrene # mg/kg <0.04 510 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04
Dibenzo(ah)anthracene # mg/kg <0.04 3.6 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04
Benzo(ghi)perylene # mg/kg <0.04 4000 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04
Coronene mg/kg <0.04 No S4UL <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04
PAH 17 Total mg/kg <0.64 No S4UL <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64
Benzo(b)fluoranthene mg/kg <0.05 45 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Benzo(k)fluoranthene mg/kg <0.02 1200 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
Benzo(j)fluoranthene mg/kg <1 No S4UL - - - - - - - - - - <1 <1 - - - - <1
Mineral Oil (C10-C40) mg/kg <30 No S4UL - - - - - - - - - - <30 <30 - - - - <30
Notes
# ISO17025 (UKAS) accredited - UK. Produced: Keelin Timoney
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter Checked: Patrick Sweeney
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter Approved: Anne Marie Casey
AA x10 dilution
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
a inorganic mercury
b elemental mercury
c Alpha-Hexachlorocyclohexane
d Beta-Hexachlorocyclohexane
e gamma-Hexachlorocyclohexanes (including Lindane)
f phenol
g Aliphatic 16-35
h S4UL for Aliphatic EC >35-44
i S4UL for Aromatic EC >35-44
NAD - No asbestos detected
* Surrogate using Benzo(b)fluoranthene
Metals
PAH MS
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insp
ectio
n pur
pose
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.
Conse
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se.
EPA Export 28-05-2019:04:59:37
DescriptionWOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP
Trial Pits
WOP Trial
Pits
WOP Trial
Pits
JE Job No. 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/3119 17/3119 17/3119 17/3119 17/3119
J E Sample No. 1-4 5-8 9-10 11-12 15-16 17-18 19-20 21-22 23-24 25-26 13-14 27-28 1-2 3-4 5-6 7-8 9-10
Sample ID WOP TP05/17 WOP TP05/17 WOP TP04/17 WOP TP04/17 WOP TP03/17 WOP TP03/17 WOP TP02/17 WOP TP02/17 WOP TP01/17 WOP TP01/17 WOP TP04/17 WOP TP01/17 WOP TP06/17 WOP TP06/17WOP
TP07/17WOP TP08/17 WOP TP06/17
Sampled Date Time 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 27/01/2017 27/01/2017 27/01/2017 27/01/2017 27/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Depth 1.00 4.00 2.00 3.50 0.50 2.50 1.00 2.00 0.50 3.00 0.50-2.00 0.50-1.50 0.75 1.50 0.50 1.00 0.50-1.50
Chem Group Chem Name Unit LOD Commercial #3
Mineral Oil (C10-C40) mg/kg <30 No S4UL - - - - - - - - - - <30 <30 - - - - <30
Methyl Tertiary Butyl Ether # ug/kg <2 No S4UL <20AA <20AA <20AA <20AA <20SV
AA <20SV
AA <20SV
AA <20SV
AA <20SV
AA <20AA <5SV
<5SV
<5SV <2 <5 <5 <5
SV
Benzene # ug/kg <3 90000 99AA <30AA <30AA <30AA <30SV
AA <30SV
AA <30SV
AA <30SV
AA <30SV
AA 70AA <5SV
<5SV
<5SV <3 <5 <5 <5
SV
Toluene # ug/kg <3180000000
vap
(4360000) <30AA <30AA <30AA <30AA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30AA <5
SV<5
SV<5
SV 3 <5 <5 <5SV
Ethylbenzene # ug/kg <3 27000000vap
(2840000) <30AA <30AA <30AA <30AA <30SV
AA <30SV
AA <30SV
AA <30SV
AA <30SV
AA <30AA <5SV
<5SV
<5SV <3 <5 <5 <5
SV
p/m-Xylene # ug/kg <530000000
sol (3170000) /
31000000vap
(3460000) <50AA <50AA 175AA <50AA <50
SVAA <50
SVAA <50
SVAA <50
SVAA <50
SVAA <50AA <5
SV<5
SV<5
SV <5 <5 <5 <5SV
o-Xylene # ug/kg <3 33000000sol
(2620000) <30AA <30AA 92AA <30AA <30SV
AA <30SV
AA <30SV
AA <30SV
AA <30SV
AA <30AA <5SV
<5SV
<5SV <3 <5 <5 <5
SV
Aldrin mg/kg <5 170 - <5 - - - - - - - - - - - - - - -
Chlordane (cis & trans) mg/kg <5 No S4UL - <5 - - - - - - - - - - - - - - -
Chlordecone mg/kg <5 No S4UL - <5 - - - - - - - - - - - - - - -
Dieldrin mg/kg <5 170 - <5 - - - - - - - - - - - - - - -
Endrin mg/kg <5 No S4UL - <5 - - - - - - - - - - - - - - -
Heptachlor mg/kg <5 No S4UL - <5 - - - - - - - - - - - - - - -
Hexabromobiphenyl (PBB 153) mg/kg <2.5 No S4UL - <2.5 - - - - - - - - - - - - - - -
Heptabromobiphenyl (PBB 180) mg/kg <2.5 No S4UL - <2.5 - - - - - - - - - - - - - - -
Bromobiphenyls (PBB 153 & 180) mg/kg <5 No S4UL - <5 - - - - - - - - - - - - - - -
Hexachlorobenzene mg/kg <5 120 - <5 - - - - - - - - - - - - - - -
Hexachlorocyclohexane (all isomers) mg/kg <5
180 c
65 d
70 e - <5 - - - - - - - - - - - - - - -
Mirex mg/kg <5 No S4UL - <5 - - - - - - - - - - - - - - -
p,p'-DDT mg/kg <5 No S4UL - <5 - - - - - - - - - - - - - - -
Pentachlorobenzene mg/kg <5 830 - <5 - - - - - - - - - - - - - - -
PCB 28 # ug/kg <5 240
#4 - <5 - - - - - <5 - - <5 <5 - <5 - - <5
PCB 52 # ug/kg <5 240
#4 - <5 - - - - - <5 - - <5 <5 - <5 - - <5
PCB 101 # ug/kg <5 240
#4 - <5 - - - - - <5 - - <5 <5 - <5 - - <5
PCB 118 # ug/kg <5 240
#4 - <5 - - - - - <5 - - <5 <5 - <5 - - <5
PCB 138 # ug/kg <5 240
#4 - <5 - - - - - <5 - - <5 <5 - <5 - - <5
PCB 153 # ug/kg <5 240
#4 - <5 - - - - - <5 - - <5 <5 - <5 - - <5
PCB 180 # ug/kg <5 240
#4 - <5 - - - - - <5 - - <5 <5 - <5 - - <5
Total 7 PCBs # ug/kg <35 240
#4 - <35 - - - - - <35 - - <35 <35 - <35 - - <35
Notes
# ISO17025 (UKAS) accredited - UK. Produced: Keelin Timoney
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter Checked: Patrick Sweeney
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter Approved: Anne Marie Casey
AA x10 dilution
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
a inorganic mercury
b elemental mercury
c Alpha-Hexachlorocyclohexane
d Beta-Hexachlorocyclohexane
e gamma-Hexachlorocyclohexanes (including Lindane)
f phenol
g Aliphatic 16-35
h S4UL for Aliphatic EC >35-44
i S4UL for Aromatic EC >35-44
NAD - No asbestos detected
* Surrogate using Benzo(b)fluoranthene
PCBs
For
insp
ectio
n pur
pose
s only
.
Conse
nt of
copy
right
owne
r req
uired
for a
ny ot
her u
se.
EPA Export 28-05-2019:04:59:37
DescriptionWOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
WOP
Trial Pits
JE Job No. 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/3119 17/3119 17/3119 17/3119 17/3119
J E Sample No. 1-4 5-8 9-10 11-12 15-16 17-18 19-20 21-22 23-24 25-26 13-14 27-28 1-2 3-4 5-6 7-8 9-10
Sample ID WOP TP05/17 WOP TP05/17 WOP TP04/17 WOP TP04/17 WOP TP03/17 WOP TP03/17 WOP TP02/17 WOP TP02/17 WOP TP01/17 WOP TP01/17 WOP TP04/17 WOP TP01/17 WOP TP06/17 WOP TP06/17 WOP TP07/17 WOP TP08/17 WOP TP06/17
Sampled Date Time 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 27/01/2017 27/01/2017 27/01/2017 27/01/2017 27/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Depth 1.00 4.00 2.00 3.50 0.50 2.50 1.00 2.00 0.50 3.00 0.50-2.00 0.50-1.50 0.75 1.50 0.50 1.00 0.50-1.50
Chem Group Chem Name Unit LOD Commercial #3
Total Phenols HPLC mg/kg <0.15 3200dir (37000) f - <0.15 - - - - - <0.15 - - - - - 0.38 - - -
Natural Moisture Content % <0.1 No S4UL 45.5 104.7 124.2 144.6 100.0 126.8 132.7 84.1 91.6 83.6 144.9 125.0 5.2 5.5 5.6 6.5 5.9
Ammoniacal Nitrogen as N mg/kg <0.6 No S4UL - <0.6 - <0.6 <0.6 <0.6 - <0.6 - <0.6 - - <0.6 3.3 <0.6 - -
Chloride # mg/kg <2 No S4UL 42 67 81 185 2480 80 - 44 - 48 - - 52 50 21 - -
Hexavalent Chromium # mg/kg <0.3 33 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3
Ortho Phosphate as PO4 mg/kg <0.3 No S4UL - <0.3 - <0.3 <0.3 <0.3 - <0.3 - <0.3 - - <0.3 <0.3 <0.3 - -
Sulphate as SO4 (2:1 Ext) # g/l <0.0015 No S4UL - 0.9992 - 0.4972 2.7156 1.8604 - 0.0471 - 0.0244 - - 0.9224 0.1850 0.3027 - -
Chromium III mg/kg <0.5 8600 13.7 16.0 8.5 18.1 17.7 14.9 17.6 21.0 22.3 14.4 25.8 15.0 22.8 18.5 22.2 22.7 88.5
Organic Matter % <0.2 No S4UL - - - 13.7 - - - 5.3 - 31.1 - - - - - - -
TPH CWG >C5-C6 # mg/kg <0.1 12000 (1150)
sol - - - - - - - - - - <0.1SV
<0.1SV - - - - <0.1
SV
>C6-C8 # mg/kg <0.1 40000 (736)
sol - - - - - - - - - - <0.1SV
<0.1SV - - - - <0.1
SV
>C8-C10 mg/kg <0.1 11000 (451) vap - - - - - - - - - - <0.1
SV<0.1
SV - - - - <0.1SV
>C10-C12 # mg/kg <0.2 47000 (283)
vap - - - - - - - - - - <0.2 <0.2 - - - - <0.2
>C12-C16 # mg/kg <4 90000 (142)
sol - - - - - - - - - - <4 <4 - - - - <4
>C16-C21 # mg/kg <7 180000 g - - - - - - - - - - <7 <7 - - - - <7
>C21-C35 # mg/kg <7 180000 g - - - - - - - - - - <7 <7 - - - - <7
>C35-C40 mg/kg <7 180000 h - - - - - - - - - - <7 <7 - - - - <7
Total aliphatics C5-40 mg/kg <26 No S4UL - - - - - - - - - - <26 <26 - - - - <26
>C6-C10 mg/kg <0.1 No S4UL - - - - - - - - - - <0.1SV
<0.1SV - - - - <0.1
SV
>C10-C25 mg/kg <10 No S4UL - - - - - - - - - - <10 <10 - - - - <10
>C25-C35 mg/kg <10 No S4UL - - - - - - - - - - <10 <10 - - - - <10
>C5-EC7 # mg/kg <0.1 86000 (4710)
sol - - - - - - - - - - <0.1SV
<0.1SV - - - - <0.1
SV
>EC7-EC8 # mg/kg <0.1 180000 (4360)
vap - - - - - - - - - - <0.1SV
<0.1SV - - - - <0.1
SV
>EC8-EC10 # mg/kg <0.1 17000 (3580)
vap - - - - - - - - - - <0.1SV
<0.1SV - - - - <0.1
SV
>EC10-EC12 # mg/kg <0.2 34000 (2150)
sol - - - - - - - - - - <0.2 <0.2 - - - - <0.2
>EC12-EC16 # mg/kg <4 38000 - - - - - - - - - - <4 <4 - - - - <4
>EC16-EC21 # mg/kg <7 28000 - - - - - - - - - - <7 <7 - - - - <7
>EC21-EC35 # mg/kg <7 28000 - - - - - - - - - - <7 <7 - - - - <7
>EC35-EC40 mg/kg <7 28000 i - - - - - - - - - - <7 <7 - - - - <7
Total aromatics C5-40 mg/kg <26 No S4UL - - - - - - - - - - <26 <26 - - - - <26
Total aliphatics and aromatics(C5-40) mg/kg <52 No S4UL - - - - - - - - - - <52 <52 - - - - <52
>EC6-EC10 # mg/kg <0.1 No S4UL - - - - - - - - - - <0.1
SV<0.1
SV - - - - <0.1SV
>EC10-EC25 mg/kg <10 No S4UL - - - - - - - - - - <10 <10 - - - - <10
>EC25-EC35 mg/kg <10 No S4UL - - - - - - - - - - <10 <10 - - - - <10
Notes
# ISO17025 (UKAS) accredited - UK. Produced: Keelin Timoney
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter Checked: Patrick Sweeney
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter Approved: Anne Marie Casey
AA x10 dilution
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
a inorganic mercury
b elemental mercury
c Alpha-Hexachlorocyclohexane
d Beta-Hexachlorocyclohexane
e gamma-Hexachlorocyclohexanes (including Lindane)
f phenol
g Aliphatic 16-35
h S4UL for Aliphatic EC >35-44
i S4UL for Aromatic EC >35-44
NAD - No asbestos detected
* Surrogate using Benzo(b)fluoranthene
Aliphatics
Aromatics
For
insp
ectio
n pur
pose
s only
.
Conse
nt of
copy
right
owne
r req
uired
for a
ny ot
her u
se.
EPA Export 28-05-2019:04:59:38
DescriptionWOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
JE Job No. 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/2941 17/3119 17/3119 17/3119 17/3119
J E Sample No. 5-8 11-12 15-16 17-18 19-20 23-24 13-14 27-28 1-2 3-4 5-6 9-10
Sample ID WOP TP05/17 WOP TP04/17 WOP TP03/17 WOP TP03/17 WOP TP02/17 WOP TP01/17 WOP TP04/17 WOP TP01/17 WOP TP06/17 WOP TP06/17 WOP TP07/17 WOP TP06/17
Sampled Date Time 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 27/01/2017 27/01/2017 27/01/2017 27/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Depth 4.00 3.50 0.50 2.50 1.00 0.50 0.50-2.00 0.50-1.50 0.75 1.50 0.50 0.50-1.50
Chem Group Chem Name Unit LOD Commercial #3
Total Organic Carbon # % <0.02 No S4UL - - - - - - 31.39 21.79 - - - 0.44
pH # pH units <0.01 No S4UL - - - - - - 12.27 12.75 - - - 7.80
General Description (Bulk Analysis) No S4UL soil/stones soil/stones soil/stones soil/stones soil/stones soil/stones soil/stones soil/stones soil/stones - soil/stones Soil/Stones
Asbestos Fibres No S4UL NAD NAD NAD NAD NAD NAD NAD NAD NAD - NAD NAD
Asbestos Fibres (2) No S4UL NAD NAD NAD NAD NAD NAD NAD NAD NAD - NAD NAD
Asbestos ACM No S4UL NAD NAD NAD NAD NAD NAD NAD NAD NAD - NAD NAD
Asbestos ACM (2) No S4UL NAD NAD NAD NAD NAD NAD NAD NAD NAD - NAD NAD
Asbestos Type No S4UL NAD NAD NAD NAD NAD NAD NAD NAD NAD - NAD NAD
Asbestos Type (2) No S4UL NAD NAD NAD NAD NAD NAD NAD NAD NAD - NAD NAD
Asbestos Level Screen No S4UL NAD NAD NAD NAD NAD NAD NAD NAD NAD - NAD NAD
2-Chlorophenol # ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
2-Methylphenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
2-Nitrophenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
2,4-Dichlorophenol # ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
2,4-Dimethylphenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
2,4,5-Trichlorophenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
2,4,6-Trichlorophenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
4-Chloro-3-methylphenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
4-Methylphenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
4-Nitrophenol ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
Pentachlorophenol ug/kg <10 400000 <10 <10 - - - - - - - <10 - -
Phenol # ug/kg <10 760000dir (31000000) <10 <10 - - - - - - - <10 - -
2-Chloronaphthalene # ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
2-Methylnaphthalene # ug/kg <10 No S4UL <10 <10 - - - - - - - <10 - -
Bis(2-ethylhexyl) phthalate ug/kg <100 No S4UL <100 <100 - - - - - - - <100 - -
Butylbenzyl phthalate ug/kg <100 No S4UL <100 <100 - - - - - - - <100 - -
Di-n-butyl phthalate ug/kg <100 No S4UL <100 <100 - - - - - - - <100 - -
Di-n-Octyl phthalate ug/kg <100 No S4UL <100 <100 - - - - - - - <100 - -
Diethyl phthalate ug/kg <100 No S4UL <100 <100 - - - - - - - <100 - -
Dimethyl phthalate # ug/kg <100 No S4UL <100 <100 - - - - - - - <100 - -
Notes
# ISO17025 (UKAS) accredited - UK. Produced: Keelin Timoney
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter Checked: Patrick Sweeney
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter Approved: Anne Marie Casey
AA x10 dilution
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
a inorganic mercury
b elemental mercury
c Alpha-Hexachlorocyclohexane
d Beta-Hexachlorocyclohexane
e gamma-Hexachlorocyclohexanes (including Lindane)
f phenol
g Aliphatic 16-35
h S4UL for Aliphatic EC >35-44
i S4UL for Aromatic EC >35-44
NAD - No asbestos detected
* Surrogate using Benzo(b)fluoranthene
Asbestos
Phenols
PAHs
Phthalates
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DescriptionWOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
JE Job No. 17/2941 17/2941 17/2941 17/3119
J E Sample No. 5-8 11-12 15-16 3-4
Sample ID WOP TP05/17 WOP TP04/17 WOP TP03/17 WOP TP06/17
Sampled Date Time 24/01/2017 24/01/2017 24/01/2017 27/01/2017
Sample Type Soil Soil Soil Soil
Depth 4.00 3.50 0.50 1.50
Chem Group Chem Name Unit LOD Commercial #3
1,2-Dichlorobenzene ug/kg <10 2000000 (571000) sol <10 <10 - <10
1,2,4-Trichlorobenzene # ug/kg <10 220000 <10 <10 - <10
1,3-Dichlorobenzene ug/kg <10 30000 <10 <10 - <10
1,4-Dichlorobenzene ug/kg <10 4400000 (224000) vap <10 <10 - <10
2-Nitroaniline ug/kg <10 No S4UL <10 <10 - <10
2,4-Dinitrotoluene ug/kg <10 No S4UL <10 <10 - <10
2,6-Dinitrotoluene ug/kg <10 No S4UL <10 <10 - <10
3-Nitroaniline ug/kg <10 No S4UL <10 <10 - <10
4-Bromophenylphenylether # ug/kg <10 No S4UL <10 <10 - <10
4-Chloroaniline ug/kg <10 No S4UL <10 <10 - <10
4-Chlorophenylphenylether ug/kg <10 No S4UL <10 <10 - <10
4-Nitroaniline ug/kg <10 No S4UL <10 <10 - <10
Azobenzene ug/kg <10 No S4UL <10 <10 - <10
Bis(2-chloroethoxy)methane ug/kg <10 No S4UL <10 <10 - <10
Bis(2-chloroethyl)ether ug/kg <10 No S4UL <10 <10 - <10
Carbazole ug/kg <10 No S4UL <10 <10 - <10
Dibenzofuran # ug/kg <10 No S4UL <10 <10 - <10
Hexachlorobenzene ug/kg <10 110000 (200) vap <10 <10 - <10
Hexachlorobutadiene # ug/kg <10 31000 <10 <10 - <10
Hexachlorocyclopentadiene ug/kg <10 No S4UL <10 <10 - <10
Hexachloroethane ug/kg <10 No S4UL <10 <10 - <10
Isophorone # ug/kg <10 No S4UL <10 <10 - <10
N-nitrosodi-n-propylamine # ug/kg <10 No S4UL <10 <10 - <10
Nitrobenzene # ug/kg <10 No S4UL <10 <10 - <10
VOC MS Dichlorodifluoromethane ug/kg <2 No S4UL <20AA - <20SV
AA <2
Methyl Tertiary Butyl Ether # ug/kg <2 No S4UL <20AA - <20
SVAA <2
Chloromethane # ug/kg <3 No S4UL <30AA - <30
SVAA <3
Vinyl Chloride ug/kg <2 59 <20AA - <20SV
AA <2
Bromomethane ug/kg <1 No S4UL <10AA - <10SV
AA <1
Chloroethane # ug/kg <2 No S4UL <20AA - <20
SVAA <2
Trichlorofluoromethane # ug/kg <2 No S4UL <20AA - <20
SVAA <2
1,1-Dichloroethene (1,1 DCE) # ug/kg <6 No S4UL <60AA - <60
SVAA <6
Notes
# ISO17025 (UKAS) accredited - UK.
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter
AA x10 dilution
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
a inorganic mercury
b elemental mercury
c Alpha-Hexachlorocyclohexane
d Beta-Hexachlorocyclohexane
e gamma-Hexachlorocyclohexanes (including Lindane)
f phenol
g Aliphatic 16-35
h S4UL for Aliphatic EC >35-44
i S4UL for Aromatic EC >35-44
NAD - No asbestos detected
* Surrogate using Benzo(b)fluoranthene
Produced: Keelin Timoney
Checked: Patrick Sweeney
Approved: Anne Marie Casey
Other SVOCs
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DescriptionWOP Trial
Pits
WOP Trial
Pits
WOP Trial
Pits
JE Job No. 17/2941 17/2941 17/3119
J E Sample No. 5-8 15-16 3-4
Sample ID WOP TP05/17 WOP TP03/17 WOP TP06/17
Sampled Date Time 24/01/2017 24/01/2017 27/01/2017
Sample Type Soil Soil Soil
Depth 4.00 0.50 1.50
Chem Group Chem Name Unit LOD Commercial #3
VOC MS
continuedDichloromethane (DCM)
# ug/kg <30 No S4UL <300AA <300SV
AA 45
trans-1-2-Dichloroethene # ug/kg <3 No S4UL <30AA <30
SVAA <3
1,1-Dichloroethane # ug/kg <3 No S4UL <30AA <30
SVAA <3
cis-1-2-Dichloroethene # ug/kg <3 No S4UL <30AA <30
SVAA <3
2,2-Dichloropropane ug/kg <4 No S4UL <40AA <40SV
AA <4
Bromochloromethane # ug/kg <3 No S4UL <30AA <30
SVAA <3
Chloroform # ug/kg <3 No S4UL <30AA <30
SVAA <3
1,1,1-Trichloroethane # ug/kg <3 660000 <30AA <30
SVAA <3
1,1-Dichloropropene # ug/kg <3 No S4UL <30AA <30
SVAA <3
Carbon tetrachloride # ug/kg <4 2900 <40AA <40
SVAA <4
1,2-Dichloroethane # ug/kg <4 670 <40AA <40
SVAA <4
Benzene # ug/kg <3 27000 <30AA <30
SVAA <3
Trichloroethene (TCE) # ug/kg <3 1200 <30AA <30
SVAA <3
1,2-Dichloropropane # ug/kg <6 No S4UL <60AA <60
SVAA <6
Dibromomethane # ug/kg <3 No S4UL <30AA <30
SVAA <3
Bromodichloromethane # ug/kg <3 No S4UL <30AA <30
SVAA <3
cis-1-3-Dichloropropene ug/kg <4 No S4UL <40AA <40SV
AA <4
Toluene # ug/kg <3 56000000
vap (869000) <30AA <30
SVAA 3
trans-1-3-Dichloropropene ug/kg <3 No S4UL <30AA <30SV
AA <3
1,1,2-Trichloroethane # ug/kg <3 No S4UL <30AA <30
SVAA <3
Tetrachloroethene (PCE) # ug/kg <3 No S4UL <30AA <30
SVAA <3
1,3-Dichloropropane # ug/kg <3 No S4UL <30AA <30
SVAA <3
Dibromochloromethane # ug/kg <3 No S4UL <30AA <30
SVAA <3
1,2-Dibromoethane # ug/kg <3 No S4UL <30AA <30
SVAA <3
Chlorobenzene # ug/kg <3 56000 <30AA <30
SVAA <3
1,1,1,2-Tetrachloroethane ug/kg <3 110000 <30AA <30SV
AA <3
Ethylbenzene # ug/kg <3 5700000v
ap (518000) <30AA <30
SVAA <3
p/m-Xylene # ug/kg <5
5900000sol
(576000)
/ 6200000vap
(625000)<50AA <50
SVAA <5
o-Xylene # ug/kg <3 6600000sol (478000) <30AA <30
SVAA <3
Styrene ug/kg <3 No S4UL <30AA <30SV
AA <3
Bromoform ug/kg <3 No S4UL <30AA <30SV
AA <3
Isopropylbenzene # ug/kg <3 No S4UL <30AA <30
SVAA <3
1,1,2,2-Tetrachloroethane # ug/kg <3 270000 <30AA <30
SVAA <3
Bromobenzene ug/kg <2 No S4UL <20AA <20SV
AA <2
1,2,3-Trichloropropane # ug/kg <4 No S4UL <40AA <40
SVAA <4
Propylbenzene # ug/kg <4 No S4UL <40AA <40
SVAA <4
2-Chlorotoluene ug/kg <3 No S4UL <30AA <30SV
AA <3
1,3,5-Trimethylbenzene # ug/kg <3 No S4UL <30AA <30
SVAA <3
4-Chlorotoluene ug/kg <3 No S4UL <30AA <30SV
AA <3
tert-Butylbenzene # ug/kg <5 No S4UL <50AA <50
SVAA <5
1,2,4-Trimethylbenzene # ug/kg <6 No S4UL <60AA <60
SVAA <6
sec-Butylbenzene # ug/kg <4 No S4UL <40AA <40
SVAA <4
4-Isopropyltoluene # ug/kg <4 No S4UL <40AA <40
SVAA <4
1,3-Dichlorobenzene # ug/kg <4 30000 <40AA <40
SVAA <4
1,4-Dichlorobenzene # ug/kg <4 4400000 (224000)
vap <40AA <40SV
AA <4
n-Butylbenzene # ug/kg <4 No S4UL <40AA <40
SVAA <4
1,2-Dichlorobenzene # ug/kg <4 2000000 (571000)
sol <40AA <40SV
AA <4
1,2-Dibromo-3-chloropropane # ug/kg <4 No S4UL <40AA <40
SVAA <4
1,2,4-Trichlorobenzene # ug/kg <7 220000 <70AA <70
SVAA <7
Hexachlorobutadiene ug/kg <4 31000 <40AA <40SV
AA <4
Naphthalene ug/kg <27 190000 (76400) sol <270AA <270
SVAA <27
1,2,3-Trichlorobenzene # ug/kg <7 102000 <70AA <70
SVAA <7
Notes
# ISO17025 (UKAS) accredited - UK.
#2 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 1% Soil Organic Matter
#3 The LQM/CIEH S4ULs for Human Health Risk Assessment - Commercial - 6% Soil Organic Matter
AA x10 dilution
#4 UK Environment Agency, Soil Guideliine Values for dioxins, furans and dioxin-lie PCBs in soil - Based on 6% Soil Organic Matter
SV Surrogate recovery outside performance criteria. This may be due to a matrix effect.
vap S4ULs presented exceed the vapour saturation limit, which is presented in brackets.
sol S4ULs presented exceed the solubility saturation limit, which is presented in brackets.
Exceeds LQM/CIEH S4ULs for Commercial
a inorganic mercury
b elemental mercury
c Alpha-Hexachlorocyclohexane
d Beta-Hexachlorocyclohexane
e gamma-Hexachlorocyclohexanes (including Lindane)
f phenol
g Aliphatic 16-35
h S4UL for Aliphatic EC >35-44
i S4UL for Aromatic EC >35-44
NAD - No asbestos detected
* Surrogate using Benzo(b)fluoranthene
Produced: Keelin Timoney
Checked: Patrick Sweeney
Approved: Anne Marie Casey
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EPA Export 28-05-2019:04:59:38
92
Appendix 4.Soil Laboratory Results
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EPA Export 28-05-2019:04:59:38
Unit 3 Deeside Point
Zone 3
Deeside Industrial Park
Deeside
Causeway Geotech
Attention :
Date :
Your reference :
Our reference :
Location :
Date samples received :
Status :
Issue :
Colm Hurley
28th February, 2017
1
Exova Jones Environmental
CH5 2UA
Tel: +44 (0) 1244 833780
Fax: +44 (0) 1244 833781
8 Drumahiskey Road
Bainamore
Ballymoney
Co Antrim
BT53 7QL
Registered Address : Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian, EH28 8PL
Ten samples were received for analysis on 25th January, 2017 of which ten were scheduled for analysis. Please find attached our Test Report
which should be read with notes at the end of the report and should include all sections if reproduced. Interpretations and opinions are outside the
scope of any accreditation, and all results relate only to samples supplied.
All analysis is carried out on as received samples and reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected.
Where Waste Acceptance Criteria Suite (EC Decision of 19 December 2002 (2003/33/EC)) has been requested, all analyses have been performed
using the relevant EN methods where they exist.
Phil Sommerton BSc
Project Manager
WOP 16-1239
Project Gemini
25th January, 2017
Final report
Compiled By:
Test Report 17/2941 Batch 1
QF-PM 3.1.1 v16Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 1 of 16
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EPA Export 28-05-2019:04:59:38
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/2941
J E Sample No. 1-4 5-8 9-10 11-12 15-16 17-18 19-20 21-22 23-24 25-26
Sample ID WOP TP05/17 WOP TP05/17 WOP TP04/17 WOP TP04/17 WOP TP03/17 WOP TP03/17 WOP TP02/17 WOP TP02/17 WOP TP01/17 WOP TP01/17
Depth 1.00 4.00 2.00 3.50 0.50 2.50 1.00 2.00 0.50 3.00
COC No / misc
Containers V J V J V J V J V J V J V J V J V J V J
Sample Date 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017
Aluminium 8159 11190 3302 7675 9979 10130 7435 8023 11300 5995 <50 mg/kg TM30/PM15
Arsenic # 27.2 34.2 3.5 12.8 29.3 36.9 28.1 36.2 26.5 3.9 <0.5 mg/kg TM30/PM15
Barium # 196 199 163 273 184 225 203 176 192 73 <1 mg/kg TM30/PM15
Cadmium # 0.5 0.7 <0.1 1.3 0.8 0.8 0.7 0.9 0.7 0.3 <0.1 mg/kg TM30/PM15
Chromium # 13.7 16.0 8.5 18.1 17.7 14.9 17.6 21.0 22.3 14.4 <0.5 mg/kg TM30/PM15
Copper # 20 17 5 22 17 18 18 26 22 25 <1 mg/kg TM30/PM15
Iron 30370 36380 7620 20370 31510 37640 31880 33190 42000 12710 <20 mg/kg TM30/PM15
Lead # 20 14 <5 13 17 21 13 25 11 11 <5 mg/kg TM30/PM15
Mercury # <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 mg/kg TM30/PM15
Molybdenum # 7.0 7.4 1.3 6.8 5.3 6.7 4.9 8.6 7.3 3.9 <0.1 mg/kg TM30/PM15
Nickel # 32.6 36.3 10.1 42.1 34.6 33.7 35.3 42.1 54.0 25.0 <0.7 mg/kg TM30/PM15
Selenium # 7 10 2 10 10 11 10 11 8 4 <1 mg/kg TM30/PM15
Zinc # 57 57 8 46 55 59 48 89 65 18 <5 mg/kg TM30/PM15
PAH MS
Naphthalene # <0.04 <0.04 <0.04 <0.04 <0.04 0.14 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Acenaphthylene <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Acenaphthene # <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 mg/kg TM4/PM8
Fluorene # <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Phenanthrene # <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Anthracene # <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Fluoranthene # <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Pyrene # <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Benzo(a)anthracene # <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 <0.06 mg/kg TM4/PM8
Chrysene # <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 mg/kg TM4/PM8
Benzo(bk)fluoranthene # <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 <0.07 mg/kg TM4/PM8
Benzo(a)pyrene # <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Indeno(123cd)pyrene # <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Dibenzo(ah)anthracene # <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Benzo(ghi)perylene # <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Coronene <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
PAH 17 Total <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 mg/kg TM4/PM8
Benzo(b)fluoranthene <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 mg/kg TM4/PM8
Benzo(k)fluoranthene <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 mg/kg TM4/PM8
PAH Surrogate % Recovery 109 94 48SV 109 88 78 103 107 104 88 <0 % TM4/PM8
Methyl Tertiary Butyl Ether # <20AA <20AA <20AA <20AA <20
SVAA <20
SVAA <20
SVAA <20
SVAA <20
SVAA <20AA <2 ug/kg TM15/PM10
Benzene # 99AA <30AA <30AA <30AA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30
SVAA 70AA <3 ug/kg TM15/PM10
Toluene # <30AA <30AA <30AA <30AA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30AA <3 ug/kg TM15/PM10
Ethylbenzene # <30AA <30AA <30AA <30AA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30AA <3 ug/kg TM15/PM10
p/m-Xylene # <50AA <50AA 175AA <50AA <50
SVAA <50
SVAA <50
SVAA <50
SVAA <50
SVAA <50AA <5 ug/kg TM15/PM10
o-Xylene # <30AA <30AA 92AA <30AA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30
SVAA <30AA <3 ug/kg TM15/PM10
Surrogate Recovery Toluene D8 88AA 74AA 73AA 75AA 81SV
AA 76SV
AA 79SV
AA 65SV
AA 71SV
AA 90AA <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 49AA 52AA 63AA 54AA 48SV
AA 47SV
AA 47SV
AA 44SV
AA 45SV
AA 57AA <0 % TM15/PM10
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 2 of 16
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EPA Export 28-05-2019:04:59:38
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/2941
J E Sample No. 1-4 5-8 9-10 11-12 15-16 17-18 19-20 21-22 23-24 25-26
Sample ID WOP TP05/17 WOP TP05/17 WOP TP04/17 WOP TP04/17 WOP TP03/17 WOP TP03/17 WOP TP02/17 WOP TP02/17 WOP TP01/17 WOP TP01/17
Depth 1.00 4.00 2.00 3.50 0.50 2.50 1.00 2.00 0.50 3.00
COC No / misc
Containers V J V J V J V J V J V J V J V J V J V J
Sample Date 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017 24/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017 25/01/2017
Aldrin - <5 - - - - - - - - <5 mg/kg TM163/PM8
Chlordane (cis & trans) - <5 - - - - - - - - <5 mg/kg TM163/PM8
Chlordecone - <5 - - - - - - - - <5 mg/kg TM163/PM8
Dieldrin - <5 - - - - - - - - <5 mg/kg TM163/PM8
Endrin - <5 - - - - - - - - <5 mg/kg TM163/PM8
Heptachlor - <5 - - - - - - - - <5 mg/kg TM163/PM8
Hexabromobiphenyl (PBB 153) - <2.5 - - - - - - - - <2.5 mg/kg TM163/PM8
Heptabromobiphenyl (PBB 180) - <2.5 - - - - - - - - <2.5 mg/kg TM163/PM8
Bromobiphenyls (PBB 153 & 180) - <5 - - - - - - - - <5 mg/kg TM163/PM8
Hexachlorobenzene - <5 - - - - - - - - <5 mg/kg TM163/PM8
Hexachlorocyclohexane (all isomers) - <5 - - - - - - - - <5 mg/kg TM163/PM8
Mirex - <5 - - - - - - - - <5 mg/kg TM163/PM8
p,p'-DDT - <5 - - - - - - - - <5 mg/kg TM163/PM8
Pentachlorobenzene - <5 - - - - - - - - <5 mg/kg TM163/PM8
PCB 28 # - <5 - - - - - <5 - - <5 ug/kg TM17/PM8
PCB 52 # - <5 - - - - - <5 - - <5 ug/kg TM17/PM8
PCB 101 # - <5 - - - - - <5 - - <5 ug/kg TM17/PM8
PCB 118 # - <5 - - - - - <5 - - <5 ug/kg TM17/PM8
PCB 138 # - <5 - - - - - <5 - - <5 ug/kg TM17/PM8
PCB 153 # - <5 - - - - - <5 - - <5 ug/kg TM17/PM8
PCB 180 # - <5 - - - - - <5 - - <5 ug/kg TM17/PM8
Total 7 PCBs # - <35 - - - - - <35 - - <35 ug/kg TM17/PM8
Total Phenols HPLC - <0.15 - - - - - <0.15 - - <0.15 mg/kg TM26/PM21
Natural Moisture Content 45.5 104.7 124.2 144.6 100.0 126.8 132.7 84.1 91.6 83.6 <0.1 % PM4/PM0
Ammoniacal Nitrogen as N - <0.6 - <0.6 <0.6 <0.6 - <0.6 - <0.6 <0.6 mg/kg TM38/PM20
Chloride # 42 67 81 185 2480 80 - 44 - 48 <2 mg/kg TM38/PM20
Hexavalent Chromium # <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 mg/kg TM38/PM20
Ortho Phosphate as PO4 - <0.3 - <0.3 <0.3 <0.3 - <0.3 - <0.3 <0.3 mg/kg TM38/PM20
Sulphate as SO4 (2:1 Ext) # - 0.9992 - 0.4972 2.7156 1.8604 - 0.0471 - 0.0244 <0.0015 g/l TM38/PM20
Chromium III 13.7 16.0 8.5 18.1 17.7 14.9 17.6 21.0 22.3 14.4 <0.5 mg/kg NONE/NONE
Organic Matter - - - 13.7 - - - 5.3 - 31.1 <0.2 % TM21/PM24
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 3 of 16
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Client Name: Report : CEN 10:1 1 Batch
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/2941
J E Sample No. 5-8 11-12 15-16 21-22
Sample ID WOP TP05/17 WOP TP04/17 WOP TP03/17 WOP TP02/17
Depth 4.00 3.50 0.50 2.00
COC No / misc
Containers V J V J V J V J
Sample Date 24/01/2017 24/01/2017 24/01/2017 24/01/2017
Sample Type Soil Soil Soil Soil
Batch Number 1 1 1 1
Date of Receipt 25/01/2017 25/01/2017 25/01/2017 25/01/2017
Dissolved Aluminium # 2.6 <1.5 186.0 6.6 <1.5 ug/l TM30/PM14
Dissolved Arsenic # 1.4 <0.9 <0.9 <0.9 <0.9 ug/l TM30/PM14
Dissolved Barium # 961.6 1169.0 35.0 196.3 <1.8 ug/l TM30/PM14
Dissolved Cadmium # <0.03 <0.03 <0.03 <0.03 <0.03 ug/l TM30/PM14
Dissolved Chromium # <0.2 <0.2 3.9 <0.2 <0.2 ug/l TM30/PM14
Dissolved Copper # <3 <3 <3 <3 <3 ug/l TM30/PM14
Dissolved Iron # <4.7 <4.7 5.1 <4.7 <4.7 ug/l TM30/PM14
Dissolved Lead # <0.4 <0.4 <0.4 <0.4 <0.4 ug/l TM30/PM14
Dissolved Mercury # 1.6 1.6 0.9 1.1 <0.5 ug/l TM30/PM14
Dissolved Molybdenum # 26.4 31.3 15.9 37.0 <0.2 ug/l TM30/PM14
Dissolved Nickel # <0.2 <0.2 <0.2 <0.2 <0.2 ug/l TM30/PM14
Dissolved Selenium # <1.2 <1.2 <1.2 <1.2 <1.2 ug/l TM30/PM14
Dissolved Zinc # 3.1 3.2 2.0 2.0 <1.5 ug/l TM30/PM14
PAH MS
Naphthalene 0.3 <0.1 0.1 <0.1 <0.1 ug/l TM4/PM30
Acenaphthylene 0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Acenaphthene 0.03 0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Fluorene 0.03 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Phenanthrene 0.04 0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Anthracene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Pyrene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(a)anthracene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Chrysene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(bk)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(a)pyrene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Indeno(123cd)pyrene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Dibenzo(ah)anthracene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(ghi)perylene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
PAH 16 Total 0.4 <0.1 0.1 <0.1 <0.1 ug/l TM4/PM30
Benzo(b)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(k)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
PAH Surrogate % Recovery 70 70 69 68 <0 % TM4/PM30
Phenol <0.5 <0.5 - <0.5 <0.5 ug/l TM26/PM0
Chloride # 8.9 27.8 - 5.9 <0.3 mg/l TM38/PM0
Ortho Phosphate as PO4 <0.03 <0.03 - <0.03 <0.03 mg/l TM38/PM0
Leachant Volume 0.802 0.753 - 0.804 l NONE/PM17
Dissolved Chromium III <2 <2 <2 <2 <2 ug/l NONE/NONE
Hexavalent Chromium <2 <2 4 <2 <2 ug/l TM38/PM0
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 4 of 16
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EPA Export 28-05-2019:04:59:38
Client Name: SVOC Report : Solid
Reference:
Location:
Contact:
JE Job No.: 17/2941
J E Sample No. 5-8 15-16
Sample ID WOP TP05/17 WOP TP03/17
Depth 4.00 0.50
COC No / misc
Containers V J V J
Sample Date 24/01/2017 24/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 25/01/2017 25/01/2017
SVOC MS
Phenols
2-Chlorophenol # <10 <10 <10 ug/kg TM16/PM8
2-Methylphenol <10 <10 <10 ug/kg TM16/PM8
2-Nitrophenol <10 <10 <10 ug/kg TM16/PM8
2,4-Dichlorophenol # <10 <10 <10 ug/kg TM16/PM8
2,4-Dimethylphenol <10 <10 <10 ug/kg TM16/PM8
2,4,5-Trichlorophenol <10 <10 <10 ug/kg TM16/PM8
2,4,6-Trichlorophenol <10 <10 <10 ug/kg TM16/PM8
4-Chloro-3-methylphenol <10 <10 <10 ug/kg TM16/PM8
4-Methylphenol <10 <10 <10 ug/kg TM16/PM8
4-Nitrophenol <10 <10 <10 ug/kg TM16/PM8
Pentachlorophenol <10 <10 <10 ug/kg TM16/PM8
Phenol # <10 <10 <10 ug/kg TM16/PM8
PAHs
2-Chloronaphthalene # <10 <10 <10 ug/kg TM16/PM8
2-Methylnaphthalene # <10 <10 <10 ug/kg TM16/PM8
Phthalates
Bis(2-ethylhexyl) phthalate <100 <100 <100 ug/kg TM16/PM8
Butylbenzyl phthalate <100 <100 <100 ug/kg TM16/PM8
Di-n-butyl phthalate <100 <100 <100 ug/kg TM16/PM8
Di-n-Octyl phthalate <100 <100 <100 ug/kg TM16/PM8
Diethyl phthalate <100 <100 <100 ug/kg TM16/PM8
Dimethyl phthalate # <100 <100 <100 ug/kg TM16/PM8
Other SVOCs
1,2-Dichlorobenzene <10 <10 <10 ug/kg TM16/PM8
1,2,4-Trichlorobenzene # <10 <10 <10 ug/kg TM16/PM8
1,3-Dichlorobenzene <10 <10 <10 ug/kg TM16/PM8
1,4-Dichlorobenzene <10 <10 <10 ug/kg TM16/PM8
2-Nitroaniline <10 <10 <10 ug/kg TM16/PM8
2,4-Dinitrotoluene <10 <10 <10 ug/kg TM16/PM8
2,6-Dinitrotoluene <10 <10 <10 ug/kg TM16/PM8
3-Nitroaniline <10 <10 <10 ug/kg TM16/PM8
4-Bromophenylphenylether # <10 <10 <10 ug/kg TM16/PM8
4-Chloroaniline <10 <10 <10 ug/kg TM16/PM8
4-Chlorophenylphenylether <10 <10 <10 ug/kg TM16/PM8
4-Nitroaniline <10 <10 <10 ug/kg TM16/PM8
Azobenzene <10 <10 <10 ug/kg TM16/PM8
Bis(2-chloroethoxy)methane <10 <10 <10 ug/kg TM16/PM8
Bis(2-chloroethyl)ether <10 <10 <10 ug/kg TM16/PM8
Carbazole <10 <10 <10 ug/kg TM16/PM8
Dibenzofuran # <10 <10 <10 ug/kg TM16/PM8
Hexachlorobenzene <10 <10 <10 ug/kg TM16/PM8
Hexachlorobutadiene # <10 <10 <10 ug/kg TM16/PM8
Hexachlorocyclopentadiene <10 <10 <10 ug/kg TM16/PM8
Hexachloroethane <10 <10 <10 ug/kg TM16/PM8
Isophorone # <10 <10 <10 ug/kg TM16/PM8
N-nitrosodi-n-propylamine # <10 <10 <10 ug/kg TM16/PM8
Nitrobenzene # <10 <10 <10 ug/kg TM16/PM8
Surrogate Recovery 2-Fluorobiphenyl 37 23 <0 % TM16/PM8
Surrogate Recovery p-Terphenyl-d14 56 87 <0 % TM16/PM8
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.3 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 5 of 16
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EPA Export 28-05-2019:04:59:38
Client Name: VOC Report : Solid
Reference:
Location:
Contact:
JE Job No.: 17/2941
J E Sample No. 5-8 15-16
Sample ID WOP TP05/17 WOP TP03/17
Depth 4.00 0.50
COC No / misc
Containers V J V J
Sample Date 24/01/2017 24/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 25/01/2017 25/01/2017
VOC MS
Dichlorodifluoromethane <20AA <20SV
AA<2 ug/kg TM15/PM10
Methyl Tertiary Butyl Ether #
<20AA <20SV
AA<2 ug/kg TM15/PM10
Chloromethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Vinyl Chloride <20AA <20SV
AA<2 ug/kg TM15_A/PM10
Bromomethane <10AA <10SV
AA<1 ug/kg TM15/PM10
Chloroethane #
<20AA <20SV
AA<2 ug/kg TM15/PM10
Trichlorofluoromethane #
<20AA <20SV
AA<2 ug/kg TM15/PM10
1,1-Dichloroethene (1,1 DCE) #
<60AA <60SV
AA<6 ug/kg TM15/PM10
Dichloromethane (DCM) #
<300AA <300SV
AA<30 ug/kg TM15/PM10
trans-1-2-Dichloroethene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,1-Dichloroethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
cis-1-2-Dichloroethene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
2,2-Dichloropropane <40AA <40SV
AA<4 ug/kg TM15/PM10
Bromochloromethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Chloroform #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,1,1-Trichloroethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,1-Dichloropropene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Carbon tetrachloride #
<40AA <40SV
AA<4 ug/kg TM15/PM10
1,2-Dichloroethane #
<40AA <40SV
AA<4 ug/kg TM15/PM10
Benzene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Trichloroethene (TCE) #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,2-Dichloropropane #
<60AA <60SV
AA<6 ug/kg TM15/PM10
Dibromomethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Bromodichloromethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
cis-1-3-Dichloropropene <40AA <40SV
AA<4 ug/kg TM15/PM10
Toluene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
trans-1-3-Dichloropropene <30AA <30SV
AA<3 ug/kg TM15/PM10
1,1,2-Trichloroethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Tetrachloroethene (PCE) #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,3-Dichloropropane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Dibromochloromethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,2-Dibromoethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Chlorobenzene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,1,1,2-Tetrachloroethane <30AA <30SV
AA<3 ug/kg TM15/PM10
Ethylbenzene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
p/m-Xylene #
<50AA <50SV
AA<5 ug/kg TM15/PM10
o-Xylene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Styrene <30AA <30SV
AA<3 ug/kg TM15_A/PM10
Bromoform <30AA <30SV
AA<3 ug/kg TM15/PM10
Isopropylbenzene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
1,1,2,2-Tetrachloroethane #
<30AA <30SV
AA<3 ug/kg TM15/PM10
Bromobenzene <20AA <20SV
AA<2 ug/kg TM15/PM10
1,2,3-Trichloropropane #
<40AA <40SV
AA<4 ug/kg TM15/PM10
Propylbenzene #
<40AA <40SV
AA<4 ug/kg TM15/PM10
2-Chlorotoluene <30AA <30SV
AA<3 ug/kg TM15/PM10
1,3,5-Trimethylbenzene #
<30AA <30SV
AA<3 ug/kg TM15/PM10
4-Chlorotoluene <30AA <30SV
AA<3 ug/kg TM15/PM10
tert-Butylbenzene #
<50AA <50SV
AA<5 ug/kg TM15/PM10
1,2,4-Trimethylbenzene #
<60AA <60SV
AA<6 ug/kg TM15/PM10
sec-Butylbenzene #
<40AA <40SV
AA<4 ug/kg TM15/PM10
4-Isopropyltoluene #
<40AA <40SV
AA<4 ug/kg TM15/PM10
1,3-Dichlorobenzene #
<40AA <40SV
AA<4 ug/kg TM15/PM10
1,4-Dichlorobenzene #
<40AA <40SV
AA<4 ug/kg TM15/PM10
n-Butylbenzene #
<40AA <40SV
AA<4 ug/kg TM15/PM10
1,2-Dichlorobenzene #
<40AA <40SV
AA<4 ug/kg TM15/PM10
1,2-Dibromo-3-chloropropane #
<40AA <40SV
AA<4 ug/kg TM15/PM10
1,2,4-Trichlorobenzene #
<70AA <70SV
AA<7 ug/kg TM15/PM10
Hexachlorobutadiene <40AA <40SV
AA<4 ug/kg TM15/PM10
Naphthalene <270AA <270SV
AA<27 ug/kg TM15/PM10
1,2,3-Trichlorobenzene #
<70AA <70SV
AA<7 ug/kg TM15/PM10
Surrogate Recovery Toluene D8 74AA 81SV
AA<0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 52AA 48SV
AA<0 % TM15/PM10
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.4 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 6 of 16
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Client Name:
Reference:
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Note:
J E
Job
No.
Batch Depth
J E
Sample
No.
Date Of
AnalysisAnalysis Result
17/2941 1 4.00 7 03/02/2017 General Description (Bulk Analysis) soil/stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
17/2941 1 3.50 12 03/02/2017 General Description (Bulk Analysis) soil/stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
17/2941 1 0.50 16 03/02/2017 General Description (Bulk Analysis) soil/stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
17/2941 1 2.50 18 03/02/2017 General Description (Bulk Analysis) Soil-Silt/Stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
17/2941 1 1.00 20 03/02/2017 General Description (Bulk Analysis) Soil-Silt/Stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
WOP TP02/17
WOP TP03/17
WOP TP03/17
WOP TP04/17
Ryan Butterworth
Asbestos Team Leader
Sample ID
WOP TP05/17
Analysis was carried out in accordance with our documented in-house methods PM042 and TM065 and HSG 248 by Stereo and Polarised Light Microscopy using Dispersion
Staining Techniques and is covered by our UKAS accreditation. Samples are retained for not less than 6 months from the date of analysis unless specifically requested.
Opinions, including ACM type and Asbestos level, lie outside the scope of our UKAS accreditation.
Where the sample is not taken by a Jones Environmental Laboratory consultant, Jones Environmental Laboratory cannot be responsible for inaccurate or unrepresentative
sampling.
Signed on behalf of Jones Environmental Laboratory:
Exova Jones Environmental Asbestos Analysis
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
QF-PM 3.1.15 v10 Please include all sections of this report if it is reproduced 7 of 16
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Asbestos Analysis
Client Name:
Reference:
Location:
Contact:
J E
Job
No.
Batch Depth
J E
Sample
No.
Date Of
AnalysisAnalysis Result
17/2941 1 1.00 20 03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
17/2941 1 0.50 24 03/02/2017 General Description (Bulk Analysis) Soil-Silt/Stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
WOP TP01/17
WOP TP02/17
Jones Environmental Laboratory
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
Sample ID
QF-PM 3.1.15 v10 Please include all sections of this report if it is reproduced 8 of 16
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Notification of Deviating Samples
J E
Job
No.
Batch Depth J E Sample
No.Analysis Reason
Please note that only samples that are deviating are mentioned in this report. If no samples are listed it is because none were deviating.
Only analyses which are accredited are recorded as deviating if set criteria are not met.
Exova Jones Environmental
WOP 16-1239
Project Gemini
Colm HurleyContact:
Sample ID
Client Name: Causeway Geotech
Reference:
Location:
No deviating sample report results for job 17/2941
QF-PM 3.1.11 v3 Please include all sections of this report if it is reproduced 9 of 16
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JE Job No.:
SOILS
DEVIATING SAMPLES
SURROGATES
DILUTIONS
BLANKS
NOTE
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
Please note we are not a UK Drinking Water Inspectorate (DWI) Approved Laboratory .
If you have not already done so, please send us a purchase order if this is required by your company.
Samples must be received in a condition appropriate to the requested analyses. All samples should be submitted to the laboratory in suitable
containers with sufficient ice packs to sustain an appropriate temperature for the requested analysis. If this is not the case you will be informed and
any test results that may be compromised highlighted on your deviating samples report.
ISO17025 accreditation applies to surface water and groundwater and usually one other matrix which is analysis specific, any other liquids are
outside our scope of accreditation.
As surface waters require different sample preparation to groundwaters the laboratory must be informed of the water type when submitting samples.
Where appropriate please make sure that our detection limits are suitable for your needs, if they are not, please notify us immediately.
Data is only reported if the laboratory is confident that the data is a true reflection of the samples analysed. Data is only reported as accredited when
all the requirements of our Quality System have been met. In certain circumstances where all the requirements of the Quality System have not been
met, for instance if the associated AQC has failed, the reason is fully investigated and documented. The sample data is then evaluated alongside
the other quality control checks performed during analysis to determine its suitability. Following this evaluation, provided the sample results have not
been effected, the data is reported but accreditation is removed. It is a UKAS requirement for data not reported as accredited to be considered
indicative only, but this does not mean the data is not valid.
Where possible, and if requested, samples will be re-extracted and a revised report issued with accredited results. Please do not hesitate to contact
the laboratory if further details are required of the circumstances which have led to the removal of accreditation.
Where an MCERTS report has been requested, you will be notified within 48 hours of any samples that have been identified as being outside our
MCERTS scope. As validation has been performed on clay, sand and loam, only samples that are predominantly these matrices, or combinations
of them will be within our MCERTS scope. If samples are not one of a combination of the above matrices they will not be marked as MCERTS
accredited.
Negative Neutralization Potential (NP) values are obtained when the volume of NaOH (0.1N) titrated (pH 8.3) is greater than the volume of HCl (1N)
to reduce the pH of the sample to 2.0 - 2.5. Any negative NP values are corrected to 0.
Where a CEN 10:1 ZERO Headspace VOC test has been carried out, a 10:1 ratio of water to wet (as received) soil has been used.
All samples will be discarded one month after the date of reporting, unless we are instructed to the contrary.
% Asbestos in Asbestos Containing Materials (ACMs) is determined by reference to HSG 264 The Survey Guide - Appendix 2 : ACMs in buildings
listed in order of ease of fibre release.
All analysis is reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected. Samples are dried at 35°C ±5°C unless
otherwise stated. Moisture content for CEN Leachate tests are dried at 105°C ±5°C.
Surrogate compounds are added during the preparation process to monitor recovery of analytes. However low recovery in soils is often due to peat,
clay or other organic rich matrices. For waters this can be due to oxidants, surfactants, organic rich sediments or remediation fluids. Acceptable
limits for most organic methods are 70 - 130% and for VOCs are 50 - 150%. When surrogate recoveries are outside the performance criteria but
the associated AQC passes this is assumed to be due to matrix effect. Results are not surrogate corrected.
A dilution suffix indicates a dilution has been performed and the reported result takes this into account. No further calculation is required.
NOTES TO ACCOMPANY ALL SCHEDULES AND REPORTS
Please note we are only MCERTS accredited (UK soils only) for sand, loam and clay and any other matrix is outside our scope of accreditation.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
17/2941
WATERS
Where analytes have been found in the blank, the sample will be treated in accordance with our laboratory procedure for dealing with contaminated
blanks.
It is assumed that you have taken representative samples on site and require analysis on a representative subsample. Stones will generally be
included unless we are requested to remove them.
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 10 of 16
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EPA Export 28-05-2019:04:59:38
JE Job No.:
#
SA
B
DR
M
NA
NAD
ND
NDP
SS
SV
W
+
++
*
AD
CO
LOD/LOR
ME
NFD
BS
LB
N
TB
OC
AA x10 Dilution
Dilution required.
Analysis subcontracted to a Jones Environmental approved laboratory.
Matrix Effect
Blank Sample
Client Sample
Trip Blank Sample
AQC Sample
Suspected carry over
Limit of Detection (Limit of Reporting) in line with ISO 17025 and MCERTS
Samples are dried at 35°C ±5°C
17/2941
AQC failure, accreditation has been removed from this result, if appropriate, see 'Note' on previous page.
Calibrated against a single substance
Not applicable
No Asbestos Detected.
No Determination Possible
Indicates analyte found in associated method blank.
None Detected (usually refers to VOC and/SVOC TICs).
ISO17025 (SANAS) accredited - South Africa.
MCERTS accredited.
Outside Calibration Range
No Fibres Detected
Result outside calibration range, results should be considered as indicative only and are not accredited.
Results expressed on as received basis.
Surrogate recovery outside performance criteria. This may be due to a matrix effect.
ISO17025 (UKAS) accredited - UK.
ABBREVIATIONS and ACRONYMS USED
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 11 of 16
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JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required.
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR
TM5/TM36
TM005: Modified USEPA 8015B. Determination of solvent Extractable Petroleum
Hydrocarbons (EPH) including column fractionation in the carbon range of C10-35 into
aliphatic and aromatic fractions by GC-FID.
TM036: Modified USEPA 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C5-10 by headspace GC-FID. Including determination of
BTEX and calculation of Aliphatic fractions.
PM12/PM16
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis./Fractionation into aliphatic and aromatic fractions using a Rapid
Trace SPE.
AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 12 of 16
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EPA Export 28-05-2019:04:59:38
JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. Yes AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM17Modified US EPA method 8270. Determination of specific Polychlorinated Biphenyl
congeners by GC-MS.PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM20Modified BS 1377-3: 1990/USEPA 160.3 Gravimetric determination of Total Dissolved
Solids/Total SolidsPM0 No preparation is required. Yes AR Yes
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.AD Yes
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.Yes AD Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM0 No preparation is required. AR Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM21
As received solid or water samples are extracted in Methanol: Sodium Hydroxide (0.1M
NaOH) (60:40) by orbital shaker.AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 13 of 16
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EPA Export 28-05-2019:04:59:38
JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM14
Analysis of waters and leachates for metals by ICP OES/ICP MS. Samples are filtered for
dissolved metals and acidified if required.Yes AR Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.Yes AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM17
Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.Yes AR Yes
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. Yes AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 14 of 16
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EPA Export 28-05-2019:04:59:38
JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AR Yes
TM60
Modified USEPA 9060. Determination of TOC by calculation from Total Carbon and
Inorganic Carbon using a TOC analyser, the carbon in the sample is converted to CO2
and then passed through a non-dispersive infrared gas analyser (NDIR).
PM0 No preparation is required. AR Yes
TM61Modified US EPA methods 245.7 and 200.7. Determination of Mercury by Cold Vapour
Atomic Fluorescence. PM38
Samples are brominated to reduce all mercury compounds to Mercury (II) which is
analysed using method TM061.Yes AR Yes
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.AR
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.Yes AR
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM0 No preparation is required. AR Yes
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM11 Extraction of as received solid samples using one part solid to 2.5 parts deionised water. Yes AR No
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 15 of 16
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EPA Export 28-05-2019:04:59:39
JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM163Quantitative determination of Persistent Organic Pollutants (Pesticides) and Toxaphene
by GC-MSPM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM173 Analysis of fluoride by ISE (Ion Selective Electrode) using modified ISE method 340.2 PM0 No preparation is required. AR Yes
NONE No Method Code NONE No Method Code AR Yes
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.AR
NONE No Method Code PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.AR
TM15_AModified USEPA 8260. Quantitative Determination of Volatile Organic Compounds, Vinyl
Chloride & Styrene by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 16 of 16
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EPA Export 28-05-2019:04:59:39
Unit 3 Deeside Point
Zone 3
Deeside Industrial Park
Deeside
Causeway Geotech
Attention :
Date :
Your reference :
Our reference :
Location :
Date samples received :
Status :
Issue :
Colm Hurley
28th February, 2017
1
Exova Jones Environmental
CH5 2UA
Tel: +44 (0) 1244 833780
Fax: +44 (0) 1244 833781
8 Drumahiskey Road
Bainamore
Ballymoney
Co Antrim
BT53 7QL
Registered Address : Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian, EH28 8PL
Two samples were received for analysis on 25th January, 2017 of which two were scheduled for analysis. Please find attached our Test Report
which should be read with notes at the end of the report and should include all sections if reproduced. Interpretations and opinions are outside the
scope of any accreditation, and all results relate only to samples supplied.
All analysis is carried out on as received samples and reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected.
Where Waste Acceptance Criteria Suite (EC Decision of 19 December 2002 (2003/33/EC)) has been requested, all analyses have been performed
using the relevant EN methods where they exist.
Phil Sommerton BSc
Project Manager
WOP 16-1239
Project Gemini
25th January, 2017
Final report
Compiled By:
Test Report 17/2941 Batch 1
QF-PM 3.1.1 v16Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 1 of 18
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EPA Export 28-05-2019:04:59:39
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/2941
J E Sample No. 13-14 27-28
Sample ID WOP TP04/17 WOP TP01/17
Depth 0.50-2.00 0.50-1.50
COC No / misc
Containers V J V J
Sample Date 24/01/2017 24/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 25/01/2017 25/01/2017
Antimony <1 <1 <1 mg/kg TM30/PM15
Arsenic # 12.9 20.8 <0.5 mg/kg TM30/PM15
Barium # 169 200 <1 mg/kg TM30/PM15
Cadmium # 0.5 0.6 <0.1 mg/kg TM30/PM15
Chromium # 25.8 15.0 <0.5 mg/kg TM30/PM15
Copper # 14 18 <1 mg/kg TM30/PM15
Lead # 14 11 <5 mg/kg TM30/PM15
Mercury # <0.1 <0.1 <0.1 mg/kg TM30/PM15
Molybdenum # 3.0 6.4 <0.1 mg/kg TM30/PM15
Nickel # 26.3 34.3 <0.7 mg/kg TM30/PM15
Selenium # 5 8 <1 mg/kg TM30/PM15
Zinc # 40 41 <5 mg/kg TM30/PM15
PAH MS
Naphthalene # <0.04 0.32 <0.04 mg/kg TM4/PM8
Acenaphthylene <0.03 <0.03 <0.03 mg/kg TM4/PM8
Acenaphthene # <0.05 <0.05 <0.05 mg/kg TM4/PM8
Fluorene # <0.04 <0.04 <0.04 mg/kg TM4/PM8
Phenanthrene # <0.03 <0.03 <0.03 mg/kg TM4/PM8
Anthracene # <0.04 <0.04 <0.04 mg/kg TM4/PM8
Fluoranthene # <0.03 <0.03 <0.03 mg/kg TM4/PM8
Pyrene # <0.03 <0.03 <0.03 mg/kg TM4/PM8
Benzo(a)anthracene # <0.06 <0.06 <0.06 mg/kg TM4/PM8
Chrysene # <0.02 <0.02 <0.02 mg/kg TM4/PM8
Benzo(bk)fluoranthene # <0.07 <0.07 <0.07 mg/kg TM4/PM8
Benzo(a)pyrene # <0.04 <0.04 <0.04 mg/kg TM4/PM8
Indeno(123cd)pyrene # <0.04 <0.04 <0.04 mg/kg TM4/PM8
Dibenzo(ah)anthracene # <0.04 <0.04 <0.04 mg/kg TM4/PM8
Benzo(ghi)perylene # <0.04 <0.04 <0.04 mg/kg TM4/PM8
Coronene <0.04 <0.04 <0.04 mg/kg TM4/PM8
PAH 6 Total # <0.22 <0.22 <0.22 mg/kg TM4/PM8
PAH 17 Total <0.64 <0.64 <0.64 mg/kg TM4/PM8
Benzo(b)fluoranthene <0.05 <0.05 <0.05 mg/kg TM4/PM8
Benzo(k)fluoranthene <0.02 <0.02 <0.02 mg/kg TM4/PM8
Benzo(j)fluoranthene <1 <1 <1 mg/kg TM4/PM8
PAH Surrogate % Recovery 36 93 <0 % TM4/PM8
Mineral Oil (C10-C40) <30 <30 <30 mg/kg TM5/PM16
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
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EPA Export 28-05-2019:04:59:39
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/2941
J E Sample No. 13-14 27-28
Sample ID WOP TP04/17 WOP TP01/17
Depth 0.50-2.00 0.50-1.50
COC No / misc
Containers V J V J
Sample Date 24/01/2017 24/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 25/01/2017 25/01/2017
TPH CWG
Aliphatics
>C5-C6 #
<0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>C6-C8 #
<0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>C8-C10 <0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>C10-C12 # <0.2 <0.2 <0.2 mg/kg TM5/PM16
>C12-C16 # <4 <4 <4 mg/kg TM5/PM16
>C16-C21 # <7 <7 <7 mg/kg TM5/PM16
>C21-C35 # <7 <7 <7 mg/kg TM5/PM16
>C35-C40 <7 <7 <7 mg/kg TM5/PM16
Total aliphatics C5-40 <26 <26 <26 mg/kg TM5/TM36/PM12/PM16
>C6-C10 <0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>C10-C25 <10 <10 <10 mg/kg TM5/PM16
>C25-C35 <10 <10 <10 mg/kg TM5/PM16
Aromatics
>C5-EC7 #
<0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>EC7-EC8 #
<0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>EC8-EC10 #
<0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>EC10-EC12 # <0.2 <0.2 <0.2 mg/kg TM5/PM16
>EC12-EC16 # <4 <4 <4 mg/kg TM5/PM16
>EC16-EC21 # <7 <7 <7 mg/kg TM5/PM16
>EC21-EC35 # <7 <7 <7 mg/kg TM5/PM16
>EC35-EC40 <7 <7 <7 mg/kg TM5/PM16
Total aromatics C5-40 <26 <26 <26 mg/kg TM5/TM36/PM12/PM16
Total aliphatics and aromatics(C5-40) <52 <52 <52 mg/kg TM5/TM36/PM12/PM16
>EC6-EC10 #
<0.1SV
<0.1SV <0.1 mg/kg TM36/PM12
>EC10-EC25 <10 <10 <10 mg/kg TM5/PM16
>EC25-EC35 <10 <10 <10 mg/kg TM5/PM16
MTBE #
<5SV
<5SV <5 ug/kg TM31/PM12
Benzene #
<5SV
<5SV <5 ug/kg TM31/PM12
Toluene #
<5SV
<5SV <5 ug/kg TM31/PM12
Ethylbenzene #
<5SV
<5SV <5 ug/kg TM31/PM12
m/p-Xylene #
<5SV
<5SV <5 ug/kg TM31/PM12
o-Xylene #
<5SV
<5SV <5 ug/kg TM31/PM12
PCB 28 # <5 <5 <5 ug/kg TM17/PM8
PCB 52 # <5 <5 <5 ug/kg TM17/PM8
PCB 101 # <5 <5 <5 ug/kg TM17/PM8
PCB 118 # <5 <5 <5 ug/kg TM17/PM8
PCB 138 # <5 <5 <5 ug/kg TM17/PM8
PCB 153 # <5 <5 <5 ug/kg TM17/PM8
PCB 180 # <5 <5 <5 ug/kg TM17/PM8
Total 7 PCBs # <35 <35 <35 ug/kg TM17/PM8
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 3 of 18
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EPA Export 28-05-2019:04:59:39
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/2941
J E Sample No. 13-14 27-28
Sample ID WOP TP04/17 WOP TP01/17
Depth 0.50-2.00 0.50-1.50
COC No / misc
Containers V J V J
Sample Date 24/01/2017 24/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 25/01/2017 25/01/2017
Natural Moisture Content 144.9 125.0 <0.1 % PM4/PM0
Moisture Content (% Wet Weight) 59.2 55.6 <0.1 % PM4/PM0
Hexavalent Chromium # <0.3 <0.3 <0.3 mg/kg TM38/PM20
Chromium III 25.8 15.0 <0.5 mg/kg NONE/NONE
Total Organic Carbon # 31.39 21.79 <0.02 % TM21/PM24
pH # 12.27 12.75 <0.01 pH units TM73/PM11
Mass of raw test portion 0.2589 0.1826 kg NONE/PM17
Mass of dried test portion 0.09 0.09 kg NONE/PM17
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 4 of 18
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EPA Export 28-05-2019:04:59:39
Client Name: Report : CEN 10:1 1 Batch
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/2941
J E Sample No. 13-14 27-28
Sample ID WOP TP04/17 WOP TP01/17
Depth 0.50-2.00 0.50-1.50
COC No / misc
Containers V J V J
Sample Date 24/01/2017 24/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 25/01/2017 25/01/2017
Dissolved Antimony # <0.002 <0.002 <0.002 mg/l TM30/PM17
Dissolved Antimony (A10) # <0.02 <0.02 <0.02 mg/kg TM30/PM17
Dissolved Arsenic # <0.0025 <0.0025 <0.0025 mg/l TM30/PM17
Dissolved Arsenic (A10) # <0.025 <0.025 <0.025 mg/kg TM30/PM17
Dissolved Barium # 0.312 0.842 <0.003 mg/l TM30/PM17
Dissolved Barium (A10) # 3.12 8.42 <0.03 mg/kg TM30/PM17
Dissolved Cadmium # <0.0005 <0.0005 <0.0005 mg/l TM30/PM17
Dissolved Cadmium (A10) # <0.005 <0.005 <0.005 mg/kg TM30/PM17
Dissolved Chromium # <0.0015 <0.0015 <0.0015 mg/l TM30/PM17
Dissolved Chromium (A10) # <0.015 <0.015 <0.015 mg/kg TM30/PM17
Dissolved Copper # <0.007 <0.007 <0.007 mg/l TM30/PM17
Dissolved Copper (A10) # <0.07 <0.07 <0.07 mg/kg TM30/PM17
Dissolved Lead # <0.005 <0.005 <0.005 mg/l TM30/PM17
Dissolved Lead (A10) # <0.05 <0.05 <0.05 mg/kg TM30/PM17
Dissolved Molybdenum # 0.035 0.040 <0.002 mg/l TM30/PM17
Dissolved Molybdenum (A10) # 0.35 0.40 <0.02 mg/kg TM30/PM17
Dissolved Nickel # <0.002 <0.002 <0.002 mg/l TM30/PM17
Dissolved Nickel (A10) # <0.02 <0.02 <0.02 mg/kg TM30/PM17
Dissolved Selenium # <0.003 <0.003 <0.003 mg/l TM30/PM17
Dissolved Selenium (A10) # <0.03 <0.03 <0.03 mg/kg TM30/PM17
Dissolved Zinc # 0.004 0.007 <0.003 mg/l TM30/PM17
Dissolved Zinc (A10) # 0.04 0.07 <0.03 mg/kg TM30/PM17
Mercury Dissolved by CVAF # <0.00001 <0.00001 <0.00001 mg/l TM61/PM38
Mercury Dissolved by CVAF # <0.0001 <0.0001 <0.0001 mg/kg TM61/PM38
Phenol <0.01 <0.01 <0.01 mg/l TM26/PM0
Phenol <0.1 <0.1 <0.1 mg/kg TM26/PM0
Fluoride <0.3 <0.3 <0.3 mg/l TM173/PM0
Fluoride <3 <3 <3 mg/kg TM173/PM0
Sulphate # 27.90 24.15 <0.05 mg/l TM38/PM0
Sulphate # 278.9 241.4 <0.5 mg/kg TM38/PM0
Chloride # 9.7 9.1 <0.3 mg/l TM38/PM0
Chloride # 97 91 <3 mg/kg TM38/PM0
Leachant Volume 0.73 0.807 l NONE/PM17
Eluate Volume 0.53 0.05 l NONE/PM17
Dissolved Organic Carbon 5 20 <2 mg/l TM60/PM0
Dissolved Organic Carbon 50 200 <20 mg/kg TM60/PM0
pH 12.15 12.66 <0.01 pH units TM73/PM0
Total Dissolved Solids # 784 1841 <35 mg/l TM20/PM0
Total Dissolved Solids # 7836 18406 <350 mg/kg TM20/PM0
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 5 of 18
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EPA Export 28-05-2019:04:59:39
Mass of sample taken (kg) 0.2589 Dry Matter Content Ratio (%) = 34.7
Mass of dry sample (kg) = 0.09 Leachant Volume (l) 0.73
Particle Size <4mm = >95% Eluate Volume (l) 0.53
JEFL Job No
Sample No
Client Sample No
Depth/Other
Sample Date
Batch No
Solid Waste Analysis
Total Organic Carbon (%) 31.39 3 5 6
Sum of BTEX (mg/kg) <0.025 6 - -
Sum of 7 PCBs (mg/kg) <0.035 1 - -
Mineral Oil (mg/kg) <30 500 - -
PAH Sum of 6 (mg/kg) <0.22 - - -
PAH Sum of 17 (mg/kg) <0.64 100 - -
10:1
concn
leached
A10
mg/kg
Arsenic <0.025 0.5 2 25
Barium 3.12 20 100 300
Cadmium <0.005 0.04 1 5
Chromium <0.015 0.5 10 70
Copper <0.07 2 50 100
Mercury <0.0001 0.01 0.2 2
Molybdenum 0.35 0.5 10 30
Nickel <0.02 0.4 10 40
Lead <0.05 0.5 10 50
Antimony <0.02 0.06 0.7 5
Selenium <0.03 0.1 0.5 7
Zinc 0.04 4 50 200
Chloride 97 800 15000 25000
Fluoride <3 10 150 500
Sulphate as SO4 278.9 1000 20000 50000
Total Dissolved Solids 7836 4000 60000 100000
Phenol <0.1 1 - -
Dissolved Organic Carbon 50 500 800 1000
24/01/2017
1
Eluate Analysis
Limit values for compliance
leaching test using
BS EN 12457-2 at L/S 10 l/kg
mg/kg
Exova Jones Environmental EN-12457-2 Result Report
17/2941 Landfill Waste Acceptance
Criteria Limits 14
WOP TP04/17
InertStable
Non-reactiveHazardous
0.50-2.00
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EPA Export 28-05-2019:04:59:39
Mass of sample taken (kg) 0.1826 Dry Matter Content Ratio (%) = 49.2
Mass of dry sample (kg) = 0.09 Leachant Volume (l) 0.807
Particle Size <4mm = >95% Eluate Volume (l) 0.05
JEFL Job No
Sample No
Client Sample No
Depth/Other
Sample Date
Batch No
Solid Waste Analysis
Total Organic Carbon (%) 21.79 3 5 6
Sum of BTEX (mg/kg) <0.025 6 - -
Sum of 7 PCBs (mg/kg) <0.035 1 - -
Mineral Oil (mg/kg) <30 500 - -
PAH Sum of 6 (mg/kg) <0.22 - - -
PAH Sum of 17 (mg/kg) <0.64 100 - -
10:1
concn
leached
A10
mg/kg
Arsenic <0.025 0.5 2 25
Barium 8.42 20 100 300
Cadmium <0.005 0.04 1 5
Chromium <0.015 0.5 10 70
Copper <0.07 2 50 100
Mercury <0.0001 0.01 0.2 2
Molybdenum 0.40 0.5 10 30
Nickel <0.02 0.4 10 40
Lead <0.05 0.5 10 50
Antimony <0.02 0.06 0.7 5
Selenium <0.03 0.1 0.5 7
Zinc 0.07 4 50 200
Chloride 91 800 15000 25000
Fluoride <3 10 150 500
Sulphate as SO4 241.4 1000 20000 50000
Total Dissolved Solids 18406 4000 60000 100000
Phenol <0.1 1 - -
Dissolved Organic Carbon 200 500 800 1000
24/01/2017
1
Eluate Analysis
Limit values for compliance
leaching test using
BS EN 12457-2 at L/S 10 l/kg
mg/kg
Exova Jones Environmental EN-12457-2 Result Report
17/2941 Landfill Waste Acceptance
Criteria Limits 28
WOP TP01/17
InertStable
Non-reactiveHazardous
0.50-1.50
QF-PM 3.1.18 v1Please include all sections of this report if it is reproduced
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EPA Export 28-05-2019:04:59:39
EPH Interpretation Report
Matrix : Solid
J E
Job
No.
Batch Depth J E Sample
No.EPH Interpretation
17/2941 1 0.50-2.00 13-14 No interpretation possible
17/2941 1 0.50-1.50 27-28 No interpretation possible
Contact: Colm Hurley
Sample ID
WOP TP04/17
WOP TP01/17
Client Name: Causeway Geotech
Reference: WOP 16-1239
Location: Project Gemini
Exova Jones Environmental
QF-PM 3.1.8 v10 Please include all sections of this report if it is reproduced 8 of 18
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Client Name:
Reference:
Location:
Contact:
Note:
J E
Job
No.
Batch Depth
J E
Sample
No.
Date Of
AnalysisAnalysis Result
17/2941 1 0.50-2.00 14 03/02/2017 General Description (Bulk Analysis) soil/stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
17/2941 1 0.50-1.50 28 03/02/2017 General Description (Bulk Analysis) Soil-Silt/Stones
03/02/2017 Asbestos Fibres NAD
03/02/2017 Asbestos Fibres (2) NAD
03/02/2017 Asbestos ACM NAD
03/02/2017 Asbestos ACM (2) NAD
03/02/2017 Asbestos Type NAD
03/02/2017 Asbestos Type (2) NAD
03/02/2017 Asbestos Level Screen NAD
WOP TP01/17
Ryan Butterworth
Asbestos Team Leader
Sample ID
WOP TP04/17
Analysis was carried out in accordance with our documented in-house methods PM042 and TM065 and HSG 248 by Stereo and Polarised Light Microscopy using Dispersion
Staining Techniques and is covered by our UKAS accreditation. Samples are retained for not less than 6 months from the date of analysis unless specifically requested.
Opinions, including ACM type and Asbestos level, lie outside the scope of our UKAS accreditation.
Where the sample is not taken by a Jones Environmental Laboratory consultant, Jones Environmental Laboratory cannot be responsible for inaccurate or unrepresentative
sampling.
Signed on behalf of Jones Environmental Laboratory:
Exova Jones Environmental Asbestos Analysis
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
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Notification of Deviating Samples
J E
Job
No.
Batch Depth J E Sample
No.Analysis Reason
Please note that only samples that are deviating are mentioned in this report. If no samples are listed it is because none were deviating.
Only analyses which are accredited are recorded as deviating if set criteria are not met.
Exova Jones Environmental
WOP 16-1239
Project Gemini
Colm HurleyContact:
Sample ID
Client Name: Causeway Geotech
Reference:
Location:
No deviating sample report results for job 17/2941
QF-PM 3.1.11 v3 Please include all sections of this report if it is reproduced 10 of 18
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JE Job No.:
SOILS
DEVIATING SAMPLES
SURROGATES
DILUTIONS
BLANKS
NOTE
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
Please note we are not a UK Drinking Water Inspectorate (DWI) Approved Laboratory .
If you have not already done so, please send us a purchase order if this is required by your company.
Samples must be received in a condition appropriate to the requested analyses. All samples should be submitted to the laboratory in suitable
containers with sufficient ice packs to sustain an appropriate temperature for the requested analysis. If this is not the case you will be informed and
any test results that may be compromised highlighted on your deviating samples report.
ISO17025 accreditation applies to surface water and groundwater and usually one other matrix which is analysis specific, any other liquids are
outside our scope of accreditation.
As surface waters require different sample preparation to groundwaters the laboratory must be informed of the water type when submitting samples.
Where appropriate please make sure that our detection limits are suitable for your needs, if they are not, please notify us immediately.
Data is only reported if the laboratory is confident that the data is a true reflection of the samples analysed. Data is only reported as accredited when
all the requirements of our Quality System have been met. In certain circumstances where all the requirements of the Quality System have not been
met, for instance if the associated AQC has failed, the reason is fully investigated and documented. The sample data is then evaluated alongside
the other quality control checks performed during analysis to determine its suitability. Following this evaluation, provided the sample results have not
been effected, the data is reported but accreditation is removed. It is a UKAS requirement for data not reported as accredited to be considered
indicative only, but this does not mean the data is not valid.
Where possible, and if requested, samples will be re-extracted and a revised report issued with accredited results. Please do not hesitate to contact
the laboratory if further details are required of the circumstances which have led to the removal of accreditation.
Where an MCERTS report has been requested, you will be notified within 48 hours of any samples that have been identified as being outside our
MCERTS scope. As validation has been performed on clay, sand and loam, only samples that are predominantly these matrices, or combinations
of them will be within our MCERTS scope. If samples are not one of a combination of the above matrices they will not be marked as MCERTS
accredited.
Negative Neutralization Potential (NP) values are obtained when the volume of NaOH (0.1N) titrated (pH 8.3) is greater than the volume of HCl (1N)
to reduce the pH of the sample to 2.0 - 2.5. Any negative NP values are corrected to 0.
Where a CEN 10:1 ZERO Headspace VOC test has been carried out, a 10:1 ratio of water to wet (as received) soil has been used.
All samples will be discarded one month after the date of reporting, unless we are instructed to the contrary.
% Asbestos in Asbestos Containing Materials (ACMs) is determined by reference to HSG 264 The Survey Guide - Appendix 2 : ACMs in buildings
listed in order of ease of fibre release.
All analysis is reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected. Samples are dried at 35°C ±5°C unless
otherwise stated. Moisture content for CEN Leachate tests are dried at 105°C ±5°C.
Surrogate compounds are added during the preparation process to monitor recovery of analytes. However low recovery in soils is often due to peat,
clay or other organic rich matrices. For waters this can be due to oxidants, surfactants, organic rich sediments or remediation fluids. Acceptable
limits for most organic methods are 70 - 130% and for VOCs are 50 - 150%. When surrogate recoveries are outside the performance criteria but
the associated AQC passes this is assumed to be due to matrix effect. Results are not surrogate corrected.
A dilution suffix indicates a dilution has been performed and the reported result takes this into account. No further calculation is required.
NOTES TO ACCOMPANY ALL SCHEDULES AND REPORTS
Please note we are only MCERTS accredited (UK soils only) for sand, loam and clay and any other matrix is outside our scope of accreditation.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
17/2941
WATERS
Where analytes have been found in the blank, the sample will be treated in accordance with our laboratory procedure for dealing with contaminated
blanks.
It is assumed that you have taken representative samples on site and require analysis on a representative subsample. Stones will generally be
included unless we are requested to remove them.
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 11 of 18
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JE Job No.:
#
SA
B
DR
M
NA
NAD
ND
NDP
SS
SV
W
+
++
*
AD
CO
LOD/LOR
ME
NFD
BS
LB
N
TB
OC
Dilution required.
Analysis subcontracted to a Jones Environmental approved laboratory.
Matrix Effect
Blank Sample
Client Sample
Trip Blank Sample
AQC Sample
Suspected carry over
Limit of Detection (Limit of Reporting) in line with ISO 17025 and MCERTS
Samples are dried at 35°C ±5°C
17/2941
AQC failure, accreditation has been removed from this result, if appropriate, see 'Note' on previous page.
Calibrated against a single substance
Not applicable
No Asbestos Detected.
No Determination Possible
Indicates analyte found in associated method blank.
None Detected (usually refers to VOC and/SVOC TICs).
ISO17025 (SANAS) accredited - South Africa.
MCERTS accredited.
Outside Calibration Range
No Fibres Detected
Result outside calibration range, results should be considered as indicative only and are not accredited.
Results expressed on as received basis.
Surrogate recovery outside performance criteria. This may be due to a matrix effect.
ISO17025 (UKAS) accredited - UK.
ABBREVIATIONS and ACRONYMS USED
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
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JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required.
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR
TM5/TM36
TM005: Modified USEPA 8015B. Determination of solvent Extractable Petroleum
Hydrocarbons (EPH) including column fractionation in the carbon range of C10-35 into
aliphatic and aromatic fractions by GC-FID.
TM036: Modified USEPA 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C5-10 by headspace GC-FID. Including determination of
BTEX and calculation of Aliphatic fractions.
PM12/PM16
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis./Fractionation into aliphatic and aromatic fractions using a Rapid
Trace SPE.
AR Yes
Exova Jones Environmental Method Code Appendix
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JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. Yes AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM17Modified US EPA method 8270. Determination of specific Polychlorinated Biphenyl
congeners by GC-MS.PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM20Modified BS 1377-3: 1990/USEPA 160.3 Gravimetric determination of Total Dissolved
Solids/Total SolidsPM0 No preparation is required. Yes AR Yes
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.AD Yes
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.Yes AD Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM0 No preparation is required. AR Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM21
As received solid or water samples are extracted in Methanol: Sodium Hydroxide (0.1M
NaOH) (60:40) by orbital shaker.AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 14 of 18
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EPA Export 28-05-2019:04:59:39
JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM14
Analysis of waters and leachates for metals by ICP OES/ICP MS. Samples are filtered for
dissolved metals and acidified if required.Yes AR Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.Yes AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM17
Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.Yes AR Yes
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. Yes AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 15 of 18
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JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AR Yes
TM60
Modified USEPA 9060. Determination of TOC by calculation from Total Carbon and
Inorganic Carbon using a TOC analyser, the carbon in the sample is converted to CO2
and then passed through a non-dispersive infrared gas analyser (NDIR).
PM0 No preparation is required. AR Yes
TM61Modified US EPA methods 245.7 and 200.7. Determination of Mercury by Cold Vapour
Atomic Fluorescence. PM38
Samples are brominated to reduce all mercury compounds to Mercury (II) which is
analysed using method TM061.Yes AR Yes
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.AR
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.Yes AR
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM0 No preparation is required. AR Yes
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM11 Extraction of as received solid samples using one part solid to 2.5 parts deionised water. Yes AR No
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 16 of 18
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EPA Export 28-05-2019:04:59:39
JE Job No: 17/2941
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM163Quantitative determination of Persistent Organic Pollutants (Pesticides) and Toxaphene
by GC-MSPM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM173 Analysis of fluoride by ISE (Ion Selective Electrode) using modified ISE method 340.2 PM0 No preparation is required. AR Yes
NONE No Method Code NONE No Method Code AR Yes
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.AR
NONE No Method Code PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.AR
TM15_AModified USEPA 8260. Quantitative Determination of Volatile Organic Compounds, Vinyl
Chloride & Styrene by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 17 of 18
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Leachate tests
10l/kg; 4mmI.S. EN 12457-2:2002 Specified particle size; water added to L/S ratio; capped; agitated for 24 ± 0.5 hours; eluate settled and
filtered over 0.45 μm membrane filter.
Eluate analysis
As I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Ba I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Cd I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Cr total I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Cu I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Hg I.S. EN 13370 rec. EN 1483 (CVAAS)
Mo I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Ni I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Pb I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Sb I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Se I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Zn I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Chloride I.S. EN 12506 rec. EN ISO 10304-part 1 (liquid chromatography of ions)
Fluoride I.S. EN 12506 rec. EN ISO 10304-part 1 (liquid chromatography of ions)
Sulphate I.S. EN 12506 rec. EN ISO 10304-part 1 (liquid chromatography of ions)
Phenol index I.S. EN 13370 rec. ISO 6439 (4-Aminoantipyrine spectrometic methods after distillation)* ( BY HPLC - Jones Env)
DOC I.S. EN 1484
TDS I.S. EN 15216
Compositional analysis
TOC I.S. EN 13137 Method B: carbonates removed with acid; TOC by combustion.
BTEX GC-FID
PCB7** I.S. EN 15308 analysis by GC-ECD.
Mineral oil I.S. EN 14039 C10 to C40 analysis by GC-FID.
PAH17*** I.S. EN 15527 PAH17 analysis by GC-MS
Metals I.S. EN 13657 - Aqua regia digestion: EN ISO 11885 ( ICP-OES)
Other
Dry matter
I.S. EN 14346 sample is dried to a constant mass in an oven at 105 ± 3 °C; Method B Water content by direct Karl-Fischer-
titration and either volumetric or coulometric detection.
LOI I.S. EN 15169 Difference in mass after heating in a furnace up to 550 ± 25 °C.
ANC CEN/TS 15364 Determined by amouns of acid or base needed to cover the pH range
Notes:
*If not suitable due to LOD, precision, etc., any other suitable method can be used, e.g. AFS, ICP-MS
**PCB-28, PCB-52, PCB-101, PCB-118, PCB-138, PCB-153 and PCB-180
Appendix - Methods used for WAC (2003/33/EC)
***Naphthalene, Acenaphthylene, Acenaphthene, Anthracene, Benzo(a)anthracene, Benzo(b)fluoranthene, Benzo(k)fluoranthene, Benzo(g,h,i)perylene,
Benzo(a)pyrene, Chrysene, Coronene, Dibenzo(a,h)anthracene, Fluorene, Fluoranthene, Indeno(1,2,3-c,d)pyrene, Phenanthrene and Pyrene.
QF-PM 3.1.8 v10 Please include all sections of this report if it is reproduced 18 of 18
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EPA Export 28-05-2019:04:59:40
Unit 3 Deeside Point
Zone 3
Deeside Industrial Park
Deeside
Causeway Geotech
Attention :
Date :
Your reference :
Our reference :
Location :
Date samples received :
Status :
Issue :
Colm Hurley
28th February, 2017
1
Exova Jones Environmental
CH5 2UA
Tel: +44 (0) 1244 833780
Fax: +44 (0) 1244 833781
8 Drumahiskey Road
Bainamore
Ballymoney
Co Antrim
BT53 7QL
Registered Address : Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian, EH28 8PL
Four samples were received for analysis on 30th January, 2017 of which four were scheduled for analysis. Please find attached our Test Report
which should be read with notes at the end of the report and should include all sections if reproduced. Interpretations and opinions are outside the
scope of any accreditation, and all results relate only to samples supplied.
All analysis is carried out on as received samples and reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected.
Phil Sommerton BSc
Project Manager
WOP 16-1239
Project Gemini
30th January, 2017
Final report
Compiled By:
Test Report 17/3119 Batch 1
QF-PM 3.1.1 v16Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 1 of 14
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Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3119
J E Sample No. 1-2 3-4 5-6 7-8
Sample ID WOP TP06/17 WOP TP06/17 WOP TP07/17 WOP TP08/17
Depth 0.75 1.50 0.50 1.00
COC No / misc
Containers V J V J V J V J
Sample Date 27/01/2017 27/01/2017 27/01/2017 27/01/2017
Sample Type Soil Soil Soil Soil
Batch Number 1 1 1 1
Date of Receipt 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Aluminium 8293 2604 2899 2334 <50 mg/kg TM30/PM15
Arsenic # 40.2 6.2 6.7 4.3 <0.5 mg/kg TM30/PM15
Barium # 55 17 16 15 <1 mg/kg TM30/PM15
Cadmium # 0.2 0.3 0.4 0.4 <0.1 mg/kg TM30/PM15
Chromium # 22.8 18.5 22.2 22.7 <0.5 mg/kg TM30/PM15
Copper # 10 4 8 7 <1 mg/kg TM30/PM15
Iron 23900 7366 7143 5925 <20 mg/kg TM30/PM15
Lead # 71 13 13 9 <5 mg/kg TM30/PM15
Mercury # <0.1 <0.1 <0.1 <0.1 <0.1 mg/kg TM30/PM15
Molybdenum # 0.8 1.5 1.3 1.9 <0.1 mg/kg TM30/PM15
Nickel # 36.6 10.6 16.0 14.8 <0.7 mg/kg TM30/PM15
Selenium # <1 <1 <1 <1 <1 mg/kg TM30/PM15
Zinc # 641 159 72 74 <5 mg/kg TM30/PM15
PAH MS
Naphthalene # <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Acenaphthylene <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Acenaphthene # <0.05 <0.05 <0.05 <0.05 <0.05 mg/kg TM4/PM8
Fluorene # <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Phenanthrene # <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Anthracene # <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Fluoranthene # <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Pyrene # <0.03 <0.03 <0.03 <0.03 <0.03 mg/kg TM4/PM8
Benzo(a)anthracene # <0.06 <0.06 <0.06 <0.06 <0.06 mg/kg TM4/PM8
Chrysene # <0.02 <0.02 <0.02 <0.02 <0.02 mg/kg TM4/PM8
Benzo(bk)fluoranthene # <0.07 <0.07 <0.07 <0.07 <0.07 mg/kg TM4/PM8
Benzo(a)pyrene # <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Indeno(123cd)pyrene # <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Dibenzo(ah)anthracene # <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Benzo(ghi)perylene # <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
Coronene <0.04 <0.04 <0.04 <0.04 <0.04 mg/kg TM4/PM8
PAH 17 Total <0.64 <0.64 <0.64 <0.64 <0.64 mg/kg TM4/PM8
Benzo(b)fluoranthene <0.05 <0.05 <0.05 <0.05 <0.05 mg/kg TM4/PM8
Benzo(k)fluoranthene <0.02 <0.02 <0.02 <0.02 <0.02 mg/kg TM4/PM8
PAH Surrogate % Recovery 102 116 115 111 <0 % TM4/PM8
Methyl Tertiary Butyl Ether # - <2 - - <2 ug/kg TM15/PM10
Benzene # - <3 - - <3 ug/kg TM15/PM10
Toluene # - 3 - - <3 ug/kg TM15/PM10
Ethylbenzene # - <3 - - <3 ug/kg TM15/PM10
p/m-Xylene # - <5 - - <5 ug/kg TM15/PM10
o-Xylene # - <3 - - <3 ug/kg TM15/PM10
Surrogate Recovery Toluene D8 - 93 - - <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene - 63 - - <0 % TM15/PM10
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
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EPA Export 28-05-2019:04:59:40
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3119
J E Sample No. 1-2 3-4 5-6 7-8
Sample ID WOP TP06/17 WOP TP06/17 WOP TP07/17 WOP TP08/17
Depth 0.75 1.50 0.50 1.00
COC No / misc
Containers V J V J V J V J
Sample Date 27/01/2017 27/01/2017 27/01/2017 27/01/2017
Sample Type Soil Soil Soil Soil
Batch Number 1 1 1 1
Date of Receipt 30/01/2017 30/01/2017 30/01/2017 30/01/2017
MTBE #
<5SV - <5 <5 <5 ug/kg TM31/PM12
Benzene #
<5SV - <5 <5 <5 ug/kg TM31/PM12
Toluene #
<5SV - <5 <5 <5 ug/kg TM31/PM12
Ethylbenzene #
<5SV - <5 <5 <5 ug/kg TM31/PM12
m/p-Xylene #
<5SV - <5 <5 <5 ug/kg TM31/PM12
o-Xylene #
<5SV - <5 <5 <5 ug/kg TM31/PM12
PCB 28 # - <5 - - <5 ug/kg TM17/PM8
PCB 52 # - <5 - - <5 ug/kg TM17/PM8
PCB 101 # - <5 - - <5 ug/kg TM17/PM8
PCB 118 # - <5 - - <5 ug/kg TM17/PM8
PCB 138 # - <5 - - <5 ug/kg TM17/PM8
PCB 153 # - <5 - - <5 ug/kg TM17/PM8
PCB 180 # - <5 - - <5 ug/kg TM17/PM8
Total 7 PCBs # - <35 - - <35 ug/kg TM17/PM8
Total Phenols HPLC - 0.38 - - <0.15 mg/kg TM26/PM21
Natural Moisture Content 5.2 5.5 5.6 6.5 <0.1 % PM4/PM0
Ammoniacal Nitrogen as N <0.6 3.3 <0.6 - <0.6 mg/kg TM38/PM20
Chloride # 52 50 21 - <2 mg/kg TM38/PM20
Hexavalent Chromium # <0.3 <0.3 <0.3 <0.3 <0.3 mg/kg TM38/PM20
Ortho Phosphate as PO4 <0.3 <0.3 <0.3 - <0.3 mg/kg TM38/PM20
Sulphate as SO4 (2:1 Ext) # 0.9224 0.1850 0.3027 - <0.0015 g/l TM38/PM20
Chromium III 22.8 18.5 22.2 22.7 <0.5 mg/kg NONE/NONE
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 3 of 14
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Client Name: SVOC Report : Solid
Reference:
Location:
Contact:
JE Job No.: 17/3119
J E Sample No. 3-4
Sample ID WOP TP06/17
Depth 1.50
COC No / misc
Containers V J
Sample Date 27/01/2017
Sample Type Soil
Batch Number 1
Date of Receipt 30/01/2017
SVOC MS
Phenols
2-Chlorophenol # <10 <10 ug/kg TM16/PM8
2-Methylphenol <10 <10 ug/kg TM16/PM8
2-Nitrophenol <10 <10 ug/kg TM16/PM8
2,4-Dichlorophenol # <10 <10 ug/kg TM16/PM8
2,4-Dimethylphenol <10 <10 ug/kg TM16/PM8
2,4,5-Trichlorophenol <10 <10 ug/kg TM16/PM8
2,4,6-Trichlorophenol <10 <10 ug/kg TM16/PM8
4-Chloro-3-methylphenol <10 <10 ug/kg TM16/PM8
4-Methylphenol <10 <10 ug/kg TM16/PM8
4-Nitrophenol <10 <10 ug/kg TM16/PM8
Pentachlorophenol <10 <10 ug/kg TM16/PM8
Phenol # <10 <10 ug/kg TM16/PM8
PAHs
2-Chloronaphthalene # <10 <10 ug/kg TM16/PM8
2-Methylnaphthalene # <10 <10 ug/kg TM16/PM8
Phthalates
Bis(2-ethylhexyl) phthalate <100 <100 ug/kg TM16/PM8
Butylbenzyl phthalate <100 <100 ug/kg TM16/PM8
Di-n-butyl phthalate <100 <100 ug/kg TM16/PM8
Di-n-Octyl phthalate <100 <100 ug/kg TM16/PM8
Diethyl phthalate <100 <100 ug/kg TM16/PM8
Dimethyl phthalate # <100 <100 ug/kg TM16/PM8
Other SVOCs
1,2-Dichlorobenzene <10 <10 ug/kg TM16/PM8
1,2,4-Trichlorobenzene # <10 <10 ug/kg TM16/PM8
1,3-Dichlorobenzene <10 <10 ug/kg TM16/PM8
1,4-Dichlorobenzene <10 <10 ug/kg TM16/PM8
2-Nitroaniline <10 <10 ug/kg TM16/PM8
2,4-Dinitrotoluene <10 <10 ug/kg TM16/PM8
2,6-Dinitrotoluene <10 <10 ug/kg TM16/PM8
3-Nitroaniline <10 <10 ug/kg TM16/PM8
4-Bromophenylphenylether # <10 <10 ug/kg TM16/PM8
4-Chloroaniline <10 <10 ug/kg TM16/PM8
4-Chlorophenylphenylether <10 <10 ug/kg TM16/PM8
4-Nitroaniline <10 <10 ug/kg TM16/PM8
Azobenzene <10 <10 ug/kg TM16/PM8
Bis(2-chloroethoxy)methane <10 <10 ug/kg TM16/PM8
Bis(2-chloroethyl)ether <10 <10 ug/kg TM16/PM8
Carbazole <10 <10 ug/kg TM16/PM8
Dibenzofuran # <10 <10 ug/kg TM16/PM8
Hexachlorobenzene <10 <10 ug/kg TM16/PM8
Hexachlorobutadiene # <10 <10 ug/kg TM16/PM8
Hexachlorocyclopentadiene <10 <10 ug/kg TM16/PM8
Hexachloroethane <10 <10 ug/kg TM16/PM8
Isophorone # <10 <10 ug/kg TM16/PM8
N-nitrosodi-n-propylamine # <10 <10 ug/kg TM16/PM8
Nitrobenzene # <10 <10 ug/kg TM16/PM8
Surrogate Recovery 2-Fluorobiphenyl 73 <0 % TM16/PM8
Surrogate Recovery p-Terphenyl-d14 97 <0 % TM16/PM8
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.3 v11Please include all sections of this report if it is reproduced
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Client Name: VOC Report : Solid
Reference:
Location:
Contact:
JE Job No.: 17/3119
J E Sample No. 3-4
Sample ID WOP TP06/17
Depth 1.50
COC No / misc
Containers V J
Sample Date 27/01/2017
Sample Type Soil
Batch Number 1
Date of Receipt 30/01/2017
VOC MS
Dichlorodifluoromethane <2 <2 ug/kg TM15/PM10
Methyl Tertiary Butyl Ether # <2 <2 ug/kg TM15/PM10
Chloromethane # <3 <3 ug/kg TM15/PM10
Vinyl Chloride <2 <2 ug/kg TM15_A/PM10
Bromomethane <1 <1 ug/kg TM15/PM10
Chloroethane # <2 <2 ug/kg TM15/PM10
Trichlorofluoromethane # <2 <2 ug/kg TM15/PM10
1,1-Dichloroethene (1,1 DCE) # <6 <6 ug/kg TM15/PM10
Dichloromethane (DCM) # 45 <30 ug/kg TM15/PM10
trans-1-2-Dichloroethene # <3 <3 ug/kg TM15/PM10
1,1-Dichloroethane # <3 <3 ug/kg TM15/PM10
cis-1-2-Dichloroethene # <3 <3 ug/kg TM15/PM10
2,2-Dichloropropane <4 <4 ug/kg TM15/PM10
Bromochloromethane # <3 <3 ug/kg TM15/PM10
Chloroform # <3 <3 ug/kg TM15/PM10
1,1,1-Trichloroethane # <3 <3 ug/kg TM15/PM10
1,1-Dichloropropene # <3 <3 ug/kg TM15/PM10
Carbon tetrachloride # <4 <4 ug/kg TM15/PM10
1,2-Dichloroethane # <4 <4 ug/kg TM15/PM10
Benzene # <3 <3 ug/kg TM15/PM10
Trichloroethene (TCE) # <3 <3 ug/kg TM15/PM10
1,2-Dichloropropane # <6 <6 ug/kg TM15/PM10
Dibromomethane # <3 <3 ug/kg TM15/PM10
Bromodichloromethane # <3 <3 ug/kg TM15/PM10
cis-1-3-Dichloropropene <4 <4 ug/kg TM15/PM10
Toluene # 3 <3 ug/kg TM15/PM10
trans-1-3-Dichloropropene <3 <3 ug/kg TM15/PM10
1,1,2-Trichloroethane # <3 <3 ug/kg TM15/PM10
Tetrachloroethene (PCE) # <3 <3 ug/kg TM15/PM10
1,3-Dichloropropane # <3 <3 ug/kg TM15/PM10
Dibromochloromethane # <3 <3 ug/kg TM15/PM10
1,2-Dibromoethane # <3 <3 ug/kg TM15/PM10
Chlorobenzene # <3 <3 ug/kg TM15/PM10
1,1,1,2-Tetrachloroethane <3 <3 ug/kg TM15/PM10
Ethylbenzene # <3 <3 ug/kg TM15/PM10
p/m-Xylene # <5 <5 ug/kg TM15/PM10
o-Xylene # <3 <3 ug/kg TM15/PM10
Styrene <3 <3 ug/kg TM15_A/PM10
Bromoform <3 <3 ug/kg TM15/PM10
Isopropylbenzene # <3 <3 ug/kg TM15/PM10
1,1,2,2-Tetrachloroethane # <3 <3 ug/kg TM15/PM10
Bromobenzene <2 <2 ug/kg TM15/PM10
1,2,3-Trichloropropane # <4 <4 ug/kg TM15/PM10
Propylbenzene # <4 <4 ug/kg TM15/PM10
2-Chlorotoluene <3 <3 ug/kg TM15/PM10
1,3,5-Trimethylbenzene # <3 <3 ug/kg TM15/PM10
4-Chlorotoluene <3 <3 ug/kg TM15/PM10
tert-Butylbenzene # <5 <5 ug/kg TM15/PM10
1,2,4-Trimethylbenzene # <6 <6 ug/kg TM15/PM10
sec-Butylbenzene # <4 <4 ug/kg TM15/PM10
4-Isopropyltoluene # <4 <4 ug/kg TM15/PM10
1,3-Dichlorobenzene # <4 <4 ug/kg TM15/PM10
1,4-Dichlorobenzene # <4 <4 ug/kg TM15/PM10
n-Butylbenzene # <4 <4 ug/kg TM15/PM10
1,2-Dichlorobenzene # <4 <4 ug/kg TM15/PM10
1,2-Dibromo-3-chloropropane # <4 <4 ug/kg TM15/PM10
1,2,4-Trichlorobenzene # <7 <7 ug/kg TM15/PM10
Hexachlorobutadiene <4 <4 ug/kg TM15/PM10
Naphthalene <27 <27 ug/kg TM15/PM10
1,2,3-Trichlorobenzene # <7 <7 ug/kg TM15/PM10
Surrogate Recovery Toluene D8 93 <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 63 <0 % TM15/PM10
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.4 v11Please include all sections of this report if it is reproduced
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Client Name:
Reference:
Location:
Contact:
Note:
J E
Job
No.
Batch Depth
J E
Sample
No.
Date Of
AnalysisAnalysis Result
17/3119 1 0.75 2 07/02/2017 General Description (Bulk Analysis) Soil/Stones
07/02/2017 Asbestos Fibres NAD
07/02/2017 Asbestos Fibres (2) NAD
07/02/2017 Asbestos ACM NAD
07/02/2017 Asbestos ACM (2) NAD
07/02/2017 Asbestos Type NAD
07/02/2017 Asbestos Type (2) NAD
07/02/2017 Asbestos Level Screen NAD
17/3119 1 0.50 6 07/02/2017 General Description (Bulk Analysis) Soil/Stones
07/02/2017 Asbestos Fibres NAD
07/02/2017 Asbestos Fibres (2) NAD
07/02/2017 Asbestos ACM NAD
07/02/2017 Asbestos ACM (2) NAD
07/02/2017 Asbestos Type NAD
07/02/2017 Asbestos Type (2) NAD
07/02/2017 Asbestos Level Screen NAD
WOP TP07/17
Ryan Butterworth
Asbestos Team Leader
Sample ID
WOP TP06/17
Analysis was carried out in accordance with our documented in-house methods PM042 and TM065 and HSG 248 by Stereo and Polarised Light Microscopy using Dispersion
Staining Techniques and is covered by our UKAS accreditation. Samples are retained for not less than 6 months from the date of analysis unless specifically requested.
Opinions, including ACM type and Asbestos level, lie outside the scope of our UKAS accreditation.
Where the sample is not taken by a Jones Environmental Laboratory consultant, Jones Environmental Laboratory cannot be responsible for inaccurate or unrepresentative
sampling.
Signed on behalf of Jones Environmental Laboratory:
Exova Jones Environmental Asbestos Analysis
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
QF-PM 3.1.15 v10 Please include all sections of this report if it is reproduced 6 of 14
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Notification of Deviating Samples
J E
Job
No.
Batch Depth J E Sample
No.Analysis Reason
Please note that only samples that are deviating are mentioned in this report. If no samples are listed it is because none were deviating.
Only analyses which are accredited are recorded as deviating if set criteria are not met.
Exova Jones Environmental
WOP 16-1239
Project Gemini
Colm HurleyContact:
Sample ID
Client Name: Causeway Geotech
Reference:
Location:
No deviating sample report results for job 17/3119
QF-PM 3.1.11 v3 Please include all sections of this report if it is reproduced 7 of 14
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JE Job No.:
SOILS
DEVIATING SAMPLES
SURROGATES
DILUTIONS
BLANKS
NOTE
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
Please note we are not a UK Drinking Water Inspectorate (DWI) Approved Laboratory .
If you have not already done so, please send us a purchase order if this is required by your company.
Samples must be received in a condition appropriate to the requested analyses. All samples should be submitted to the laboratory in suitable
containers with sufficient ice packs to sustain an appropriate temperature for the requested analysis. If this is not the case you will be informed and
any test results that may be compromised highlighted on your deviating samples report.
ISO17025 accreditation applies to surface water and groundwater and usually one other matrix which is analysis specific, any other liquids are
outside our scope of accreditation.
As surface waters require different sample preparation to groundwaters the laboratory must be informed of the water type when submitting samples.
Where appropriate please make sure that our detection limits are suitable for your needs, if they are not, please notify us immediately.
Data is only reported if the laboratory is confident that the data is a true reflection of the samples analysed. Data is only reported as accredited when
all the requirements of our Quality System have been met. In certain circumstances where all the requirements of the Quality System have not been
met, for instance if the associated AQC has failed, the reason is fully investigated and documented. The sample data is then evaluated alongside
the other quality control checks performed during analysis to determine its suitability. Following this evaluation, provided the sample results have not
been effected, the data is reported but accreditation is removed. It is a UKAS requirement for data not reported as accredited to be considered
indicative only, but this does not mean the data is not valid.
Where possible, and if requested, samples will be re-extracted and a revised report issued with accredited results. Please do not hesitate to contact
the laboratory if further details are required of the circumstances which have led to the removal of accreditation.
Where an MCERTS report has been requested, you will be notified within 48 hours of any samples that have been identified as being outside our
MCERTS scope. As validation has been performed on clay, sand and loam, only samples that are predominantly these matrices, or combinations
of them will be within our MCERTS scope. If samples are not one of a combination of the above matrices they will not be marked as MCERTS
accredited.
Negative Neutralization Potential (NP) values are obtained when the volume of NaOH (0.1N) titrated (pH 8.3) is greater than the volume of HCl (1N)
to reduce the pH of the sample to 2.0 - 2.5. Any negative NP values are corrected to 0.
Where a CEN 10:1 ZERO Headspace VOC test has been carried out, a 10:1 ratio of water to wet (as received) soil has been used.
All samples will be discarded one month after the date of reporting, unless we are instructed to the contrary.
% Asbestos in Asbestos Containing Materials (ACMs) is determined by reference to HSG 264 The Survey Guide - Appendix 2 : ACMs in buildings
listed in order of ease of fibre release.
All analysis is reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected. Samples are dried at 35°C ±5°C unless
otherwise stated. Moisture content for CEN Leachate tests are dried at 105°C ±5°C.
Surrogate compounds are added during the preparation process to monitor recovery of analytes. However low recovery in soils is often due to peat,
clay or other organic rich matrices. For waters this can be due to oxidants, surfactants, organic rich sediments or remediation fluids. Acceptable
limits for most organic methods are 70 - 130% and for VOCs are 50 - 150%. When surrogate recoveries are outside the performance criteria but
the associated AQC passes this is assumed to be due to matrix effect. Results are not surrogate corrected.
A dilution suffix indicates a dilution has been performed and the reported result takes this into account. No further calculation is required.
NOTES TO ACCOMPANY ALL SCHEDULES AND REPORTS
Please note we are only MCERTS accredited (UK soils only) for sand, loam and clay and any other matrix is outside our scope of accreditation.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
17/3119
WATERS
Where analytes have been found in the blank, the sample will be treated in accordance with our laboratory procedure for dealing with contaminated
blanks.
It is assumed that you have taken representative samples on site and require analysis on a representative subsample. Stones will generally be
included unless we are requested to remove them.
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
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JE Job No.:
#
SA
B
DR
M
NA
NAD
ND
NDP
SS
SV
W
+
++
*
AD
CO
LOD/LOR
ME
NFD
BS
LB
N
TB
OC
Dilution required.
Analysis subcontracted to a Jones Environmental approved laboratory.
Matrix Effect
Blank Sample
Client Sample
Trip Blank Sample
AQC Sample
Suspected carry over
Limit of Detection (Limit of Reporting) in line with ISO 17025 and MCERTS
Samples are dried at 35°C ±5°C
17/3119
AQC failure, accreditation has been removed from this result, if appropriate, see 'Note' on previous page.
Calibrated against a single substance
Not applicable
No Asbestos Detected.
No Determination Possible
Indicates analyte found in associated method blank.
None Detected (usually refers to VOC and/SVOC TICs).
ISO17025 (SANAS) accredited - South Africa.
MCERTS accredited.
Outside Calibration Range
No Fibres Detected
Result outside calibration range, results should be considered as indicative only and are not accredited.
Results expressed on as received basis.
Surrogate recovery outside performance criteria. This may be due to a matrix effect.
ISO17025 (UKAS) accredited - UK.
ABBREVIATIONS and ACRONYMS USED
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
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JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required.
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR
TM5/TM36
TM005: Modified USEPA 8015B. Determination of solvent Extractable Petroleum
Hydrocarbons (EPH) including column fractionation in the carbon range of C10-35 into
aliphatic and aromatic fractions by GC-FID.
TM036: Modified USEPA 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C5-10 by headspace GC-FID. Including determination of
BTEX and calculation of Aliphatic fractions.
PM12/PM16
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis./Fractionation into aliphatic and aromatic fractions using a Rapid
Trace SPE.
AR Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. Yes AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 10 of 14
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JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM17Modified US EPA method 8270. Determination of specific Polychlorinated Biphenyl
congeners by GC-MS.PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM20Modified BS 1377-3: 1990/USEPA 160.3 Gravimetric determination of Total Dissolved
Solids/Total SolidsPM0 No preparation is required. Yes AR Yes
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.Yes AD Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM0 No preparation is required. AR Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM21
As received solid or water samples are extracted in Methanol: Sodium Hydroxide (0.1M
NaOH) (60:40) by orbital shaker.AR Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.Yes AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM17
Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.Yes AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 11 of 14
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JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AR Yes
TM60
Modified USEPA 9060. Determination of TOC by calculation from Total Carbon and
Inorganic Carbon using a TOC analyser, the carbon in the sample is converted to CO2
and then passed through a non-dispersive infrared gas analyser (NDIR).
PM0 No preparation is required. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 12 of 14
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EPA Export 28-05-2019:04:59:40
JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM61Modified US EPA methods 245.7 and 200.7. Determination of Mercury by Cold Vapour
Atomic Fluorescence. PM38
Samples are brominated to reduce all mercury compounds to Mercury (II) which is
analysed using method TM061.Yes AR Yes
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.AR
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.Yes AR
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM0 No preparation is required. AR Yes
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM11 Extraction of as received solid samples using one part solid to 2.5 parts deionised water. Yes AR No
TM173 Analysis of fluoride by ISE (Ion Selective Electrode) using modified ISE method 340.2 PM0 No preparation is required. AR Yes
NONE No Method Code NONE No Method Code AR Yes
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.AR
NONE No Method Code PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.AR
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 13 of 14
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EPA Export 28-05-2019:04:59:40
JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM15_AModified USEPA 8260. Quantitative Determination of Volatile Organic Compounds, Vinyl
Chloride & Styrene by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 14 of 14
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EPA Export 28-05-2019:04:59:40
Unit 3 Deeside Point
Zone 3
Deeside Industrial Park
Deeside
Causeway Geotech
Attention :
Date :
Your reference :
Our reference :
Location :
Date samples received :
Status :
Issue :
Colm Hurley
28th February, 2017
1
Exova Jones Environmental
CH5 2UA
Tel: +44 (0) 1244 833780
Fax: +44 (0) 1244 833781
8 Drumahiskey Road
Bainamore
Ballymoney
Co Antrim
BT53 7QL
Registered Address : Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian, EH28 8PL
One sample was received for analysis on 30th January, 2017 of which one were scheduled for analysis. Please find attached our Test Report
which should be read with notes at the end of the report and should include all sections if reproduced. Interpretations and opinions are outside the
scope of any accreditation, and all results relate only to samples supplied.
All analysis is carried out on as received samples and reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected.
Where Waste Acceptance Criteria Suite (EC Decision of 19 December 2002 (2003/33/EC)) has been requested, all analyses have been performed
using the relevant EN methods where they exist.
Phil Sommerton BSc
Project Manager
WOP 16-1239
Project Gemini
30th January, 2017
Final report
Compiled By:
Test Report 17/3119 Batch 1
QF-PM 3.1.1 v16Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 1 of 17
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EPA Export 28-05-2019:04:59:40
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3119
J E Sample No. 9-10
Sample ID WOP TP06/17
Depth 0.50-1.50
COC No / misc
Containers V J
Sample Date 27/01/2017
Sample Type Soil
Batch Number 1
Date of Receipt 30/01/2017
Antimony <1 <1 mg/kg TM30/PM15
Arsenic # 5.9 <0.5 mg/kg TM30/PM15
Barium # 15 <1 mg/kg TM30/PM15
Cadmium # 0.3 <0.1 mg/kg TM30/PM15
Chromium # 88.5 <0.5 mg/kg TM30/PM15
Copper # 5 <1 mg/kg TM30/PM15
Lead # 11 <5 mg/kg TM30/PM15
Mercury # <0.1 <0.1 mg/kg TM30/PM15
Molybdenum # 6.1 <0.1 mg/kg TM30/PM15
Nickel # 13.0 <0.7 mg/kg TM30/PM15
Selenium # <1 <1 mg/kg TM30/PM15
Zinc # 87 <5 mg/kg TM30/PM15
PAH MS
Naphthalene # <0.04 <0.04 mg/kg TM4/PM8
Acenaphthylene <0.03 <0.03 mg/kg TM4/PM8
Acenaphthene # <0.05 <0.05 mg/kg TM4/PM8
Fluorene # <0.04 <0.04 mg/kg TM4/PM8
Phenanthrene # <0.03 <0.03 mg/kg TM4/PM8
Anthracene # <0.04 <0.04 mg/kg TM4/PM8
Fluoranthene # <0.03 <0.03 mg/kg TM4/PM8
Pyrene # <0.03 <0.03 mg/kg TM4/PM8
Benzo(a)anthracene # <0.06 <0.06 mg/kg TM4/PM8
Chrysene # <0.02 <0.02 mg/kg TM4/PM8
Benzo(bk)fluoranthene # <0.07 <0.07 mg/kg TM4/PM8
Benzo(a)pyrene # <0.04 <0.04 mg/kg TM4/PM8
Indeno(123cd)pyrene # <0.04 <0.04 mg/kg TM4/PM8
Dibenzo(ah)anthracene # <0.04 <0.04 mg/kg TM4/PM8
Benzo(ghi)perylene # <0.04 <0.04 mg/kg TM4/PM8
Coronene <0.04 <0.04 mg/kg TM4/PM8
PAH 6 Total # <0.22 <0.22 mg/kg TM4/PM8
PAH 17 Total <0.64 <0.64 mg/kg TM4/PM8
Benzo(b)fluoranthene <0.05 <0.05 mg/kg TM4/PM8
Benzo(k)fluoranthene <0.02 <0.02 mg/kg TM4/PM8
Benzo(j)fluoranthene <1 <1 mg/kg TM4/PM8
PAH Surrogate % Recovery 115 <0 % TM4/PM8
Mineral Oil (C10-C40) <30 <30 mg/kg TM5/PM16
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 2 of 17
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EPA Export 28-05-2019:04:59:40
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3119
J E Sample No. 9-10
Sample ID WOP TP06/17
Depth 0.50-1.50
COC No / misc
Containers V J
Sample Date 27/01/2017
Sample Type Soil
Batch Number 1
Date of Receipt 30/01/2017
TPH CWG
Aliphatics
>C5-C6 #
<0.1SV <0.1 mg/kg TM36/PM12
>C6-C8 #
<0.1SV <0.1 mg/kg TM36/PM12
>C8-C10 <0.1SV <0.1 mg/kg TM36/PM12
>C10-C12 # <0.2 <0.2 mg/kg TM5/PM16
>C12-C16 # <4 <4 mg/kg TM5/PM16
>C16-C21 # <7 <7 mg/kg TM5/PM16
>C21-C35 # <7 <7 mg/kg TM5/PM16
>C35-C40 <7 <7 mg/kg TM5/PM16
Total aliphatics C5-40 <26 <26 mg/kg TM5/TM36/PM12/PM16
>C6-C10 <0.1SV <0.1 mg/kg TM36/PM12
>C10-C25 <10 <10 mg/kg TM5/PM16
>C25-C35 <10 <10 mg/kg TM5/PM16
Aromatics
>C5-EC7 #
<0.1SV <0.1 mg/kg TM36/PM12
>EC7-EC8 #
<0.1SV <0.1 mg/kg TM36/PM12
>EC8-EC10 #
<0.1SV <0.1 mg/kg TM36/PM12
>EC10-EC12 # <0.2 <0.2 mg/kg TM5/PM16
>EC12-EC16 # <4 <4 mg/kg TM5/PM16
>EC16-EC21 # <7 <7 mg/kg TM5/PM16
>EC21-EC35 # <7 <7 mg/kg TM5/PM16
>EC35-EC40 <7 <7 mg/kg TM5/PM16
Total aromatics C5-40 <26 <26 mg/kg TM5/TM36/PM12/PM16
Total aliphatics and aromatics(C5-40) <52 <52 mg/kg TM5/TM36/PM12/PM16
>EC6-EC10 #
<0.1SV <0.1 mg/kg TM36/PM12
>EC10-EC25 <10 <10 mg/kg TM5/PM16
>EC25-EC35 <10 <10 mg/kg TM5/PM16
MTBE #
<5SV <5 ug/kg TM31/PM12
Benzene #
<5SV <5 ug/kg TM31/PM12
Toluene #
<5SV <5 ug/kg TM31/PM12
Ethylbenzene #
<5SV <5 ug/kg TM31/PM12
m/p-Xylene #
<5SV <5 ug/kg TM31/PM12
o-Xylene #
<5SV <5 ug/kg TM31/PM12
PCB 28 # <5 <5 ug/kg TM17/PM8
PCB 52 # <5 <5 ug/kg TM17/PM8
PCB 101 # <5 <5 ug/kg TM17/PM8
PCB 118 # <5 <5 ug/kg TM17/PM8
PCB 138 # <5 <5 ug/kg TM17/PM8
PCB 153 # <5 <5 ug/kg TM17/PM8
PCB 180 # <5 <5 ug/kg TM17/PM8
Total 7 PCBs # <35 <35 ug/kg TM17/PM8
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 3 of 17
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EPA Export 28-05-2019:04:59:41
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3119
J E Sample No. 9-10
Sample ID WOP TP06/17
Depth 0.50-1.50
COC No / misc
Containers V J
Sample Date 27/01/2017
Sample Type Soil
Batch Number 1
Date of Receipt 30/01/2017
Natural Moisture Content 5.9 <0.1 % PM4/PM0
Moisture Content (% Wet Weight) 5.5 <0.1 % PM4/PM0
Hexavalent Chromium # <0.3 <0.3 mg/kg TM38/PM20
Chromium III 88.5 <0.5 mg/kg NONE/NONE
Total Organic Carbon # 0.44 <0.02 % TM21/PM24
pH # 7.80 <0.01 pH units TM73/PM11
Mass of raw test portion 0.1 kg NONE/PM17
Mass of dried test portion 0.09 kg NONE/PM17
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 4 of 17
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EPA Export 28-05-2019:04:59:41
Client Name: Report : CEN 10:1 1 Batch
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3119
J E Sample No. 9-10
Sample ID WOP TP06/17
Depth 0.50-1.50
COC No / misc
Containers V J
Sample Date 27/01/2017
Sample Type Soil
Batch Number 1
Date of Receipt 30/01/2017
Dissolved Antimony # <0.002 <0.002 mg/l TM30/PM17
Dissolved Antimony (A10) # <0.02 <0.02 mg/kg TM30/PM17
Dissolved Arsenic # <0.0025 <0.0025 mg/l TM30/PM17
Dissolved Arsenic (A10) # <0.025 <0.025 mg/kg TM30/PM17
Dissolved Barium # 0.013 <0.003 mg/l TM30/PM17
Dissolved Barium (A10) # 0.13 <0.03 mg/kg TM30/PM17
Dissolved Cadmium # <0.0005 <0.0005 mg/l TM30/PM17
Dissolved Cadmium (A10) # <0.005 <0.005 mg/kg TM30/PM17
Dissolved Chromium # <0.0015 <0.0015 mg/l TM30/PM17
Dissolved Chromium (A10) # <0.015 <0.015 mg/kg TM30/PM17
Dissolved Copper # <0.007 <0.007 mg/l TM30/PM17
Dissolved Copper (A10) # <0.07 <0.07 mg/kg TM30/PM17
Dissolved Lead # <0.005 <0.005 mg/l TM30/PM17
Dissolved Lead (A10) # <0.05 <0.05 mg/kg TM30/PM17
Dissolved Molybdenum # 0.004 <0.002 mg/l TM30/PM17
Dissolved Molybdenum (A10) # 0.04 <0.02 mg/kg TM30/PM17
Dissolved Nickel # <0.002 <0.002 mg/l TM30/PM17
Dissolved Nickel (A10) # <0.02 <0.02 mg/kg TM30/PM17
Dissolved Selenium # <0.003 <0.003 mg/l TM30/PM17
Dissolved Selenium (A10) # <0.03 <0.03 mg/kg TM30/PM17
Dissolved Zinc # 0.004 <0.003 mg/l TM30/PM17
Dissolved Zinc (A10) # 0.04 <0.03 mg/kg TM30/PM17
Mercury Dissolved by CVAF # <0.00001 <0.00001 mg/l TM61/PM38
Mercury Dissolved by CVAF # <0.0001 <0.0001 mg/kg TM61/PM38
Phenol <0.01 <0.01 mg/l TM26/PM0
Phenol <0.1 <0.1 mg/kg TM26/PM0
Fluoride <0.3 <0.3 mg/l TM173/PM0
Fluoride <3 <3 mg/kg TM173/PM0
Sulphate # 88.12 <0.05 mg/l TM38/PM0
Sulphate # 881.2 <0.5 mg/kg TM38/PM0
Chloride # 1.0 <0.3 mg/l TM38/PM0
Chloride # 10 <3 mg/kg TM38/PM0
Leachant Volume 0.89 l NONE/PM17
Eluate Volume 0.82 l NONE/PM17
Dissolved Organic Carbon <2 <2 mg/l TM60/PM0
Dissolved Organic Carbon <20 <20 mg/kg TM60/PM0
pH 8.51 <0.01 pH units TM73/PM0
Total Dissolved Solids # 177 <35 mg/l TM20/PM0
Total Dissolved Solids # 1770 <350 mg/kg TM20/PM0
Project Gemini
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
WOP 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 5 of 17
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EPA Export 28-05-2019:04:59:41
Mass of sample taken (kg) 0.1 Dry Matter Content Ratio (%) = 90.0
Mass of dry sample (kg) = 0.09 Leachant Volume (l) 0.89
Particle Size <4mm = >95% Eluate Volume (l) 0.82
JEFL Job No
Sample No
Client Sample No
Depth/Other
Sample Date
Batch No
Solid Waste Analysis
Total Organic Carbon (%) 0.44 3 5 6
Sum of BTEX (mg/kg) <0.025 6 - -
Sum of 7 PCBs (mg/kg) <0.035 1 - -
Mineral Oil (mg/kg) <30 500 - -
PAH Sum of 6 (mg/kg) <0.22 - - -
PAH Sum of 17 (mg/kg) <0.64 100 - -
10:1
concn
leached
A10
mg/kg
Arsenic <0.025 0.5 2 25
Barium 0.13 20 100 300
Cadmium <0.005 0.04 1 5
Chromium <0.015 0.5 10 70
Copper <0.07 2 50 100
Mercury <0.0001 0.01 0.2 2
Molybdenum 0.04 0.5 10 30
Nickel <0.02 0.4 10 40
Lead <0.05 0.5 10 50
Antimony <0.02 0.06 0.7 5
Selenium <0.03 0.1 0.5 7
Zinc 0.04 4 50 200
Chloride 10 800 15000 25000
Fluoride <3 10 150 500
Sulphate as SO4 881.2 1000 20000 50000
Total Dissolved Solids 1770 4000 60000 100000
Phenol <0.1 1 - -
Dissolved Organic Carbon <20 500 800 1000
27/01/2017
1
Eluate Analysis
Limit values for compliance
leaching test using
BS EN 12457-2 at L/S 10 l/kg
mg/kg
Exova Jones Environmental EN-12457-2 Result Report
17/3119 Landfill Waste Acceptance
Criteria Limits 10
WOP TP06/17
InertStable
Non-reactiveHazardous
0.50-1.50
QF-PM 3.1.18 v1Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 6 of 17
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EPA Export 28-05-2019:04:59:41
EPH Interpretation Report
Matrix : Solid
J E
Job
No.
Batch Depth J E Sample
No.EPH Interpretation
17/3119 1 0.50-1.50 9-10 No interpretation possible
Contact: Colm Hurley
Sample ID
WOP TP06/17
Client Name: Causeway Geotech
Reference: WOP 16-1239
Location: Project Gemini
Exova Jones Environmental
QF-PM 3.1.8 v10 Please include all sections of this report if it is reproduced 7 of 17
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EPA Export 28-05-2019:04:59:41
Client Name:
Reference:
Location:
Contact:
Note:
J E
Job
No.
Batch Depth
J E
Sample
No.
Date Of
AnalysisAnalysis Result
17/3119 1 0.50-1.50 10 07/02/2017 General Description (Bulk Analysis) Soil/Stones
07/02/2017 Asbestos Fibres NAD
07/02/2017 Asbestos Fibres (2) NAD
07/02/2017 Asbestos ACM NAD
07/02/2017 Asbestos ACM (2) NAD
07/02/2017 Asbestos Type NAD
07/02/2017 Asbestos Type (2) NAD
07/02/2017 Asbestos Level Screen NAD
Ryan Butterworth
Asbestos Team Leader
Sample ID
WOP TP06/17
Analysis was carried out in accordance with our documented in-house methods PM042 and TM065 and HSG 248 by Stereo and Polarised Light Microscopy using Dispersion
Staining Techniques and is covered by our UKAS accreditation. Samples are retained for not less than 6 months from the date of analysis unless specifically requested.
Opinions, including ACM type and Asbestos level, lie outside the scope of our UKAS accreditation.
Where the sample is not taken by a Jones Environmental Laboratory consultant, Jones Environmental Laboratory cannot be responsible for inaccurate or unrepresentative
sampling.
Signed on behalf of Jones Environmental Laboratory:
Exova Jones Environmental Asbestos Analysis
Causeway Geotech
WOP 16-1239
Project Gemini
Colm Hurley
QF-PM 3.1.15 v10 Please include all sections of this report if it is reproduced 8 of 17
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EPA Export 28-05-2019:04:59:41
Notification of Deviating Samples
J E
Job
No.
Batch Depth J E Sample
No.Analysis Reason
Please note that only samples that are deviating are mentioned in this report. If no samples are listed it is because none were deviating.
Only analyses which are accredited are recorded as deviating if set criteria are not met.
Exova Jones Environmental
WOP 16-1239
Project Gemini
Colm HurleyContact:
Sample ID
Client Name: Causeway Geotech
Reference:
Location:
No deviating sample report results for job 17/3119
QF-PM 3.1.11 v3 Please include all sections of this report if it is reproduced 9 of 17
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EPA Export 28-05-2019:04:59:41
JE Job No.:
SOILS
DEVIATING SAMPLES
SURROGATES
DILUTIONS
BLANKS
NOTE
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
Please note we are not a UK Drinking Water Inspectorate (DWI) Approved Laboratory .
If you have not already done so, please send us a purchase order if this is required by your company.
Samples must be received in a condition appropriate to the requested analyses. All samples should be submitted to the laboratory in suitable
containers with sufficient ice packs to sustain an appropriate temperature for the requested analysis. If this is not the case you will be informed and
any test results that may be compromised highlighted on your deviating samples report.
ISO17025 accreditation applies to surface water and groundwater and usually one other matrix which is analysis specific, any other liquids are
outside our scope of accreditation.
As surface waters require different sample preparation to groundwaters the laboratory must be informed of the water type when submitting samples.
Where appropriate please make sure that our detection limits are suitable for your needs, if they are not, please notify us immediately.
Data is only reported if the laboratory is confident that the data is a true reflection of the samples analysed. Data is only reported as accredited when
all the requirements of our Quality System have been met. In certain circumstances where all the requirements of the Quality System have not been
met, for instance if the associated AQC has failed, the reason is fully investigated and documented. The sample data is then evaluated alongside
the other quality control checks performed during analysis to determine its suitability. Following this evaluation, provided the sample results have not
been effected, the data is reported but accreditation is removed. It is a UKAS requirement for data not reported as accredited to be considered
indicative only, but this does not mean the data is not valid.
Where possible, and if requested, samples will be re-extracted and a revised report issued with accredited results. Please do not hesitate to contact
the laboratory if further details are required of the circumstances which have led to the removal of accreditation.
Where an MCERTS report has been requested, you will be notified within 48 hours of any samples that have been identified as being outside our
MCERTS scope. As validation has been performed on clay, sand and loam, only samples that are predominantly these matrices, or combinations
of them will be within our MCERTS scope. If samples are not one of a combination of the above matrices they will not be marked as MCERTS
accredited.
Negative Neutralization Potential (NP) values are obtained when the volume of NaOH (0.1N) titrated (pH 8.3) is greater than the volume of HCl (1N)
to reduce the pH of the sample to 2.0 - 2.5. Any negative NP values are corrected to 0.
Where a CEN 10:1 ZERO Headspace VOC test has been carried out, a 10:1 ratio of water to wet (as received) soil has been used.
All samples will be discarded one month after the date of reporting, unless we are instructed to the contrary.
% Asbestos in Asbestos Containing Materials (ACMs) is determined by reference to HSG 264 The Survey Guide - Appendix 2 : ACMs in buildings
listed in order of ease of fibre release.
All analysis is reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected. Samples are dried at 35°C ±5°C unless
otherwise stated. Moisture content for CEN Leachate tests are dried at 105°C ±5°C.
Surrogate compounds are added during the preparation process to monitor recovery of analytes. However low recovery in soils is often due to peat,
clay or other organic rich matrices. For waters this can be due to oxidants, surfactants, organic rich sediments or remediation fluids. Acceptable
limits for most organic methods are 70 - 130% and for VOCs are 50 - 150%. When surrogate recoveries are outside the performance criteria but
the associated AQC passes this is assumed to be due to matrix effect. Results are not surrogate corrected.
A dilution suffix indicates a dilution has been performed and the reported result takes this into account. No further calculation is required.
NOTES TO ACCOMPANY ALL SCHEDULES AND REPORTS
Please note we are only MCERTS accredited (UK soils only) for sand, loam and clay and any other matrix is outside our scope of accreditation.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
17/3119
WATERS
Where analytes have been found in the blank, the sample will be treated in accordance with our laboratory procedure for dealing with contaminated
blanks.
It is assumed that you have taken representative samples on site and require analysis on a representative subsample. Stones will generally be
included unless we are requested to remove them.
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 10 of 17
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JE Job No.:
#
SA
B
DR
M
NA
NAD
ND
NDP
SS
SV
W
+
++
*
AD
CO
LOD/LOR
ME
NFD
BS
LB
N
TB
OC
Dilution required.
Analysis subcontracted to a Jones Environmental approved laboratory.
Matrix Effect
Blank Sample
Client Sample
Trip Blank Sample
AQC Sample
Suspected carry over
Limit of Detection (Limit of Reporting) in line with ISO 17025 and MCERTS
Samples are dried at 35°C ±5°C
17/3119
AQC failure, accreditation has been removed from this result, if appropriate, see 'Note' on previous page.
Calibrated against a single substance
Not applicable
No Asbestos Detected.
No Determination Possible
Indicates analyte found in associated method blank.
None Detected (usually refers to VOC and/SVOC TICs).
ISO17025 (SANAS) accredited - South Africa.
MCERTS accredited.
Outside Calibration Range
No Fibres Detected
Result outside calibration range, results should be considered as indicative only and are not accredited.
Results expressed on as received basis.
Surrogate recovery outside performance criteria. This may be due to a matrix effect.
ISO17025 (UKAS) accredited - UK.
ABBREVIATIONS and ACRONYMS USED
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 11 of 17
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JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required.
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. AR
TM5/TM36
TM005: Modified USEPA 8015B. Determination of solvent Extractable Petroleum
Hydrocarbons (EPH) including column fractionation in the carbon range of C10-35 into
aliphatic and aromatic fractions by GC-FID.
TM036: Modified USEPA 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C5-10 by headspace GC-FID. Including determination of
BTEX and calculation of Aliphatic fractions.
PM12/PM16
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis./Fractionation into aliphatic and aromatic fractions using a Rapid
Trace SPE.
AR Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. Yes AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 12 of 17
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JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM17Modified US EPA method 8270. Determination of specific Polychlorinated Biphenyl
congeners by GC-MS.PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM20Modified BS 1377-3: 1990/USEPA 160.3 Gravimetric determination of Total Dissolved
Solids/Total SolidsPM0 No preparation is required. Yes AR Yes
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.Yes AD Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM0 No preparation is required. AR Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM21
As received solid or water samples are extracted in Methanol: Sodium Hydroxide (0.1M
NaOH) (60:40) by orbital shaker.AR Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.Yes AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM17
Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.Yes AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 13 of 17
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JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM31Modified USEPA 8015B. Determination of Methyltertbutylether, Benzene, Toluene,
Ethylbenzene and Xylene by headspace GC-FID.PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AR Yes
TM60
Modified USEPA 9060. Determination of TOC by calculation from Total Carbon and
Inorganic Carbon using a TOC analyser, the carbon in the sample is converted to CO2
and then passed through a non-dispersive infrared gas analyser (NDIR).
PM0 No preparation is required. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 14 of 17
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EPA Export 28-05-2019:04:59:41
JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM61Modified US EPA methods 245.7 and 200.7. Determination of Mercury by Cold Vapour
Atomic Fluorescence. PM38
Samples are brominated to reduce all mercury compounds to Mercury (II) which is
analysed using method TM061.Yes AR Yes
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.AR
TM65 Asbestos Bulk Identification method based on HSG 248. PM42Solid samples undergo a thorough visual inspection for asbestos fibres prior to asbestos
identification using TM065.Yes AR
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM0 No preparation is required. AR Yes
TM73Modified US EPA methods 150.1 and 9045D. Determination of pH by Metrohm
automated probe analyser.PM11 Extraction of as received solid samples using one part solid to 2.5 parts deionised water. Yes AR No
TM173 Analysis of fluoride by ISE (Ion Selective Electrode) using modified ISE method 340.2 PM0 No preparation is required. AR Yes
NONE No Method Code NONE No Method Code AR Yes
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.AR
NONE No Method Code PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.AR
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 15 of 17
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EPA Export 28-05-2019:04:59:41
JE Job No: 17/3119
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM15_AModified USEPA 8260. Quantitative Determination of Volatile Organic Compounds, Vinyl
Chloride & Styrene by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 16 of 17
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Leachate tests
10l/kg; 4mmI.S. EN 12457-2:2002 Specified particle size; water added to L/S ratio; capped; agitated for 24 ± 0.5 hours; eluate settled and
filtered over 0.45 μm membrane filter.
Eluate analysis
As I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Ba I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Cd I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Cr total I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Cu I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Hg I.S. EN 13370 rec. EN 1483 (CVAAS)
Mo I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Ni I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Pb I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Sb I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Se I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Zn I.S. EN 12506 : EN ISO 11885 (ICP-OES)
Chloride I.S. EN 12506 rec. EN ISO 10304-part 1 (liquid chromatography of ions)
Fluoride I.S. EN 12506 rec. EN ISO 10304-part 1 (liquid chromatography of ions)
Sulphate I.S. EN 12506 rec. EN ISO 10304-part 1 (liquid chromatography of ions)
Phenol index I.S. EN 13370 rec. ISO 6439 (4-Aminoantipyrine spectrometic methods after distillation)* ( BY HPLC - Jones Env)
DOC I.S. EN 1484
TDS I.S. EN 15216
Compositional analysis
TOC I.S. EN 13137 Method B: carbonates removed with acid; TOC by combustion.
BTEX GC-FID
PCB7** I.S. EN 15308 analysis by GC-ECD.
Mineral oil I.S. EN 14039 C10 to C40 analysis by GC-FID.
PAH17*** I.S. EN 15527 PAH17 analysis by GC-MS
Metals I.S. EN 13657 - Aqua regia digestion: EN ISO 11885 ( ICP-OES)
Other
Dry matter
I.S. EN 14346 sample is dried to a constant mass in an oven at 105 ± 3 °C; Method B Water content by direct Karl-Fischer-
titration and either volumetric or coulometric detection.
LOI I.S. EN 15169 Difference in mass after heating in a furnace up to 550 ± 25 °C.
ANC CEN/TS 15364 Determined by amouns of acid or base needed to cover the pH range
Notes:
*If not suitable due to LOD, precision, etc., any other suitable method can be used, e.g. AFS, ICP-MS
**PCB-28, PCB-52, PCB-101, PCB-118, PCB-138, PCB-153 and PCB-180
Appendix - Methods used for WAC (2003/33/EC)
***Naphthalene, Acenaphthylene, Acenaphthene, Anthracene, Benzo(a)anthracene, Benzo(b)fluoranthene, Benzo(k)fluoranthene, Benzo(g,h,i)perylene,
Benzo(a)pyrene, Chrysene, Coronene, Dibenzo(a,h)anthracene, Fluorene, Fluoranthene, Indeno(1,2,3-c,d)pyrene, Phenanthrene and Pyrene.
QF-PM 3.1.8 v10 Please include all sections of this report if it is reproduced 17 of 17
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EPA Export 28-05-2019:04:59:41
Unit 3 Deeside Point
Zone 3
Deeside Industrial Park
Deeside
Causeway Geotech
Attention :
Date :
Your reference :
Our reference :
Location :
Date samples received :
Status :
Issue :
Colm Hurley
13th February, 2017
1
Exova Jones Environmental
CH5 2UA
Tel: +44 (0) 1244 833780
Fax: +44 (0) 1244 833781
8 Drumahiskey Road
Bainamore
Ballymoney
Co Antrim
BT53 7QL
Registered Address : Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian, EH28 8PL
Eighteen samples were received for analysis on 1st February, 2017 of which fourteen were scheduled for analysis. Please find attached our Test
Report which should be read with notes at the end of the report and should include all sections if reproduced. Interpretations and opinions are
outside the scope of any accreditation, and all results relate only to samples supplied.
All analysis is carried out on as received samples and reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected.
Phil Sommerton BSc
Project Manager
Gemini 16-1239
WOP-ADF
1st February, 2017
Final report
Compiled By:
Test Report 17/3272 Batch 1
QF-PM 3.1.1 v16Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 1 of 15
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Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3272
J E Sample No. 1-2 3-4 5-6 7-8 11-12 15-16 17-18 21-22 23-24 25-26
Sample IDWOP-ADF
TP02/17
WOP-ADF
TP02/17
WOP-ADF
TP03/17
WOP-ADF
TP03/17
WOP-ADF
TP04/17
WOP-ADF
TP05/17
WOP-ADF
TP06/17
WOP-ADF
TP07/17
WOP-ADF
TP08/17
WOP-ADF
TP08/17
Depth 1.50 2.50 0.50 1.50 2.50 2.00 1.00 1.50 0.50 2.50
COC No / misc
Containers V J V J V J V J V J V J V J V J V J V J
Sample Date 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017
Aluminium 212 7575 23690 9008 6804 4400 974 1352 - 1559 <50 mg/kg TM30/PM15
Arsenic # 0.5 7.5 5.2 2.0 11.1 2.9 2.5 1.1 - 1.4 <0.5 mg/kg TM30/PM15
Barium # 34 47 120 28 88 19 29 8 - 9 <1 mg/kg TM30/PM15
Cadmium # <0.1 1.0 0.7 0.2 1.0 0.8 0.2 0.7 - 0.6 <0.1 mg/kg TM30/PM15
Chromium # 19.0 27.7 58.9 27.5 30.9 29.6 33.9 17.1 - 15.2 <0.5 mg/kg TM30/PM15
Copper # 2 15 34 11 16 11 5 5 - 6 <1 mg/kg TM30/PM15
Iron 4812 10640 16960 13320 14140 6663 6474 3045 - 5475 <20 mg/kg TM30/PM15
Lead # <5 13 31 12 13 9 <5 5 - <5 <5 mg/kg TM30/PM15
Mercury # <0.1 <0.1 <0.1 <0.1 0.2 <0.1 <0.1 <0.1 - <0.1 <0.1 mg/kg TM30/PM15
Molybdenum # 2.1 1.6 1.0 0.6 2.4 2.2 3.1 0.6 - 0.6 <0.1 mg/kg TM30/PM15
Nickel # 3.8 37.7 75.0 31.1 34.1 24.5 10.3 9.9 - 12.5 <0.7 mg/kg TM30/PM15
Selenium # 2 <1 1 <1 2 <1 2 <1 - <1 <1 mg/kg TM30/PM15
Zinc # <5 69 121 62 64 36 9 23 - 26 <5 mg/kg TM30/PM15
PAH MS
Naphthalene # - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
Acenaphthylene - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 mg/kg TM4/PM8
Acenaphthene # - <0.05 <0.05 <0.05 - - <0.05 <0.05 - - <0.05 mg/kg TM4/PM8
Fluorene # - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
Phenanthrene # - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 mg/kg TM4/PM8
Anthracene # - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
Fluoranthene # - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 mg/kg TM4/PM8
Pyrene # - <0.03 <0.03 <0.03 - - <0.03 <0.03 - - <0.03 mg/kg TM4/PM8
Benzo(a)anthracene # - <0.06 <0.06 <0.06 - - <0.06 <0.06 - - <0.06 mg/kg TM4/PM8
Chrysene # - <0.02 <0.02 <0.02 - - <0.02 <0.02 - - <0.02 mg/kg TM4/PM8
Benzo(bk)fluoranthene # - <0.07 <0.07 <0.07 - - <0.07 <0.07 - - <0.07 mg/kg TM4/PM8
Benzo(a)pyrene # - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
Indeno(123cd)pyrene # - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
Dibenzo(ah)anthracene # - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
Benzo(ghi)perylene # - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
Coronene - <0.04 <0.04 <0.04 - - <0.04 <0.04 - - <0.04 mg/kg TM4/PM8
PAH 17 Total - <0.64 <0.64 <0.64 - - <0.64 <0.64 - - <0.64 mg/kg TM4/PM8
Benzo(b)fluoranthene - <0.05 <0.05 <0.05 - - <0.05 <0.05 - - <0.05 mg/kg TM4/PM8
Benzo(k)fluoranthene - <0.02 <0.02 <0.02 - - <0.02 <0.02 - - <0.02 mg/kg TM4/PM8
PAH Surrogate % Recovery - 117 121 112 - - 118 118 - - <0 % TM4/PM8
Methyl Tertiary Butyl Ether # - - <2 <2 - - - <2 - - <2 ug/kg TM15/PM10
Benzene # - - <3 <3 - - - <3 - - <3 ug/kg TM15/PM10
Toluene # - - <3 <3 - - - <3 - - <3 ug/kg TM15/PM10
Ethylbenzene # - - <3 <3 - - - <3 - - <3 ug/kg TM15/PM10
p/m-Xylene # - - <5 <5 - - - <5 - - <5 ug/kg TM15/PM10
o-Xylene # - - <3 <3 - - - <3 - - <3 ug/kg TM15/PM10
Surrogate Recovery Toluene D8 - - 102 99 - - - 102 - - <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene - - 105 90 - - - 114 - - <0 % TM15/PM10
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 2 of 15
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EPA Export 28-05-2019:04:59:41
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3272
J E Sample No. 1-2 3-4 5-6 7-8 11-12 15-16 17-18 21-22 23-24 25-26
Sample IDWOP-ADF
TP02/17
WOP-ADF
TP02/17
WOP-ADF
TP03/17
WOP-ADF
TP03/17
WOP-ADF
TP04/17
WOP-ADF
TP05/17
WOP-ADF
TP06/17
WOP-ADF
TP07/17
WOP-ADF
TP08/17
WOP-ADF
TP08/17
Depth 1.50 2.50 0.50 1.50 2.50 2.00 1.00 1.50 0.50 2.50
COC No / misc
Containers V J V J V J V J V J V J V J V J V J V J
Sample Date 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017
TPH CWG
Aliphatics
>C5-C6 # - - - <0.1 - - - <0.1 - - <0.1 mg/kg TM36/PM12
>C6-C8 # - - - <0.1 - - - <0.1 - - <0.1 mg/kg TM36/PM12
>C8-C10 - - - <0.1 - - - <0.1 - - <0.1 mg/kg TM36/PM12
>C10-C12 # - - - <0.2 - - - <0.2 - - <0.2 mg/kg TM5/PM16
>C12-C16 # - - - <4 - - - <4 - - <4 mg/kg TM5/PM16
>C16-C21 # - - - <7 - - - <7 - - <7 mg/kg TM5/PM16
>C21-C35 # - - - <7 - - - <7 - - <7 mg/kg TM5/PM16
Total aliphatics C5-35 - - - <19 - - - <19 - - <19 mg/kg TM5/TM36/PM12/PM16
Aromatics
>C5-EC7 # - - - <0.1 - - - <0.1 - - <0.1 mg/kg TM36/PM12
>EC7-EC8 # - - - <0.1 - - - <0.1 - - <0.1 mg/kg TM36/PM12
>EC8-EC10 # - - - <0.1 - - - <0.1 - - <0.1 mg/kg TM36/PM12
>EC10-EC12 # - - - <0.2 - - - <0.2 - - <0.2 mg/kg TM5/PM16
>EC12-EC16 # - - - <4 - - - <4 - - <4 mg/kg TM5/PM16
>EC16-EC21 # - - - <7 - - - <7 - - <7 mg/kg TM5/PM16
>EC21-EC35 # - - - <7 - - - <7 - - <7 mg/kg TM5/PM16
Total aromatics C5-35 # - - - <19 - - - <19 - - <19 mg/kg TM5/TM36/PM12/PM16
Total aliphatics and aromatics(C5-35) - - - <38 - - - <38 - - <38 mg/kg TM5/TM36/PM12/PM16
Natural Moisture Content 472.4 28.1 38.7 14.7 50.3 14.0 780.0 12.5 878.3 9.3 <0.1 % PM4/PM0
Ammoniacal Nitrogen as N 17.2 - - <0.6 - - - <0.6 28.4 - <0.6 mg/kg TM38/PM20
Chloride # 148 - - 24 - - - 22 121 - <2 mg/kg TM38/PM20
Hexavalent Chromium # <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 - <0.3 <0.3 mg/kg TM38/PM20
Ortho Phosphate as PO4 <0.3 - - <0.3 - - - <0.3 5.6 - <0.3 mg/kg TM38/PM20
Sulphate as SO4 (2:1 Ext) # 0.0820 - - 0.0243 - - - 0.0038 0.0115 - <0.0015 g/l TM38/PM20
Chromium III 19.0 27.7 58.9 27.5 30.9 29.6 33.9 17.1 - 15.2 <0.5 mg/kg NONE/NONE
Organic Matter - - - 0.5 - - - 0.2 - - <0.2 % TM21/PM24
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 3 of 15
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EPA Export 28-05-2019:04:59:41
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3272
J E Sample No. 27-28 31-32 33-34 35-36
Sample IDWOP-ADF
TP09/17
WOP-ADF
TP10/17
WOP-ADF
TP01/17
WOP-ADF
TP01/17
Depth 1.00 1.00 1.50 3.00
COC No / misc
Containers V J V J V J V J
Sample Date 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil
Batch Number 1 1 1 1
Date of Receipt 01/02/2017 01/02/2017 01/02/2017 01/02/2017
Aluminium 1393 7952 511 4662 <50 mg/kg TM30/PM15
Arsenic # 1.0 3.3 0.7 5.9 <0.5 mg/kg TM30/PM15
Barium # 9 31 9 25 <1 mg/kg TM30/PM15
Cadmium # 0.9 0.5 <0.1 0.9 <0.1 mg/kg TM30/PM15
Chromium # 17.4 48.6 16.5 32.2 <0.5 mg/kg TM30/PM15
Copper # 5 15 3 11 <1 mg/kg TM30/PM15
Iron 2574 8603 1168 8860 <20 mg/kg TM30/PM15
Lead # 7 11 <5 10 <5 mg/kg TM30/PM15
Mercury # <0.1 <0.1 <0.1 <0.1 <0.1 mg/kg TM30/PM15
Molybdenum # 0.8 3.1 1.3 2.2 <0.1 mg/kg TM30/PM15
Nickel # 9.2 37.9 2.9 28.7 <0.7 mg/kg TM30/PM15
Selenium # <1 1 <1 <1 <1 mg/kg TM30/PM15
Zinc # 18 58 <5 48 <5 mg/kg TM30/PM15
PAH MS
Naphthalene # <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
Acenaphthylene <0.03 - <0.03 <0.03 <0.03 mg/kg TM4/PM8
Acenaphthene # <0.05 - <0.05 <0.05 <0.05 mg/kg TM4/PM8
Fluorene # <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
Phenanthrene # <0.03 - <0.03 <0.03 <0.03 mg/kg TM4/PM8
Anthracene # <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
Fluoranthene # <0.03 - <0.03 <0.03 <0.03 mg/kg TM4/PM8
Pyrene # <0.03 - <0.03 <0.03 <0.03 mg/kg TM4/PM8
Benzo(a)anthracene # <0.06 - <0.06 <0.06 <0.06 mg/kg TM4/PM8
Chrysene # <0.02 - <0.02 <0.02 <0.02 mg/kg TM4/PM8
Benzo(bk)fluoranthene # <0.07 - <0.07 <0.07 <0.07 mg/kg TM4/PM8
Benzo(a)pyrene # <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
Indeno(123cd)pyrene # <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
Dibenzo(ah)anthracene # <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
Benzo(ghi)perylene # <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
Coronene <0.04 - <0.04 <0.04 <0.04 mg/kg TM4/PM8
PAH 17 Total <0.64 - <0.64 <0.64 <0.64 mg/kg TM4/PM8
Benzo(b)fluoranthene <0.05 - <0.05 <0.05 <0.05 mg/kg TM4/PM8
Benzo(k)fluoranthene <0.02 - <0.02 <0.02 <0.02 mg/kg TM4/PM8
PAH Surrogate % Recovery 108 - 97 114 <0 % TM4/PM8
Methyl Tertiary Butyl Ether # <2 - <2 <2 <2 ug/kg TM15/PM10
Benzene # <3 - <3 <3 <3 ug/kg TM15/PM10
Toluene # <3 - <3 <3 <3 ug/kg TM15/PM10
Ethylbenzene # <3 - <3 <3 <3 ug/kg TM15/PM10
p/m-Xylene # <5 - <5 <5 <5 ug/kg TM15/PM10
o-Xylene # <3 - <3 <3 <3 ug/kg TM15/PM10
Surrogate Recovery Toluene D8 101 - 83 101 <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 114 - 71 88 <0 % TM15/PM10
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 4 of 15
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s only
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Conse
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uired
for a
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EPA Export 28-05-2019:04:59:41
Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3272
J E Sample No. 27-28 31-32 33-34 35-36
Sample IDWOP-ADF
TP09/17
WOP-ADF
TP10/17
WOP-ADF
TP01/17
WOP-ADF
TP01/17
Depth 1.00 1.00 1.50 3.00
COC No / misc
Containers V J V J V J V J
Sample Date 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil
Batch Number 1 1 1 1
Date of Receipt 01/02/2017 01/02/2017 01/02/2017 01/02/2017
TPH CWG
Aliphatics
>C5-C6 # <0.1 - - <0.1 <0.1 mg/kg TM36/PM12
>C6-C8 # <0.1 - - <0.1 <0.1 mg/kg TM36/PM12
>C8-C10 <0.1 - - <0.1 <0.1 mg/kg TM36/PM12
>C10-C12 # <0.2 - - <0.2 <0.2 mg/kg TM5/PM16
>C12-C16 # <4 - - <4 <4 mg/kg TM5/PM16
>C16-C21 # <7 - - <7 <7 mg/kg TM5/PM16
>C21-C35 # <7 - - <7 <7 mg/kg TM5/PM16
Total aliphatics C5-35 <19 - - <19 <19 mg/kg TM5/TM36/PM12/PM16
Aromatics
>C5-EC7 # <0.1 - - <0.1 <0.1 mg/kg TM36/PM12
>EC7-EC8 # <0.1 - - <0.1 <0.1 mg/kg TM36/PM12
>EC8-EC10 # <0.1 - - <0.1 <0.1 mg/kg TM36/PM12
>EC10-EC12 # <0.2 - - <0.2 <0.2 mg/kg TM5/PM16
>EC12-EC16 # <4 - - <4 <4 mg/kg TM5/PM16
>EC16-EC21 # <7 - - <7 <7 mg/kg TM5/PM16
>EC21-EC35 # <7 - - <7 <7 mg/kg TM5/PM16
Total aromatics C5-35 # <19 - - <19 <19 mg/kg TM5/TM36/PM12/PM16
Total aliphatics and aromatics(C5-35) <38 - - <38 <38 mg/kg TM5/TM36/PM12/PM16
Natural Moisture Content 11.5 17.7 670.0 15.6 <0.1 % PM4/PM0
Ammoniacal Nitrogen as N - - - 4.9 <0.6 mg/kg TM38/PM20
Chloride # - - - 29 <2 mg/kg TM38/PM20
Hexavalent Chromium # <0.3 <0.3 <0.3 <0.3 <0.3 mg/kg TM38/PM20
Ortho Phosphate as PO4 - - - <0.3 <0.3 mg/kg TM38/PM20
Sulphate as SO4 (2:1 Ext) # - - - 0.0111 <0.0015 g/l TM38/PM20
Chromium III 17.4 48.6 16.5 32.2 <0.5 mg/kg NONE/NONE
Organic Matter - - - 1.0 <0.2 % TM21/PM24
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 5 of 15
For
insp
ectio
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Conse
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EPA Export 28-05-2019:04:59:42
Client Name: Report : CEN 10:1 1 Batch
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3272
J E Sample No. 1-2 3-4 5-6 7-8 11-12 15-16 17-18 21-22 23-24 25-26
Sample IDWOP-ADF
TP02/17
WOP-ADF
TP02/17
WOP-ADF
TP03/17
WOP-ADF
TP03/17
WOP-ADF
TP04/17
WOP-ADF
TP05/17
WOP-ADF
TP06/17
WOP-ADF
TP07/17
WOP-ADF
TP08/17
WOP-ADF
TP08/17
Depth 1.50 2.50 0.50 1.50 2.50 2.00 1.00 1.50 0.50 2.50
COC No / misc
Containers V J V J V J V J V J V J V J V J V J V J
Sample Date 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017 01/02/2017
Dissolved Aluminium # 5.1 37.8 582.9 668.6 55.4 346.2 6.9 676.5 - 377.6 <1.5 ug/l TM30/PM14
Dissolved Arsenic # <0.9 6.0 <0.9 3.2 5.1 6.6 8.9 3.9 - 4.5 <0.9 ug/l TM30/PM14
Dissolved Barium # 8.0 16.7 6.9 4.0 16.0 <1.8 8.2 2.2 - <1.8 <1.8 ug/l TM30/PM14
Dissolved Cadmium # <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 - <0.03 <0.03 ug/l TM30/PM14
Dissolved Chromium # <0.2 <0.2 0.9 1.0 <0.2 0.9 <0.2 1.1 - 0.9 <0.2 ug/l TM30/PM14
Dissolved Copper # <3 <3 <3 <3 <3 <3 <3 <3 - <3 <3 ug/l TM30/PM14
Dissolved Iron # 38.4 8.3 168.5 150.5 12.6 192.0 73.4 126.6 - 75.8 <4.7 ug/l TM30/PM14
Dissolved Lead # <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 - <0.4 <0.4 ug/l TM30/PM14
Dissolved Mercury # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - <0.5 <0.5 ug/l TM30/PM14
Dissolved Molybdenum # 0.2 12.6 0.7 2.6 24.2 10.1 0.8 2.2 - 3.9 <0.2 ug/l TM30/PM14
Dissolved Nickel # 0.7 14.4 1.7 1.6 2.7 1.6 0.3 1.6 - 2.5 <0.2 ug/l TM30/PM14
Dissolved Selenium # <1.2 <1.2 <1.2 <1.2 2.4 4.6 <1.2 <1.2 - <1.2 <1.2 ug/l TM30/PM14
Dissolved Zinc # 5.0 4.6 6.1 4.8 6.0 4.4 7.2 4.2 - 7.1 <1.5 ug/l TM30/PM14
PAH MS
Naphthalene - <0.1 <0.1 <0.1 - - - <0.1 - - <0.1 ug/l TM4/PM30
Acenaphthylene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Acenaphthene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Fluorene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Phenanthrene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Anthracene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Fluoranthene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Pyrene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Benzo(a)anthracene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Chrysene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Benzo(bk)fluoranthene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Benzo(a)pyrene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Indeno(123cd)pyrene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Dibenzo(ah)anthracene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Benzo(ghi)perylene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
PAH 16 Total - <0.1 <0.1 <0.1 - - - <0.1 - - <0.1 ug/l TM4/PM30
Benzo(b)fluoranthene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
Benzo(k)fluoranthene - <0.01 <0.01 <0.01 - - - <0.01 - - <0.01 ug/l TM4/PM30
PAH Surrogate % Recovery - 71 76 74 - - - 74 - - <0 % TM4/PM30
Chloride # 9.1 - - <0.3 - - - <0.3 17.3 - <0.3 mg/l TM38/PM0
Ortho Phosphate as PO4 <0.03 - - <0.03 - - - <0.03 <0.03 - <0.03 mg/l TM38/PM0
Mass of raw test portion - - - - - - - - 0.918 - kg NONE/PM17
Leachant Volume - - - - - - - - 0.068 - l NONE/PM17
Dissolved Chromium III <2 <2 <2 <2 <2 <2 <2 <2 - <2 <2 ug/l NONE/NONE
Hexavalent Chromium <2 <2 <2 <2 <2 <2 <2 <2 - <2 <2 ug/l TM38/PM0
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 6 of 15
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insp
ectio
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.
Conse
nt of
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r req
uired
for a
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se.
EPA Export 28-05-2019:04:59:42
Client Name: Report : CEN 10:1 1 Batch
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/3272
J E Sample No. 27-28 31-32 33-34 35-36
Sample IDWOP-ADF
TP09/17
WOP-ADF
TP10/17
WOP-ADF
TP01/17
WOP-ADF
TP01/17
Depth 1.00 1.00 1.50 3.00
COC No / misc
Containers V J V J V J V J
Sample Date 30/01/2017 30/01/2017 30/01/2017 30/01/2017
Sample Type Soil Soil Soil Soil
Batch Number 1 1 1 1
Date of Receipt 01/02/2017 01/02/2017 01/02/2017 01/02/2017
Dissolved Aluminium # 722.7 357.8 13.3 242.9 <1.5 ug/l TM30/PM14
Dissolved Arsenic # 1.2 2.6 2.2 8.8 <0.9 ug/l TM30/PM14
Dissolved Barium # 2.4 <1.8 <1.8 3.8 <1.8 ug/l TM30/PM14
Dissolved Cadmium # <0.03 <0.03 <0.03 <0.03 <0.03 ug/l TM30/PM14
Dissolved Chromium # 1.1 1.0 <0.2 0.5 <0.2 ug/l TM30/PM14
Dissolved Copper # <3 <3 <3 <3 <3 ug/l TM30/PM14
Dissolved Iron # 177.7 149.0 11.1 46.2 <4.7 ug/l TM30/PM14
Dissolved Lead # <0.4 <0.4 <0.4 <0.4 <0.4 ug/l TM30/PM14
Dissolved Mercury # <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM30/PM14
Dissolved Molybdenum # 0.4 5.5 <0.2 14.7 <0.2 ug/l TM30/PM14
Dissolved Nickel # 1.3 1.9 <0.2 6.4 <0.2 ug/l TM30/PM14
Dissolved Selenium # <1.2 <1.2 <1.2 <1.2 <1.2 ug/l TM30/PM14
Dissolved Zinc # 4.9 5.3 14.0 4.9 <1.5 ug/l TM30/PM14
PAH MS
Naphthalene <0.1 - 0.5 - <0.1 ug/l TM4/PM30
Acenaphthylene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Acenaphthene 0.01 - 0.02 - <0.01 ug/l TM4/PM30
Fluorene 0.02 - 0.04 - <0.01 ug/l TM4/PM30
Phenanthrene 0.02 - 0.09 - <0.01 ug/l TM4/PM30
Anthracene <0.01 - 0.02 - <0.01 ug/l TM4/PM30
Fluoranthene <0.01 - 0.02 - <0.01 ug/l TM4/PM30
Pyrene <0.01 - 0.02 - <0.01 ug/l TM4/PM30
Benzo(a)anthracene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Chrysene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Benzo(bk)fluoranthene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Benzo(a)pyrene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Indeno(123cd)pyrene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Dibenzo(ah)anthracene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Benzo(ghi)perylene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
PAH 16 Total <0.1 - 0.7 - <0.1 ug/l TM4/PM30
Benzo(b)fluoranthene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
Benzo(k)fluoranthene <0.01 - <0.01 - <0.01 ug/l TM4/PM30
PAH Surrogate % Recovery 76 - 78 - <0 % TM4/PM30
Chloride # - - - 1.5 <0.3 mg/l TM38/PM0
Ortho Phosphate as PO4 - - - <0.03 <0.03 mg/l TM38/PM0
Mass of raw test portion - - - - kg NONE/PM17
Leachant Volume - - - - l NONE/PM17
Dissolved Chromium III <2 <2 <2 <2 <2 ug/l NONE/NONE
Hexavalent Chromium <2 <2 <2 <2 <2 ug/l TM38/PM0
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
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Client Name: SVOC Report : Solid
Reference:
Location:
Contact:
JE Job No.: 17/3272
J E Sample No. 7-8 35-36
Sample IDWOP-ADF
TP03/17
WOP-ADF
TP01/17
Depth 1.50 3.00
COC No / misc
Containers V J V J
Sample Date 30/01/2017 30/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 01/02/2017 01/02/2017
SVOC MS
Phenols
2-Chlorophenol # <10 <10 <10 ug/kg TM16/PM8
2-Methylphenol <10 <10 <10 ug/kg TM16/PM8
2-Nitrophenol <10 <10 <10 ug/kg TM16/PM8
2,4-Dichlorophenol # <10 <10 <10 ug/kg TM16/PM8
2,4-Dimethylphenol <10 <10 <10 ug/kg TM16/PM8
2,4,5-Trichlorophenol <10 <10 <10 ug/kg TM16/PM8
2,4,6-Trichlorophenol <10 <10 <10 ug/kg TM16/PM8
4-Chloro-3-methylphenol <10 <10 <10 ug/kg TM16/PM8
4-Methylphenol <10 <10 <10 ug/kg TM16/PM8
4-Nitrophenol <10 <10 <10 ug/kg TM16/PM8
Pentachlorophenol <10 <10 <10 ug/kg TM16/PM8
Phenol # <10 <10 <10 ug/kg TM16/PM8
PAHs
2-Chloronaphthalene # <10 <10 <10 ug/kg TM16/PM8
2-Methylnaphthalene # <10 <10 <10 ug/kg TM16/PM8
Phthalates
Bis(2-ethylhexyl) phthalate <100 <100 <100 ug/kg TM16/PM8
Butylbenzyl phthalate <100 <100 <100 ug/kg TM16/PM8
Di-n-butyl phthalate <100 <100 <100 ug/kg TM16/PM8
Di-n-Octyl phthalate <100 <100 <100 ug/kg TM16/PM8
Diethyl phthalate <100 <100 <100 ug/kg TM16/PM8
Dimethyl phthalate # <100 <100 <100 ug/kg TM16/PM8
Other SVOCs
1,2-Dichlorobenzene <10 <10 <10 ug/kg TM16/PM8
1,2,4-Trichlorobenzene # <10 <10 <10 ug/kg TM16/PM8
1,3-Dichlorobenzene <10 <10 <10 ug/kg TM16/PM8
1,4-Dichlorobenzene <10 <10 <10 ug/kg TM16/PM8
2-Nitroaniline <10 <10 <10 ug/kg TM16/PM8
2,4-Dinitrotoluene <10 <10 <10 ug/kg TM16/PM8
2,6-Dinitrotoluene <10 <10 <10 ug/kg TM16/PM8
3-Nitroaniline <10 <10 <10 ug/kg TM16/PM8
4-Bromophenylphenylether # <10 <10 <10 ug/kg TM16/PM8
4-Chloroaniline <10 <10 <10 ug/kg TM16/PM8
4-Chlorophenylphenylether <10 <10 <10 ug/kg TM16/PM8
4-Nitroaniline <10 <10 <10 ug/kg TM16/PM8
Azobenzene <10 <10 <10 ug/kg TM16/PM8
Bis(2-chloroethoxy)methane <10 <10 <10 ug/kg TM16/PM8
Bis(2-chloroethyl)ether <10 <10 <10 ug/kg TM16/PM8
Carbazole <10 <10 <10 ug/kg TM16/PM8
Dibenzofuran # <10 <10 <10 ug/kg TM16/PM8
Hexachlorobenzene <10 <10 <10 ug/kg TM16/PM8
Hexachlorobutadiene # <10 <10 <10 ug/kg TM16/PM8
Hexachlorocyclopentadiene <10 <10 <10 ug/kg TM16/PM8
Hexachloroethane <10 <10 <10 ug/kg TM16/PM8
Isophorone # <10 <10 <10 ug/kg TM16/PM8
N-nitrosodi-n-propylamine # <10 <10 <10 ug/kg TM16/PM8
Nitrobenzene # <10 <10 <10 ug/kg TM16/PM8
Surrogate Recovery 2-Fluorobiphenyl 63SV
44SV <0 % TM16/PM8
Surrogate Recovery p-Terphenyl-d14 84 80 <0 % TM16/PM8
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
QF-PM 3.1.3 v11Please include all sections of this report if it is reproduced
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Client Name: VOC Report : Solid
Reference:
Location:
Contact:
JE Job No.: 17/3272
J E Sample No. 7-8 35-36
Sample IDWOP-ADF
TP03/17
WOP-ADF
TP01/17
Depth 1.50 3.00
COC No / misc
Containers V J V J
Sample Date 30/01/2017 30/01/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 01/02/2017 01/02/2017
VOC MS
Dichlorodifluoromethane <2 <2 <2 ug/kg TM15/PM10
Methyl Tertiary Butyl Ether # <2 <2 <2 ug/kg TM15/PM10
Chloromethane # <3 <3 <3 ug/kg TM15/PM10
Vinyl Chloride <2 <2 <2 ug/kg TM15_A/PM10
Bromomethane <1 <1 <1 ug/kg TM15/PM10
Chloroethane # <2 <2 <2 ug/kg TM15/PM10
Trichlorofluoromethane # <2 <2 <2 ug/kg TM15/PM10
1,1-Dichloroethene (1,1 DCE) # <6 <6 <6 ug/kg TM15/PM10
Dichloromethane (DCM) # <30 <30 <30 ug/kg TM15/PM10
trans-1-2-Dichloroethene # <3 <3 <3 ug/kg TM15/PM10
1,1-Dichloroethane # <3 <3 <3 ug/kg TM15/PM10
cis-1-2-Dichloroethene # <3 <3 <3 ug/kg TM15/PM10
2,2-Dichloropropane <4 <4 <4 ug/kg TM15/PM10
Bromochloromethane # <3 <3 <3 ug/kg TM15/PM10
Chloroform # <3 <3 <3 ug/kg TM15/PM10
1,1,1-Trichloroethane # <3 <3 <3 ug/kg TM15/PM10
1,1-Dichloropropene # <3 <3 <3 ug/kg TM15/PM10
Carbon tetrachloride # <4 <4 <4 ug/kg TM15/PM10
1,2-Dichloroethane # <4 <4 <4 ug/kg TM15/PM10
Benzene # <3 <3 <3 ug/kg TM15/PM10
Trichloroethene (TCE) # <3 <3 <3 ug/kg TM15/PM10
1,2-Dichloropropane # <6 <6 <6 ug/kg TM15/PM10
Dibromomethane # <3 <3 <3 ug/kg TM15/PM10
Bromodichloromethane # <3 <3 <3 ug/kg TM15/PM10
cis-1-3-Dichloropropene <4 <4 <4 ug/kg TM15/PM10
Toluene # <3 <3 <3 ug/kg TM15/PM10
trans-1-3-Dichloropropene <3 <3 <3 ug/kg TM15/PM10
1,1,2-Trichloroethane # <3 <3 <3 ug/kg TM15/PM10
Tetrachloroethene (PCE) # <3 <3 <3 ug/kg TM15/PM10
1,3-Dichloropropane # <3 <3 <3 ug/kg TM15/PM10
Dibromochloromethane # <3 <3 <3 ug/kg TM15/PM10
1,2-Dibromoethane # <3 <3 <3 ug/kg TM15/PM10
Chlorobenzene # <3 <3 <3 ug/kg TM15/PM10
1,1,1,2-Tetrachloroethane <3 <3 <3 ug/kg TM15/PM10
Ethylbenzene # <3 <3 <3 ug/kg TM15/PM10
p/m-Xylene # <5 <5 <5 ug/kg TM15/PM10
o-Xylene # <3 <3 <3 ug/kg TM15/PM10
Styrene <3 <3 <3 ug/kg TM15_A/PM10
Bromoform <3 <3 <3 ug/kg TM15/PM10
Isopropylbenzene # <3 <3 <3 ug/kg TM15/PM10
1,1,2,2-Tetrachloroethane # <3 <3 <3 ug/kg TM15/PM10
Bromobenzene <2 <2 <2 ug/kg TM15/PM10
1,2,3-Trichloropropane # <4 <4 <4 ug/kg TM15/PM10
Propylbenzene # <4 <4 <4 ug/kg TM15/PM10
2-Chlorotoluene <3 <3 <3 ug/kg TM15/PM10
1,3,5-Trimethylbenzene # <3 <3 <3 ug/kg TM15/PM10
4-Chlorotoluene <3 <3 <3 ug/kg TM15/PM10
tert-Butylbenzene # <5 <5 <5 ug/kg TM15/PM10
1,2,4-Trimethylbenzene # <6 <6 <6 ug/kg TM15/PM10
sec-Butylbenzene # <4 <4 <4 ug/kg TM15/PM10
4-Isopropyltoluene # <4 <4 <4 ug/kg TM15/PM10
1,3-Dichlorobenzene # <4 <4 <4 ug/kg TM15/PM10
1,4-Dichlorobenzene # <4 <4 <4 ug/kg TM15/PM10
n-Butylbenzene # <4 <4 <4 ug/kg TM15/PM10
1,2-Dichlorobenzene # <4 <4 <4 ug/kg TM15/PM10
1,2-Dibromo-3-chloropropane # <4 <4 <4 ug/kg TM15/PM10
1,2,4-Trichlorobenzene # <7 <7 <7 ug/kg TM15/PM10
Hexachlorobutadiene <4 <4 <4 ug/kg TM15/PM10
Naphthalene <27 <27 <27 ug/kg TM15/PM10
1,2,3-Trichlorobenzene # <7 <7 <7 ug/kg TM15/PM10
Surrogate Recovery Toluene D8 99 101 <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 90 88 <0 % TM15/PM10
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
QF-PM 3.1.4 v11Please include all sections of this report if it is reproduced
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Notification of Deviating Samples
J E
Job
No.
Batch Depth J E Sample
No.Analysis Reason
Please note that only samples that are deviating are mentioned in this report. If no samples are listed it is because none were deviating.
Only analyses which are accredited are recorded as deviating if set criteria are not met.
Exova Jones Environmental
Gemini 16-1239
WOP-ADF
Colm HurleyContact:
Sample ID
Client Name: Causeway Geotech
Reference:
Location:
No deviating sample report results for job 17/3272
QF-PM 3.1.11 v3 Please include all sections of this report if it is reproduced 10 of 15
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JE Job No.:
SOILS
DEVIATING SAMPLES
SURROGATES
DILUTIONS
BLANKS
NOTE
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
Please note we are not a UK Drinking Water Inspectorate (DWI) Approved Laboratory .
If you have not already done so, please send us a purchase order if this is required by your company.
Samples must be received in a condition appropriate to the requested analyses. All samples should be submitted to the laboratory in suitable
containers with sufficient ice packs to sustain an appropriate temperature for the requested analysis. If this is not the case you will be informed and
any test results that may be compromised highlighted on your deviating samples report.
ISO17025 accreditation applies to surface water and groundwater and usually one other matrix which is analysis specific, any other liquids are
outside our scope of accreditation.
As surface waters require different sample preparation to groundwaters the laboratory must be informed of the water type when submitting samples.
Where appropriate please make sure that our detection limits are suitable for your needs, if they are not, please notify us immediately.
Data is only reported if the laboratory is confident that the data is a true reflection of the samples analysed. Data is only reported as accredited when
all the requirements of our Quality System have been met. In certain circumstances where all the requirements of the Quality System have not been
met, for instance if the associated AQC has failed, the reason is fully investigated and documented. The sample data is then evaluated alongside
the other quality control checks performed during analysis to determine its suitability. Following this evaluation, provided the sample results have not
been effected, the data is reported but accreditation is removed. It is a UKAS requirement for data not reported as accredited to be considered
indicative only, but this does not mean the data is not valid.
Where possible, and if requested, samples will be re-extracted and a revised report issued with accredited results. Please do not hesitate to contact
the laboratory if further details are required of the circumstances which have led to the removal of accreditation.
Where an MCERTS report has been requested, you will be notified within 48 hours of any samples that have been identified as being outside our
MCERTS scope. As validation has been performed on clay, sand and loam, only samples that are predominantly these matrices, or combinations
of them will be within our MCERTS scope. If samples are not one of a combination of the above matrices they will not be marked as MCERTS
accredited.
Negative Neutralization Potential (NP) values are obtained when the volume of NaOH (0.1N) titrated (pH 8.3) is greater than the volume of HCl (1N)
to reduce the pH of the sample to 2.0 - 2.5. Any negative NP values are corrected to 0.
Where a CEN 10:1 ZERO Headspace VOC test has been carried out, a 10:1 ratio of water to wet (as received) soil has been used.
All samples will be discarded one month after the date of reporting, unless we are instructed to the contrary.
% Asbestos in Asbestos Containing Materials (ACMs) is determined by reference to HSG 264 The Survey Guide - Appendix 2 : ACMs in buildings
listed in order of ease of fibre release.
All analysis is reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected. Samples are dried at 35°C ±5°C unless
otherwise stated. Moisture content for CEN Leachate tests are dried at 105°C ±5°C.
Surrogate compounds are added during the preparation process to monitor recovery of analytes. However low recovery in soils is often due to peat,
clay or other organic rich matrices. For waters this can be due to oxidants, surfactants, organic rich sediments or remediation fluids. Acceptable
limits for most organic methods are 70 - 130% and for VOCs are 50 - 150%. When surrogate recoveries are outside the performance criteria but
the associated AQC passes this is assumed to be due to matrix effect. Results are not surrogate corrected.
A dilution suffix indicates a dilution has been performed and the reported result takes this into account. No further calculation is required.
NOTES TO ACCOMPANY ALL SCHEDULES AND REPORTS
Please note we are only MCERTS accredited (UK soils only) for sand, loam and clay and any other matrix is outside our scope of accreditation.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
17/3272
WATERS
Where analytes have been found in the blank, the sample will be treated in accordance with our laboratory procedure for dealing with contaminated
blanks.
It is assumed that you have taken representative samples on site and require analysis on a representative subsample. Stones will generally be
included unless we are requested to remove them.
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 11 of 15
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JE Job No.:
#
SA
B
DR
M
NA
NAD
ND
NDP
SS
SV
W
+
++
*
AD
CO
LOD/LOR
ME
NFD
BS
LB
N
TB
OC
Dilution required.
Analysis subcontracted to a Jones Environmental approved laboratory.
Matrix Effect
Blank Sample
Client Sample
Trip Blank Sample
AQC Sample
Suspected carry over
Limit of Detection (Limit of Reporting) in line with ISO 17025 and MCERTS
Samples are dried at 35°C ±5°C
17/3272
AQC failure, accreditation has been removed from this result, if appropriate, see 'Note' on previous page.
Calibrated against a single substance
Not applicable
No Asbestos Detected.
No Determination Possible
Indicates analyte found in associated method blank.
None Detected (usually refers to VOC and/SVOC TICs).
ISO17025 (SANAS) accredited - South Africa.
MCERTS accredited.
Outside Calibration Range
No Fibres Detected
Result outside calibration range, results should be considered as indicative only and are not accredited.
Results expressed on as received basis.
Surrogate recovery outside performance criteria. This may be due to a matrix effect.
ISO17025 (UKAS) accredited - UK.
ABBREVIATIONS and ACRONYMS USED
QF-PM 3.1.9 v33Please include all sections of this report if it is reproduced
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JE Job No: 17/3272
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required.
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. AR
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM16 Fractionation into aliphatic and aromatic fractions using a Rapid Trace SPE. Yes AR Yes
TM5/TM36
TM005: Modified USEPA 8015B. Determination of solvent Extractable Petroleum
Hydrocarbons (EPH) including column fractionation in the carbon range of C10-35 into
aliphatic and aromatic fractions by GC-FID.
TM036: Modified USEPA 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C5-10 by headspace GC-FID. Including determination of
BTEX and calculation of Aliphatic fractions.
PM12/PM16
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis./Fractionation into aliphatic and aromatic fractions using a Rapid
Trace SPE.
AR Yes
TM5/TM36
TM005: Modified USEPA 8015B. Determination of solvent Extractable Petroleum
Hydrocarbons (EPH) including column fractionation in the carbon range of C10-35 into
aliphatic and aromatic fractions by GC-FID.
TM036: Modified USEPA 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C5-10 by headspace GC-FID. Including determination of
BTEX and calculation of Aliphatic fractions.
PM12/PM16
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis./Fractionation into aliphatic and aromatic fractions using a Rapid
Trace SPE.
Yes AR Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 13 of 15
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EPA Export 28-05-2019:04:59:42
JE Job No: 17/3272
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. Yes AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.AR Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM8
End over end extraction of solid samples for organic analysis. The solvent mix varies
depending on analysis required.Yes AR Yes
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM14
Analysis of waters and leachates for metals by ICP OES/ICP MS. Samples are filtered for
dissolved metals and acidified if required.Yes AR Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.Yes AD Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.AR Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 14 of 15
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JE Job No: 17/3272
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AR Yes
NONE No Method Code NONE No Method Code AR Yes
NONE No Method Code PM17Modified method EN12457-2 As received solid samples are leached with water in a 10:1
water to soil ratio for 24 hours, the moisture content of the sample is included in the ratio.
NONE No Method Code PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.AR
TM15_AModified USEPA 8260. Quantitative Determination of Volatile Organic Compounds, Vinyl
Chloride & Styrene by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. AR Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 15 of 15
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EPA Export 28-05-2019:04:59:42
Unit 3 Deeside Point
Zone 3
Deeside Industrial Park
Deeside
Causeway Geotech
Attention :
Date :
Your reference :
Our reference :
Location :
Date samples received :
Status :
Issue :
Colm Hurley
15th March, 2017
1
Exova Jones Environmental
CH5 2UA
Tel: +44 (0) 1244 833780
Fax: +44 (0) 1244 833781
8 Drumahiskey Road
Bainamore
Ballymoney
Co Antrim
BT53 7QL
Registered Address : Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian, EH28 8PL
Two samples were received for analysis on 2nd March, 2017 of which two were scheduled for analysis. Please find attached our Test Report which
should be read with notes at the end of the report and should include all sections if reproduced. Interpretations and opinions are outside the scope
of any accreditation, and all results relate only to samples supplied.
All analysis is carried out on as received samples and reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected.
Bruce Leslie
Project Co-ordinator
Gemini 16-1239
WOP-ADF
2nd March, 2017
Final report
Compiled By:
Test Report 17/4799 Batch 1
QF-PM 3.1.1 v16Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 1 of 8
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Client Name: Report : Solid
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/4799
J E Sample No. 1-4 5-8
Sample IDWOP-ADF
BH01/17
WOP-ADF
BH03/17
Depth 2.20 4.00
COC No / misc
Containers V J T V J T
Sample Date 22/02/2017 22/02/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 02/03/2017 02/03/2017
Aluminium 7939 7472 <50 mg/kg TM30/PM15
Arsenic # 3.9 7.3 <0.5 mg/kg TM30/PM15
Barium # 51 43 <1 mg/kg TM30/PM15
Cadmium # 1.2 1.2 <0.1 mg/kg TM30/PM15
Chromium # 24.4 33.7 <0.5 mg/kg TM30/PM15
Copper # 19 17 <1 mg/kg TM30/PM15
Iron 12480 12070 <20 mg/kg TM30/PM15
Lead # 15 13 <5 mg/kg TM30/PM15
Mercury # <0.1 <0.1 <0.1 mg/kg TM30/PM15
Molybdenum # 1.1 2.0 <0.1 mg/kg TM30/PM15
Nickel # 39.3 38.5 <0.7 mg/kg TM30/PM15
Selenium # <1 <1 <1 mg/kg TM30/PM15
Zinc # 86 75 <5 mg/kg TM30/PM15
Natural Moisture Content 26.2 26.3 <0.1 % PM4/PM0
Ammoniacal Nitrogen as N 10.6 - <0.6 mg/kg TM38/PM20
Chloride # 18 - <2 mg/kg TM38/PM20
Hexavalent Chromium # <0.3 <0.3 <0.3 mg/kg TM38/PM20
Ortho Phosphate as PO4 <0.3 - <0.3 mg/kg TM38/PM20
Sulphate as SO4 (2:1 Ext) # 0.0248 - <0.0015 g/l TM38/PM20
Chromium III 24.4 33.7 <0.5 mg/kg NONE/NONE
Organic Matter 1.1 - <0.2 % TM21/PM24
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 2 of 8
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EPA Export 28-05-2019:04:59:42
Client Name: Report : CEN 10:1 1 Batch
Reference:
Location: Solids: V=60g VOC jar, J=250g glass jar, T=plastic tub
Contact:
JE Job No.: 17/4799
J E Sample No. 1-4 5-8
Sample IDWOP-ADF
BH01/17
WOP-ADF
BH03/17
Depth 2.20 4.00
COC No / misc
Containers V J T V J T
Sample Date 22/02/2017 22/02/2017
Sample Type Soil Soil
Batch Number 1 1
Date of Receipt 02/03/2017 02/03/2017
Dissolved Aluminium # 21.0 25.2 <1.5 ug/l TM30/PM14
Dissolved Arsenic # <0.9 <0.9 <0.9 ug/l TM30/PM14
Dissolved Barium # 16.4 3.8 <1.8 ug/l TM30/PM14
Dissolved Cadmium # <0.03 <0.03 <0.03 ug/l TM30/PM14
Dissolved Chromium # <0.2 <0.2 <0.2 ug/l TM30/PM14
Dissolved Copper # <3 <3 <3 ug/l TM30/PM14
Dissolved Iron # <4.7 <4.7 <4.7 ug/l TM30/PM14
Dissolved Lead # <0.4 <0.4 <0.4 ug/l TM30/PM14
Dissolved Mercury # <0.5 <0.5 <0.5 ug/l TM30/PM14
Dissolved Molybdenum # 12.0 15.8 <0.2 ug/l TM30/PM14
Dissolved Nickel # 4.0 12.0 <0.2 ug/l TM30/PM14
Dissolved Selenium # <1.2 <1.2 <1.2 ug/l TM30/PM14
Dissolved Zinc # <1.5 <1.5 <1.5 ug/l TM30/PM14
Chloride # <0.3 - <0.3 mg/l TM38/PM0
Ortho Phosphate as PO4 0.06 - <0.03 mg/l TM38/PM0
Dissolved Chromium III <0.002 <0.002 <0.002 mg/l NONE/NONE
Hexavalent Chromium <0.002 <0.002 <0.002 mg/l TM38/PM0
WOP-ADF
Colm Hurley
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
Causeway Geotech
Gemini 16-1239
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 3 of 8
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EPA Export 28-05-2019:04:59:42
Notification of Deviating Samples
J E
Job
No.
Batch Depth J E Sample
No.Analysis Reason
Please note that only samples that are deviating are mentioned in this report. If no samples are listed it is because none were deviating.
Only analyses which are accredited are recorded as deviating if set criteria are not met.
Exova Jones Environmental
Gemini 16-1239
WOP-ADF
Colm HurleyContact:
Sample ID
Client Name: Causeway Geotech
Reference:
Location:
No deviating sample report results for job 17/4799
QF-PM 3.1.11 v3 Please include all sections of this report if it is reproduced 4 of 8
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JE Job No.:
SOILS
DEVIATING SAMPLES
SURROGATES
DILUTIONS
BLANKS
NOTE
Samples must be received in a condition appropriate to the requested analyses. All samples should be submitted to the laboratory in suitable
containers with sufficient ice packs to sustain an appropriate temperature for the requested analysis. If this is not the case you will be informed and
any test results that may be compromised highlighted on your deviating samples report.
Where an MCERTS report has been requested, you will be notified within 48 hours of any samples that have been identified as being outside our
MCERTS scope. As validation has been performed on clay, sand and loam, only samples that are predominantly these matrices, or combinations
of them will be within our MCERTS scope. If samples are not one of a combination of the above matrices they will not be marked as MCERTS
accredited.
Negative Neutralization Potential (NP) values are obtained when the volume of NaOH (0.1N) titrated (pH 8.3) is greater than the volume of HCl (1N)
to reduce the pH of the sample to 2.0 - 2.5. Any negative NP values are corrected to 0.
Where a CEN 10:1 ZERO Headspace VOC test has been carried out, a 10:1 ratio of water to wet (as received) soil has been used.
All samples will be discarded one month after the date of reporting, unless we are instructed to the contrary.
% Asbestos in Asbestos Containing Materials (ACMs) is determined by reference to HSG 264 The Survey Guide - Appendix 2 : ACMs in buildings
listed in order of ease of fibre release.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
Please note we are not a UK Drinking Water Inspectorate (DWI) Approved Laboratory .
If you have not already done so, please send us a purchase order if this is required by your company.
The calculation of Pyrite content assumes that all oxidisable sulphides present in the sample are pyrite. This may not be the case. The calculation
may be an overesitimate when other sulphides such as Barite (Barium Sulphate) are present.
Where analytes have been found in the blank, the sample will be treated in accordance with our laboratory procedure for dealing with contaminated
blanks.
ISO17025 accreditation applies to surface water and groundwater and usually one other matrix which is analysis specific, any other liquids are
outside our scope of accreditation.
As surface waters require different sample preparation to groundwaters the laboratory must be informed of the water type when submitting samples.
Where appropriate please make sure that our detection limits are suitable for your needs, if they are not, please notify us immediately.
Data is only reported if the laboratory is confident that the data is a true reflection of the samples analysed. Data is only reported as accredited when
all the requirements of our Quality System have been met. In certain circumstances where all the requirements of the Quality System have not been
met, for instance if the associated AQC has failed, the reason is fully investigated and documented. The sample data is then evaluated alongside
the other quality control checks performed during analysis to determine its suitability. Following this evaluation, provided the sample results have not
been effected, the data is reported but accreditation is removed. It is a UKAS requirement for data not reported as accredited to be considered
indicative only, but this does not mean the data is not valid.
Where possible, and if requested, samples will be re-extracted and a revised report issued with accredited results. Please do not hesitate to contact
the laboratory if further details are required of the circumstances which have led to the removal of accreditation.
It is assumed that you have taken representative samples on site and require analysis on a representative subsample. Stones will generally be
included unless we are requested to remove them.
All analysis is reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected. Samples are dried at 35°C ±5°C unless
otherwise stated. Moisture content for CEN Leachate tests are dried at 105°C ±5°C.
Surrogate compounds are added during the preparation process to monitor recovery of analytes. However low recovery in soils is often due to peat,
clay or other organic rich matrices. For waters this can be due to oxidants, surfactants, organic rich sediments or remediation fluids. Acceptable
limits for most organic methods are 70 - 130% and for VOCs are 50 - 150%. When surrogate recoveries are outside the performance criteria but
the associated AQC passes this is assumed to be due to matrix effect. Results are not surrogate corrected.
A dilution suffix indicates a dilution has been performed and the reported result takes this into account. No further calculation is required.
NOTES TO ACCOMPANY ALL SCHEDULES AND REPORTS
Please note we are only MCERTS accredited (UK soils only) for sand, loam and clay and any other matrix is outside our scope of accreditation.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
17/4799
WATERS
QF-PM 3.1.9 v34Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 5 of 8
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EPA Export 28-05-2019:04:59:42
JE Job No.:
#
SA
B
DR
M
NA
NAD
ND
NDP
SS
SV
W
+
++
*
AD
CO
LOD/LOR
ME
NFD
BS
LB
N
TB
OC
Matrix Effect
Blank Sample
Client Sample
No Determination Possible
Indicates analyte found in associated method blank.
None Detected (usually refers to VOC and/SVOC TICs).
Samples are dried at 35°C ±5°C
17/4799
AQC failure, accreditation has been removed from this result, if appropriate, see 'Note' on previous page.
Calibrated against a single substance
Not applicable
No Asbestos Detected.
Dilution required.
Analysis subcontracted to a Jones Environmental approved laboratory.
ISO17025 (SANAS) accredited - South Africa.
Outside Calibration Range
No Fibres Detected
Result outside calibration range, results should be considered as indicative only and are not accredited.
Results expressed on as received basis.
Surrogate recovery outside performance criteria. This may be due to a matrix effect.
Trip Blank Sample
AQC Sample
Suspected carry over
Limit of Detection (Limit of Reporting) in line with ISO 17025 and MCERTS
MCERTS accredited.
ISO17025 (UKAS) accredited - UK.
ABBREVIATIONS and ACRONYMS USED
QF-PM 3.1.9 v34Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 6 of 8
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EPA Export 28-05-2019:04:59:42
JE Job No: 17/4799
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required.
PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.PM0 No preparation is required. AR
TM21
Modified USEPA 415.1. Determination of Total Organic Carbon or Total Carbon by
combustion in an Eltra TOC furnace/analyser in the presence of oxygen. The CO2
generated is quantified using infra-red detection.
PM24Dried and ground solid samples are washed with hydrochloric acid, then rinsed with
deionised water to remove the mineral carbon before TOC analysis.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM14
Analysis of waters and leachates for metals by ICP OES/ICP MS. Samples are filtered for
dissolved metals and acidified if required.Yes AR Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.AD Yes
TM30Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7 and 6010BPM15
Acid digestion of dried and ground solid samples using Aqua Regia refluxed at 112.5 °C.
Samples containing asbestos are not dried and ground.Yes AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. Yes AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AD Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AD Yes
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 7 of 8
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EPA Export 28-05-2019:04:59:42
JE Job No: 17/4799
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
AR Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM20
Extraction of dried and ground or as received samples with deionised water in a 2:1
water to solid ratio using a reciprocal shaker for all analytes except hexavalent
chromium. Extraction of as received sample using 10:1 ratio of 0.2M sodium hydroxide to
soil for hexavalent chromium using a reciprocal shaker.
Yes AR Yes
NONE No Method Code NONE No Method Code AR Yes
NONE No Method Code PM4Gravimetric measurement of Natural Moisture Content and % Moisture Content at either
35°C or 105°C. Calculation based on ISO 11465 and BS1377.AR
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 8 of 8
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EPA Export 28-05-2019:04:59:43
181
Appendix 5 Groundwater Analytical Results
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid Report : Liquid
Reference:
Location:
Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 1-8 9-16 17-26 27-34 35-42 51-58 59-66 67-74 75-82 83-92 93-102 103-110 119-126 127-134 NOTES
Sample ID WOP BH02/17 WOP BH04/17 WOP BH05/17 WOP BH06/17 WOP BH09/17WOP-PS-
GW1WOP-PS-GW2
WOP_ADF
BH01/17
WOP_ADF
BH02/17
WOP-ADF
BH03/17
WOP ADF
GW3
WOP ADF
GW4
WOP ADF
GW5
WOP ADF
GW6
Containers V H HN Z P G V H HN Z P G V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G BC V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1 1 1 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
GW Regulations GTV IGV SW EQS checked standards checked results incl units
Metals Dissolved Aluminium # 150 291 20 661 1083 20 20 20 20 20 20 20 20 20 20 When 20<20 <20 ug/l TM30/PM14
Dissolved Arsenic # 7.5 2.5 2.8 5.3 6.7 2.5 2.5 2.5 3 19.8 19.1 2.5 2.5 49.5 14.1 2.5 = <2.5 <2.5 ug/l TM30/PM14
Dissolved Boron 1000 <12 52 18 105 79 27 80 <12 <12 <12 <12 <12 <12 <12 <12 ug/l TM30/PM14
Dissolved Cadmium # 3.75 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 = <0.5 <0.5 ug/l TM30/PM14
Dissolved Calcium # 200000 186.3 143 101.1 54 61.2 148 115.6 98.2 127.7 143.5 95.4 92.7 132 117.4 <0.2 mg/l TM30/PM14
Total Dissolved Chromium # 37.5 1.5 1.5 11.3 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 = <1.5 <1.5 ug/l TM30/PM14
Dissolved Copper # 1500 <7 <7 <7 <7 <7 <7 18 <7 <7 <7 <7 <7 <7 <7 <7 ug/l TM30/PM14
Total Dissolved Iron # 200 20 7588 21 69 20 242 1800 2602 3615 2803 1203 2691 9159 5720 20=<20 <20 ug/l TM30/PM14
Dissolved Lead # 18.75 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ug/l TM30/PM14
Dissolved Magnesium # 50000 <0.1 15.2 0.4 <0.1 17.1 15.1 20.4 10.1 4.5 3.5 4.7 2.2 1.9 5 <0.1 mg/l TM30/PM14
Dissolved Manganese # 50 2 928 2 2 239 823 203 3672 877 168 86 95 56 110 2=<2 <2 ug/l TM30/PM14
Dissolved Mercury # 0.75 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 ug/l TM30/PM14
Dissolved Molybdenum # 65 11 95 109 51 <2 5 4 7 <2 <2 <2 4 <2 <2 ug/l TM30/PM14
Dissolved Nickel # 15 2 9 4 2 2 2 2 2 15 6 2 2 20 2 2 = <2 <2 ug/l TM30/PM14
Dissolved Potassium # 5000 88.5 11.8 42.9 63.7 4.9 0.8 19.9 1.4 1.5 1.7 0.7 10.5 1.6 1.5 <0.1 mg/l TM30/PM14
Dissolved Selenium # <3 <3 5 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 ug/l TM30/PM14
Dissolved Sodium # 150 160.8 96.1 105 193.6 37.2 11 80.4 9 9.9 10.2 7.9 26.7 8.5 7.4 <0.1 mg/l TM30/PM14
Dissolved Zinc # 100 <3 <3 <3 <3 <3 7 <3 <3 <3 4 <3 <3 <3 <3 <3 ug/l TM30/PM14
PAH MS Naphthalene # 1 1.2 <0.1
B<0.1
B<0.1
B<0.1
B<0.1
B<0.1
B<0.1
B<0.1
B<0.1
B<0.1
B<0.1
B0.1
B<0.1
B0.1
B <0.1 ug/l TM4/PM30
Acenaphthylene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Acenaphthene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 0.061 <0.013 <0.013 ug/l TM4/PM30
Fluorene # <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 0.056 <0.014 <0.014 ug/l TM4/PM30
Phenanthrene # 0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 0.03 <0.011 <0.011 ug/l TM4/PM30
Anthracene # 10000 0.1 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 0.019 <0.013 <0.013 ug/l TM4/PM30
Fluoranthene # 1 0.1 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 ug/l TM4/PM30
Pyrene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Benzo(a)anthracene # <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 ug/l TM4/PM30
Chrysene # <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Benzo(bk)fluoranthene # <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 ug/l TM4/PM30
Benzo(a)pyrene # <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 ug/l TM4/PM30
Indeno(123cd)pyrene # 0.05 0.002 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Dibenzo(ah)anthracene # <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(ghi)perylene # 0.05 0.002 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Coronene <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 ug/l TM4/PM30
PAH 17 Total <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 ug/l TM4/PM30
Benzo(b)fluoranthene 0.05 0.002 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(k)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
PAH Surrogate % Recovery 90 92 92 94 89 96 89 91 93 95 95 92 90 92 <0 % TM4/PM30
Methyl Tertiary Butyl Ether # <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - <0.1 ug/l TM15/PM10
Benzene # 0.75 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - <0.5 ug/l TM15/PM10
Toluene # 10 10 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 - - - <5 ug/l TM15/PM10
Ethylbenzene # 10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 - - - <1 ug/l TM15/PM10
p/m-Xylene # 10 <2 <2 <2 <2 <2 7 <2 <2 <2 <2 <2 - - - <2 ug/l TM15/PM10
o-Xylene # 10 <1 <1 <1 <1 <1 3 <1 <1 <1 <1 <1 - - - <1 ug/l TM15/PM10
Surrogate Recovery Toluene D8 113 115 104 118 124 124 114 104 109 99 106 - - - <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 111 116 114 119 117 118 112 107 99 107 99 - - - <0 % TM15/PM10
Pesticides Aldrin 0.01 - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Standards
ESB Networks
West Offaly Power
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
West Offaly Power
LOD/LOR UnitsMethod
No.
GWM 6557 (Gemini)
QF-PM 3.1.2 v11
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Organochlorine Pesticides Alpha-HCH (BHC) - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Beta-HCH (BHC) - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Delta-HCH (BHC) - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Dieldrin 0.075 - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Endosulphan I - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Endosulphan II - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Endosulphan sulphate - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Endrin - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Gamma-HCH (BHC) - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Heptachlor - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Heptachlor Epoxide - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
o,p'-Methoxychlor - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
p,p'-DDE - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
p,p'-DDT 0.01 - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
p,p'-Methoxychlor - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
p,p'-TDE - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Organophosphorus Pesticides Azinphos methyl - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Diazinon - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Dichlorvos 0.001 - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Disulfoton - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Ethion - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Ethyl Parathion (Parathion) - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Fenitrothion - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Malathion - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Methyl Parathion - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Mevinphos - - <0.01 - - - - - - <0.01 <0.01 - - - <0.01 ug/l TM149/PM30
Benazolin - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Bentazone 0.075 - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Bromoxynil 5 - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Clopyralid - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
4 - CPA - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
2,4 - D - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
2,4 - DB - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Dicamba - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Dichloroprop 100 - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Diclofop - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Fenoprop - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Flamprop - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Flamprop – isopropyl - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Ioxynil - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
MCPA 0.075 - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
MCPB - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Mecoprop 0.075 10 - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Picloram - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Pentachlorophenol 2 - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
2,4,5 - T - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
2,3,6 - TBA - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
Triclopyr - - <0.1 - - - - - - <0.1 <0.1 - - - <0.1 ug/l TM42/PM30
TPH CWG >C5-C6 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
Aliphatics >C6-C8 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C8-C10 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C10-C12 # <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ug/l TM5/PM30
>C12-C16 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>C16-C21 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>C21-C35 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
Total aliphatics C5-35 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Aromatics >C5-EC7 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC7-EC8 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC8-EC10 # <10 <10 <10 <10 <10 15 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC10-EC12 # <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ug/l TM5/PM30
>EC12-EC16 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>EC16-EC21 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>EC21-EC35 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
Total aromatics C5-35 # <10 <10 <10 <10 <10 15 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Total aliphatics and aromatics(C5-35) # <10 <10 <10 <10 <10 15 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Phenols Total Phenols HPLC <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - <0.1 <0.1 <0.1 mg/l TM26/PM0
Other Sulphate as SO4 # 187.5 120.9 191 310.9 108.3 162.8 41.3 248.6 1.1 <0.5 18.6 <0.5 <0.5 <0.5 <0.5 <0.5 mg/l TM38/PM0
Chloride # 187.5 53.5 43.8 41.4 83.6 27.9 16.3 50.5 11.5 13.2 47.3 15.3 38.4 11 9.9 <0.3 mg/l TM38/PM0
Nitrate as NO3 # 37.5 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 = <0.02 <0.2 mg/l TM38/PM0
QF-PM 3.1.2 v11
Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 2 of 3
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Nitrite as NO2 # 375 <0.02 0.03 <0.02 <0.02 0.14 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 mg/l TM38/PM0
Ortho Phosphate as P # 30 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 0.04 <0.03 mg/l TM38/PM0
Ammoniacal Nitrogen as N # 0.175 3.69 2.44 6.72 21.29 1.78 0.04 9.81 2.07 9.22 7.52 2.03 3.17 7.95 4.71 <0.03 mg/l TM38/PM0
Ammoniacal Nitrogen as NH3 # 4.48 2.96 8.17 25.89 2.16 0.05 11.92 2.52 11.21 9.14 2.46 3.85 9.67 5.72 <0.03 mg/l TM38/PM0
Hexavalent Chromium <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 mg/l TM38/PM0
Total Dissolved Chromium III <6 <6 11 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 ug/l NONE/NONE
Sulphide <10 <10 <10 20 <10 <10 20 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM106/PM0
COD (Settled) # - - 40 - - - - - - 21 48 - - - <7 mg/l TM57/PM0
Total Coliforms* - - <1 - - - - - - <1 <1 - - - CFU/100ml Subcontracted
Produced: Oonagh Duffy
Checked: Keelin Timoney
Approved: Anne Marie Casey
QF-PM 3.1.2 v11
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185
Appendix 6.Groundwater Laboratory Results
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EPA Export 28-05-2019:04:59:43
Unit 3 Deeside Point
Zone 3
Deeside Industrial Park
Deeside
ESB Networks
Attention :
Date :
Your reference :
Our reference :
Location :
Date samples received :
Status :
Issue :
Anne-Marie Casey
26th May, 2017
1
Exova Jones Environmental
CH5 2UA
Tel: +44 (0) 1244 833780
Fax: +44 (0) 1244 833781
Newcastle West
Co Limerick
Ireland
Registered Address : Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian, EH28 8PL
Sixteen samples were received for analysis on 15th May, 2017 of which sixteen were scheduled for analysis. Please find attached our Test Report
which should be read with notes at the end of the report and should include all sections if reproduced. Interpretations and opinions are outside the
scope of any accreditation, and all results relate only to samples supplied.
All analysis is carried out on as received samples and reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected.
Paul Boden BSc
Project Manager
GWM 6557 (Gemini)
West Offaly Power
15th May, 2017
Final report
Compiled By:
Test Report 17/8629 Batch 1
QF-PM 3.1.1 v16Please include all sections of this report if it is reproduced
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid
Reference:
Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 1-8 9-16 17-26 27-34 35-42 43-50 51-58 59-66 67-74 75-82
Sample ID WOP BH02/17 WOP BH04/17 WOP BH05/17 WOP BH06/17 WOP BH09/17WOP BH09/17
(DUP)
WOP-PS-
GW1
WOP-PS-
GW2WOP BH01/17 WOP BH02/17
Depth
COC No / misc
Containers V H HN Z P G V H HN Z P G V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Dissolved Aluminium # 291 <20 661 1083 <20 <20 <20 <20 <20 <20 <20 ug/l TM30/PM14
Dissolved Arsenic # <2.5 2.8 5.3 6.7 <2.5 <2.5 <2.5 <2.5 3.0 19.8 <2.5 ug/l TM30/PM14
Dissolved Boron <12 52 18 105 79 83 27 80 <12 <12 <12 ug/l TM30/PM14
Dissolved Cadmium # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM30/PM14
Dissolved Calcium # 186.3 143.0 101.1 54.0 61.2 63.0 148.0 115.6 98.2 127.7 <0.2 mg/l TM30/PM14
Total Dissolved Chromium # <1.5 <1.5 11.3 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 ug/l TM30/PM14
Dissolved Copper # <7 <7 <7 <7 <7 <7 <7 18 <7 <7 <7 ug/l TM30/PM14
Total Dissolved Iron # <20 7588 21 69 <20 <20 242 1800 2602 3615 <20 ug/l TM30/PM14
Dissolved Lead # <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ug/l TM30/PM14
Dissolved Magnesium # <0.1 15.2 0.4 <0.1 17.1 17.8 15.1 20.4 10.1 4.5 <0.1 mg/l TM30/PM14
Dissolved Manganese # <2 928 <2 <2 239 233 823 203 3672 877 <2 ug/l TM30/PM14
Dissolved Mercury # <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 ug/l TM30/PM14
Dissolved Molybdenum # 65 11 95 109 51 51 <2 5 4 7 <2 ug/l TM30/PM14
Dissolved Nickel # <2 9 4 <2 <2 <2 <2 <2 2 15 <2 ug/l TM30/PM14
Dissolved Potassium # 88.5 11.8 42.9 63.7 4.9 5.0 0.8 19.9 1.4 1.5 <0.1 mg/l TM30/PM14
Dissolved Selenium # <3 <3 5 <3 <3 <3 <3 <3 <3 <3 <3 ug/l TM30/PM14
Dissolved Sodium # 160.8 96.1 105.0 193.6 37.2 38.8 11.0 80.4 9.0 9.9 <0.1 mg/l TM30/PM14
Dissolved Zinc # <3 <3 <3 <3 <3 <3 7 <3 <3 <3 <3 ug/l TM30/PM14
PAH MS
Naphthalene #
<0.1B
<0.1B
<0.1B
<0.1B
<0.1B
<0.1B
<0.1B
<0.1B
<0.1B
<0.1B <0.1 ug/l TM4/PM30
Acenaphthylene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Acenaphthene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Fluorene # <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 ug/l TM4/PM30
Phenanthrene # 0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Anthracene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Fluoranthene # <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 ug/l TM4/PM30
Pyrene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Benzo(a)anthracene # <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 ug/l TM4/PM30
Chrysene # <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Benzo(bk)fluoranthene # <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 ug/l TM4/PM30
Benzo(a)pyrene # <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 ug/l TM4/PM30
Indeno(123cd)pyrene # <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Dibenzo(ah)anthracene # <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(ghi)perylene # <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Coronene <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 ug/l TM4/PM30
PAH 17 Total <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 ug/l TM4/PM30
Benzo(b)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(k)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
PAH Surrogate % Recovery 90 92 92 94 89 93 96 89 91 93 <0 % TM4/PM30
Methyl Tertiary Butyl Ether # <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 ug/l TM15/PM10
Benzene # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM15/PM10
Toluene # <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ug/l TM15/PM10
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 2 of 16
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Client Name: Report : Liquid
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Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 1-8 9-16 17-26 27-34 35-42 43-50 51-58 59-66 67-74 75-82
Sample ID WOP BH02/17 WOP BH04/17 WOP BH05/17 WOP BH06/17 WOP BH09/17WOP BH09/17
(DUP)
WOP-PS-
GW1
WOP-PS-
GW2WOP BH01/17 WOP BH02/17
Depth
COC No / misc
Containers V H HN Z P G V H HN Z P G V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Ethylbenzene # <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 ug/l TM15/PM10
p/m-Xylene # <2 <2 <2 <2 <2 <2 7 <2 <2 <2 <2 ug/l TM15/PM10
o-Xylene # <1 <1 <1 <1 <1 <1 3 <1 <1 <1 <1 ug/l TM15/PM10
Surrogate Recovery Toluene D8 113 115 104 118 124 129 124 114 104 109 <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 111 116 114 119 117 117 118 112 107 99 <0 % TM15/PM10
Pesticides
Organochlorine Pesticides
Aldrin - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Alpha-HCH (BHC) - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Beta-HCH (BHC) - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Delta-HCH (BHC) - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Dieldrin - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Endosulphan I - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Endosulphan II - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Endosulphan sulphate - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Endrin - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Gamma-HCH (BHC) - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Heptachlor - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Heptachlor Epoxide - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
o,p'-Methoxychlor - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
p,p'-DDE - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
p,p'-DDT - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
p,p'-Methoxychlor - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
p,p'-TDE - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Organophosphorus Pesticides
Azinphos methyl - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Diazinon - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Dichlorvos - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Disulfoton - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Ethion - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Ethyl Parathion (Parathion) - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Fenitrothion - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Malathion - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Methyl Parathion - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Mevinphos - - <0.01 - - - - - - - <0.01 ug/l TM149/PM30
Benazolin - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Bentazone - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Bromoxynil - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Clopyralid - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
4 - CPA - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
2,4 - D - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
2,4 - DB - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 3 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid
Reference:
Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 1-8 9-16 17-26 27-34 35-42 43-50 51-58 59-66 67-74 75-82
Sample ID WOP BH02/17 WOP BH04/17 WOP BH05/17 WOP BH06/17 WOP BH09/17WOP BH09/17
(DUP)
WOP-PS-
GW1
WOP-PS-
GW2WOP BH01/17 WOP BH02/17
Depth
COC No / misc
Containers V H HN Z P G V H HN Z P G V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Dicamba - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Dichloroprop - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Diclofop - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Fenoprop - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Flamprop - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Flamprop – isopropyl - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Ioxynil - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
MCPA - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
MCPB - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Mecoprop - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Picloram - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Pentachlorophenol - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
2,4,5 - T - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
2,3,6 - TBA - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
Triclopyr - - <0.1 - - - - - - - <0.1 ug/l TM42/PM30
TPH CWG
Aliphatics
>C5-C6 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C6-C8 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C8-C10 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C10-C12 # <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ug/l TM5/PM30
>C12-C16 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>C16-C21 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>C21-C35 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
Total aliphatics C5-35 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Aromatics
>C5-EC7 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC7-EC8 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC8-EC10 # <10 <10 <10 <10 <10 <10 15 <10 <10 <10 <10 ug/l TM36/PM12
>EC10-EC12 # <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 ug/l TM5/PM30
>EC12-EC16 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>EC16-EC21 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>EC21-EC35 # <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
Total aromatics C5-35 # <10 <10 <10 <10 <10 <10 15 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Total aliphatics and aromatics(C5-35) # <10 <10 <10 <10 <10 <10 15 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Total Phenols HPLC <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 mg/l TM26/PM0
Sulphate as SO4 # 120.9 191.0 310.9 108.3 162.8 162.0 41.3 248.6 1.1 <0.5 <0.5 mg/l TM38/PM0
Chloride # 53.5 43.8 41.4 83.6 27.9 27.8 16.3 50.5 11.5 13.2 <0.3 mg/l TM38/PM0
Nitrate as NO3 # <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 mg/l TM38/PM0
Nitrite as NO2 # <0.02 0.03 <0.02 <0.02 0.14 0.21 <0.02 <0.02 <0.02 <0.02 <0.02 mg/l TM38/PM0
Ortho Phosphate as P # <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 mg/l TM38/PM0
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 4 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid
Reference:
Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 1-8 9-16 17-26 27-34 35-42 43-50 51-58 59-66 67-74 75-82
Sample ID WOP BH02/17 WOP BH04/17 WOP BH05/17 WOP BH06/17 WOP BH09/17WOP BH09/17
(DUP)
WOP-PS-
GW1
WOP-PS-
GW2WOP BH01/17 WOP BH02/17
Depth
COC No / misc
Containers V H HN Z P G V H HN Z P G V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 11/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Ammoniacal Nitrogen as N # 3.69 2.44 6.72 21.29 1.78 1.76 0.04 9.81 2.07 9.22 <0.03 mg/l TM38/PM0
Ammoniacal Nitrogen as NH3 # 4.48 2.96 8.17 25.89 2.16 2.14 0.05 11.92 2.52 11.21 <0.03 mg/l TM38/PM0
Hexavalent Chromium <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 mg/l TM38/PM0
Total Dissolved Chromium III <6 <6 11 <6 <6 <6 <6 <6 <6 <6 <6 ug/l NONE/NONE
Sulphide <10 <10 <10 20 <10 <10 <10 20 <10 <10 <10 ug/l TM106/PM0
COD (Settled) # - - 40 - - - - - - - <7 mg/l TM57/PM0
Total Coliforms* - - <1 - - - - - - - CFU/100ml Subcontracted
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 5 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid
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Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 83-92 93-102 103-110 111-118 119-126 127-134
Sample ID WOP BH03/17WOP ADF
GW3
WOP ADF
GW4
WOP ADF
GW4(DUP)
WOP ADF
GW5
WOP ADF
GW6
Depth
COC No / misc
Containers V H HN Z P G BC V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Dissolved Aluminium # <20 <20 <20 <20 <20 <20 <20 ug/l TM30/PM14
Dissolved Arsenic # 19.1 <2.5 <2.5 <2.5 49.5 14.1 <2.5 ug/l TM30/PM14
Dissolved Boron <12 <12 <12 <12 <12 <12 <12 ug/l TM30/PM14
Dissolved Cadmium # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM30/PM14
Dissolved Calcium # 143.5 95.4 92.7 95.1 132.0 117.4 <0.2 mg/l TM30/PM14
Total Dissolved Chromium # <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 <1.5 ug/l TM30/PM14
Dissolved Copper # <7 <7 <7 <7 <7 <7 <7 ug/l TM30/PM14
Total Dissolved Iron # 2803 1203 2691 2617 9159 5720 <20 ug/l TM30/PM14
Dissolved Lead # <5 <5 <5 <5 <5 <5 <5 ug/l TM30/PM14
Dissolved Magnesium # 3.5 4.7 2.2 2.2 1.9 5.0 <0.1 mg/l TM30/PM14
Dissolved Manganese # 168 86 95 93 56 110 <2 ug/l TM30/PM14
Dissolved Mercury # <1 <1 <1 <1 <1 <1 <1 ug/l TM30/PM14
Dissolved Molybdenum # <2 <2 <2 <2 4 <2 <2 ug/l TM30/PM14
Dissolved Nickel # 6 <2 <2 <2 20 <2 <2 ug/l TM30/PM14
Dissolved Potassium # 1.7 0.7 10.5 11.5 1.6 1.5 <0.1 mg/l TM30/PM14
Dissolved Selenium # <3 <3 <3 <3 <3 <3 <3 ug/l TM30/PM14
Dissolved Sodium # 10.2 7.9 26.7 27.2 8.5 7.4 <0.1 mg/l TM30/PM14
Dissolved Zinc # 4 <3 <3 <3 <3 <3 <3 ug/l TM30/PM14
PAH MS
Naphthalene #
<0.1B
<0.1B
0.1B
0.1B
<0.1B
0.1B <0.1 ug/l TM4/PM30
Acenaphthylene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Acenaphthene # <0.013 <0.013 <0.013 <0.013 0.061 <0.013 <0.013 ug/l TM4/PM30
Fluorene # <0.014 <0.014 <0.014 <0.014 0.056 <0.014 <0.014 ug/l TM4/PM30
Phenanthrene # <0.011 <0.011 <0.011 <0.011 0.030 <0.011 <0.011 ug/l TM4/PM30
Anthracene # <0.013 <0.013 <0.013 <0.013 0.019 <0.013 <0.013 ug/l TM4/PM30
Fluoranthene # <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 <0.012 ug/l TM4/PM30
Pyrene # <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 <0.013 ug/l TM4/PM30
Benzo(a)anthracene # <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 <0.015 ug/l TM4/PM30
Chrysene # <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Benzo(bk)fluoranthene # <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 <0.018 ug/l TM4/PM30
Benzo(a)pyrene # <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 <0.016 ug/l TM4/PM30
Indeno(123cd)pyrene # <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Dibenzo(ah)anthracene # <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(ghi)perylene # <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 <0.011 ug/l TM4/PM30
Coronene <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 ug/l TM4/PM30
PAH 17 Total <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 <0.295 ug/l TM4/PM30
Benzo(b)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
Benzo(k)fluoranthene <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 ug/l TM4/PM30
PAH Surrogate % Recovery 95 95 92 95 90 92 <0 % TM4/PM30
Methyl Tertiary Butyl Ether # <0.1 <0.1 - - - - <0.1 ug/l TM15/PM10
Benzene # <0.5 <0.5 - - - - <0.5 ug/l TM15/PM10
Toluene # <5 <5 - - - - <5 ug/l TM15/PM10
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 6 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid
Reference:
Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 83-92 93-102 103-110 111-118 119-126 127-134
Sample ID WOP BH03/17WOP ADF
GW3
WOP ADF
GW4
WOP ADF
GW4(DUP)
WOP ADF
GW5
WOP ADF
GW6
Depth
COC No / misc
Containers V H HN Z P G BC V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Ethylbenzene # <1 <1 - - - - <1 ug/l TM15/PM10
p/m-Xylene # <2 <2 - - - - <2 ug/l TM15/PM10
o-Xylene # <1 <1 - - - - <1 ug/l TM15/PM10
Surrogate Recovery Toluene D8 99 106 - - - - <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 107 99 - - - - <0 % TM15/PM10
Pesticides
Organochlorine Pesticides
Aldrin <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Alpha-HCH (BHC) <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Beta-HCH (BHC) <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Delta-HCH (BHC) <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Dieldrin <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Endosulphan I <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Endosulphan II <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Endosulphan sulphate <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Endrin <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Gamma-HCH (BHC) <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Heptachlor <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Heptachlor Epoxide <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
o,p'-Methoxychlor <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
p,p'-DDE <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
p,p'-DDT <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
p,p'-Methoxychlor <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
p,p'-TDE <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Organophosphorus Pesticides
Azinphos methyl <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Diazinon <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Dichlorvos <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Disulfoton <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Ethion <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Ethyl Parathion (Parathion) <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Fenitrothion <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Malathion <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Methyl Parathion <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Mevinphos <0.01 <0.01 - - - - <0.01 ug/l TM149/PM30
Benazolin <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Bentazone <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Bromoxynil <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Clopyralid <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
4 - CPA <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
2,4 - D <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
2,4 - DB <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 7 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid
Reference:
Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 83-92 93-102 103-110 111-118 119-126 127-134
Sample ID WOP BH03/17WOP ADF
GW3
WOP ADF
GW4
WOP ADF
GW4(DUP)
WOP ADF
GW5
WOP ADF
GW6
Depth
COC No / misc
Containers V H HN Z P G BC V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Dicamba <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Dichloroprop <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Diclofop <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Fenoprop <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Flamprop <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Flamprop – isopropyl <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Ioxynil <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
MCPA <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
MCPB <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Mecoprop <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Picloram <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Pentachlorophenol <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
2,4,5 - T <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
2,3,6 - TBA <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
Triclopyr <0.1 <0.1 - - - - <0.1 ug/l TM42/PM30
TPH CWG
Aliphatics
>C5-C6 # <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C6-C8 # <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C8-C10 # <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>C10-C12 # <5 <5 <5 <5 <5 <5 <5 ug/l TM5/PM30
>C12-C16 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>C16-C21 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>C21-C35 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
Total aliphatics C5-35 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Aromatics
>C5-EC7 # <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC7-EC8 # <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC8-EC10 # <10 <10 <10 <10 <10 <10 <10 ug/l TM36/PM12
>EC10-EC12 # <5 <5 <5 <5 <5 <5 <5 ug/l TM5/PM30
>EC12-EC16 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>EC16-EC21 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
>EC21-EC35 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/PM30
Total aromatics C5-35 # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Total aliphatics and aromatics(C5-35) # <10 <10 <10 <10 <10 <10 <10 ug/l TM5/TM36/PM30/PM12
Total Phenols HPLC <0.1 <0.1 - - <0.1 <0.1 <0.1 mg/l TM26/PM0
Sulphate as SO4 # 18.6 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 mg/l TM38/PM0
Chloride # 47.3 15.3 38.4 39.5 11.0 9.9 <0.3 mg/l TM38/PM0
Nitrate as NO3 # <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 mg/l TM38/PM0
Nitrite as NO2 # <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 mg/l TM38/PM0
Ortho Phosphate as P # <0.03 <0.03 <0.03 <0.03 <0.03 0.04 <0.03 mg/l TM38/PM0
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 8 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: Report : Liquid
Reference:
Location:
Contact: Liquids/products: V=40ml vial, G=glass bottle, P=plastic bottle
JE Job No.: 17/8629 H=H2SO4, Z=ZnAc, N=NaOH, HN=HN03
J E Sample No. 83-92 93-102 103-110 111-118 119-126 127-134
Sample ID WOP BH03/17WOP ADF
GW3
WOP ADF
GW4
WOP ADF
GW4(DUP)
WOP ADF
GW5
WOP ADF
GW6
Depth
COC No / misc
Containers V H HN Z P G BC V H HN Z P G BC V H HN Z P G V H HN Z P G V H HN Z P G V H HN Z P G
Sample Date 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
Ammoniacal Nitrogen as N # 7.52 2.03 3.17 3.13 7.95 4.71 <0.03 mg/l TM38/PM0
Ammoniacal Nitrogen as NH3 # 9.14 2.46 3.85 3.80 9.67 5.72 <0.03 mg/l TM38/PM0
Hexavalent Chromium <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 <0.006 mg/l TM38/PM0
Total Dissolved Chromium III <6 <6 <6 <6 <6 <6 <6 ug/l NONE/NONE
Sulphide <10 <10 <10 <10 <10 <10 <10 ug/l TM106/PM0
COD (Settled) # 21 48 - - - - <7 mg/l TM57/PM0
Total Coliforms* <1 <1 - - - - CFU/100ml Subcontracted
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
QF-PM 3.1.2 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 9 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: SVOC Report : Liquid
Reference:
Location:
Contact:
JE Job No.: 17/8629
J E Sample No. 1-8 17-26 51-58 83-92 93-102
Sample ID WOP BH02/17 WOP BH05/17WOP-PS-
GW1WOP BH03/17
WOP ADF
GW3
Depth
COC No / misc
Containers V H HN Z P G V H HN Z P G BC V H HN Z P G V H HN Z P G BC V H HN Z P G BC
Sample Date 11/05/2017 11/05/2017 11/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
SVOC MS
Phenols
2-Chlorophenol # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
2-Methylphenol # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
2-Nitrophenol <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
2,4-Dichlorophenol # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
2,4-Dimethylphenol <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
2,4,5-Trichlorophenol # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
2,4,6-Trichlorophenol <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
4-Chloro-3-methylphenol # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
4-Methylphenol <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
4-Nitrophenol <10 <10 <10 <10 <10 <10 ug/l TM16/PM30
Pentachlorophenol <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Phenol <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
PAHs
2-Chloronaphthalene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
2-Methylnaphthalene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Phthalates
Bis(2-ethylhexyl) phthalate <5 <5 <5 <5 <5 <5 ug/l TM16/PM30
Butylbenzyl phthalate <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Di-n-butyl phthalate #
<1.5+ <1.5 <1.5 <1.5 <1.5 <1.5 ug/l TM16/PM30
Di-n-Octyl phthalate <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Diethyl phthalate # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Dimethyl phthalate <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Other SVOCs
1,2-Dichlorobenzene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
1,2,4-Trichlorobenzene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
1,3-Dichlorobenzene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
1,4-Dichlorobenzene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
2-Nitroaniline <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
2,4-Dinitrotoluene # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
2,6-Dinitrotoluene <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
3-Nitroaniline <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
4-Bromophenylphenylether # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
4-Chloroaniline <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
4-Chlorophenylphenylether # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
4-Nitroaniline <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
Azobenzene # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
Bis(2-chloroethoxy)methane # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
Bis(2-chloroethyl)ether # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Carbazole # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
Dibenzofuran # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
Hexachlorobenzene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Hexachlorobutadiene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Hexachlorocyclopentadiene <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Hexachloroethane # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Isophorone # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
N-nitrosodi-n-propylamine # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM16/PM30
Nitrobenzene # <1 <1 <1 <1 <1 <1 ug/l TM16/PM30
Surrogate Recovery 2-Fluorobiphenyl 112 102 105 116 102 <0 % TM16/PM30
Surrogate Recovery p-Terphenyl-d14 75 71 72 79 80 <0 % TM16/PM30
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
QF-PM 3.1.3 v11Please include all sections of this report if it is reproduced
All solid results are expressed on a dry weight basis unless stated otherwise. 10 of 16
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EPA Export 28-05-2019:04:59:43
Client Name: VOC Report : Liquid
Reference:
Location:
Contact:
JE Job No.: 17/8629
J E Sample No. 1-8 17-26 51-58 83-92 93-102
Sample ID WOP BH02/17 WOP BH05/17WOP-PS-
GW1WOP BH03/17
WOP ADF
GW3
Depth
COC No / misc
Containers V H HN Z P G V H HN Z P G BC V H HN Z P G V H HN Z P G BC V H HN Z P G BC
Sample Date 11/05/2017 11/05/2017 11/05/2017 10/05/2017 10/05/2017
Sample Type Ground Water Ground Water Ground Water Ground Water Ground Water
Batch Number 1 1 1 1 1
Date of Receipt 15/05/2017 15/05/2017 15/05/2017 15/05/2017 15/05/2017
VOC MS
Dichlorodifluoromethane <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Methyl Tertiary Butyl Ether # <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 ug/l TM15/PM10
Chloromethane # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Vinyl Chloride # <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 ug/l TM15/PM10
Bromomethane <1 <1 <1 <1 <1 <1 ug/l TM15/PM10
Chloroethane # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Trichlorofluoromethane # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,1-Dichloroethene (1,1 DCE) # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Dichloromethane (DCM) # <5 <5 <5 <5 <5 <5 ug/l TM15/PM10
trans-1-2-Dichloroethene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,1-Dichloroethane # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
cis-1-2-Dichloroethene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
2,2-Dichloropropane <1 <1 <1 <1 <1 <1 ug/l TM15/PM10
Bromochloromethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Chloroform # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,1,1-Trichloroethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,1-Dichloropropene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Carbon tetrachloride # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,2-Dichloroethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Benzene # <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ug/l TM15/PM10
Trichloroethene (TCE) # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,2-Dichloropropane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Dibromomethane # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Bromodichloromethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
cis-1-3-Dichloropropene <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Toluene # <5 <5 <5 <5 <5 <5 ug/l TM15/PM10
trans-1-3-Dichloropropene <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,1,2-Trichloroethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Tetrachloroethene (PCE) # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,3-Dichloropropane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Dibromochloromethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,2-Dibromoethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Chlorobenzene # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,1,1,2-Tetrachloroethane # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Ethylbenzene # <1 <1 <1 <1 <1 <1 ug/l TM15/PM10
p/m-Xylene # <2 <2 7 <2 <2 <2 ug/l TM15/PM10
o-Xylene # <1 <1 3 <1 <1 <1 ug/l TM15/PM10
Styrene <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Bromoform # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
Isopropylbenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,1,2,2-Tetrachloroethane <4 <4 <4 <4 <4 <4 ug/l TM15/PM10
Bromobenzene # <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,2,3-Trichloropropane # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Propylbenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
2-Chlorotoluene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,3,5-Trimethylbenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
4-Chlorotoluene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
tert-Butylbenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,2,4-Trimethylbenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
sec-Butylbenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
4-Isopropyltoluene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,3-Dichlorobenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,4-Dichlorobenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
n-Butylbenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,2-Dichlorobenzene # <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
1,2-Dibromo-3-chloropropane <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,2,4-Trichlorobenzene <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Hexachlorobutadiene <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Naphthalene <2 <2 <2 <2 <2 <2 ug/l TM15/PM10
1,2,3-Trichlorobenzene <3 <3 <3 <3 <3 <3 ug/l TM15/PM10
Surrogate Recovery Toluene D8 113 104 124 99 106 <0 % TM15/PM10
Surrogate Recovery 4-Bromofluorobenzene 111 114 118 107 99 <0 % TM15/PM10
West Offaly Power
Anne-Marie Casey
Please see attached notes for all
abbreviations and acronyms
LOD/LOR UnitsMethod
No.
Exova Jones Environmental
ESB Networks
GWM 6557 (Gemini)
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Notification of Deviating Samples
J E
Job
No.
Batch Depth J E Sample
No.Analysis Reason
Please note that only samples that are deviating are mentioned in this report. If no samples are listed it is because none were deviating.
Only analyses which are accredited are recorded as deviating if set criteria are not met.
Exova Jones Environmental
GWM 6557 (Gemini)
West Offaly Power
Anne-Marie CaseyContact:
Sample ID
Client Name: ESB Networks
Reference:
Location:
No deviating sample report results for job 17/8629
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JE Job No.:
SOILS
DEVIATING SAMPLES
SURROGATES
DILUTIONS
BLANKS
NOTE
Samples must be received in a condition appropriate to the requested analyses. All samples should be submitted to the laboratory in suitable
containers with sufficient ice packs to sustain an appropriate temperature for the requested analysis. If this is not the case you will be informed and
any test results that may be compromised highlighted on your deviating samples report.
Where an MCERTS report has been requested, you will be notified within 48 hours of any samples that have been identified as being outside our
MCERTS scope. As validation has been performed on clay, sand and loam, only samples that are predominantly these matrices, or combinations
of them will be within our MCERTS scope. If samples are not one of a combination of the above matrices they will not be marked as MCERTS
accredited.
Negative Neutralization Potential (NP) values are obtained when the volume of NaOH (0.1N) titrated (pH 8.3) is greater than the volume of HCl (1N)
to reduce the pH of the sample to 2.0 - 2.5. Any negative NP values are corrected to 0.
Where a CEN 10:1 ZERO Headspace VOC test has been carried out, a 10:1 ratio of water to wet (as received) soil has been used.
All samples will be discarded one month after the date of reporting, unless we are instructed to the contrary.
% Asbestos in Asbestos Containing Materials (ACMs) is determined by reference to HSG 264 The Survey Guide - Appendix 2 : ACMs in buildings
listed in order of ease of fibre release.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
Please note we are not a UK Drinking Water Inspectorate (DWI) Approved Laboratory .
If you have not already done so, please send us a purchase order if this is required by your company.
The calculation of Pyrite content assumes that all oxidisable sulphides present in the sample are pyrite. This may not be the case. The calculation
may be an overesitimate when other sulphides such as Barite (Barium Sulphate) are present.
Where analytes have been found in the blank, the sample will be treated in accordance with our laboratory procedure for dealing with contaminated
blanks.
ISO17025 accreditation applies to surface water and groundwater and usually one other matrix which is analysis specific, any other liquids are
outside our scope of accreditation.
As surface waters require different sample preparation to groundwaters the laboratory must be informed of the water type when submitting samples.
Where appropriate please make sure that our detection limits are suitable for your needs, if they are not, please notify us immediately.
Data is only reported if the laboratory is confident that the data is a true reflection of the samples analysed. Data is only reported as accredited when
all the requirements of our Quality System have been met. In certain circumstances where all the requirements of the Quality System have not been
met, for instance if the associated AQC has failed, the reason is fully investigated and documented. The sample data is then evaluated alongside
the other quality control checks performed during analysis to determine its suitability. Following this evaluation, provided the sample results have not
been effected, the data is reported but accreditation is removed. It is a UKAS requirement for data not reported as accredited to be considered
indicative only, but this does not mean the data is not valid.
Where possible, and if requested, samples will be re-extracted and a revised report issued with accredited results. Please do not hesitate to contact
the laboratory if further details are required of the circumstances which have led to the removal of accreditation.
It is assumed that you have taken representative samples on site and require analysis on a representative subsample. Stones will generally be
included unless we are requested to remove them.
All analysis is reported on a dry weight basis unless stated otherwise. Results are not surrogate corrected. Samples are dried at 35°C ±5°C unless
otherwise stated. Moisture content for CEN Leachate tests are dried at 105°C ±5°C.
Surrogate compounds are added during the preparation process to monitor recovery of analytes. However low recovery in soils is often due to peat,
clay or other organic rich matrices. For waters this can be due to oxidants, surfactants, organic rich sediments or remediation fluids. Acceptable
limits for most organic methods are 70 - 130% and for VOCs are 50 - 150%. When surrogate recoveries are outside the performance criteria but
the associated AQC passes this is assumed to be due to matrix effect. Results are not surrogate corrected.
A dilution suffix indicates a dilution has been performed and the reported result takes this into account. No further calculation is required.
NOTES TO ACCOMPANY ALL SCHEDULES AND REPORTS
Please note we are only MCERTS accredited (UK soils only) for sand, loam and clay and any other matrix is outside our scope of accreditation.
Where Mineral Oil or Fats, Oils and Grease is quoted, this refers to Total Aliphatics C10-C40.
17/8629
WATERS
QF-PM 3.1.9 v34Please include all sections of this report if it is reproduced
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JE Job No.:
#
SA
B
DR
M
NA
NAD
ND
NDP
SS
SV
W
+
++
*
AD
CO
LOD/LOR
ME
NFD
BS
LB
N
TB
OC
Matrix Effect
Blank Sample
Client Sample
No Determination Possible
Indicates analyte found in associated method blank.
None Detected (usually refers to VOC and/SVOC TICs).
Samples are dried at 35°C ±5°C
Analysis subcontracted to a Jones Environmental approved laboratory.
AQC failure, accreditation has been removed from this result, if appropriate, see 'Note' on previous page.
Calibrated against a single substance
Not applicable
No Asbestos Detected.
Dilution required.
ISO17025 (SANAS) accredited - South Africa.
Outside Calibration Range
No Fibres Detected
Result outside calibration range, results should be considered as indicative only and are not accredited.
Results expressed on as received basis.
Surrogate recovery outside performance criteria. This may be due to a matrix effect.
Trip Blank Sample
AQC Sample
Suspected carry over
Limit of Detection (Limit of Reporting) in line with ISO 17025 and MCERTS
MCERTS accredited.
ISO17025 (UKAS) accredited - UK.
17/8629
ABBREVIATIONS and ACRONYMS USED
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JE Job No: 17/8629
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex.
TM4Modified USEPA 8270 method for the solvent extraction and determination of 16 PAHs
by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. Yes
TM5Modified USEPA 8015B method for the determination of solvent Extractable Petroleum
Hydrocarbons (EPH) with carbon banding within the range C8-C40 GC-FID. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. Yes
TM5/TM36
TM005: Modified USEPA 8015B. Determination of solvent Extractable Petroleum
Hydrocarbons (EPH) including column fractionation in the carbon range of C10-35 into
aliphatic and aromatic fractions by GC-FID.
TM036: Modified USEPA 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C5-10 by headspace GC-FID. Including determination of
BTEX and calculation of Aliphatic fractions.
PM30/PM12 CWG GC-FID Yes
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.
TM15Modified USEPA 8260. Quantitative Determination of Volatile Organic Compounds
(VOCs) by Headspace GC-MS.PM10
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis. Yes
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex.
TM16Modified USEPA 8270. Quantitative determination of Semi-Volatile Organic compounds
(SVOCs) by GC-MS. PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex. Yes
TM26Determination of phenols by Reversed Phased High Performance Liquid
Chromatography and Electro-Chemical Detection.PM0 No preparation is required.
TM30
Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7, 6010B and BS EN ISO
11885 2009
PM14Analysis of waters and leachates for metals by ICP OES/ICP MS. Samples are filtered for
dissolved metals and acidified if required.
Exova Jones Environmental Method Code Appendix
QF-PM 3.1.10 v14 Please include all sections of this report if it is reproduced 15 of 16
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JE Job No: 17/8629
Test Method No. Description
Prep Method
No. (if
appropriate)
Description
ISO
17025
(UKAS/S
ANAS)
MCERTS
(UK soils
only)
Analysis done
on As Received
(AR) or Dried
(AD)
Reported on
dry weight
basis
TM30
Determination of Trace Metal elements by ICP-OES (Inductively Coupled Plasma -
Optical Emission Spectrometry). Modified US EPA Method 200.7, 6010B and BS EN ISO
11885 2009
PM14Analysis of waters and leachates for metals by ICP OES/ICP MS. Samples are filtered for
dissolved metals and acidified if required.Yes
TM36Modified US EPA method 8015B. Determination of Gasoline Range Organics (GRO) in
the carbon chain range of C4-12 by headspace GC-FID. PM12
Modified US EPA method 5021. Preparation of solid and liquid samples for GC
headspace analysis.Yes
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required.
TM38Soluble Ion analysis using the Thermo Aquakem Photometric Automatic Analyser.
Modified US EPA methods 325.2, 375.4, 365.2, 353.1, 354.1PM0 No preparation is required. Yes
TM42 Modified US EPA method 8270. Pesticides and herbicdes by GC-MS PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex.
TM57Modified US EPA Method 410.4. Chemical Oxygen Demand is determined by hot
digestion with Potassium Dichromate and measured spectrophotometerically.PM0 No preparation is required. Yes
TM106 Determination of Sulphide by Skalar Continuous Flow Analyser PM0 No preparation is required.
TM149Determination of Pesticides by Large Volume Injection on GC Triple Quad MS, based
upon USEPA method 8270PM30 Water samples are extracted with solvent using a magnetic stirrer to create a vortex.
NONE No Method Code NONE No Method Code
Subcontracted Subcontracted analysis, sent to an ISO 17025 accredited laboratory where possible.
Exova Jones Environmental Method Code Appendix
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