i
Contents
S. No. Description Page No.
1.0 Executive Summary 1
1.1 Salient Features of the Project 2
2.0 Introduction 4 2.1 Identification of the Project and project proponent 4 2.2 Brief description of Nature of the Project 5
2.3 Need for the Project and its importance to the country and or region
6
2.4 Demand and Supply Gap 7
2.5 Imports Vs. Indigenous production, Export Possibility, Domestic/Export Markets
7
2.6 Employment Generation 7
3.0 Project Description 7
3.1 Type of the project including interlinked and interdependent projects, if any 7
3.2 Location 8 3.3 Alternate sites 8 3.4 Size or magnitude of operation 8 3.5 Project description 12 3.6 Raw materials 13 3.7 Resources optimization / recycling and reuse 13 3.8 Availability of water and Energy 14
3.9 Quantity of Wastes Generation and their Management / Disposal
14
3.9.1 Water requirement and Wastewater generation and their Management / Disposal
14
3.9.2 Hazardous / Solid Waste Generation, Handling and their Disposal
16
3.10 Schematic flow sheet for EIA procedure 18
4.0 Site Analysis 18
4.1 Connectivity 18 4.2 Land Form, Land use and Land ownership 18 4.3 Topography 18 4.4 Existing Land use pattern 18 4.5 Existing Infrastructure 19 4.6 Soil Classification 19
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S. No. Description Page No.
4.7 Climate data from Secondary sources 19 4.8 Social Infrastructure 20
5.0 Planning 20 5.1 Planning Concept 20 5.2 Population Projection 20 5.3 Land use planning 20 5.4 Assessment of Infrastructure Demand 21 5.5 Amenities/Facilities 21
6.0 Proposed Infrastructure 21 6.1 Industrial Area 21 6.2 Residential Area 21 6.3 Green Belt 21 6.4 Social Infrastructure 22 6.5 Connectivity 22 6.6 Drinking Water management 22 6.7 Sewerage System 22 6.8 Industrial Waste Management 22 6.8.1 Process Emissions Management 22 6.8.2 Fugitive emissions 23 6.8.3 Emissions–Utilities 23 6.8.4 Noise Environment 24 6.9 Hazardous / Solid Waste Management 25 6.10 Power Requirement & Supply / Source 25
7.0 Rehabilitation and Resettlement (R&R) Plan 25 8.0 Project Schedule & Cost Estimates 25
8.1 Time Schedule for the project construction 25 8.2 Estimated project cost 25
9.0 Analysis of proposal (Final Recommendations) 25 9.1 Budgetary allocation for Pollution Control Measures 26
iii
List of Tables
Table Title Page
1 Coordinates of all Corners of the Project Site 8
2A Permitted Products and their Capacities as per EC-2012 9
2B Permitted products and their capacities as per CFE - 2014 9
3A Proposed Products, their Capacity and End use 9
3B Products Permitted, proposed and total after expansion with its status 11
4 Existing Water Requirement, Wastewater Generation and its Treatment
15
5 Proposed Water Requirement and Waste water Generation with Segregation 15
6 Effluent Treatment Flow as per segregation 16
7 Hazardous Waste Generation from the Existing (CFO) Products 17
8 Hazardous / Solid Waste Generation from the Proposed Products 17
9 Environmental Components Shortest distance from Project Periphery 19
10 Land Break-up details 21
11 Maximum quantity of process Emissions from Existing Products
22
12 Maximum Quantity of Process emission from Proposed Products 23
13 Stack Emission Details – Proposed 24
14 Budgetary allocation for pollution Control Measures 26
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LIST of Annexures
Annexure No.
Title Page
I EC vide order F.no. J-11011/132/2010-IA-II (I) dated 20-07-2012 27
II CFE from KSPCB vide order no. KSPCB/HPI/189/Hyd-Chemicals/2012-13/571 dated 17-08-2012 34
III CFO vide No. KSPCB/189/Hyd-Chemicals/ 2012-13/09 dated 02-04-2013 46
IV CFE – CPM from KSPCB vide order no. PCB//189/HPI/2014-15/718 dated 09-09-2014 57
V Latest CFO vide No. AW-30313, PCB ID: 29166 dated 19-07-2017 and valid till 30-06-2021 62
VI Latest Hazardous waste authorization vide order no. PCB/HWM/ SEO/H.D. Reg.No.77665/2014-15 dated 27-8-2014 valid upto 30-06-2019
67
VII RoC of Nector Crop Sciences Private Limited 70
VIII RoC of Nichino Chemical India Private Limited 71
IX MoEF&CC Acknowledgement on submission Name Change application 72
X CA Certificate 73 XI General location of the Proposed Project 74 XII Specific Location of the Proposed Project 75 XIII Google map showing the coordinates 76 XIV Plant Layout 77 XV Typical process description & Flowchart for proposed products 78 XVI Raw Materials of Proposed products 128 XVII Hazardous Raw Materials 151 XVIII Ground water analysis report 152 XIX ETP Flow Scheme 153 XX Schematic Flow Sheet for EIA Procedure 154 XXI Topomap of 10km radius 156 XXII Soil analysis report 157
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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Pre-Feasibility Report for Expansion of Pesticide technical, its intermediates,
Bio Pesticides & Pesticides Formulations with R&D Facility 1.0 Executive Summary
M/s. Nichino Chemical India Pvt. Limited (Formerly known as Hyderabad Chemical Products
Limited) proposes to expand its Pesticide Technical Manufacturing and Formulation Unit to Pesticide
technical, its intermediates, Bio Pesticides & Pesticides Formulations with R&D products
manufacturing unit in the existing plant premises of 5.46 Ha i.e. 54634.5 sq.m (13.5 acres). The Unit
is located in Plot nos. 50, 82P, 83 and 84P of Karnataka Industrial Area Development Board (KIADB)
Industrial Area, Humnabad Taluk, Bidar district, Karnataka.
Background:
Industry granted Environmental Clearance (EC) by MoEF vide F.No. J-11011/132/2010-IA-II (I) dated
20-07-2012 in favor of M/s Hyderabad Chemical Products Limited (Annexure-I) for 4 pesticide and
formulation products with a production capacity of 1900 TPA wherein it is stated that Public Hearing
was exempted as per section 7(i), (iii) Stage (3), Para (i) (b) of EIA Notification, 2006. Industry was
established in the year 2012 and granted CFE by Karnataka State Pollution Control Board (KSPCB)
vide KSPCB/HPI/189/Hyd-Chemicals/2012-13/571 dated 17-08-2012 (Annexure-II) The combined
(water & Air) consent for operation as per EC granted in favor of M/s Hyderabad Chemical Products
Limited vide KSPCB/189/Hyd-Chemicals/ 2012-13/09 dated 02-04-2013 for 4 pesticide products with
a production capacity of 1900 MTPA (Annexure-III). Subsequently, consent for establishment for
expansion was granted in favor of M/s Hyderabad Chemical Products limited for 13 products mix for
manufacture of pesticide technical and formulations using existing plant and machinery by reducing
existing production capacity of 3 products and retaining one product capacity along with addition of 9
new products with a total production capacity of 1900 TPA by PCB//189/HPI/2014-15/718 dated 09-
09-2014 (Annexure-IV).
Industry granted regular renewals for consent for operation of the plant from time to time. The Latest
combined Consent for the Operation (CFO) granted in favor of M/s Nector Crop Sciences Pvt. Limited
by KSPCB vide AW-30313, PCB ID: 29166 dated 19-07-2017 and valid till 30-06-2021 (Annexure-V). Latest Hazardous waste authorization vide order no. PCB/HWM/SEO/H.D. Reg.No.77665/2014-
15 dated 27-8-2014 in the name of Hyderabad Chemical Product Limited valid upto 30-06-2019
(Annexure-VI).
The Nector Crop Sciences Limited which was originally incorporated on 05-12-2013 and
subsequently converted to Nector Crop Sciences Private Limited has been incorporated on 25-03-
2015 (Annexure-VII). Further, name of the company has been changed from Nector Crop Sciences
Private Limited to Nichino Chemical India Private Limited with effect from 16-12-2017 (Annexure-
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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The expansion proposal is to grant Environmental Clearance (EC) by the Ministry of Environment,
Forests and Climate Change (MoEF&CC) to manufacture 9 campaign products at a time out of 48
products, Bio pesticides, R&D products with a production capacity of 6251.8 TPA from existing
production capacity of 1900 TPA with additional investment of Rs.75.42 Crores, the existing
investment is Rs. 51.47 Crores and total investment after expansion will be Rs.126.89 Crores
(Annexure-X).
The proposed expansion of Pesticide Technical Grade, its intermediates, Bio pesticides, R&D
products manufacturing and formulation unit falls under Category 'A' project under 5 (b) of EIA
Notification 2006 and will be appraised by the sector specific expert appraisal committee (EAC) of the
Ministry of Environment, Forest and Climate Change, Govt. of India, New Delhi.
1.1 Salient Features of the Project
• Proposing expansion in the existing pesticides manufacturing & formulation unit premises land
area of 5.46 Ha. Total Greenbelt area is 1.87 Ha (34.4%) of 5.46 Ha.
• This proposed project site is located at an aerial distance of:
i. National Highway-65 : Machilipatnam-Hyderabad-Pune (old NH-9)-1.4 km (N)
ii. NH-218: Bidar to Hospet-0.6 km (W)
iii. Nearest town: Humnabad-2.3 km (NE)
iv. Bidar District: 42 km (NE)
v. Humnabad Railway Station-4.7 km (ENE)
vi. Kalaburag Airport-52 km (SSW)
vii. Rajiv Gandhi International Airport, Hyderabad -153 km (E)
viii. Nearest Village: Ganwanti-2 km (N)
• Total cost of the expansion is Rs.126.89 Crores including existing investment of Rs. 51.47
Crores. Total capital cost allocated towards environmental pollution control measures is Rs.
8.59 Crores including existing investment of Rs. 3.44 Crores. Recurring cost will be about Rs.
9.48 Crores per annum.
• The proposed power requirement of the plant is 1350 KVA (CMD) including existing 900 KVA
(CMD). Power will be met from Karnataka State Power Distribution Corporation Limited.
• Total water requirement will be about 527 KLD of which fresh water requirement will be
367 KLD. Treated effluent of 162 KLD from ETP will be reused in cooling tower makeup. Fresh
water will be met from bore wells & private tankers
• Diesel of about 300 lit/hr will be used in the proposed DG sets of 625 KVA, in addition to
existing 625 KVA & 250 KVA DG sets. DG sets are used as standby during power failure.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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• About 60 TPD of coal will be used in the proposed 2 nos of 5 TPH coal / Bio fuel fired boilers
along with existing 3 & 2 TPH coal fired boilers.
• Existing Incinerator of 75 kg/hr will be dismantled, as it is not required to operate, due to
discontinuation of Monocrotophos Technical production.
• About 397 employees including existing 197 employees will be benefitted due to the proposed
project. Out of which direct 187 and indirect 210 employees.
• Industry will provide dual scrubbers based on the characteristics of process emissions. Multi-
cyclone separator & bag filter will be provided to Boilers to reduce the particulate emissions into
atmosphere.
• Wastewater generated from the plant will be about 178 KLD from process, washing, utilities,
Fresh water RO rejects, scrubber, Q.C, R&D and domestic wastewater.
• Effluent will be pumped to the above ground level RCC lined tanks for storage and
neutralization then sent to upgraded ETP-ZLD of 200 KLD capacity within the premises.
• Domestic wastewater will be sent to ETP - ZLD.
• Hazardous waste will be segregated and collected in the HDPE drums / bags as appropriate
and will be stored in the covered and raised platform with provision of leachate collection
system.
• Solid waste like boiler ash will be sent to cement brick manufacturers.
• Existing solvent recovery system consists of 3x125 lph and 250 lph distillation columns. Industry
will upgrade the existing solvent recovery system for recovery of solvents from the process by
addition of 3 nos. as required. Primary and secondary condensers will continue to be provided
with cooling water and chilled brine circulation for effective recovery of solvents thereby
reducing the solvent emissions.
• Compressors, Boilers and DG sets will be the major noise generating units in the plant. Out of
these, the generator will be functioning at the time of power failure only. Built-in acoustic
enclosures provided for DG sets unit to minimize the noise levels. However, the workers in this
area will be provided with ear muffs.
Industry has prepared Form-I application along with draft Terms of Reference (ToR) in the process of
granting ToR for preparation of EIA, in line with issue of Environmental Clearance. Hence, pre-
feasibility report highlighting the expansion project and the various operations including waste
generation and mitigation measures are prepared & submitted to the Expert Appraisal Committee
(EAC) for its consideration and appraisal.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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2.0 Introduction
2.1 Identification of the Project and Project Proponent
The present unit was established in 2012 in the name of M/s. Hyderabad Chemical Products
Limited was granted Environmental Clearance (EC) by the Ministry of Environment and Forests
(MoEF), New Delhi in 2012 for production quantity of 1900 TPA vide F.No. J-11011/132/2010-IA-II (I)
dated 20-07-2012. Industry proposes expansion of Pesticides Technical, its intermediates, Bio
pesticide, Formulation and R&D products manufacturing unit with the production quantity of
6251.8TPA in the land extent of 5.46 Ha at Plot nos. 50, 82P, 83 and 84P, Karnataka Industrial Area
Development Board (KIADB) Industrial Area, Humnabad, Bidar district, Karnataka.
• Industry was established in the year 2012 and granted CFE by Karnataka State Pollution
Control Board (KSPCB) vide KSPCB/HPI/189/ Hyd-chemical /2012-13/571 dated 17-08-2012
(Annexure-II). The combined (water & Air) consent for operation as per EC granted in favor of
M/s. Hyderabad Chemical Products limited vide KSPCB/189/Hyd-Chemicals/2012-13/09
dated 02-04-2013 for 4 pesticide products with a production capacity of 1900 MTPA.
Subsequently, consent for establishment for expansion was granted in favor of M/s
Hyderabad Chemical Products limited for 13 products mix for manufacture of pesticide
technical and formulations using existing plant and machinery by reducing existing production
capacity of 3 products and retaining one product capacity along with addition of 9 new
products with a total production capacity of 1900 TPA by PCB//189/HPI/2014-15/718 dated
09-09-2014.
• Management have changed the Name of the company from M/s. Hyderabad Chemical
Products Limited to M/s. Nectar Crop Sciences Limited in 2014 and Nectar Crop Sciences
Private Limited in 2015 and to M/s. Nichino Chemical India Private Limited in December 2017
located at Plot No. 50, 82 83 and 84, KIADB Industrial Area, Humnabad, Bidar District,
Karnataka State in confirmation of the Board of Directors.
• Industry granted regular renewals for consent for operation of the plant from time to time. The
Latest combined Consent for Operation (CFO) granted in favor of M/s Nector Crop Sciences
Pvt. Limited by KSPCB vide AW-30313, PCB ID: 29166 dated 19-07-2017 and valid till 30-06-
2021.
• Latest Hazardous waste authorization vide order no. PCB/HWM/SEO/H.D.
Reg.No.77665/2014-15 dated 27-08-2014 in the name of Hyderabad Chemical Product
Limited valid upto 30-06-2019.
Project Proponent
Since its inception in 1954, established by Dr. Ramesh Gandhi for over 4 Decades Nichino India
(formerly Hyderabad Chemicals Limited) have been working for well-being of Farmers in India.
Nichino is one of the leading Manufacturer of Technical Grade Pesticides in India. Which engaged in
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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Agro Farm Industry to increase Agro farm Productivity, Profitability and to develop sustainable
agriculture by offering various innovative and Customer / Crop focused products by maintaining
international quality standards at affordable prices.
Nichino India has a broad portfolio of agrochemicals including insecticides, herbicides, fungicides &
growth promoters. The Crop Protection Products help farmers to prevent crop losses from the effects
of weeds, pests & diseases thereby enhancing production of food, fiber and feed. The Plants are
operated by well qualified and experienced senior professionals, Engineers and others who are well
versed with Plant Operations. Having in-built flexibility of plant and machinery is able to produce and
distribute new products in a short time.
Mr. Hideii. Hosoda- (CMD): He was nominated as Chairman & Managing Director by Nihon Nohyaku
Co., Ltd. He holds a Master Degree in Science. He has joined the parent company Nihon Nohyaku
Co., Ltd in the year 1979 and is having over 35 years of experience in the fields of Agrochemical
Regulatory, Product Development and Sales and Marketing.
Mr. Mitsuhiro Kishida - (Director): He was nominated as Director by Nihon Nohyaku Co., Ltd. He is
holding Masters in Agricultural Science. He joined Nihon Nohyaku Co., Ltd in the year 1985 and has
over 30 years of experience in the fields of Chemical, Product Development and Sales and
Marketing.
Mr. N. Sukumar- (Director): He inducted into the Board of Directors in September 1988.he is
renowned for his business acumen, innovative thinking and he has been instrumental in propelling
the Nichino India (HCL) group forward into several core industrial sectors and in the emerging of
Nichino India (HCL) group as an enterprise with commitment to society and in expanding into the
international markets and built strong relationships with powerful distributors. He plays an active role
in Crop Care Federation of India (CCFI) as a Director.
Mr. Mahendra Uday Bhalerao- (Executive Director): He holds a graduation Degree in Engineering
from Osmania University. He is having over 26 years of rich experience in Chemical &
Pharmaceutical Industry. Over 11 years association with the Nichino India (HCL) as Technical
Consultant for Synthetic Chemistry, Process Development, and Engineering. Mr. Mahendra Uday
Bhalerao was nominated as Executive Director by Nihon Nohyaku Co., Ltd. On 16th May, 2017.
2.2 Brief Description of the Nature of the Project
This is an expansion of existing Pesticides technical and formulations manufacturing unit to
Pesticide technical, its intermediates, Bio Pesticides & Pesticides Formulations with R&D facility. The
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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products manufactured are used as insecticide, fungicide, herbicide, pesticide, etc., which are
applicable for agricultural activity.
The manufacturing process of Pesticides consists of chemical synthesis and multiple stage of
processing extending to maximum of 4 stages involving different types of chemical reactions. The
entire process operations are operated by various technical, skilled and unskilled persons with due
care to be met various standards prescribed by authorities.
Technology for manufacturing the products listed under proposed expansion is available from
in-house R&D & private consultants and proposes to adopt new technologies and techniques that are
continuously refined in every stage of manufacturing to meet global standards. Industry will adopt the
state of art technologies and dedicated team of environmental professionals for treatment and
recycling of effluents, operation and monitoring of all pollution control equipment. Industry has a
defined EHS policy and robust environmental management system supported by a well-defined
organizational structure to ensure the prevention of pollution and to protect the environment.
2.3 Need for the Project and its Importance to the Country and or Region
Pesticides have been recognized as an essential tool in India to increase agricultural
production by preventing crop losses before and after harvesting. Pesticides comprise of a large
group of chemicals that are used in agriculture to control plants and animals infestation. Pesticides,
being the last input in agricultural operation, are used for preventing the destruction of crops from
pests like insects, weeds, etc., thereby increasing the agricultural production. On the production front,
pesticides are first manufactured as technical grade product (85% or more of the active chemical
ingredients), which has a higher commercial purity. The active ingredients are then mixed with inert
ingredients (solvents, adjuvant and fillers) to achieve the desired formulation. The active ingredient
kills the pest whereas the inert ingredient facilitates ease of handling, spraying and coating on plants.
In India, the pesticides are broadly divided into five types and in the market share Insecticides
cover the major part i.e. 60% of the market share, whereas Fungicides 18%, Herbicides 16% and the
rest 6% by others. Bio-pesticides are an emerging category and are currently a small proportion of
the market but have a huge growth potential considering its non-toxic nature.
Currently, India is the fourth largest global producer of pesticides with an estimated market
size of around $4.9 billion in FY-2017 after United States, Japan and China. The Indian pesticide
industry is predominated with generic version products and has a substantial opportunity to explore
the drugs going off-patent during FY2017-2020 and through acquisitions and strategic partnerships of
global giants with domestic players.
www.careratings.com : Outlook of Indian Pesticide Industry
India being, an Agriculture based Economy it has become one of the strategically important
countries for Agro related Businesses, In Purview of this on March 11th 2015, a Japanese Company
Nihon Nohyaku Co. Ltd., had acquired the stakes of Hyderabad Chemicals Pvt. Ltd., Which now
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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transformed into commencement of the manufacturing and sales of their proprietary active
ingredients in India, and the sales of finished products in the country through “Nichino India”.
2.4 Demand and Supply Gap
The Indian pesticides industry is characterized by low capacity utilization. The total installed
capacity in 2011 is 146,000 tonnes and has a low capacity utilization of <60%. The industry suffers
from high inventory owing to seasonal and irregular demand on account of monsoons. The
consumption of pesticides in India is low in comparison to other countries. There is a marked
difference in the consumption pattern of pesticides in India vis-à-vis the rest of the world. Insecticides
account for 76% of the total domestic market. On the other hand, herbicides and fungicides have a
significantly higher share in the global market. Crops like cotton, wheat and rice together account for
70% of total agrochemical consumption.
2.5 Imports vs. Indigenous production, Export Possibility, Domestic/Export Markets
The Indian crop protection industry was estimated to be USD 4.25 billion in FY14 and is
expected to grow at a CAGR of 12% to reach USD 7.5 billion by FY19. Exports currently constitute
almost 50% of Indian crop protection industry and are expected to grow at a CAGR of 16% to reach
USD 4.2 billion by FY19, resulting in 60% share in Indian crop protection industry. Domestic market
on the other hand would grow at 8% CAGR, as it is predominantly monsoon dependent, to reach
USD 3.3 billion by FY19. Globally, India is fourth largest producer of crop protection chemicals, after
United States, Japan and China. The crop protection companies in India can be categorized into
three types –Multi-National, Indian including public sector companies and small sector units.
Source: A Report on Indian Agrochemical Industry
2.6 Employment Generation
The expansion facility will generate direct and indirect employment. At present the company
has over 197 employees. About 397 employees including existing 197 employees will be benefitted
due to the proposed project, in that 187 nos. direct employment and 210 nos. of indirect employment.
3.0 Project Description
3.1 Type of the project including interlinked and interdependent projects, if any:
The proposed expansion of Pesticide technical, its intermediates, Bio Pesticides & Pesticides
Formulations with R&D products manufacturing unit falls under Category 'A' project under 5 (b) of EIA
Notification 2006 and its subsequent amendments. The proposed unit is located in KIADB Industrial
area, Humnabad, Bidar District, Karnataka. There is no interlink and interdependent project for this
expansion project.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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3.2 Location
The Unit is located in Plot nos. 50, 82P, 83 and 84P, KIADB Industrial Area, Humnabad Taluk,
Bidar district, Karnataka. Project site co-ordinates of all corners are presented in Table 1. The project
site is well connected by the State High Way.
Table 1: Co-ordinates of all corners of the Project site
Sl. No. Latitude Longitude Sl. No. Latitude Longitude 1 17°45'24"N 77° 5'39"E 5 17°45'28"N 77° 5'54"E 2 17°45'28"N 77° 5'44"E 6 17°45'21"N 77° 5'47"E 3 17°45'25"N 77° 5'48"E 7 17°45'17"N 77° 5'46"E 4 17°45'29"N 77° 5'53"E 8 17°45'19"N 77° 5'44"E
The map showing general location, specific location, Google map showing the Co-ordinates
and Plant layout of the project showing existing and proposed facilities are presented at Annexures- XI, XII, XIII and XIV respectively.
3.3 Alternate Sites
This proposed expansion project is in the existing plant premises in KIADB Industrial Area,
Humnabad Taluk, Bidar district, Karnataka. Hence, Alternate sites are not considered for the present
expansion project.
Environmental considerations of this expansion project site.
• 2.3 km away from human habitation i.e. Humnabad-2.3 km (NE)
• Water Bodies
a) Pond Near Dhumansur Tanda at 6.1 km (NE)
b) Pond Near Hallikhed at 7.6 km (S)
c) Mullamari Reservoir at 9.1 km (SW)
d) Chandri Halla at 2 Km (N)
• Reserved forests:
RF near Kallur Tanda (open scrub)-3.1 km (S)
RF near Pandaragera (Dense scrub)-5.8 km (SW)
• Exist Transportation and Communication network
• There are no rare or endangered or endemic or threatened (REET) species of animals or birds.
3.4 Size or Magnitude of Operation Project Area: 5.46 Ha.
Production Capacity: 6251.8TPA from Pesticide Technical products & Bio pesticides along
with R&D products (permitted production capacity: 1900 TPA). The permitted (EC, CFO) and
proposed products with its production capacities are presented in Tables 2A, 2B & 3A respectively.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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Table 2A: Permitted Products and their Capacities as per EC-2012
Sl. No. Name of the product Quantity
(MTPA) 1. Cartap Hydrochloride technical 1000 2. Indoxacarb technical 50 3. Acephate technical 250 4. Monochrotophos technical 600
Total Production Quantity 1900
Table 2B: Permitted Products and their Capacities as per CFE-2014
Sl. No. Name of the product
Consented Capacity
(TPA)
Additional Capacity
(TPA) 1. Profenofos -- 150 2. Imidachlopride -- 50 3. Acetamipride -- 30 4. Buprofugin -- 50 5. Fipronil -- 25 6. Chloropyrofos -- 100 7 Dichlorvos -- 100 8. Tricyclazole -- 50 9 Chlodinofop -- 25
Revises (Reduced) Capacity TPA 10. Cartap Hydrochloride technical 1000 800 11. Indoxacarb technical 50 50 12. Acephate technical 250 220 13 Monochrotophos technical 600 250
Total 1900 1900
Table 3A: Proposed Products, their Capacity and End Use Sl. No. Products Quantity
kg/day Quantity
(TPA) CAS No. End Use
1. Acephate 66.67 24 30560-19-1 Insecticide 2. Acetamiprid 166.67 60 160430-64-8 Insecticide 3. Azoxystrobin 100 36 131860-33-8 Fungicide
4 5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethyl phenyl)pyrazole (Phenyl Pyrazole)
333.33 120 120068-79-3 Intermediate
5 Benzpyrimoxan (NNI-1501) 666.67 240 1449021-97-9 Insecticide 6 Bifenthrin 166.67 60 82657-04-3 Insecticide 7 Bispyribac sodium 33.33 12 125401-92-5 Herbicide 8 Bufrofezin 666.67 240 69327-76-0 Insecticide 9 Cartap Hydrochloride 50 18 15263-52-2 Insecticide
10 Chloropyrifos 66.67 24 2921-88-2 Pesticide 11 Clodinafop Propargyl 83.33 30 105512-06-9 Herbicide 12 Cloquintocet Mexyl 250 90 99607-70-2 Herbicide
13 (R)-(+)-2-(4-Hydroxyphenoxy) Propionic acid (DHPPA) 166.67 60 94050-90-5 Intermediate
14 Diafenthiuron 1000 360 80060-09-9 Insecticide
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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Sl. No. Products Quantity
kg/day Quantity
(TPA) CAS No. End Use
15 Ethiprole 166.67 60 181587-01-9 Insecticide 16 Fenoxanil 166.67 60 115852-48-7 Fungicide 17 Fenpyroximate 333.33 120 134098-61-6 Insecticide 18 Fipronil 500 180 120068-37-3 Insecticide 19 Flubendiamide 333.33 120 272451-65-7 Pesticide 20 Flutolanil 1333.33 480 66332-96-5 Fungicide 21 Imidacloprid 2000 720 138261-41-3 Insecticide 22 Indoxacarb 100 36 144171-61-9 Insecticide 23 Isoprothiolane 3333.33 1200 50512-35-1 Fungicide 24 Meta isopropoxy aniline [MIPA] 3000 1080 41406-00-2 Intermediate 25 Metaflumizone 33.33 12 139968-49-3 Insecticide 26 Orthosulfamuron 66.67 24 213464-77-8 Herbicide 27 Profenofos 166.67 60 41198-08-7 Insecticide 28 Pyflubumide 50 18 926914-55-8 Insecticide 29 Pymetrozine 333.33 120 123312-89-0 Insecticide 30 Pyraflufen-ethyl 66.67 24 129630-19-9 Herbicide 31 Pyrafluprole 66.67 24 315208-17-4 Insecticide 32 Pyrifluquinazon 66.67 24 337458-27-2 Insecticide 33 Pyriprole 33.33 12 394730-71-3 Insecticide 34 Quizalofop ethyl 33.33 12 76578-14-8 Herbicide 35 Sodium Trifluoromethane Sulfinate 500 180 2926-29-6 Intermediate 36 Tebufenpyrad 66.67 24 119168-77-3 Insecticide 37 Thiodicarb 722.34 260 59669-26-0 Insecticide 38 Tiadinil 666.67 240 223580-51-6 Fungicide 39 Tolfenpyrad 100 36 129558-76-5 Insecticide 40 Tricyclazole 1166.67 420 41814-78-2 Fungicide 41 Chlorantraniliprole 166.67 60 500008-45-7 Insecticide 42 Dimethoate 33.33 12 60-51-5 Insecticide 43 Ethion 33.33 12 563-12-2 Insecticide 44 Hexaconazole 33.33 12 79983-71-4 Fungicide 45 Penoxsulam 66.67 24 219714-96-2 Herbicide 46 Pretilachlor 333.33 120 51218-49-6 Herbicide 47 Sulfosulfuron 33.33 12 141776-32-1 Herbicide 48 Thiamethoxam 333.33 120 153719-23-4 Insecticide
Total 9 products to be manufactured from the total 48 products 13889.01 5000
Bio-Pesticides 1 Bio Pesticides 3472.2 1250
R & D Products 1 R&D Products 5 1.8
Total Production 9 campaign Pesticides Technical products, Bio-Pesticide products & R&D products
17366.21 6251.8
Source: Nichino Chemical India Pvt. Ltd.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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List of By-Products
Sl. No
Name of the By-Product
Quantity Kg/day
Quantity (TPA) Name of the Product
1 Ammonium Sulphate 29.48 10.6 Acephate 2 Acetic acid 26.8 9.6 3 Potassium Bisulphate 50 18.0 Azoxystrobin
4 Potassium Chloride 891.91 321
Azoxystrobin, Bifenthrin, Cloquintocet Mexyl, Fenpyroximate, Imidacloprid, Quizalofop Ethyl, Thiamethoxam,
5 Hydrogen Chloride 592.15 213.2 Benzpyrimoxan 6 Phosphoric acid 794.95 286.2 Benzpyrimoxan 7 Ammonia 48 17.3 Diafenthiuron
8 Potassium Bromide 2804.68 1009.7 Fenpyroximate, Metaisopropoxy Aniline
9 Trimethylamine Bromoethane 82.3 29.6 Profenofos
10 Potassium bicarbonate 944.55 340 Imidacloprid, Quizalofop Ethyl, Thiamethoxam
11 Sodium Bromide 17.82 6.4 Ethion Source: Nichino Chemical India Pvt. Ltd.,
Table 3B: Products Permitted, Proposed and Total After expansion with its Status
Sl. No. Products Permitted
(TPA)
Proposed / Additional / (Reduced)
(TPA)
Total After Expansion
(TPA) Status after Expansion
1 Acephate 220 (-196) 24 Reduced 2 Acetamiprid 30 30 60 Increased 3 Azoxystrobin -- 36 36 New
4
5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethyl phenyl)pyrazole (Phenyl Pyrazole)
-- 120 120 New
5 Benzpyrimoxan (NNI-1501) -- 240 240 New 6 Bifenthrin -- 60 60 New 7 Bispyribac sodium -- 12 12 New 8 Bufrofezin 50 190 240 Increased 9 Cartap Hydrochloride 800 (-782) 18 Reduced 10 Chloropyrifos 100 (-76) 24 Reduced 11 Clodinafop Propargyl 25 5 30 Increased 12 Cloquintocet Mexyl -- 90 90 New
13 (R)-(+)-2-(4-Hydroxyphenoxy) Propionic acid (DHPPA) -- 60 60 New
14 Diafenthiuron -- 360 360 New 15 Ethiprole -- 60 60 New 16 Fenoxanil -- 60 60 New
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
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Sl. No. Products Permitted
(TPA)
Proposed / Additional / (Reduced)
(TPA)
Total After Expansion
(TPA) Status after Expansion
17 Fenpyroximate -- 120 120 New 18 Fipronil 25 155 180 Increased 19 Flubendiamide -- 120 120 New 20 Flutolanil -- 480 480 New 21 Imidacloprid 50 670 720 Increased 22 Indoxacarb 50 (-14) 36 Reduced 23 Isoprothiolane -- 1200 1200 New
24 Meta isopropoxy aniline [MIPA] -- 1080 1080 New
25 Metaflumizone -- 12 12 New 26 Orthosulfamuron -- 24 24 New 27 Profenofos 150 (-90) 60 Reduced 28 Pyflubumide -- 18 18 New 29 Pymetrozine -- 120 120 New 30 Pyraflufen-ethyl -- 24 24 New 31 Pyrafluprole -- 24 24 New 32 Pyrifluquinazon -- 24 24 New 33 Pyriprole -- 12 12 New 34 Quizalofop ethyl -- 12 12 New
35 Sodium Trifluoromethane Sulfinate
-- 180 180 New
36 Tebufenpyrad -- 24 24 New 37 Thiodicarb -- 260 260 New 38 Tiadinil -- 240 240 New 39 Tolfenpyrad -- 36 36 New 40 Tricyclazole 50 370 420 Increased 41 Chlorantraniliprole -- 60 60 New 42 Dimethoate -- 12 12 New 43 Ethion -- 12 12 New 44 Hexaconazole -- 12 12 New 45 Penoxsulam -- 24 24 New 46 Pretilachlor -- 120 120 New 47 Sulfosulfuron -- 12 12 New 48 Thiamethoxam -- 120 120 New 49 Dichlorvos 100 - -- Dropped
50 Monochrotophos technical
250 - -- Dropped
3.5 Project Description
The manufacturing process of Pesticides consists of chemical synthesis and multiple stages
of processing extending to maximum of 4 stages involving different types of chemical reactions.
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Process description with flow chart details for all 48 products and Typical Bio-Pesticide product are
enclosed at Annexure-XV. These pesticides & Biopesicides are mainly used in agricultural
production by preventing crop losses before and after harvesting. Industry will implement the proven
technologies in the R&D for the cost effective & environment friendly practices. The plant layout
showing existing and proposed components of the project is enclosed at Annexure-XIV.
3.6 Raw Materials
The raw materials required for the manufacture of proposed products are the
chemicals/solvents and the fuel. The chemicals required for the process are mostly secured from the
local (indigenous) markets. Some of these raw materials will be imported from various countries.
Mode of transportation of all raw materials and finished products from the project site is by road to
local markets and by road / rail / sea if exported.
• The Pesticides manufacturing involve the use of various chemicals and organic solvents either
directly as reactant or for extraction of a product of interest from the reaction mixture.
• About 60 TPD of coal will be used in the proposed 2 nos. of 5 TPH coal / bio fuel fired boilers
along with existing 3 and 2 TPH coal fired boilers.
• Diesel of about 300 lit/hr will be used in the proposed DG sets of 625 KVA, in addition to
existing 625 KVA & 250 KVA DG sets. DG sets are used as standby during power failure.
• The proposed power requirement of the plant is 1350 KVA (CMD) including existing 900 KVA
(CMD). Power will be met from Karnataka State Power Distribution Corporation Limited.
• The chemicals (raw materials) required for the manufacture of proposed products is presented
at Annexure -XVI and Hazardous chemicals list is presented at Annexure-XVII.
3.7 Resources Optimization / Recycling and Reuse
R&D facility in the unit is making all efforts to recycle the wastes / reuse wherever possible.
However, R&D is a continuous process, where improvements in the processes adopted by the
industry, waste minimization etc. will be worked out as the project progresses. Following are some of
the recycle options proposed by the Proponent.
Improvement of yield of the products so as to reduce the waste generation during
manufacturing.
Industry uses zero liquid discharge plant to reuse all treated effluents as makeup water for
utilities like Cooling Tower. This will reduce the fresh water consumption.
All solvents are recovered to the extent possible and reused in the process.
Organic residue, spent carbon, distillation residue will be sent to Authorized Cement Industries
to burn in Cement Kiln as an alternate fuel or TSDF in case of shut down of Cement
industries.
Boiler ash will be sent to Brick manufacturing units.
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ETP sludge / Evaporation salts will be sent to TSDF or Authorized Cement Industries based
on the calorific value of the waste.
Container & container liners of hazardous chemicals, Polythene / HDPE Bags, broken plastic
drums will be disposed off to outside agencies after complete detoxification.
Spent catalyst will be sent back to suppliers
Waste Lead acid batteries will be sent back to suppliers on buy back basis.
Optimum utilization of solar energy.
There is tremendous potential for implementation of clean technologies, recovery and reuse
techniques in this proposed APIs unit which will be explored and implemented after R&D process.
3.8 Availability of Water and Energy
Fresh water requirement is about 367 KLD which will be met from bore wells and private
tankers. The proposal is to minimize the effect on the level of water table by practicing reuse /
recycling of the treated water wherever possible thereby reducing the fresh water requirement.
Characteristics of Ground water are enclosed at Annexure–XVIII.
The proposed power requirement (Contract Power Demand) of the plant is 1350 KVA
including existing 900 KVA and it is sourced from the Karnataka State Power Distribution Corporation
Limited. Coal and Diesel will be procured from the distribution sources closer to the project site.
3.9 Quantity of Wastes Generation and their Management /Disposal
3.9.1 Water requirement and Wastewater Generation and their Management / Disposal
The permitted water requirement and waste water generation with treatment is presented in
Table 4. The proposed gross water requirement after expansion will be 527 KLD of which total fresh
water requirement will be 367 KLD. Treated effluent from ETP-ZLD of about 162 KLD will be reused
in utilities. Fresh water will be met from bore wells and private tankers. Proposed Water Requirement
and Waste water Generation with Segregation is presented in Table 5. The sources of wastewater
generation are from the process, floor & reactor washings, utilities, Q.C, R&D, scrubber and plant
domestic waste. Total proposed wastewater will be 178 KLD, which will be segregated into
HTDS/HCOD & LTDS/LCOD and collected by gravity into a collection tank separately. This individual
effluent will be pumped to the above ground level RCC lined tanks for storage and neutralization then
sent to ETP-ZLD. The effluents segregated quantity, characteristics and treatment flow is briefly
presented in Table 6.
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Table 4 : Existing Water Requirement, Wastewater Generation and its Treatment
(Water consumption & Effluent details for EC / CTE 2010-2012)
Sl. No. Description
Input (KLD)
Output (KLD)
Fresh Water
Evaporation loss /
(Generation) Total
Wastewater Treatment as per Consent Order
1. Process 7.6 (-1) 8.6
( HTDS: 5 KLD LTDS: 3.6 KLD )
Shall be treated and evaporated in MEE and condensate shall be treated in biological treatment plant to the standards (on land for irrigation) and treated effluents shall be used for cooling and gardening.
2. Washings (Reactors, floor washing, etc.)
6.4 -- 6.4 (LTDS)
3. Boiler & Cooling tower Make up 33 25 8
(LTDS) 4. Gardening 2 2 0
5. Domestic (Sewage) 2 -- 2
(LTDS)
Sewage shall be treated in septic tank with soak pit. No overflow from soak pit allowed.
Total 51 26 25
Table 5: Proposed Water Requirement and Waste water Generation with Segregation
Description Input (KLD) Output (KLD)
Fresh Water
Recycled Water
Evaporation / Handling
Loss Total
Wastewater Segregation type of
Wastewater
Process (9 products at a time) 91 -- (-5) 96
(105) HTDS/HCOD
Washings (reactor, centrifuges, nutch filters, dryers, floor, etc.,)
10 -- -- 10 LTDS/LCOD
Boiler (5, 5, 3 & 2 TPH boilers)
108 -- 96 12
(Blow down) Utilities (LTDS/LCOD)
(makeup) Cooling Tower 4200 TR 92 160 231 21
(Bleed) Fresh water RO rejects 10 -- -- 10 LTDS / LCOD
Scrubber 10 -- -- 10 HTDS / LCOD Q.C, R&D & formulation 3 -- -- 3 LTDS/LCOD
Domestic (397 nos @50 lpcd) 20 -- 4 16 LTDS/LCOD Greenbelt (4 acres @ 5KL/acre) 20 -- 20 -- -- Formulation 3 -- 3 --
Total
367 162 349 178 Stripper condensate 0.5 KLD; Moisture in salt & ETP sludge is 1 KLD, Water loss in ETP 16.5 KLD (Total water loss is 18 KLD = 10 %) Reuse: 162 KLD
527 527
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Table 6: Effluent Treatment Flow as per Segregation
Effluent Characteristics
Quantity (KLD) Treatment Flow
Stream -1 (Process & scrubber)
TDS > 5000 mg/l COD > 5000 mg/l
106
Collection Equalization cum Neutralization Settling Holding Steam stripper MEE along with HTDS effluent Condensate to ETP (biological treatment) Concentrate to ATFD MEE & ATFD Condensate to ETP (Biological Treatment) along with domestic wastewater holding tank Pressure Sand Filter Activated Carbon Filter ETP RO system RO permeate water reuse in Cooling towers. ETP RO rejects to MEE. ATFD Salts to TSDF and stripped solvents to SPCB authorized cement industries
Stream- 2 (Washings, Utilities, QC, R&D, Formulation and
Domestic) TDS / COD < 5000 mg/l
62 Collection Equalization cum Neutralization ETP (Biological Treatment) along with MEE & ATFD Condensate
Stream 3 (Fresh water RO rejects) 10 Collection Tank ETP RO system
Existing treatment system will be enhanced to meet the proposed effluent quantities. All the
proposed additional tanks in the ETP will be constructed / installed above the ground with water proof
lining. These individual effluents will be pumped to the RCC lined tanks for storage and neutralization
and then sent to upgraded ETP-ZLD of 200 KLD capacity within the plant premises. Effluent
Treatment Plant flow chart is enclosed as Annexure-XIX.
ETP – ZLD facility consists of primary treatment (equalization and neutralization), thermal
treatment (stripper with MEE, ATFD), secondary treatment (biological) and tertiary treatment
(Pressure sand filter, Activated carbon filter & Reverse Osmosis) will be provided. Domestic
wastewater will be sent to ETP (biological treatment). Concentrate from MEE system will be sent to
ATFD and the salts from the evaporation system will be collected and sent to TSDF or Authorized
Cement industries for safe disposal based on calorific value of the waste.
3.9.2 Hazardous / Solid Waste Generation, Handling and their Disposal
Hazardous / Solid waste will be segregated, detoxified and collected in the HDPE drums /
bags and will be stored in the covered and raised platform with Leachate collection system. The
existing and proposed solid waste and other waste generated, handling and disposal method from
the various stages of Pesticides manufacturing plant is presented in the Tables 7 & 8 respectively. Spillages such as wastewater / solid wastes / raw materials are possible and the risk of this would be
limited to within the premises of the manufacturing facility. A precautionary measure like spillage
control management is practiced in the industry.
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Table 7: Hazardous Waste Generation from the Existing (CFO) Products
Description Waste Category
Quantity Disposal method as per CFO
Used Oil 5.1 0.3 KL/A
Shall be collected in leak proof containers & disposed to KSPCB registered authorized re-processors provided the oil meets the standards as per Schedule-5 Part-A of the Rules.
Organic Residue 29.1 213 MT/A
Shall be stored in a secured manner and handed over to KSPCB authorized incinerator/ co-processing in cement kiln.
Discarded containers 33.3 1000 No’s/A Shall be stored in secured manner and handed over to authorized recycler after wash only
Sludge from MEE 34.3 5.4 MT/A Shall be stored in secured manner and handed over to TSDF
Table 8: Hazardous / Solid Waste Generation from the Proposed Products
Sl. No. Description
Proposed Quantity
(TPD) HW Stream Handling
Method Disposal
1. Organic residue from Process 2.1 28.1 of Schedule -I
HDPE Drums
Sent to SPCB Authorized Cement
industries or to TSDF for Incineration
2. Distillation Bottom Residue (1% of spent solvents) 0.5 36.1 of
Schedule -I
3. Spent carbon 0.01 28.3 of Schedule -I
4. Inorganic & Evaporation salt (Process) (10% moisture) 10.4 28.1 of
Schedule -I HDPE Bags
Sent to SPCB Authorized Cement
industries or to TSDF for Incineration
(based on Calorific value)
5. Evaporation salt with moisture (Non-Process) 0.5 35.3 of
Schedule -I
6. ETP Sludge with moisture 0.5 35.3 of Schedule -I
7. Boiler ash 24 -- HDPE Bags
Sent to Brick Manufacturers
Other Hazardous Waste generation from the Plant
8.
a) Detoxified Container / Liners drums, HDPE Carboys, Fiber Drums,
100 nos./month
33.1 of Schedule-I Designated
covered area
Disposed to SPCB Authorized agencies
after complete detoxification b) PP Bags 0.3 TPM --
9. Spent solvents (49.4 KLD + 1.6 KLD water) 51 KLD 28.6 of
Schedule -I Tanks / Drums
Recovered within the premises
10.
Recovered Solvents from Spent solvents (85% recovery from spent solvents)
42 KLD 28.6 of
Schedule -I
Tanks / Drums
Reuse or sold to Recyclers
11. Spent Mixed solvents (unrecovered solvents) 9 KLD 28.6 of
Schedule -I Tanks/ Drums
Sent to SPCB Authorized agencies
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Sl. No. Description
Proposed Quantity
(TPD) HW Stream Handling
Method Disposal
12. Waste oils & Grease 2 KL/ Annum
5.1 of Schedule -I MS Drums
Sent to SPCB Authorized agencies for
reprocessing
13. Used Lead acid Batteries 30 nos. / annum
A1160 of Schedule-III
Stored in Covered
shed
Sent to suppliers on buy-back basis.
14. Misc. Waste (spill control waste) L.S. -- Stored in
Drums TSDF 15. Rejects L.S. --
16. E- waste L.S. -- Designated covered
area
Authorized reprocessor or
TSDF
17. Waste papers & other types of packing scrap L.S. -- Sold to scrap venders
18. Canteen waste L.S. -- HDPE bags
Composted on site and reused for green belt
19 Bio Medical Waste LS. -- Color coded
containers
Sent to SPCB authorized Biomedical
waste incinerator
20 Off-spec / Shelf Life expired chemicals / Products etc., L.S 28.5 of
Schedule -I HDPE Bags
Sent to SPCB Authorized Cement
industries or to TSDF for Incineration
(based on Calorific value) Note: Hazardous / Solid waste quantities maximum on various combinations i.e., 9 products on campaign products at a point of time & Bio pesticides, formulations R&D products.
3.10 Schematic Flow Sheet for EIA Procedure
The schematic flow sheet for EIA procedure is depicted as Annexure -XX.
4.0 Site Analysis 4.1 Connectivity
This proposed expansion project site is located at a distance (aerial) of 1.4 km (N) from
National Highway No. 65 (Machilipatnam-Hyderabad-Pune); about 0.6 km (W) from NH-218 (Bidar-
Hospet); 52 km (SSW) to Kalaburagi Airport.
4.2 Land Form, Land use and Land Ownership
The proposed expansion is in the existing manufacturing unit. Total land is 5.46 Ha plain land
and is in possession of Project Proponent.
4.3 Topography
The Topography map with a 10 km radius is enclosed as Annexure-XXI.
4.4 Existing Land Use Pattern
The existing and proposed land use pattern of project area (core area) of 5.46 Ha is Industrial
land and shortest aerial distance environmental components in buffer area from the project periphery
are given in Table 9.
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Table 9: Environmental Components shortest distance from Project periphery S. No. Description Distance & Direction w.r.t. site
1. Water bodies • Pond Near Dhumansur Tanda at 6.1 km (NE) • Pond Near Hallikhed at 7.6 km (S) • Mullamari Reservoir at 9.1 km (SW)
2. Reserved Forests • RF near Kallur Tanda (open scrub)-3.1 km (S) • RF near Pandaragera(Dense scrub)-5.8 km (SW)
3. National Parks/ Wild Life Sanctuaries/ Eco sensitive areas
Nil
4. Industries 1. Satya Deeptha Pharmaceutical 2. Lakshmi Durga Chemicals 3. GPR Sciences Pvt. Ltd. 4. Venkata Sai Chemicals (Pharmaceuticals)
5. R K Chemicals 6. Sahiti Organics 7. Kshatriya Organics 8. Skents Chemicals
5. Habitation Humnabad -2.3 km (NE) 4.5 Existing Infrastructure
Internal CC / Black top roads, Transportation facilities, water supply, In-house ETP facility,
Power supply, Primary Health Centre, Conference halls, Fire hydrant system, Telecommunication
facility, canteen etc., are available.
4.6 Soil Classification
The soil in the study area is Laterite soil with brownish in colour and sandy clay texture. Soil
analysis report is enclosed as Annexure-XXII.
4.7 Climate Data from Secondary Sources
The district experiences semi-arid climate with extreme summer. The dust storms and severe
heat waves are common in the district between April and May. The temperature begins to rise
towards the end of February till the end of May, which is the hottest month of the year. Coldest
months are December and January. The temperature varies in the district between 20 ºC and 42 ºC
The year in the district may be divided into summer season from March to May, southwest monsoon
season from June to September, post-monsoon season from October to November and winter
season from December to February. Generally, the monsoon sets in the month of June and reaches
its peak in the month of September. The rainfall generally is spread over 45 to 55 days. Nearly 75%
to 80% of the annual rainfall is during the period of southwest monsoon. A few showers are also
received during the Northeast monsoon period, generally in the month of December. Bidar district
receives an average normal rainfall of 886 mm. The normal rainfall over the district ranges from 821
mm to 998 mm.
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4.8 Social Infrastructure
This proposed expansion project site is located at a distance (aerial) of 1.4 km (N) from
National Highway No. 65 (Machilipatnam-Hyderabad-Pune); about 0.6 km (W) from NH-218 (Bidar-
Hospet); Road network, Transportation facilities, Private water supply, Power supply, Fire station,
Hospitals, Telecommunication facility, Schools, Community centers etc., are available at Humnabad,
Bidar district located at a distance of 2.3 km (aerial distance) and also available in nearby villages.
5.0 Planning
5.1 Planning Concept
Type of Industry: Pesticide technical, its intermediates, Bio Pesticides & Pesticides Formulations
with R&D products manufacturing unit.
Facilities: Industry proposed for expansion at existing land and facilities required for the proposed
project will be provided as per requirement.
Transportation: Transportation of raw materials and final products is done via roads as the proposed
expansion project is well connected to Road, Rail and Airways.
Town and Country Planning Classification: This is industrial area and allotted to Proponent and is
in possession of project proponent.
5.2 Population Projection
Proposal is for expansion of the existing industry and there is a scope for increase in the
population in the vicinity as most of the skilled workers prefers to stay in the nearby locations to avoid
travelling from long distances. However semi skilled and indirect employment potential is from local
villages. Hence, there is a possibility of increase in population of the skilled and semi skilled. The
local unskilled villagers will be preferred for the unskilled jobs such as gardening, movement of
materials, etc. Educated youth will be employed as semi-skilled workers and training will be provided.
However, on the whole there is a possibility of little increase in population of the area.
5.3 Land use Planning
The expansion unit has been proposed in existing area of about 5.46 Ha i.e., (54634.5 sq.m).
Total land is in the procession of the Proponent. The Break-up of the Land in procession of the
proponent is presented in Table 10.
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Table 10: Land Break-up Details
S. No. Description
Existing Area
Additional Area
Total Area
(SQ.M) (SQ.M) (SQ.M) Percent (%)
1. Built-up area 10883 13843 24726 45.2 2. Roads 9990 1120 11110 20.3 3. Greenbelt 18798 Same 18798 34.4 4. Open Area 14963 Reduced 0 0
Total 54634 54634 100
5.4 Assessment of Infrastructure Demand
On assessment of infrastructure demand near the project area; Hospital with Ambulance
facility and Fire station requirement for the nearby villages of project area. Project site located in
Karnataka Industrial Area Development Board (KIADB) Industrial Area, Humnabad, Bidar district,
Karnataka.
5.5 Amenities/Facilities
Industry will continue to provide and upgrade the following amenities / facilities in the
proposed expansion project.
• Canteen • Potable drinking water • Training block • Laying of Concrete internal roads • Fire hydrant facility • Eye/body wash showers • First Aid kits at all prominent places. • Head nurse for emergency medication. • Rest Room for employees • Seating facilities for those employees who do their work standing and ergonomically designed
seating facilities for those who do their work seating • Pre-employment and routine medical examinations and the necessary follow up actions • Communication systems like Phone, Internet with safety measures, etc. • Security system at the entrance etc.
6.0 Proposed Infrastructure
6.1 Industrial Area
Additional Production Blocks, Utilities area, ETP up-gradation has been proposed in the
existing area of 5.46 Ha.
6.2 Residential Area
There will be no residential area within the project site.
6.3 Greenbelt
• The existing Greenbelt area is 1.88 Ha (34.4%) of 5.46 Ha.
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6.4 Social Infrastructure
As Enterprise Social Commitment (ESC), Industry will contribute for development of village
social infrastructure.
6.5 Connectivity
There is no change in connectivity compare to existing facility.
6.6 Drinking Water Management
Potable drinking water will be provided to additional employees. The source of drinking water
is packaged drinking water.
6.7 Sewerage System
Sewage will be generated from the Canteen and Toilets, which will be collected into sewage
collection tank through pipelines and will be sent to ETP – ZLD system which needs to be upgraded
to meet the project demand.
6.8 Industrial Waste Management
Existing storage system needs to be enhanced to meet the expansion project demand. The
management of these wastes is to be handled very sensitively and by adopting proper segregation
techniques.
6.8.1 Process Emissions Management
Manufacturing of Pesticides technical, its intermediates, Bio pesticides, formulation & R&D
products manufacturing unit will result in gaseous emissions. Maximum process emissions for
existing and proposed products are given in Tables 11 & 12 respectively. Proposed gaseous
emissions will be scrubbed in two stages with water and caustic solution based on the characteristics
of gases. Proposed additional 4 scrubbers for the expansion project in addition to the existing 5
scrubbers to scrub the additional process emissions.
Table 11: Maximum Quantity of Process Emissions from Existing Products
Sl. No.
Process Emission
Maximum Quantity on various
combinations (kg/day)
Treatment
1. CO2 208.05 • Scrubbed using Caustic Lye
2. SO2 77.29 • Scrubbed by using CS lye solution
3 CH3Cl 227.09 • Connected to Incinerator with Scrubbing system (Discontinued the Monochrotophos Tech Production)
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Table 12: Maximum Quantity of Process Emissions from Proposed Products
Sl. No.
Process Emission
Maximum Quantity on various combinations
(kg/day) Treatment
1. HCl 693.2 • Scrubbed by using water & CS lye sol.
2. SO2 817.94 • Scrubbed by using CS lye solution
3. CO2 542.68 • Scrubbed using Caustic Lye
4. H2 3.29 • Diffused with Flame Arrestor
6.8.2 Fugitive emissions
Solvents used in the Pesticides technical, its intermediates, Bio Pesticides & Pesticides
Formulations with R&D products manufacturing process unit will be stored in drums and bulk
quantities will be stored in above ground storage tanks.
Solvents are handled in closed conditions thereby reducing the losses in the form of
evaporation.
Proper earthing will be provided to all the electrical equipment and the joints / connections
wherever solvent handling is done.
Reactor and solvent handling pump will have mechanical seals to prevent leakage.
The industry will take measures for reduction of fugitive emissions and for further reduction
industry will provide vent condensers to the tanks.
Chilled brine circulation will be carried out to condensate the solvent vapour and to the
receivers of the solvent vapors which ensures the maximum recovery.
Solvent vapours from the Centrifuge and Catch pots will be connect to vent condensers.
The height of the solvent receiver tank vent is above production block roof level and the
diameter is 20 mm.
Flame proof fitting / equipments / pumps / lighting will be used wherever solvents are used.
The solvent storage tanks will be provided with breather valve to prevent losses
Solvent Input Solvent in
Solvent in Product
Solvent Recovery Effluent Org. residue Handling loss
51.6 0.4 0.17 1.43 0.2 49.4 (95.7%)
6.8.3 Emissions–Utilities
Boilers and DG sets are the main sources contributing to emissions from the plant. Proposed
2 nos. of 5 TPH coal / bio-fuel fired boilers in addition to the existing 3 & 2 TPH coal fired boilers.
Coal of about 60 TPD will be used in the boilers.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
24
Diesel about 300 lit / hr will be used at full operation load in the DG sets. Proposed DG set of
625 KVA, in addition to existing 625 KVA & 250 KVA DG sets. DG sets will be used as standby
during power failure. The stack emissions from the boiler and DG sets are given in Table 13.
Table 13: Stack Emission Details – Proposed
Source Stack Height
(m)
Diameter (m)
Temperature (oC)
Flue Gas Flow rate
(m3/hr)
Exit Gas
Velocity (m/sec)
PM SO2 NOx
kg/hr
Coal Fired Boilers 5 TPH
(Proposed) 30 0.6 150 13308 13.1 0.675 7.08 4.05
5 TPH (Proposed) 30 0.6 150 13308 13.1 0.675 7.08 4.05
3 TPH (Existing) 30 0.5 150 7985 11.3 0.405 4.25 2.43
2 TPH (Existing) 30 0.5 150 5322 7.5 0.27 2.83 1.62
Diesel Generator (DG) sets Proposed 625 KVA 10 0.3 150 3528 13.9 0.0396 0.782 0.84
Existing 625 KVA 10 0.3 150 3528 13.9 0.0396 0.782 0.84 250 KVA 8 0.2 150 1411 12.5 0.016 0.31 0.34
The various measures proposed to minimize the pollution from the boiler are as follows:
Multi-cyclone separator followed by Bag filter will be installed to control the particulate (PM)
emissions within statutory limit of 115 mg/Nm3. To facilitate wider dispersion of pollutants,
30m height stack each will be installed.
The NOx emissions from the boilers will be controlled by controlling combustion measures,
which will be approached by way of low NOx burners or by air stagging in boiler.
Stack height will be based on Sulphur content in fuel as per CPCB guidelines
Stacks will be provided to proposed DG sets as per CPCB / SPCB Guidelines.
Fugitive dust will be controlled by adopting dust extraction and dust suppression measures
and development of greenbelt along the periphery of the proposed Boiler area.
6.8.4 Noise Environment
• Compressors, Boilers and DG sets will be the major noise generating units in the plant.
• The noise levels of the DG sets will be well within the limits as these will be installed with acoustic enclosures. Workers will always be provided with ear muffs.
• All the equipment in the plant would be designed to have a total noise level not exceeding 85-
90 dB(A) as per the requirement of OSHA (Occupational Safety and Health Administration)
standards.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
25
6.9 Hazardous / Solid Waste Management
• Solid waste mainly segregated into process organic residues, inorganic salts, distillation
residue, boiler ash, spent mixed unrecoverable solvents and spent carbon.
• The organic residues, Spent carbon & Spent mixed unrecoverable solvents, distillation residue
can be disposed off to Cement plants as recommended by CPCB for use as alternate fuels
either in the solid or liquid form.
• Boiler ash will be sold to brick manufacturers.
• Inorganic salts are to be sent for landfill at TSDF.
Solid waste will be segregated, stored and disposed as mentioned in the Table 8
6.10 Power Requirement & Supply / Source
The proposed power requirement (Contract Power Demand) of the plant is 1350 KVA
including existing 450 KVA. Proposed DG sets are 625 KVA, in addition to existing 625 & 250 KVA
DG set. DG set which will be used as standby during power failure.
7.0 Rehabilitation and Resettlement (R&R) Plan
The proposed project is in the existing area and is in possession of project proponent.
Therefore Rehabilitation and Resettlement plan is not applicable to this expansion project. The
nearest town is away from 2.3 km away from the project site.
8.0 Project Schedule & Cost Estimates
8.1 Time Schedule for the project construction
The timelines for commencement of proposed construction activity will be from April 2019 as it
is expected that the expansion project will be in a position to obtain Environmental Clearance for the
project and Consent to Establish from the State Pollution Control Board. In end of 2019 the
commercial production is expected to be commenced.
8.2 Estimated Project Cost
Overall estimated cost involved in the total project (existing and proposed) like land, building,
plant & machinery is Rs. 126.89 Crores. Total capital cost allocated towards environmental pollution
control measures is Rs. 8.59 Crores including the existing Rs. 3.44 Cr. Recurring cost will be about
Rs. 9.48 Crores per annum.
9.0 Analysis of proposal (Final Recommendations)
• The proposed expansion project will result in growth of surrounding area by generating direct
and indirect employment to local people. Around 397 members will be benefitted due to the
expansion project (including existing 197 nos.).
• Under the Enterprise Social Commitment, Industry will continue to develop a policy of
developing the surrounding villages in the vicinity by identifying the requirements.
M/s Nichino Chemical India Pvt. Ltd. Pre-Feasibility Report
26
• No adverse effect on environment is envisaged as proper mitigation measures will be taken up.
• Industry will strengthen the existing Safety, Health & Environment Department and also
continue to engage recognized laboratories to carry out all necessary monitoring parameters for
its activities.
• The segregated (HTDS / LTDS) wastewater will regularly analyzed before and after treatment in
ETP-ZLD.
• Qualified staff will be appointed for the purpose of Operation and Maintenance of the pollution
control facilities.
• Stand-by facilities will be provided to all the pumps so as to ensure fail proof treatment, handling
and disposal
9.1 Budgetary allocation for Pollution Control Measures
The management will set aside adequate funds in its budget to fully meet the stated objectives
of the environmental policy. The proposed and existing capital equipment for environmental
management include up-gradation of effluent treatment plant, pipelines and channels for wastewater
discharge, greenbelt development, air pollution control equipments and the environment laboratory.
The Estimated break-up of budgetary allocation for various control measures is presented in Table 14.
Table 14: Budgetary allocation for Pollution Control Measures
S. No. Description
Existing cost (in lakhs)
Proposed cost (in lakhs)
Capital *Recurring Capital *Recurring
1. Air Pollution Control
97 19 85 30 a. Multi-cyclone / Bag filter with Stacks b. Scrubbers
2. Water Pollution Control
100 45 250 450 a. ETP Civil works, Steam stripper, MEE, ATFD, RO and mechanical equipment
3. Noise Pollution Control 15 1 10 2 a. Silencers / acoustic enclosures
4. Solid Waste Management
14 16 10 350** a. Covered Platform with leachate collection system
5. Greenbelt Development 4 3 5 6 6. Occupation Health and Safety 20 20 30 30 7. Fire Management 20 5 20 5 8. Dyke walls and Storm water drains 5 5 5 5 9. Environmental Laboratory 9 4 20 10 10 Miscellaneous 60 30 80 60
Total 344 148 515 948 *Recurring cost includes manpower, consumables, maintenance, energy charges per annum
** includes transportation, stabilization and handling charges to Cement industries / TSDF
Annexures
ANNEXURE - I
27
ANNEXURE - I
28
ANNEXURE - I
29
ANNEXURE - I
30
ANNEXURE - I
31
ANNEXURE - I
32
ANNEXURE - I
33
ANNEXURE - II
34
ANNEXURE - II
35
ANNEXURE - II
36
ANNEXURE - III
46
ANNEXURE - III
47
ANNEXURE - III
48
ANNEXURE - IV
57
ANNEXURE - IV
58
ANNEXURE - V
62
ANNEXURE - V
63
ANNEXURE - V
64
ANNEXURE - V
65
ANNEXURE - V
66
ANNEXURE - VI
67
ANNEXURE - VI
68
ANNEXURE - VI
69
GOVERNMENT OF INDIA
MINISTRY OF CORPORATE AFFAIRS
Certificate of Incorporation Consequent upon Conversion to
Private Limited Company
Corporate Identity Number : U24100TG2013PTC091503.
IN THE MATTER OF NECTAR CROP SCIENCES LIMITED
I hereby certify that NECTAR CROP SCIENCES LIMITED which was originally incorporated on Fifth day ofDecember Two Thousand Thirteen under any previous company law as NECTAR CROP SCIENCES LIMITED andupon an intimation made for conversion into Private limited by shares Company under Section 18 of theCompanies Act, 2013; and approval of Central Government signified in writing having been accorded thereto by theAndhra Pradesh vide SRN C46286373 dated 25/03/2015 the name of the said company is this day changed toNECTAR CROP SCIENCES Private Limited.
Given under my hand at Hyderabad this Twenty Fifth day of March Two Thousand Fifteen.
Hyderabad
2nd Floor , CPWD Building , Kendriya Sadan , Sultan Bazar, Koti Hyderabad - 500195,
Telangana, INDIA
Fresh Certificate of Incorporation Consequent upon Conversion from Public Company to Private Company .
Mailing Address as per record available in Registrar of Companies office:
NECTAR CROP SCIENCES Private LimitedA-24/25, APIE, BALANAGAR,HYDERABAD - 500037,Telangana, INDIA
Registrar of Companies
Hyderabad
Varaha Santoshi Jagirdar
Assistant Registrar of Companies
Digitally signed by NKRISHNA MURTHYDate: 2015.03.2516:09:40 GMT+05:30
Signature Not Verified
ANNEXURE - VII
70
Certificate of Incorporation pursuant to change of name
[Pursuant to rule 29 of the Companies (Incorporation) Rules, 2014]
GOVERNMENT OF INDIA MINISTRY OF CORPORATE AFFAIRS
Registrar of Companies
Mailing Address as per record available in Registrar of Companies office:
Corporate Identification Number (CIN):
Office of the Registrar of Companies
I hereby certify that the name of the company has been changed from NECTAR CROP SCIENCES PRIVATE LIMITED to NICHINO CHEMICAL INDIA PRIVATE LIMITED with effect from the date of this certificate and that the company is limited by shares. Company was originally incorporated with the name NECTAR CROP SCIENCES PRIVATE LIMITED. Given under my hand at Hyderabad this Sixteenth day of December two thousand seventeen.
DS MINISTRY OF CORPORATE AFFAIRS 24
Digitally signed by DS MINISTRY OF CORPORATE AFFAIRS 24 DN: c=IN, o=MINISTRY OF CORPORATE AFFAIRS, postalCode=500068, st=Telangana, street=NAGOLE BANDKAGUDA HYDERABAD, 2.5.4.51=2 ND FLOOR CORPORATE BHAWAN, cn=DS MINISTRY OF CORPORATE AFFAIRS 24 Reason: I attest to the accuracy and integrity of this document Date: 2017.12.16 14:00:11 +05'30'
2nd Floor, CPWD Building Kendriya Sadan, Hyderabad, Telangana, India, 500195
RoC - Hyderabad
RAMESH CHANDRA MISHRA
NICHINO CHEMICAL INDIA PRIVATE LIMITED
A-24/25, APIE, BALANAGAR, HYDERABAD, Hyderabad, Telangana, India, 500037
U24100TG2013PTC091503
ANNEUXRE - VIII
71
3/17/2018 Gmail - Acknowledgement Slip for EC application
https://mail.google.com/mail/?ui=2&ik=e2c370d4b0&jsver=7NKBhY4B7p8.en.&view=pt&search=inbox&th=1622f08ab89d41e6&siml=1622f08ab8… 1/1
Nichino Chemical India Pvt Ltd <[email protected]>
Acknowledgement Slip for EC application 1 message
[email protected] <[email protected]> Fri, Mar 16, 2018 at 7:08 PMTo: [email protected], [email protected]: [email protected], [email protected]
Acknowledgement Slip for amendment in EC
This is to acknowledge that the proposal for amendment in EC has been successfullyuploaded on the portal of the Ministry. The proposal shall be examined in the Ministryto ensure that required information has been submitted. An email will be sent forseeking additional information , if any, within 20 working days. Once verified, anacceptance letter shall be issued to the project proponent.
Following should be mentioned in further correspondence
1. Proposal No. : IA/KA/IND2/73539/20122. Category of the Proposal : Industrial Projects - 23. Name of the proposal : Nichino Chemical India Private Limited4. Date of submission : 16 Mar 20185. Name of the Project proponent along with contact details
a) Name of the proponent : NICHINO CHEMICAL INDIA PVT LTDb) Mobile No. : 9848443076c) State : Karnatakad) District : Bidare) Pincode : 585330
ANNEUXRE - IX
72
ANNEUXRE - X
73
General Location Map
Bidar District
Project Site
India
Karnataka State
Humnabad Tehsil
ANNEXURE - XI
74
Specific Location (Route map)
M/s. Nichino Chemical India Pvt. Limited
M/s. Nichino Chemical India Pvt. Limited
ANNEUXRE - XII
75
Google Image of the Proposed Project with Site Coordinates
Sl. No. Latitude Longitude Sl.
No. Latitude Longitude
1 17°45'24"N 77° 5'39"E 5 17°45'28"N 77° 5'54"E 2 17°45'28"N 77° 5'44"E 6 17°45'21"N 77° 5'47"E 3 17°45'25"N 77° 5'48"E 7 17°45'17"N 77° 5'46"E 4 17°45'29"N 77° 5'53"E 8 17°45'19"N 77° 5'44"E
ANNEXUER - XIII
76
ANNEXURE - XIV
77
Flow Chart
Dichloromethane Stage-1 MassDimethyl Sulfate
Stage-1 Mass By-Product Ammonia (21%) Sol.RecoveryAcetic Anhydride Evaporation LossSulfuric Acid EffluentEthyl Acetate Organic ResidueWater
Acephate
Stage-1 : Dimethyl Phosphoryl Amide is dissolved in the Dichloro methane to get Dimethyl Phosphoryl Amidesolution. To this solution, Dimethyl Sulfate is added to get Isomerised product called Methamidophos.
Stage-2 : Methamidophos is reacted with Acetic Anhydride in the presence of Sulfuric Acid to get Acetylationproduct. The Acetylation product is hydrolised with Ammonia, then the organic layer and aqueous layers areseparated. Organic layer is distilled for recovery of the solvent and Acephate.
PRODUCT : Acephate
Description :
O,O-Dimethyl Phosphoramidothionate
Stage I
Stage II
ANNEXURE - XV
78
Flow Chart
Sol.RecoveryEvaporation Loss
Sodium Hydroxide (98%)
Stage-1 Mass Sol.RecoveryEthyl-N-Cyano Acetaimidate Evaporation LossWater Effluent
Organic Residue
Acetamiprid
Stage-1 : 2-Chloro-5-Chloromethyl Pyridine is reacted with Monomethyl Amine and Sodium Hydroxide inMonomethyl Amine with Methanol to get Stage-1.
Stage-2 : Stage-1 is reacted with Methyl-N-Cyano acetoimidate to get Acetamiprid.
PRODUCT : Acetamiprid
Description :
2-Chloro-5-Chloromethyl PyridineMonomethyl Amine (30% in Methanol)
Stage I
Stage II
ANNEXURE - XV
79
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentPotassium BisulphateTolueneDimethyl formamideWater
Sol.RecoveryEvaporation Loss
2-Cyanophenol EffluentPotassium carbonate Organic ResidueMethanol Process EmissionsWater
Azoxystrobin
Methyl 2-[2-(6-chloropyrimidin-4-yloxy)phenyl]-3,3- dimethoxy propanoate
Stage-1 Mass in Dimethyl formamide
PRODUCT : Azoxystrobin
Description :
Stage-1 : Stage 1 involves the reaction of Methyl 2-[2-(6-chloropyrimidin-4-yloxy)phenyl]-3,3-dimethoxypropanoate (MDCPP) with Potassium bisulphate in toluene. Water is added to dissolve salts. Tolueneis distilled and DMF added to the mass.
Stage-2 : This mass is taken to stage-2 where the reaction of stage-1 intermediate with 2-cyanophenol inpresence of potassium carbonate. DMF is distilled and water added to dissolve the salts and filtered the crudeproduct. The crude product which is crystallized with Methanol to give pure Azoxystrobin technical.
Stage I
Stage II
ANNEXURE - XV
80
Flow Chart
Sol.RecoverySodium Nitrite Evaporation LossHydrochloric acid (32%) EffluentEthyl 2,3-dicyano propionate Organic ResidueAmmonia (25%) Process EmissionsMethanolEthylene dichlorideWater
PRODUCT : 5-Amino-3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole (Phenyl Pyrazole)
Description :
Stage-1 : 2,6-dichloro4-trifluoromethyl aniline reacts with sodium nitrite and HCl(32%) to form diazonium saltwhich further reacts with Ethyl-2,3-dicyanopropionate to give a intermediate. This intermediate cyclize inpresence of ammonia to give Phenyl pyrazole product.
5-Amino-3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole (Phenyl Pyrazole)
2,6-dichloro-4-trifluoromethyl aniline
Stage I
ANNEXURE - XV
81
Flow Chart
4,6-DihydroxypyrimidinePhosphrous oxychloride1,3-propanediol EffluentDimethyl formamide Process EmissionsTolueneWater
4-Trifluromethyl benzyl alcohol EffluentSodium carbonate (25%) Organic ResidueWater Process Emissions
Stage-2 intermediate in Toluene Sol.RecoveryCatalyst Evaporation LossHydrogen EffluentWater Organic ResidueMethanol Process Emissions
Benzpyrimoxan
Stage-1 intermediate in Toluene
Stage-1 : 4,6-dihydroxy pyrimidine, phosphorous oxychloride, and 1,3-propanediol reacted in solvent dimethylformamide and toluene to give the stage -1 intermediate, 4,6-dichloro-5-(1,3-dioxan-2-yl) pyrimidine.
Stage-2 : The stage-1 intermediate is reacted with 4-trifluromethyl benzyl alcohol in presence of a base sodiumcarbonate to give the stage-2 intermediate 6-chloro-5-(1,3-dioxan-2-yl)-[4-(-4-trifluromethyl) benzyloxy)]pyrimidine.
Stage-3 : The stage-2 intermediate is reacted with hydrogen in presence of catalyst to give the final productBenzpyrimoxan technical.
PRODUCT : Benzpyrimoxan
Description :
Stage I
Stage II
Stage III
ANNEXURE - XV
82
Flow Chart
Sol.RecoveryEvaporation Loss
Thionyl chloride EffluentDimethylformamide Organic Residue
Process Emissions
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
DimethylformamidePotassium carbonateTetrabutyl ammonium bromideWater
Stage-1
Lamda Cyhalothric acid (MTH Acid)
Bifenthrin
Stage-1 : Stage 1 involves reaction of 2-methyl-3-biphenyl methyl alcohol with thionyl chloride to prepare BPC.
Stage-2 : Then this intermediate reacts with Lamda cyhalothric acid in stage-2 in presence of potassiumcarbonate to form the product. The solvent is distilled and crude is crystallized with methanol to get Bifenthrintechnical.
PRODUCT : Bifenthrin
Description :
2-methyl-3-biphenyl methyl alcohol (BPA)
Stage I
Stage II
ANNEXURE - XV
83
Flow Chart
Sol.RecoveryEvaporation Loss
2,6-dihydroxy benzoic acid EffluentSodium hydroxide (48%) Organic ResidueTetrabutyl ammonium bromideToluenen-ButanolEthyl acetateWater
Bispyribac Sodium
4,6-dimethoxy-2-methyl sulfonyl pyrimidine
Stage-1 : This process is involving reaction of 2,6-dihydoxy benzoic acid with 2-methyl sulfonyl 4,6-dimethoxypyrimidine in presence of sodium hydroxide to form the product. Then toluene is distilled and the crude iscrystallized with mixture of butanol and ethyl acetate to get Bispyribac sodium technical.
PRODUCT : Bispyribac Sodium
Description :
Stage I
ANNEXURE - XV
84
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentAmmonium bicarbonate Organic ResidueEthylene dichloride Process EmissionsMethanolWater
Buprofezin
N-Tertiary butyl N-isopropyl thio urea
Stage-1 : N-Tertiary butyl N-isopropyl thio urea, N-Chloro methyl N-phenyl Carbamoyl chloride, Ammoniumbicarbonate and Ethylene dichloride were charged to the reactor to get the reaction to form Buprofezin. Wateradded and layer separated to get Buprofezin in EDC. EDC distilled out and methanol added to crystallize andfiltered to get Buprofezin technical.
PRODUCT : Buprofezin
Description :
N-Chloro methyl N-phenyl Carbamoyl chloride
Stage I
ANNEXURE - XV
85
Flow Chart
Dimethylamine (40% in water)Allyl ChlorideEthylene dichloride EffluentSodium Hydroxide (48%)Water
Stage- 1 mass Sol.RecoverySulfuryl Chloride Evaporation LossToluene Process Emissions
Stage 2 massSodium thiocyanateWater Effluent
Stage- 3 mass Sol.RecoveryHydrogen chloride gas Evaporation LossMethanol Organic ResidueWater
Cartap Hydrochloride
Stage-1 : Allyl chloride (liquid), dimethylamine (40% solution in water) and sodium hydroxide (30%) solution arereacted to give stage-1 intermediate.
Stage-2 : .stage-1 intermediate reaction with sulfuryl chloride to give stage-2 intermediate.
Stage-3 : Stage-2 intermediate reacted with sodium thiocyanate to give Stage-3 intermediate.
Stage-4 : Stage-3 intermediate reacted with hydrochloride gas passing gives the final product, CartapHydrochloride.
PRODUCT : Cartap Hydrochloride
Description :
Stage I
Stage II
Stage III
Stage IV
ANNEXURE - XV
86
Flow Chart
2,3,5,6-Tetrachloro PyridineCaustic lye (48%) Stage-1 MassWater
Stage -1 Mass Sol.RecoveryEvaporation Loss
EffluentEthylene dichloride Organic Residue
Chlorpyrifos
Diethoxy thiophosphoryl chloride
PRODUCT : Chlorpyrifos
Description :
Stage-1 : ,3,5,6-tetrachloropyridine reacted with sodium hydroxide in water to give sodium salt of 3,5,6-trichloro-2-hydroxy pyridine.
Stage-2 : This stage 1 material is then reacted with DETCl (diethoxy thiophosphoryl chloride) in presenceEthylene dichloride as solvent to give the product chlorpyrifos. Ethylene dichloride layer is distilled to givechlorpyrifos technical.
Stage I
Stage II
ANNEXURE - XV
87
Flow Chart
Stage -1 MassProcess Emissions
5-Chloro-2,3-difluoropyridinePotassium carbonateToluene
Stage-1 Mass Sol.RecoveryPropargyl chloride Evaporation LossMethanol EffluentCarbon Organic ResidueWater Spent Carbon
R-(+)-2-[4-5(-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid
PRODUCT : Clodinafop Propargyl
Clodinafop Propargyl
Stage-1 : This process is involving two stages. Stage 1 involves preparation of potassium salt of R-(+)-2-[4-5(-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid by reacting 5-Chloro-2,3-difluoropyridine with R(+)-2-(4-hydroxy phenoxy)propionic acid in presence of base and solvent.
Stage-2 : Stage 2 involves reaction of potassium salt of R-(+)-2-[4-(5-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid resulted from Stage 1 with propargyl chloride in solvent to give crude product andfollowed by crystallization with methanol to give Clodinafop Propargyl.
Description :
Stage I
Stage II
ANNEXURE - XV
88
Flow Chart
2-HeptanolChloro acetic acid Stage-1 massn-Hexane EffluentWater
Stage-1 Mass Sol.Recovery8-Hydroxy-5-chloroquinoline Evaporation LossPotassium Carbonate EffluentToluene Organic ResidueMethanolWater
PRODUCT : Cloquintocet Mexyl
Description :
Stage-1 : Chloroacetic acid and 2-heptanol reacted to give 2-heptyl chloracetyl ester in presence of n-Hexaneas solvent. Stage 1,
Stage-2 : Stage 1 is reacted with 8-hydroxy quinoline in presence of potassium carbonate and toluene to givethe product Cloquintocet mexyl. Water is added and layer separation done., Toluene layer is distilled, methanoladded to crystallize the product and filtered to get the product.
Cloquintocet Mexyl
Stage I
Stage II
ANNEXURE - XV
89
Flow Chart
D-methyl lactate Stage 1 MassThionyl chloride EffluentWater Process Emissions
Stage 1 Mass Sol.RecoveryHydroquinone Evaporation LossSodium hydroxide (48%) EffluentMethylisobutyl ketone Organic ResidueSulfuric acidHydrochloric acid(33%)Water
PRODUCT : (R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]
Description :
Stage-1 : This process is involving the reaction of D-methyl lactate and thionyl chloride to prepare theintermediate.
Stage-2 : Methyl-2-chloro propionate which further reacts with hydroquinone in the presence of a base, sodiumhydroxide to give the product (R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]). This is one of a raw materialfor the production of Clodinafop propargyl.
(R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]
Stage I
Stage II
ANNEXURE - XV
90
Flow Chart
Sol.RecoveryEvaporation Loss
O-xylene Process Emissions
Stage-1 Sol.Recoveryt-butyl amine Evaporation LossDichloromethane EffluentMethanol Organic ResidueWater
Stage-1 : This process is involving two stages. Stage 1 involves the heating of 2,6-diisopropyl-4-phenoxy phenyl thiourea to give the intermediate, -isothiocynate.
Stage-2 : This intermediate reacts with tert-butyl amine to give the product. After the solvent is distilled, thecrude mass is crystallized in methanol to get the product Diafenthiuron technical.
Diafenthiuron
PRODUCT : Diafenthiuron
Description :
2,6-diisopropyl-4-phenoxy phenyl thiourea Stage I
Stage II
ANNEXURE - XV
91
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
Hydrogen Peroxide (30%)DichloromethaneMethanolWater
PRODUCT : Ethiprole
Description :
Stage-1 : This process is involving the reaction between 5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-3-(ethylthio)-1H-pyrazole-4-carbonitrile (sulfide) and hydrogen peroxide in DCM as solvent to obtain Ethiprole.
Ethiprole
5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-3-(ethylthio)-1H-pyrazole-4-carbonitrile (Sulfide)
Stage I
ANNEXURE - XV
92
Flow Chart
D-Methyl Lactate EffluentThionyl chloride Process EmissionsWater
Stage-12,4-DichlorophenolSodium Hydroxide (48%) EffluentTolueneWater
Stage-2 in Toluene Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
Hydrochloric acid(32%)MethanolWater
Stage-3 : The stage-2 intermediate is reacted with 2-amno-2,3,-dimethylbutyronirtrile in presence of base,sodium methoxide to give the final product Fenoxanil technical.
2-amino-2,3-dimethyl butyronitrileSodium methoxide (28%) in Methanol
Fenoxanil
Stage-1 : D-methyllactate and thionyl chloride reacted to give the stage -1 intermediate, methyl 2-chloropropionate.
Stage-2 : The stage-1 intermediate is reacted with 2,4-dichlorophenol in presence of a base sodium hydroxideto give the stage-2 intermediate methyl (2,4-dichlorophenoxy)propionate.
PRODUCT : Fenoxanil
Description :
Stage I
Stage II
Stage III
ANNEXURE - XV
93
Flow Chart
Phenol EffluentSodium Hydroxide (48%)TolueneCuprous chloride [CuCl]Water
Stage 1 in Toluene layer Sol.RecoveryHydroxylamine hydrochloride Evaporation Loss
EffluentOrganic Residue
Potassium hydroxide (50%)MethanolWater
Fenpyroximate
Stage-1 : This process is involving the reaction between Pyrazole 1,3-dimethyl-5-chloro-4-carbaldehyde andPhenol in presence of CuCl to give Stage 1 intermediate.
Stage-2 : Stage 1 intermediate reacts with hydroxylamine hydrochloride and t-butyl 4-(bromomethyl)benzoate inpresence of a base, potassium hydroxide, in a solvent. After the completion of reaction, the inorganic salt isdissolved in water and layer separated. The organic toluene layer distilled and crude mass crystallized inMethanol to get Fenpyroximate technical.
PRODUCT : Fenpyroximate
Description :
Pyrazole 1,3-dimethyl-5-chloro-4-carbaldehyde
t-butyl 4-(bromomethyl)benzoate
Stage I
Stage II
ANNEXURE - XV
94
Flow Chart
Dimethyl amine (40%) EffluentEthylene dichlorideWater
Stage 1 Mass
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
Process EmissionsThionyl chlorideAcetonitrileWater
Fipronil
Stage-1 : Dimethyl amine is added to p-toluene sulfonic acid at low temperature. Then water is distilled out andethylene dichloride added to make solution of p-toluenesulfonyl-dimethylamine complex in EDC.
Stage-2 : Trifluoromethane sulfinyl sodium salt is dissolved in ethyl acetate and filter the inorganic salt. Thenethyl acetate distilled out and added stage 1, p-toluenesulfonyl-dimethylamine complex in EDC. The mass iscooled and added pyrazole and thionyl chloride. Then again raised the temperature to RT and maintained for 10hrs to get fipronil product.
PRODUCT : Fipronil
Description :
P-toluene sulfonic acid mono hydrate
5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole
Sodium trifluoromethanesulfinate (65%)
Stage I
Stage II
ANNEXURE - XV
95
Flow Chart
6-iodo ortho phthaloyl chloride
EffluentProcess Emissions
Ethylene Dichloride
Stage-1[dicarboxamide] Sol.RecoveryHydrogen Peroxide (30%) Evaporation LossMethanol EffluentWater Organic Residue
Stage-2 : 1-N-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-2-N-[2-methyl-1-methylthio)propan-2-yl]benzene-1,2-dicarboxamide which is further oxidized with Hydrogen peroxide in Ethylene dichloride to give the product Flubendiamide.
Flubendiamide
2-methyl-1-methylthio propan-2-amine
2-methyl-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)- aniline
PRODUCT : Flubendiamide
Description :
Stage-1 : 6-iodo ortho phthaloyl chloride reacts with 2-methyl-1-methylthio propan-2-amine and 2-methyl-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)- aniline to give the intermediate 1-N-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-2-N-[2-methyl-1-methylthio)propan-2-yl]benzene-1,2-dicarboxamide
Stage I
Stage II
ANNEXURE - XV
96
Flow Chart
2-Trifluromethyl benzoic acid Sol.RecoveryThionyl chloride Process EmissionsToluene
Stage-1 Mass in Toluene layer Sol.Recovery3-Isopropoxy aniline Evaporation LossMethanol EffluentWater Organic ResidueSodium carbonate Process Emissions
Flutolanil
PRODUCT : Flutolanil
Description :
Stage-1 : Stage 1 involves preparation of 2-trifluromethyl benzoyl chloride by reacting 2-trifluromethyl benzoicacid with thionyl chloride in a solvent.
Stage-2 : Stage 2 involves reaction of 2-trifluromethyl benzoyl chloride with 3-isopropxy aniline in a solvent togive crude product and followed by crystallization with methanol to give Flutolanil product.
Stage I
Stage II
ANNEXURE - XV
97
Flow Chart
2-Chloro-5-Chloro Methyl Pyridine Sol.RecoveryN-Nitro Imino Imidazolidine Evaporation LossPotassium Carbonate EffluentDimethyl formamide Organic ResidueMethanolWater
PRODUCT : Imidacloprid
Description :
Stage-1 : 2-Chloro-5-Chloro Methyl Pyridine, N-Nitro imino imidazolidine, Potassium Carbonate and DimethylFormamide will be charged in reactor and mixed to get Imidacloprid.
Imidacloprid
Stage I
ANNEXURE - XV
98
Flow Chart
Stage-1 MassSol.Recovery
Methyl acetateHydrogenPd/C catalyst
Stage-1 Mass Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
Sodium citrate solution Inorgainc Solid Wasten-HexaneSilicaWater
Indoxacarb
Phenyl methyl ( 5-chloro-2,3-dihydro-2-hydroxy-2-
(methoxycarbonyl)-1H-inden-1-ylidne hydrazine carboxylate
PRODUCT : Indoxacarb
Description :
Stage-1 : Phenyl Methyl [5-Chloro-2,3-dihydro -2-hydroxy-2-(methoxycarbonyl)-1H-inden-1-ylidene hydrazinecarboxylate (solid), methyl acetate (liquid), and Palladium/Carbon catalyst are charged to the reactor.Hydrogenation is done by giving Hydrogen pressure to the reactor. The catalyst is filtered through filter. Filteredcatalyst is reused in the next batch. Total mass, which is liquid, this stage-1 Intermidiate.
Stage-2 : Stage-1 Intermidiate is reacted with Methyl (Chlorocarbonyl)[ 4-(trifluoromethoxy) phenyl] Carbamate (solid) and sodium citrate solution are added and stirred. Methyl acetate layer is taken for distillation to recover the methyl acetate. Recovered methyl acetate will be reused in the next batch. To the residue, n-hexane is added to crystallize the material.Crystallized material is filtered to get the wet product and dried. Hexane mother liquor is taken for recovery of hexane
Methyl (chlorocarbonyl)- [4-(trifluromethoxy) phenyl] carbamate
Stage I
Stage II
ANNEXURE - XV
99
Flow Chart
Diisopropyl malonate Sol.RecoveryCarbondisulfide Evaporation LossSodium Hydroxide (48%) EffluentEthylene dichloride as reactant Organic ResidueEthylene dichlorideMethanolHydrochlorid acid (32%)Water
Stage-1 : This process is involving the reaction of Diisopropyl malonate with Carbon disulphide to form aintermediate salt which further reacts with ethylene dichloride to give the product. After workup, the product iscrystallized with methanol to get Isoprothiolane technical.
Isoprothiolane
PRODUCT : Isoprothiolane
Description :
Stage I
ANNEXURE - XV
100
Stage-2 : Stage-1 intermediate reacted with isopropyl bromide to give the stage-2 intermediate.
Stage-3 : stage-2 is deprotected with methanolic hydrochloride to give the product Meta isopropoxy aniline.
PRODUCT : Metaisopropoxy Aniline
Description :
Stage-1 : Stage 1 involves protection of meta amino phenol with acetic acid to get stage -1 intermediate.
ANNEXURE - XV
101
Flow Chart
Meta amino phenol Sol.RecoveryAcetic acid as reactant Evaporation LossAcetic acid EffluentWater
Stage-1 Sol.RecoveryIsopropyl bromide Evaporation LossPotassium carbonate EffluentDimethyl formamideWater
Stage-2 Sol.RecoveryEvaporation Loss
EffluentSodium Hydroxide Organic ResidueWater
PRODUCT : Metaisopropoxy Aniline
Hydrochloric acid in Methanol (25%)
Metaisopropoxy Aniline
Stage I
Stage II
Stage III
ANNEXURE - XV
102
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
4-cyanobenzyl-3-trifluoromethyl-phenylketone hydrazone
4-trifluoromethoxyphenyl isocyanate
Metaflumizone
PRODUCT : Metaflumizone
Description :
Stage-1 : 4-cyanobenzyl-3-trifluoromethyl-phenylketone hydrazone is reacted with 4-trifluoromethoxyphenylisocyanate in presence of ethylene dichloride to obtain Metaflumizone.
Stage I
ANNEXURE - XV
103
Flow Chart
Sol.RecoveryEvaporation Loss
chlorosulfonylisocyanate EffluentOrganic Residue
Methylene DichlorideMethanolWaterSodium Hydroxide (48%)
2-amino-N,N'-dimethylbenzamide
4,6-dimethoxy-2-aminopyrimidine
PRODUCT : Orthosulfamuron
Description :
Stage-1 : 2-amino-N,N'-dimethylbenzamide is condensed with chlorosulfonyl isocyanate and 4,6-dimethoxy-2-aminopyrimidine in presence of DCM at room temperature to obtain Orthosulfamuron.
Stage I
ANNEXURE - XV
104
Flow Chart
Effluent
Sodium Hydroxide (26%)Water
Stage-1 Stage-2 MassTrimethylamine(30%)
Stage-2 Mass(Q-Salt) Sol.Recoveryn-Propyl Bromide EffluentWater Organic Residue
Profenofos
4-Bromo-2-Chloro Phenol (BCP)Diethyl Thiophosphoryl Chloride (DTC)
PRODUCT : Profenofos
Description :
Stage-1 : 4-Bromo-2-Chloro Phenol is reacted with diethyl thio phosphoryl Chloride and Sodium Hydroxide toget Triester (stage-1) compound.
Stage-2 : tage1 Compound is reacted with Trimethylamine to get (Stage-2) Compund.
Stage-3 : Stage 2 compound is reacted with Propyl Bromide and to get Profenofos.
Stage I
Stage II
Stage III
ANNEXURE - XV
105
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
Process Emissions
2-methyl propionyl chlorideSodium Hydride [NaH] (60%)TetrahydrafuronMethanolWater
N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2-yl)-3-(2-methylpropyl)phenyl]-1,3,5-
trimethyl-N-(2-methylpropanoyl)-1H-pyrazole-
4-carboxamide
Pyflubumide
PRODUCT : Pyflubumide
Description :
Stage-1 : N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2yl)-3-(2-methylpropyl)phenyl]-1,3,5-trimethyl-1H-pyrazole-4-carboxamide is reacted with 2-methyl propionyl chloride inpresence of alkali sodium metal at room temperature to obtain N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2-yl)-3-(2-methylpropyl)phenyl]-1,3,5-trimethyl-N-(2-methylpropanoyl)-1H-pyrazole-4-carboxamide.
Stage I
ANNEXURE - XV
106
Flow Chart
Stage-1 intermediate
Hydrochloric acid(32%)Methanol
Stage-1 intermediate Sol.Recovery3-cyanopyridine Evaporation LossSodium hydroxide (48%) EffluentRaney Nickel Organic ResidueHydrogen Process EmissionsWater
Description :
Stage-1 : This process is involving de acetylation of the reaction of 4-Acetylamino-6-methyl-3-oxo-2,3,4,5-tetrahydro-1,2,4-triazine with Hydrochloric acid to get stage 1 intermediate.
Stage-2 : Then stage 2 intermediate is reacted with 3-Cyano Pyridine in methanol solvent under hydrogenationto give the product. The product then cooled and filtered to get pure Pymetrozine technical.
4-Acetylamino-6-methyl-3-oxo-2,3,4,5-tetrahydro-1,2,4-triazine
Pymetrozine
PRODUCT : Pymetrozine
Stage I
Stage II
ANNEXURE - XV
107
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
3-[(3-hydroxy-4-chloro-5-fluoro)phenyl]-4-chloro-5-difluoromethoxy-1-methyl pyrazole
Pyraflufen-ethyl
PRODUCT : Pyraflufen-ethyl
Description :
Stage-1 : 3-[(3-hydroxy-4-chloro-5-fluoro)phenyl]-4-chloro-5-difluoromethoxy-1-methyl pyrazole is reacted withethylchloroacetate in presence of alkali potassium salt and dimethyl formamide as solvent to obtain Pyraflufen-ethyl.
Stage I
ANNEXURE - XV
108
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
Process Emissions
Dimethylamine hydrochlorideEthylene dichlorideMethanolWaterSodium Carbonate
1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile Monofluoromethyl sulfenyl chloride
Pyrafluprole
PRODUCT : Pyrafluprole
Description :
Stage-1 : 1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile isreacted with Monofluoromethyl sulfenyl chloride in presence of a catalyst and Ethylene dichloride as solvent toobtain Pyrafluprole.
Stage I
ANNEXURE - XV
109
Flow Chart
Sol.RecoveryEvaporation Loss
Acetic anhydride EffluentSodium hydride (60%), NaH Organic ResidueDimethylformamide Process EmissionsEthylacetateMethanolWater
3-[(3-pyridylmethyl)amino]-3,4-dihydro-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl] quinazolin-2-one
Pyrifluquinazone
PRODUCT : Pyrifluquinazone
Description :
Stage-1 : 3-[(3-pyridylmethyl)amino]-3,4-dihydro-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl] quinazolin-2-oneis reaction with acetic anhydride in presence of a strong alkali metal in dimethyl formamide as a solvent to obtainPyrifluquinazon.
Stage I
ANNEXURE - XV
110
Flow Chart
Sol.RecoveryEvaporation Loss
Difluoromethyl sulfenyl chloride EffluentDimethylamine hydrochloride Organic ResidueEthylene dichloride Process EmissionsMethanolWaterSodium carbonate
1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyridylmethyl)amino]-1H-pyrazole-3-carbonitrile
Pyriprole
PRODUCT : Pyriprole
Description :
Stage-1 : 1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile isreacted with Monofluoromethyl sulfenyl chloride in presence of a catalyst and Ethylene dichloride as solvent toobtain Pyrafluprole.
Stage I
ANNEXURE - XV
111
Flow Chart
2,6-dichloro quinoxaline Sol.RecoveryHydroquinone Evaporation LossSodium hydroxide (98%) EffluentDimethyl formamideWater
6-chloro quinoxaline Sol.RecoveryEthyl-2-chloropropionate Evaporation LossPotassium carbonate EffluentDimethyl formamide Organic ResidueWaterMethanol
Quizalofop Ethyl
PRODUCT : Quizalofop Ethyl
Description :
Stage-1 : Stage 1 involves the reaction of 2,6-dichloro quinoxaline with hydroquionone in presence of sodiumhydroxide in a solvent dimethyl formamide to get the Stage-1 intermediate.
Stage-2 : Stage-1 intermediate reacts with ethyl 2-chloro propionate in stage-2 to give Quizalofop ethyltechnical.
Stage I
Stage II
ANNEXURE - XV
112
Flow Chart
Bromotrifluoromethane (gas) Sol.RecoverySodium phosphate Evaporation LossSodiumdithionite (85%) EffluentSodium hydroxide (98%)AcetonitrileWater
Stage-1 : Sodiumdithionite, Sodium phosphate and Bromotrifluoromethane reacted in the presence of sodiumhydroxide under pressure conditions in Acetonitrile and Water as mixture solvent to give the product of Sodiumtrifluoromethane sulfinate.
Sodium Trifluoromethane Sulfinate
PRODUCT : Sodium Trifluoromethane Sulfinate
Description :
Stage I
ANNEXURE - XV
113
Flow Chart
Methyl ethyl ketoneDiethyl oxalate
Sol.RecoveryEvaporation Loss
Toluene EffluentHydrazine hydrate (80%) Organic ResidueDimethyl sulphate Process EmissionsSodium hydroxide(30%)Sulfuryl chlorideDichloromethaneWater
EMCA Thionyl chloride Sol.RecoveryToluene Evaporation Loss4-tertiarybutyl benzyl amine EffluentMethanol Organic ResidueSodium Hydroxide (25%) Process EmissionsWater
Tolfenpyrad
Sodium ethoxide (21%) in ethanol
PRODUCT : Tolfenpyrad
Description :
Stage-1 : Intermediate EMCA: Methylethyl ketone and Diethyl oxalate reacts to give an intermediate whichreacts with hydrazine to get cyclized intermediate. It is reacted with dimethyl sulphate and sodium hydroxide togive an intermediate which on reaction with sulfuryl chloride gives the intermediate EMCA [4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid].
Stage-2 : 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid [EMCA] is reacted with thionyl chloride toform acid chloride and further reacted with 4-tertiarybutyl benzyl amine in presence of sodium hydroxide basein Toluene solvent to obtain Tebufenpyrad.
Stage I
Stage II
ANNEXURE - XV
114
Flow Chart
Methomyl Oxime Sol.RecoveryN-methyl carbamoyl chloride Evaporation LossDichloromethane EffluentCaustic Lye (48%) Organic ResidueWater
Sol.RecoveryStage -1 (Methomyl) Evaporation LossSulfur dichloride EffluentPyridine Organic ResidueMixed XyleneMethanolWater
Stage-2 : This intermediate and Sulfur dichloride reacted in the presence of Pyridine and mixed Xylene solventto give Thiodicarb. . After the reaction, water added to dissolve pyridine hydrochloride and the solid materialfiltered. The wet cake is crystallized in methanol to get Thiodicarb technical. Filtrate is basified to get pyridineand recycled.
Thiodicarb
PRODUCT : Thiodicarb
Description :
Stage-1 : In stage 1, methomyl oxime and N-methyl carbamoyl chloride reacted to give Methomyl asintermediate.
Stage I
Stage II
ANNEXURE - XV
115
Flow Chart
Ethyl acetateHydrazine hydrate (82%) Stage-1 Mass
Stage-1 Mass Sol.RecoveryMethylacetoacetate Evaporation LossDichloromethane Effluent
Stage-2 Mass Sol.RecoveryThionyl chloride Evaporation LossSodium Hydroxide (48 %) EffluentWater Process Emissions
Stage-3 Sol.Recovery3-chloro-4-toluidine Evaporation Loss
EffluentOrganic Residue
Hydrochloric acid (32%)Water
Tiadinil
Stage-1 : Stage 1 involves reaction of ethylacetate and hydrazine hydrate to prepare intermediate 1
Stage-2 : This intermediate reacts with methyl acetoacetate to give intermediate 2 in stage 2.
Stage-3 : Stage 3 involves reaction of thionyl chloride with intermediate 2 to yield the intermediate 3.
Stage-4 : Finally intermediate 3 reacts with 3-chloro-4-toluidine to give Tiadinil technical.
PRODUCT : Tiadinil
Description :
Sodium methoxide (28% in Methanol)
Stage I
Stage II
Stage III
Stage IV
ANNEXURE - XV
116
Flow Chart
Methyl ethyl ketoneDiethyl oxalateSodium ethoxide (21%) in ethanol Sol.RecoveryToluene Evaporation LossHydrazine hydrate (80%) EffluentDimethyl sulphate Organic ResidueSodium hydroxide(30%) Process EmissionsSulfuryl chlorideDichloromethaneWater
p-Cresolp-Chlorobenzonitrile Sol.RecoverySodium hydroxide (48%) Evaporation LossToluene EffluentHydrogen gas Process EmissionsPalladium carbonMethanolWater
EMCA Sol.RecoveryThionyl chloride Evaporation LossToluene EffluentTOBA crude Organic ResidueMethanol Process EmissionsSodium Hydroxide (25%)Water
Tolfenpyrad
PRODUCT : Tolfenpyrad
Description :
Stage-1 : Intermediate EMCA: Methylethyl ketone and Diethyl oxalate reacts to give an intermediate whichreacts with hydrazine to get cyclised intermediate. It is reacted with dimethyl sulphate and sodium hydroxide togive an intermediate which on reaction with sulfuryl chloride gives the intermediate EMCA [4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carboxylic acid].Stage-2 : Intermdiate TOBA: This involves the reaction of p-Cresol and p-chlorobenzonitrile in presence of a base to give an intermediatewhich on hydrogenation gives the intermediate TOBA [4-(p-tolyloxy) benzylamine].
Stage-3 : Tolfenpyrad: EMCA reacts with thionyl chloride in stage-1 and the intermediate further reacts withTOBA to give the product Tolfenpyrad.
Stage I
Stage II
Stage III
ANNEXURE - XV
117
Flow Chart
Sol.RecoveryEvaporation Loss
Formic Acid EffluentWater
Tricyclazole
PRODUCT : Tricyclazole
Description :
Stage-1 : 2-Hydrazine-4-methyl Benzothiazole and Formic acid will be charged in reactor and mixed to getTricyclazole. Recovered Formic Acid to be reused and aqueous layer is sent to effluent treatment plant forfurther treatment purpose.
2-Hydrazino-4-Methyl Benzothiazole
Stage I
ANNEXURE - XV
118
Flow Chart
Sol.RecoveryMethane sulfonylchloride Evaporation Loss3-Picoline EffluentAcetonitrile Organic ResidueDichloromethaneMethanolSodium Hydroxide(30%)Water
Stage-1 : Chlorantraniliprole is prepared by reaction of 3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid with 2-methyl-4-chloro-N-methylcarbamoyl)aniline in presence of methanesulfonyl chloride andpicoline in acetonitrile.
PRODUCT : Chlorantraniliprole
Description :
Chlorantraniliprole
3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid2-methyl-4-chloro-N-methylcarbamoyl)aniline
Stage I
ANNEXURE - XV
119
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
PRODUCT : Dimethoate
Description :
Dimethoate
O,O-dimethyl S-[methylaceto] dithiophosphate
Stage-1 : O,O-dimethyl S-[methylaceto] dithiophosphate is reacted with Monomethyl Amine solution (40%) toget Dimethoate. Ethylene dichloride is used to extract the product and distilled to get Dimethoate technical.
Stage I
ANNEXURE - XV
120
Flow Chart
Diethyl Thiophosphoric Acid Sol.RecoverySodium Hydroxide (35%) Evaporation LossTolueneWater
Stage-1 Mass By-ProductMethylene Dibromide EffluentWater Organic Residue
Description :
Ethion
Stage-1 : Diethyl Thiophosphoric Acid is neutralized with 35% Sodium Hydroxide to get Sodium DiethylThiophosphoric Acid.
Stage-2 : Sodium Diethyl thiophosphoric Acid is reacted with Methylene Dibromide to get Ethion and Sodiumbromide organic layer contains Ethion and Aqueous layer contains sodium bromide, aqueous layer (sodiumBromide layer) selling as a bi product. Organic layer to be purified.Crude Ethion steam spurging to be done to get pure Ehion, Technical. Recovery organic residue sent toincinerator and aqueous layer is sent to ETP for further treatment.
PRODUCT : Ethion
Stage I
Stage II
ANNEXURE - XV
121
Flow Chart
2,4-Dichloro Valerophenone Sol.RecoveryDimethyl Sulfate Evaporation LossDimethyl Sulfide EffluentPotassium HydroxideEthylacetateWater
Stage-1 Mass Sol.Recovery1,2,4-Triazole Evaporation LossDimethyl Formamide EffluentPotassium Carbonate Organic ResidueWater
Hexaconazole
Stage-1 : Valerophenone, Dimethyl Sulfide, Dimethyl sulfate and Potassium Hydroxide will be charged in to thereactor and mixed to get 2-Butyl-2-(2,4-dichloro phenyl) oxirane product.
Stage-2 : 2-Butyl-2-(2,4-dichloro phenyl) oxirane, 1,2,4-Trizole, Dimethyl Formamide and water will be chargedinto the reactor and mixed to get final product Hexaconzole. Aqueous layer is sent to effluent treatment plant forfurther treatment purpose.
PRODUCT : HEXACONAZOLE
Description :
Stage I
Stage II
ANNEXURE - XV
122
Flow Chart
Sol.RecoveryEvaporation Loss
Pyridine EffluentAcetonitrile Organic ResidueDichloromethaneSodium Hydroxide (30%)MethanolWater
2-amino-5,8-dimethoxy-[1,2,4]triazolo[1,5-c] pyrimidine
2-(2,2-Difluoroethoxy)-6-(trifluoromethyl) benzene-1-sulfonylchloride
Stage-1 : Penoxsulam is prepared by reaction of 2-(2,2-Difluoroethoxy)-6-(trifluoromethyl) benzene-1-sulfonylchloride with 2-amino-5,8-dimethoxy-[1,2,4]triazolo[1,5-c]pyrimidine in presence of dry pyridine andacetonitrile.
PRODUCT : Penoxsulam
Description :
Stage I
ANNEXURE - XV
123
Flow Chart
2,6-Diethyl Anilinen-Propoxy Ethylchloride EffluentSodium Hydroxide (25%) Organic ResidueWater
Stage-1 Sol.RecoveryChloro Acetyl Chloride Evaporation LossSodium Bicarbonate EffluentHexane Organic ResidueHydrochloric acid (32%) Process EmissionsWater
Pretilachlor
Stage-1 : 2,6-Diethyl Aniline is reacted with n-Propoxy Ethyl Chloride and Sodium Hydroxide to get (Stage-1)Compound.
Stage-2 : Stage 1 compound is reacted with Chloro Acetyl Chloride in n-Hexane and quenched tosodiumbicarbonate solution to get the product. The solvent , n-Hexane is distilled to Pretilachlor technical.
PRODUCT : Pretilachlor
Description :
Stage I
Stage II
ANNEXURE - XV
124
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentC S Lye (30%) Organic ResidueAcetoneHydrochloric acid(32%)Water Inorgainc Solid Waste
PRODUCT : Sulfosulfuron
Description :
Stage-1 : Sulfonamide, carbamate and Acetone are charged to the reactor. Addition of caustic lye solution at<100C gives the product of sulfosulfuron. Then the mass is neutralized with HCl and centrifuged to getSulfosulfuron technical. Acetone is distilled to recover and reused.
Sulfosulfuron
[4,6-Dimethoxy-2-(phenoxycarbonylamino)-pyrimidine]
[2-Ethylsulfonyl imidazo [1,2-a] pyridine-3-sulfonamide]
Stage I
ANNEXURE - XV
125
Flow Chart
Sol.RecoveryEvaporation Loss
EffluentOrganic Residue
Potassium carbonateTolueneMethanolWater
3-methyl-4-nitroiminoperhydro-1,3,5-oxadiazine
2-Chloro-(5-chloromethyl)thiazole
Description :
Stage-1 : 2-Chloro-(5-chloromethyl)thiazole reacts with 3-methyl-4-nitroiminoperhydro-1,3,5-oxadiazine inpresence of base and solvent. After filtration of potassium salts, the solvent is distilled off and the crude mass iscrystallized from methanol to give Thiamethoxam technical.
Thiamethoxam
PRODUCT : Thiamethoxam
Stage I
ANNEXURE - XV
126
BLOCK FLOW DIAGRAM for AZADIRECTIN BIO PESTICIDE
Cold Press Method Water Spent Kernels as fertilizer
Neem Seed Kernels
Neem Oil
Extraction of Azadirectin
Formulation of
Azadirectin (0.1%) as Bio pesticide
Kernels
ANNEXURE - XV
127
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgAcetic Anhydride = 660 44.0Ammonia (21%) = 938 62.5Dichloromethane = 1000 66.7Dimethyl Sulfate = 127 8.5Ethyl Acetate = 1000 66.7O,O-Dimethyl Phosphoramidothionate = 900 60.0Sulfuric Acid = 320 21.3
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-Chloro-5-Chloromethyl Pyridine = 800 133.3Ethyl-N-Cyano Acetaimidate = 600 100.0Monomethyl Amine (30% in Methanol) = 2000 333.3Sodium Hydroxide (98%) = 202 33.7
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-Cyanophenol = 360 36.0Dimethyl formamide = 2120 212.0Methanol = 2000 200.0
Potassium Bisulphate = 500 50.0Potassium Carbonate = 225 22.5Toluene = 2650 265.0
Methyl 2-[2-(6-chloropyrimidin-4-yloxy)phenyl]-3,3- dimethoxy propanoate = 1056 200.0
PRODUCT : AcephateLIST OF RAW MATERIALS
PRODUCT : AcetamipridLIST OF RAW MATERIALS
PRODUCT : AzoxystrobinLIST OF RAW MATERIALS
ANNEXURE - XVI
128
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2,6-dichloro-4-trifluoromethyl aniline = 800 266.7Ammonia (25%) = 710 236.7Ethyl 2,3-dicyano propionate = 550 183.3Ethylene dichloride = 2400 800.0Hydrochloric acid (32%) = 875 291.7Methanol = 1600 533.3Sodium Nitrite = 264 88.0
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg1,3-propanediol = 310 206.74,6-Dihydroxypyrimidine = 452 301.34-Trifluromethyl benzyl alcohol = 710 473.3Catalyst = 20 13.3Dimethyl formamide = 300 200.0Hydrogen = 10 6.7Methanol = 1000 666.7Phosphrous oxychloride = 1860 1240.0Sodium carbonate (25%) = 1536 1024.0Toluene = 2800 1866.7
PRODUCT : 5-Amino-3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole (Phenyl Pyrazole)
LIST OF RAW MATERIALS
PRODUCT : BenzpyrimoxanLIST OF RAW MATERIALS
ANNEXURE - XVI
129
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-methyl-3-biphenyl methyl alcohol (BPA) = 544 90.7Dimethylformamide = 1360 226.7Lamda Cyhalothric acid (MTH Acid) = 666 111.0Methanol = 1500 250.0n-Hexane = 2000 333.3Potassium carbonate = 400 66.7Tetrabutyl ammonium bromide = 32 5.3Thionyl chloride = 330 55.0
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2,6-dihydroxy benzoic acid = 380 12.7
4,6-dimethoxy-2-methyl sulfonyl pyrimidine = 1150 38.3Ethyl acetate = 500 16.7n-Butanol = 5000 166.7Sodium hydroxide (48%) = 640 21.3Tetrabutyl ammonium bromide = 20 0.7Toluene = 1500 50.0
PRODUCT : BifenthrinLIST OF RAW MATERIALS
PRODUCT : Bispyribac SodiumLIST OF RAW MATERIALS
ANNEXURE - XVI
130
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgAmmonium bicarbonate = 542 361.3Ethylene dichloride = 2100 1400.0Methanol = 2000 1333.3N-Chloro methyl N-phenyl Carbamoyl chlori = 700 466.7N-Tertiary butyl N-isopropyl thio urea = 597 398.0
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgAllyl Chloride = 316 15.8Dimethylamine (40% in water) = 466 23.3Ethylene dichloride = 1270 63.5Hydrogen chloride gas = 150 7.5Methanol = 1269 63.5Sodium Hydroxide (48%) = 350 17.5Sodium thiocyanate = 670 33.5Sulfuryl Chloride = 558 27.9Toluene = 1270 63.5
PRODUCT : BuprofezinLIST OF RAW MATERIALS
PRODUCT : Cartap HydrochlorideLIST OF RAW MATERIALS
ANNEXURE - XVI
131
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgEthylene dichloride = 1700 113.3Diethoxy thiophosphoryl chloride = 598 39.9Caustic lye (48%) = 582 38.82,3,5,6-Tetrachloro Pyridine = 688 45.9
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg5-Chloro-2,3-difluoropyridine = 480 40.0Carbon = 20 1.7Methanol = 1500 125.0Potassium carbonate = 816 68.0Propargyl chloride = 245 20.4R-(+)-2-[4-5(-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionic acid = 567 47.3
Toluene = 1700 141.7
PRODUCT : ChlorpyrifosLIST OF RAW MATERIALS
PRODUCT : Clodinafop PropargylLIST OF RAW MATERIALS
ANNEXURE - XVI
132
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgToluene = 1200 300Potassium Carbonate = 440 110n-Hexane = 900 225Methanol = 1500 375Chloro acetic acid = 300 758-Hydroxy-5-chloroquinoline = 546 1372-Heptanol = 353 88
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgD-methyl lactate = 675 112.5Hydrochloric acid(33%) = 1427 237.8Hydroquinone = 714 119.0Methylisobutyl ketone = 1000 166.7Sodium hydroxide (48%) = 2168 361.3Sulfuric acid = 650 108.3Thionyl chloride = 772 128.7
PRODUCT : Cloquintocet MexylLIST OF RAW MATERIALS
PRODUCT : (R) 2-(4-Hydroxyphenoxy) Propionic Acid [DHPPA]
LIST OF RAW MATERIALS
ANNEXURE - XVI
133
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kgt-butyl amine = 210 210.0O-xylene = 1730 1730.0Methanol = 2000 2000.0Dichloromethane = 300 300.02,6-diisopropyl-4-phenoxy phenyl thiourea = 935 935.0
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg5-amino-1-(2,6-dichloro-4-(trifluoromethyl)phenyl)-3-(ethylthio)-1H-pyrazole-4-carbonitrile (Sulfide)
= 1050 175.0
Dichloromethane = 2100 350.0Hydrogen Peroxide (30%) = 375 62.5Methanol = 2000 333.3
PRODUCT : DiafenthiuronLIST OF RAW MATERIALS
PRODUCT : EthiproleLIST OF RAW MATERIALS
ANNEXURE - XVI
134
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2,4-Dichlorophenol = 580 96.72-amino-2,3-dimethyl butyronitrile = 400 66.7D-Methyl Lactate = 370 61.7Hydrochloric acid(32%) = 385 64.2Methanol = 1200 200.0Sodium Hydroxide (48%) = 320 53.3Sodium methoxide (28%) in Methanol = 650 108.3Thionyl chloride = 423 70.5Toluene = 1000 166.7
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgToluene = 1920 320.0t-butyl 4-(bromomethyl)benzoate = 825 137.5Sodium Hydroxide (48%) = 256 42.7Pyrazole 1,3-dimethyl-5-chloro-4-carbaldehyde = 480 80.0
Potassium hydroxide (50%) = 680 113.3Phenol = 285 47.5Methanol = 2000 333.3Hydroxylamine hydrochloride = 215 35.8Cuprous chloride [CuCl] = 24 4.0
PRODUCT : FenoxanilLIST OF RAW MATERIALS
PRODUCT : FenpyroximateLIST OF RAW MATERIALS
ANNEXURE - XVI
135
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg5-Amino-3-cyano-1-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole = 929 464.5
Acetonitrile = 2085 1042.5Dimethyl amine (40%) = 550 275.0Ethylene dichloride = 2800 1400.0P-toluene sulfonic acid mono hydrate = 550 275.0Sodium trifluoromethanesulfinate (65%) = 695 347.5Thionyl chloride = 345 172.5
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-methyl-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)- aniline = 490 163.3
2-methyl-1-methylthio propan-2-amine = 215 71.76-iodo ortho phthaloyl chloride = 585 195.0Ethylene Dichloride = 1755 585.0Hydrogen Peroxide (30%) = 410 136.7Methanol = 2000 666.7Sodium Bicarbonate = 300 100.0
PRODUCT : FipronilLIST OF RAW MATERIALS
PRODUCT : FlubendiamideLIST OF RAW MATERIALS
ANNEXURE - XVI
136
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-Trifluromethyl benzoic acid = 692 922.73-Isopropoxy aniline = 551 734.7Methanol = 1500 2000.0Sodium carbonate = 193 257.3Thionyl chloride = 434 578.7Toluene = 1385 1846.7
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-Chloro-5-Chloro Methyl Pyridine = 661 1322.0Dimethyl formamide = 1980 3960.0Methanol = 2000 4000.0N-Nitro Imino Imidazolidine = 636 1272.0Potassium Carbonate = 570 1140.0
PRODUCT : FlutolanilLIST OF RAW MATERIALS
PRODUCT : ImidaclopridLIST OF RAW MATERIALS
ANNEXURE - XVI
137
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgHydrogen = 4 0.4Methyl (chlorocarbonyl)- [4- = 595 59.5Methyl acetate = 1576 157.6n-Hexane = 1500 150.0Pd/C catalyst = 10 1.0Phenyl methyl ( 5-chloro-2,3-dihydro-2-hydroxy-2-(methoxycarbonyl)-1H-inden-1-ylidne hydrazine carboxylate
= 80080.0
Silica = 260 26.0Sodium citrate solution = 1017 101.7
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgCarbondisulfide = 284 947Diisopropyl malonate = 695 2317Ethylene dichloride = 2550 8500Ethylene dichloride as reactant = 370 1233Hydrochlorid acid (32%) = 50 167Methanol = 1200 4000Sodium Hydroxide (48%) = 650 2167
PRODUCT : IndoxacarbLIST OF RAW MATERIALS
PRODUCT : IsoprothiolaneLIST OF RAW MATERIALS
ANNEXURE - XVI
138
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgAcetic acid = 550 1650.0Acetic acid as reactant = 452 1356.0Dimethyl formamide = 2000 6000.0Hydrochloric acid in Methanol (25%) = 1100 3300.0Isopropyl bromide = 930 2790.0Meta amino phenol = 820 2460.0Potassium carbonate = 1038 3114.0Sodium Hydroxide = 602 1806.0
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg4-cyanobenzyl-3-trifluoromethyl-phenylketone hydrazone = 665 22.2
4-trifluoromethoxyphenyl isocyanate = 450 15.0Ethylene dichloride = 1330 44.3Methanol = 1200 40.0Triethylamine = 10 0.3
PRODUCT : Metaisopropoxy AnilineLIST OF RAW MATERIALS
PRODUCT : MetaflumizoneLIST OF RAW MATERIALS
ANNEXURE - XVI
139
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-amino-N,N'-dimethylbenzamide = 430 28.74,6-dimethoxy-2-aminopyrimidine = 406 27.1chlorosulfonylisocyanate = 380 25.3Methanol = 1500 100.0Methylene Dichloride = 1200 80.0Sodium Hydroxide (48%) = 225 15.0
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg4-Bromo-2-Chloro Phenol (BCP) = 598 99.7Diethyl Thiophosphoryl Chloride (DTC) = 543 90.5n-Propyl Bromide = 380 63.3Sodium Hydroxide (26%) = 462 77.0Trimethylamine(30%) = 567 94.5
PRODUCT : OrthosulfamuronLIST OF RAW MATERIALS
PRODUCT : ProfenofosLIST OF RAW MATERIALS
ANNEXURE - XVI
140
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgTetrahydrafuron = 1932 96.6Sodium Hydride [NaH] (60%) = 83 4.2N-[4-(1,1,1,3,3,3-hexafluoro-2-methoxypropan-2-yl)-3-(2-methylpropyl)phenyl]-1,3,5-trimethyl-N-(2-methylpropanoyl)-1H-pyrazole-4-carboxamide
= 966 48.3
Methanol = 1500 75.02-methyl propionyl chloride = 230 11.5
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg3-cyanopyridine = 591 197.04-Acetylamino-6-methyl-3-oxo-2,3,4,5- = 967 322.3Hydrochloric acid(32%) = 1050 350.0Hydrogen = 15 5.0Methanol = 2901 967.0Raney Nickel = 10 3.3Sodium hydroxide (48%) = 767 255.7
PRODUCT : PyflubumideLIST OF RAW MATERIALS
PRODUCT : PymetrozineLIST OF RAW MATERIALS
ANNEXURE - XVI
141
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg3-[(3-hydroxy-4-chloro-5-fluoro)phenyl]-4-chloro-5-difluoromethoxy-1-methyl pyrazole
= 880 58.7
Dimethylformamide = 1760 117.3Ethylchloroacetate = 340 22.7Methanol = 1500 100.0Potassium carbonate = 400 26.7
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyrazinylmethyl)amino]-1H-pyrazole-3-carbonitrile
= 960 64.0
Dimethylamine hydrochloride = 195 13.0Ethylene dichloride = 2800 186.7Methanol = 1200 80.0Monofluoromethyl sulfenyl chloride = 240 16.0Sodium Carbonate = 125 8.3
PRODUCT : Pyraflufen-EthylLIST OF RAW MATERIALS
PRODUCT : PyrafluproleLIST OF RAW MATERIALS
ANNEXURE - XVI
142
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg3-[(3-pyridylmethyl)amino]-3,4-dihydro-6-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl] quinazolin-2-one
= 1011 67.4
Acetic anhydride = 243 16.2Dimethylformamide = 2022 134.8Ethylacetate = 2100 140.0Methanol = 1500 100.0Sodium hydride (60%), NaH = 95 6.3
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-5-[(2-pyridylmethyl)amino]-1H-pyrazole-3-carbonitrile
= 927 30.9
Difluoromethyl sulfenyl chloride = 275 9.2Dimethylamine hydrochloride = 195 6.5Ethylene dichloride = 2800 93.3Methanol = 1200 40.0Sodium carbonate = 125 4.2
PRODUCT : PyrifluquinazoneLIST OF RAW MATERIALS
PRODUCT : PyriproleLIST OF RAW MATERIALS
ANNEXURE - XVI
143
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2,6-dichloro quinoxaline = 630 21.06-chloro quinoxaline = 862 28.7Dimethyl formamide = 1250 41.7Dimethyl formamide = 2300 76.7Ethyl-2-chloropropionate = 432 14.4Hydroquinone = 350 11.7Methanol = 1200 40.0Potassium carbonate = 470 15.7Sodium hydroxide (98%) = 154 5.1
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgAcetonitrile = 1200 600.0Bromotrifluoromethane (gas) = 960 480.0Sodium hydroxide (98%) = 265 132.5Sodium phosphate = 375 187.5Sodiumdithionite (85%) = 1320 660.0
PRODUCT : Quizalofop EthylLIST OF RAW MATERIALS
PRODUCT : Sodium Trifluoromethane SulfinateLIST OF RAW MATERIALS
ANNEXURE - XVI
144
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg4-tertiarybutyl benzyl amine = 545 36.3Dichloromethane = 844 56.3Diethyl oxalate = 620 41.3Dimethyl sulphate = 525 35.0Hydrazine hydrate (80%) = 248 16.5Methanol = 1500 100.0Methyl ethyl ketone = 300 20.0Sodium ethoxide (21%) in ethanol = 276 18.4Sodium Hydroxide (25%) = 540 36.0Sodium hydroxide(30%) = 1110 74.0Sulfuryl chloride = 570 38.0Thionyl chloride = 396 26.4Toluene = 2126 141.7
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgCaustic Lye (48%) = 1125 812.6Dichloromethane = 1450 1047.4Methanol = 2000 1444.7Methomyl Oxime = 725 523.7Mixed Xylene = 3100 2239.3N-methyl carbamoyl chloride = 660 476.7Pyridine = 500 361.2Sulfur dichloride = 330 238.4
PRODUCT : TebufenpyradLIST OF RAW MATERIALS
PRODUCT : ThiodicarbLIST OF RAW MATERIALS
ANNEXURE - XVI
145
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg3-chloro-4-toluidine = 616 410.7Dichloromethane = 2556 1704.0Ethyl acetate = 394 262.7Hydrazine hydrate (82%) = 275 183.3Hydrochloric acid (32%) = 547 364.7Methylacetoacetate = 518 345.3Sodium Hydroxide (48 %) = 585 390.0Sodium methoxide (28% in Methanol) = 926 617.3Thionyl chloride = 1060 706.7
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgDichloromethane = 750 75.0Diethyl oxalate = 550 55.0Dimethyl sulphate = 475 47.5Hydrazine hydrate (80%) = 220 22.0Hydrogen gas = 14 1.4Methanol = 2500 250.0Methyl ethyl ketone = 270 27.0Palladium carbon = 10 1.0p-Chlorobenzonitrile = 461 46.1p-Cresol = 362 36.2Sodium ethoxide (21%) in ethanol = 245 24.5Sodium Hydroxide (25%) = 550 55.0Sodium hydroxide (48%) = 335 33.5Sodium hydroxide(30%) = 1000 100.0Sulfuryl chloride = 507 50.7Thionyl chloride = 352 35.2TOBA crude = 713 71.3Toluene = 2750 275.0
PRODUCT : TiadinilLIST OF RAW MATERIALS
PRODUCT : TolfenpyradLIST OF RAW MATERIALS
ANNEXURE - XVI
146
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-Hydrazino-4-Methyl Benzothiazole = 1000 1166.7Formic Acid = 2400 2800.0
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-methyl-4-chloro-N- = 460 76.73-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid = 700 116.7
3-Picoline = 215 35.8Acetonitrile = 1400 233.3Dichloromethane = 1000 166.7Methane sulfonylchloride = 263 43.8Methanol = 1200 200.0Sodium Hydroxide(30%) = 615 102.5
PRODUCT : TricyclazoleLIST OF RAW MATERIALS
PRODUCT : ChlorantraniliproleLIST OF RAW MATERIALS
ANNEXURE - XVI
147
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgEthylene Dichloride = 1000 33.3Methyl Amine (40%) = 376 12.5O,O-dimethyl S-[methylaceto] dithiophosphate = 1116 37.2
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg KgDiethyl Thiophosphoric Acid = 1073 35.8Methylene Dibromide = 502 16.7Sodium Hydroxide (35%) = 660 22.0Toluene = 700 23.3
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg1,2,4-Triazole = 246 8.22,4-Dichloro Valerophenone = 825 27.5Dimethyl Formamide = 1400 46.7Dimethyl Sulfate = 1050 35.0Ethylacetate = 1000 33.3Potassium Carbonate = 83 2.8Potassium Hydroxide = 220 7.3
PRODUCT : DimethoateLIST OF RAW MATERIALS
PRODUCT : EthionLIST OF RAW MATERIALS
PRODUCT : HEXACONAZOLELIST OF RAW MATERIALS
ANNEXURE - XVI
148
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-(2,2-Difluoroethoxy)-6-(trifluoromethyl) benzene-1-sulfonylchloride = 750 50
2-amino-5,8-dimethoxy-[1,2,4]triazolo[1,5-c] pyrimidine = 450 30
Acetonitrile = 1500 100Dichloromethane = 1000 67Methanol = 1200 80Pyridine = 182 12Sodium Hydroxide (30%) = 308 21
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2,6-Diethyl Aniline = 560 186.7Chloro Acetyl Chloride = 390 130.0Hexane = 1000 333.3Hydrochloric acid (32%) = 375 125.0n-Propoxy Ethylchloride = 460 153.3Sodium Bicarbonate = 290 96.7Sodium Hydroxide (25%) = 600 200.0
PRODUCT : PenoxsulamLIST OF RAW MATERIALS
PRODUCT : PretilachlorLIST OF RAW MATERIALS
ANNEXURE - XVI
149
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg[2-Ethylsulfonyl imidazo [1,2-a] pyridine-3-sulfonamide] 1 641 21.4
[4,6-Dimethoxy-2-(phenoxycarbonylamino)-pyrimidine] 1 610 20.3
Acetone = 2564 85.5C S Lye (30%) = 300 10.0Hydrochloric acid(32%) = 256 8.5
Raw Material
Consumption of Raw Material /
Batch of Product
Daily Consumption of
Raw Material
Kg Kg2-Chloro-(5-chloromethyl)thiazole = 606 202.03-methyl-4-nitroiminoperhydro-1,3,5-oxadiazine = 577.5 192.5
Methanol = 1250 416.7Potassium carbonate = 497.8 165.9Toluene = 750 250.0
PRODUCT : SulfosulfuronLIST OF RAW MATERIALS
PRODUCT : ThiamethoxamLIST OF RAW MATERIALS
ANNEXURE - XVI
150
LIST OF HAZARDOUS RAW MATERIALS
Raw Material
Acetic acid Acetic AnhydrideAcetoneAcetonitrileAmmonia (25%)Chloro acetic acidChloro Acetyl ChlorideDichloromethaneDiethyl oxalateDimethyl amine (40%)Dimethyl formamideDimethyl SulfateEthyl AcetateEthylene dichlorideFormic Acid Hydrazine hydrate (82%)Hydrochloric acid (32%)Hydrogen chloride gasHydrogen gasHydrogen Peroxide (30%)Isopropyl bromideMethane sulfonylchlorideMethanolMethyl Amine (40%)Methyl ethyl ketoneMethylene DibromideMethylene DichlorideMethylisobutyl ketoneMixed Xylenen-Butanoln-HexaneO-xylenePhenolPhosphrous oxychloridePotassium BisulphatePotassium CarbonatePyridineSodium BicarbonateSodium NitriteSulfuric AcidSulfuryl Chloridet-butyl amineTetrahydrafuronThionyl chlorideTolueneTriethylamine
ANNEXURE - XVII
151
ANNEXURE - XVIII
152
Effluent Treatment Flow Scheme - ZLD
ANNEXURE - XIX
153
Schematic flow Sheet for EIA Procedure
Time schedule for obtaining the EC from MOEF
Submission of application by proponent (Form 1, Pre-feasilibility report and Draft Terms of Reference)
Scrutiny by EAC
Scoping an communication of Terms of Reference for EIA Studies to the Proponent for EIA preparation
Submission of proceedings of the public hearing by the SPCB / PCC to EAC
Conducting public hearing by SPCB / PCC or any other public Agency / authority engaged by regulatory authority
Submission of Draft EIA / Summary EIA / Application for Public consultation
Appraisal by EAC
Submission of final EIA by the proponent after improving EIA / EMP
Decision of MoEF
Decision of MoEF
Specific Concerns
Yes NO Rejection
Issuing clearance to project proponent
60 days
45 days
60 days
Scop
ing
Publ
ic C
onsu
ltanc
y De
cisio
n M
akin
g Ap
prai
sal
Reservation on the proposal conveyed to EAC
EAC views on reservations sent to MoEF
45 days
60 days
30 days
Category A Project
Preparation of FORM I Application & Prefeasibility report
30 days on obtaining information from industry
as per check list
Preparation of Draft EIA report 120 days minimum other than monsoon period of 120 days
30 days for preparation of Final REIA Maximum
ANNEXURE - XX
154
Environmental Baseline Monitoring (To Establish quality of the
Environment)
Application of Impact Prediction Tools (Quantitative Significance Analysis)
Identification of Likely Impacts (Quantitative Significance Analysis
(Ref: Impact Matrix)
EIA Team
Social Impact Assessment
Risk Assessment
Project Features (Pre-feasibility Report,
Form1)
Valued Environment Components
Mitigation Measures
Environmental Management Plan
Reporting
Approach of EIA Study – 4 months other than monsoon period after obtaining TOR copy from MOEF
ANNEXURE - XX
155
ANNEXURE - XXI
156
ANNEXURE - XXII
157