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~ B o
"ito
~ o - 3 3 0 0 4 / 9 9
REGD.
NO. n
L.-33004/99
~ " P t . I
fil
Q ne
< 5 a ~ e t t e
o
n d i a
a m r ~ : m O I
EXTRAORDINARY
'mlTH-l.9U'$ 3 - d ' Q " - ~ (i)
PART
n-Section
3-Sub-section
(i)
it 9(f11i1tlfl
PUBLISHEDBY
AUTIlORlTY
9,
18, 1934
781
No.
NEW NOVEMBER
20t2IKARTIKA
1934
q:qfi lWI
am Cf1
~ ~ , 9 ~ , 2 0 1 2
m:CfiT:A. 8 2 0 ( 3 T ) . - ~ mcfiR, ('W8JUT) 3 1 f ~ , 1986 (1986q;r29) Cfi1 1:ffiJ 11
a:m:
25
*
31Qt::r>r0
q;r
m
~ ~ ,
Cffi:8JUT)
f.T<ri:I, 1986q;ram
~ ~ enB
~
~
f . p : 1 f ~ f { i j J d
f.T<ri:I
or-mit
t
312lfu:
1.
t) ~ f . F : r q ' f q ; r m ~ - , r q ~ (ma;rur)
( . , . , f r ~ ~ ~ ) ~ ,
2012i I
(2) i t ~ - B ~ < t t m t h : § j - A ~ ~ I
2.
(ma;rur)
f.r<rtr,
1986
-B : -
(Cfl) I-B
~ ~
38,
~ t i l q i f I 1 C f i i 1
( 3 1 1 ~ a f u : ~ ) afu: ~ ~
~ '11:,-
CD
1=< f
P
Q 2 ~
3 1 ~
'Ifq
fte.< fY
-B,
~
wax\
~
~
1:f{ f.n:;:j 31an: am
wax\
"31.
~
w
~
I
i i)
31'cr
-B, f.rq > f C l ~ 4 i -nm ~ , .-
( ~ , ~ ,
~ , clllsqlCfiI(Cfi)
~ ~ ( S 0 2 )
~ ~
50
1150
250
50
1700
350
~ ( N O )
(f{(.Yf 450
350
~ q : ) U [ (PM)
i1B
10 05
(f{(.Yf 100
50
CfiTiif.:r
~
i1B 150
100
(CO) (f{(.Yf 200 150
fZU1'ilit.-( 1 ) ~ i f t i.TRf"ifiT 3% 1:f{
~
fen4r \lITQ; I
(2)
FSCfilf
c
;'ll ~ ~ 1:f{ ~ l"1l-A
fcl:;<;rr
\lITQ;
I
(3) f i T i i f . : r ~ ~ 1 ~ ~ I ~ : g
(PA) ~ 1 ~ ~ I g
(MA)
- M ~ ~
(PTA)
a m : ~ ~ ~
(DMT)
~ ~ 1 . J T i B - B t h r . m m r ~
~ I ~ ~ ~ ~ ~ ~ P A I M A ~ e n B t T I ~ ~ 3 0 0 0 0
r-r>rft;
crr:f
-A <i>l1 Cfi1 f.l4dY11 ~ -B i.1Tll ~ ~ , <@{ ~ )lCfl]\Cfi1 ~ ~ ~
' J : n ; ; c ~
~
~
<i>l1
~
<li11
30
~
<tt
fqq;ft
m
I
4279
GI12012
(I)
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THE GAZETTE OF INDIA: EXTRAORDINARY
IPART
l ~ S E C .
0 2)
(3 )
4)
_____________
. _____________ , ..
1 - _.
____________________
~ ) 1 l
~ 1 ~ l C f ( > l 1 f h f l 3fcF{>f
~ i ~ cillc ct:m
~
30
c m ~
31tHl
fc:llli
;:m;r
~ Q$) (> lc·i)S;:I$(>
cillc, 75
4iYli>1CfcCfl cillc
~ ~
iiW:m
R l ~ c i l c - c , cillc
~ ~ ~ _ ~ = ~ l ( M ~ ) 3-fR ( Q C l 1 d T ~ )
_C(>Iie +
_______________
+ __
-------1
. E'1$$1;jf<i1 fll$"11$5 Q$)(>l);;:fJ?I$(>I
cillc
, (HeN)
cfl3lMr(HAPs
)
t ) - g t ~
3-fR
~ ~
t)-gt3n"$,
1 1 1 ~ ' I I
i>f <i1
BfCti..t
III (>I
~
fI'lfll Ac
~ ~ )
~
---
- ~ - - - - - - - - -
,¥151$<i1
cillc
0.1
5.0
5.0
i
{jT3lMr (HAPs), 3 f t , C I ~ l f I ~ Q J ' I ,
~ , ~ ,
QT3IT
~ .----
20.0--- -10.'0\
~ : ; ; : ' - . ,----,--.--,-J
C f i l ~ f c l ~
fctfclmCfiUT _Q'rQ", lJJ'I1 3-fR
t ) - g t ~ cillc
I _
50
2 ~ ~
USfiiR' 3( f1dif1l f l l f j I r ; q ~ )
,
d
mer ~ ~ flr iIJT i ~ m:J
~ a t
t t -
{jT
3lMr
(lJJ'I1 , Q'rQ" 3-fR lJJ'I1 ,
Q'rQ",
cillc
20
. ~
~
JlI';Ii>f)<i1,
~
JlI$i>f)<i1,
(HMR:CftI, ~ 3-fR tfh;fr)
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~ tfh;fr
cillc
o
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3 - f R ~ )
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_' _ .. ___________________
.
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Q ~ : H C f i e : t R l l
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gQCJ &
3RR
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I
1
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3
'llflT
1 I ~ 3 i)]
(J) 4 ~ 75 ElG1i1:flC{ $" ~ cfi r a:r.AC1T c;m;t
tq;- Jf'R
~ ~ ~ ~ fcnm ~ AA lR,
~ u : c T ~
~
a2IT
q ~ c m q ~ ~ ~ ~
I
(2)
75
~
500 ElG1< 1:i lc{
cfi r
a:r.AC1T Cffiit tq;- Jf'R
~
CJ.ll>q
~
10
~
76
fcnm
$
~ AA lR,
u:cT
3 1 1 c - 1 ~ t f )
tffi:ft"
.wrm 'Cll(J
tffi:ft"
~
Jf'RCl'T&l
cfi r
Uq;2ITd1
3 f ~ CITIm
f I " - ( : ~ ) ( ' C 1
~ ~ ~ I
(3)
500 ttG1A'kA
~ 3fRtCfi a:r.AC1T c;m;t
tq;- Jf'R
~ ~ ~ 10 ~
76
fcnm $" ~
AA
Q1", u:cT 311..-(1 f{tf)
3fm:rT
'Cll(J
~ Jf'RCITIm Uq;2ITd1 ~
I
(4) 75 ElCitA",c{ ~ a:r.AC1T c;m;t
tq;-
Jf'R ~ ~ ~ 76
fcnm
QTftf) if ~ AA lR, u:cT
J f R C I T I m ~ ~ ~ ~ ~
I
(i)
(Cfl) i cfi r
3 1 1 c - ( 1 ~ C h
q:(>Iij1d!
u:cT
Jf'R
ClTPT
q:(>Ilftal
u:cT 96%
cfi r
dl,C1(1<H CITIm
cfi r ¥:
mR?r
~ ~ m ~ ~ q m r ~ I
(l.9)
lfNlj1<11
~ cfi r
~ ~
~
~
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m
tq;-
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u:rm
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200 mt
nfiC{
tJm I
(dT) Jf'tur ~ f{1flR ~ ~ Itfi<;r
cfi r 1.3 {t.m. ~ Jf'R
m 'tci1 $"u:rmq;r
20
mt{t.m. /;RTc-{tJ<rrr I
(i)(Cfl)
M CfiT
~ a : r u r
Jf'R
- n m c : r
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RP
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~ I
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__
4 THE GAZETTE OF INDIA: EXTRA.oRDINARY
II-SEC.
(I)
~ r i u:cT ~
tq,
at
lllfJll4l{UI c);
crp;;q
c); ~
crp;;q!.!ft>r 4lIJfc:l4l
;q1fJlChl
(YOC) cfiI ' l
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~ ; 3 1 ~
rn
f i l 3 l I ( I ~ q : ;
~
B ( 1 / ~
~
0;(1
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u;('1' cfiI m-;Jf ~ ~ si'h: ~
fri
c); 'fIT2T ~
'Cfi'di
~
qgr 99%
c f i I ~ ; ~
(3) 3i"h' B 1 c);
~ 3i1c-("If{q:;
~ si'h:CiI$;;.hICi
3flCRUT
4lT an l l
i)
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.w:rc:rr
(ii)
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( f:1.ff
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i) YOcGfli'!c:fi,%
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ii) 5("8;;;lCi, f.!1aJr/QCiJfIC{
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__
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(i
)
5f { I di
Ci,
fa :r.
.IT.I
QCi JOtI
c,,{
~ , 3 1 ~ :
- . - - · - - - - - · - · - - - - · - r - - - - - - - - -
w . ~ .
3llPT
f------f------..
"9
c.tiliifo'lc.ti
fcrfc:rffi
C,fiUT
_ . _ _ . _ -
.
VOC-HAPs
c : T f t ~ q C 1 ' - ~ - : : 3 i I $ { : n ' B I $ ~ e ( t r . g J . ~ . )
( O O ~ , J : . T J I t r ~ )
f a : r ~ sl$fCnCif$(>f,
g l $ f i 1 C ' 1 I $ ~ c
~ ~ ) CNic: 5("'B;;aCi
VOC-HAPs
~
(I,< \CJ51$Ci )
-------,.-.--+-------..------------
..
- - . ~
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.
~ . 3 f t ,
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4'lfi'tQ(}f, ~ ,
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5\'8di01
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Q C i ~ I $ ; i 1 $ 5 (llJI".Q') ~ - ~
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~
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5
~ n ~
3(i)]
3 1 ~ f { : ~ - J(>II Chl(>l,
QtJfr-q)fQJlCi
d(>lI Ch)(>I, ~ 3 i T - ~ 31ICf'HI 5,
i:rlfi'IQJl-RlCilll(>l
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~ ~ ~ ~
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31ICffll$5, Q : q f f h f i i ~
tll C1I S " I
[CfiT. tf. ~ 1 5 0 l 7 / l 2 1 2 0 0 R m . c I T . s ~ J
~ r < W i T ~ ~
~ . - 1 F l 3 1 f ~ l R R < t ~ - q ~ . 3 1 T .
8 4 4 ( ~ ) , ~
1 9 ~
1986
~ ~ C f f t ~ ~ ~ ~ ~ t f .
Cl iT.3IT.433 (31)
18:mt<>r
1987; JfR 3 1 ~ ~ dfm.Cl iT.fc1 512
(31),
9 2009; m.CIiT.fc1 543
(31),
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794
(31) 4 2009;
m.CIiT.f.i 826 (31) 6 ~
2009;
m.CIiT.fc1
01 (31)
1
2010; m.CIiT.fc1 61 (31) c:rrfug 5
2010;
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485 (31) 9 ¥ 2010; m.CIiT.fc1
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(31)
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9
RldkH 2010; m.CfiT.fc1 809 (31) 4 2010; m.CIiT.fc1 215 (31) c:rrfug 15 2011; m.CIiT.fc1 221
(31)
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18 ~ 2011; m.CIiT.fc:t 354 (31) 2 ~ 2011; m.CIiT.fc:t
424
(31) c:rrfug 1
¥
2011; m.CIiT.fc:t
446 (31) 13 WI 2011; m.CIiT.fc1. 152 (31) 16 2012; m.CIiT.fc1. 266 (31) 30 2012
3iR' m.CIiT.fc:t. 277 (31) 3 1 Jl'T' 2012 c)l t i ~ i i t f ; ; : r f t j .rnr I
MINISTRY OF ENVIRONMENT AND FORESTS
NOTIFICATION
New Delhi, the 9th November, 2012
GS.R.
820 E).-
In exercise of the powers conferred by sections 6 and
25
of the Environment
(Protection) Act, 1986 (29 of 1986), the Central Government hereby makes the following rules further to
amend the Environment (Protection) Rules, 1986, namely:
1.
(1) These rules may be called the Environment (Protection) Fourth Amendment Rules, 2012.
(2) They shall come into force on the date of their publication in the Official Gazette.
2. In the Environment (Protection) Rules, 1986,
(a) in Schedule
I,
in the entries against serial number 38 relating to 'Petrochemical (Basic and
Intermediates ),
(i) in the entries under column 2, for the word "EFFLUENT", the letter and word "A.
Effluent" shall be substituted;
ii) at the end, the following entries shall be inserted, namely:
S.No.
Industry
Parameter
Standards
(1)
(2)
(3) (4)
B. Emission
from Chimney Stack
... ~ .
Limiting concentration in mglNm
j
, unless stated
Fuel Type Existing
INew
plants
Expansion of
"(Furnace,
Plants
. Existing
Plant
Boiler,
Sulphur Dioxide Gas 50
I
50
Heater,
(
S0
2)
850
iquid 1700
Vaporiser)
350 250
xides of Nitrogen
. Gas
(NOx)
350
iquid 450
I
Particulate Matter
I
Gas
05
0
(PM)
50
iquid
100
-
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6
THE GAZETTE OF INDIA: EXTRAORDINARY
-
(1)
(2)
(3)
I
4)
ICarbon Monoxide
~
I
150
I
100
, (CO)
150
------
200
I
iquid
I
Note,
(i)
All values shall be corrected to 3% Oxygen.
(ii)
Wet scrubber shall necessarily
be
operated at
the
time of decoking.
(iii)
Norms for
CO
shall be monitored only in case
of
Phthalic Anhydride
(PA), Maleic Anhydride (MA), Terephthalic
Acid
(PTA) and Dimethyl
Terephalate (DMT) Plants. Norms for CO emissions shall not be applicable to
P
A/
MA manufacturing standalone existing piants with an installed capacity
of
less than 30,000 metric tonnes per annum, provided that such units have
a
i
chimney/stack
of
minimum
30
metres height for emitting Carbon Monoxide.
f--
Process Emission (Specific
Pollutant)
Source Limiting concentration in
m ~ m
Exiting New Plants
Plants
Chlorine
ED N M Plant and 10 10
Incinerator
Hydrochlor:c Acid Mist
EDC / VCM P4mt and
30
30
Incinerator
Ammonia
Wastewater stripper, 75 75
acrylonitrile plant,
caprolactum plant
Hydrogen Sulphide Naphtha pre-treatment 05 05
plant, olefinplant
Phosgene
(TDI) and (MDI) plant
01
01
Hydrogen
Cyanide(HCNl
Acrylonitrile plant 10 10
VOC
(HAPs)-
TDI
and
TDI,
Methylenediphenyl 0.1 0.1
MDI
Di-isocY. illte (MDI) Plants
VOC (HAPs), Benzene
Benzene, Butadiene Plants 5.0 5.0
and Butadiene
VOC
(HAPs), EO, VCM, EO, VCM,
EDC, ACN, PO
20.0
]0.0
EDC,
ACN
and PO Plants
/
Organic Particulate PA, MA and
TDI
Plants
50 25
Process Emission (General
Pollutant)
~ 7 , _ ~ ~
Source
Limitin¥ concentration in
meINm
VOC (MA, PA and
MA,
PA, Phenol Plants
20
Phenol)
VOC (EB, Styrene,
Ethyl benzene (EB),
100
Toluene, Xylene, Styrene, Toluene, Xylene,
Aromatics, EG and PG)
Aromatics, EG, PG Plants
VOC
(paraffin, Acetone
Non-methane, HC
150
and Olefins)
(paraffin), Acetone, Olefms
Plants
NOfE.
HAP
- Hazardous Air Pollutants are those pollutants that cause cancer or other serious health
effects, or adverse environmental and ecological effects.
C Standards for ugitive Emission
Storage
of
Volatile Liquids: General Petrochemical/Petroleum Products
Storae tanks with ca aci between 4 to 75m
3
and
totJ l1
vJ'\nrmr
nr...,
....
{T\ l \
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7
( ilPT ~ 3(i)]
(2)
Storage tanks with capacity between 75 to 500 m
3
and total vapour pressure (TVP) of 10 to
76
kpa should have internal floating roof or external floating roof or fixed roof with vapour
control or vapour balancing system.
(3)
Storage tanks with the capacity
of
more than 500 m
3
and total vapour pressure (TVP)
of
10
to
76
kpa should have internal floating roof or external floating roof or fixed roof with
vapour control system.
(4)
The tanks with the capacity of more than
75
m
3
and total vapour pressure (TVP) of more
than 76 kpa should have fixed roof with vapour control system.
(5)
Requirement for seals in Floating Roof Tanks
(i) (a) Internal Floating Roof Tank (IFRT) and External Floating oofTank (EFRT) shall
be provided double seals with minimum vapour recovery of 96%.
(b) Primary seal shall be liquid or shoe mounted for EFRT and vapour mounted for
IFRT. Maximum seal gap width will
be
4 cm and maximum gap area will
be
200
cm
2
m of tank diameter.
(c) Secondary seal shall be rim mounted. Maximum seal gap width will be 1.3 cm and
maximum gap area will be 20
cm
2
m of
tank diameter.
(d) Material
of
seal and construction shall ensure high performance and durability.
(ii) Fixed roof tanks shall have vapour control efficiency
of
95% and vapour balancing
efficiency of90%.
(iii) (a) inspection and maintenance of storage tanks shall be carried out under strict
control;
(b) for the inspection, API RP
575
may
be
adopted;
(c) In-service inspection with regard seal gap should be carried out once in every six
months and repair to be implemented in short time; and
(d) the possibility
of
on-stream repair
of
both shall be examined.
(iv) Storage tanks shall be painted with white colour shade, except for derogation
of
visually sensitive area.
D. Storage of Benzene, VCM and ACN
(i) FRT with vapour for incineration with 99.9% of removal efficiency for volatile organic
compounds (VOC) shall be provided; or
(ii) IFRT/EFRT with double seals, emission-reducing roof fitting and fitted with fixed roof
with vapour removal efficiency of at least 99% shall be provided; or
(iii) Internal floating roof and nitrogen blanketing in between fixed and floating roofs shall
be
provided.
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8
THE GAZETTE OF INDV\ : EXTRAORDfNARY
(Emission control for Road tank, truck Rail tank, wagon loading)
Loading
of
Volatile
Products
Naphtha:
i) VOC reduction,
i) 2::99 5
or
or
(ii) Emission, gm/m] I (ii)
<5
Benzene and Butadiene:
(i) VOC reduction, (i)
~ 9 9 9 9
or
or
ii) Emission, mg/m
3
, (ii) 20
T oluene/Xylene:
(i) VOC reduction, (i)
9 9 9 8
or or
ii)
Emission, mg/m
3
ii)
< 150.".
(b) in Schedule VI, in Part D relating to General Standards, in the entries under item III relating to
LoadlMass based Standards, after serial number 8 relating to 'Glass Industry' and entries relating
thereto, the following serial number and entries shall be inserted, namely
:-
S
No
Industry
Parameter
Standard
,
"9 Petrochemicals
(Basic and
Intermediates)
Source
Quantum limit in
gmlhour for Newl
Expansion Plants
(gmlhr)
Organic
Particulate
Phthalic
anhydride
(PA),
Maleic anhydride (MA),
Toluene Di-isocyanate (TDI)
plants . process emission
100
VOC-HAPs
(TDI
+MDI
(Toluene Di-isocyate) TDI,
Methylenediphenyl
Di
isocyante
(MDI) Plants-
Process emission
0.5
VOC-HAPs
(Benzene
+
Butadiene)
Benzene, Butadiene Plants -
Process emission
25.0
VOC-HAPs
(EO,
VCM,
EDC, ACN +
PO)
EO, VCM, EDC, ACN,
PO
Plants - Process emission
50.0
Abbreviations: EG Ethylene Glycol, PG Propylene Glycol, EO - Ethylene Oxide, VCM - Vinyl
Chloride Monomer, EDC Ethylene Di Chloride, ACN - Acrylonitrile, PO - Propylene Oxide, HCN
Hydrogen Cyanide.".
[F.
No. Q-15017/1212008-CPWJ
AJAY TYAGl,
Jt
Secy.
8/11/2019 Moef Guidelines for Petrochemical Basic & Intermediates
http://slidepdf.com/reader/full/moef-guidelines-for-petrochemical-basic-intermediates 9/9
9
Note.- The principal rules were published in the Gazette of India vide number S.O. 844 E), 19
th
November, 1986 and subsequently amended vide notifications numbers S.O. 433 E), dated 18
th
April
1987; G.S.R. 97 E), dated the
18
th
February, 2009; G.S.R. 149 E), dated the 4th March 2009; G.S.R.
512 E), dated the 9
th
July, 2009;G.S.R. 543 E), dated the 22
nd
July, 2009; G.S.R. 595 E), dated the
21
st
August, 2009; G.S.R. 794 E), dated the 4th November, 2009; G.S.R. 826 E), dated the 16
th
November, 2009; G.S.R.
01
E), dated the 1
st
January, 2010; G.S.R,
61
E), dated the 5
t
February,
2010; G.S.R. 485 E), dated the 9
th
June, 2010; G.S.R. 608 E) ,dated the
2pt
July, 2010; G.S.R. 739
E), dated the 9
th
September, 2010; G.S.R. 809 E), dated, the
4th
October, 2010, G.S.R.
215
E), dated
the 15
th
March, 2011; G.S.R. 221 E), dated the
18
th
March, 2011; G.S.R. 354 E), dated the 2
n
May,
2011; G.S.R. 424 E), dated the 1
st
June, 2011; G.S.R. 446 E), dated the
13
t
h
June, 2011; G.S.R.
152
E), dated the
16
th
March, 2012; G.s.R. 266 E), dated the 30
th
March, 2012; and G.S.R. 277 E), dated
the 31
sl
March, 2012.
~
-
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and Published
by
the Controller
of
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