Dalton Transactions
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This journal is © The Royal Society of Chemistry 20xx Dalton Trans., 2018, 00, 1-3 | 1
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Received 00th January 20xx, Accepted 00th January 20xx
DOI: 10.1039/x0xx00000x
www.rsc.org/
Synthesis and Reactivity of Selenium Functionalised Allylidynes and Propargylidynes Anthony F. Hill*, Richard A. Manzano and Jas S. Ward.
a. Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia.
†Corresponding author: Email: [email protected] CCDC 1559203 - 1559205 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre.
Electronic Supplementary Material (ESI) for Dalton Transactions.This journal is © The Royal Society of Chemistry 2018
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1H NMR of E-[W{≡CC(SePh)=CHSePh}(CO)2(Tp*)] (E-3)
13C NMR of E-[W{≡CC(SePh)=CHSePh}(CO)2(Tp*)] (E-3)
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1H NMR of Z-[W{≡CC(SePh)=CHSePh}(CO)2(Tp*)] (Z-3)
13 C NMR of E-[W{≡CC(SePh)=CHSePh}(CO)2(Tp*)] (Z-3)
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HSQC - E/Z-[W{≡CC(SePh)=CHSePh}(CO)2(Tp*)] (E/Z-3) (Vinyl protons)
HMBC - E/Z-[W{≡CC(SePh)=CHSePh}(CO)2(Tp*)] (E/Z-3) (Vinyl protons)
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1H NMR of [W(≡CC(SePh)=C(SePh)2}(CO)2(Tp*)] (4)
1H NMR of [W(≡CC≡CSePh)(CO)2(Tp*)] (5) – Decomposition already present
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13C NMR of [W(≡CC≡CSePh)(CO)2(Tp*)] (5) - Decomposition already present
1H NMR of [(Tp*)(OC)2W≡CC(SePh)=C(SePh)-C≡CC≡W(CO)2(Tp*)] (6)
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13C NMR of [(Tp*)(OC)2W≡CC(SePh)=C(SePh)-C≡CC≡W(CO)2(Tp*)] (6)