Book reviews 113
mixtures in a more conventional type system, followed by afurther group of papers on the way in which liquid crystallinepolymers and other systems may be organized when inter-acting with substrates. These papers tend to be concernedwith physical measurement of the nature of these systemsrather than the usual emphasis on synthesis and conceptualorganization, and cover the whole spread of possible types oforganization in interactions which might be envisaged withinpolymer systems, presenting an interesting view of the currentstate of understanding in nanostructures.
As a collection of papers, the life of this publication is likelyto be limited. However, it will be of interest to all thosecurrent PhD students attempting to understand the complex-ities of interactions at a polymeric level both in the solid andsolution phase. It is an interesting collection of papers, but isnot necessarily a comprehensive view of the topic.
A.R. Pethrick
Metal-containing polymeric materialsEdited by C. U. Pittman, Jr., C. E. Carraher, Jr., M. Zelldin,J. E. Sheats and B. M. CulbertsonPlenum Press, New York, 1996.pp. x] 518, price, US$125.00.ISBN 0-306-45295-2
This is a selection of the papers presented at the Sixth Interna-tional Symposium on Metal-Containing Polymeric Materialsorganized within the ACS Fall Meeting held in 1994, originat-ing from all corners of the world. The subject is developingrapidly, spurred on by the search for new optoelectronicmaterials, catalysts, polyelectrolytes and preceramics, and bythe need to understand further the roles that metals play inbiological systems. The Ðrst chapter presents an editorialoverview of the subject : it makes ideal reading for the non-specialist. It is followed by six sections, the Ðrst two of whichare devoted to synthesis, structural characterization andmodiÐcation of new polymeric systems ; later sections dealwith the characterization of properties, and the special con-siderations that apply to biological systems.
The Ðrst section, “Synthesis and characterisation of newsystemsÏ is an excellent introduction to ring-opening poly-merization of strained metallocenophanes ; in 1994 this excit-ing work, leading to the incorporation of iron in a variety ofpolymeric backbones, was entirely new. The later chapters inthis section describe the incorporation of other metals,through complexation or as clusters, in a range of conven-tional carbon-chain polymeric structures. The papers of thenext section are concerned with the methods of incorporatingmetals in silicon-backbone polymers, and in cages and net-works. Syntheses of metal-containing siloxanes, polysilanesand polycarbosilanes are all represented, along withceramicization studies and polymer-supported catalysts. Inthe concluding sections, all the properties expected of modernmaterials are given consideration, from the electrical, magneticand photonic properties through to ion-exchange, ion-bindingand electrolytic properties È there is even a paper on the massspectrometry of metal-containing polymers.
In so far as it is possible to identify a natural order of pres-entation, it has been achieved È a task by no means easy when
presenting conference papers. Four previous conferencesunder the same banner have led to publications : together withthis volume they form a basis for following a developingsubject area. Several papers here will maintain their signiÐ-cance and be good research reading in years to come.
While this book would be a useful reference to have to handwithin any laboratory concerned with polymers and theirapplications, its price means that it is most likely to be pur-chased by libraries rather than by individuals.
R. G. Jones
Statistical mechanics deformation ultrasonic spectroscopyAdvances in polymer science 125A. Abe et al.SpringerÈVerlag, Berlin, 1996.pp. 197, price, DM184.00.ISBN 3-540-60483-9
This volume contains three articles concerned with di†erentbut related topics.
The Ðrst chapter, on “Statistical mechanics of transport phe-nomena ; polymeric liquid mixturesÏ, is written by Curtiss andBird. For the reader to obtain full beneÐt they should be fam-iliar with Dynamics of polymeric liquids by Bird, Armstrong,Hassager and Curtiss : it opens with a summary of the kinetictheories of Ñexible macromolecules based on bead springmodels of arbitrary connectivity. The Ðrst part summarizesthe more detailed developments of the fundamentals of thesubject. The authors have addressed, very concisely, manyimportant assumptions made in development of the theory,and highlighted areas of potential concern with its validationin relation to real systems, presenting a look at the currentstate of theoretical development from the statistical mechani-cal point of view of the transport properties of polymericmaterials. The chapter concludes with suggestions for furtherresearch and identiÐes clearly the issues in relation to limi-tations imposed on the theoretical development which artiÐ-cially constrain the validity of the model used for real systems.Recognition of the importance of optical electrical phenomenain providing information on transport phenomena, and theneed for additional theoretical development in this area, is tobe applauded.
The second chapter “Kinetics and deformation of relaxationin highly oriented polymersÏ by Bronnikov, Vettegren andFrankel looks at the kinetics of deformation in orientatedmaterials, notably polyimide type structures, as a mixture oftheory and modelling of experimental data to validate theassumptions made in the theory. This is a useful discussion ofan area which is infrequently visited in terms of theoreticalanalysis.
The Ðnal chapter, on ultrasonic spectroscopy of polymericmaterials, by Matsushige, Hiramatsu and Okabe, describesthe development of a novel ultrasonic spectrometer withpiezoelectric polymeric transducers, using fast Fourier trans-form analysis to study polymeric materials. It concentrates ondetailed description of equipment and the appropriate dataanalysis required for the application of this technique, in thecharacterization of solid polymers, phase transition pheno-
POLYMER INTERNATIONAL VOL. 44, NO. 1, 1997
