![Page 1: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/1.jpg)
CO2 UTILIZATION BY ETHANOL
PRODUCTION IN THE CEMENT
INDUSTRY
Juliana Monteiro (TNO), Peter van Os (TNO), Earl Goetheer (TNO), Helmut Hoppe (VDZ)
14th
June 2017
![Page 2: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/2.jpg)
THE CEMENT INDUSTRY
19 May 2017 2 | CO2 Utilization by Ethanol production in the Cement Industry
65%
35%
CO2 emissions
CaCO3
Coal
1.88
0.83
1.05
2008 2050
CO2 emissions, Gt/year
CO2 emmited CO2 captured
![Page 3: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/3.jpg)
THE CEMCAP CONTEXT (1/3)
WP3: CEMCAP Framework
• Reference case: Best Available Technique (BAT) standard
• Representative size for a European cement plant
• Cement production of 1.36 Mt per year
• Heat and mass balances available
3 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017
![Page 4: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/4.jpg)
THE CEMCAP CONTEXT (2/3)
WP4: Comparative capture process analysis, D4.2
Economic Key Performance Indicators
19 May 2017 4 | CO2 Utilization by Ethanol production in the Cement Industry
Cost, €/ton No capture 90% capture 60% capture
Cement 45,3 80,7 70,5
CO2 captured 63,2 67,4
MEA 30wt%
CO2 compression to 110 bar
![Page 5: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/5.jpg)
THE CEMCAP CONTEXT (3/3)
WP5: Post-capture CO2 management (CCUS)
1. CCS: Geological sequestration: option to be defined (TNO)
2. CCS: Mineralization to MgCO3 (ETH Zurich)
3. CCU: CO2 hydrogenation to ethanol (TNO)
4. CCU: CO2 polymerization to Poly(propylene carbonate) (TNO)
5. CCU: food-grade CO2 (TNO)
5 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017
![Page 6: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/6.jpg)
ETHANOL
![Page 7: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/7.jpg)
WHY ETHANOL?
Fuel large market 110 billion liters per year
Potential for CO2 utilization = 166 Mton CO2
per year
195 BAT cement plants
Market has potential to increase: drop-in fuel
19 May 2017 7 | CO2 Utilization by Ethanol production in the Cement Industry
![Page 8: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/8.jpg)
WHY ETHANOL?
Community already looking into methanol and methane
Ethanol has a higher price
19 May 2017 8 | CO2 Utilization by Ethanol production in the Cement Industry
![Page 9: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/9.jpg)
INTEGRATION
![Page 10: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/10.jpg)
PROCESSES
19 May 2017 10 | CO2 Utilization by Ethanol production in the Cement Industry
cement plant
cement
CaCO3
water electrolysis
hydrogenation water
ethanol
H2
O2
coal
air capture
CO2
![Page 11: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/11.jpg)
INTEGRATED PROCESSES
19 May 2017 11 | CO2 Utilization by Ethanol production in the Cement Industry
cement plant
cement
CaCO3
water electrolysis
hydrogenation water
ethanol
H2
O2
coal
air capture
CO2
![Page 12: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/12.jpg)
HEAT AND MASS
BALANCES
![Page 13: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/13.jpg)
90% DIRECT EMISSION REDUCTION
19 May 2017 13 | CO2 Utilization by Ethanol production in the Cement Industry
cement plant
cement
CaCO3
water electrolysis
hydrogenation water
ethanol
H2
O2
coal
air capture
CO2
336 t/d
87% 585 t/d
307 t/d
![Page 14: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/14.jpg)
100% DIRECT EMISSION REDUCTION
19 May 2017 14 | CO2 Utilization by Ethanol production in the Cement Industry
cement plant
cement
CaCO3
water electrolysis
hydrogenation water
ethanol
H2
O2
coal
air
336 t/d
585 t/d
307 t/d
CO2 2,6 Mm3/d
790 t/d O2
814 t/d
6634 t/d
![Page 15: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/15.jpg)
ENERGY NUMBERS
19 May 2017 15 | CO2 Utilization by Ethanol production in the Cement Industry
cement plant
cement
CaCO3
water electrolysis
hydrogenation water
ethanol
H2
O2
585 t/d 307 t/d
CO2
814 t/d
6634 t/d
![Page 16: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/16.jpg)
WIND FARM SCALE
19 May 2017 16 | CO2 Utilization by Ethanol production in the Cement Industry
electrolysis
http://www.fosenvind.no/om-fosen-vind/
= 7,22 TWh/year = 2 x
Fosen Vind = 3,4 TWh/year
3 x Manhattan
½ Trondheim
22000+ soccer fields
![Page 17: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/17.jpg)
ECONOMICS
19 May 2017 17 | CO2 Utilization by Ethanol production in the Cement Industry
Cement €/ton No capture 90% CCS 90% CCU
Variable OPEX 17,04 37,45 488,14
Fixed OPEX 13,33 19,64 25,00
CAPEX 14,99 23,60 50,00
Ethanol revenue 0,00 0,00 91,00
Cost of cement 45,36 80,69 472,14
hydrogen
4000 €/ton
![Page 18: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/18.jpg)
ECONOMIC SCENARIOS
19 May 2017 18 | CO2 Utilization by Ethanol production in the Cement Industry
0
50
100
150
200
250
300
350
400
450
500
0 500 1000 1500 2000 2500 3000 3500 4000
Cem
ent cost, €
/ton
Hydrogen cost, €/ton
BAT
90% CO2 capture
Price of cement US 2016, Portland
![Page 19: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/19.jpg)
ECONOMIC SCENARIOS
19 May 2017 19 | CO2 Utilization by Ethanol production in the Cement Industry
0
50
100
150
200
250
300
350
400
450
500
0 500 1000 1500 2000 2500 3000 3500 4000
Cem
ent cost, €
/ton
Hydrogen cost, €/ton
Ethanol
BAT
90% CO2 capture
2020 DoE target
Price of cement
gap
Break-even cost
![Page 20: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/20.jpg)
#1 INCREASE REVENUE – SELLING OXYGEN
6634 ton/day = 0,55% of global
market
Hydrogen future (2050?)
oxygen may have little to no value
Oxygen price = €40/ton cost of
on-site production
19 May 2017 20 | CO2 Utilization by Ethanol production in the Cement Industry
![Page 21: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/21.jpg)
ECONOMIC SCENARIOS
19 May 2017 21 | CO2 Utilization by Ethanol production in the Cement Industry
-100
0
100
200
300
400
500
0 500 1000 1500 2000 2500 3000 3500 4000
Cem
ent cost, €
/ton
Hydrogen cost, €/ton
Ethanol
Ethanol + O2
BAT
90% CO2 capture
2020 DoE target
Price of cement
gap
Break-even cost
![Page 22: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/22.jpg)
#2 DECREASE COSTS
Lower or no tax on “green” cement
Lower hydrogen cost
• Cheaper electricity
• Improvements on hydrolysis
• Alternative technologies
• SMR + CCS (yesterday’s Statoil key note)
19 May 2017 22 | CO2 Utilization by Ethanol production in the Cement Industry
![Page 23: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/23.jpg)
CONCLUSIONS
Ethanol production using CO2 from cement industry: technically feasible
Integration between production units: 100% direct emission reduction in combination with oxy-
combustion
Added cost is the main challenge hydrogen cost
19 May 2017 23 | CO2 Utilization by Ethanol production in the Cement Industry
![Page 24: CO2 UTILIZATION BY ETHANOL PRODUCTION IN … SCENARIOS 19 | CO2 Utilization by Ethanol production in the Cement Industry 19 May 2017 0 50 100 150 200 250 300 350 400 450 500 0 500](https://reader031.vdocuments.us/reader031/viewer/2022022505/5aba19fa7f8b9af27d8b488b/html5/thumbnails/24.jpg)
THANK YOU FOR YOUR
ATTENTION
Take a look: TIME.TNO.NL