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GreenSyngas
Workshop ”GREENSYNGAS” Güssing February 23, 2011
General Presentation of GREENSYNGASAdvanced Cleaning Devices for Production
of Green Syngas
Mehri SanatiLund University
Faculty of [email protected]
http://www.eat.lth.se/greensyngas/
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Role of each contractor in the project1-ULUND: Coordinator & Management; research of downstream processing, particle phase characterisation for performance measurement of cleaning, catalytic system, demonstration2-TUM: Development of sophisticated techniques (Laser diagnostics, Optical) for characterisation of tar & alkali in gasifier 3-TUD: On-line tar measurements and gasification with different biomass supply by Lantmännen, the gasifier was also used for field test of reforming catalyst (gas supply to the reactor system), and calibrating of the developed methodology for high temperature fine particle in produced gas (gas supply)4-PA: Filter system that responds to the requirement of clean gas for downstream processing in GREENSYNGAS, multi-cyclone and sintered metal
Role of each contractor in the project1-ULUND: Coordinator & Management; research of downstream processing, particle phase characterisation for performance measurement of cleaning, catalytic system, demonstration2-TUM: Development of sophisticated techniques (Laser diagnostics, Optical) for characterisation of tar & alkali in gasifier 3-TUD: On-line tar measurements and gasification with different biomass supply by Lantmännen, the gasifier was also used for field test of reforming catalyst (gas supply to the reactor system), and calibrating of the developed methodology for high temperature fine particle in produced gas (gas supply)4-PA: Filter system that responds to the requirement of clean gas for downstream processing in GREENSYNGAS, multi-cyclone and sintered metal
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5-FZJ: Chemical hot gas cleaning and thermodynamic modelling, small gasification system, Biomass characterisation supply by Lantmännen6-UNIBO: Downstream catalytic system; steam reforming, WGS reaction, catalytic tar cracking7-JM: Scientific aspect of the catalytic system, catalysts supply, process flow-sheeting 8-NTNU: Downstream catalytic system; steam reforming, WGS reaction9-BKG: Gasification, demo of cleaning device, experimental concerning catalyst exposure, supply of product gas from the gasifier to the partners laboratory10-LANTM: biomass quality, accessibility and supply to different laboratories 11. Science in Society: Bil Sweden, Karin Kvist
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Total budget and duration
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Total EC support, in €: 2,718,461.00
Total Contract cost, in €: 4,089,167.00
38 months projectContract start date:2008-01-01Contract end date: 2011-02-28
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WPs name and WPs leader and involved partners
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WPN°
Title of WP WP LeaderShort name
1 Coordination and Management
ULUND
2 Development of characterisation techniques for emissions measurement from Biomass Gasification
TUM
3 Gas purification of particulates
PA
4 Tar, alkali, HCl, NH3 and sulphur removal including water treatment at high- low temperature
TUD
5 Non –catalytic and Catalytic steam reforming, catalytic poisoning and process flow sheeting tasks
ULUND
6 Water Gas Shift reaction and scale-up
NTNU
7 Large scale-Plant testing
BKG
8 Dissemination and Exploitation
UNIBO
WP ParticipantShort name
Type of WP°° Start
Date
End Date
All partners Management 1 38
ULUND, TUM. LANTM Research 1 38
ULUND, PA Research and demo
12 38
ULUND, TUD, FZJ, UNIBO, JM
Research and demo
2 38
ULUND, UNIBO, JM, NTNU
Research and demo
4 38
ULUND, UNIBO, JM, NTNU
Research and demo
10 38
ULUND, TUD, PA, FZJ, UNIBO, JM, NTNU,
BKG, LANTM
Demo 32 38
All partners Dissemination
1 38
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Optimisation of units in Biofuel production route?
Schematic energy conversion in a biomass to added value products (Thermochemical Conversion)
Fuel
Forest Processing
HarvestingTransportPalletizing
Heat lossesThermo-ChemicalConversion
Gas cleaning
Heat losses Upgrading step
to added valueproducts
Heat losses reforming and shift
Product gas from gasification process consists of CO, CO2, H2, H2O, unburned hydrocarbons, tar, sot, char, inorganic, and generally orgThe aim will be increasing utilization of LHV of feedstock to added value products
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collaboration between applied oriented technical discipline and basic research concentrated on new
field of scientific knowledge
Technological research targets
Basic Research and Applied Investigation towards an innovative improved particle cleanup system and preventing catalytic deactivation
Catalytic and nion-catalytic reaction system
Improved particle removal system
Combustion
Thermo-chemical conversion & synthesis of product gas to heat & power, chemical and vehicle fuels
Gasification
High temperature Aerosol Physics
FluidDynamics
TransportPhenomena
ThermodynamicsMultiphase reaction system
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Gas Composition in BKG biomass gasification, balance; Güssing gasification plant full load
After gasifier (raw gas) Before gas engine (clean
gas) Water content v-% ~40 ~10 CH4 v-% (dry) 9…11 9…11 C2H4 v-% (dry) 2…3 2…3 C3-Fract. v-% (dry) 0.5…1 0.5…1 CO v-% (dry) 22…25 22…25 CO2 v-% (dry) 20…25 20…25 H2 v-% (dry) 38…40 38…40 N2 v-% (dry) 1.2…2.0 1.2…2.0 H2S v-ppm (dry) ~150 ~150 Organic S v-ppm (dry) ~30 ~30 HCl v-ppm (dry) n.d. ~5 NH3 v-ppm (dry) 1000…2000 500…1500 Benzene g/m³N (dry) n.d. 5...8 Napthalene g/m³N (dry) n.d. 1..2 Heavy tar (PAH larger than Napthalene)
g/m³N (dry) 0.5…1 0.02…0.05
Particulates g/m³N (dry) ~50 < 0.02 n.d. not measured
Baserad på gas produktsammansättning olika ”down stream” process kan vara aktuella.
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Partners contribution in relation to this Figure
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High temperature Cleaning device, in market
High temperature Gas phase characterization
High temperature particle characterization
Ammonia removal
Tar cracking
Capture of sulfur and alkali
Flow sheeting
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Fue lSte a m
He a t
C O ,C O 2H2,H2O
Fue lSte a m He a t C O ,C O 2
H2,H2O(N2)
Air,o xyg e n
A B
Reforming Step
A) Steam reforming B)Auto-thermal reforming
2224 42 HCOOHCH
224 3 HCOOHCH
steam: carbon ratio about 2-4
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Upgrading Steps-production routes of Syngas; Steam reforming
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Regenerative System for endothermic process, no heat waste (Energy Saving)
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High temperature sampling probe for particulate (submicrone)
High temperature Particle emission from wood GasificationTo develop and evaluate methods for characterization of particles- Physically; Size, Mass, Number concentration-Chemical composition- Deposition on heat surface (corrosion issue)
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ACKNOWLEDGMENTS
The work was supported by European Commission (EC) 7th Framework Programme (GREENSYNGAS Project Contract number 213628) and the Swedish Energy Agency
ACKNOWLEDGMENTS
The work was supported by European Commission (EC) 7th Framework Programme (GREENSYNGAS Project Contract number 213628) and the Swedish Energy Agency